SLIDING BEARING ELEMENT
20180017107 ยท 2018-01-18
Assignee
Inventors
Cpc classification
C22C30/00
CHEMISTRY; METALLURGY
F16C33/124
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C2204/34
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C17/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C33/125
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C43/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C33/127
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C33/121
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C17/022
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F16C33/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
The invention relates to a sliding bearing element (1) with a running layer (4) made from a first tin-based alloy and an additional layer (5) made from an additional tin-based alloy, said alloys containing at least one element from a group comprising Cu, Ni, Ag, Sb, As, Pb, Bi, Te, Tl and/or non-metal particles. The first tin-based alloy has a strength index FI of at least 5 and at most 25, and the additional tin-based alloy has a strength index FI of at least 0.3 and at most 3. The strength index of the running layer (4) is at least five times the strength index of the additional layer (5), and the strength index FI is defined by the equation,
in which C represents at least one of the elements Cu, Ni, Ag; S represents Sb and/or non-metal particles; B represents at least one of the elements Pb, Bi, Te, Tl; and represents the total content of each of the tin-based alloy components assigned to the letters C, S, and B.
Claims
1. A sliding bearing element (1), in particular a radial sliding bearing element, comprising in this sequence a support element, which in particular forms a support layer (3), at least one running layer (4), at least one additional layer (5), and possible at least one bearing metal layer (3a) between the support element and the at least one running layer (4), wherein the at least one running layer (4) is formed by at least one first tin-based alloy and the at least one additional layer (5) is formed by at least one additional tin-based alloy, wherein the first tin-based alloy and the additional tin-based alloy contain at least one element of a group comprising Cu, Ni, Ag, Sb, As, Pb, Bi, Te, Tl and/or non-metal particles, and the at least one first and the at least one additional tin-based alloy contain beta-tin grains (13), wherein the at least one first tin-based alloy has a strength index FI of at least 5 and at most 25 and the at least one additional tin-based alloy has a strength index FI of at least 0.3 and at most 3, the strength index of the running layer (4) is at least five times the strength index of the at least one additional layer (5) arranged directly on the running layer (4), and the strength index FI is defined by the equation,
2. The sliding bearing element (1) as claimed in claim 1, wherein the at least one additional layer (5) is arranged at least also on a sliding bearing element rear (8).
3. The sliding bearing element (1) as claimed in claim 1, wherein the at least one additional layer (5) at least in the region of a radial inner surface (17) has a layer thickness (15), which is selected from a range of at least 5*10.sup.6 of a bearing inner diameter (16) to 50*10.sup.6 of a bearing inner diameter (16), wherein the layer thickness (15) of the at least one additional layer (5) is at least 1.5 m and at most 15 m.
4. The sliding bearing element (1) as claimed in claim 3, wherein the layer thickness (17) of the at least one additional layer (5) in the region of the radial inner surface (17) is greater than twice the arithmetic roughness average value Ra DIN EN ISO 4287:2010 of said surface (17).
5. The sliding bearing element (1) as claimed in claim 3, wherein the layer thickness (15) of the at least one additional layer (5) in the region of the radial inner surface (17) is smaller than twice the average roughness depth Rz DIN EN ISO 4287:2010 of said surface (17).
6. The sliding bearing element (1) as claimed in claim 3, wherein a layer thickness (19) of the at least one additional layer (5) on the sliding bearing element rear (8) is between 0.1 times and 0.5 times the layer thickness (15) of the at least one additional layer (5) in the region of the radial inner surface (17).
7. The sliding bearing element (1) as claimed in claim 3, wherein the layer thickness (15) of the at least one additional layer (5) is 0.3 times to 5 times, in particular 1 times to 2 times, as large as the average height (18) of the dominant waviness profile WDc according to the measurement process of VDA 2007.
8. The sliding bearing element (1) as claimed in claim 3, wherein the preferred orientation of the beta-tin grains (13) in at least two adjoining layers of the at least one running layer (4) and/or the at least one additional layer (5) or in the at least one running layer (4) and the adjoining at least one additional layer (5) is mostly identical.
9. The sliding bearing element (1) as claimed in claim 1, wherein the tin-based alloy of the at least one running layer (4) contains between 0 wt. % and 40 wt. % antimony and/or between 0 wt. % and 25 wt. % copper.
10. The sliding bearing element (1) as claimed in claim 1, wherein the tin-based alloy of the at least on additional layer (5) contains between 0 wt. % and 3 wt. % copper and/or antimony and between 0.01 and 10 wt. % bismuth and/or lead.
11. The sliding bearing element (1) as claimed in claim 1, wherein the at least one further layer (5) has only one grain layer of beta-tin grains (13).
12. The sliding bearing element (1) as claimed in claim 1, wherein the beta-tin grains (13) in the at least one additional layer (5) have an average grain size of between 10% and 90% of the layer thickness (15) of the at least one additional layer (5).
13. The sliding bearing element (1) as claimed in claim 1, wherein the at least one additional layer (5) is deposited galvanically.
14. The sliding bearing element (1) as claimed in claim 1, wherein the at least one additional layer (5) is arranged directly on the at least one running layer (4).
Description
[0022] For a better understanding of the invention the latter is explained in more detail with reference to the following Figures.
[0023] In a simplified, schematic representation:
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031] First of all, it should be noted that in the variously described exemplary embodiments the same parts have been given the same reference numerals and the same component names, whereby the disclosures contained throughout the entire description can be applied to the same parts with the same reference numerals and same component names. Also details relating to position used in the description, such as e.g. top, bottom, side etc. relate to the currently described and represented figure and in case of a change in position should be adjusted to the new position.
