Device and method for dynamic processing in water purification
09862624 · 2018-01-09
Assignee
Inventors
- Meng H. Lean (Santa Clara, CA)
- Jeonggi Seo (Albany, CA, US)
- Armin R. Völkel (Mountain View, CA, US)
- Ashutosh Kole (Sunnyvale, CA, US)
- Huangpin B. Hsieh (Mountain View, CA)
- Nitin S. Parekh (Los Altos, CA, US)
- Norine E. Chang (Menlo Park, CA, US)
Cpc classification
C02F9/00
CHEMISTRY; METALLURGY
C02F1/001
CHEMISTRY; METALLURGY
B01D21/265
PERFORMING OPERATIONS; TRANSPORTING
C02F1/52
CHEMISTRY; METALLURGY
B01D29/48
PERFORMING OPERATIONS; TRANSPORTING
B01D21/26
PERFORMING OPERATIONS; TRANSPORTING
B01D46/403
PERFORMING OPERATIONS; TRANSPORTING
C02F9/00
CHEMISTRY; METALLURGY
B01D21/26
PERFORMING OPERATIONS; TRANSPORTING
C02F1/001
CHEMISTRY; METALLURGY
International classification
B01D21/26
PERFORMING OPERATIONS; TRANSPORTING
B01D29/48
PERFORMING OPERATIONS; TRANSPORTING
C02F1/52
CHEMISTRY; METALLURGY
B01D46/40
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A transformational approach to water treatment is provided that incorporates membrane-free filtration with dynamic processing of the fluid to significantly reduce treatment times, chemical cost, land use, and operational overhead. This approach provides hybrid capabilities of filtration, together with chemical treatment, as the water is transported through various spiral stages.
Claims
1. A system for dynamic processing for water purification, the system comprising: an inlet to receive water from a source; a filter stage operative to filter first particles; a mixing stage operative to receive and coagulate the filtered water; a spiral stage operative to receive the water and separate second particles from the water, wherein the spiral stage comprises a channel in which separation occurs, having a central inlet, structured to provide continuous flow to a peripheral outlet thereof having a split channel egress with a first single channel egress for effluent and a second single channel egress for concentrate; and a second filter stage operative to filter third particles from the water.
2. The system as set forth in claim 1 wherein the first filter stage is a screen filter.
3. The system as set forth in claim 1 wherein the spiral stage is incorporated in a single spiral device.
4. The system as set forth in claim 1 wherein the mixing stage is incorporated in a single spiral device.
5. The system as set forth in claim 1 wherein the mixing stage is incorporated in a flash mixer.
6. The system as set forth in claim 1 wherein the spiral stage is incorporated in a first spiral device to receive the coagulated water and treat with flocculant and a second spiral device to separate second particles from the water.
7. The system as set forth in claim 1 wherein the second filter stage is a filter device.
8. The system as set forth in claim 1 further comprising a feedback path to the source or to the inlet of the channel.
9. The system as set forth in claim 8 wherein the feedback path includes a spiral stage for dewatering that receives backwash from the second filter stage.
10. The system as set forth in claim 1 wherein the first particles are approximately 1-3 mm in diameter.
11. The system as set forth in claim 1 wherein the second particles are approximately 5 m or larger in diameter.
12. The system as set forth in claim 1 wherein the third particles are 0.5 m or larger in diameter.
13. A system for dynamic processing for water purification, the system comprising: an inlet to receive water from a source; a filter stage operative to filter first particles; a spiral mixing stage operative to receive and coagulate the filtered water, the spiral mixing stage having a central inlet and a peripheral outlet; a separating stage operative to receive the coagulated water and treat with flocculant and separate second particles from the water, wherein the separating stage comprises a channel in which separation occurs, having an inlet, structured to provide continuous flow to an outlet thereof having a split channel egress with a first single channel egress for effluent and a second single channel egress for concentrate, wherein the separating stage eliminates sedimentation to separate the second particles; a second filter stage operative to filter third particles from the water.
