Injection molding process of a preform for use in biaxial stretching and blow molding

Abstract

Disclosed is an injection molding device and process for a test tube shaped preform, that can laminate a colored layer at certain positions with a certain thickness accurately. Included is a nozzle section, in which a molten main resin and second resin are joined together to form a joined resin mass, the nozzle section including: an outer flow channel through which the main resin flows, an inner flow channel through which the second resin flows, a cylindrical column-shaped flow channel where the second resin joins the main resin, a first confluence where the main resin flows into the joined flow channel, a second confluence where the second resin flows into the joined flow channel wherein the first confluence is downstream of the second confluence, and a cylindrical shutoff pin inserted in the joined flow channel to open or close one or both the first and second confluences.

Claims

1. A injection molding process of a preform for use in biaxial stretching and blow molding, the preform having a shape of a test tube and having at least one second resin layer laminated with a main resin layer that forms a shape of the preform, the injection molding process including an injection molding device having: a mold having a cavity and a pin gate; a nozzle section facing the mold, the nozzle section supplying: (i) a molten main resin to be formed into the main resin layer, and (ii) a molten second resin to be formed into the at least one resin layer, the nozzle section joining the molten main resin and the molten second resin to form a joined resin mass, the nozzle section including: an outer flow channel through which the main resin flows, an inner flow channel through which the second resin flows, a cylindrical column-shaped joined flow channel that joins the second resin from the inner flow channel with the main resin from the outer flow channel, a first confluence disposed at a point where the main resin from the outer flow channel flows into the joined flow channel, a second confluence disposed at a point where the second resin flows into the joined flow channel, the first confluence being located downstream of the second confluence with a predetermined space left between the first and second confluences, and a cylindrical shutoff pin inserted slidably in the joined flow channel, the shutoff pin being capable of shutting off or opening one or both of the first and second confluences based on a sliding position of the shutoff pin; and the injection molding process comprising the steps of: maintaining the first confluence in an open state while controlling the sliding position of the shutoff pin, and supplying the main resin from the outer flow channel into the joined flow channel in a predetermined time span; supplying the second resin: (A) after a predetermined time lag in which the main resin is supplied into the joined flow channel, and (B) at a higher velocity than the main resin, from the inner flow channel to the joined flow channel such that the second resin plunges into a central portion of the main resin and breaks through a forefront portion of the main resin to take a lead position in the joined flow channel or in the cavity of the mold, wherein the at least one second resin layer is formed and laminated on both outer and inner surfaces of a peripheral wall over a predetermined height range of the preform; forming the joined resin mass by simultaneously joining the main resin and the second resin in the joined flow channel for a predetermined period of time within the predetermined time span by bringing the second confluence to an open state; while the supply of the main resin is continued, the supply of the second resin is stopped with the second confluence part in a shut off state, and the main resin plunges into a central portion and breaks through a forefront portion of the second resin; and injecting the joined resin mass into the cavity of the mold through the pin gate and filling the cavity with the joined resin mass.

2. The process for injection molding the preform according to claim 1, wherein the at least one second resin layer is a decorative layer made of a colored resin.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a schematic explanatory diagram showing a vertical section of an important part of the injection molding device in an embodiment of this invention.

(2) FIG. 2 is a vertical section of an embodiment of the mold for preform molding use.

(3) FIGS. 3(a)-(c) are explanatory diagrams showing the sliding positions of the shutoff pin used in the injection molding device of FIG. 1.

(4) FIG. 4 is an explanatory diagram showing an example of the injection patterns used by the injection molding process of this invention

(5) FIGS. 5(a)-(c) are schematic explanatory diagrams showing steps of filling the mold cavity with molten resins according to an injection pattern P1 in FIG. 4.

(6) FIG. 6 is a front view, with a vertical section on the right side, of a preform molded according to the injection pattern P1 in FIG. 4.

(7) FIG. 7(a) is a front view of the bottle in an embodiment of this invention, and FIG. 7(b), a vertical section of peripheral wall of this bottle biaxially stretched and blow molded from the preform of FIG. 6.

(8) FIGS. 8(a)-(d) are explanatory diagrams showing a comparison of laminate conditions for the preforms molded according to the injection patterns P1 to P4 in FIG. 4.

(9) FIG. 9 is an explanatory diagram showing other examples of injection patterns.

(10) FIG. 10 is a front view, with a vertical section on the right side, of a preform molded according to the injection pattern P5 in FIG. 9.

(11) FIG. 11(a) is a front view, and FIG. 11(b) is a vertical section of the peripheral wall, of the bottle biaxially stretched and blow molded from the preform of FIG. 10.

