DETECTOR FOR AN OPTICAL DETECTION OF AT LEAST ONE OBJECT
20180017679 ยท 2018-01-18
Assignee
Inventors
- Sebastian VALOUCH (Lampertheim, DE)
- Ingmar BRUDER (Neuleiningen, DE)
- Robert Send (Karlsruhe, DE)
- Christoph LUNGENSCHMIED (Mannheim, DE)
- Wilfried HERMES (Karlruhe, DE)
- Erwin THIEL (Siegen, DE)
- Stephan IRLE (Siegen, DE)
Cpc classification
H01L31/09
ELECTRICITY
A63F13/213
HUMAN NECESSITIES
H10K39/00
ELECTRICITY
H10K30/30
ELECTRICITY
G01S17/66
PHYSICS
A63F13/30
HUMAN NECESSITIES
H10K85/113
ELECTRICITY
Y02E10/549
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
G01S17/66
PHYSICS
A63F13/213
HUMAN NECESSITIES
G01S7/481
PHYSICS
H01L31/09
ELECTRICITY
A63F13/30
HUMAN NECESSITIES
Abstract
Disclosed herein is a detector (110) containing: at least one longitudinal optical sensor (114), wherein the longitudinal optical sensor (114); and at least one evaluation device (140), wherein the evaluation device (140) is designed to generate at least one item of information on a longitudinal position of the object (112) by evaluating the longitudinal sensor signal of the longitudinal optical sensor (114). Also disclosed herein are articles containing the detector (110), and methods for optical detection of objects using the detector (110).
Claims
1. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region, wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the sensor region comprises at least one photoconductive material, wherein an electrical conductivity of the photoconductive material, given the same total power of the illumination, is dependent on the beam cross-section of the light beam in the sensor region, wherein the longitudinal sensor signal is dependent on the electrical conductivity; and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
2. The detector according to claim 1, wherein the photoconductive material is an inorganic photoconductive material.
3. The detector according to claim 2, wherein the chalcogenide is selected from the group consisting of: a sulfide chalcogenide, a selenide chalcogenide, a telluride chalcogenide, a ternary chalcogenide, a quaternary chalcogenide, a higher chalcogenide, and a solid solution and/or a doped variant thereof.
4. The detector according to claim 3, wherein the chalcogenide is selected from the group consisting of: lead sulfide (PbS), copper indium sulfide (CIS), copper indium gallium selenide (CIGS), copper zinc tin sulfide (CZTS), lead selenide (PbSe), copper zinc tin selenide (CZTSe), cadmium telluride (CdTe), mercury cadmium telluride (HgCdTe), mercury zinc telluride (HgZnTe), lead sulfoselenide (PbSSe), copper-zinc-tin sulfur-selenium chalcogenide (CZTSSe), and a solid solution and/or a doped variant thereof.
5. The detector according to claim 1, wherein the pnictogenide is selected from the group consisting of: nitride pnictogenides, phosphide pnictogenides, arsenide pnictogenides, antimonide pnictogenides, ternary pnictogenides, quarternary, and higher pnictogenides.
6. The detector according to claim 5, wherein the pnictogenide is selected from the group consisting of indium nitride (InN), gallium nitride (GaN), indium gallium nitride (InGaN), indium phosphide (InP), gallium phosphide (GaP), indium gallium phosphide (InGaP), indium arsenide (InAs), gallium arsenide (GaAs), indium gallium arsenide (InGaAs), indium antimonide (InSb), gallium antimonide (GaSb), indium gallium antimonide (InGaSb), indium gallium phosphide (InGaP), gallium arsenide phosphide (GaAsP), and aluminum gallium phosphide (AlGaP).
7. The detector according to claim 1, wherein the photoconductive material comprises doped silicon.
8. The detector according to claim 1, wherein the photoconductive material is provided as a colloidal film, wherein the colloidal film comprises quantum dots.
9. The detector according to claim 1, wherein the photoconductive material is an organic photoconductive material, wherein the organic photoconductive material comprises at least one conjugated aromatic molecule, in particular a dye or a pigment, and/or a mixture comprising an electron donor material and an electron acceptor material.
10. The detector according to claim 9, wherein the organic photoconductive material comprises a compound selected from the group consisting of: phthalocyanines, naphthalocyanines, subphthalocyanines, perylenes, anthracenes, pyrenes , oligo- and polythiophenes, fullerenes, indigoid dyes, bis-azo pigments, squarylium dyes, thiapyrilium dyes, azulenium dyes, dithioketo-pyrrolopyrroles, quinacridones, dibromoanthanthrone, polyvinylcarbazole, derivatives and combinations thereof.
11. The detector according to claim 9, wherein the electron donor material comprises an organic donor polymer.
12. The detector according to claim 9, wherein the electron acceptor material comprises a fullerene-based electron acceptor material.
13. The detector according to claim 9, wherein the electron acceptor material comprises an organic acceptor polymer.
14. The detector according to claim 1, wherein the optical detector is adapted to generate the longitudinal sensor signal by one or more of measuring an electrical resistance or a conductivity of at least one part of the sensor region.
15. The detector according to claim 14, wherein a bias voltage is applied across the material.
16. The detector according to claim 15, wherein a bias voltage source and a load resistor are arranged in series with the longitudinal optical sensor.
17. The detector according to claim 1, wherein the electrical conductivity of the sensor region, given the same total power of the illumination, decreases with decreasing beam width of a light spot generated by the light beam in the sensor region.