14. The system as set forth in claim 13 wherein the first filter stage is a screen filter.
15. The system as set forth in claim 13 wherein the second filter stage is a filter device.
16. The system as set forth in claim 13 further comprising a feedback path to the source.
17. The system as set forth in claim 13 wherein the first particles are approximately 1-3 mm in diameter.
18. The system as set forth in claim 13 wherein the second particles are approximately 5 m or larger in diameter.
19. The system as set forth in claim 13 wherein the third particles are 0.5 m or larger in diameter.
20. The system as set forth in claim 1 wherein the channel is membrane-free.
21. The system as set forth in claim 13 wherein the channel is membrane-free.
22. A system for dynamic processing for water purification, the system comprising: an inlet to receive water from a source; a filter stage operative to filter first particles; a spiral mixing stage operative to receive, coagulate and mix flocculant into the filtered water, the spiral mixing stage having a central inlet and a peripheral outlet; a spiral separating stage operative to receive the water from the mixing stages and separate second particles from the water, wherein the spiral stage comprises a channel in which separation occurs, having a central inlet, structured to provide continuous flow to a peripheral outlet thereof having a split channel egress with a first single channel egress for effluent and a second single channel egress for concentrate; and, a second filter stage operative to filter third particles from the water.
23. The System as set forth in claim 22 further comprising a water feedback path.
24. A system for dynamic processing for water purification, the system comprising: an inlet to receive water from a source; a filter stage operative to filter first particles; a spiral stage operative to receive the water, mix the water and separate second particles from the water, wherein the spiral stage comprises a channel in which mixing and separation occurs, having a central inlet, structured to provide continuous flow to a peripheral outlet thereof having a split channel egress with a first single channel egress for effluent and a second single channel egress for concentrate; and a second filter stage operative to filter third particles from the water.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(16) The presently described embodiments represent a transformational approach to water treatment that incorporates membrane-free filtration with dynamic processing of the fluid to significantly reduce treatment times, chemical cost, land use, and operational overhead. The approach provides hybrid capabilities of filtration together with chemical treatment as the water is transported through various spiral stages.
(17) Features of the system include, but are not limited to, the following:
(18) 1) Use of a spiral particle extraction capability as a front-end to lighten the TSS (total suspended solids) loading on the system. The flash mixing at the front-end of the process also enhances chemical kinetics and results in a more complete reaction;
(19) 2) Use of a dynamic transport capability in narrow flow channels where the high rate of shear from rapid parabolic flow and coagulants results in seed particles of uniform size which are ideal for accelerated agglomeration kinetics;
(20) 3) Allowance for removal of pin floccs (particle size at transition point between the end of coagulation and start of flocculation) as small as 5 m by the spiral device rather than rely on the conventional practice of allowing them to agglomerate to hundreds of microns in size before settling out in the sedimentation basin. This process also results in accelerated agglomeration;
(21) 4) Allow for the entire or near elimination of the flocculation and sedimentation steps together with all the attendant chemicals. This will also allow for reduced land use and maintenance labor; and,
(22) 5) Allow for gradual dosage of chemicals.
(23) In this regard,
(24) As shown in
(25) The system 100 further includes a first stage 106, a second spiral stage 108 and a third spiral stage 110. It is to be appreciated that the spiral stages may be incorporated within a single spiral separator device. As an alternative, any one of the spiral stages may be implemented in its own unique spiral separator device. In any case, the first stage 106 is a flash mixing stage. It should be understood that this stage may take the form of a flash mixer, a turbulent mixer or another spiral mixing stage. If a spiral mixing stage is used here, a sufficient amount of turbulence is introduced into the spiral stage to achieve sufficient mixing. The second spiral stage 108 is a spiral slow mixing stage. And, the third spiral stage is a spiral separating stage. In the third stage, particles of 5 m or larger are typically separated from the fluid.
(26) A filter 112 is also provided to the system. The filter 112 may take a variety of forms. However, in one form, it comprises multiple filtering media or membrane filters to, for example, conform to EPA mandates for physical barriers. The particles that are filtered by the filter device 112 are typically in the 0.5 m or larger range. Also shown in the system 100 is an optional spiral stage 114 that provides for dewatering. In this stage, the spiral dewatering device receives backwash fluid from the filter 112 and separates sludge from water which is provided back to the water source.
(27) In operation, the system 100 receives water from the source 102 which may include ground, surface, brackish, sea or waste water. This water is filtered through the screen filter 104 to remove a first group of particles in the noted range. The water supply is then flash mixed in stage 106 along with the potassium permanganate, coagulant, and chlorine. Next, flocculant is slow mixed into the supply in spiral slow mixing stage 108. In the third spiral stage 110, another group of particles is separated out from the supply. As noted, these particles are typically in the 5 m or larger range. Then, the filter 112 filters out a third group of particles that are generally smaller and are in the range of 0.5 m or larger. The output is then transmitted on for any of a variety of uses.