[0032]
[0033] The term at least one with regard to the running layer 4 and the additional layer 5 means that it is possible for the running layer 4 to be formed from a plurality of individual running layers with different compositions and/or the additional layer 5 can be made up of several individual running layers with different compositions or can consist of said plurality of individual layers. However, it is also possible for the concentration of at least individual alloy elements in the running layer 4 and/or the further layer 5 to decrease or increase continually in the direction of the radial inner surface of the sliding bearing element 1. In all of these cases the composition of the running layer 4 and the additional layer 5 according to the following details on the general composition of the two layers according to table 1 is such that the latter show the average proportions of the individual alloy elements in the whole running layer 4 and the whole additional layer 5.
[0034] In addition it is possible that the running layer 4 is arranged directly on a support element, which forms in particular the supporting layer 3, so that a bearing metal layer 3a is not necessary. This direct coating is used for example in connecting rods. The at least one additional layer 5 is also arranged on the running layer 4 in this embodiment variant. If necessary, a bonding layer and/or a diffusion barrier layer can be arranged between the support element and the at least one running layer 4.
[0035] As indicated by dashed lines in
[0036] It is also possible that the at least one further layer 5 is arranged not only on a radial inner surface 7 of the at least one running layer 4, but that the at least one further layer 5 is also arranged on a sliding bearing element rear 8, as also indicated by dashed lines in in
[0037] The sliding bearing element 1 forms together with at least one further sliding bearing element a sliding bearingdepending on the structure also more than one additional sliding bearing element can be provided, as already known. Here preferably the sliding bearing element loaded more strongly during operation is formed by the sliding bearing element 1 according to the invention. However, it is also possible that at least one of the at least one additional sliding bearing elements is formed by the sliding bearing element 1 according to the invention.
[0038] The sliding bearing element 1 according to
[0039] In particular, the sliding bearing element 1 is provided for use in the motor industry or in engines according to the above explanations.
[0040] The supporting layer 3 is preferably made of steel, but can also be made of other suitable material such as e.g. bronze.
[0041] The bearing metal layer 3a is preferably made from a copper-based alloy or an aluminum-based alloy, as known from the prior art for these purposes. For example the bearing metal layer 3a can be made from an alloy with a copper base according to DIN ISO 4383, such as e.g. CuSn10, CuAl10Fe5Ni5, CuZn31Si, CuPb24Sn2, CuSn8Bi10, CuSn4Zn.
[0042] The at least one intermediate layer 6 consists of a material known for this purpose from the prior art.
[0043] The at least one running layer 4 consists of at least one first tin-based alloy. The at least one further layer 5 consists of at least one further tin-based alloy. Both the at least one first tin-based alloy and the at least one further tin-based alloy consists of a matrix made from beta-tin grains and one or more element(s) from a group comprising or consisting of Cu, Ni, Ag, Sb, Pb, Bi, Te, Tl. Furthermore, alternatively to this, at least one element or in addition non-metal particles can be contained in the at least one first tin-based alloy and/or the at least one additional tin-based alloy. The non-metal particles are in particular inorganic particles, for example Al.sub.2O.sub.3, Si.sub.3N.sub.4, TiO.sub.2, SiC, etc. Preferably, the inorganic particles have a maximum particle size of between 0.05 m and 5 m, in particular between 0.1 m and 2 m.
[0044] The maximum particle size is determined by means of laser diffraction according to the standard ISO 13320:2009.
[0045]
[0046] As explained above, reinforced surface coatings are used in a highly loaded radial sliding bearing. The usual finishing processes, such as fine boring or broaching, after the coating of the substrate by means of scoring effects cause the surface to become wavy in radial or axial direction. Said microwaves result in extremely high loads at the start of the operation with a reinforced surface coating. Due to the unevenness of the surface the shaft is mostly supported by the scored peaks, by means of an extremely thin oil film which may also peel off in some circumstances.
[0047] The left part of
[0048] The shafts are formed by the rotation of the fine bore spindle, a distance 11 is formed between the shaft tips of e.g. 0.1-0.2 mm by the forward feed per rotation.
[0049] The actual, random roughness overlayers the waviness, the bandwidth of which is often only a fraction of the profile heightin this case about a quarter, as shown in
[0050] On the right in
[0051] Due to the low plastic deformation and the wear of the top roughness peaks in this example at the beginning of the running-in of the sliding bearing element there is a load-bearing area of only about 20%.
[0052] The lubricant also transmits a portion of the forces into deeper lying profile areas, where this portion is low particularly when using thin lubricant oils.
[0053] It is thus expected that there will be approximately 2 to 5 times more localized loading on the surface. By means of the excellent wearing resistance of the reinforced coating the running-in phase, the period up to about 80% of the profile (and taking into account the lubricant thus about 100% of the surface) for supporting the shaft, will be delayed considerably.
[0054] The localized loading increased about 2 to 5 times can also outstrip the fatigue strength of reinforced layers and thus result in premature damage.
[0055] Not only small differences in the surface at a distance of about 0.1 mm can reduce the localized bearing area, but also differences in form of similar height at a distance of millimeters (on the edges) or centimeters (in wand thickness fluctuations of the running surface) can have an unfavorable effect on the bearing area.
[0056] In order to overcome these problems of highly loaded sliding bearing elements more effectively, the sliding bearing element 1 according to the invention comprises a combination of the at least one running layer 4 and the at least one additional layer 5, which is preferably arranged directly on the at least one running layer 4. For this
[0057] Here the at least one running layer 4 consists of the at least one first tin-based alloy, wherein the at least one first tin-based alloy has a strength index FI of at least 5 and at most 25, in particular at least 10 and at most 25. The at least one further layer 5 consists of the at least one additional tin-based alloy, wherein said tin-based alloy only has a strength index FI of at least 0.3 and at most 3, in particular at least 0.3 and at most 1.5.
[0058] With this combination of the two layers it is possible that the wear of the at least one additional layer 5 of several micrometers leads to a clear improvement in the bearing area and thus to a significant reduction of localized loads.
