LIGHT-EMITTING DEVICE AND ELECTRONIC APPARATUS INCLUDING THE SAME

Abstract

Provided are a light-emitting device and an electronic apparatus including the same, the light-emitting device including: a first electrode; a second electrode facing the first electrode; and an emission layer between the first electrode and the second electrode. The emission layer includes i) a first emission layer and ii) a second emission layer located between the first emission layer and the second electrode, the first emission layer is in direct contact with the second emission layer, the first emission layer includes a dopant, a first hole-transporting compound, and a first compound, the second emission layer includes a dopant, a second hole-transporting compound, and a second compound, the dopant included in the first emission layer and the dopant included in the second emission layer are identical to each other, the first compound and the second compound are different from each other, and an absolute value of the difference between a HOMO energy level of the second hole-transporting compound and a HOMO energy level of the second compound is about 0.3 eV or less.

Claims

1. A light-emitting device comprising: a first electrode; a second electrode facing the first electrode; and an emission layer between the first electrode and the second electrode, wherein the emission layer comprises i) a first emission layer and ii) a second emission layer located between the first emission layer and the second electrode, the first emission layer is in direct contact with the second emission layer, the first emission layer comprises a dopant, a first hole-transporting compound, and a first compound, the second emission layer comprises a dopant, a second hole-transporting compound, and a second compound, the dopant included in the first emission layer and the dopant included in the second emission layer are identical to each other, the first compound and the second compound are different from each other, an absolute value of the difference between a highest occupied molecular orbital (HOMO) energy level of the second hole-transporting compound and a HOMO energy level of the second compound is about 0.3 eV or less, and a HOMO energy level of the second hole-transporting compound and a HOMO energy level of the second compound are each a negative value measured by using a photoelectron spectroscopy in air.

2. The light-emitting device of claim 1, wherein the dopant is a phosphorescent dopant.

3. The light-emitting device of claim 1, wherein the first hole-transporting compound and the second hole-transporting compound are different from each other.

4. The light-emitting device of claim 1, wherein the first hole-transporting compound and the second hole-transporting compound are identical to each other.

5. The light-emitting device of claim 1, wherein a minimum value of the HOMO energy level of the first hole-transporting compound and the HOMO energy level of the second hole-transporting compound is about −5.80 eV or more.

6. The light-emitting device of claim 1, wherein the HOMO energy level of the first hole-transporting compound and the HOMO energy level of the second hole-transporting compound are each about −5.80 eV or more.

7. The light-emitting device of claim 1, wherein the HOMO energy level of the first compound is smaller than the HOMO energy level of the second compound.

8. The light-emitting device of claim 1, wherein the HOMO energy level of the first compound and the HOMO energy level of the second compound are each about −6.15 eV or more.

9. The light-emitting device of claim 1, wherein the HOMO energy level of the second compound is about −6.00 eV or more.

10. The light-emitting device of claim 1, wherein the HOMO energy level of the second compound is about −5.80 eV or more.

11. The light-emitting device of claim 1, wherein an absolute value of the difference between the HOMO energy level of the second hole-transporting compound and the HOMO energy level of the second compound is about 0.16 eV or less.

12. The light-emitting device of claim 1, wherein a maximum value from among the HOMO energy level of the first hole-transporting compound, the HOMO energy level of the first compound, the HOMO energy level of the second hole-transporting compound, and the HOMO energy level of the second compound is smaller than a HOMO energy level of the dopant.

13. The light-emitting device of claim 1, wherein a HOMO energy level of the dopant is from about −5.60 eV to about −5.20 eV.

14. The light-emitting device of claim 1, wherein a thickness of the second emission layer is identical to a thickness of the first emission layer.

15. The light-emitting device of claim 1, wherein a thickness of the second emission layer is greater than a thickness of the first emission layer.

16. The light-emitting device of claim 1, wherein light emitted from the emission layer to the outside through at least one of the first electrode and the second electrode is not white light.

17. The light-emitting device of claim 1, wherein light emitted from the emission layer to the outside through at least one of the first electrode and the second electrode is green light having a maximum emission wavelength of about 500 nm to about 580 nm.

18. The light-emitting device of claim 1, further comprising a hole-transporting region located between the first electrode and the emission layer, wherein the hole-transporting region does not include a charge-generation layer and an emission layer.

19. The light-emitting device of claim 1, further comprising an electron-transporting region, which is located between the emission layer and the second electrode, wherein the electron-transporting region does not include a charge-generation layer and an emission layer.

20. An electronic apparatus comprising the light-emitting device of claim 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0020] The above and other aspects, features, and advantages of certain embodiments of the disclosure will be more apparent from the following description taken in conjunction with the accompanying drawings, in which:

[0021] FIG. 1 shows an exemplary diagram illustrating a highest occupied molecular orbital (HOMO) energy level of first hole-transporting compound (HOMO(HT1)), a HOMO energy level of a first compound (HOMO(ET)), a HOMO energy level of a second hole-transporting compound (HOMO(HT2)), a HOMO energy level of a second compound (HOMO(BP)), and a HOMO energy level of a dopant (HOMO(D)); and

[0022] FIG. 2 is a schematic view of an organic light-emitting device according to an exemplary embodiment.

DETAILED DESCRIPTION

[0023] Reference will now be made in detail to embodiments, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout the specification. In this regard, the present embodiments may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, the embodiments are merely described below, by referring to the figures, to explain aspects. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.

[0024] It will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present therebetween In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present

[0025] It will be understood that, although the terms “first,” “second,” “third” etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section Thus, “a first element,” “component,” “region,” “layer” or “section” discussed below could be termed a second element, component, region, layer or section without departing from the teachings herein.

[0026] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting. As used herein, “a,” “an,” “the,” and “at least one” do not denote a limitation of quantity, and are intended to cover both the singular and plural, unless the context clearly indicates otherwise. For example, “an element” has the same meaning as “at least one element,” unless the context clearly indicates otherwise.

[0027] “Or” means “and/or.” As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items It will be further understood that the terms “comprises” and/or “comprising,” or “includes” and/or “including” when used in this specification, specify the presence of stated features, regions, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, regions, integers, steps, operations, elements, components, and/or groups thereof.

[0028] Furthermore, relative terms, such as “lower” or “bottom” and “upper” or “top,” may be used herein to describe one element's relationship to another element as illustrated in the Figures It will be understood that relative terms are intended to encompass different orientations of the device in addition to the orientation depicted in the Figures For example, if the device in one of the figures is turned over, elements described as being on the “lower” side of other elements would then be oriented on “upper” sides of the other elements The exemplary term “lower,” can therefore, encompasses both an orientation of “lower” and “upper,” depending on the particular orientation of the figure Similarly, if the device in one of the figures is turned over, elements described as “below” or “beneath” other elements would then be oriented “above” the other elements The exemplary terms “below” or “beneath” can, therefore, encompass both an orientation of above and below.

[0029] “About” or “approximately” as used herein is inclusive of the stated value and means within an acceptable range of deviation for the particular value as determined by one of ordinary skill in the art, considering the measurement in question and the error associated with measurement of the particular quantity (i.e., the limitations of the measurement system). For example, “about” can mean within one or more standard deviations, or within ±30%, 20%, 10% or 5% of the stated value.

[0030] Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.

[0031] Exemplary embodiments are described herein with reference to cross section illustrations that are schematic illustrations of idealized embodiments As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected Thus, embodiments described herein should not be construed as limited to the particular shapes of regions as illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, a region illustrated or described as flat may, typically, have rough and/or nonlinear features Moreover, sharp angles that are illustrated may be rounded Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the precise shape of a region and are not intended to limit the scope of the present claims.

[0032] The light-emitting device may include: a first electrode; a second electrode facing the first electrode; and an emission layer located between the first electrode and the second electrode, wherein the emission layer may include i) a first emission layer; and ii) a second emission layer located between the first emission layer and the second electrode.

[0033] The first emission layer may be in direct contact with the second emission layer.

[0034] The first emission layer includes a dopant, a first hole-transporting compound, and a first compound, and the second emission layer includes a dopant, a second hole-transporting compound, and a second compound.

[0035] The dopant, the first hole-transporting compound, and the first compound included in the first emission layer may be different from each other.

[0036] The dopant, the second hole-transporting compound, and the second compound included in the second emission layer may be different from each other.

[0037] The total weight of the first hole-transporting compound and the first compound in the first emission layer may be greater than the weight of the dopant included in the first emission layer.

[0038] The total weight of the second hole-transporting compound and the second compound in the second emission layer may be greater than the weight of the dopant included in the second emission layer.

[0039] The dopant included in the first emission layer and the dopant included in the second emission layer may be identical to each other. The detailed description of the dopants is the same as described in the present specification.

[0040] In one or more embodiments, the dopant may be a phosphorescent dopant.

[0041] In one or more embodiments, the dopant may be a transition metal-containing organometallic compound.

[0042] In one or more embodiments, the dopant may be a transition metal-containing heteroleptic organometallic compound.

[0043] In one or more embodiments, the dopant may be an organometallic compound represented by Formula 1. Formula 1 will be described in detail later.

[0044] In one or more embodiments, the dopant includes a transition metal-containing organometallic compound, wherein the transition metal-containing organometallic compound includes a pyridine group, a benzimidazole group (or a naphthimidazole group), and a dibenzofuran group (or azadibenzofuran group, a dibenzothiophene group, or an azadibenzothiophene group), each of the pyridine group and the benzimidazole group (or a naphthimidazole group) may be attached to the transition metal of the transition metal-containing organometallic compound via nitrogen, and the dibenzofuran group (or azadibenzofuran group, a dibenzothiophene group, or an azadibenzothiophene group) may be attached to the transition metal of the transition metal-containing organometallic compound via carbon. The pyridine group, the benzimidazole group (or a naphthimidazole group), and the dibenzofuran group (or an azadibenzofuran group, a dibenzothiophene group, or an azadibenzothiophene group) may be optionally substituted with at least one R.sub.1. R.sub.1 is the same as described in connection with Formula 1.

[0045] In one or more embodiments, the dopant may be a transition metal-containing organometallic compound, and the transition metal-containing organometallic compound may include a group represented by —Si(Q.sub.3)(Q.sub.4)(Q.sub.5), a group represented by —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5), or any combination thereof. —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) and —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5) are the same as described in connection with Formula 1.

[0046] Each of the first hole-transporting compound and the second hole-transporting compound may include at least one π electron rich C.sub.3-C.sub.60 cyclic group (for example, π electron rich C.sub.6-C.sub.60 cyclic group, such as a carbazole group, an indolocarbazole group, a benzene group, etc.) and may not include an electron-transporting group. Examples of the electron-transporting group include a cyano group, a fluoro group, a π electron-deficient nitrogen-containing C.sub.1-C.sub.60 cyclic group (for example, a π electron-deficient nitrogen-containing C.sub.5-C.sub.60 cyclic group), a phosphine oxide group, and a sulfoxide group.

[0047] In one or more embodiments, the first hole-transporting compound and the second hole-transporting compound may each be a compound represented by Formula 5. Formula 5 will be described in detail later.

[0048] In one or more embodiments, the first hole-transporting compound and the second hole-transporting compound may be different from each other.

[0049] In one or more embodiments, the first hole-transporting compound and the second hole-transporting compound may be identical to each other.

[0050] The first compound included in the first emission layer and the second compound included in the second emission layer may be different from each other.

[0051] In one or more embodiments, the first compound may be an electron-transporting compound. For example, the first compound may be a compound containing at least one electron-transporting group. The electron-transporting group may be a cyano group, a fluoro group, a π electron-deficient nitrogen-containing C.sub.1-C.sub.60 cyclic group, a phosphine oxide group, a sulfoxide group, or a combination thereof.

[0052] In one or more embodiments, the first compound may be a compound represented by Formula 7. Formula 7 will be described in detail later.

[0053] The absolute value of the difference between the highest occupied molecular orbital (HOMO) energy level of the second hole-transporting compound included in the second emission layer and the HOMO energy level of the second compound included in the second emission layer may be about 0.3 eV or less. The second compound included in the second emission layer may be any compound that satisfies the absolute value relationship of the difference in HOMO energy levels as described above.

[0054] In one or more embodiments, the second compound may be a bipolar compound.

[0055] In one or more embodiments, the second compound may be a compound represented by Formula 9 below. Formula 9 is the same as described in the present specification.

[0056] The “HOMO energy level” is a found value measured by using a photoelectron spectroscopy in air, and is a negative value.

[0057] Hereinafter, the HOMO energy level relationship among the dopant, the first hole-transporting compound, the first compound, the second hole-transporting compound and the second compound will be described with reference to FIG. 1.

[0058] FIG. 1 shows an example of a diagram illustrating a highest occupied molecular orbital (HOMO) energy level of first hole-transporting compound (HOMO(HT1)), a HOMO energy level of a first compound (HOMO(ET)), a HOMO energy level of a second hole-transporting compound (HOMO(HT2)), a HOMO energy level of a second compound (HOMO(BP)), and a HOMO energy level of a dopant (HOMO(D)).

[0059] The “HOMO energy level” illustrated in FIG. 1 is a found value obtained by measuring by using a photoelectron spectroscopy in air, and is a negative value.

[0060] The HOMO energy level of the first hole-transporting compound (HOMO(HT1)) may be smaller than the HOMO energy level of the second hole-transporting compound (HOMO(HT2)).

[0061] The minimum value from among the HOMO energy level of the first hole-transporting compound (HOMO(HT1)) and the HOMO energy level of the second hole-transporting compound (HOMO(HT2)) may be about −5.80 eV or more.

[0062] For example, the minimum value from among the HOMO energy level of the first hole-transporting compound (HOMO (HT1)) and the HOMO energy level of the second hole-transporting compound (HOMO (HT2)) may be about −5.80 eV or more, from about −5.80 eV to about −5.30 eV, from about −5.80 eV to about −5.40 eV, from about −5.70 eV to about −5.20 eV, from about −5.65 eV to about −5.20 eV, from about −5.70 eV to about −5.30 eV, from about −5.70 eV to about −5.40 eV, or from about −5.65 eV to about −5.45 eV.

[0063] In one or more embodiments, the HOMO energy level of the first hole-transporting compound (HOMO(HT1)) and the HOMO energy level of the second hole-transporting compound (HOMO(HT2)) may each be about −5.80 eV or more.

[0064] For example, the HOMO energy level of the first hole-transporting compound (HOMO(HT1)) and the HOMO energy level of the second hole-transporting compound (HOMO(HT2)) may each be about −5.80 eV or more, from about −5.80 eV to about −5.30 eV, from about −5.80 eV to about −5.40 eV, from about −5.70 eV to about −5.20 eV, from about −5.65 eV to about −5.20 eV, from about −5.70 eV to about −5.30 eV, from about −5.70 eV to about −5.40 eV, or from about −5.65 eV to about −5.45 eV.

[0065] The HOMO energy level of the first compound (HOMO(ET)) may be smaller than the HOMO energy level of the second compound (HOMO(BP)).

[0066] For example, the HOMO energy level of the first compound (HOMO(ET)) and the HOMO energy level of the second compound (HOMO(BP)) may be about −6.15 eV or more, or about −6.08 eV or more, respectively.

[0067] In one or more embodiments, the HOMO energy level of the second compound (HOMO(BP)) may be about −6.00 eV or more, about −5.90 eV or more, or about −5.80 eV or more.

[0068] The absolute value of the difference (ΔHOMO2) between the HOMO energy level of the second hole-transporting compound (HOMO(HT2)) and the HOMO energy level of the second compound (HOMO(BP)) may be about 0.30 eV or less, about 0.20 eV or less, about 0.16 eV or less, from about 0.001 eV to about 0.30 eV, from about 0.001 eV to about 0.20 eV, from about 0.001 eV to about 0.16 eV, from about 0.01 eV to about 0.20 eV, from about 0.01 eV to about 0.16 eV, from about 0.02 eV to about 0.16 eV, from about 0.03 eV to about 0.16 eV, from about 0.04 eV to about 0.16 eV, from about 0.05 eV to about 0.16 eV, from about 0.06 eV to about 0.16 eV, from about 0.07 eV to about 0.16 eV, from about 0.08 eV to about 0.16 eV, or from about 0.09 eV to about 0.16 eV.

[0069] The maximum value from among the HOMO energy level of the first hole-transporting compound (HOMO(HT1)), the HOMO energy level of the first compound (HOMO(ET)), the HOMO energy level of the second hole-transporting compound (HOMO(HT2)), and the HOMO energy level of the second compound (HOMO(BP)) may be smaller than the HOMO energy level of the dopant (HOMO(D)).

[0070] For example, the HOMO energy level of the dopant (HOMO(D)) may be from about −5.60 eV to about −5.20 eV, for ex ample, about −5.50 eV to about −5.25 eV.

[0071] In one or more embodiments, the first hole-transporting compound and the second hole-transporting compound may be different from each other, and may satisfy the condition of, as illustrated in FIG. 1, HOMO(D)>HOMO(HT2)>HOMO(HT1)>HOMO(BP)>HOMO(ET).

[0072] In the light-emitting device including the emission layer including the first emission layer and the second emission layer as described above, hole mobility in the second emission layer is improved, the electrical resistance of the emission layer is lowered when the light-emitting device is driven, and the exciton distribution into the second emission layer may be enlarged. Accordingly, the light-emitting device may have excellent characteristics in terms of driving voltage, luminescence efficiency, roll-off ratio and/or lifespan.

[0073] In one or more embodiments, in the second emission layer, the weight of the second compound may be the same as the weight of the second hole-transporting compound. In one or more embodiments, in the second emission layer, the weight of the second compound in the second emission layer may be greater than the weight of the second hole-transporting compound. In one or more embodiments, in the second emission layer, the weight of the second compound in the second emission layer may be less than the weight of the second hole-transporting compound. In one or more embodiments, in the second emission layer, the weight ratio of the second hole-transporting compound to the second compound may be from 2:8 to 8:2, for example, 3:7 to 7:3, or 4:6 to 6:4, or 5:5.

[0074] In one or more embodiments, the thickness of the second emission layer may be the same as the thickness of the first emission layer.

[0075] In one or more embodiments, the thickness of the second emission layer may be greater than the thickness of the first emission layer.

[0076] In one or more embodiments, the light emitted from the emission layer to the outside through at least one of the first electrode and the second electrode may not be white light.

[0077] In one or more embodiments, the light emitted from the emission layer to the outside through at least one of the first electrode and the second electrode may be green light having a maximum emission wavelength of about 500 nm to about 580 nm.

[0078] In one or more embodiments, the light-emitting device may further include a hole-transporting region located between the first electrode and the emission layer, and the hole-transporting region may not include a charge-generation layer or an emission layer. The hole-transporting region may include a hole injection layer, a hole-transporting layer, an electron-blocking layer, a buffer layer, or a combination thereof.

[0079] In one or more embodiments, the light-emitting device may further include an electron-transporting region located between the emission layer and the second electrode, and the electron-transporting region may not include a charge-generation layer and an emission layer. The electron-transporting region may include a hole-blocking layer, an electron-transporting layer, an electron injection layer, or any combination thereof.

[0080] In one or more embodiments, the emission layer may not include compounds of Group A:

##STR00001## ##STR00002## ##STR00003## ##STR00004## ##STR00005## ##STR00006##

[0081] The first electrode may be an anode, which is a hole injection electrode, and the second electrode may be a cathode, which is an electron injection electrode; or the first electrode may be a cathode, which is an electron injection electrode, and the second electrode may be an anode, which is a hole injection electrode.

Description of Formula 1

[0082] Formula 1 is shown below.

M(L.sub.1).sub.n1(L.sub.2).sub.n2

[0083] M in Formula 1 may be a transition metal.

[0084] For example, M may be a Period 1 transition metal, a Period 2 transition metal, or a Period 3 transition metal of the Periodic Table of Elements.

[0085] In one or more embodiments, M may be iridium (Ir), platinum (Pt), osmium (Os), titanium (Ti), zirconium (Zr), hafnium (Hf), europium (Eu), terbium (Tb), thulium (Tm)), or rhodium (Rh).

[0086] In one or more embodiments, M may be Ir, Pt, Os, or Rh.

[0087] In Formula 1, L.sub.1 may be a ligand represented by Formula 2A, and L.sub.2 may be a ligand represented by Formula 2B:

##STR00007##

[0088] Formulae 2A and 2B are the same as described in the present specification.

[0089] n1 in Formula 1 may be 1, 2, or 3, wherein, when n1 is 2 or more, two or more of Li(s) may be identical to or different from each other.

[0090] n2 in Formula 1 may be 0, 1, or 2, wherein, when n2 is 2, two L.sub.2(s) may be identical to or different from each other.

[0091] The sum of n1 and n2 in Formula 1 may be 2 or 3. For example, the sum of the n1 and n2 may be 3.

[0092] In one or more embodiments, in Formula 1, i) M may be Ir, and the sum of n1 and n2 may be 3; or ii) M may be Pt, and the sum of n1 and n2 may be 2.

[0093] In one or more embodiments, in Formula 1, M may be Ir, and i) n1 may be 1 and n2 may be 2, or ii) n1 may be 2 and n2 may be 1.