(28) It should also be understood that the filter 112 may be subjected to a backwashing process which will provide fluid to an optional spiral dewatering stage 114 to, again, separate sludge from water that is provided back to the water source.
(29) With reference now to
(30) The outlet 111 connects to a waste stream 115 which, as shown, includes particles greater than 1-5 micrometers in size. Also shown is an optional recirculation path 117 that may have disposed therein a reduced coagulation tank 119. The recirculation path connects with the inlet 107 of the device 109. The outlet 113 connects to a filter 112, which operates and is configured as described above in connection with
(31) An example of spiral wound prototype of a spiral device is shown in
(32) The spiral device 200 may be structured so that a single spiral stage, as noted above, or multiple contemplated spirals stages are incorporated therein. Of course, the objectives of flash mixing, slow mixing and separating are taken into account in the design of each of the stages. For example, the channel width and flow velocity of each of the stages is taken into consideration in the spiral device implementation. In this regard, it should also be understood that the spiral device shown is merely an example. Any similar spiral device may be implemented to achieve the objectives of the presently described embodiments. For example, spiral devices described in U.S. application Ser. No. 11/606,460, filed Nov. 30, 2006, entitled Particle Separation and Concentration System, or U.S. patent application Ser. No. 11/936,729, filed on Nov. 7, 2007, entitled Fluidic Device and Method for Separation of Neutrally Buoyant Particles, and naming Lean et al. as inventors which are incorporated in their entirety herein by this reference, may be used. It should be appreciated that any suitable material may be used to implement the spiral devices of the contemplated system.
(33) Further, the dimensions of the spiral channel may vary depending on the implementation. In one form, however, the diameter of the spiral device is 12 inches and the height may vary from 1 inch to 16 inches. The dimensions may have an impact on pressure and output power of the system. Likewise, dimensions of the actual channels may impact pressure and power output. Generally, more pressure (which can be a result of a narrow channel) will result in more power.
(34) Also, the device may be cascaded and/or placed in parallel to achieve greater control of the output and/or greater throughput through the system. As a mere simple example used for explanatory purposes, with reference now to
(35) In operation, the system 500 with the cascaded spiral stages facilitates a first separation of particles between those of greater than 10 micrometers being output from the first spiral separator in a waste stream and particles less than 10 micrometers being input to the second spiral separator 520 for further processing. The second spiral separator then separates particles greater than 1 micrometer and outputs fluid within which those particles reside by way of outlet 524. The remaining fluid or effluent is output through outlet 526. In this manner, the system 500 is able to isolate particles between 1 and 10 micrometers for various sampling processing. This concept can be extended by continued cascading of spiral structures with smaller size cut-offs to achieve fractionation of particles with decreasing size ranges.
(36) With reference to
(37) This device 700 includes a spirally wound body 704 having inlet 706, a first outlet 708 and a second outlet 710. The device 700, as shown in
(38) In
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(40) Dynamic processing of the water during transport through the various spiral stages refers to the use of coagulants and high shear rates to enhance agglomeration kinetics. Proof of concept is demonstrated in water treatment experiments using conventional jar tests with and without a spiral device. Jar tests are a standard lab-scale procedure for optimizing the aggregation/flocculation/sedimentation dosage and performance in the water treatment process. The type and amount of coagulant needed depends on the turbidity and native pH of the sample water. Our sample water had a turbidity level of between 25 to 30 NTU and a native pH value of about 9. The standard jar test is typically performed in three phases: In the first phase the liquid is stirred at a high rate (e.g. 275 to 280 rpm) during which the coagulant is added rapidly and the pH level of the sample is adjusted to a value of 9 using 1 N NaOH solution. In a second phase stirring is reduced to a moderate level (e.g. 25 to 30 rpm) that promotes some mixing, but allows the growth of larger floccs. In the third phase no external stirring takes place while the particles grow even larger and sediment out of solution.
(41) In a first modification of the standard jar test (subsequently referred to as step wise coagulant addition) we added the coagulant gradually in small doses, and adjusted the pH level to a value of 9 after each of these additions.
(42) In a second modification (subsequently referred to as modified jar test), we pumped the fluid at a fixed flow rate through a spiral channel device during phase 1, and optionally during phase 2. The average shear rate inside the channel is approximately 300/s, corresponding to a conventional square jar. In comparison, the average shear rates inside the cylindrical glass beaker are 100/s and 10/s for the rapid and slow mixing phases, respectively.