[0059] The strength index FI is defined by the equation
in which C represents at least one of the elements Cu, Ni, Ag; S represents Sb and/or non-metal particles; B represents at least one of the elements Pb, Bi, Te, Tl; and represents the total content of each of the tin-based alloy components assigned to the letters C, S, and B.
[0060] Below a strength index of 0.3 of the additional layer 5 it was not possible to observe any improvement in the tribological behavior of the sliding bearing element 1 compared to those with pure tin layers. The reason for this is probably that technical pure tin naturally has impurities. Tin today is usually obtainable with a purity of >99.95%. Individual impurities of lead, antimony and bismuth (the three main impurities) each in the region of about 0.005-0.01% are standard. When using galvanic production methods the elements antimony and bismuth are generally reduced further, as they dissolve from the anode only slightly into the electrolytes. Thus the deposited tin, which is used for example for the so-called tin flash, has an even lower content of impurities. A strength index of at least 0.3 can thus not be achieved with pure tin with the usual impurities.
[0061] Tin alloys which are not doped with lead, antimony or bismuth are not sufficiently protected from allotropic transformation in cool storage. The period up to the beginning of the transformation and the transformation speed can be delayed sufficiently by a total amount of lead, bismuth and antimony of 0.04%.
[0062] With a strength index of the additional layer 5 of more than 3 the adjustability of the additional layer 5 is reduced by the then already increased strength.
[0063] It is also possible to form a transitional area between the at least one running layer 4 and the at least one additional layer 5. For this reason in the description the terms at least one running layer 4 and at least one additional layer 5 are used, as in this way the running layer 4 and/or the additional layer 5 can be seen to be multilayered.
[0064] The transitional area between the running layer 4 and the further layer 5 can have a strength index FI of at least 3 and at most 5.
[0065] It is thus possible to design the layer system of a running layer 4 and additional layer 5 as a gradient layer with respect to the course of the au strength index in radial direction.
[0066] Preferably, the transitional area has a layer thickness which is not greater than the layer thickness 15 of the additional layer 5. The aforementioned values for the layer thickness 15 of the additional layer 5 therefore also apply to the transitional area.
[0067] Preferably, the running layer 4 also contains a total proportion of lead, bismuth and antimony of at least 0.04%.
[0068] With a strength index FI of the running layer 4 of less than 5 the latter has a wearing resistance which does not correspond with the desired property profile of the sliding bearing element 1. Furthermore, it ability to adapt and embed dirt (also in a run-in state) decreases significantly at a strength index of more than 25.
[0069] The at least one further layer 5 is preferably galvanically deposited. In addition the at least one running layer 4 is preferably galvanically deposited. As the galvanic deposition is known, reference is made to the relevant prior art, for example to AT 509 111 B1 or AT 509 867 B1 with the same applicant, which is incorporated into the present description in relation to the conditions of the galvanic deposition of the tin-based alloy(s).
[0070] Preferably, after the deposition of the at least one further layer 5 it is no longer necessary to finish the sliding bearing element 1 for example by fine boring.
[0071] If the at least one further layer 5 is also to be deposited on the sliding bearing element rear 8 on the other surfaces of the sliding bearing element 1, in particular in the form of a thin, visually appealing tin flash which protects from the formation of rust, the latter can be combined with the deposition of the at least one additional layer 5 on the radially inner side of the sliding bearing element 1. The layer thickness can thereby be reduced on the sliding bearing element rear 8, in that radially inward and radially outwards the current density and/or coating time is selected to differ accordingly.
[0072] The non-metal particles can be added to the respective galvanic bath as such and co-deposited with the tin.
[0073] The respective strength indices of the at least one running layer 4 and the at least one additional layer 5 are adjusted by the compositions of the respective layers. In general said layers can have the proportions of the individual components given in the following table 1, where tin made up the remainder to 100 wt. %. All of the details of proportions in table 1, and generally in the whole description are given in wt. % (provided that nothing else is described in particular).
TABLE-US-00001 TABLE 1 Proportions of the tin-based alloys Running Preferred range Preferred range layer 4 running layer 4 Layer 5 layer 5 Cu 0-25 7-13 or 2-5 (in 0-3 <1 particular when Sb is contained in the given proportion) Ni 0-25 0 (Impurities by 0-3 0 (Impurities by diffusion to 1) diffusion to 0.1) Ag 0-25 0-10 0-3 0 Sb 0-40 1.5-5 or 6-13 (in 0-6 <1 particular when Cu is contained in the given proportion) As 0-10 0-0.8 0-6 0-0.8 Pb In total 0-0.05 (max. 0.2) In total 0-0.05 (max. 0.2) Bi 0-0.5 0-0.5 Te 0-10 0 0-10 0 Tl 0 0 Non- 0-10 0 0-6 0 metallic particles
[0074] These details about the composition are such that the tin-based alloys of the running layer 4 and the further layer 5 in any case contain at least one of said alloy elements in table 1, as otherwise the desired strength indices of said layers are not achieved. Thus pure tin is excluded for the running layer 4 and pure tin for the additional layer 5.
[0075] According to preferred embodiment variants of the sliding bearing element 1 it is possible that the tin-based alloy of the at least one running layer 4 contains between 2 wt. % and 12 wt. % antimony and/or between 2 wt. % and 12 wt. % copper, and/or that the tin-based alloy of the at least one additional layer 5 contains between 0 wt. % and 0.5 wt. % copper or between 0 wt. % and 0.5 wt. % antimony or between 0 wt. % and 0.5 wt. % copper and antimony, and between 0.01 and 10 wt. % bismuth or between 0.01 and 2 wt. % lead or between 0.01 and 10 wt. % bismuth and lead.