[0094] L.sub.1 and L.sub.2 in Formula 1 may be different from each other.

[0095] Y.sub.1 to Y.sub.4 in Formulae 2A to 2B may be each independently be C or N. For example, Y.sub.1 and Y.sub.3 may each be N, and Y.sub.2 and Y.sub.4 may each be C.

[0096] Ring CY.sub.1 to ring CY.sub.4 in Formulae 2A and 2B may each independently be a C.sub.5-C.sub.30 carbocyclic group or a C.sub.1-C.sub.30 heterocyclic group.

[0097] For example, ring CY.sub.1 to ring CY.sub.4 may each independently be, i) a third ring, ii) a fourth ring, iii) a condensed ring in which two or more third rings are condensed with each other, iv) a condensed ring in which two or more fourth rings are condensed with each other, or v) a condensed ring in which one or more third rings and one or more fourth rings are condensed with each other,

[0098] the third ring may be a cyclopentane group, a cyclopentene group, a furan group, a thiophene group, a pyrrole group, a silole group, a borole group, a phosphole group, a germole group, a selenophene group, an oxazole group, an oxadiazole group, an oxatriazole group, a thiazole group, a thiadiazole group, a thiatriazole group, a pyrazole group, an imidazole group, a triazole group, a tetrazole group, or an azasilole group, and

[0099] the fourth ring may be an adamantane group, a norbornane group, a norbornene group, a cyclohexane group, a cyclohexene group, a benzene group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, or a triazine group.

[0100] In one or more embodiments, ring CY.sub.1 to ring CY.sub.4 may each independently be a cyclopentane group, a cyclohexane group, a cyclohexene group, a benzene group, a naphthalene group, an anthracene group, a phenanthrene group, a triphenylene group, a pyrene group, a chrysene group, a 1,2,3,4-tetrahydronaphthalene group, a cyclopentadiene group, a pyrrole group, a furan group, a thiophene group, a silole group, a borole group, a phosphole group, a germole group, a selenophene group, an indene group, an indole group, a benzofuran group, a benzothiophene group, a benzosilole group, a benzoborole group, a benzophosphole group, a benzogermole group, a benzoselenophene group, a fluorene group, a carbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzosilole group, a dibenzoborole group, a dibenzophosphole group, a dibenzogermole group, a dibenzoselenophene group, a benzofluorene group, a benzocarbazole group, a naphthobenzofuran group, a naphthobenzothiophene group, a naphthobenzosilole group, a naphthobenzoborole group, a naphthobenzophosphole group, a naphthobenzogermole group, a naphthobenzoselenophene group, a dibenzofluorene group, a dibenzocarbazole group, a dinaphthofuran group, a dinaphthothiophene group, a dinaphthosilole group, a dinaphthoborole group, a dinaphthophosphole group, a dinaphthogermole group, a dinaphthoselenophene group, an indenophenanthrene group, an indolophenanthrene group, a phenanthrobenzofuran group, a phenanthrobenzothiophene group, a phenanthrobenzosilole group, a phenanthrobenzoborole group, a phenanthrobenzophosphole group, a phenanthrobenzogermole group, a phenanthrobenzoselenophene group, a dibenzothiophene 5-oxide group, a 9H-fluorene-9-one group, a dibenzothiophene 5,5-dioxide group, an azaindene group, an azaindole group, an azabenzofuran group, an azabenzothiophene group, an azabenzosilole group, an azabenzoborole group, an azabenzophosphole group, an azabenzogermole group, an azabenzoselenophene group, an azafluorene group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzogermole group, an azadibenzoselenophene group, an azabenzofluorene group, an azabenzocarbazole group, an azanaphthobenzofuran group, an azanaphthobenzothiophene group, an azanaphthobenzosilole group, an azanaphthobenzoborole group, an azanaphthobenzophosphole group, an azanaphthobenzogermole group, an azanaphthobenzoselenophene group, an azadibenzofluorene group, an azadibenzocarbazole group, an azadinaphthofuran group, an azadinaphthothiophene group, an azadinaphthosilole group, an azadinaphthoborole group, an azadinaphthophosphole group, an azadinaphthogermole group, an azadinaphthoselenophene group, an azaindenophenanthrene group, an azaindolophenanthrene group, an azaphenanthrobenzofuran group, an azaphenanthrobenzothiophene group, an azaphenanthrobenzosilole group, an azaphenanthrobenzoborole group, an azaphenanthrobenzophosphole group, an azaphenanthrobenzogermole group, an azaphenanthrobenzoselenophene group, an azadibenzothiophene 5-oxide group, an aza9H-fluorene-9-one group, an azadibenzothiophene 5,5-dioxide group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, a triazine group, a quinoline group, an isoquinoline group, a quinoxaline group, a quinazoline group, a benzoquinoline group, a benzoisoquinoline group, a benzoquinoxaline group, a benzoquinazoline group, a phenanthroline group, a phenanthridine group, a pyrrole group, a pyrazole group, an imidazole group, a triazole group, an oxazole group, an isooxazole group, a thiazole group, an isothiazole group, an oxadiazole group, a thiadiazole group, an azasilole group, an azaborole group, an azaphosphole group, an azagermole group, an azaselenophene group, a benzopyrrole group, a benzopyrazole group, a benzimidazole group, a benzoxazole group, a benzisoxazole group, a benzothiazole group, a benzisothiazole group, a benzoxadiazole group, a benzothiadiazole group, a pyridinopyrrole group, a pyridinopyrazole group, a pyridinoimidazole group, a pyridinooxazole group, a pyridinoisoxazole group, a pyridinothiazole group, a pyridinoisothiazole group, a pyridinooxadiazole group, a pyridinothiadiazole group, a pyrimidinopyrrole group, a pyrimidinopyrazole group, a pyrimidinoimidazole group, a pyrimidinooxazole group, a pyrimidinoisoxazole group, a pyrimidinothiazole group, a pyrimidinoisothiazole group, a pyrimidinooxadiazole group, a pyrimidinothiadiazole group, a 5,6,7,8-tetrahydroisoquinoline group, a 5,6,7,8-tetrahydroquinoline group, an adamantane group, a norbornane group, a norbornene group, a benzene group condensed with a cyclohexane group, a benzene group condensed with a norbornane group, a pyridine group condensed with a cyclohexane group, or a pyridine group condensed with a norbornane group.

[0101] In one or more embodiments, ring CYC may be an azaindene group, an azaindole group, an azabenzofuran group, an azabenzothiophene group, an azabenzosilole group, an azabenzoborole group, an azabenzophosphole group, an azabenzogermole group, an azabenzoselenophene group, an azafluorene group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzogermole group, an azadibenzoselenophene group, an azabenzofluorene group, an azabenzocarbazole group, an azanaphthobenzofuran group, an azanaphthobenzothiophene group, an azanaphthobenzosilole group, an azanaphthobenzoborole group, an azanaphthobenzophosphole group, an azanaphthobenzogermole group, an azanaphthobenzoselenophene group, an azadibenzofluorene group, an azadibenzocarbazole group, an azadinaphthofuran group, an azadinaphthothiophene group, an azadinaphthosilole group, an azadinaphthoborole group, an azadinaphthophosphole group, an azadinaphthogermole group, an azadinaphthoselenophene group, an azaindenophenanthrene group, an azaindolophenanthrene group, an azaphenanthrobenzofuran group, an azaphenanthrene benzothiophene group, an azaphenanthrobenzosilole group, an azaphenanthrobenzoborole group, an azaphenanthrobenzophosphole group, an azaphenanthrobenzogermole group, an azaphenanthrobenzoselenophene group, an azadibenzothiophene 5-oxide group, an aza9H-fluorene-9-one group, an azadibenzothiophene 5,5-dioxide group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, a triazine group, a quinoline group, an isoquinoline group, a quinoxaline group, a quinazoline group, a benzoquinoline group, a benzoisoquinoline group, a benzoquinoxaline group, a benzoquinazoline group, a phenanthroline group, a phenanthridine group, a pyrrole group, a pyrazole group, an imidazole group, a triazole group, an oxazole group, an isooxazole group, a thiazole group, an isothiazole group, an oxadiazole group, a thiadiazole group, an azasilole group, an azaborole group, an azaphosphole group, an azagermole group, an azaselenophene group, a benzopyrrole group, a benzopyrazole group, a benzimidazole group, a benzoxazole group, a benzisoxazole group, a benzothiazole group, a benzisothiazole group, a benzoxadiazole group, a benzothiadiazole group, a pyridinopyrrole group, a pyridinopyrazole group, a pyridinoimidazole group, a pyridinooxazole group, a pyridinoisoxazole group, a pyridinothiazole group, a pyridinoisothiazole group, a pyridinooxadiazole group, a pyridinothiadiazole group, a pyrimidinopyrrole group, a pyrimidinopyrazole group, a pyrimidinoimidazole group, a pyrimidinooxazole group, a pyrimidinoisoxazole group, a pyrimidinothiazole group, a pyrimidinoisothiazole group, a pyrimidinooxadiazole group, a pyrimidinothiadiazole group, a 5,6,7,8-tetrahydroisoquinoline group, a 5,6,7,8-tetrahydroquinoline group, a pyridine group condensed with a cyclohexane group, or a pyridine group condensed with a norbornane group.

[0102] In one or more embodiments, ring CY.sub.2 and CY.sub.4 may each independently be a cyclopentane group, a cyclohexane group, a cyclohexene group, a benzene group, a naphthalene group, an anthracene group, a phenanthrene group, a triphenylene group, a pyrene group, a chrysene group, a 1,2,3,4-tetrahydronaphthalene group, a cyclopentadiene group, a pyrrole group, a furan group, a thiophene group, a silole group, a borole group, a phosphole group, a germole group, a selenophene group, an indene group, an indole group, a benzofuran group, a benzothiophene group, a benzosilole group, a benzoborole group, a benzophosphole group, a benzogermole group, a benzoselenophene group, a fluorene group, a carbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzosilole group, a dibenzoborole group, a dibenzophosphole group, a dibenzogermole group, a dibenzoselenophene group, a benzofluorene group, a benzocarbazole group, a naphthobenzofuran group, a naphthobenzothiophene group, a naphthobenzosilole group, a naphthobenzoborole group, a naphthobenzophosphole group, a naphthobenzogermole group, a naphthobenzoselenophene group, a dibenzofluorene group, a dibenzocarbazole group, a dinaphthofuran group, a dinaphthothiophene group, a dinaphthosilole group, a dinaphthoborole group, a dinaphthophosphole group, a dinaphthogermole group, a dinaphthoselenophene group, an indenophenanthrene group, an indolophenanthrene group, a phenanthrobenzofuran group, a phenanthrobenzothiophene group, a phenanthrobenzosilole group, a phenanthrobenzoborole group, a phenanthrobenzophosphole group, a phenanthrobenzogermole group, a phenanthrobenzoselenophene group, a dibenzothiophene 5-oxide group, a 9H-fluorene-9-one group, a dibenzothiophene 5,5-dioxide group, an azaindene group, an azaindole group, an azabenzofuran group, an azabenzothiophene group, an azabenzosilole group, an azabenzoborole group, an azabenzophosphole group, an azabenzogermole group, an azabenzoselenophene group, an azafluorene group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzogermole group, an azadibenzoselenophene group, an azabenzofluorene group, an azabenzocarbazole group, an azanaphthobenzofuran group, an azanaphthobenzothiophene group, an azanaphthobenzosilole group, an azanaphthobenzoborole group, an azanaphthobenzophosphole group, an azanaphthobenzogermole group, an azanaphthobenzoselenophene group, an azadibenzofluorene group, an azadibenzocarbazole group, an azadinaphthofuran group, an azadinaphthothiophene group, an azadinaphthosilole group, an azadinaphthoborole group, an azadinaphthophosphole group, an azadinaphthogermole group, an azadinaphthoselenophene group, an azaindenophenanthrene group, an azaindolophenanthrene group, an azaphenanthrobenzofuran group, an azaphenanthrobenzothiophene group, an azaphenanthrobenzosilole group, an azaphenanthrobenzoborole group, an azaphenanthrobenzophosphole group, an azaphenanthrobenzogermole group, an azaphenanthrobenzoselenophene group, an azadibenzothiophene 5-oxide group, an aza9H-fluorene-9-one group, an azadibenzothiophene 5,5-dioxide group, a pyridine group, an adamantane group, a norbornane group, a norbornene group, a benzene group condensed with a cyclohexane group, or a benzene group condensed with a norbornane group.

[0103] In one or more embodiments, ring CY.sub.3 may be an azaindene group, an azaindole group, an azabenzofuran group, an azabenzothiophene group, an azabenzosilole group, an azabenzoborole group, an azabenzophosphole group, an azabenzogermole group, an azabenzoselenophene group, an azafluorene group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzogermole group, an azadibenzoselenophene group, an azabenzofluorene group, an azabenzocarbazole group, an azanaphthobenzofuran group, an azanaphthobenzothiophene group, an azanaphthobenzosilole group, an azanaphthobenzoborole group, an azanaphthobenzophosphole group, an azanaphthobenzogermole group, an azanaphthobenzoselenophene group, an azadibenzofluorene group, an azadibenzocarbazole group, an azadinaphthofuran group, an azadinaphthothiophene group, an azadinaphthosilole group, an azadinaphthoborole group, an azadinaphthophosphole group, an azadinaphthogermole group, an azadinaphthoselenophene group, an azaindenophenanthrene group, an azaindolophenanthrene group, an azaphenanthrobenzofuran group, an azaphenanthrobenzothiophene group, an azaphenanthrobenzosilole group, an azaphenanthrobenzoborole group, an azaphenanthrobenzophosphole group, an azaphenanthrobenzogermole group, an azaphenanthrobenzoselenophene group, an azadibenzothiophene 5-oxide group, an aza9H-fluorene-9-one group, an azadibenzothiophene 5,5-dioxide group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, a triazine group, a quinoline group, an isoquinoline group, a quinoxaline group, a quinazoline group, a benzoquinoline group, a benzoisoquinoline group, a benzoquinoxaline group, a benzoquinazoline group, a phenanthroline group, a phenanthridine group, a 5,6,7,8-tetrahydroquinoline group, a pyridine group condensed with a cyclohexane group, or a pyridine group condensed with a norbornane group.

[0104] In one or more embodiments, ring CYC of Formula 2A may be a pyridine group, a benzimidazole group, a pyridinoimidazole group, or a pyrimidinoimidazole group.

[0105] In one or more embodiments, ring CY.sub.2 in Formula 2A may be a fluorene group, a carbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzosilole group, a dibenzoborole group, a dibenzophosphole group, a dibenzogermole group, a dibenzoselenophene group, a benzofluorene group, a benzocarbazole group, a naphthobenzofuran group, a naphthobenzothiophene group, a naphthobenzosilole group, a naphthobenzoborole group, a naphthobenzophosphole group, a naphthobenzogermole group, a naphthobenzoselenophene group, a dibenzofluorene group, a dibenzocarbazole group, a dinaphthofuran group, a dinaphthothiophene group, a dinaphthosilole group, a dinaphthoborole group, a dinaphthophosphole group, a dinaphthogermole group, a dinaphthoselenophene group, an indenophenanthrene group, an indolophenanthrene group, a phenanthrobenzofuran group, a phenanthrobenzothiophene group, a phenanthrobenzosilole group, a phenanthrobenzoborole group, a phenanthrobenzophosphole group, a phenanthrobenzogermole group, a phenanthrobenzoselenophene group, an azafluorene group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzogermole group, an azadibenzoselenophene group, an azabenzofluorene group, an azabenzocarbazole group, an azanaphthobenzofuran group, an azanaphthobenzothiophene group, an azanaphthobenzosilole group, an azanaphthobenzoborole group, an azanaphthobenzophosphole group, an azanaphthobenzogermole group, an azanaphthobenzoselenophene group, an azadibenzofluorene group, an azadibenzocarbazole group, an azadinaphthofuran group, an azadinaphthothiophene group, an azadinaphthosilole group, an azadinaphthoborole group, an azadinaphthophosphole group, an azadinaphthogermole group, an azadinaphthoselenophene group, an azaindenophenanthrene group, an azaindolophenanthrene group, an azaphenanthrobenzofuran group, an azaphenanthrobenzothiophene group, an azaphenanthrobenzosilole group, an azaphenanthrobenzoborole group, an azaphenanthrobenzophosphole group, an azaphenanthrobenzogermole group, or an azaphenanthrobenzoselenophene group.

[0106] In one or more embodiments, ring CY.sub.3 of Formula 2B may be a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, a triazine group, a 5,6,7,8-tetrahydroquinoline group, a pyridine group condensed with a cyclohexane group, or a pyridine group condensed with a norbornane group.

[0107] In one or more embodiments, ring CY.sub.4 of Formula 2B may be a benzene group, a naphthalene group, an anthracene group, a phenanthrene group, a triphenylene group, a pyrene group, a chrysene group, a 1,2,3,4-tetrahydronaphthalene group, a benzene group condensed with a cyclohexane group, or a benzene group condensed with a norbornane group.

[0108] For example, ring CY.sub.1 and ring CY.sub.3 in Formulae 2A and 2B may be different from each other.

[0109] In one or more embodiments, ring CY.sub.2 and ring CY.sub.4 in Formulae 2A and 2B may be different from each other.

[0110] In one or more embodiments, ring CY.sub.1 to ring CY.sub.4 may be different from each other.

[0111] R.sub.1 to R.sub.4 in Formulae 2A and 2B may each independently be hydrogen, deuterium, —F, —Cl, —Br, —I, —SF.sub.5, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.1-C.sub.60 alkylthio group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, —N(Q.sub.1)(Q.sub.2), —Si(Q.sub.3)(Q.sub.4)(Q.sub.5), —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5), —B(Q.sub.6)(Q.sub.7), —P(═O)(Q.sub.8)(Q.sub.9), or —P(Q.sub.8)(Q.sub.9). Q.sub.1 to Q.sub.9 are the same as described in the present specification.

[0112] In one or more embodiments, R.sub.1 to R.sub.4 in Formulae 2A and 2B may each independently be:

[0113] hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, —SF.sub.5, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, or a C.sub.1-C.sub.20 alkylthio group;

[0114] a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, or a C.sub.1-C.sub.20 alkylthio group, each substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.2]octyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptyl group, a (C.sub.1-C.sub.20 alkyl)cyclooctyl group, a (C.sub.1-C.sub.20 alkyl)adamantanyl group, a (C.sub.1-C.sub.20 alkyl)norbornanyl group, a (C.sub.1-C.sub.20 alkyl)norbornenyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentenyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexenyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptenyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[1.1.1]pentyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.1.1]hexyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.2]octyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, or any combination thereof; a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.2]octyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)a phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzoisothiazolyl group, a benzoxazolyl group, a benzoisoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, an azacarbazolyl group, an azadibenzofuranyl group or azadibenzothiophenyl group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a (phenyl)C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.2]octyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptyl group, a (C.sub.1-C.sub.20 alkyl)cyclooctyl group, a (C.sub.1-C.sub.20 alkyl)adamantanyl group, a (C.sub.1-C.sub.20 alkyl)norbornanyl group, a (C.sub.1-C.sub.20 alkyl)norbornenyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentenyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexenyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptenyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[1.1.1]pentyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.1.1]hexyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.2]octyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzoisothiazolyl group, a benzoxazolyl group, a benzoisoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, an azacarbazolyl group, an azadibenzofuranyl group, an azadibenzothiophenyl group, or any combination thereof; or

[0115] —N(Q.sub.1)(Q.sub.2), —Si(Q.sub.3)(Q.sub.4)(Q.sub.5), —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5), —B(Q.sub.6)(Q.sub.7), —P(═O)(Q.sub.8)(Q.sub.9) or —P(Q.sub.8)(Q.sub.9),

[0116] wherein Q.sub.1 to Q.sub.9 are each independently:

[0117] —CH.sub.3, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CH.sub.2CH.sub.3, —CH.sub.2CD.sub.3, —CH.sub.2CD.sub.2H, —CH.sub.2CDH.sub.2, —CHDCH.sub.3, —CHDCD.sub.2H, —CHDCDH.sub.2, —CHDCD.sub.3, —CD.sub.2CD.sub.3, —CD.sub.2CD.sub.2H, or —CD.sub.2CDH.sub.2; or

[0118] an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, a phenyl group, a biphenyl group, or a naphthyl group, each unsubstituted or substituted with deuterium, a C.sub.1-C.sub.10 alkyl group, a phenyl group, or any combination thereof.