(12) FIG. 12 is a front view of the bottle biaxially stretched and blow molded from the preform molded according to the injection pattern P6 of FIG. 9.

(13) FIG. 13 is a front view of the bottle biaxially stretched and blow molded from the preform molded according to the injection pattern P7 of FIG. 9.

MODE OF CARRYING OUT THE INVENTION

(14) The injection molding device, injection molding process, and bottle of this invention are further described with respect to embodiments, now referring to the drawings. FIGS. 1 and 2 schematically show the injection molding device of this invention, in which FIG. 1 is a vertical section of the device in the portions near the nozzle section 11, and FIG. 2 is a vertical section showing a schematic structure of the mold.

(15) This nozzle section 11 has a first mandrel 21, a second mandrel 22, and a third mandrel 23 disposed in an order of from inside to outside, all of which are cylindrical in shape and are concentric on an axis. A cylindrical shutoff pin 20 is inserted into the first mandrel 21 in a manner capable of sliding upward or downward to perform the function of shutting off or permitting the flow of molten resins at the forefront of the shutoff pin 20. Each mandrel has a tapered portion at the leading end where the diameter is reduced toward the downstream side. A cylindrical outer flow channel 15a through which to flow the main resin Ra is formed between the third mandrel and the second mandrel. A cylindrical inner flow channel 15b through which to flow the second resin Rb is formed between the second mandrel and the first mandrel.

(16) The main resin Ra and the second resin Rb are supplied respectively from resin feeders Sa and Sb, each of which is provided with a screw extruder or an accumulator having a plunger at the tip of the extruder. The resins Ra and Rb are sent to guide channels 12a and 12b, respectively, and are introduced into the outer flow channel 15a or the inner flow channel 15b from inlet ports 13a or 13b through manifolds 14a or 14b.

(17) The main resin Ra passes through a tapered flow channel 15as disposed at the end of the outer flow channel 15a, and through a first confluence 17a, enters a cylindrical column-shaped joined flow channel 19. The second resin Rb passes through a tapered flow channel 15bs disposed at the end of the inner flow channel 15b, and through a second confluence 17b, enters the joined flow channel 19, in which the main resin Ra and the second resin Rb join together to form a joined resin mass. The joined resin mass is injected into, and fills up, a cavity 4 comprising a core mold 2 and a cavity mold 3 of the mold 1, by way of a pin gate 5 disposed at a position corresponding to the center of a bottom wall of a bottom 106 of a preform 101.

(18) The first confluence 17a is at a point where the outer flow channel 15a meets the joined flow channel 19, and the second confluence 17b is at a point where the inner flow channel 15b meets the joined flow channel 19. The first confluence 17a is disposed downstream of the second confluence 17b, with a predetermined space from the second one. Since the confluences are set up in this way, the sliding position of the shutoff pin 20, and especially the position of the forefront 20p thereof, would function so that either or both of the first confluence 17a and/or the second confluence 17b can be opened and/or shut off. The sliding movement (in the upward or downward direction in FIG. 1) of the shutoff pin 20 is controlled by a servo-mechanism using a servo motor (not shown in the drawings).

(19) FIG. 3 are explanatory diagrams showing typical sliding positions of the shutoff pin 20 inside the injection molding device of FIG. 1. In FIG. 3(a), the forefront 20p is located downstream of the first confluence 17a, i.e., at the end of the nozzle section 11, as depicted in FIG. 1. Under this condition, both the first confluence 17a and the second confluence 17b are in a shutoff state. As shown in FIG. 3(b), the forefront 20p is at a position between the first confluence 17a and the second confluence 17b. Under this condition, the first confluence 17a is open, while the second confluence 17b is shut off. Therefore, only the main resin Ra is supplied to the joined flow channel 19. If the forefront 20p is located upstream of the second confluence 17b, as shown in FIG. 3(c), then both the first confluence 17a and the second confluence 17b are in the open state, and both the main resin Ra and the second resin Rb are supplied to the joined flow channel.

(20) The shutting or opening operation for each confluence is controlled by a simple mechanism of linearly sliding the shutoff pin 20. In addition to this mechanism, a servo mechanism is also used to control the sliding movement of the shutoff pin 20, as described above. Thus, the position of the forefront 20p of the shutoff pin 20 can be shifted to any predetermined position accurately with predetermined timing. Therefore, the first confluence 17a and the second confluence 17b can be shut off or opened with a high degree of accuracy. Furthermore, the extent to which the second confluence 17b is opened can be adjusted accurately between a complete shutoff state and a full open state.