[0076] According to a further preferred embodiment variant of the sliding bearing element 1 it is possible that the tin-based alloy of the at least one running layer 4 and/or the at least one additional layer 5 contain a total proportion of alloy elements given in the table 1, in particular the elements tin, antimony and bismuth, of at least 0.04 wt. %, in particular at least 0.3 wt. %, wherein the upper limit of the proportion of said elements in said layer or layers is defined by the above data.
[0077] The following tables show several comparison examples and embodiments of sliding bearing elements 1 according to the invention.
[0078] Different variants of the additional layer 5 on sliding bearing half shells (width 25 mm, diameter 80 mm) are specified and subjected to a dynamic sliding bearing test. The used sliding bearing shells had a disadvantageous surface quality (Ra=0.7 m, Rq=0.8 m, Rz=2.8 m, Rt=3 m).
[0079] Two tests were performed, one a test without tilting the running surface (variant 1), the second test with tilting the running surface by 0.5 m/mm (variant 2). This second test exerts an extreme load on an edge, as occurs with non-ideally aligned bores or e.g. a buckles connecting rod. The first test was evaluated for wear and microscopic findings, the second test by visual and microscopic assessment. The individual assessments were summarized by an overall assessment number 0-5 (0=very poor, 5=very good).
[0080] For a better comparison the structure of the layer of the sliding bearing element 1 including the running layer 4 was kept constant and only the additional layer 5 varied.
[0081] The thickness of the coating, unless otherwise indicated, was also kept constant at 20 m and comprises the thickness of the running layer 4 and in the examples according to the invention of the further layer 5.
[0082] In the composition column the numbers after the elements indicate the percentage of their mass (e.g. SnTe1 means tin with 1 wt. % tellurium). The abbreviation FI stands for the strength index. In the left column in the tables for the structure the number 5 stands for the additional layer 5 and the number 4 stands for the running layer 4. In the results tables in the left column the number 1 stands for variant 1 and the number 2 for variant 2. This nomenclature is used for tables relating to the examples throughout the description.
COMPARATIVE EXAMPLE 1
Structure
[0083]
TABLE-US-00002 Layer thickness Composition FI 5 1 m SnPb0.1 misc. elements <0.005% 0.4 4 19 m SnCu2Pb0.5 misc. elements <0.005% 3.4
Results
[0084]
TABLE-US-00003 Wear Visual and microscopic findings 1 22 m Total wear, runs into bearing metal 1 2 Total wear, runs into bearing metal 1
[0085] The additional layer 5 was shown to be too thin and the running layer 4 too soft.
COMPARATIVE EXAMPLE 2
Structure
[0086]
TABLE-US-00004 Layer thickness Composition FI 5 1.5 m Sn misc. elements <0.005% <0.3 4 18.5 m SnCu8Pb0.1 misc. elements <0.005% 8.6
Results
[0087]
TABLE-US-00005 wear Visual and microscopic findings 1 6 m Low wear, heavy fatigue fractures 3 2 Total wear on one side, heavy fatigue fractures 2
[0088] The additional layer 5 was shown to be too soft.
COMPARATIVE EXAMPLE 3
Structure
[0089]
TABLE-US-00006 Layer thickness Composition FI 5 0 m 4 20 m SnCu16Sb3Bi0.15 misc. elements <0.005% 18.3
Results
[0090]
TABLE-US-00007 Wear Visual and microscopic findings 1 4 m Very low wear, heavy fatigue fractures 3 2 Attrition 0
COMPARATIVE EXAMPLE 4
Structure
[0091]
TABLE-US-00008 Layer thickness Composition FI 5 2 m SnPb0.2Sb0.1 misc. elements <0.005% 0.5 4 18 m SnSb6Cu0.5Pb0.25 misc. elements <0.005% 4.5
Results
[0092]
TABLE-US-00009 Wear Visual and microscopic findings 1 10 m Significant wear, fatigue fractures 3 2 Total wear on one side, heavy fatigue fractures 2
[0093] With this layer structure the running layer 4 is too soft.
COMPARATIVE EXAMPLE 5
Structure
[0094]
TABLE-US-00010 Layer thickness Composition FI 5 0.5 m SnPb0.2Sb0.1 misc. elements <0.005% 0.5 4 19.5 m SnSb8Cu0.3Pb0.2 particles-ZrO.sub.2 d50 = 0.1 m. 5.7 1% misc elements <0.005%
Results
[0095]
TABLE-US-00011 wear Visual and microscopic findings 1 7 m Significant wear, fatigue fractures 3 2 Total wear on one side, heavy fatigue fractures 2
[0096] The additional layer 5 is too thin.
COMPARATIVE EXAMPLE 6
Structure
[0097]
TABLE-US-00012 Layer thickness Composition FI 5 1 m Sn misc. elements <0.005% <0.3 4 19 m SnAg5Cu1 misc. elements <0.005% 6
Results
[0098]
TABLE-US-00013 Wear Visual and microscopic findings 1 7 m Significant wear, fatigue fractures 3 2 Total wear on one side, heavy fatigue fractures 2
[0099] The additional layer 5 is too thin and too soft.
COMPARATIVE EXAMPLE 7
Structure
[0100]
TABLE-US-00014 Layer thickness Composition FI 5 1 m Sn misc. elements <0.005% <0.3 4 19 m SnNi8Te0.5 misc. elements <0.005% (Sputter) 9.4
Results
[0101]
TABLE-US-00015 Wear Visual and microscopic findings 1 8 m Significant wear, fatigue fractures 3 2 Total wear on one side, heavy fatigue fractures 2
[0102] The additional layer 5 is too soft.
COMPARATIVE EXAMPLE 8
Structure
[0103]
TABLE-US-00016 Layer thickness Composition FI 5 1 m SnSb1Cu1 misc. elements <0.005% 1.5 4 19 m SnSb15Cu5 misc. elements <0.005% 12.5
Results
[0104]
TABLE-US-00017 Wear Visual and microscopic findings 1 4 m Very low wear, heavy fatigue fractures 3 2 Attrition 0
[0105] The additional layer 5 is too thin.