18. The detector according to claim 1, wherein the longitudinal optical sensor comprises at least one layer of the photoconductive material and at least two electrodes contacting the layer, wherein the at least two electrodes are applied at different locations of the layer of the photoconductive material.
19. The detector according to claim 18, wherein the at least two electrodes are applied to the same side of the layer.
20. The detector according to claim 18, wherein a Schottky barrier is formed at a boundary between the layer of the photoconductive material and at least one of the electrodes contacting the layer.
21. The detector according to claim 18, wherein the at least one layer of the photoconductive material is directly or indirectly applied to at least one substrate.
22. The detector according to claim 21, wherein the substrate is an insulating substrate.
23. The detector according to claim 21, wherein the substrate is at least partially transparent or translucent.
24. The detector according to claim 1, wherein the at least one longitudinal optical sensor comprises at least one transparent longitudinal optical sensor.
25. The detector according to claim 1, wherein the detector comprises at least one stack of at least two longitudinal optical sensors.
26. The detector according to claim 1, wherein the detector comprises at least one array of at least two longitudinal optical sensors, wherein the array is arranged perpendicular to the optical axis.
27. The detector according to claim 26, wherein the longitudinal optical sensors in the array are arranged as a matrix of individual resistors, wherein an aggregate resistance of the individual resistors in the matrix depends on a number N of the longitudinal optical sensors within the array which are illuminated by the incident light beam, wherein the evaluation device is adapted to determine a number N of the longitudinal optical sensors which are illuminated by the light beam, the evaluation device further being adapted to determine at least one longitudinal coordinate of the object by using the number N of the longitudinal optical sensors which are illuminated by the light beam.
28. The detector according to claim 1, wherein the longitudinal optical sensor is furthermore designed in such a manner that the illumination of the sensor region by the light beam additionally causes an increase in temperature of the sensor region, wherein the electrical conductivity in the sensor region, given the same total power of the illumination, is further dependent on the temperature of the sensor region, wherein the longitudinal sensor signal, given the same total power of the illumination, is further dependent on the temperature in the sensor region.
29. The detector according to claim 1, wherein the evaluation device is designed to generate the at least one item of information on the longitudinal position of the object from at least one predefined relationship between the geometry of the illumination and a relative positioning of the object with respect to the detector.
30. The detector according to claim 29, wherein the evaluation device is adapted to generate the at least one item of information on the longitudinal position of the object by determining a beam cross-section of the light beam from the longitudinal sensor signal.
31. The detector according to claim 30, wherein the evaluation device is adapted to compare the beam cross-section of the light beam with known beam properties of the light beam in order to determine the at least one item of information on the longitudinal position of the object.
32. The detector according to claim 1, wherein the light beam is a non-modulated continuous-wave light beam.
33. The detector according to claim 1, further comprising: at least one transversal optical sensor, the transversal optical sensor being adapted to determine a transversal position of the light beam traveling from the object to the detector, the transversal position being a position in at least one dimension perpendicular an optical axis of the detector, the transversal optical sensor being adapted to generate at least one transversal sensor signal, wherein the evaluation device is further designed to generate at least one item of information on a transversal position of the object by evaluating the transversal sensor signal.
34. The detector according to claim 33, wherein the transversal optical sensor is a photo detector having at least one first electrode, at least one second electrode and at least one layer of a photoconductive material embedded in between two separate layers of a transparent conductive oxide, wherein the transversal optical sensor has a sensor area, wherein the first electrode and the second electrode are applied to different locations of one of the layers of the transparent conductive oxide, wherein the at least one transversal sensor signal indicates a position of the light beam in the sensor area.
35. The detector according to claim 34, wherein at least one electrode is a split electrode having at least two partial electrodes, wherein electrical currents through the partial electrodes are dependent on a position of the light beam in the sensor area, wherein the transversal optical sensor is adapted to generate the transversal sensor signal in accordance with the electrical currents through the partial electrodes.
36. The detector according to claim 35, wherein the detector is adapted to derive the information on the transversal position of the object from at least one ratio of the currents through the partial electrodes.
37. The detector according to claim 33, wherein the at least one transversal optical sensor comprises at least one transparent transversal optical sensor.
38. The detector according to claim 1, furthermore comprising at least one illumination source.
39. The detector according to claim 1, wherein the detector further comprises at least one imaging device.
40. The detector according to claim 39, wherein the imaging device comprises a camera.
41. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the sensor region comprises at least one material capable of sustaining an electrical current, wherein at least one property of the material, given the same total power of the illumination, is dependent on the beam cross-section of the light beam in the sensor region, wherein the longitudinal sensor signal is dependent on the at least one property: and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
42. The detector according to claim 41, wherein the material capable of sustaining the electrical current is one of the group consisting of: amorphous silicon (a-Si), an alloy comprising amorphous silicon (a-Si), microcrystalline silicon (e-Si), germanium (Ge), cadmium telluride (CdTe), mercury cadmium telluride (HgCdTe), indium arsenide (InAs), indium gallium arsenide (InGaAs), indium antimonide (InSb), copper indium sulfide (CIS), copper indium gallium selenide (CIGS), copper zinc tin sulfide (CZTS), copper zinc tin selenide (CZTSe), copper-zinc-tin sulfur-selenium chalcogenide (CZTSSe), and solid solutions and/or doped variants thereof; wherein the property comprises an electrical conductivity of the material capable of sustaining the electrical current.