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(44) There are different modes of aggregation: For small particles and/or slow stirring diffusion driven aggregation dominates. For larger particles (approx 1 m and above) and/or higher mixing rates aggregation is shear dominated. In this case the maximum particle size is limited, since the shear force on the particles will increase with the aggregate size and eventually exceed the binding force between the individual (primary) particles. Most of the particle aggregation and flocculation happens while the sample liquid is not agitated or only moderately stirred. In this case, diffusion driven aggregation is the dominant growth mode for particles below a few m in size. The total particle number decreases over time as
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where N.sub.0 is the particle concentration at the start of the experiment, t is time, and is the characteristic time scale of the process. For the diffusion driven (or perikinetic) aggregation depends on the fluid viscosity, temperature, the initial concentration of particles, and the type of aggregates that grow (loose and light vs. compact and dense).
(46) Turbidity is a measure that includes both light absorption as well as light scattering off particles. Though it is not an exact measurement of the particle concentration or size distribution inside the sample liquid, we may still expect a similar time dependence of the NTU value, if particle scattering dominates the measured value. To compare measured turbidity vs. time curves with model predictions, we fit the experimental data to the function
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which was derived from Eqn. (1) by adding a time offset and a constant background:
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with
b.sub.0=f(N.sub.0); b.sub.1=t.sub.0; b.sub.2=NTU.sub.base.(4)
(49) Comparison of Standard Jar Test Vs. Step-Wise Coagulant Addition
(50) To start the aggregation process coagulant is added and the pH is adjusted to an alkaline level of about 9. The rate and order of addition of these two substances to the sample liquid matter, as they define the ionic strength of the solution and the surface charge of the colloidal particles. Rapid mixing at this stage is essential, as the coagulant destabilizes the sample solution at the injection point and leads to the formation of very large, but loosely connected, floccs that increase the local viscosity substantially. Sufficient shear will break up this flocc network and promote good mixing of all the coagulant within the sample volume. In the standard jar test, all the coagulant is added first at a rapid rate, and then the pH is adjusted with 1 N NaOH solution. Here we compare this standard process with a step-wise procedure, where the coagulant is added in small amounts, followed by an immediate adjustment of the pH level with NaOH solution.
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(52) Comparison of Standard Jar Test Vs. Modified Jar Test
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(55) In summary, the aggregation dynamics depends crucially on the rate and mode of coagulant addition and pH adjustment. Initial inhomogeneities in the coagulant concentration appear to create large loose floccs that do not break up even under the applied stirring rate. These loose floccs have a low diffusion rate due to their large size which leads to a slower growth rate. Step-wise coagulant addition with immediate adjustment of the pH of the sample liquid prevents the uncontrolled growth of large, loose floccs and promotes the formation of more compact aggregates that grow faster due to their faster diffusion rates. Moving the sample fluid through a channel at sufficient flow rate (causing sufficiently large shear rate) will prevent aggregate growth and will lead to break-up of the loose floccs that form during coagulant addition. Once the sample liquid is no longer moving through the micro channel, aggregates grow rapidly, suggesting again the formation of compact particles.
(56) The advantages of the presently described embodiments include:
(57) 1) Particulate extraction based on design cut-off down to 1 um
(58) 2) Dynamic processingtransport and enhancement of agglomeration kinetics
(59) 3) Replacement of intermediate filtration steps
(60) 4) Front-end to MWT to lighten the TSS loading
(61) 5) Cascaded operation
(62) 6) Parallelizable operation
(63) 7) Scalable, high-throughput, continuous flow
(64) 8) Shorter processing time, smaller footprint, reduce TCO (total cost of ownership)
(65) 9) Elimination of flocculation and sedimentation stepssavings on chemicals, land, and operating incidentals including labor, power, etc.
(66) 10) May be used for other applications in water including but not limited to IC fab reclaim, cooling tower water, MBR (membrane bio reactor), pre-treatment for RO (reverse osmosis), and waste water reclaim.
(67) It will be appreciated that various of the above-disclosed and other features and functions, or alternatives thereof, may be desirably combined into many other different systems or applications. Also that various presently unforeseen or unanticipated alternatives, modifications, variations or improvements therein may be subsequently made by those skilled in the art which are also intended to be encompassed by the following claims.