COMPARATIVE EXAMPLE 9 (SIMILAR TO GB 2 375 801 A, PAGE 9, EXAMPLES 3 AND 4)
Structure
[0106]
TABLE-US-00018 Layer thickness Composition FI 5 18 m SnCu4Sb0.6 misc. elements <0.005% 4.3 4 2 m SnCu15Sb2 misc. elements <0.005% 16
Results
[0107]
TABLE-US-00019 Wear Visual and microscopic findings 1 15 m Heavy wear, fatigue fractures 2 2 Total wear, runs into bearing metal 1
[0108] The additional layer 5 is too thick.
EXAMPLE OF THE INVENTION 1
Structure
[0109]
TABLE-US-00020 Layer thickness Composition FI 5 3 m SnPb0.1 misc. elements <0.005% 0.6 4 17 m SnCu8Pb0.1 misc. elements <0.005% 8.6
Results
[0110]
TABLE-US-00021 wear Visual and microscopic findings 1 7 m Significant wear, light fatigue fractures 4 2 Heavy wear on one side, heavy fatigue fractures 2
[0111] There was an improvement in the bearing capacity of the sliding bearing element 1 compare to comparative example 2.
EXAMPLE OF THE INVENTION 2
Structure
[0112]
TABLE-US-00022 Layer thickness Composition FI 5 4 m SnCu2Sb0.5Bi0.1 2.9 4 16 m SnCu16Sb3Bi0.15 misc. elements <0.005% 18.3
Results
[0113]
TABLE-US-00023 Wear Visual and microscopic findings 1 7 m Significant wear, light fatigue fractures 4 2 Wear on one side, fatigue fractures 3
[0114] In this example there is also an improvement in the bearing capacity of the sliding bearing element when compared to comparative example 3.
EXAMPLE OF THE INVENTION 3
Structure
[0115]
TABLE-US-00024 Layer thickness Composition FI 5 2 m SnPb0.2Sb0.1 misc. elements <0.005% 0.5 4 18 m SnSb9Cu1Pb0.25 misc. elements <0.005% 6.5
Results
[0116]
TABLE-US-00025 Wear Visual and microscopic findings 1 7 m Significant wear, fatigue fractures 3 2 Wear on one side, fatigue fractures 3
[0117] Here there was an improvement with respect to both variations of the test compared with comparative example 4.
EXAMPLE OF THE INVENTION 4
Structure
[0118]
TABLE-US-00026 Layer thickness Composition FI 5 3 m SnAg1 misc. elements <0.005% 1 4 17 m SnAg8Cu1 misc. elements <0.005% 6
Results
[0119]
TABLE-US-00027 Wear Visual and microscopic findings 1 6 m Significant wear, light fatigue fractures 4 2 Wear on one side, fatigue fractures 3
[0120] Here there was an improvement with respect to the load bearing ability of the sliding bearing element 1 compared with comparative example 6.
EXAMPLE OF THE INVENTION 5
Structure
[0121]
TABLE-US-00028 Layer thickness Composition FI 5 3 m SnCu1 misc. elements <0.005% 1 4 17 m SnNi8Te0.5 misc. elements <0.005% (Sputter) 9.4
Results
[0122]
TABLE-US-00029 Wear Visual and microscopic findings 1 8 m Significant wear, light fatigue fractures 4 2 Total wear on one side, heavy fatigue fractures 2
[0123] There was an improvement in terms of the fatigue fracture compared to comparative example 7.
EXAMPLE OF THE INVENTION 6
Structure
[0124]
TABLE-US-00030 Layer thickness Composition FI 5 5 m SnSb1Cu1 misc. elements <0.005% 1.5 4 15 m SnSb15Cu5 misc. elements <0.005% 12.5
Results
[0125]
TABLE-US-00031 Wear Visual and microscopic findings 1 7 m Significant wear, no fatigue fractures 4 2 Wear on one side, light fatigue fractures 4
[0126] Compared with comparative example 8 the wear is greater in a direction normal to the sliding surface, however an improvement was achieved with regard to the test variant 2.
EXAMPLE OF INVENTION 7
Structure
[0127]
TABLE-US-00032 Layer thickness Composition FI 5 3 m SnCu2Sb0.6 misc. elements <0.005% 2.3 4 17 m SnCu15Sb2 misc. elements <0.005% 16
Results
[0128]
TABLE-US-00033 Wear Visual and microscopic findings 1 5 m Low wear, no fatigue fractures 5 2 Wear on one side, light fatigue fractures 4
[0129] Compared with comparative example 9 there was an improvement with regard to a non-tilted and also with regard to a tilted bearing.
EXAMPLE OF THE INVENTION 8
Structure
[0130]
TABLE-US-00034 Layer thickness Composition FI 5 3 m SnCu2Sb0.6Pb0.05 misc. elements <0.005% 2.7 4 17 m SnCu18Sb8Pb1 misc. elements <0.005% 24
Results
[0131]
TABLE-US-00035 Wear Visual and microscopic findings 1 5 m Low wear, no fatigue fractures 5 2 Attrition 0
[0132] As shown by the results, this embodiment variant is not very suitable for tilted bearings.
EXAMPLE OF THE INVENTION 9
Structure
[0133]
TABLE-US-00036 Layer thickness Composition FI 5 5 m SnCu1Sb0.6Pb0.05 misc. elements <0.005% 1.7 4 15 m SnSb26Pb1 misc. elements <0.005% 15
Results
[0134]
TABLE-US-00037 Wear Visual and microscopic findings 1 8 m Significant wear, light fatigue fractures 4 2 Total wear on one side, heavy fatigue fractures 2
High Sb
[0135] The results are similar to the preceding example 9, wherein here there is an improvement with regard to the tilted bearings.