[0119] In one or more embodiments, R.sub.1 to R.sub.4 may each independently be:

[0120] hydrogen, deuterium, —F, or a cyano group;

[0121] a C.sub.1-C.sub.20 alkyl group unsubstituted or substituted with deuterium, a cyano group, a C.sub.3-C.sub.10 cycloalkyl group, a deuterated C.sub.3-C.sub.10 cycloalkyl group, a fluorinated C.sub.3-C.sub.10 cycloalkyl group, a (C.sub.1-C.sub.20 alkyl)C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a deuterated heterocycloalkyl group, a fluorinated C.sub.1-C.sub.10 heterocycloalkyl group, a (C.sub.1-C.sub.20 heterocycloalkyl group, a phenyl group, a deuterated a phenyl group, a fluorinated a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a deuterated a biphenyl group, a fluorinated a biphenyl group, a (C.sub.1-C.sub.20 alkyl)biphenyl group, a dibenzofuranyl group, a deuterated a dibenzofuranyl group, a fluorinated a dibenzofuranyl group, a (C.sub.1-C.sub.20 alkyl)dibenzofuranyl group, a dibenzothiophenyl group, a deuterated a dibenzothiophenyl group, a fluorinated a dibenzothiophenyl group, a (C.sub.1-C.sub.20 alkyl)dibenzothiophenyl group, or any combination thereof;

[0122] a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a phenyl group, or a biphenyl group, each unsubstituted or substituted with deuterium, a cyano group, a C.sub.1-C.sub.20 alkyl group, a deuterated C.sub.1-C.sub.20 alkyl group, fluorinated C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a deuterated alkoxy group, a fluorinated C.sub.1-C.sub.20 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a deuterated C.sub.3-C.sub.10 cycloalkyl group, a fluorinated C.sub.3-C.sub.10 cycloalkyl group, a (C.sub.1-C.sub.20 alkyl)C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a deuterated heterocycloalkyl group, a fluorinated C.sub.1-C.sub.10 heterocycloalkyl group, a (C.sub.1-C.sub.20 heterocycloalkyl group, a phenyl group, a deuterated phenyl group, a fluorinated a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a deuterated biphenyl group, a fluorinated a biphenyl group, a (C.sub.1-C.sub.20 alkyl)biphenyl group, a dibenzofuranyl group, a deuterated dibenzofuranyl group, a fluorinated a dibenzofuranyl group, a (C.sub.1-C.sub.20 alkyl)dibenzofuranyl group, a dibenzothiophenyl group, a deuterated dibenzothiophenyl group, a fluorinated a dibenzothiophenyl group, a (C.sub.1-C.sub.20 alkyl)dibenzothiophenyl group, or any combination thereof; or

[0123] —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5).

[0124] b1 to b4 in Formula 2A and 2B indicate the numbers of R.sub.1 to R.sub.4, respectively, and may each independently be an integer from 0 to 20. When b1 is 2 or more, two or more of R.sub.1(s) may be identical to or different from each other, when b2 is 2 or more, two or more of R.sub.2(s) may be identical to or different from each other, when b3 is 2 or more, two or more of R.sub.3(s) may be identical to or different from each other, and when b4 is 2 or more, two or more of R.sub.4(s) may be identical to or different from each other. For example, b1 to b4 may each independently be an integer from 0 to 8.

[0125] In one or more embodiments, n2 in Formula 1 may not be 0, b3 of Formula 2B may not be 0, and at least one of R.sub.3(s) in the number of b3 may be —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5). Q.sub.3 to Q.sub.5 are the same as described in the present specification.

[0126] For example, Q.sub.3 to Q.sub.5 may each independently be:

[0127] a C.sub.1-C.sub.60 alkyl group unsubstituted or substituted with deuterium, a C.sub.1-C.sub.60 alkyl group, a C.sub.6-C.sub.60 aryl group, or any combination thereof; or

[0128] a C.sub.6-C.sub.60 aryl group unsubstituted or substituted with deuterium, a C.sub.1-C.sub.60 alkyl group, a C.sub.6-C.sub.60 aryl group, or any combination thereof.

[0129] In one or more embodiments, Q.sub.3 to Q.sub.5 may each independently be:

[0130] —CH.sub.3, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CH.sub.2CH.sub.3, —CH.sub.2CD.sub.3, —CH.sub.2CD.sub.2H, —CH.sub.2CDH.sub.2, —CHDCH.sub.3, —CHDCD.sub.2H, —CHDCDH.sub.2, —CHDCD.sub.3, —CD.sub.2CD.sub.3, —CD.sub.2CD.sub.2H, or —CD.sub.2CDH.sub.2; or

[0131] an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, a phenyl group, a biphenyl group, or a naphthyl group, each unsubstituted or substituted with deuterium, a C.sub.1-C.sub.10 alkyl group, a phenyl group, or any combination thereof.

[0132] In one or more embodiments, Q.sub.3 to Q.sub.5 may be identical to each other.

[0133] In one or more embodiments, two or more of Q.sub.3 to Q.sub.5 may be different from each other.

[0134] In one or more embodiments, the organometallic compound represented by Formula 1 may include at least one deuterium.

[0135] In one or more embodiments, the organometallic compound represented by Formula 1 may satisfy at least one of Condition (1) to Condition (8):

[0136] Condition (1)

[0137] b1 in Formula 2A is not 0, and at least one of R.sub.1(s) in the number of b1 includes deuterium.

[0138] Condition (2)

[0139] b2 in Formula 2A is not 0, and at least one of R.sub.2(s) in the number of b2 includes deuterium.

[0140] Condition (3)

[0141] b3 in Formula 2B is not 0, and at least one of R.sub.3(s) in the number of b3 includes deuterium.

[0142] Condition (4)

[0143] b4 in Formula 2B is not 0, and at least one of R.sub.4(s) in the number of b4 includes deuterium.

[0144] Condition (5)

[0145] b1 in Formula 2A is not 0, and at least one of R.sub.1(s) in the number of b1 includes a fluoro group.

[0146] Condition (6)

[0147] b2 in Formula 2A is not 0, and at least one of R.sub.2(s) in the number of b2 includes a fluoro group.

[0148] Condition (7)

[0149] b3 in Formula 2B is not 0, and at least one of R.sub.3(s) in the number of b3 includes a fluoro group.

[0150] Condition (8)

[0151] b4 in Formula 2B is not 0, and at least one of R.sub.4(s) in the number of b4 includes a fluoro group

[0152] In one or more embodiments, R.sub.1 to R.sub.4 in Formulae 2A and 2B may each independently be hydrogen, deuterium, —F, a cyano group, a nitro group, —SF.sub.5, —CH.sub.3, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, —OCH.sub.3, —OCDH.sub.2, —OCD.sub.2H, —OCD.sub.3, —SCH.sub.3, —SCDH.sub.2, —SCD.sub.2H, —SCD.sub.3, a group represented by one of Formulae 9-1 to 9-39, a group represented by one of Formulae 9-1 to 9-39 in which at least one hydrogen is substituted with deuterium, a group represented by one of Formulae 9-1 to 9-39 in which at least one hydrogen is substituted with —F, a group represented by one of Formulae 9-201 to 9-230, a group represented by one of Formulae 9-201 to 9-230 in which at least one hydrogen is substituted with deuterium, a group represented by one of Formulae 9-201 to 9-230 in which at least one hydrogen is substituted with —F, a group represented by one of Formulae 10-1 to 10-145, a group represented by one of Formulae 10-1 to 10-145 in which at least one hydrogen is substituted with deuterium, a group represented by one of Formulae 10-1 to 10-145 in which at least one hydrogen is substituted with —F, a group represented by one of Formulae 10-201 to 10-354, a group represented by one of Formulae 10-201 to 10-354 in which at least one hydrogen is substituted with deuterium, a group represented by one of Formulae 10-201 to 10-354 in which at least one hydrogen is substituted with —F, —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5) (where Q.sub.3 to Q.sub.5 are the same as described in the present specification):

##STR00008## ##STR00009## ##STR00010## ##STR00011## ##STR00012## ##STR00013## ##STR00014## ##STR00015## ##STR00016## ##STR00017## ##STR00018## ##STR00019## ##STR00020## ##STR00021## ##STR00022## ##STR00023## ##STR00024## ##STR00025## ##STR00026## ##STR00027## ##STR00028## ##STR00029## ##STR00030## ##STR00031## ##STR00032##

##STR00033## ##STR00034## ##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039## ##STR00040## ##STR00041## ##STR00042## ##STR00043## ##STR00044## ##STR00045## ##STR00046## ##STR00047## ##STR00048## ##STR00049## ##STR00050## ##STR00051## ##STR00052## ##STR00053##

[0153] In Formulae 9-1 to 9-39, 9-201 to 9-230, 10-1 to 10-145 and 10-201 to 10-354, * indicates a binding site to a neighboring atom, Ph is a phenyl group, TMS is a trimethylsilyl group, TMG is a trimethylgermyl group, and OMe is a methoxy group.

[0154] The “group represented by one of Formulae 9-1 to 9-39 in which at least one hydrogen is substituted with deuterium” and the “group represented by one of Formulae 9-201 to 9-230 in which at least one hydrogen is substituted with deuterium” may be, for example, a group represented by one of Formulae 9-501 to 9-514 and 9-601 to 9-637:

##STR00054## ##STR00055## ##STR00056## ##STR00057## ##STR00058## ##STR00059## ##STR00060## ##STR00061##

[0155] The “group represented by one of Formulae 9-1 to 9-39 in which at least one hydrogen is substituted with —F” and the “group represented by one of Formulae 9-201 to 9-230 in which at least one hydrogen is substituted with —F” may be, for example, a group represented by one of Formulae 9-701 to 9-710:

##STR00062##

[0156] The “group represented by one of Formulae 10-1 to 10-145 in which at least one hydrogen is substituted with deuterium” and the “group represented by one of Formulae 10-201 to 10-354 in which at least one hydrogen is substituted with deuterium” may be, for example, a group represented by one of Formulae 10-501 to 10-553:

##STR00063## ##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069## ##STR00070##

[0157] The “group represented by one of Formulae 10-1 to 10-145 in which at least one hydrogen is substituted with —F” and the “group represented by one of Formulae 10-201 to 10-354 in which at least one hydrogen is substituted with —F” may be, for example, a group represented by one of Formulae 10-601 to 10-636:

##STR00071## ##STR00072## ##STR00073## ##STR00074##

[0158] In Formulae 2A and 2B, i) two or more of a plurality of R.sub.1(s) may be optionally linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a, ii) two or more of a plurality of R.sub.2(s) may be optionally linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a, iii) two or more of a plurality of R.sub.3(s) may be optionally linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a, iv) two or more of a plurality of R.sub.4(s) may be optionally linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a. R.sub.10a may be the same as described in connection with R.sub.1.

[0159] * and *′ in Formulae 2A and 2B each indicate a binding site to M in Formula 1.

[0160] In one or more embodiments, a group represented by

##STR00075##

in Formula 2A may be a group represented by one of Formulae CY1(1) to CY1(42):

##STR00076## ##STR00077## ##STR00078## ##STR00079## ##STR00080## ##STR00081## ##STR00082##

[0161] In Formulae CY1(1) to CY1(42),

[0162] X.sub.19 is O, S, N(R.sub.19a), C(R.sub.19a)(R.sub.19b), or Si(R.sub.19a)(R.sub.19b), and R.sub.19a and R.sub.19b are the same as described in connection with R.sub.1, Y.sub.1 may be carbon or nitrogen, and

[0163] * indicates a binding site to M in Formula 1, and *″ indicates a binding site to a neighboring carbon atom in Formula 2A.

[0164] In one or more embodiments, a group represented by

##STR00083##

in Formula 2A may be a group represented by one of Formulae CY1(1) to CY1(22).

[0165] In one or more embodiments, a group represented by

##STR00084##

in Formula 2A may be a group represented by one of Formulae CY1(23) to CY1(42).

[0166] In one or more embodiments, a group represented by

##STR00085##

in Formula 2A may be a group represented by one of Formulae CY2(1) to CY2(40):

##STR00086## ##STR00087## ##STR00088## ##STR00089## ##STR00090## ##STR00091## ##STR00092##

[0167] In Formulae CY2(1) to CY2(40),

[0168] T.sub.1 to T.sub.8 may each be carbon or nitrogen,

[0169] Y.sub.2 may be carbon or nitrogen,

[0170] X.sub.29 is O, S, N(R.sub.29a), C(R.sub.29a)(R.sub.29b), or Si(R.sub.29a)(R.sub.29b), and R.sub.29a and R.sub.29b are the same as described in connection with R.sub.2,

[0171] *′ indicates a binding site to M in Formula 1, and *″ indicates a binding site to ring CYC in Formula 2A.

[0172] For example, T.sub.1 to T.sub.8 in Formulae CY2(17) to CY2(40) may each be carbon.

[0173] In one or more embodiments,

[0174] at least one of T.sub.3 to T.sub.8 in Formula CY2(17) may be nitrogen,

[0175] at least one of T.sub.3, T.sub.4, T.sub.7 and T.sub.8 in Formula CY2(18) may be nitrogen,

[0176] at least one of T.sub.3, T.sub.4, T.sub.5 and T.sub.8 in Formula CY2(19) may be nitrogen,

[0177] at least one of T.sub.3, T.sub.4, T.sub.5 and T.sub.6 in Formula CY2(20) may be nitrogen,

[0178] at least one of T.sub.1, T.sub.2, T.sub.5, T.sub.6, T.sub.7 and T.sub.8 in Formula CY2(21) may be nitrogen,

[0179] at least one of T.sub.1, T.sub.2, T.sub.7 and T.sub.8 in Formula CY2(22) may be nitrogen,

[0180] at least one of T.sub.1, T.sub.2, T.sub.5 and T.sub.8 in Formula CY2(23) may be nitrogen,

[0181] at least one of T.sub.1, T.sub.2, T.sub.5 and T.sub.6 of Formula CY2(24) may be nitrogen,

[0182] at least one of T.sub.1, T.sub.4, T.sub.5, T.sub.6, T.sub.7 and T.sub.8 in Formula CY2(25) may be nitrogen,

[0183] at least one of T.sub.1, T.sub.4, T.sub.7 and T.sub.8 in Formula CY2(26) may be nitrogen,

[0184] at least one of T.sub.1, T.sub.4, T.sub.5 and T.sub.8 in Formula CY2(27) may be nitrogen,

[0185] at least one of T.sub.1, T.sub.4, T.sub.5 and T.sub.6 in Formula CY2(28) may be nitrogen,

[0186] at least one of T.sub.2, T.sub.4, T.sub.5, T.sub.6, T.sub.7 and T.sub.8 in Formula CY2(29) may be nitrogen,

[0187] at least one of T.sub.2, T.sub.4, T.sub.7 and T.sub.8 in Formula CY2(30) may be nitrogen,

[0188] at least one of T.sub.2, T.sub.4, T.sub.5 and T.sub.8 in Formula CY2(31) may be nitrogen,

[0189] at least one of T.sub.2, T.sub.4, T.sub.5 and T.sub.6 of Formula CY2(32) may be nitrogen,

[0190] at least one of T.sub.1, T.sub.2, T.sub.5, T.sub.6, T.sub.7 and T.sub.8 in Formula CY2(33) may be nitrogen,

[0191] at least one of T.sub.1, T.sub.2, T.sub.7 and T.sub.8 in Formula CY2(34) may be nitrogen,

[0192] at least one of T.sub.1, T.sub.2, T.sub.5 and T.sub.8 in Formula CY2(35) may be nitrogen,

[0193] at least one of T.sub.1, T.sub.2, T.sub.5 and T.sub.6 of Formula CY2(36) may be nitrogen,

[0194] at least one of T.sub.3 to T.sub.8 of Formula CY2(37) may be nitrogen,

[0195] at least one of T.sub.3, T.sub.4, T.sub.7 and T.sub.8 of Formula CY2(38) may be nitrogen,

[0196] at least one of T.sub.3, T.sub.4, T.sub.5 and T.sub.8 in Formula CY2(39) may be nitrogen, or

[0197] at least one of T.sub.3 to T.sub.6 of Formula CY2(40) may be nitrogen.

[0198] In one or more embodiments, in Formulae CY2(17) to CY2(40), T.sub.8 may be N and T.sub.1 to T.sub.7 may each be carbon.

[0199] In one or more embodiments, a group represented by

##STR00093##

in Formula 2A may be a group represented by one of Formulae CY2(17) to CY2(40).

[0200] In one or more embodiments, a group represented by

##STR00094##

in Formula 2B may be a group represented by Formula CY3(1):

##STR00095##

[0201] In Formula CY3(1),

[0202] Y.sub.3 may be carbon or nitrogen,

[0203] X.sub.31 may be Si or Ge, and

[0204] R.sub.3 and Q.sub.3 to Q.sub.5 are the same as described in the present specification,

[0205] b33 may each independently be an integer from 0 to 3,

[0206] two or more of R.sub.3(s) in the number of b33 may optionally be linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a (for example, a cyclohexane group, a norbornane group, a benzene group, a pyridine group, a naphthalene group, a quinoline group, or an isoquinoline group, each unsubstituted or substituted with at least one R.sub.10a),

[0207] * indicates a binding site to M in Formula 1, and

[0208] *″ indicates a binding site to ring CY4 in Formula 2B.

[0209] For example, at least one of R.sub.3(s) in the number of b33 in Formula CY3(1) may include two or more of carbon.

[0210] In one or more embodiments, a group represented by

##STR00096##

in Formula 2B may be a group represented by one of Formulae CY3-1 to CY3-16:

##STR00097## ##STR00098##

[0211] In Formulae CY3-1 to CY3-16,

[0212] R.sub.31 to R.sub.34 are the same as described in connection with R.sub.3, and each of R.sub.31 to R.sub.34 is not hydrogen,

[0213] Y.sub.3 may be carbon or nitrogen

[0214] * indicates a binding site to M in Formula 1, and

[0215] *″ indicates a binding site to ring CY.sub.4 in Formula 2B.

[0216] For example, R.sub.32 in Formulae CY3-1 to CY3-16 may be a C.sub.1-C.sub.10 alkyl group substituted with at least one deuterium; —Si(Q.sub.3)(Q.sub.4)(Q.sub.5); or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5).

[0217] In one or more embodiments, R.sub.33 in Formulae CY3-1 to CY3-16 may include two or more of carbons.

[0218] In one or more embodiments, R.sub.33 and R.sub.34 in Formulae CY3-1 to CY3-16 may optionally be linked to each other to form a C.sub.5-C.sub.30 carbocyclic group that is unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.30 heterocyclic group that is unsubstituted or substituted with at least one R.sub.10a (for example, a cyclohexane group, a norbornane group, a benzene group, a pyridine group, a naphthalene group, a quinoline group, or an isoquinoline group, each unsubstituted or substituted with at least one R.sub.10a).

[0219] In one or more embodiments, a group represented by

##STR00099##

in Formula 2B may be a group represented by Formula CY3-3, CY3-6, CY3-9, CY3-10, CY3-12, CY3-13, CY3-15, or CY3-16, and R.sub.32 in Formulae CY3-3, CY3-6, CY3-9, CY3-10, CY3-12, CY3-13, CY3-15 and CY3-16 may be —Si(Q.sub.3)(Q.sub.4)(Q.sub.5); or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5).

[0220] In one or more embodiments, a group represented by

##STR00100##

in Formula 2B may be a group represented by one of Formulae CY4-1 to CY4-16:

##STR00101## ##STR00102##

[0221] In Formulae CY4-1 to CY4-16,

[0222] Y.sub.4 may be carbon or nitrogen, R.sub.41 to R.sub.44 are the same as described in connection with R.sub.4, and each of R.sub.41 to R.sub.44 is not hydrogen,

[0223] *′ indicates a binding site to M in Formula 1, and

[0224] *″ indicates a binding site to ring CY.sub.3 in Formula 2B.

[0225] In one or more embodiments, the organometallic compound represented by Formula 1 may emit green light with a maximum emission wavelength in the range of about 500 nm to about 580 nm (in photoluminescence (PL) spectrum).

[0226] In one or more embodiments, the organometallic compound represented by Formula 1 may satisfy Condition 1 or Condition 2:

[0227] Condition 1

[0228] A group represented by

##STR00103##

in Formula 2A is a group represented by one of Formulae CY1(1) to CY1(22), and

[0229] a group represented by

##STR00104##

in Formula 2A is a group represented by one of Formulae CY2(17) to CY2(40), and

[0230] a group represented by

##STR00105##

in Formula 2B is a group represented by Formula CY3(1) (for example, a group represented by Formula CY3-3, CY3-6, CY3-9, CY3-10, CY3-12, CY3-13, CY3-15, or CY3-16 in which R.sub.32 is —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5)), and

[0231] a group represented by

##STR00106##

in Formula 2B is a group represented by one of Formulae CY4-1 to CY4-16.

[0232] Condition 2

[0233] A group represented by

##STR00107##

in Formula 2A is a group represented by one of Formulae CY1(23) to CY1(42),

[0234] a group represented by

##STR00108##

in Formula 2A is a group represented by one of Formulae CY2(17) to CY2(40),

[0235] a group represented by

##STR00109##

in Formula 2B is a group represented by Formula CY3(1) (for example, a group represented by Formula CY3-3, CY3-6, CY3-9, CY3-10, CY3-12, CY3-13, CY3-15, or CY3-16 in which R.sub.32 is —Si(Q.sub.3)(Q.sub.4)(Q.sub.5) or —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5)), and

[0236] a group represented by

##STR00110##

in Formula 2B is a group represented by one of Formulae CY4-1 to CY4-16.