43. The detector according to claim 41, wherein the longitudinal optical sensor is a photo detector having at least one first electrode, at least one second electrode, and a layer of the material capable of sustaining an electrical current located between the first electrode and the second electrode, wherein at least one of the first electrode and the second electrode is a transparent electrode.
44. The detector according to claim 41, wherein the material capable of sustaining the electrical current is located between the first electrode and the second electrode is arranged as a PIN diode, wherein the PIN diode comprises an i-type semiconductor layer located between an n-type semiconductor layer and a p-type semiconductor layer, wherein the i-type semiconductor layer exhibits a thickness which exceeds the thickness of each of the n-type semiconductor layer and the p-type semiconductor layer.
45. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region, wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the longitudinal optical sensor, given the same total power of the illumination, is capable of generating at least one longitudinal sensor signal being dependent on the beam cross-section of the light beam in the sensor region such that an amplitude of the longitudinal sensor signal decreases with decreasing cross-section of a light spot generated by the light beam in the sensor region; and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
46. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region, wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the longitudinal optical sensor, given the same total power of the illumination, is capable of generating at least one longitudinal sensor signal being dependent on the beam cross-section of the light beam in the sensor region, wherein a minimum of the longitudinal sensor signal occurs under a condition in which the sensor region is impinged by a light beam with the smallest available beam cross-section; and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
47. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region, wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the longitudinal sensor is substantially frequency-independent in a range of a modulation frequency of the light beam of 0 Hz to 500 Hz; and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
48. A detector for an optical detection of at least one object, the detector comprising: at least one longitudinal optical sensor, wherein the longitudinal optical sensor has at least one sensor region, wherein the longitudinal optical sensor is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the longitudinal optical sensor comprises at least one photodiode driven in a photoconductive mode, wherein an electrical conductivity of the sensor region, given the same total power of the illumination, is dependent on the beam cross-section of the light beam in the sensor region, wherein the longitudinal sensor signal is dependent on the electrical conductivity; and at least one evaluation device, wherein the evaluation device is designed to generate at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
49. The detector according to claim 48, wherein the photodiode comprises at least one p-type absorber material, at least one n-type semiconductor layer, and at least one pair of electrodes.
50. The detector according to claim 49, wherein the p-type absorber material is selected from the group consisting of: III-V compounds, II-VI compounds, I-III-VI.sub.2 compounds, and I.sub.2-II-IV-VI.sub.4 compounds.
51. The detector according to claim 50, wherein the p-type absorber material is selected from the group consisting of: amorphous silicon (a-Si), an alloy comprising amorphous silicon (a-Si), microcrystalline silicon (c-Si), germanium (Ge), copper indium sulfide (CIS), copper indium gallium selenide (CIGS), copper zinc tin sulfide (CZTS), copper zinc tin selenide (CZTSe), copper-zinc-tin sulfur-selenium chalcogenide (CZTSSe), cadmium telluride (CdTe), mercury cadmium telluride (HgCdTe), indium arsenide (InAs), indium gallium arsenide (InGaAs), indium antimonide (InSb), an organic-inorganic halide perovskite, and solid solutions and/or doped variants thereof.
52. The detector according to claim 48, wherein a bias voltage is applied across the photodiode in a reverse biased mode.
53. A camera for imaging at least one object, the camera comprising at least one detector according to claim 1.
54. A human-machine interface for exchanging at least one item of information between a user and a machine, wherein the human-machine interface comprises at least one detector according to claim 1, wherein the human-machine interface is designed to generate at least one item of geometrical information of the user by means of the detector wherein the human-machine interface is designed to assign to the geometrical information at least one item of information.
55. An entertainment device for carrying out at least one entertainment function, wherein the entertainment device comprises at least one human-machine interface according to claim 54, wherein the entertainment device is designed to enable at least one item of information to be input by a player by means of the human-machine interface, wherein the entertainment device is designed to vary the entertainment function in accordance with the information.
56. A tracking system for tracking the position of at least one movable object, the tracking system comprising at least one detector according to claim 1, the tracking system further comprising at least one track controller, wherein the track controller is adapted to track a series of positions of the object, each position comprising at least one item of information on at least a longitudinal position of the object at a specific point in time.
57. A scanning system for determining at least one position of at least one object, the scanning system comprising at least one detector according to claim 1, the scanning system further comprising at least one illumination source adapted to emit at least one light beam configured for an illumination of at least one dot located at at least one surface of the at least one object, wherein the scanning system is designed to generate at least one item of information about the distance between the at least one dot and the scanning system by using the at least one detector.
58. A stereoscopic system, comprising at least one tracking system according to claim 57 and the at least one scanning system, wherein the tracking system and the scanning system each comprise at least one longitudinal optical sensor which are located in a collimated arrangement in a manner that they are aligned in an orientation parallel to the optical axis of the stereoscopic system and exhibit an individual displacement in the orientation perpendicular to the optical axis of the stereoscopic system.
59. A method for an optical detection of at least one object, the method comprising: generating at least one longitudinal sensor signal by using at least one longitudinal optical sensor, wherein the longitudinal sensor signal is dependent on an illumination of a sensor region of the longitudinal optical sensor by a light beam, wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam in the sensor region, wherein the sensor region comprises at least one photoconductive material, wherein an electrical conductivity of the photoconductive material in the sensor region, given the same total power of the illumination, is dependent on the beam cross-section of the light beam in the sensor region, wherein the longitudinal sensor signal is dependent on the electrical conductivity; and generating at least one item of information on a longitudinal position of the object by evaluating the longitudinal sensor signal of the longitudinal optical sensor.