EXAMPLE OF THE INVENTION 10
Structure
[0136]
TABLE-US-00038 Layer thickness Composition FI 5 6 m SnCu2Bi0.5 misc. elements <0.005% 2.4 4 14 m SnCu23Bi1 misc. elements <0.005% 25
Results
[0137]
TABLE-US-00039 Wear Visual and microscopic findings 1 10 m Significant wear, light fatigue fractures 4 2 Total wear on one side, heavy fatigue fractures 2
[0138] Said sliding bearing element 1 shows a similar bearing capacity to example 10.
EXAMPLE OF THE INVENTION 11
Structure
[0139]
TABLE-US-00040 Layer thickness Composition FI 5 8 m SnCu1Sb0.5 misc. elements <0.005% 1.25 4 12 m SnCu7Sb7Bi0.1Pb0.1 misc. elements <0.005% 11.4
Results
[0140]
TABLE-US-00041 Wear Visual and microscopic findings 1 10 m Significant wear, light fatigue fractures 4 2 Wear on one side, fatigue fractures 3
[0141] By means of the very high thickness of the additional layer 5 relative to the running layer 4 the wear increased with respect to loading normal to the sliding surface.
EXAMPLE OF THE INVENTION 12
Structure
[0142]
TABLE-US-00042 Layer thickness Composition FI 5 2.5 m SnPb0.01Bi0.02 misc. elements <0.005% 0.35 4 18 m SnCu9Sb5Bi0.2Pb0.1 misc. elements <0.005% 12.6
Results
[0143]
TABLE-US-00043 Wear Visual and microscopic findings 1 6 m Low wear, light fatigue fractures 5 2 Wear on one side, light fatigue fractures 4
[0144] This structure according to example 12 shows good results with respect to both test variants so that it can be applied both in non-tilted and in tilted bearings.
EXAMPLE OF THE INVENTION 13
Structure
[0145]
TABLE-US-00044 Thickness Composition Index 1 3 m SnBi2 misc. elements <0.005% 2.8 2 17 m SnCu8Bi8 misc. elements <0.005% 13.7
Results
[0146]
TABLE-US-00045 Wear Visual and microscopic findings 1 5 m Low wear, no fatigue fractures 5 2 Wear on one side, fatigue fractures 3
[0147] Furthermore, also two tests were carried out by the directly coated boring of a connecting rod, wherein in both cases the final bore internal diameter as in the test bearings had a significantly higher layer thickness of 40 m.
[0148] In these tests the coatings were applied directly onto the steel provided with a thin, adhesive intermediate layer.
COMPARATIVE EXAMPLE 10
Structure
[0149]
TABLE-US-00046 Layer thickness Composition FI 5 4 40 m SnSb15Cu5 misc. elements <0.005% 12.5
Results
[0150]
TABLE-US-00047 Wear Visual and microscopic findings 2 Attrition 0
EXAMPLE OF THE INVENTION 14
Structure
[0151]
TABLE-US-00048 Layer thickness Composition FI 5 5 m SnSb1Cu1 misc. elements <0.005% 1.5 4 35 m SnSb15Cu5 misc. elements <0.005% 12.5
Results
[0152]
TABLE-US-00049 Wear Visual and microscopic findings 1 10 m Significant wear, fatigue fractures 3
COMPARATIVE EXAMPLE 11
Structure
[0153]
TABLE-US-00050 Layer thickness Composition FI 5 1 Sn misc. elements <0.005% <0.3 4 39 m SnCu15Sb5 misc. elements <0.005% 17.5
Results
[0154]
TABLE-US-00051 Wear Visual and microscopic findings 1 Attrition 0
EXAMPLE OF THE INVENTION 15
Structure
[0155]
TABLE-US-00052 Layer thickness Composition FI 5 10 m SnSb2Cu2 misc. elements <0.005% 3.0 4 30 m SnCu15Sb5 misc. elements <0.005% 17.5
Results
[0156]
TABLE-US-00053 Wear Visual and microscopic findings 1 15 m Significant wear, light fatigue fractures 4
[0157] As already mentioned, the running layer 4 can consist of several part layers having different compositions. It is possible in this way that the strength index of said part layers is greater in the direction of the sliding bearing element rear 8. The same applies to the at least one additional layer 5. Compositions of the individual part layers can be selected according to the examples given in table 2 or generally from the values given in table 1 for the proportions of the individual components of the tin-based alloys.
[0158] For example, in the following the production of a running layer 4 and a further layer 5 of a plurality of part layers is described. With regard to the possible additives to the produced electrolytes reference is made to AT 509 112 B1, which is referred to in particular here.
EXAMPLE OF THE INVENTION 16
[0159] Electrolyte for depositing the running layer 4:
Sn . . . 50 g/L (as tin (II)tetrafluoroborate)
[0160] Sb . . . 7 g/L (as antimony trifluoride)
Cu . . . 7 g/L (as copper tetrafluoroborate)
Bath temperature 40 C.
TABLE-US-00054 Current density Duration Thickness Composition FI Partial 1 A/dm.sup.2 10 min 4.5 m SnSb15Cu15, 22.5 layer 1 misc. <0.005% Partial 2 A/dm.sup.2 5 min 4.5 m SnSb10Cu10, 15.0 layer 2 misc. <0.005% Partial 4 A/dm.sup.2 3 min 5 m SnSb6Cu7, 10.0 layer 3 misc. <0.005% Partial 6 A/dm.sup.2 1.5 min 4.5 m SnSb4Cu5, 7.0 layer 4 misc. <0.005%
[0161] Electrolyte for deposition of the additional layer 5
Sn . . . 40 g/L (as tin (II)tetrafluoroborate)
[0162] Sb . . . 0.5 g/L (as antimonytrifluoride)
Cu . . . 0.2 g/L (as copper tetrafluoroborate)
Bath temperature 25 C.