(21) Conventionally, the resin supplies have been shut off or opened by check valves or spool valves, which are disposed upstream of the nozzle section at positions remote from the joined flow channel 19. In comparison, this invention enables the molten resin supplies to be shut off or opened at the first confluence 17a and second confluence 17b, which are quite near the joined flow channel 19. Therefore, the shutoff and supplying operations can be controlled with a higher degree of accuracy than in prior art, while avoiding the time lag caused by the viscoelastic properties of the molten resins.

(22) The process of this invention for injection molding the preform by using the above-described injection molding device is now described. FIG. 4 is an explanatory diagram showing injection patterns according to which the preform 101 is injection molded by the injection molding device shown in FIG. 1. Four injection patterns P1 to P4 are shown, taking the horizontal axis as time and the vertical axis as speed of molten resin supply. The pattern for the supply of the main resin Ra is common to these four patterns, and the second resin Rb has different supply patterns.

(23) Descriptions will be made to explain the process for molding the preform based on the injection pattern P1 shown in FIG. 4 and the bottle of this invention made by biaxially stretching and blow molding this preform, now referring to FIGS. 5, 6, and 7. It is premised in the descriptions that the second resin Rb is a colored resin and that a second resin layer or layers 101b is/are a decorative layer or layers. In the case of the pattern P1, the supply of the main resin Ra starts at time ta1, continues at a constant supply velocity Va, and ends at time ta2. The supply of the colored resin Rb starts at time tb1, separated by a delayed time td1 from the start time ta1 for the supply of the main resin Ra, continues at a higher supply velocity Vb1 than the supply velocity Va for the main resin Ra, and ends at time tb2.

(24) FIGS. 5(a)-(c) are schematic explanatory diagrams showing steps of filling the cavity 4 of the mold 1 with molten resins according to the injection pattern P1. FIG. 6 is a front view, with a vertical section in a half, of the preform 101 injection molded under the pattern P1. FIG. 7(a) is a front view, and FIG. 7(b) is a vertical section of peripheral wall of the bottle 201 in an embodiment of this invention, which has been biaxially stretched and blow molded from the preform 101 in FIG. 6. The preform 101 shown in FIG. 6 has a shape of a test tube and comprises a neck 102, a neck ring 103, a body 105, and a bottom 106. The preform has a total height of 100 mm, and the body 105 has an outer diameter of 20 mm and an average wall thickness of 2.5 mm. The peripheral wall comprises an opaque main resin layer 101a made of a PET resin colored in white with a pigment, and decorative layers 101b made of the same PET resin, but colored in red with another pigment, and laminated onto the main resin layer 101a.

(25) For the main resin Ra, the pattern P1 sets a supply time of 4.1 sec and a supply velocity Va of 4.0 ml/sec. For the colored resin Rb, it sets a delayed time td1 of 1.5 sec till the supply start, an injection time of 0.5 sec, and a supply velocity Vb1 of 10.5 ml/sec. FIG. 5(a) shows a situation just before time tb1; FIG. 5(b), just before time tb2; and FIG. 5(c), at time ta2, i.e., a situation in which filling has completed. At the time ta1, the forefront 20p of the shutoff pin 20 shifts from the downstream position of FIG. 3(a) to the middle position of FIG. 3(b) so that the first confluence 17a is opened to supply the main resin Ra at a supply velocity Va. Just before the time tb1, the main resin Ra advances from the bottom 106 of the cavity 4 to a position corresponding to a lower end of the body 105, as shown in FIG. 5(a).

(26) At the time tb1, after the delayed time td1 from the time ta1, the position of the forefront 20p is shifted from the middle position of FIG. 3(b) to the upstream position of FIG. 3(c). At this forefront position, both the first confluence 17a and the second confluence 17b are open. The main resin Ra is supplied at the velocity Va, and the colored resin Rb is supplied at the velocity Vb1, which is higher than Va.

(27) In the state of FIG. 5(a), cooling of the main resin Ra is in progress in the vicinity of mold surfaces facing the cavity 4, and the resin becomes solidified and has an increasingly high level of melting viscosity. However, in the central portion of the cavity 4, remote from the mold surfaces, a high temperature is still maintained by setting the delayed time td1 at 1.5 sec. When supplied at a higher supply velocity Vb1, the colored resin Rb plunges into a central portion of the preceding main resin Ra and breaks through a forefront portion of the preceding main resin Ra. At the time tb2, the second resin partially precedes the main resin Ra, as shown in FIG. 5(b).