60. A detector according to claim 1, where the detector is adapted to function as a detector for at least one application selected from the group consisting of: a distance measurement; a position measurement; an entertainment application; a security application; a human-machine interface application; a tracking application; a scanning application; in stereoscopic vision; a photography application; an imaging application or camera application; a mapping application for generating maps of at least one space; a homing or tracking beacon detector for vehicles; a distance and/or position measurement of objects with a thermal signature; a machine vision application; a robotic application; a logistics application.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0540] Further optional details and features of the invention are evident from the description of preferred exemplary embodiments which follows in conjunction with the dependent claims. In this context, the particular features may be implemented alone or with features in combination. The invention is not restricted to the exemplary embodiments. The exemplary embodiments are shown schematically in the figures. Identical reference numerals in the individual figures refer to identical elements or elements with identical function, or elements which correspond to one another with regard to their functions.
[0541] Specifically, in the figures:
[0542]
[0543]
[0544]
[0545]
[0546]
[0547]
[0548]
[0549]
[0550]
[0551]
[0552]
[0553]
EXEMPLARY EMBODIMENTS
[0554]
[0555] Further, the longitudinal optical sensor 114 is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of a sensor region 130 by a light beam 132. Thus, according to the FiP effect, the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam 132 in the respective sensor region 130, as will be outlined in further detail below. According to the present invention, the 130 sensor region comprises at least one photoconductive material 134, in particular a chalcogenide 136, preferably lead sulfide (PbS) or lead selenide (PbSe). However, other photoconductive materials 134, in particular other chalcogenides 136, may be used. As a result of the use of the photoconductive material 134 in the sensor region 130, an electrical conductivity of the sensor region 130, given the same total power of the illumination, depends on the beam cross-section of the light beam 132 in the sensor region 130. Consequently, the resulting longitudinal sensor signal as provided by the longitudinal optical sensor 114 upon impingement by the light beam 132 depends on the electrical conductivity of the photoconductive material 134 in the sensor region 130 and thus allows determining the beam cross-section of the light beam 132 in the sensor region 130. Via a longitudinal signal lead 138, the longitudinal sensor signal may be transmitted to an evaluation device 140, which will be explained in further detail below. Preferably, the sensor region 130 of the longitudinal optical sensor 114 may be transparent or translucent with respect to the light beam 132 travelling from the object 112 to the detector 110. However, this feature may not be required since the sensor region 130 of longitudinal optical sensor 114 may also be intransparent.
[0556] In a preferred embodiment, the longitudinal optical sensor 114 may be located at a focal point 142 of the transfer device 120. Additionally or alternatively, in particular in embodiment in which the optical detector 110 may not comprise a transfer device 120, the longitudinal optical sensor 114 may be arranged in a movable fashion along the optical axis 116, such as by means of an optional actuator 144, which may be controllable by using an actuator control unit 146, which may be placed within the evaluation device 136. However, other kinds of setups are feasible.
[0557] The evaluation device 140 is, generally, designed to generate at least one item of information on a position of the object 112 by evaluating the sensor signal of the transversal optical sensor 114. For this purpose, the evaluation device 140 may comprise one or more electronic devices and/or one or more software components, in order to evaluate the sensor signals, which are symbolically denoted by a longitudinal evaluation unit 148 (denoted by z). As will be explained below in more detail, the evaluation device 140 may be adapted to determine the at least one item of information on the longitudinal position of the object 112 by comparing more than one longitudinal sensor signals of the longitudinal optical sensor 114.
[0558] As explained above, the longitudinal sensor signal as provided by the longitudinal optical sensor 114 upon impingement by the light beam 132 depends on the electrical conductivity of the photoconductive material 134 in the sensor region 130. In order to determine a variation of the electrical conductivity of the photoconductive material 134 it may, as schematically depicted in
[0559] The light beam 132 for illumining the sensor region 130 of the longitudinal optical sensor 114 may be generated by a light-emitting object 112. Alternatively or in addition, the light beam 132 may be generated by a separate illumination source 156, which may include an ambient light source and/or an artificial light source, such as a light-emitting diode 158, being adapted to illuminate the object 112 that the object 112 may be able to reflect at least a part of the light generated by the illumination source 156 in a manner that the light beam 132 may be configured to reach the sensor region 130 of the longitudinal optical sensor 114, preferably by entering the housing 118 of the optical detector 110 through the opening 124 along the optical axis 116. In a specific embodiment, the illumination source 156 may be a modulated light source 160, wherein one or more modulation properties of the illumination source 156 may be controlled by at least one optional modulation device 162. Alternatively or in addition, the modulation may be effected in a beam path between the illumination source 156 and the object 112 and/or between the object 112 and the longitudinal optical sensor 114. Further possibilities may be conceivable. In this specific embodiment, it may be advantageous taking into account one or more of the modulation properties, in particular the modulation frequency, when evaluating the sensor signal of the transversal optical sensor 114 for determining the at least one item of information on the position of the object 112. For this purpose, the respective property as provided by the modulation device 162 may also be supplied to the amplifier 154, which, in this specific embodiment, may be a lock-in amplifier 164.
[0560] Generally, the evaluation device 140 may be part of a data processing device 166 and/or may comprise one or more data processing devices 166. The evaluation device 140 may be fully or partially integrated into the housing 118 and/or may fully or partially be embodied as a separate device which is electrically connected in a wireless or wire-bound fashion to the longitudinal optical sensor 114. The evaluation device 140 may further comprise one or more additional components, such as one or more electronic hardware components and/or one or more software components, such as one or more measurement units and/or one or more evaluation units and/or one or more controlling units (not depicted here).