TABLE-US-00055 Current density Duration Thickness composition FI Partial 1 A/dm.sup.2 3 min 1.5 m SnSb2Cu0.5, 1.5 layer 1 misc. <0.005% Partial 2 A/dm.sup.2 2 min 2 m SnSb1Cu0.2 0.7 layer 2 misc. <0.005%
EXAMPLE OF THE INVENTION 17
[0163] Electrolyte for deposition of the running layer 4
Sn . . . 50 g/L (as tin (II)methanesulfonate)
[0164] Cu . . . 7 g/L (as copper tetrafluoroborate)
Bi . . . 5 g/L (as bismuthhmethanesulfonate)
T40 C.
[0165]
TABLE-US-00056 current density duration Thickness composition FI Partial 1 A/dm.sup.2 10 min 4.5 m SnCu10Bi7, misc. 15.3 layer 1 <0.005% Partial 2 A/dm.sup.2 5 min 4.5 m SnCu8Bi5, misc. 12.5 layer 2 <0.005% Partial 4 A/dm.sup.2 3 min 5 m SnCu6Bi4, misc. 10.0 layer 3 <0.005%
[0166] Electrolyte for the deposition of the further layer 5
Sn . . . 20 g/L (as tin (II)methanesulfonate)
[0167] Bi . . . 1 g/L (as bismuthhmethanesulfonate)
Cu . . . 0.5 g/L (as copper tetrafluoroborate)
Bath temperature 40 C.
TABLE-US-00057 Current density Duration Thickness Composition FI Partial 1 A/dm.sup.2 3 min 1.5 m SnBi1.5Cu0.4 misc. 2.8 layer 1 <0.005% Partial 2 A/dm.sup.2 2 min 2 m SnBi0.5Cu0.2 misc. 1.6 layer 2 <0.005%
[0168] In the following further embodiment variants of the sliding bearing element 1 are described.
[0169] As shown in
[0170] Preferably, the beta-tin grains 13 in the at least one additional layer 5, for the aforementioned reasons, can have an average grain size of between 10% and 90% of a layer thickness 15 (
[0171] The average grain size is determined by laser diffraction, as described above.
[0172] It is also preferable if the preferred orientation of the beta-tin grains 13 in at least two adjoining layers of the at least one running layer 4 and/or the at least one additional layer 5 is identical. In particular, the beta-tin grains 13 of the running layer 4 and the additional layer 5 arranged thereon and connected to the latter have the same preferred orientation. It is particularly preferable here if the X-ray diffraction intensity of the additional layer 5 with the highest orientation index is also the X-ray diffraction intensity with the highest orientation index of the running layer 4 or one of the three X-ray diffraction intensities of the running layer 4 with the highest orientation index, or if in particular also the X-ray diffraction intensities with the second and/or third-highest orientation index of the additional layer 5 is or are the X-ray diffraction intensities with the second and/or third highest orientation index of the running layer 4. X-ray diffraction intensities with an index of below 1.5, in particular below 2, are here ignored as being not sufficiently oriented.
[0173] Preferably the beta-tin grains 13 are oriented according to {220} and/or {321} (Miller indices).
[0174] For a quantitative description of the preferred orientation the orientation index M{hkl} with the following formula is used:
wherein I{hkl} represents the XRD intensities (X-ray diffraction intensities) for the {hkl} levels of the sliding layer and I.sup.0 {hkl} represents the XRD intensities of the completely unorientated tin powder sample (ICDD PDF 00-004-0673).
[0175] The sum of the diffraction intensities I{hkl} or I.sup.0{hkl} needs to be over the same range, for example comprise all of the intensities of the reflexes from {200} to {431}, which when using CuK, radiation corresponds to all reflexes with a diffraction angle 2 between 30 and 90.
[0176] In the following table the X-ray diffraction intensities (lines 3 to 5) and the associated orientation indices (lines 6 to 8) are shown of a SnCu10Sb5 running layer 4 with a proportion of further alloy elements of less than 0.005 wt. % and a strength index FI of 12.5 (abbreviation QZ2), of a SnCu10Sb5 running layer 4 with a proportion of further alloy elements of less than 0.005 wt. % and a strength index FI of 12.5 with a SnCu1Bi0.02 alloy as an additional layer 5 arranged thereon, which had a proportion of further alloy elements of less than 0.005 wt. % and a strength index FI of 1.3 (abbreviation QZ4) and a SnCu6Pb1 running layer according to the prior art (abbreviation Ref. 1). The abbreviation Sn-Ref. stands for the completely unoriented tin powder (ICDD PDF 00-004-0673).
TABLE-US-00058 TABLE X-ray diffraction intensities and orientation indices HKL 200 101 220 211 301 112 400 321 420 411 312 431 Total Sn-Ref 100 90 34 74 17 23 13 20 15 14 20 13 433 QZ2 100 43.5 63.5 55.3 12.4 9.4 9.3 20.2 13.9 9.4 10.2 7.6 354.7 QZ4 18.5 13.4 100 79.1 8.9 3.2 3.7 35 16.1 9 7.4 12 306.3 Ref 1 100 60 32.2 64 22 11 9.5 21 10.3 11 12.7 5.8 339.2 I-QZ2 1.22 0.59 2.28 0.91 0.89 0.50 0.87 1.23 1.13 0.82 0.62 0.71 I-QZ4 0.26 0.21 4.16 1.51 0.74 0.20 0.40 2.47 1.52 0.91 0.52 1.30 Ref 1 1.28 0.85 1.21 1.10 0.17 0.61 0.93 1.34 0.88 0.96 0.81 0.57
[0177] For the test results given in the following the orientation of QZ02 is referred to as alignment a, the orientation of QZ04 as alignment b and the orientation of Ref. 1 as alignment c.