Description of Formulae 5, 7, and 9

[0237] ##STR00111##

[0238] Ar.sub.1, Ar.sub.2, Ar.sub.11, Ar.sub.101, and Ar.sub.102 in Formulae 5, 7, and 9 may each independently be a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50 or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50,

[0239] Ar.sub.91 in Formula 9 may be a single bond, a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.90, or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.90,

[0240] Ar.sub.5 and Ar.sub.12 in Formulae 5 and 7 may each independently be a single bond, a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50a, or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50a, or may not exist,

[0241] n6 in Formula 5 may be 1, 2, or 3, and when n6 is 1, Ar.sub.5 may not exist,

[0242] p in Formula 7 may be 1, 2, or 3, and when p is 1, Ar.sub.12 may not exist,

[0243] a1 and a2 in Formula 5 may each independently be an integer from 0 to 5, and the sum of a1 and a2 may be 1 or more,

[0244] ring CY.sub.51, ring CY.sub.52, ring CY.sub.91 and ring CY.sub.92 in Formulae 5 and 9 may each independently be a C.sub.5-C.sub.60 carbocyclic group or a C.sub.1-C.sub.60 heterocyclic group, and ring CY.sub.51 and ring CY.sub.52 may be optionally combined with each other with a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50b or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50b therebetween,

[0245] L.sub.5 in Formula 5 may be a single bond, O, S, N(R.sub.50c), C(R.sub.50c)(R.sub.50d), or Si(R.sub.50c)(R.sub.50d), and n5 may be 0 or 1, wherein, when n5 is 0, L.sub.5 may not exist,

[0246] Het1 in Formula 7 may be a π electron-deficient nitrogen-containing C.sub.1-C.sub.60 cyclic group, and

[0247] a11, a91 and m in Formulae 7 and 9 may each independently be an integer from 1 to 10,

[0248] In Formula 9, X.sub.101 may be N or C(R.sub.101), X.sub.102 may be N or C(R.sub.102), X.sub.103 may be N or C(R.sub.103), and at least two of X.sub.101 to X.sub.103 may be N, and

[0249] X.sub.91 in Formula 9 may be a single bond, O, S, N(R.sub.91a), C(R.sub.91a)(R.sub.91b), or Si(R.sub.91a)(R.sub.91b).

[0250] The term “π electron-deficient nitrogen-containing C.sub.1-C.sub.60 cyclic group” as used herein refers to a cyclic group having 1 to 60 carbon atoms including at least one *—N=*′ as a ring-constituting moiety, and may be, for example, a) a first ring, b) a condensed ring in which two or more first rings are condensed with each other, or c) a condensed ring in which at least one first ring is condensed with at least one second ring. The first ring and the second ring are the same as described in the present specification.

[0251] The π electron-deficient nitrogen-containing C.sub.1-C.sub.60 cyclic group may be, for example, an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, an indazole group, a purine group, a quinoline group, an isoquinoline group, a benzoquinoline group, a benzoisoquinoline group, a phthalazine group, a naphthyridine group, a quinoxaline group, a benzoquinoxaline group, a quinazoline group, a cinnoline group, a phenanthridine group, an acridine group, a phenanthroline group, a phenazine group, a benzimidazole group, an isobenzothiazole group, a benzoxazole group, a benzoisoxazole group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, a thiadiazole group, an imidazopyridine group, an imidazopyrimidine group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, a benzonaphthofuran group, a benzonaphthothiophene group, an (indolo)phenanthrene group, a (benzofurano)phenanthrene group, a (benzothieno)phenanthrene group, or a pyridopyrazine group.

[0252] The term “π electron-rich C.sub.6-C.sub.60 cyclic group” used herein refers to a cyclic group having 3 to 60 carbon atoms not including *—N=*′ as a ring-constituting moiety, and may be, for example, a) a second ring or b) a condensed cyclic group in which two or more second rings are condensed with each other. The second ring are the same as described in the present specification.

[0253] The π electron-rich C.sub.6-C.sub.60 cyclic group may be, for example, a benzene group, a heptalene group, an indene group, a naphthalene group, an azulene group, an indacene group, an acenaphthylene group, a fluorene group, a spiro-bifluorene group, a benzofluorene group, a dibenzofluorene group, a phenalene group, a phenanthrene group, an anthracene group, a fluoranthene group, a triphenylene group, a pyrene group, a chrysene group, a naphthacene group, a picene group, a perylene group, a pentacene group, a hexacene group, a pentaphene group, a rubicene group, a coronene group, an ovalene group, a pyrrole group, a furan group, a thiophene group, an isoindole group, an indole group, an indene group, a benzofuran group, a benzothiophene group, a benzosilole group, a naphthopyrrole group, a naphthofuran group, a naphthothiophene group, a naphthosilole group, a benzocarbazole group, a dibenzocarbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzothiophene sulfone group, a carbazole group, a dibenzosilole group, an indenocarbazole group, an indolocarbazole group, a benzofurocarbazole group, a benzothienocarbazole group, a benzosilolocarbazole group, a triindolobenzene group, an acridine group, a dihydroacridine group, a pyrrolophenanthrene group, a furanophenanthrene group, or a thienophenanthrene group.

[0254] In some embodiments,

[0255] Ar.sub.1, Ar.sub.2, Ar.sub.11, Ar.sub.101 and Ar.sub.102 in Formulae 5, 7 and 9 may each independently be a group derived from i) a first ring unsubstituted or substituted with at least one R.sub.50, ii) a second ring unsubstituted or substituted with at least one R.sub.50, iii) a condensed cyclic group in which two or more first rings, substituted or unsubstituted with at least one R.sub.50, are condensed with each other, iv) a condensed cyclic group in which two or more second rings, substituted or unsubstituted with at least one R.sub.50, are condensed with each other, or v) a condensed cyclic group in which at least one first ring unsubstituted or substituted with at least one R.sub.50 is condensed with at least one second ring unsubstituted or substituted with at least one R.sub.50,

[0256] Ar.sub.91 in Formula 9 may be a single bond, or a group derived from i) a first ring unsubstituted or substituted with at least one R.sub.90, ii) a second ring unsubstituted or substituted with at least one R.sub.90, iii) a condensed cyclic group in which two or more first rings, unsubstituted or substituted with at least one R.sub.90, are condensed with each other, iv) a condensed cyclic group in which two or more second rings, unsubstituted or substituted with at least one R.sub.90, are condensed with each other, or v) a condensed cyclic group in which at least one first ring unsubstituted or substituted with at least one R.sub.90 is condensed with at least one second ring unsubstituted or substituted with at least one R.sub.90,

[0257] Ar.sub.5 and Ar.sub.12 in Formulae 5 and 7 may each independently be a single bond, or a group derived from i) a first ring unsubstituted or substituted with at least one R.sub.50a, ii) a second ring unsubstituted or substituted with at least one R.sub.50a, iii) a condensed cyclic group in which two or more first rings, substituted or unsubstituted with at least one R.sub.50a, are condensed with each other, iv) a condensed cyclic group in which two or more second rings, substituted or unsubstituted with at least one R.sub.50a, are condensed with each other, or v) a condensed cyclic group in which at least one first ring unsubstituted or substituted with at least one R.sub.50a is condensed with at least one second ring unsubstituted or substituted with at least one R.sub.50a, or may not exist,

[0258] ring CY.sub.51, ring CY.sub.52, ring CY.sub.91 and ring CY.sub.92 in Formulae 5 and 9 may each independently be i) a first ring, ii) a second ring, iii) a condensed ring in which two or more first rings are condensed with each other, iv) a condensed ring in which two or more second rings are condensed with each other, or v) a condensed ring in which one or more first rings and one or more second rings are condensed with each other,

[0259] Het1 in Formula 7 may be a group derived from i) a first ring, ii) a condensed cyclic group in which two or more first rings are condensed with each other or iii) a condensed cyclic group in which at least one first ring is condensed with at least one second ring,

[0260] the first ring may be an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, or a thiadiazole group, and the second ring may be a benzene group, a cyclopentadiene group, a pyrrole group, a furan group, a thiophene group, or a silole group.

[0261] In one or more embodiments, Ar.sub.1, Ar.sub.2, Ar.sub.11, Ar.sub.101 and Ar.sub.102 in Formulae 5, 7, and 9 may each independently be a benzene group, a heptalene group, an indene group, a naphthalene group, an azulene group, an indacene group, an acenaphthylene group, a fluorene group, a spiro-bifluorene group, a benzofluorene group, a dibenzofluorene group, a phenalene group, a phenanthrene group, an anthracene group, a fluoranthene group, a triphenylene group, a pyrene group, a chrysene group, a naphthacene group, a picene group, a perylene group, a pentacene group, a hexacene group, a pentaphene group, a rubicene group, a coronene group, an ovalene group, a pyrrole group, a furan group, a thiophene group, an isoindole group, an indole group, an indene group, a benzofuran group, a benzothiophene group, a benzosilole group, a naphthopyrrole group, a naphthofuran group, a naphthothiophene group, a naphthosilole group, a benzocarbazole group, a dibenzocarbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzothiophene sulfone group, a carbazole group, a dibenzosilole group, an indenocarbazole group, an indolocarbazole group, a benzofurocarbazole group, a benzothienocarbazole group, a benzosilolocarbazole group, a triindolobenzene group, an acridine group, a dihydroacridine group, an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, an indazole group, a purine group, a quinoline group, an isoquinoline group, a benzoquinoline group, a benzoisoquinoline group, a phthalazine group, a naphthyridine group, a quinoxaline group, a benzoquinoxaline group, a quinazoline group, a cinnoline group, a phenanthridine group, an acridine group, a phenanthroline group, a phenazine group, a benzimidazole group, an isobenzothiazole group, a benzoxazole group, a benzoisoxazole group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, a thiadiazole group, an imidazopyridine group, an imidazopyrimidine group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, a benzonaphthofuran group, a benzonaphthothiophene group, an (indolo)phenanthrene group, a (benzofurano)phenanthrene group, or a (benzothieno)phenanthrene group, each unsubstituted or substituted with at least one R.sub.50.

[0262] In one or more embodiments, Ar.sub.91 in Formula 9 may be a single bond, or a benzene group, a heptalene group, an indene group, a naphthalene group, an azulene group, an indacene group, an acenaphthylene group, a fluorene group, a spiro-bifluorene group, a benzofluorene group, a dibenzofluorene group, a phenalene group, a phenanthrene group, an anthracene group, a fluoranthene group, a triphenylene group, a pyrene group, a chrysene group, a naphthacene group, a picene group, a perylene group, a pentacene group, a hexacene group, a pentaphene group, a rubicene group, a coronene group, an ovalene group, a pyrrole group, a furan group, a thiophene group, an isoindole group, an indole group, an indene group, a benzofuran group, a benzothiophene group, a benzosilole group, a naphthopyrrole group, a naphthofuran group, a naphthothiophene group, a naphthosilole group, a benzocarbazole group, a dibenzocarbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzothiophene sulfone group, a carbazole group, a dibenzosilole group, an indenocarbazole group, an indolocarbazole group, a benzofurocarbazole group, a benzothienocarbazole group, a benzosilolocarbazole group, a triindolobenzene group, an acridine group, a dihydroacridine group, an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, an indazole group, a purine group, a quinoline group, an isoquinoline group, a benzoquinoline group, a benzoisoquinoline group, a phthalazine group, a naphthyridine group, a quinoxaline group, a benzoquinoxaline group, a quinazoline group, a cinnoline group, a phenanthridine group, an acridine group, a phenanthroline group, a phenazine group, a benzimidazole group, an isobenzothiazole group, a benzoxazole group, a benzoisoxazole group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, a thiadiazole group, an imidazopyridine group, an imidazopyrimidine group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, a benzonaphthofuran group, a benzonaphthothiophene group, an (an indolo)phenanthrene group, a (benzofurano)phenanthrene group, or a (benzothieno)phenanthrene group, each unsubstituted or substituted with at least one R.sub.90.

[0263] In one or more embodiments, Ar.sub.5 and Ar.sub.12 in Formulae 5 and 7 may each independently be a single bond, or a benzene group, a naphthalene group, or a carbazole group, each unsubstituted or substituted with at least one R.sub.50a, or may not exist.

[0264] In one or more embodiments, ring CY.sub.51, ring CY.sub.52, ring CY.sub.91 and ring CY.sub.92 of Formulae 5 and 9 may each independently be a benzene group, a heptalene group, an indene group, a naphthalene group, an azulene group, an indacene group, an acenaphthylene group, a fluorene group, a spiro-bifluorene group, a benzofluorene group, a dibenzofluorene group, a phenalene group, a phenanthrene group, an anthracene group, a fluoranthene group, a triphenylene group, a pyrene group, a chrysene group, a naphthacene group, a picene group, a perylene group, a pentacene group, a hexacene group, a pentaphene group, a rubicene group, a coronene group, an ovalene group, a pyrrole group, a furan group, a thiophene group, an isoindole group, an indole group, an indene group, a benzofuran group, a benzothiophene group, a benzosilole group, a naphthopyrrole group, a naphthofuran group, a naphthothiophene group, a naphthosilole group, a benzocarbazole group, a dibenzocarbazole group, a dibenzofuran group, a dibenzothiophene group, a dibenzothiophene sulfone group, a carbazole group, a dibenzosilole group, an indenocarbazole group, an indolocarbazole group, a benzofurocarbazole group, a benzothienocarbazole group, a benzosilolocarbazole group, a triindolobenzene group, an acridine group, a dihydroacridine group, an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, an indazole group, a purine group, a quinoline group, an isoquinoline group, a benzoquinoline group, a benzoisoquinoline group, a phthalazine group, a naphthyridine group, a quinoxaline group, a benzoquinoxaline group, a quinazoline group, a cinnoline group, a phenanthridine group, an acridine group, a phenanthroline group, a phenazine group, a benzimidazole group, an isobenzothiazole group, a benzoxazole group, a benzoisoxazole group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, a thiadiazole group, an imidazopyridine group, an imidazopyrimidine group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, a pyrrolophenanthrene group, a furanophenanthrene group, or a thienophenanthrene group.

[0265] In one or more embodiments, Het1 in Formula 7 may be an imidazole group, a pyrazole group, a thiazole group, an isothiazole group, an oxazole group, an isoxazole group, a pyridine group, a pyrazine group, a pyridazine group, a pyrimidine group, an indazole group, a purine group, a quinoline group, an isoquinoline group, a benzoquinoline group, a benzoisoquinoline group, a phthalazine group, a naphthyridine group, a quinoxaline group, a benzoquinoxaline group, a quinazoline group, a cinnoline group, a phenanthridine group, an acridine group, a phenanthroline group, a phenazine group, a benzimidazole group, an isobenzothiazole group, a benzoxazole group, a benzoisoxazole group, a triazole group, a tetrazole group, an oxadiazole group, a triazine group, a thiadiazole group, an imidazopyridine group, an imidazopyrimidine group, an azacarbazole group, an azadibenzofuran group, an azadibenzothiophene group, an azadibenzosilole group, or a pyridopyrazine group.

[0266] In one or more embodiments, Ar.sub.1, Ar.sub.2, Ar.sub.11, Ar.sub.101 and Ar.sub.102 in Formulae 5, 7, and 9 may each independently be a π electron-rich C.sub.3-C.sub.60 cyclic group unsubstituted or substituted with at least one R.sub.50.

[0267] In one or more embodiments, Ar.sub.91 in Formula 9 may be a single bond, or a π electron-rich C.sub.3-C.sub.60 cyclic group unsubstituted or substituted with at least one R.sub.90.

[0268] In one or more embodiments, Ar.sub.5 and Ar.sub.12 in Formulae 5 and 7 may each independently be a single bond or a π electron-rich C.sub.3-C.sub.60 cyclic group unsubstituted or substituted with at least one R.sub.50a, or may not exist.

[0269] In one or more embodiments, ring CY.sub.51, ring CY.sub.52, ring CY.sub.91, and ring CY.sub.92 in Formulae 5 and 9 may each independently be a π electron-rich C.sub.3-C.sub.60 cyclic group.

[0270] In one or more embodiments, ring CY.sub.91 and ring CY.sub.92 in Formula 9 may each independently be a benzene group, a naphthalene group, a phenanthrene group, a dibenzofuran group, a dibenzothiophene group, a carbazole group, a fluorene group, or a dibenzosilole group.

[0271] In one or more embodiments, one of ring CY.sub.91 and ring CY.sub.92 in Formula 9 may be a benzene group, a naphthalene group, or a phenanthrene group, and the other one may be a dibenzofuran group, a dibenzothiophene group, a carbazole group, a fluorene group, or a dibenzosilole group.

[0272] In one or more embodiments, n6 and p in Formulae 5 and 7 may each independently be 1 or 2.

[0273] In one or more embodiments, when n6 in Formula 5 is 1, at least one of ring CY.sub.51 and ring CY.sub.52 may not be a benzene group.

[0274] In one or more embodiments, when n6 in Formula 5 is 1, at least one of ring CY.sub.51 and ring CY.sub.52 may be a) a condensed ring in which two or more first rings are condensed with each other, b) a condensed ring in which two or more second rings are condensed with each other, or c) a condensed ring in which at least one first ring is condensed with at least one second ring. In this regard, the first ring and the second ring are the same as described in the present specification.

[0275] In one or more embodiments, the compound represented by Formula 5 may be a compound represented by Formula 5(1):

##STR00112##

[0276] In Formula 5(1),

[0277] Ar.sub.5 may be a single bond, a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50a, or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50a,

[0278] Ar.sub.1, Ar.sub.2, Ar.sub.5, a1, a2, ring CY.sub.51, ring CY.sub.52, R.sub.51, R.sub.52, b51, and b52 are the same as described in the present specification,

[0279] Ar.sub.3 and Ar.sub.4 may each independently be a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50 or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50,

[0280] a3, a4, ring CY.sub.53, ring CY.sub.54, R.sub.53, R.sub.54, b53, and b54 are the same as described in connection with a1, a2, ring CY.sub.51, ring CY.sub.52, R.sub.51, R.sub.52, b51, and b52, respectively.

[0281] For example, Ar.sub.5 in Formula 5(1) may be a single bond.

[0282] In one or more embodiments, the compound represented by Formula 7 may include a compound represented by Formula 7(1):

##STR00113##

[0283] In Formula 7(1),

[0284] Ar.sub.12 may be a single bond, a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.50a, or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.50a,

[0285] Het1, Ar.sub.11, R.sub.70, R.sub.80, a11, b7, b8, and m are the same as described in the present specification, and

[0286] Het3, Ar.sub.13, R.sub.73, R.sub.83, a13, b73, b83, and m3 are the same as described in connection with Het1, Ar.sub.11, R.sub.70, R.sub.80, a11, b7, b8, and m, respectively.

[0287] In one or more embodiments, a group represented by

##STR00114##

in Formula 5, a group represented by

##STR00115##

in Formula 5(1) and a group represented by

##STR00116##

in Formula 5(1) may each independently be a group represented by one of Formulae 2-1 to 2-93:

##STR00117## ##STR00118## ##STR00119## ##STR00120## ##STR00121## ##STR00122## ##STR00123## ##STR00124## ##STR00125## ##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133##

[0288] In Formulae 2-1 to 2-93,

[0289] X.sub.51 may be O, S, N(R.sub.51a), C(R.sub.51a)(R.sub.51b), or Si(R.sub.51a)(R.sub.51b),

[0290] X.sub.52 may be O, S, N(R.sub.52a), C(R.sub.52a)(R.sub.52b), or Si(R.sub.52a)(R.sub.52b), R.sub.51a, R.sub.51b, R.sub.52a, and R.sub.52b are the same as described in connection with R.sub.51, and

[0291] * indicates a binding site to Ar.sub.1 or Ar.sub.2 in Formula 5 or 5(1).

[0292] In one or more embodiments, Het1 in Formula 7 and Het1 and Het3 in Formula 7(1) may each independently be a group derived from one of Formulae 3-1 to 3-40:

##STR00134## ##STR00135## ##STR00136## ##STR00137##

[0293] In one or more embodiments, a group represented by

##STR00138##

in Formula 9 may be a group represented by one of Formulae 9-1 to 9-6:

##STR00139##

[0294] In Formulae 9-1 to 9-6,

[0295] X.sub.91 is the same as described above,

[0296] X.sub.92 may be O, S, N(R.sub.92a), C(R.sub.92a)(R.sub.92b), or Si(R.sub.92a)(R.sub.92b), and

[0297] * indicates a binding site to an adjacent atom.

[0298] In one or more embodiments, X.sub.101 to X.sub.103 in Formula 9 may be N.

[0299] a1 and a2 in Formulae 5 and 5(1) may indicate the number of Ar.sub.1(s) and the number of Ar.sub.2(s), respectively, and may each independently be an integer from 0 to 5 (for example, 0, 1, or 2), and the sum of a1 and a2 may be 1 or more. When a1 is 2 or more, two or more of Ar.sub.1(s) may be identical to or different from each other, and when a2 is 2 or more, two or more of Ar.sub.2(s) may be identical to each other or different from each other. When a1 is 0, *—(Ar.sub.1).sub.a1—*′ in Formula 2 may be a single bond.