[0561]
[0562] As described above, the illumination of the photoconductive material 134 in the sensor region 130 by the incident light beam 132 results in a variation of the electrical conductivity of the photoconductive material 134 which, given the same total power of the illumination, depends on a beam cross-section 174 of the light beam 132 in the sensor region 130. Consequently, upon impingement of the sensor region 130 by the light beam 132 at least two separated electrodes 176, 178 provide the longitudinal sensor signal which depends on the electrical conductivity of the photoconductive material 134 and, thus, allows determining the beam cross-section 174 of the light beam 132 in the sensor region 130. Preferably, the optically intransparent electrodes 176, 178 each comprise a metal electrode, in particular one or more of a silver (Ag) electrode, a platinum (Pt) electrode, an aluminum (Al) electrode, or a gold (Au) electrode, or, alternatively, a graphene electrode. Herein, the electrodes 176, 178 are, preferably, placed on different locations on top of the layer 168 of the photoconductive material 134, in particular in form of bars which may be spaced apart a distance between 1 mm and 10 cm, such as about 1 cm.
[0563] Whereas in the exemplary setup of the longitudinal optical sensor 114 according to
[0564] In an alternative embodiment, the layer 168 of the photoconductive material 134 within the longitudinal optical sensor 114 comprises a mixture of an organic donor polymer as electron donor material and a fullerene-based electron acceptor material. In a particular example, the organic donor polymer comprises a 80:20 wt % mixture of poly(3-hexylthiophene-2,5.diyl) (P3HT) as the electron donor material and of [6,6]-phenyl-C61-butyric acid methyl ester (PC60BM) as the electron acceptor material. However, other kinds of mixture ratios and/or organic photoconductive materials 134 may also be suitable. Preferably, the single layer 168 of the photoconductive material 134 comprising the mixture of P3HT: PC60BM is similarly placed on the insulating substrate 170, preferably on the transparent or translucent substrate 180, 182, such as a glass or a quartz substrate. For this purpose, the mixture of P3HT:PC60BM may, preferably, be cast from a solution, in particular from a chlorobenzene solution, by using a deposition method, preferably a coating method, more preferred a spin-coating method, a slot-coating method, or a blade-coating method, or, alternatively, by evaporation, into the single layer 168 which may exhibit a thickness from 100 m to 2000 m, in particular from 200 m to 750 m.
[0565] Irrespective whether the embodiment according to
[0566] In
[0567] Herein,
[0568] During the experiment, the longitudinal optical sensor 114 was moved along the z-axis of the optical detector 110 by using the actuator 144 and the resulting voltage in millivolts (mV) was measured. Herein, the focal point 142 of the refractive lens 122 was located at a distance of 43.5 mm, whereby the refractive lens 122 and the light-emitting diode 158 serving as the illumination source 156 were placed at larger z-values. Moving the sensor along the z-axis of the optical detector 110 during the experiment resulted in a variation of the beam cross-section (spot size) of the incident light beam 132 at the position of the sensor region 130, thus yielding a z-dependent voltage signal.
[0569] As can be seen in
[0570] In the experiment according to
[0571] As can be, furthermore, extracted from
[0572]
[0573] Whereas
[0574] In
[0575] In measurement according to
[0576]
[0577] Accordingly, the photoconductive material 134 as used for the experiments as shown in
[0578]
[0579] Similar to the measurements according to
[0580] As a result, the curves in both
[0581] The ratio which provides a quotient between the photo-induced current of the sensor region 130 being located at the focal point 142 to the sensor region 130 outside the focal point 142 assumes a value from 4 to 5 as indicated in
[0582] Further,
[0585] with the third curve indicated as difference provides the difference between the respective values for the illuminated curve minus the values for the dark curve. As can be derived from a comparison of the three different curves in
[0586]
[0587] In contrast thereto, in the example as shown in
[0588] Finally,
[0589] As described above, the optical detector 110 may comprise a single longitudinal optical sensor 114 or, as e.g. disclosed in WO 2014/097181 A1, a stack of longitudinal optical sensors 114, particularly in combination with one or more transversal optical sensors 184. Hereby, using a layer of the organic photoconductive materials in the longitudinal optical sensors 114 may, particularly, by preferred, mainly due to the transparency, semitransparency or translucency of the organic photoconductive materials. As an example, one or more transversal optical sensors 184 may be located on a side of the stack of longitudinal optical sensors 114 facing towards the object. Alternatively or additionally, one or more transversal optical sensors 184 may be located on a side of the stack of longitudinal optical sensors 114 facing away from the object. Again, additionally or alternatively, one or more transversal optical sensors 184 may be interposed in between the longitudinal optical sensors 114 of the stack. However, embodiments which may only comprise a single longitudinal optical 114 sensor but no transversal optical sensor 184 may still be possible, such as in a case wherein only determining the depth, i.e. the z-coordinate, of the object may be desired.
[0590] Thus, in a case in which determining the x- and/or y-coordinate of the object in addition to the z-coordinate may be desired, it may be advantageous to employ, in addition to the at one longitudinal optical sensor 114 at least one transversal optical sensor 184 which may provide at least one transversal sensor signal. For potential embodiments of the transversal optical sensor, reference may be made to WO 2014/097181 A1. Accordingly, the transversal optical sensor 184 may be a photo detector having at least one first electrode, at least one second electrode and at least one photovoltaic material, wherein the photovoltaic material, preferably, one or more dye-sensitized organic solar cells, such as one or more solid dye-sensitized organic solar cells, may be embedded in between the first electrode and the second electrode.