EXAMPLE OF THE INVENTION 18
Structure
[0178]
TABLE-US-00059 Thickness Composition Index 4 3 m SnCu1Bi0.02 <0.005% (alignment b) 2.8 5 17 m SnCu10Bi5 misc. elements 13.7 <0.005% (alignment a)
Results
[0179]
TABLE-US-00060 Wear Visual and microscopic findings 1 5 m Low wear, no fatigue fractures 5 2 Wear on one side, light fatigue fractures 4
COMPARATIVE EXAMPLE
Structure
[0180]
TABLE-US-00061 Thickness Composition Index 4 3 m SnCu1Bi0.02 <0.005% (alignment c) 2.8 5 17 m SnCu10Bi5 misc. elements 13.7 <0.005% (alignment a)
Results
[0181]
TABLE-US-00062 Wear Visual and microscopic findings 1 7 m Significant wear, light fatigue fractures 4 2 Wear on one side, fatigue fractures 3
[0182] Here the beta-tin grains 13, as shown in
[0183] For the same reasons it can also be an advantage if the beta-tin grains 13 have at least approximately dice-shaped form.
[0184] It was established in tests on different additional layers 5 that with a grain size of the beta-tin grains 13 of less than 0.2 m very high internal tensions occur in the additional layer 5. With a grain size of more than 10 m a surface is formed which prevents the even hold of the lubricant oil and thus the preferred formation of the lubricating gap.
[0185] According to a further embodiment variant of the sliding bearing element 1 it is possible that the average grain size, in particular the grain size, of the beta-tin grains 13 in the at least one additional layer 4 is greater than the average grain size, in particular the grain size, of the beta-tin grains 13 in the running layer 4. This can be achieved for example by changing the precipitation parameters during the galvanic deposition, in that for example the bath temperature is increased and/or the precipitation speed and/or the tin concentration in the galvanic bath are reduced. It is also possible to perform a subsequent temperature treatment on the sliding bearing element 1 for this purpose.
[0186] Preferably, the beta-tin grains 13 of the at least one additional layer 5 are grown directly on the beta-tin grains 13 of the running layer 5.
[0187] It is also preferable if the at least one further layer 5, at least in the region of the radial inner surface 7 (
[0188] The radial inner additional layer 5 can have a layer thickness 15, which is between 10% and 50%, in particular between 15% and 30%, of the total layer thickness formed by the layer thickness of the running layer 4 and the further layer 5.
[0189] It is also preferable if the layer thickness of the running layer 4 is greater than the layer thickness of the further layer 5, in particular greater than three time the layer thickness of the additional layer 5.
[0190] The bearing inner diameter 16 is the diameter of the sliding bearing element 1 on its radial innermost surface, as shown in
[0191] As shown by the test results of the above examples of the invention, with a layer thickness of less than 1.5 m the aforementioned effect of the at least one additional layer 5 is relatively weak so that the support element of the sliding bearing element 1 cannot be increased to the desired extent. In this way localized overloading of the sliding surface can only be avoided insufficiently. Furthermore, with a layer thickness 15 of the additional layer 5 of more than 15 m said additional layer 5 is so thick that the running-in phase is extended again, as more time is required for the partial abrasion of the additional layer 5. In addition, with a layer thickness 15 of more than 15 m the underlying higher strength running layer 4 of the at least one additional layer 5 can only provide insufficient support.
[0192] To give greater consideration to the surface topography of the at least one running layer 4 it is possible that the layer thickness 15 of the at least one additional layer 5 in the region of a radial inner surface 17 (
[0193] According to another embodiment variant it is possible that the layer thickness 15 (
[0194] In order to investigate the interaction of the surface roughness with the thickness of the at least one additional layer 5 tests were carried out as described above (variant 1 without tilting). The bearing shells had roughnesses in the range of Ra 0.3-0.7 m and Rz 2-5. In addition in two thirds of the bearing shells a dominant waviness was discovered with WDc 0.5-2.5 m.
[0195] The bearing shells were coated according to the example 11 of the invention, wherein the layer thickness 15 of the at least one additional layer 5 was varied between 0.1 and 12 m.
[0196]
[0197] It is evident from
[0198] Furthermore, it is possible that a layer thickness 19 (
[0199] With back layer thicknesses of 5 m or more there is an increased risk of material displacement during operation, which can lead to the deformation of the bore and worsening of the rear bearing.
[0200] The range of 0.1-0.5 times the layer thickness 15 of the radial inner additional layer 5 has the advantage in a galvanic production process that by means of a moderate shortening (e.g. by a factor of 2-3) of the duration of the coating on the rear and/or a reduction of the current density a layer thickness 19 can be produced which provides sufficient protection from corrosion, but does not increase the risk of material displacement.
[0201] Reducing the current density too much can result in too great a change to the composition of the deposition and thus lead to reduced corrosion protection.
[0202] The example embodiments show possible embodiment variants of the sliding bearing element 1, whereby it should be noted at this point that various different combinations of the individual embodiment variants are also possible.
[0203] Finally, as a point of formality, it should be noted that for a better understanding of the structure of the sliding bearing element 1, the latter and its components have not been represented true to scale in part and/or have been enlarged and/or reduced in size.
LIST OF REFERENCE NUMERALS
[0204] 1 sliding bearing element [0205] 2 sliding bearing element body [0206] 3 supporting layer [0207] 3a bearing metal layer [0208] 4 running layer [0209] 5 layer [0210] 6 intermediate layer [0211] 7 surface [0212] 8 sliding bearing element rear [0213] 9 end face [0214] 10 end face [0215] 11 distance [0216] 12 grain layer [0217] 13 beta-tin grain [0218] 14 phase [0219] 15 layer thickness [0220] 16 bearing inner diameter [0221] 17 surface [0222] 18 height [0223] 19 layer thickness