[0300] a11 and m in Formulae 7 and 7(1) indicate the number of Ar.sub.11(s) and the number of *—(Ar.sub.11).sub.a11—(R.sub.70).sub.a70 (s), respectively, and may each independently be an integer from 1 to 10. When a11 is 2 or more, two or more of Ar.sub.11(s) may be identical to or different from each other, and when m is 2 or more, two or more of *—(Ar.sub.11).sub.a11—(R.sub.70).sub.a70(s) may be identical to or different from each other.

[0301] In one or more embodiments, a11 and m in Formulae 7 and 7(1) may each independently be an integer from 1 to 3.

[0302] a91 in Formula 9 indicates the number of Ar.sub.91(s), and may be an integer from 1 to 10.

[0303] R.sub.50 to R.sub.54, R.sub.50a to R.sub.50d, R.sub.51a, R.sub.51b, R.sub.52a, R.sub.52b, R.sub.70, R.sub.73, R.sub.80, R.sub.83, R.sub.90 to R.sub.92, R.sub.91a, R.sub.91b, R.sub.92a, R.sub.92b, and R.sub.101 to R.sub.103 used herein may each independently be hydrogen, deuterium, —F, —Cl, —Br, —SF.sub.5, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, —N(Q.sub.1)(Q.sub.2), —Si(Q.sub.3)(Q.sub.4)(Q.sub.5), —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5), —B(Q.sub.6)(Q.sub.7), —P(═O)(Q.sub.8)(Q.sub.9), or —P(Q.sub.8)(Q.sub.9). Q.sub.1 to Q.sub.9 are the same as described in the present specification.

[0304] For example, R.sub.50 to R.sub.54, R.sub.50a to R.sub.50d, R.sub.51a, R.sub.51b, R.sub.52a, R.sub.52b, R.sub.70, R.sub.73, R.sub.80, R.sub.83, R.sub.90 to R.sub.92, R.sub.91a, R.sub.91b, R.sub.92a, R.sub.92b, and R.sub.101 to R.sub.103 may each independently be:

[0305] hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, —SF.sub.5, a C.sub.1-C.sub.20 alkyl group, or a C.sub.1-C.sub.20 alkoxy group; a C.sub.1-C.sub.20 alkyl group or a C.sub.1-C.sub.20 alkoxy group, each substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a deuterated C.sub.1-C.sub.20 alkyl group, a fluorinated C.sub.1-C.sub.20 alkyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.1]heptyl group (norbornanyl group), a bicyclo[2.2.2]octyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptyl group, a (C.sub.1-C.sub.20 alkyl)cyclooctyl group, a (C.sub.1-C.sub.20 alkyl)adamantanyl group, a (C.sub.1-C.sub.20 alkyl)norbornenyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentenyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexenyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptenyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[1.1.1]pentyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.1.1]hexyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.1]heptyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.2]octyl group, a silolanyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a 1,2,3,4-tetrahydronaphthyl group, a pyridinyl group, a pyrimidinyl group, or any combination thereof;

[0306] a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.1]heptyl group, a bicyclo[2.2.2]octyl group, a silolanyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a 1,2,3,4-tetrahydronaphthyl group, a fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzoisothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, an azacarbazolyl group, an azadibenzofuranyl group, or an azadibenzothiophenyl group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a deuterated C.sub.1-C.sub.20 alkyl group, a fluorinated C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornenyl group, a cyclopentenyl group, a cyclohexenyl group, a cycloheptenyl group, a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, a bicyclo[2.2.1]heptyl group, a bicyclo[2.2.2]octyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptyl group, a (C.sub.1-C.sub.20 alkyl)cyclooctyl group, a (C.sub.1-C.sub.20 alkyl)adamantanyl group, a (C.sub.1-C.sub.20 alkyl)norbornenyl group, a (C.sub.1-C.sub.20 alkyl)cyclopentenyl group, a (C.sub.1-C.sub.20 alkyl)cyclohexenyl group, a (C.sub.1-C.sub.20 alkyl)cycloheptenyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[1.1.1]pentyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.1.1]hexyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.1]heptyl group, a (C.sub.1-C.sub.20 alkyl)bicyclo[2.2.2]octyl group, a silolanyl group, a phenyl group, a (C.sub.1-C.sub.20 alkyl)phenyl group, a biphenyl group, a terphenyl group, a naphthyl group, a 1,2,3,4-tetrahydronaphthyl group, a fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzoisothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, an azacarbazolyl group, an azadibenzofuranyl group, an azadibenzothiophenyl group, or any combination thereof; or

[0307] —N(Q.sub.1)(Q.sub.2), —Si(Q.sub.3)(Q.sub.4)(Q.sub.5), —Ge(Q.sub.3)(Q.sub.4)(Q.sub.5), —B(Q.sub.8)(Q.sub.7), —P(═O)(Q.sub.8)(Q.sub.9), or —P(Q.sub.8)(Q.sub.9),

[0308] wherein Q.sub.1 to Q.sub.9 are each independently:

[0309] —CH.sub.3, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CH.sub.2CH.sub.3, —CH.sub.2CD.sub.3, —CH.sub.2CD.sub.2H, —CH.sub.2CDH.sub.2, —CHDCH.sub.3, —CHDCD.sub.2H, —CHDCDH.sub.2, —CHDCD.sub.3, —CD.sub.2CD.sub.3, —CD.sub.2CD.sub.2H, or —CD.sub.2CDH.sub.2; or

[0310] an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, a phenyl group, a biphenyl group, or a naphthyl group, each unsubstituted or substituted with deuterium, a C.sub.1-C.sub.20 alkyl group, a phenyl group, or any combination thereof.

[0311] b51 to b54, b7, b73, b8, b83, b91, and b92 indicates the numbers of R.sub.51 to R.sub.54, R.sub.70, R.sub.73, R.sub.80, R.sub.83, R.sub.91, and R.sub.92, respectively, and may each independently be an integer from 0 to 20. For example, b51 to b54, b7, b73, b8, b83, b91, and b92 may each independently be an integer from 0 to 10. when b51 is 2 or more, two or more of R.sub.51(s) may be identical to or different from each other, when b52 is 2 or more, two or more of R.sub.52(s) may be identical to or different from each other, when b53 is 2 or more, two or more of R.sub.53(s) may be identical to or different from each other, when b54 is 2 or more, two or more of R.sub.54(s) may be identical to or different from each other, when b7 is 2 or more, two or more of R.sub.70(s) may be identical to or different from each other, when b73 is 2 or more, two or more of R.sub.73(s) may be identical to or different from each other, when b8 is 2 or more, two or more of R.sub.80(s) may be identical to or different from each other, when b83 is 2 or more, two or more of R.sub.83(s) may be identical to or different from each other, when b91 is 2 or more, two or more of R.sub.91(s) may be identical to or different from each other, when b92 is 2 or more, two or more of R.sub.92(s) may be identical to or different from each other.

[0312] For example, R.sub.50 to R.sub.54, R.sub.50a to R.sub.50d, R.sub.51a, R.sub.51b, R.sub.52a, R.sub.52b, R.sub.70, R.sub.73, R.sub.80, R.sub.83, R.sub.90 to R.sub.92, R.sub.91a, R.sub.91b, R.sub.92a, R.sub.92b, and R.sub.101 to R.sub.103 may each independently be:

[0313] hydrogen or deuterium;

[0314] a C.sub.1-C.sub.29 alkyl group or a C.sub.1-C.sub.29 alkoxy group, each substituted or unsubstituted with deuterium, a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a fluorenyl group, a di(C.sub.1-C.sub.10 alkyl)fluorenyl group, a di(C.sub.6-C.sub.69 aryl)fluorenyl group, a dibenzosilolyl group, a di(C.sub.1-C.sub.10 alkyl)dibenzosilolyl group, a di(C.sub.6-C.sub.60 aryl)dibenzosilolyl group, a carbazolyl group, a (C.sub.1-C.sub.10 alkyl)carbazolyl group, a (C.sub.6-C.sub.60 aryl)carbazolyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a biphenyl group, a terphenyl group, —N(Q.sub.31)(Q.sub.32), or any combination thereof;

[0315] a π electron-rich C.sub.3-C.sub.60 cyclic group, unsubstituted or substituted with deuterium, a C.sub.1-C.sub.29 alkyl group, a C.sub.1-C.sub.29 alkoxy group, a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a fluorenyl group, a alkyl)fluorenyl group, a di(C.sub.6-C.sub.60 aryl)fluorenyl group, a dibenzosilolyl group, a alkyl)dibenzosilolyl group, a di(C.sub.6-C.sub.60 aryl)dibenzosilolyl group, a carbazolyl group, a (C.sub.1-C.sub.10 alkyl)carbazolyl group, a (C.sub.6-C.sub.60 aryl)carbazolyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a biphenyl group, a terphenyl group, —N(Q.sub.31)(Q.sub.32), or any combination thereof; or

[0316] —N(Q.sub.1)(Q.sub.2).

[0317] In this regard, Q.sub.1, Q.sub.2, Q.sub.31, and Q.sub.32 are the same as described in the present specification.

[0318] In one or more embodiments, R.sub.50 to R.sub.54, R.sub.50a to R.sub.50d, R.sub.51a, R.sub.51b, R.sub.52a, R.sub.52b, R.sub.70, R.sub.73, R.sub.80, R.sub.83, R.sub.90 to R.sub.92, R.sub.91a, R.sub.91b, R.sub.92a, R.sub.92b, and R.sub.101 to R.sub.103 may each independently be:

[0319] hydrogen or deuterium;

[0320] a C.sub.1-C.sub.29 alkyl group unsubstituted or substituted with deuterium, a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a fluorenyl group, a di(C.sub.1-C.sub.10 alkyl)fluorenyl group, a di(C.sub.6-C.sub.60 aryl)fluorenyl group, a dibenzosilolyl group, a di(C.sub.1-C.sub.10 alkyl)dibenzosilolyl group, a di(C.sub.6-C.sub.60 aryl)dibenzosilolyl group, a carbazolyl group, a (C.sub.1-C.sub.10 alkyl)carbazolyl group, a (C.sub.6-C.sub.60 aryl)carbazolyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a biphenyl group, a terphenyl group, —N(Q.sub.31)(Q.sub.32), or any combination thereof; or

[0321] a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a fluorenyl group, a dibenzosilolyl group, a carbazolyl group, a dibenzofuranyl group, or a dibenzothiophenyl group, each unsubstituted or substituted with deuterium, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a fluorenyl group, a di(C.sub.1-C.sub.10 alkyl)fluorenyl group, a di(C.sub.6-C.sub.60 aryl)fluorenyl group, a dibenzosilolyl group, a di(C.sub.1-C.sub.10 alkyl)dibenzosilolyl group, a di(C.sub.6-C.sub.60 aryl)dibenzosilolyl group, a carbazolyl group, a (C.sub.1-C.sub.10 alkyl)carbazolyl group, a (C.sub.6-C.sub.60 aryl)carbazolyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a biphenyl group, a terphenyl group, or any combination thereof.

[0322] In this regard, Q.sub.31 and Q.sub.32 are the same as described in the present specification.

[0323] In Formulae 5, 7, and 9, 1) two or more of R.sub.51(s) may optionally be combined with each other to form a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.10a, 2) two or more of R.sub.52(s) may optionally be combined with each other to form a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.10a, and 3) two or more of ring CY.sub.51, ring CY.sub.52, R.sub.51, and R.sub.52 may optionally be combined with each other to form a C.sub.5-C.sub.60 carbocyclic group unsubstituted or substituted with at least one R.sub.10a or a C.sub.1-C.sub.60 heterocyclic group unsubstituted or substituted with at least one R.sub.10a. R.sub.10a may be the same as described in connection with R.sub.1.

Description of Examples of Compound

[0324] In one or more embodiments, the dopants included in the first emission layer and the second emission layer may be one of compounds of Group 1-1 to Group 1-7:

##STR00140## ##STR00141## ##STR00142## ##STR00143## ##STR00144## ##STR00145## ##STR00146## ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159## ##STR00160## ##STR00161## ##STR00162## ##STR00163## ##STR00164## ##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177## ##STR00178## ##STR00179## ##STR00180## ##STR00181## ##STR00182## ##STR00183## ##STR00184## ##STR00185## ##STR00186## ##STR00187## ##STR00188## ##STR00189## ##STR00190## ##STR00191## ##STR00192## ##STR00193## ##STR00194## ##STR00195##

##STR00196## ##STR00197## ##STR00198## ##STR00199## ##STR00200## ##STR00201## ##STR00202## ##STR00203## ##STR00204## ##STR00205## ##STR00206## ##STR00207## ##STR00208## ##STR00209## ##STR00210## ##STR00211## ##STR00212## ##STR00213## ##STR00214## ##STR00215##

##STR00216## ##STR00217## ##STR00218## ##STR00219## ##STR00220## ##STR00221## ##STR00222## ##STR00223## ##STR00224## ##STR00225## ##STR00226## ##STR00227## ##STR00228## ##STR00229## ##STR00230## ##STR00231## ##STR00232## ##STR00233## ##STR00234## ##STR00235## ##STR00236## ##STR00237## ##STR00238## ##STR00239## ##STR00240## ##STR00241## ##STR00242## ##STR00243## ##STR00244## ##STR00245## ##STR00246## ##STR00247## ##STR00248## ##STR00249## ##STR00250## ##STR00251## ##STR00252## ##STR00253## ##STR00254## ##STR00255## ##STR00256## ##STR00257## ##STR00258## ##STR00259## ##STR00260## ##STR00261## ##STR00262## ##STR00263## ##STR00264## ##STR00265## ##STR00266## ##STR00267## ##STR00268## ##STR00269## ##STR00270## ##STR00271## ##STR00272## ##STR00273## ##STR00274## ##STR00275## ##STR00276## ##STR00277## ##STR00278## ##STR00279## ##STR00280## ##STR00281## ##STR00282## ##STR00283## ##STR00284## ##STR00285## ##STR00286## ##STR00287## ##STR00288## ##STR00289## ##STR00290## ##STR00291## ##STR00292## ##STR00293## ##STR00294## ##STR00295## ##STR00296## ##STR00297## ##STR00298## ##STR00299## ##STR00300## ##STR00301## ##STR00302## ##STR00303## ##STR00304## ##STR00305##

##STR00306## ##STR00307## ##STR00308## ##STR00309## ##STR00310## ##STR00311## ##STR00312## ##STR00313## ##STR00314## ##STR00315## ##STR00316## ##STR00317## ##STR00318## ##STR00319## ##STR00320## ##STR00321## ##STR00322## ##STR00323## ##STR00324## ##STR00325## ##STR00326## ##STR00327## ##STR00328## ##STR00329## ##STR00330## ##STR00331## ##STR00332## ##STR00333## ##STR00334## ##STR00335## ##STR00336## ##STR00337## ##STR00338## ##STR00339## ##STR00340## ##STR00341## ##STR00342## ##STR00343## ##STR00344## ##STR00345## ##STR00346## ##STR00347## ##STR00348## ##STR00349## ##STR00350## ##STR00351## ##STR00352## ##STR00353## ##STR00354## ##STR00355## ##STR00356## ##STR00357## ##STR00358## ##STR00359## ##STR00360## ##STR00361## ##STR00362## ##STR00363## ##STR00364## ##STR00365## ##STR00366## ##STR00367## ##STR00368## ##STR00369## ##STR00370## ##STR00371## ##STR00372## ##STR00373## ##STR00374## ##STR00375## ##STR00376## ##STR00377## ##STR00378## ##STR00379## ##STR00380## ##STR00381## ##STR00382## ##STR00383## ##STR00384## ##STR00385## ##STR00386## ##STR00387## ##STR00388## ##STR00389## ##STR00390## ##STR00391## ##STR00392## ##STR00393## ##STR00394## ##STR00395## ##STR00396## ##STR00397## ##STR00398## ##STR00399## ##STR00400##

##STR00401## ##STR00402## ##STR00403## ##STR00404## ##STR00405## ##STR00406## ##STR00407## ##STR00408## ##STR00409## ##STR00410## ##STR00411## ##STR00412## ##STR00413## ##STR00414## ##STR00415## ##STR00416## ##STR00417## ##STR00418## ##STR00419## ##STR00420## ##STR00421## ##STR00422## ##STR00423## ##STR00424## ##STR00425## ##STR00426## ##STR00427## ##STR00428## ##STR00429## ##STR00430## ##STR00431## ##STR00432## ##STR00433## ##STR00434## ##STR00435## ##STR00436## ##STR00437## ##STR00438## ##STR00439## ##STR00440## ##STR00441## ##STR00442## ##STR00443## ##STR00444## ##STR00445## ##STR00446## ##STR00447## ##STR00448## ##STR00449## ##STR00450## ##STR00451## ##STR00452## ##STR00453## ##STR00454## ##STR00455## ##STR00456## ##STR00457## ##STR00458## ##STR00459## ##STR00460## ##STR00461## ##STR00462## ##STR00463## ##STR00464## ##STR00465## ##STR00466## ##STR00467## ##STR00468## ##STR00469## ##STR00470## ##STR00471##

##STR00472## ##STR00473## ##STR00474## ##STR00475## ##STR00476## ##STR00477## ##STR00478## ##STR00479## ##STR00480## ##STR00481## ##STR00482## ##STR00483## ##STR00484## ##STR00485## ##STR00486## ##STR00487## ##STR00488## ##STR00489## ##STR00490## ##STR00491## ##STR00492## ##STR00493## ##STR00494## ##STR00495## ##STR00496## ##STR00497## ##STR00498## ##STR00499## ##STR00500## ##STR00501## ##STR00502## ##STR00503## ##STR00504## ##STR00505## ##STR00506## ##STR00507## ##STR00508## ##STR00509## ##STR00510##

##STR00511## ##STR00512## ##STR00513## ##STR00514## ##STR00515## ##STR00516## ##STR00517## ##STR00518## ##STR00519## ##STR00520## ##STR00521## ##STR00522## ##STR00523## ##STR00524## ##STR00525## ##STR00526## ##STR00527## ##STR00528## ##STR00529## ##STR00530## ##STR00531## ##STR00532## ##STR00533## ##STR00534## ##STR00535## ##STR00536## ##STR00537## ##STR00538## ##STR00539## ##STR00540## ##STR00541## ##STR00542## ##STR00543## ##STR00544## ##STR00545## ##STR00546## ##STR00547## ##STR00548## ##STR00549## ##STR00550## ##STR00551## ##STR00552## ##STR00553## ##STR00554## ##STR00555## ##STR00556## ##STR00557## ##STR00558## ##STR00559## ##STR00560## ##STR00561## ##STR00562## ##STR00563## ##STR00564## ##STR00565## ##STR00566## ##STR00567## ##STR00568## ##STR00569## ##STR00570## ##STR00571## ##STR00572##

[0325] In compounds 1 to 1621 of [Group 1-1], OMe represents a methoxy group.