[0591] In contrast to this known embodiment,
[0592] Accordingly, the transversal optical sensor 184 has a layer 168 of the photoconductive material 134 which, in particular comprises a chalcogenide 136, such as lead sulfide (PbS), lead selenide (PbSe), or another appropriate material. Herein, the layer 168 of the photoconductive material 134 may, preferably, be embedded in between two layers 186 of a transparent conducting oxide 188, preferably comprising indium tin oxide (ITO), fluorine doped tin oxide (FTO), or magnesium oxide (MgO). However, other material may be feasible, in particular according to the desired transparent spectral range.
[0593] Further, at least two electrodes 190, 192 may be present for recording the transversal optical signal. As schematically depicted in the side view of the of the transversal optical sensor 184 according to
[0594] As an example,
[0595] With regard to the optical detector 110 and to the detector system 200, reference may be made to the full disclosure of this application. Basically, all potential embodiments of the detector 110 may also be embodied in the embodiment shown in
[0596] Further, the evaluation device 140 may fully or partially be integrated into the optical sensors 114, 184 and/or into other components of the optical detector 110. The evaluation device 140 may also be enclosed into housing 118 and/or into a separate housing. The evaluation device 140 may comprise one or more electronic devices and/or one or more software components, in order to evaluate the sensor signals, which are symbolically denoted by the longitudinal evaluation unit 148 (denoted by z) and a transversal evaluation unit 210 (denoted by xy) and. By combining results derived by these evolution units 154, 156, a position information 212, preferably a three-dimensional position information, may be generated (denoted by x, y, z). Similar to the embodiment according to
[0597] Further, the optical detector 110 and/or to the detector system 200 may comprise an imaging device 214 which may be configured in various ways. Thus, as depicted in
[0598] In the exemplary embodiment as shown in
[0599] The optical detector 110 may be adapted to determine at least one item on a longitudinal position of one or more of the beacon devices 220 and, optionally, at least one item of information regarding a transversal position thereof, and/or at least one other item of information regarding the longitudinal position of the object 112 and, optionally, at least one item of information regarding a transversal position of the object 112. Particularly, the optical detector 110 may be adapted for identifying colors and/or for imaging the object 112, such as different colors of the object 112, more particularly, the color of the beacon devices 220 which might comprise different colors. The opening 124 in the housing 118, which, preferably, may be located concentrically with regard to the optical axis 116 of the detector 110, may preferably define a direction of a view 126 of the optical detector 110.
[0600] The optical detector 110 may be adapted for determining the position of the at least one object 112. Additionally, the optical detector 110, specifically an embodiment including the camera 202, may be adapted for acquiring at least one image of the object 112, preferably a 3D-image. As outlined above, the determination of a position of the object 112 and/or a part thereof by using the optical detector 110 and/or the detector system 200 may be used for providing a human-machine interface 204, in order to provide at least one item of information to a machine 222. In the embodiments schematically depicted in
[0601] Similarly, as outlined above, the human-machine interface 204 may form part of the entertainment device 206. Thus, by means of the user 218 functioning as the object 112 and/or by means of the user 218 handling the object 112 and/or the control element 216 functioning as the object 112, the user 218 may input at least one item of information, such as at least one control command, into the machine 222, particularly the computer, thereby varying the entertainment function, such as controlling the course of a computer game.
[0602]
[0603] For this simulation, a resistor network software was initially compared with experimental results for photoconductors comprising PbS as the photoconductive material in the longitudinal optical sensor. After having achieved reasonable agreement between simulation and experiment, an interconnected array of individual photoconductors was employed for simulation. Herein, the array yielded an aggregate DC resistance which turned out to be non-linear with respect to the illumination density as long as not all of the individual photoconductors were illuminated equally. This feature could even be observed in a case in which the individual photoconductors exhibit a perfectly linear resistive response to the illumination density. Consequently, this feature could be employed to determine the cross-section of the light beam 132 on the array within the sensor region 130 and, hence, the distance between the detector 110 and the source of the light or IR radiation, even within the LWIR spectral range, i.e. from 5 m to 15 m. For the purposes of the simulation, a Gaussian profile was assumed for the light beam 132, which, at the first step, significantly overfilled the array until it was consecutively reduced in diameter in the following steps.
[0604]
[0605] In the example as depicted in
[0606] As shown in
[0607] Moreover, as can be derived from
[0608] Further,
[0609] In an alternative embodiment (not depicted here), at least one of the i-type semiconductor layer 236, the n-type semiconductor layer 238, and the p-type semiconductor layer 240 in the PIN diode 234 comprises an amorphous silicon carbon alloy (a-SiC), preferably a hydrogenated amorphous silicon carbon alloy (a-SiC:H). In this alternative embodiment, at least one of the p-type semiconductor layer 240 or the i-type semiconductor layer 236 may exhibit a thickness from 2 nm to 20 nm, preferably from 4 nm to 10 nm, in particular about 5 nm. This kind of alternative PIN diode 234 may preferably be used in the detector 110 according to the present invention for detecting a wavelength of the incident beam 132 within the UV wavelength range, in particular, completely over at least one of UVA wavelength range from 315 nm to 400 nm and the UVB wavelength range from 280 nm to 315 nm.