(28) Then at the time tb2, the forefront 20p is shifted to the middle position shown in FIG. 3(b). The second confluence 17b is shut off to stop the supply of the colored resin Rb. The supply of only the main resin Ra continues at a velocity of Va. Under this condition, this time in the other way round, the main resin Ra plunges into a central portion and breaks through a forefront portion of the colored resin Rb, and at the time ta2, fills up the rest of the cavity 4, as shown in FIG. 5(c).

(29) From the state of FIG. 5(b), the colored resin Rb is further cooled in the vicinity of mold surfaces facing the cavity 4, but in the central portion of the cavity 4, the colored resin Rb still continues to flow along the cavity walls due to the flow of the main resin Ra. As a result, the colored resin Rb thinly comes in contact with the mold walls of the cavity 4 over a predetermined range, as shown in FIG. 5(c). As seen in the injection molded preform 101 of FIG. 6, the decorative layers 101b are laminated onto the outer and inner peripheral surfaces of the main resin layer 101a in a sandwich configuration in a portion of the body 105 ranging over a roughly lower half height.

(30) FIG. 7(a) shows a bottle 201 obtained by biaxially stretching and blow molding this preform 101. As shown in FIG. 7(b), the vertical section of the peripheral wall has taken over the laminate embodiment from the preform 101 in the lower half portion of a body 205. In this embodiment, a main resin layer 201a is sandwiched between decorative layers 201b, which are laminated onto the inner and outer surfaces of the main resin layer 201a. In this laminate embodiment, one of the decorative layers 201b is laminated onto the outer surface of the main resin layer 201a. Even if the main resin Ra is colored in white and is oblique, the bottle can be decorated with a red-colored decorative layer 201b on the outermost peripheral surface. Conventionally, a colored resin has been laminated as a middle layer embedded in the main resin layer if the preform is injection molded by utilizing a multi-nozzle section to join the main resin with the colored resin. In that case, decoration has not been sufficient if the main resin layer is colored and opaque.

(31) FIGS. 8(a)-(d) are explanatory diagrams showing a comparison of laminate conditions for the preforms molded according to the injection patterns P1 to P4 in FIG. 4. The preforms of FIGS. 8(a) to (d) are based on the patterns P1 to P4, respectively. The patterns P2, P3, and P4 shown in FIG. 4 will be described below in comparison with P1. P2 is a pattern having a longer delayed time td2, as compared to P1. With a longer delayed time td2, the colored resin Rb is supplied after the cavity 4 has been filled with an appreciable amount of the main resin Ra in the stage of FIG. 5(a). If the operation goes at this rate, the area laminated with the decorative layers 101b would come close to the neck ring 103, as shown in FIG. 8(b). In other words, the length of time lag can change the position of the decorative layers 101b laminated with the main resin layer 101a.

(32) P3 is a pattern having a still longer delayed time td3 up to 3.5 sec. With a delayed time this long, the cooling of the main resin Ra proceeds in the area near gate 5 of the cavity 4. Therefore, the colored resin Rb cannot break through the central portion of the main resin Ra. In that case, the decorative layer 101b is laminated as a middle layer embedded in the main resin layer 101a, and shows a laminate condition shown in FIG. 8(c).

(33) P4 is a pattern having a lower supply velocity Vb4 than in P1. The colored resin Rb cannot break through the central portion of, and outrun, the main resin Ra. In this case, too, the decorative layer 101b is laminated as a middle layer embedded in the main resin layer 101a in a portion of the peripheral wall of the preform 101, as shown in FIG. 8(d). Incidentally in this pattern, the position of the area in which to laminate the decorative layer 101b can be shifted by changing the delayed time. Since in the cases of P3 and P4, the decorative layer 101b is laminated as a middle layer, its decorative effect can be achieved by using a transparent type of the main resin layer 101a.

(34) FIG. 9 is an explanatory diagram showing other three injection patterns P5, P6, and P7. In these patterns, the colored resin Rb has supply velocities Vb that are slower than the supply velocity Va for the main resin Ra. In all these cases, the peripheral wall of the preform 101 has the decorative layer 101b laminated as a middle layer embedded in the main resin layer 101a. The pattern P5 resembles P4 of FIG. 4, but has a longer injection time. FIG. 10 shows a decorative layer 101b in the peripheral wall of the preform 101. As shown, the decorative layer 101b ranges from just under the neck ring 103 to a lower end of the body 105, and is laminated with the main resin layers 101a at a substantially uniform layer thickness.