##STR00573## ##STR00574## ##STR00575## ##STR00576## ##STR00577## ##STR00578## ##STR00579## ##STR00580## ##STR00581## ##STR00582## ##STR00583## ##STR00584## ##STR00585## ##STR00586## ##STR00587## ##STR00588## ##STR00589## ##STR00590## ##STR00591## ##STR00592## ##STR00593## ##STR00594## ##STR00595## ##STR00596## ##STR00597## ##STR00598## ##STR00599## ##STR00600## ##STR00601## ##STR00602## ##STR00603## ##STR00604## ##STR00605## ##STR00606## ##STR00607## ##STR00608## ##STR00609## ##STR00610## ##STR00611## ##STR00612## ##STR00613## ##STR00614## ##STR00615## ##STR00616## ##STR00617## ##STR00618## ##STR00619## ##STR00620## ##STR00621## ##STR00622## ##STR00623## ##STR00624## ##STR00625## ##STR00626## ##STR00627## ##STR00628## ##STR00629## ##STR00630## ##STR00631## ##STR00632## ##STR00633## ##STR00634## ##STR00635## ##STR00636## ##STR00637## ##STR00638## ##STR00639## ##STR00640##

##STR00641## ##STR00642## ##STR00643## ##STR00644## ##STR00645## ##STR00646## ##STR00647## ##STR00648## ##STR00649## ##STR00650## ##STR00651## ##STR00652## ##STR00653## ##STR00654## ##STR00655## ##STR00656## ##STR00657## ##STR00658## ##STR00659## ##STR00660## ##STR00661## ##STR00662## ##STR00663## ##STR00664## ##STR00665## ##STR00666## ##STR00667## ##STR00668## ##STR00669## ##STR00670## ##STR00671## ##STR00672## ##STR00673## ##STR00674## ##STR00675## ##STR00676## ##STR00677## ##STR00678## ##STR00679## ##STR00680## ##STR00681## ##STR00682## ##STR00683## ##STR00684## ##STR00685## ##STR00686## ##STR00687## ##STR00688## ##STR00689## ##STR00690## ##STR00691## ##STR00692## ##STR00693## ##STR00694## ##STR00695## ##STR00696## ##STR00697## ##STR00698## ##STR00699## ##STR00700## ##STR00701## ##STR00702## ##STR00703## ##STR00704## ##STR00705## ##STR00706## ##STR00707## ##STR00708## ##STR00709## ##STR00710## ##STR00711## ##STR00712## ##STR00713## ##STR00714## ##STR00715##

##STR00716## ##STR00717## ##STR00718## ##STR00719## ##STR00720## ##STR00721## ##STR00722## ##STR00723## ##STR00724## ##STR00725## ##STR00726## ##STR00727## ##STR00728## ##STR00729## ##STR00730## ##STR00731## ##STR00732## ##STR00733## ##STR00734## ##STR00735## ##STR00736## ##STR00737## ##STR00738## ##STR00739## ##STR00740## ##STR00741## ##STR00742## ##STR00743## ##STR00744## ##STR00745## ##STR00746## ##STR00747## ##STR00748## ##STR00749## ##STR00750## ##STR00751## ##STR00752## ##STR00753## ##STR00754## ##STR00755## ##STR00756## ##STR00757## ##STR00758## ##STR00759## ##STR00760## ##STR00761## ##STR00762## ##STR00763## ##STR00764## ##STR00765## ##STR00766## ##STR00767## ##STR00768## ##STR00769## ##STR00770## ##STR00771## ##STR00772## ##STR00773## ##STR00774## ##STR00775## ##STR00776## ##STR00777## ##STR00778## ##STR00779## ##STR00780## ##STR00781## ##STR00782## ##STR00783## ##STR00784## ##STR00785## ##STR00786## ##STR00787## ##STR00788## ##STR00789## ##STR00790## ##STR00791## ##STR00792## ##STR00793## ##STR00794## ##STR00795## ##STR00796## ##STR00797## ##STR00798## ##STR00799## ##STR00800## ##STR00801## ##STR00802## ##STR00803## ##STR00804## ##STR00805## ##STR00806## ##STR00807## ##STR00808## ##STR00809## ##STR00810## ##STR00811## ##STR00812## ##STR00813## ##STR00814## ##STR00815## ##STR00816## ##STR00817## ##STR00818## ##STR00819## ##STR00820## ##STR00821## ##STR00822## ##STR00823## ##STR00824## ##STR00825## ##STR00826## ##STR00827## ##STR00828## ##STR00829## ##STR00830## ##STR00831## ##STR00832##

##STR00833## ##STR00834## ##STR00835## ##STR00836## ##STR00837## ##STR00838## ##STR00839## ##STR00840## ##STR00841## ##STR00842## ##STR00843## ##STR00844## ##STR00845## ##STR00846## ##STR00847## ##STR00848## ##STR00849## ##STR00850## ##STR00851## ##STR00852## ##STR00853## ##STR00854## ##STR00855## ##STR00856## ##STR00857## ##STR00858## ##STR00859## ##STR00860## ##STR00861## ##STR00862## ##STR00863## ##STR00864## ##STR00865## ##STR00866## ##STR00867## ##STR00868## ##STR00869## ##STR00870## ##STR00871## ##STR00872## ##STR00873## ##STR00874## ##STR00875## ##STR00876## ##STR00877## ##STR00878## ##STR00879## ##STR00880## ##STR00881## ##STR00882## ##STR00883## ##STR00884## ##STR00885## ##STR00886## ##STR00887## ##STR00888## ##STR00889## ##STR00890## ##STR00891## ##STR00892## ##STR00893## ##STR00894## ##STR00895## ##STR00896## ##STR00897## ##STR00898## ##STR00899## ##STR00900## ##STR00901## ##STR00902## ##STR00903## ##STR00904## ##STR00905## ##STR00906## ##STR00907## ##STR00908## ##STR00909## ##STR00910## ##STR00911## ##STR00912## ##STR00913## ##STR00914## ##STR00915## ##STR00916## ##STR00917## ##STR00918## ##STR00919## ##STR00920## ##STR00921## ##STR00922## ##STR00923## ##STR00924## ##STR00925## ##STR00926## ##STR00927## ##STR00928## ##STR00929## ##STR00930## ##STR00931## ##STR00932## ##STR00933## ##STR00934## ##STR00935## ##STR00936## ##STR00937## ##STR00938## ##STR00939## ##STR00940## ##STR00941## ##STR00942## ##STR00943## ##STR00944## ##STR00945## ##STR00946##

##STR00947## ##STR00948## ##STR00949## ##STR00950## ##STR00951## ##STR00952## ##STR00953## ##STR00954## ##STR00955## ##STR00956## ##STR00957## ##STR00958## ##STR00959## ##STR00960## ##STR00961## ##STR00962## ##STR00963## ##STR00964## ##STR00965## ##STR00966## ##STR00967## ##STR00968## ##STR00969## ##STR00970## ##STR00971## ##STR00972## ##STR00973## ##STR00974## ##STR00975## ##STR00976## ##STR00977## ##STR00978## ##STR00979## ##STR00980## ##STR00981## ##STR00982## ##STR00983## ##STR00984## ##STR00985## ##STR00986## ##STR00987## ##STR00988## ##STR00989## ##STR00990## ##STR00991## ##STR00992## ##STR00993## ##STR00994## ##STR00995## ##STR00996## ##STR00997## ##STR00998## ##STR00999## ##STR01000## ##STR01001## ##STR01002## ##STR01003## ##STR01004## ##STR01005## ##STR01006## ##STR01007## ##STR01008## ##STR01009## ##STR01010## ##STR01011## ##STR01012## ##STR01013##

##STR01014## ##STR01015## ##STR01016## ##STR01017## ##STR01018## ##STR01019## ##STR01020## ##STR01021## ##STR01022## ##STR01023## ##STR01024## ##STR01025## ##STR01026## ##STR01027## ##STR01028## ##STR01029## ##STR01030## ##STR01031## ##STR01032## ##STR01033## ##STR01034## ##STR01035## ##STR01036## ##STR01037## ##STR01038## ##STR01039## ##STR01040## ##STR01041## ##STR01042## ##STR01043## ##STR01044## ##STR01045## ##STR01046##

##STR01047## ##STR01048## ##STR01049## ##STR01050## ##STR01051## ##STR01052## ##STR01053## ##STR01054## ##STR01055## ##STR01056## ##STR01057## ##STR01058## ##STR01059## ##STR01060## ##STR01061## ##STR01062## ##STR01063## ##STR01064## ##STR01065## ##STR01066## ##STR01067## ##STR01068## ##STR01069## ##STR01070## ##STR01071## ##STR01072## ##STR01073## ##STR01074## ##STR01075## ##STR01076## ##STR01077##

##STR01078## ##STR01079## ##STR01080## ##STR01081## ##STR01082## ##STR01083## ##STR01084## ##STR01085## ##STR01086## ##STR01087## ##STR01088## ##STR01089## ##STR01090## ##STR01091## ##STR01092## ##STR01093## ##STR01094## ##STR01095## ##STR01096## ##STR01097## ##STR01098## ##STR01099## ##STR01100## ##STR01101## ##STR01102## ##STR01103## ##STR01104## ##STR01105## ##STR01106## ##STR01107## ##STR01108## ##STR01109## ##STR01110## ##STR01111## ##STR01112## ##STR01113## ##STR01114## ##STR01115## ##STR01116## ##STR01117## ##STR01118## ##STR01119## ##STR01120## ##STR01121## ##STR01122## ##STR01123## ##STR01124## ##STR01125## ##STR01126## ##STR01127## ##STR01128## ##STR01129## ##STR01130## ##STR01131## ##STR01132## ##STR01133## ##STR01134## ##STR01135## ##STR01136## ##STR01137## ##STR01138## ##STR01139## ##STR01140## ##STR01141## ##STR01142## ##STR01143## ##STR01144## ##STR01145## ##STR01146## ##STR01147## ##STR01148## ##STR01149## ##STR01150## ##STR01151## ##STR01152## ##STR01153## ##STR01154## ##STR01155## ##STR01156## ##STR01157## ##STR01158## ##STR01159## ##STR01160## ##STR01161## ##STR01162## ##STR01163## ##STR01164## ##STR01165## ##STR01166## ##STR01167## ##STR01168## ##STR01169## ##STR01170## ##STR01171##

##STR01172## ##STR01173## ##STR01174## ##STR01175## ##STR01176## ##STR01177## ##STR01178## ##STR01179## ##STR01180## ##STR01181## ##STR01182## ##STR01183## ##STR01184## ##STR01185## ##STR01186## ##STR01187## ##STR01188## ##STR01189## ##STR01190## ##STR01191## ##STR01192## ##STR01193## ##STR01194## ##STR01195## ##STR01196## ##STR01197## ##STR01198## ##STR01199## ##STR01200## ##STR01201## ##STR01202## ##STR01203## ##STR01204## ##STR01205## ##STR01206## ##STR01207## ##STR01208## ##STR01209## ##STR01210## ##STR01211## ##STR01212## ##STR01213## ##STR01214## ##STR01215##

##STR01216## ##STR01217## ##STR01218## ##STR01219## ##STR01220## ##STR01221## ##STR01222## ##STR01223## ##STR01224## ##STR01225## ##STR01226## ##STR01227## ##STR01228## ##STR01229## ##STR01230##

##STR01231## ##STR01232## ##STR01233## ##STR01234## ##STR01235## ##STR01236## ##STR01237## ##STR01238## ##STR01239## ##STR01240## ##STR01241## ##STR01242## ##STR01243## ##STR01244## ##STR01245## ##STR01246## ##STR01247## ##STR01248## ##STR01249## ##STR01250## ##STR01251## ##STR01252## ##STR01253## ##STR01254## ##STR01255## ##STR01256## ##STR01257## ##STR01258## ##STR01259## ##STR01260## ##STR01261## ##STR01262## ##STR01263## ##STR01264## ##STR01265## ##STR01266## ##STR01267## ##STR01268## ##STR01269## ##STR01270## ##STR01271## ##STR01272## ##STR01273## ##STR01274## ##STR01275## ##STR01276## ##STR01277## ##STR01278## ##STR01279## ##STR01280## ##STR01281## ##STR01282## ##STR01283## ##STR01284## ##STR01285## ##STR01286## ##STR01287## ##STR01288## ##STR01289## ##STR01290## ##STR01291## ##STR01292## ##STR01293## ##STR01294## ##STR01295## ##STR01296## ##STR01297## ##STR01298## ##STR01299## ##STR01300## ##STR01301##

##STR01302## ##STR01303## ##STR01304## ##STR01305## ##STR01306## ##STR01307## ##STR01308## ##STR01309## ##STR01310## ##STR01311## ##STR01312## ##STR01313## ##STR01314## ##STR01315## ##STR01316## ##STR01317## ##STR01318## ##STR01319## ##STR01320## ##STR01321## ##STR01322## ##STR01323## ##STR01324## ##STR01325## ##STR01326## ##STR01327## ##STR01328## ##STR01329## ##STR01330## ##STR01331## ##STR01332## ##STR01333## ##STR01334## ##STR01335## ##STR01336## ##STR01337## ##STR01338## ##STR01339## ##STR01340## ##STR01341## ##STR01342## ##STR01343## ##STR01344## ##STR01345##

##STR01346## ##STR01347## ##STR01348## ##STR01349## ##STR01350## ##STR01351## ##STR01352## ##STR01353## ##STR01354## ##STR01355## ##STR01356## ##STR01357## ##STR01358## ##STR01359## ##STR01360## ##STR01361## ##STR01362## ##STR01363## ##STR01364## ##STR01365## ##STR01366## ##STR01367## ##STR01368## ##STR01369## ##STR01370## ##STR01371## ##STR01372## ##STR01373## ##STR01374## ##STR01375## ##STR01376## ##STR01377## ##STR01378## ##STR01379## ##STR01380## ##STR01381##

##STR01382## ##STR01383## ##STR01384## ##STR01385## ##STR01386##

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##STR02902## ##STR02903## ##STR02904## ##STR02905## ##STR02906## ##STR02907## ##STR02908## ##STR02909## ##STR02910## ##STR02911## ##STR02912## ##STR02913## ##STR02914## ##STR02915## ##STR02916## ##STR02917## ##STR02918## ##STR02919## ##STR02920## ##STR02921## ##STR02922## ##STR02923## ##STR02924## ##STR02925## ##STR02926## ##STR02927## ##STR02928## ##STR02929## ##STR02930## ##STR02931## ##STR02932## ##STR02933## ##STR02934## ##STR02935## ##STR02936## ##STR02937## ##STR02938## ##STR02939## ##STR02940## ##STR02941## ##STR02942## ##STR02943## ##STR02944## ##STR02945## ##STR02946## ##STR02947## ##STR02948## ##STR02949## ##STR02950## ##STR02951## ##STR02952## ##STR02953## ##STR02954## ##STR02955## ##STR02956## ##STR02957## ##STR02958## ##STR02959## ##STR02960## ##STR02961## ##STR02962## ##STR02963## ##STR02964## ##STR02965## ##STR02966## ##STR02967## ##STR02968## ##STR02969## ##STR02970## ##STR02971## ##STR02972## ##STR02973## ##STR02974## ##STR02975## ##STR02976## ##STR02977## ##STR02978## ##STR02979## ##STR02980## ##STR02981## ##STR02982## ##STR02983## ##STR02984## ##STR02985## ##STR02986## ##STR02987##

[0326] In one or more embodiments, the first hole-transporting compound and the second hole-transporting compound may each independently be at least one of Compounds H1-1 to H1-72 of [Group 5-1], Compounds H1-1 to H1-20 of [Group 5-2], or a combination thereof:

##STR02988## ##STR02989## ##STR02990## ##STR02991## ##STR02992## ##STR02993## ##STR02994## ##STR02995## ##STR02996## ##STR02997## ##STR02998## ##STR02999## ##STR03000## ##STR03001## ##STR03002## ##STR03003## ##STR03004## ##STR03005## ##STR03006## ##STR03007## ##STR03008##

##STR03009## ##STR03010## ##STR03011## ##STR03012## ##STR03013## ##STR03014## ##STR03015## ##STR03016##

[0327] In one or more embodiments, the first compound may be at least one of Compounds E1-1 to E1-62:

##STR03017## ##STR03018## ##STR03019## ##STR03020## ##STR03021## ##STR03022## ##STR03023## ##STR03024## ##STR03025## ##STR03026## ##STR03027## ##STR03028## ##STR03029## ##STR03030## ##STR03031## ##STR03032## ##STR03033## ##STR03034##

[0328] In one or more embodiments, the second compound may be at least one of Compounds BP1-1 to BP1-17:

##STR03035## ##STR03036## ##STR03037## ##STR03038## ##STR03039##

[0329] Description of FIG. 2

[0330] FIG. 2 schematically illustrates a cross-sectional view of an organic light-emitting device 10, which is a light-emitting device according to an embodiment. Hereinafter, the structure of an organic light-emitting device according to an embodiment of the present disclosure and a method of manufacturing an organic light-emitting device according to an embodiment of the present disclosure will be described in connection with FIG. 2.

[0331] The organic light-emitting device 10 of FIG. 2 includes a first electrode 11, a hole-transporting region 13, an emission layer 15, an electron-transporting region 17 and a second electrode 19, which are sequentially stacked. The emission layer 15 includes a first emission layer 15-1 and a second emission layer 15-2.

[0332] A substrate may be additionally located under the first electrode 11 or above the second electrode 19. For use as the substrate, any substrate that is used in organic light-emitting devices available in the art may be used, and the substrate may be a glass substrate or a transparent plastic substrate, each having excellent mechanical strength, thermal stability, transparency, surface smoothness, ease of handling, and water resistance.

[0333] In one or more embodiments, the first electrode 11 may be formed by depositing or sputtering a material for forming the first electrode 11 on the substrate. The first electrode 11 may be an anode. The material for forming the first electrode 11 may be selected from materials with a high work function to facilitate hole injection. The first electrode 11 may be a reflective electrode, a semi-transmissive electrode, or a transmissive electrode. The material for forming the first electrode 11 may be indium tin oxide (ITO), indium zinc oxide (IZO), tin oxide (SnO.sub.2), or zinc oxide (ZnO). In one or more embodiments, the material for forming the first electrode 11 may be metal, such as magnesium (Mg), aluminum (Al), aluminum-lithium (Al—Li), calcium (Ca), magnesium-indium (Mg—In), or magnesium-silver (Mg—Ag).

[0334] The first electrode 11 may have a single-layered structure or a multi-layered structure including two or more layers. For example, the first electrode 11 may have a three-layered structure of ITO/Ag/ITO, but the structure of the first electrode 11 is not limited thereto.

[0335] The hole-transporting region 13 may be located between the first electrode 11 and the emission layer 15.

[0336] The hole-transporting region 13 may include a hole injection layer, a hole-transporting layer, an electron-blocking layer, a buffer layer, or a combination thereof.

[0337] The hole-transporting region 13 may include only a hole injection layer or only a hole-transporting layer. In one or more embodiments, the hole-transporting region 13 may have a hole injection layer/hole-transporting layer structure or a hole injection layer/hole-transporting layer/electron-blocking layer structure, which are sequentially stacked in this stated order from the first electrode 11.

[0338] When the hole-transporting region 13 includes a hole injection layer, the hole injection layer may be formed on the first electrode 11 by using one or more suitable methods, for example, vacuum deposition, spin coating, casting, and/or Langmuir-Blodgett (LB) deposition.

[0339] When a hole injection layer is formed by vacuum deposition, the deposition conditions may vary depending on a material that is used to form the hole injection layer, and the structure and thermal characteristics of the hole injection layer. For example, the deposition conditions may include a deposition temperature of about 100° C. to about 500° C., a vacuum pressure of about 10.sup.−8 torr to about 10.sup.−3 torr, and a deposition rate of about 0.01 Å/sec to about 100 Å/sec.

[0340] When the hole injection layer is formed using spin coating, coating conditions may vary according to the material used to form the hole injection layer, and the structure and thermal properties of the hole injection layer. For example, a coating speed may be from about 2,000 rpm to about 5,000 rpm, and a temperature at which a heat treatment is performed to remove a solvent after coating may be from about 80° C. to about 200° C. However, the coating conditions are not limited thereto.

[0341] The conditions for forming the hole-transporting layer and the electron-blocking layer may be the same as the conditions for forming the hole injection layer.

[0342] The hole-transporting region 13 may include m-MTDATA, TDATA, 2-TNATA, NPB, β-NPB, TPD, Spiro-TPD, Spiro-NPB, methylated NPB, TAPC, HMTPD, 4,4′,4″-tris(N-carbazolyl)triphenylamine (TCTA), polyaniline/dodecylbenzenesulfonic acid (PANI/DBSA), poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) (PEDOT/PSS), polyaniline/camphor sulfonicacid (PANI/CSA), polyaniline/poly(4-styrenesulfonate) (PANI/PSS), a compound represented by Formula 201 below, a compound represented by Formula 202 below, or any combination thereof:

##STR03040## ##STR03041## ##STR03042##

[0343] Ar.sub.101 and Ar.sub.102 in Formula 201 may each independently be a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an acenaphthylene group, a fluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, or a pentacenylene group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, or any combination thereof.

[0344] xa and xb in Formula 201 may each independently be an integer from 0 to 5, or 0, 1, or 2. For example, xa may be 1 and xb may be 0, but xa and xb are not limited thereto.

[0345] R.sub.101 to R.sub.108, R.sub.111 to R.sub.119 and R.sub.121 to R.sub.124 in Formulae 201 and 202 may each independently be:

[0346] hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group (for example, a methyl group, an ethyl group, a propyl group, a butyl group, pentyl group, a hexyl group, or the like) or a C.sub.1-C.sub.10 alkoxy group (for example, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, or the like);

[0347] a C.sub.1-C.sub.10 alkyl group or a C.sub.1-C.sub.10 alkoxy group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, or any combination thereof; or

[0348] a phenyl group, a naphthyl group, an anthracenyl group, a fluorenyl group or a pyrenyl group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, or any combination thereof.

[0349] R.sub.109 in Formula 201 may be a phenyl group, a naphthyl group, an anthracenyl group, or a pyridinyl group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, an anthracenyl group, a pyridinyl group, or any combination thereof.

[0350] In one or more embodiments, the compound represented by Formula 201 may be represented by Formula 201A:

##STR03043##

[0351] R.sub.101, R.sub.111, R.sub.112, and R.sub.109 in Formula 201A may be understood by referring to the description provided herein.

[0352] For example, the hole-transporting region 13 may include one of Compounds HT1 to HT20 or any combination thereof:

##STR03044## ##STR03045## ##STR03046## ##STR03047## ##STR03048## ##STR03049## ##STR03050##

[0353] The thickness of the hole-transporting region 13 may be from about 100 Å to about 10000 Å, for example about 100 Å to about 1000 Å. When the hole-transporting region 13 includes a hole injection layer, a hole-transporting layer, an electron-blocking layer or a combination thereof, the thickness of the hole injection layer may be in a range of about 100 Å to about 10,000 Å, for example, about 100 Å to about 1,000 Å, and a thickness of the hole-transporting layer may be in a range of about 50 Å to about 2,000 Å, for example, about 100 Å to about 1,500 Å. When the thicknesses of the hole-transporting region, the hole injection layer and the hole-transporting layer are within these ranges, satisfactory hole-transporting characteristics may be obtained without a substantial increase in driving voltage.