[0610] In a further alternative embodiment as illustrated in
[0611] In order to enable the longitudinal optical sensor 114 also to be sensitive within at least a part of the ultraviolet (UV) spectral range, a further alternative embodiment, such as depicted in
[0612]
[0613] Herein, a glass of about of a thickness of 1 mm to 3 mm, such as a soda-lime glass, may here, as commonly, used as the transparent substrate 170, 180, in particular since a presence of sodium in the glass substrate allowing yielding a substantial open-circuit voltage increase, presumably through surface and/or grain boundary defects passivation. However, as in this example as depicted in
[0614] A back-contact layer 246 which can serve as the back contact and, additionally, may reflect a considerable amount of unabsorbed light into the absorbing p-type semiconductor layer 240 may comprise a thin metal layer, such as a molybdenum (Mo) metal layer, which might be produced by depositing, such as by sputtering, the respective metal onto the substrate 170. Further, following molybdenum deposition, the p-type absorber material 244 may be grown on top of the back-contact layer 246 by one of several methods, such as, for example, described in W. Hermes et al., s. o. Accordingly, thin-films of can, generally, be prepared via a two-step process. During a first step, a thin film of the p-type absorber material 244 may be deposited by a vacuum-based or a solution-based method. For this purpose, elements or a precursor material can be coated sequentially or mixed, wherein high efficiency is obtained for elements already mixed in the film. As an alternative, nanoparticles comprising the p-type absorber material 244 can be deposited. In the second step, the layer may be annealed at temperatures from 500 C. and 600 C. which may result in the formation of the desired p-type absorber material 244 from the elements or a sintering of the nanoparticles. To alternatively fabricate the p-type absorber material 244 absorber material in a one-step approach, the elements may be simultaneously deposited at elevated temperatures, such via co-sputtering or co-evaporation onto heated substrates, thus, leading to a direct formation of the p-type absorber material 244 during deposition. However, other kinds of materials may be possible.
[0615] Further, particularly as a result of a direct contact between the molybdenum (Mo) metal present in the back-contact layer 246 and the adjacent p-type absorber material 244 comprising sulfur (S) atoms as in this example, a layer comprising molybdenum sulfide MoS.sub.2 may be obtained in-situ as a thin boundary layer 248 located between the back contact layer 246 and the p-type absorber material 244.
[0616] On top of the p-type absorber material 244, a thin n-type semiconductor layer 238 which may, preferably, work as a buffer layer 250 may be provided. As typically in the case of the thin-film solar devices 242, the buffer layer 250 can comprise a material such as cadmium sulfide (CdS) which might, for example, be deposited via chemical bath deposition. In addition, the buffer layer 250 may be overlaid with a thin protection layer 252 which may, further, be capped by a comparatively thicker charge-carrier collection layer 254. Generally, the protection layer 252 may comprise a layer of intrinsic zinc oxide (i-ZnO) which can, particularly, be used for protecting both the buffer layer 250 and the p-type absorber material 244 from sputtering damages which may otherwise occur during deposition of the charge-carrier collection layer 254. Herein, the charge-carrier collection layer 254 may, preferably, comprise an aluminum (Al) doped ZnO layer (ZnO:A1), usually denoted as ZnO:Al window layer, which may, as usually, produced by DC sputtering which is known as a rather damaging process. Other kinds of materials may also be feasible for being used within the respective layers, such as zinc sulfide (ZnS), zinc oxide (ZnO), or zinc hydroxide (ZnOH) within the buffer layer 250 in order to avoid toxic cadmium (Cd). The charge-carrier collection layer 254 can, preferably, serve as a transparent conducting oxide layer 256 for collecting and moving charge-carriers from the p-type absorber material 244 while absorbing incident light from the light beam 132 to the at least one first electrode 176 and the at least one second electrode 178 as arranged here on top of the charge-carrier collection layer 254. Accordingly, a photodiode 258 is, thus, formed at least by the n-type semiconductor layer 238 and the p-type semiconductor layer 240 and which may, as further illustrated in
[0617]
[0618]
[0619]
[0620] A similar example is presented in
[0621]
[0622] Thus,
[0623] Further,
[0624] As illustrated in
[0625] In contrast to these findings, the positive FiP effect could, although having a comparatively smaller amplitude, as illustrated in
[0626] This kind of behavior with respect to the sign of the FiP effect depending on the intensity of the incident light beam 132 may, in particular, be explained by an assumption that in case in which the incident light beam 132 has, given the same total power of the illumination, a small beam cross-section 174 and, thus, causes a high intensity within the area of the beam cross-section 174, recombination of a great number of generated charge-carriers may occur within the p-type absorber material 244 CZTS. In the opposing situation in which the incident light beam 132 has, given the same total power of the illumination, a large beam cross-section 174 and, therefore, may only lead to a low intensity within the area of the beam cross-section 174, virtually no recombination can occur within the p-type absorber material 244 CZTS, moreover, since this kind of material may, in particular, have a large number of defects.
[0627] Consequently, by switching between the at least two operational modes of the longitudinal optical sensor 114, it may, thus, be feasible to acquire two individual measurement curves, wherein one of the individual curves may, in particular, be used for reference purposes. Since the photodiode 258 may, generally, not exhibit the FIR effect in the photovoltaic mode while the same photodiode 258 may actually exhibit the FiP effect in the photoconductive mode, it may, accordingly, be possible to use the measurement curve acquired in the photovoltaic mode as a reference base for resolving the above-mentioned ambiguities with respect to the longitudinal sensor signal by comparing the two individual measurement curves.