(35) When the preform 101 is molded according to the pattern P5 by using the injection molding device of FIG. 1, the decorative layer 101b is laminated as a middle layer embedded in the main resin layers 101b, and is disposed quite near the inner peripheral wall surface. This feature of the middle layer quite near the inner surface is inherited by the bottle when this preform 101 is biaxially stretched and blow molded into the bottle 201, as shown in FIG. 11. Thus, in the bottle 201 of FIG. 11(a), the decorative layer 201b is a middle layer embedded in the main resin layers 201a, and is disposed quite near the inner peripheral wall surface, as shown in the vertical section of the peripheral wall of FIG. 11(b). If the main resin layer 101a to be used is transparent, then a color shade of this decorative layer 201b would shine through an outer laminated, transparent main resin layer 201a having a sufficient thickness and can offer rich, high-grade decoration. Furthermore, thickness of the decorative layer 101b can be changed by adjusting the supply velocity Vb, which in turn, is changed by adjusting the extent to which the second confluence 17b is opened by the movement of the shutoff pin 20. Color density of the decorative layer can be changed in response to the purpose of decoration for the bottle 201.

(36) According to the pattern 6, the sliding position of the forefront 20p of the shutoff pin 20 is shifted so that the extent to which the second confluence 17b is opened is changed gradually in the opening direction, and along with this change, the supply velocity Vb is increased consistently from the time tb1 to the time tb3. This pattern P6 gives an end product of the bottle 201 such as shown in FIG. 12. In this bottle 201, a color shade caused by the decorative layer 201b creates a gradated pattern of decoration, in which the color density gradually increases downward from the shoulder 204 to a lower end of the body 205. Obviously, the color density can be gradually decreased in a pattern of top-to-bottom gradation, if the extent to which the second confluence 17b is opened is changed gradually in the closing direction.

(37) According to the pattern P7, the sliding position of the forefront 20p of the shutoff pin 20 is shifted periodically in the vicinity of the second confluence 17b in order to change periodically the extent to which the second confluence 17b is opened, so that the decorative layer 101b of the preform 101 would give a pattern of lamination showing periodical changes in the axial direction. As found in FIG. 13, the bottle 201, an end product based on this pattern P7, shows a pattern of decoration in which dark colored zones and light colored zones are alternately disposed. As a variation of P7, the decorative layer 201b is laminated in a zone and not laminated in another zone, with two types of horizontal zones being alternately disposed in the axial direction. This can be achieved by repeating periodically the open state and the shutoff state at the second confluence 17b.

(38) This invention has been described with respect to some embodiments, but it is to be understood that this invention is not construed as being limited to these embodiments. The synthetic resins to be used are not limited to PET resins, but PP resins and other resins that have been conventionally used in biaxially stretched, blow molded bottles can be used as well. The main resin and the colored resin may not always be of the same type, but other types of resins can also be used. In addition, if a high gas barrier resin, such as a nylon resin, is used as a colored resin, the bottle obtained would have color decoration and a high gas barrier property. Furthermore, various laminate embodiments can be achieved by using the second resin layer as, for example, a gas barrier layer, a light shielding layer, or a layer having another function. This feature can be advantageously used to achieve an optimum laminate embodiment and to perform these functions fully.

(39) The inner flow channel 15b for the second resin Rb is not limited to the cylindrical shape. For example, it can be a flow channel in a shape of a thin plate. The second resin Rb running through a thin-plate flow channel forms a strip-shaped decorative zone in the vertical direction over a predetermined range.

INDUSTRIAL APPLICABILITY

(40) According to the preform molding process using the injection molding device of this invention, the decorative layer or layers can be laminated with the main resin layer with a high degree of accuracy in various embodiments. Thus, it is possible to offer bottles having decorations that haven't existed before. Wide applications of use are expected for these bottles.

DESCRIPTIONS OF REFERENCE SIGNS

(41) 1. Mold 2. Core mold 3. Cavity mold 4. Cavity 5. Gate 11. Nozzle section 12a, 12b. Guide channel 13a, 13b. Inlet port 14a, 14b. Manifold 15a. Outer flow channel 15b. Inner flow channel 15as, 15bs. Diameter-reduced flow channel 17a. First confluence 17b. Second confluence 19. Joined flow channel 20. Shutoff pin 20p. Forefront 21. First mandrel 22. Second mandrel 23. Third mandrel Ra. Main resin Rb. Second resin (Colored resin) Sa, Sb. Resin feeder 101. Preform 101a. Main resin layer 101b. Second resin layer (Decorative layer) 102. Neck 103. Neck ring 105. Body 106. Bottom 201. Bottle 201a. Main resin layer 201b. Decorative layer 202. Neck 203. Neck ring 204. Shoulder 205. Body 206. Bottom