[0354] In addition to the above-described materials, the hole-transporting region 13 may further include a charge-generation material to improve conductivity. The charge-generation material may be homogeneously or non-homogeneously dispersed in the hole-transporting region.

[0355] The charge-generation material may be, for example, a p-dopant. The p-dopant may include a quinone derivative, a metal oxide, a cyano group-containing compound, or any combination. For example, the p-dopant may be: a quinone derivative such as tetracyanoquinonedimethane (TCNQ), 2,3,5,6-tetrafluoro-tetracyano-1,4-benzoquinonedimethane (F4-TCNQ), or F6-TCNNQ; metal oxide, such as tungsten oxide and molybdenum oxide; a cyano group-containing compound, such as Compound HT-D1; or any combination thereof.

##STR03051##

[0356] The hole-transporting region 13 may further include a buffer layer.

[0357] Also, the buffer layer may compensate for an optical resonance distance according to a wavelength of light emitted from the emission layer, and thus, efficiency of a formed organic light-emitting device may be improved.

[0358] Meanwhile, when the hole-transporting region 13 includes an electron-blocking layer, the material for the electron-blocking layer may include a material that can be used in the hole-transporting region 13 as described above, a host material, or a combination thereof. For example, when the hole-transporting region includes an electron-blocking layer, mCP, Compound H1-8 of [Group 5-2], or the like may be used as a material for the electron-blocking layer.

[0359] The emission layer 15 may be formed on the hole-transporting region 13 by using, for example, a vacuum deposition method, a spin coating method, a cast method, or an LB method. When the emission layer 15 is formed by vacuum deposition or spin coating, the deposition or coating conditions may be similar to those applied in forming the hole injection layer although the deposition or coating conditions may vary depending on a material that is used to form the emission layer.

[0360] The emission layer 15 may include a first emission layer 15-1 and a second emission layer 15-2 as described herein.

[0361] The amount (weight) of the dopant in the first emission layer 15-1 may be from about 0.01 to about 20 parts by weight based on 100 parts by weight, which is the total weight of the first hole-transporting compound and the first compound.

[0362] The amount (weight) of the dopant in the second emission layer 15-2 may be from about 0.01 to about 20 parts by weight based on 100 parts by weight, which is the total weight of the second hole-transporting compound and the second compound.

[0363] A thickness of the emission layer 15 may be in a range of about 100 Å to about 1,000 Å, for example, about 200 Å to about 600 Å. When the thickness of the emission layer 15 is within these ranges, excellent light-emission characteristics may be obtained without a substantial increase in driving voltage.

[0364] Next, the electron-transporting region 17 may be located on the emission layer 15.

[0365] The electron-transporting region 17 may include a hole-blocking layer, an electron-transporting layer, an electron injection layer, or a combination thereof.

[0366] For example, the electron-transporting region 17 may have a hole-blocking layer/electron-transporting layer/electron injection layer structure or an electron-transporting layer/electron injection layer structure. The electron-transporting layer may have a single-layered structure or a multi-layered structure including two or more different materials.

[0367] The conditions for the formation of the hole-blocking layer, the electron-transporting layer and the electron injection layer in the electron-transporting region 17 are the same as the conditions for the formation of the hole injection layer.

[0368] When the electron-transporting region 17 includes a hole-blocking layer, the hole-blocking layer may include, for example, at least one of the following BCP, Bphen and BAlq.

##STR03052##

[0369] In one or more embodiments, the hole-blocking layer may include any host material, and a material for an electron-transporting layer, a material for an electron injection layer, or a combination thereof, which will be described later.

[0370] A thickness of the hole-blocking layer may be in a range of about 20 Å to about 1,000 Å, for example, about 30 Å to about 300 Å. When the thickness of the hole-blocking layer is within these ranges, excellent hole-blocking characteristics can be obtained without a substantial increase in driving voltage.

[0371] The electron-transporting layer may include BCP, Bphen, TPBi, Alq.sub.3, Balq, TAZ, NTAZ, or any combination thereof:

##STR03053##

[0372] In one or more embodiments, the electron-transporting layer may include at least one of Compounds ET1 to ET25.

##STR03054## ##STR03055## ##STR03056## ##STR03057## ##STR03058## ##STR03059## ##STR03060## ##STR03061##

[0373] A thickness of the electron-transporting layer may be in the range of about 100 Å to about 1,000 Å, for example, about 150 Å to about 500 Å. When the thickness of the electron-transporting layer is within the range described above, the electron-transporting layer may have satisfactory electron-transporting characteristics without a substantial increase in driving voltage.

[0374] The electron-transporting layer may include a metal-containing material in addition to the material as described above.

[0375] The metal-containing material may include a Li complex. The Li complex may include, for example, Compound ET-D1 or ET-D2:

##STR03062##

[0376] In one or more embodiments, the electron-transporting region 17 may include an electron injection layer (EIL) that facilitates injection of electrons from the second electrode 19.

[0377] The electron injection layer may include LiF, NaCl, CsF, Li.sub.2O, BaO, or any combination thereof.

[0378] A thickness of the electron injection layer may be in a range of about 1 Å to about 100 Å, and, for example, about 3 Å to about 90 Å. When the thickness of the electron injection layer is within the range described above, the electron injection layer may have satisfactory electron injection characteristics without a substantial increase in driving voltage.

[0379] A second electrode 19 may be provided on the electron-transporting region 17. The second electrode 19 may be a cathode. A material for forming the second electrode 19 may be metal, an alloy, an electrically conductive compound, or a combination thereof, which have a relatively low work function. For example, lithium (Li), magnesium (Mg), aluminum (Al), aluminum-lithium (Al—Li), calcium (Ca), magnesium-indium (Mg—In), or magnesium-silver (Mg—Ag) may be used as the material for forming the second electrode 19. In one or more embodiments, to manufacture a top-emission type light-emitting device, a transmissive electrode formed using ITO or IZO may be used as the second electrode 19.

[0380] Hereinbefore, the organic light-emitting device has been described with reference to FIG. 2, but embodiments of the present disclosure are not limited thereto.

[0381] According to another aspect, the light-emitting device may be included in an electronic apparatus. Thus, an electronic apparatus including the light-emitting device is provided. The electronic apparatus may include, for example, a display, an illumination, a sensor, and the like.

[0382] The term “C.sub.1-C.sub.60 alkyl group” as used herein refers to a linear or branched saturated aliphatic hydrocarbons monovalent group having 1 to 60 carbon atoms, and the term “C.sub.1-C.sub.60 alkylene group” as used herein refers to a divalent group having the same structure as the C.sub.1-C.sub.60 alkyl group.

[0383] Examples of the C.sub.1-C.sub.60 alkyl group, the C.sub.1-C.sub.20 alkyl group, and/or the C.sub.1-C.sub.10 alkyl group are a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, an n-hexyl group, an isohexyl group, a sec-hexyl group, a tert-hexyl group, an n-heptyl group, an isoheptyl group, a sec-heptyl group, a tert-heptyl group, an n-octyl group, an isooctyl group, a sec-octyl group, a tert-octyl group, an n-nonyl group, an isononyl group, a sec-nonyl group, a tert-nonyl group, an n-decyl group, an isodecyl group, a sec-decyl group, or a tert-decyl group, each unsubstituted or substituted with a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, an n-hexyl group, an isohexyl group, a sec-hexyl group, a tert-hexyl group, an n-heptyl group, an isoheptyl group, a sec-heptyl group, a tert-heptyl group, an n-octyl group, an isooctyl group, a sec-octyl group, a tert-octyl group, an n-nonyl group, an isononyl group, a sec-nonyl group, a tert-nonyl group, an n-decyl group, an isodecyl group, a sec-decyl group, a tert-decyl group, or any combination thereof. For example, Formula 9-33 is a branched C.sub.6 alkyl group, for example, a tert-butyl group that is substituted with two methyl groups.

[0384] The term “C.sub.1-C.sub.60 alkoxy group” used herein refers to a monovalent group represented by —OA.sub.101 (wherein A.sub.101 is the C.sub.1-C.sub.60 alkyl group), and examples thereof are a methoxy group, an ethoxy group, a propoxy group, a butoxy group, and a pentoxy group.

[0385] The term “C.sub.2-C.sub.60 alkenyl group” as used herein refers to a hydrocarbon group formed by substituting at least one carbon-carbon double bond in the middle or at the terminus of the C.sub.2-C.sub.60 alkyl group, and examples thereof include an ethenyl group, a propenyl group, and a butenyl group. The term “C.sub.2-C.sub.60 alkenylene group” as used herein refers to a divalent group having the same structure as the C.sub.2-C.sub.60 alkenyl group.

[0386] The term “C.sub.2-C.sub.60 alkynyl group” as used herein refers to a hydrocarbon group formed by substituting at least one carbon-carbon triple bond in the middle or at the terminus of the C.sub.2-C.sub.60 alkyl group, and examples thereof include an ethynyl group, and a propynyl group. The term “C.sub.2-C.sub.60 alkynylene group” as used herein refers to a divalent group having the same structure as the C.sub.2-C.sub.60 alkynyl group.

[0387] The term “C.sub.3-C.sub.10 cycloalkyl group” as used herein refers to a monovalent saturated hydrocarbon cyclic group having 3 to 10 carbon atoms, and the C.sub.3-C.sub.10 cycloalkylene group is a divalent group having the same structure as the C.sub.3-C.sub.10 cycloalkyl group.

[0388] Examples of the C.sub.3-C.sub.10 cycloalkyl group are a cyclopropyl group, a cyclobutyl group, a cyclopentyl, cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantanyl group, a norbornanyl group (or a bicyclo[2.2.1]heptyl group), a bicyclo[1.1.1]pentyl group, a bicyclo[2.1.1]hexyl group, and a bicyclo[2.2.2]octyl group.

[0389] The term “C.sub.1-C.sub.10 heterocycloalkyl group” as used herein refers to a monocyclic group that includes at least one hetero atom selected from N, O, P, Si, S, Se, Ge, and B as a ring-forming atom and 1 to 10 carbon atoms, and the C.sub.1-C.sub.10 heterocycloalkylene group refers to a divalent group having the same structure as the C.sub.1-C.sub.10 heterocycloalkyl group.

[0390] Examples of the C.sub.1-C.sub.10 heterocycloalkyl group are a silolanyl group, a silinanyl group, tetrahydrofuranyl group, a tetrahydro-2H-pyranyl group, and a tetrahydrothiophenyl group.

[0391] The term “C.sub.3-C.sub.10 cycloalkenyl group” as used herein refers to a monovalent monocyclic group that has 3 to 10 carbon atoms and at least one carbon-carbon double bond in the ring thereof and no aromaticity, and non-limiting examples thereof include a cyclopentenyl group, a cyclohexenyl group, and a cycloheptenyl group. The term “C.sub.3-C.sub.10 cycloalkenylene group” as used herein refers to a divalent group having the same structure as the C.sub.3-C.sub.10 cycloalkenyl group.

[0392] The term “C.sub.1-C.sub.10 heterocycloalkenyl group” as used herein refers to a monovalent monocyclic group that has at least one hetero atom selected from N, O, P, Si, S, Se, Ge, and B as a ring-forming atom, 1 to 10 carbon atoms, and at least one carbon-carbon double bond in its ring. Examples of the C.sub.1-C.sub.10 heterocycloalkenyl group are a 2,3-dihydrofuranyl group, and a 2,3-dihydrothiophenyl group. The term “C.sub.1-C.sub.10 heterocycloalkenylene group” as used herein refers to a divalent group having the same structure as the C.sub.1-C.sub.10 heterocycloalkenyl group.

[0393] The term “C.sub.6-C.sub.60 aryl group” as used herein refers to a monovalent group having a carbocyclic aromatic system having 6 to 60 carbon atoms, and the term “C.sub.6-C.sub.60 arylene group” as used herein refers to a divalent group having a carbocyclic aromatic system having 6 to 60 carbon atoms. Examples of the C.sub.6-C.sub.60 aryl group include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a pyrenyl group, and a chrysenyl group. When the C.sub.6-C.sub.60 aryl group and the C.sub.6-C.sub.60 arylene group each include two or more rings, the rings may be fused to each other.

[0394] The C.sub.7-C.sub.60 alkylaryl group used herein refers to a C.sub.6-C.sub.60 aryl group substituted with at least one C.sub.1-C.sub.60 alkyl group.

[0395] The term “C.sub.1-C.sub.60 heteroaryl group” as used herein refers to a monovalent group having at least one hetero atom selected from N, O, P, Si, S, Se, Ge, and B as a ring-forming atom and a cyclic aromatic system having 1 to 60 carbon atoms, and the term “C.sub.1-C.sub.60 heteroarylene group” as used herein refers to a divalent group having at least one hetero atom selected from N, O, P, Si, S, Se, Ge, and B as a ring-forming atom and a carbocyclic aromatic system having 1 to 60 carbon atoms. Examples of the C.sub.1-C.sub.60 heteroaryl group include a pyridinyl group, a pyrimidinyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group. When the C.sub.6-C.sub.60 heteroaryl group and the C.sub.6-C.sub.60 heteroarylene group each include two or more rings, the rings may be fused to each other.

[0396] The C.sub.2-C.sub.60 alkylheteroaryl group used herein refers to a C.sub.1-C.sub.60 heteroaryl group substituted with at least one C.sub.1-C.sub.60 alkyl group.

[0397] The term “C.sub.6-C.sub.60 aryloxy group” as used herein indicates —OA.sub.102 (wherein A.sub.102 indicates the C.sub.6-C.sub.60 aryl group), the C.sub.6-C.sub.60 arylthio group indicates —SA.sub.103 (wherein A.sub.103 indicates the C.sub.6-C.sub.60 aryl group), and the C.sub.1-C.sub.60 alkylthio group indicates —SA.sub.104 (wherein A.sub.104 indicates the C.sub.1-C.sub.60 alkyl group).

[0398] The term “monovalent non-aromatic condensed polycyclic group” as used herein refers to a monovalent group (for example, having 8 to 60 carbon atoms) having two or more rings condensed to each other, only carbon atoms as ring-forming atoms, and no aromaticity in its entire molecular structure. Examples of the monovalent non-aromatic condensed polycyclic group include a fluorenyl group. The term “divalent non-aromatic condensed polycyclic group” as used herein refers to a divalent group having the same structure as a monovalent non-aromatic condensed polycyclic group.

[0399] The term “monovalent non-aromatic condensed heteropolycyclic group” as used herein refers to a monovalent group (for example, having 1 to 60 carbon atoms) having two or more rings condensed to each other, at least one heteroatom selected from N, O, P, Si, S, Se, Ge, and B, other than carbon atoms, as a ring-forming atom, and no aromaticity in its entire molecular structure. Examples of the monovalent non-aromatic condensed heteropolycyclic group include a carbazolyl group. The term “divalent non-aromatic condensed heteropolycyclic group” as used herein refers to a divalent group having the same structure as a monovalent non-aromatic heterocondensed polycyclic group.

[0400] The term “C.sub.5-C.sub.30 carbocyclic group” as used herein refers to a saturated or unsaturated cyclic group having, as a ring-forming atom, 5 to 30 carbon atoms only. The C.sub.5-C.sub.30 carbocyclic group may be a monocyclic group or a polycyclic group. Examples of the “C.sub.5-C.sub.30 carbocyclic group (unsubstituted or substituted with at least one R.sub.10a)” used herein are an adamantane group, a norbornene group, a bicyclo[1.1.1]pentane group, a bicyclo[2.1.1]hexane group, a bicyclo[2.2.1]heptane(norbornane) group, a bicyclo[2.2.2]octane group, a cyclopentane group, a cyclohexane group, a cyclohexene group, a benzene group, a naphthalene group, an anthracene group, a phenanthrene group, a triphenylene group, a pyrene group, a chrysene group, a 1,2,3,4-tetrahydronaphthalene group, a cyclopentadiene group, and a fluorene group (each unsubstituted or substituted with at least one R.sub.10a).

[0401] The term “C.sub.1-C.sub.30 heterocyclic group” as used herein refers to a saturated or unsaturated cyclic group having, as a ring-forming atom, at least one heteroatom selected from N, O, P, Si, S, Se, Ge, and B other than 1 to 30 carbon atoms. The C.sub.1-C.sub.30 heterocyclic group may be a monocyclic group or a polycyclic group. The “C.sub.1-C.sub.30 heterocyclic group (unsubstituted or substituted with at least one R.sub.10a)” may be, for example, a thiophene group, a furan group, a pyrrole group, a silole group, borole group, a phosphole group, a selenophene group, a germole group, a benzothiophene group, a benzofuran group, an indole group, a benzosilole group, a benzoborole group, a benzophosphole group, a benzoselenophene group, a benzogermole group, a dibenzothiophene group, a dibenzofuran group, a carbazole group, a dibenzosilole group, a dibenzoborole group, a dibenzophosphole group, a dibenzoselenophene group, a dibenzogermole group, a dibenzothiophene 5-oxide group, a 9H-fluoren-9-one group, a dibenzothiophene 5,5-dioxide group, an azabenzothiophene group, an azabenzofuran group, an azaindole group, an azaindene group, an azabenzosilole group, an azabenzoborole group, an azabenzophosphole group, an azabenzoselenophene group, an azabenzogermole group, an azadibenzothiophene group, an azadibenzofuran group, an azacarbazole group, an azafluorene group, an azadibenzosilole group, an azadibenzoborole group, an azadibenzophosphole group, an azadibenzoselenophene group, an azadibenzogermole group, an azadibenzothiophene 5-oxide group, an aza-9H-fluoren-9-one group, an azadibenzothiophene 5,5-dioxide group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, a triazine group, a quinoline group, an isoquinoline group, a quinoxaline group, a quinazoline group, a phenanthroline group, a pyrazole group, an imidazole group, a triazole group, an oxazole group, an isooxazole group, a thiazole group, an isothiazole group, an oxadiazole group, a thiadiazole group, a benzopyrazole group, a benzimidazole group, a benzoxazole group, a benzothiazole group, a benzoxadiazole group, a benzothiadiazole group, a 5,6,7,8-tetrahydroisoquinoline group, or a 5,6,7,8-tetrahydroquinoline group (each unsubstituted or substituted with at least one R.sub.10a).

[0402] In one or more embodiments, examples of the “C.sub.5-C.sub.30 carbocyclic group” and “C.sub.1-C.sub.30 heterocyclic group” used herein include i) a third ring, ii) a fourth ring, iii) a condensed ring in which two or more third rings are condensed with each other, iv) a condensed ring in which two or more fourth rings are condensed with each other, or v) a condensed ring in which at least one third ring is condensed with at least one fourth ring, the third ring may be a cyclopentane group, a cyclopentene group, a furan group, a thiophene group, a pyrrole group, a silole group, a borole group, a phosphole group, a germole group, a selenophene group, an oxazole group, an oxadiazole group, an oxatriazole group, a thiazole group, a thiadiazole group, a thiatriazole group, a pyrazole group, an imidazole group, a triazole group, a tetrazole group, or an azasilole group, and the fourth ring may be an adamantane group, a norbornane group, a norbornene group, a cyclohexane group, a cyclohexene group, a benzene group, a pyridine group, a pyrimidine group, a pyrazine group, a pyridazine group, or a triazine group.

[0403] The terms “fluorinated C.sub.1-C.sub.60 alkyl group (or a fluorinated C.sub.1-C.sub.20 alkyl group or the like)”, “fluorinated C.sub.3-C.sub.10 cycloalkyl group”, “fluorinated C.sub.1-C.sub.10 heterocycloalkyl group,” and “fluorinated phenyl group” respectively indicate a C.sub.1-C.sub.60 alkyl group (or a C.sub.1-C.sub.20 alkyl group or the like), a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, and a phenyl group, each substituted with at least one fluoro group (—F). For example, the term “fluorinated C.sub.1 alkyl group (that is, a fluorinated methyl group)” includes —CF.sub.3, —CF.sub.2H, and —CFH.sub.2. The “fluorinated C.sub.1-C.sub.60 alkyl group (or, a fluorinated C.sub.1-C.sub.20 alkyl group, or the like)”, “the fluorinated C.sub.3-C.sub.10 cycloalkyl group”, “the fluorinated C.sub.1-C.sub.10 heterocycloalkyl group”, or “the fluorinated a phenyl group” may be i) a fully fluorinated C.sub.1-C.sub.60 alkyl group (or, a fully fluorinated C.sub.1-C.sub.20 alkyl group, or the like), a fully fluorinated C.sub.3-C.sub.10 cycloalkyl group, a fully fluorinated C.sub.1-C.sub.10 heterocycloalkyl group, or a fully fluorinated phenyl group, wherein, in each group, all hydrogen included therein is substituted with a fluoro group, or ii) a partially fluorinated C.sub.1-C.sub.60 alkyl group (or, a partially fluorinated C.sub.1-C.sub.20 alkyl group, or the like), a partially fluorinated C.sub.3-C.sub.10 cycloalkyl group, a partially fluorinated C.sub.1-C.sub.10 heterocycloalkyl group, or partially fluorinated phenyl group, wherein, in each group, all hydrogen included therein is not substituted with a fluoro group.