[0628] Compared to the detector 110 in which the sensor region 130 of the longitudinal optical sensor 114 comprises the chalcogenide 136 lead sulfide (PbS) or lead selenide (PbSe) as the photoconductive material 134, the detectors 110 of this the kind as illustrated in
[0629] Further, as illustrated in
[0630] In a preferred embodiment as further illustrated in
[0631]
[0632] In a first embodiment as illustrated in
[0633] In this particular example, the PbS CQD film 262 which comprises PbS quantum dots 264 having diameters above 5 nm still exhibits a good absorption above 1000 nm. In order to achieve this result, a 100 mg/ml solution of PbS quantum dots 264 in an unpolar organic solvent, preferably octane, have been provided, from which two subsequent layers have been formed on the ITO electrode 274 by application of a deposition method, preferably by a spin-coating method with a rotation frequency from 1000 rpm to 6000 rpm, such as 4000 rpm. Each of the two layers has individually been treated with ethanedithiol during a treatment time, preferably from 10 s to 10 min, more preferred from 10 s to 1 min, such as 30 s, before a drying step was performed for a drying time, preferably from 1 min to 2 h, more preferred from 10 min to 1 h, such as 30 min, at a drying temperature from 50 C. to 250 C., preferred from 100 C. to 200 C. This kind of procedure turned out to be particularly advantageous with respect to obtaining a setup for the longitudinal optical sensor 114 with as little short circuits through the COD film 262 as possible. Finally, a 100 nm thick layer of aluminum was deposited through evaporation onto the colloidal film 262 as the metal electrode 276. Experimental results which demonstrate the occurrence of the negative FiP effect in this kind of specimen are shown in
[0634] In an alternative embodiment as illustrated in
[0635] In a further embodiment as illustrated in
[0636] As outlined above, the detector 110 may have a straight beam path or a tilted beam path, an angulated beam path, a branched beam path, a deflected or split beam path or other types of beam paths. Further, the light beam 132 may propagate along each beam path or partial beam path once or repeatedly, unidirectionally or bidirectionally. Thereby, the components listed above or the optional further components listed in further detail below may fully or partially be located in front of the longitudinal optical sensors 114 and/or behind the longitudinal optical sensors 114.
LIST OF REFERENCE NUMBERS
[0637] 110 detector
[0638] 112 object
[0639] 114 longitudinal optical sensor
[0640] 116 optical axis
[0641] 118 housing
[0642] 120 transfer device
[0643] 122 refractive lens
[0644] 124 opening
[0645] 126 direction of view
[0646] 128 coordinate system
[0647] 130 sensor region
[0648] 132 light beam
[0649] 134 photoconductive material
[0650] 136 chalcogenide
[0651] 138 signal leads
[0652] 140 evaluation device
[0653] 142 focal point
[0654] 144 actuator
[0655] 146 actuator control unit
[0656] 148 longitudinal evaluation unit
[0657] 150 bias voltage source
[0658] 152 ground
[0659] 154 amplifier
[0660] 156 illumination source
[0661] 158 light-emitting diode
[0662] 160 modulated illumination source
[0663] 162 modulation device
[0664] 164 lock-in amplifier
[0665] 166 data processing device
[0666] 168 layer of photoconductive material
[0667] 170 substrate
[0668] 172 ceramic substrate
[0669] 174 beam cross-section
[0670] 176 first electrode
[0671] 178 second electrode
[0672] 180 transparent substrate
[0673] 182 translucent substrate
[0674] 184 transversal optical sensor
[0675] 186 layer of transparent conducting oxide
[0676] 188 transparent conducting oxide
[0677] 190 first electrode
[0678] 192 second electrode
[0679] 194 first split electrode
[0680] 196 second split electrode
[0681] 198 sensor area
[0682] 200 detector system
[0683] 202 camera
[0684] 204 human-machine interface
[0685] 206 entertainment device
[0686] 208 tracking system
[0687] 210 transversal evaluation unit
[0688] 212 position information
[0689] 214 imaging device
[0690] 216 control element
[0691] 218 user
[0692] 220 beacon device
[0693] 222 machine
[0694] 224 track controller
[0695] 226 layer of material capable of sustaining an electrical current
[0696] 228 first electrode
[0697] 230 second electrode
[0698] 232 beam path
[0699] 234 PIN diode
[0700] 236 i-type semiconductor layer
[0701] 238 n-type semiconductor layer
[0702] 240 p-type semiconductor layer
[0703] 242 thin-film solar cell
[0704] 244 p-type absorber material
[0705] 246 back-contact layer
[0706] 248 boundary layer
[0707] 250 buffer layer
[0708] 252 protection layer
[0709] 254 charge-carrier collection layer
[0710] 256 transparent conducting oxide layer
[0711] 258 photodiode
[0712] 260 switching device
[0713] 262 colloidal film
[0714] 264 quantum dots
[0715] 266 Schottky diode
[0716] 268 first electrode
[0717] 270 second electrode
[0718] 272 optically transparent electrode
[0719] 274 indium-doped tin oxide (ITO) electrode
[0720] 276 metal electrode
[0721] 278 aluminum (Al) electrode
[0722] 280 Schottky barrier
[0723] 282 blocking layer
[0724] 284 titanium dioxide (TiO.sub.2) layer
[0725] 286 fluorine-doped tin oxide (SnO.sub.2:F, FTO) electrode
[0726] 288 electrically conducting polymer
[0727] 290 PEDOT layer
[0728] 292 split electrode
[0729] 294 silver (Ag) electrode
[0730] 296 mesoporous titanium oxide (TiO.sub.2) layer