[0404] The terms “deuterated C.sub.1-C.sub.60 alkyl group (or a deuterated C.sub.1-C.sub.20 alkyl group or the like)”, “deuterated C.sub.3-C.sub.10 cycloalkyl group”, “deuterated heterocycloalkyl group,” and “deuterated phenyl group” respectively indicate a C.sub.1-C.sub.60 alkyl group (or a C.sub.1-C.sub.20 alkyl group or the like), a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, and a phenyl group, each substituted with at least one deuterium. For example, the “deuterated C.sub.1 alkyl group (that is, the deuterated methyl group)” may include —CD.sub.3, —CD.sub.2H, and —CDH.sub.2, and examples of the “deuterated C.sub.3-C.sub.10 cycloalkyl group” are, for example, Formula 10-501 and the like. The “deuterated C.sub.1-C.sub.60 alkyl group (or, the deuterated C.sub.1-C.sub.20 alkyl group or the like)”, “the deuterated C.sub.3-C.sub.10 cycloalkyl group”, “the deuterated heterocycloalkyl group”, or “the deuterated phenyl group” may be i) a fully deuterated C.sub.1-C.sub.60 alkyl group (or, a fully deuterated C.sub.1-C.sub.20 alkyl group or the like), a fully deuterated C.sub.3-C.sub.10 cycloalkyl group, a fully deuterated heterocycloalkyl group, or a fully deuterated phenyl group, in which, in each group, all hydrogen included therein are substituted with deuterium, or ii) a partially deuterated C.sub.1-C.sub.60 alkyl group (or, a partially deuterated C.sub.1-C.sub.20 alkyl group or the like), a partially deuterated C.sub.3-C.sub.10 cycloalkyl group, a partially deuterated heterocycloalkyl group, or a partially deuterated phenyl group, in which, in each group, all hydrogen included therein are not substituted with deuterium.

[0405] The term “(C.sub.1-C.sub.20 alkyl) ‘X’ group” as used herein refers to a ‘X’ group that is substituted with at least one C.sub.1-C.sub.20 alkyl group. For example, the term “(C.sub.1-C.sub.20 alkyl)C.sub.3-C.sub.10 cycloalkyl group” as used herein refers to a C.sub.3-C.sub.10 cycloalkyl group substituted with at least one C.sub.1-C.sub.20 alkyl group, and the term “(C.sub.1-C.sub.20 alkyl)phenyl group” as used herein refers to a phenyl group substituted with at least one C.sub.1-C.sub.20 alkyl group. An example of a (C.sub.1 alkyl) phenyl group is a toluyl group.

[0406] The terms “an azaindole group, an azabenzoborole group, an azabenzophosphole group, an azaindene group, an azabenzosilole group, an azabenzogermole group, an azabenzothiophene group, an azabenzoselenophene group, an azabenzofuran group, an azacarbazole group, an azadibenzoborole group, an azadibenzophosphole group, an azafluorene group, an azadibenzosilole group, an azadibenzogermole group, an azadibenzothiophene group, an azadibenzoselenophene group, an azadibenzofuran group, an azadibenzothiophene 5-oxide group, an aza-9H-fluoren-9-one group, and an azadibenzothiophene 5,5-dioxide group” respectively refer to heterocyclic groups having the same backbones as “an indole group, a benzoborole group, a benzophosphole group, an indene group, a benzosilole group, a benzogermole group, a benzothiophene group, a benzoselenophene group, a benzofuran group, a carbazole group, a dibenzoborole group, a dibenzophosphole group, a fluorene group, a dibenzosilole group, a dibenzogermole group, a dibenzothiophene group, a dibenzoselenophene group, a dibenzofuran group, a dibenzothiophene 5-oxide group, a 9H-fluoren-9-one group, and a dibenzothiophene 5,5-dioxide group,” in which, in each group, at least one carbon selected from ring-forming carbons is substituted with nitrogen.

[0407] At least one substituent of the substituted C.sub.5-C.sub.30 carbocyclic group, the substituted C.sub.2-C.sub.30 heterocyclic group, the substituted C.sub.1-C.sub.60 alkyl group, the substituted C.sub.2-C.sub.60 alkenyl group, the substituted C.sub.2-C.sub.60 alkynyl group, the substituted C.sub.1-C.sub.60 alkoxy group, the substituted C.sub.1-C.sub.60 alkylthio group, the substituted C.sub.3-C.sub.10 cycloalkyl group, the substituted C.sub.1-C.sub.10 heterocycloalkyl group, the substituted C.sub.3-C.sub.10 cycloalkenyl group, the substituted C.sub.1-C.sub.10 heterocycloalkenyl group, the substituted C.sub.6-C.sub.60 aryl group, the substituted C.sub.7-C.sub.60 alkylaryl group, the substituted C.sub.6-C.sub.60 aryloxy group, the substituted C.sub.6-C.sub.60 arylthio group, the substituted C.sub.1-C.sub.60 heteroaryl group, the substituted C.sub.2-C.sub.60 alkyl heteroaryl group, the substituted monovalent non-aromatic condensed polycyclic group, and the substituted monovalent non-aromatic condensed heteropolycyclic group may each independently be:

[0408] deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, or a C.sub.1-C.sub.60 alkylthio group;

[0409] a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, or a C.sub.1-C.sub.60 alkylthio group, each substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.7-C.sub.60 alkyl aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a C.sub.2-C.sub.60 alkyl heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q.sub.11)(Q.sub.12), —Si(Q.sub.13)(Q.sub.14)(Q.sub.15), —B(Q.sub.16)(Q.sub.17), —P(═O)(Q.sub.18)(Q.sub.19), —P(Q.sub.18)(Q.sub.19), or any combination thereof;

[0410] a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.7-C.sub.60 alkyl aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a C.sub.2-C.sub.60 alkyl heteroaryl group, a monovalent non-aromatic condensed polycyclic group, or a monovalent non-aromatic condensed heteropolycyclic group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CF.sub.3, —CF.sub.2H, —CFH.sub.2, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.1-C.sub.60 alkylthio group C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.7-C.sub.60 alkyl aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a C.sub.2-C.sub.60 alkyl heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q.sub.21)(Q.sub.22), —Si(Q.sub.23)(Q.sub.24)(Q.sub.25), —B(Q.sub.26)(Q.sub.27), —P(═O)(Q.sub.28)(Q.sub.29), —P(Q.sub.28)(Q.sub.29), or any combination thereof;

[0411] —N(Q.sub.31)(Q.sub.32), —Si(Q.sub.33)(Q.sub.34)(Q.sub.35), —B(Q.sub.36)(Q.sub.37), —P(═O)(Q.sub.38)(Q.sub.39), or —P(Q.sub.38)(Q.sub.39); or

[0412] any combination thereof,

[0413] Q.sub.1 to Q.sub.9, Q.sub.11 to Q.sub.19, Q.sub.21 to Q.sub.29 and Q.sub.31 to Q.sub.39 described herein may each independently be: hydrogen; deuterium; —F; —Cl; —Br; —I; a hydroxyl group; a cyano group; a nitro group; an amidino group; a hydrazine group; a hydrazone group; a carboxylic acid group or a salt thereof; a sulfonic acid group or a salt thereof; a phosphoric acid group or a salt thereof; a C.sub.1-C.sub.60 alkyl group which is unsubstituted or substituted with deuterium, a C.sub.1-C.sub.60 alkyl group, a C.sub.6-C.sub.60 aryl group, or any combination thereof; a C.sub.2-C.sub.60 alkenyl group; a C.sub.2-C.sub.60 alkynyl group; a C.sub.1-C.sub.60 alkoxy group; a C.sub.1-C.sub.60 alkylthio group; a C.sub.3-C.sub.10 cycloalkyl group; a C.sub.1-C.sub.10 heterocycloalkyl group; a C.sub.3-C.sub.10 cycloalkenyl group; a C.sub.1-C.sub.10 heterocycloalkenyl group; a C.sub.6-C.sub.60 aryl group which is unsubstituted or substituted with deuterium, a C.sub.1-C.sub.60 alkyl group, a C.sub.6-C.sub.60 aryl group, or any combination thereof; a C.sub.6-C.sub.60 aryloxy group; a C.sub.6-C.sub.60 arylthio group; a C.sub.1-C.sub.60 heteroaryl group; a monovalent non-aromatic condensed polycyclic group; or a monovalent non-aromatic condensed heteropolycyclic group.

[0414] For example, Q.sub.1 to Q.sub.9, Q.sub.11 to Q.sub.19, Q.sub.21 to Q.sub.29 and Q.sub.31 to Q.sub.39 described herein may each independently be:

[0415] —CH.sub.3, —CD.sub.3, —CD.sub.2H, —CDH.sub.2, —CH.sub.2CH.sub.3, —CH.sub.2CD.sub.3, —CH.sub.2CD.sub.2H, —CH.sub.2CDH.sub.2, —CHDCH.sub.3, —CHDCD.sub.2H, —CHDCDH.sub.2, —CHDCD.sub.3, —CD.sub.2CD.sub.3, —CD.sub.2CD.sub.2H, or —CD.sub.2CDH.sub.2; or

[0416] an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, a tert-pentyl group, a neopentyl group, an isopentyl group, a sec-pentyl group, a 3-pentyl group, a sec-isopentyl group, a phenyl group, a biphenyl group, or a naphthyl group, each unsubstituted or substituted with deuterium, a C.sub.1-C.sub.10 alkyl group, a phenyl group, or any combination thereof.

[0417] As used herein, the number of carbons in each group that is substituted (e.g., C.sub.1-C.sub.60) excludes the number of carbons in the substituent. For example, a C.sub.1-C.sub.60 alkyl group can be substituted with a C.sub.1-C.sub.60 alkyl group. The total number of carbons included in the C.sub.1-C.sub.60 alkyl group substituted with the C.sub.1-C.sub.60 alkyl group is not limited to 60 carbons. In addition, more than one C.sub.1-C.sub.60 alkyl substituent may be present on the C.sub.1-C.sub.60 alkyl group. This definition is not limited to the C.sub.1-C.sub.60 alkyl group and applies to all substituted groups that recite a carbon range.

[0418] Hereinafter, a compound and an organic light-emitting device according to embodiments are described in detail with reference to Synthesis Example and Examples. However, the organic light-emitting device is not limited thereto. The wording “B was used instead of A” used in describing Synthesis Examples means that an amount of A used was identical to an amount of B used, in terms of a molar equivalent.

EXAMPLES

Synthesis Example 1 (D-Ir(1))

[0419] ##STR03063##

Synthesis of Compound 1390A

[0420] 4-isobutyl-2-phenyl-5-(trimethylsilyl)pyridine (33.1 mmol) and iridium chloride (IrCl.sub.3(H.sub.2O).sub.n) (5.2 g, 14.7 mmol) were mixed with 120 mL of ethoxyethanol and 40 mL of distilled water and then, stirred under reflux for 24 hours, and then the temperature was lowered to room temperature. The resulting solid was separated by filtration, washed sufficiently with water, methanol, and hexane, in this stated order, and then dried in a vacuum oven to obtain 7.4 g (74% of yield) of Compound 1390A.

Synthesis of Compound 1390B

[0421] Compound 1390A (1.2 mmol) and 45 mL of methylene chloride were mixed, and then, AgOTf (silver trifluoromethanesulfonate) (0.6 g, 2.3 mmol) was added thereto after being mixed with 15 mL of methanol. Thereafter, the mixture was stirred for 18 hours at room temperature while light was blocked with aluminum foil, and then filtered through Celite to remove the resulting solid, and the filtrate was subjected to reduced pressure to obtain a solid (Compound 1390B). Compound 1390B was used in the next reaction without an additional purification process.

Synthesis of D-Ir(1) (Compound 1390 of [Group 1-3])

[0422] Compound 1390B (2.3 mmol) and 1-(3,5-diisopropyl-[1,1′-biphenyl]-4-yl)-2-(7-phenyldibenzo[b,d]furan-4-yl)-1H-benzo[d]imidazole (2.8 mmol) were mixed with 50 mL of 2-ethoxyethanol and 50 mL of N,N-dimethylformamide and then, stirred under reflux for 48 hours and then, the temperature was lowered to a room temperature. The obtained mixture was subjected to a reduced pressure to obtain a solid, on which column chromatography (eluent: methylene chloride (MC) and hexane) was performed to obtain 0.56 g (yield of 39%) of D-Ir(1) (Compound 1390 of [Group 1-3]). The obtained compound was identified by mass spectrometry (MS) and high performance liquid chromatography (HPLC) analysis.

[0423] High resolution mass spectrometry (matrix-assisted laser desorption ionization) (HRMS(MALDI)) calcd for C.sub.79H.sub.83IrN.sub.4OSi.sub.2: m/z 1352.5735 Found: 1352.5733

Evaluation Example 1

[0424] The HOMO energy levels of the following compounds were found by the measurement using a photoelectron spectrometer (manufactured by RIKEN KEIKI Co., Ltd.: AC3) in air, and the found values are shown in Table 1.

TABLE-US-00001 TABLE 1 Measured value of HOMO energy Compound level (eV) Compounds HT(1) (Compound −5.60 used in H1-8 of [Group 5-2]) Examples HT(2) (Compound −5.58 H1-2 of [Group 5-2]) E1-62 −6.08 BP1-10 −5.74 D-Ir(1) (Compound −5.34 1390 of [Group 1-3]) Compounds CBP −6.05 used in TCTA −5.77 Comparative UGH3 <−7.00  Example 3 TAZ −6.25 — Ir(ppy).sub.3 −5.35

##STR03064## ##STR03065## ##STR03066##

Example 1

[0425] An ITO (as an anode)-patterned glass substrate was cut to a size of 50 mm×50 mm×0.5 mm, sonicated with isopropyl alcohol and pure water, each for 5 minutes, and then cleaned by exposure to ultraviolet rays and ozone for 30 minutes. The resultant glass substrate was loaded onto a vacuum deposition apparatus.

[0426] HT3 and F6-TCNNQ were vacuum deposited on the anode at the weight ratio of 98:2 to form a hole injection layer having a thickness of 100 Å, and then, HT3 was vacuum-deposited on the hole injection layer to form a hole-transporting layer having a thickness of 1,350 Å. HT(1) was vacuum-deposited on the hole-transporting layer to form an electron-blocking layer having a thickness of 300 Å.

[0427] Then, a first hole-transporting compound (HT(1)), a first compound (E1-62), and dopant (Ir(ppy).sub.3) were co-deposited on the electron-blocking layer to form a first emission layer having a thickness of 100 Å (10 nm), and a second hole-transporting compound (HT(2)), a second compound (BP1-10), and dopant (Ir(ppy).sub.3) were co-deposited on the first emission layer to form a second emission layer having a thickness of 300 Å (30 nm). The amount of the dopant in the first emission layer was 7 parts by weight based on 100 parts by weight of the first emission layer, the weight ratio of the first hole-transporting compound to the first compound in the first emission layer is shown in Table 2, and the amount of the dopant in the second emission layer was 7 parts by weight based on 100 parts by weight of the second emission layer, and the weight ratio of the second hole-transporting compound to the second compound in the second emission layers is shown in Table 2.

[0428] Then, ET3 and ET-D1 were co-deposited at the volume ratio of 50:50 on the emission layer to form an electron-transporting layer having a thickness of 350 Å, and ET-D1 was vacuum-deposited on the electron-transporting layer to form an electron injection layer having a thickness of 10 Å, and Al was vacuum-deposited on the electron injection layer to form a cathode having a thickness of 1000 Å, thereby completing the manufacture of an organic light-emitting device.

##STR03067##

Comparative Examples 1 to 3

[0429] Organic light-emitting devices were manufactured in the same method as in Example 1, except that the configuration of an emission layer was changed as described in Table 2 (Comparative Example 1 did not include a second emission layer and Comparative Example 2 did not include a first emission layer)

TABLE-US-00002 TABLE 2 Example Comparative Comparative Comparative Emission layer 1 Example 1 Example 2 Example 3 Second Second HT(2) — HT(2) TCTA emission hole- layer transporting compound Second BP1-10 — BP1-10 TAZ compound Dopant Ir(ppy).sub.3 — Ir(ppy).sub.3 Ir(ppy).sub.3 Absolute 0.16 eV — 0.16 eV 0.48 eV value of the difference between the HOMO energy level of the second hole- transporting compound and the HOMO energy level of the second compound weight 5:5 — 5:5 5:5 ratio of second hole- transporting compound to second compound thickness 30 nm — 40 nm 30 nm of the second emission layer First First hole- HT(1) HT(1) — CBP emission transporting layer compound First E1-62 E1-62 — UGH3 compound Dopant Ir(ppy).sub.3 Ir(ppy).sub.3 — Ir(ppy).sub.3 Weight 7.5:2.5 7.5:2.5 — 7.5:2.5 ratio of first hole- transporting compound to first compound Thickness 10 nm 40 nm — 10 nm of the first emission layer

Evaluation Example 2

[0430] For each of the organic light-emitting devices manufactured in Example 1 and Comparative Examples 1 to 3, the driving voltage (V), maximum value of luminescence efficiency (cd/A), roll-off ratio (%), power efficiency (Im/W), and lifespan (LT.sub.97) were evaluated, and the results are shown in Table 3. As an evaluation device, a current-voltmeter (Keithley 2400) and a luminance meter (Minolta Cs-1000A) were used, and the lifespan (LT.sub.97) (at 8000 nit) was evaluated as the time taken for luminance to reduce to 97% of 100% of the initial luminance. Lifespan (LT.sub.97) of Table 3 was represented as a relative value (%). The roll-off ratio was calculated according to Equation 20 below.

Roll-off ratio={1−(luminescence efficiency (at 8000 nit)/maximum luminescence efficiency)}×100%  <Equation 20>

TABLE-US-00003 TABLE 3 Maximum value of Power current efficiency efficiency (Im/W at Driving (cd/A) Roll-off 8000 nit) LT.sub.97 voltage (Relative ratio (Relative (Relative (V) value, %) (%) value, %) value, %) Example 1 4.1 107 13 121 155 Comparative 4.5 100 17 100 100 Example 1 Comparative 4.4 103 17 104  81 Example 2 Comparative 5.2  75 28  55  7 Example 3

[0431] From Table 3, it is confirmed that the organic light-emitting device of Example 1 has improved characteristics in terms of driving voltage, luminescence efficiency, roll-off ratio, power efficiency and lifespan, compared to the organic light-emitting devices of Comparative Examples 1 to 3.

Examples 11 to 16

[0432] Organic light-emitting devices were manufactured in the same manner as in Example 1, except that the configuration of an emission layer is changed as shown in Table 4.

TABLE-US-00004 TABLE 4 Example Example Example Example Example Example Emission layer 11 12 13 14 15 16 Second Second HT(2) HT(2) HT(2) HT(2) HT(2) HT(2) emission hole- layer transporting compound Second BP1-10 BP1-10 BP1-10 BP1-10 BP1-10 BP1-10 compound Dopant D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) Weight 6:4 5:5 4:6 5:5 4:6 3:7 ratio of second hole- transporting compound and second compound Thickness 30 nm 30 nm 30 nm 20 nm 20 nm 20 nm of the second emission layer First First hole- HT(1) HT(1) HT(1) HT(1) HT(1) HT(1) emission transporting layer compound First E1-62 E1-62 E1-62 E1-62 E1-62 E1-62 compound Dopant D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) D-Ir(1) Weight 7.5:2.5 7.5:2.5 7.5:2.5 7.5:2.5 7.5:2.5 7.5:2.5 ratio of first hole- transporting compound to first compound Thickness 10 nm 10 nm 10 nm 20 nm 20 nm 20 nm of the first emission layer

Evaluation Example 3

[0433] For each of the organic light-emitting devices manufactured according to Examples 11 to 16, the driving voltage (V), the maximum value of luminescence efficiency (cd/A), the roll-off ratio (%), power efficiency (Im/W), and the lifespan (LT.sub.97) were evaluated by using the same method as described in Evaluation Example 2, and the results are shown in Table 5. For reference, the data of Comparative Example 3 are shown in Table 5.

TABLE-US-00005 TABLE 5 Maximum value of Power current efficiency efficiency (Im/W at Driving (cd/A) Roll-off 8000 nit) LT.sub.97 voltage (Relative ratio (Relative (Relative (V) value, %) (%) value, %) value, %) Comparative 5.2  75 28  55  7 Example 3  Example 11 3.8 144 10 184 479 Example 12 3.5 148  9 203 424 Example 13 3.5 141  9 199 386 Example 14 3.9 144  8 183 548 Example 15 3.8 142  8 184 545 Example 16 3.7 144  6 193 445

[0434] From Table 5, it can be seen that the organic light-emitting devices of Examples 11 to 16 have excellent characteristics in terms of driving voltage, luminescence efficiency, roll-off ratio, power efficiency and lifespan.

[0435] Light-emitting devices according to embodiments of the present disclosure have excellent characteristics in terms of driving voltage, luminescence efficiency, roll-off ratio, power efficiency and lifespan. Accordingly, high-quality electronic devices can be manufactured using the light-emitting devices.

[0436] It should be understood that embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each embodiment should typically be considered as available for other similar features or aspects in other embodiments. While one or more embodiments have been described with reference to the figures, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope as defined by the following claims.