CRYOGENIC CONTAINER WITH THERMAL BRIDGE SWITCH
20240418320 ยท 2024-12-19
Inventors
Cpc classification
F17C2205/0332
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0316
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/031
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/054
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2221/012
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0629
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/0168
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/046
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0308
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/066
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0391
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/0109
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/0473
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C13/001
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/056
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/043
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E60/32
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F17C2223/033
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/032
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/065
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/0631
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/043
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/032
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2227/0355
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0161
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2205/0352
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/023
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A cryogenic container, in particular a hydrogen container, including an inner container and an outer container enclosing the inner container, with a cooling layer being arranged between the inner container and the outer container, the cooling layer enveloping the inner container at least partially and being insulated with respect to both the inner container and the outer container, with a removal line being routed through the inner container as well as through the cooling layer and the outer container, thereby passing through them, where the device comprises a thermal bridge switch configured to establish a contact between the cooling layer and the removal line in a closed position so as to form a thermal bridge and further configured to separate the cooling layer from the removal line in an opened position so as to eliminate the thermal bridge.
Claims
1-10. (canceled)
11. A device comprising a cryogenic container, in particular a hydrogen container, comprising an inner container and an outer container enclosing the inner container, with a cooling layer being arranged between the inner container and the outer container, the cooling layer enveloping the inner container at least partially and being insulated with respect to both the inner container and the outer container, with a removal line being routed through the inner container as well as through the cooling layer and the outer container, thereby passing through them, and wherein the device comprises a thermal bridge switch configured to establish a contact between the cooling layer and the removal line in a closed position so as to form a thermal bridge and further configured to separate the cooling layer from the removal line in an opened position so as to eliminate the thermal bridge.
12. A device according to claim 11, wherein the cooling layer is a rigid metal shield, or a single-layer or multi-layer metal foil, and has a greater thickness at end caps of the cryogenic container than at an area between the end caps.
13. A device according to claim 11, furthermore comprising a control unit which is configured to close the thermal bridge switch when cryogenic fluid is removed from the cryogenic container via the removal line and is further configured to open the thermal bridge switch as soon as the removal of cryogenic fluid from the cryogenic container via the removal line is stopped, wherein the control unit closes the thermal bridge switch not only when an active removal of cryogenic fluid from the removal line exists, but also when boil-off gas escapes through the removal line.
14. A device according to claim 13, wherein the control unit is configured to close the thermal bridge switch after a predetermined period of time upon completion of the removal, and/or wherein the control unit is configured to determine a hold time of the cryogenic container, the hold time being a time span from the end of the removal until a point in time at which the pressure in the cryogenic container reaches a predefined threshold, with the control unit being configured to close the thermal bridge switch when the hold time is reached upon completion of the removal.
15. A device according to claim 13, wherein a pressure relief valve is provided in the removal line or in a boil-off line connected to the removal line or routed into the cryogenic container, and a control line is routed from the pressure relief valve to the control unit via which the triggering of the pressure relief valve can be indicated, and the control unit is configured to close the thermal bridge switch when the pressure relief valve is opened.
16. A device according to claim 11, wherein the thermal bridge switch comprises a connecting element made of metal, which comprises a copper mesh surrounding the removal line in the closed state of the thermal bridge switch, wherein the connecting element is connected only to the cooling layer in the opened state of the thermal bridge switch and is connected to both the cooling layer and the removal line in the closed state, or vice versa.
17. A device according to claim 11, furthermore comprising a boil-off line comprising a valve that opens at a predetermined overpressure, wherein the boil-off line is in a heat-conducting connection with the cooling layer at least over a length of 0.2 m, 0.5 m or 0.8 m, and has a cross-sectional area which corresponds to at most half of the cross-sectional area of the removal line, wherein the boil-off line has a diameter of a maximum of 10 mm, a maximum of 6 mm, or a maximum of 4 mm.
18. A device according to claim 1, wherein the cryogenic container has a longitudinal axis which forms an axis of rotation of the cryogenic container, with the removal line passing through an end cap arranged essentially normal to the longitudinal axis or through a jacket of the cryogenic container that is located between end caps.
19. A vehicle comprising an engine and a device according to claim 11, wherein the removal line is connected to the engine for supplying cryogenic fluid as a fuel for the engine.
20. A non-transitory storage medium for a device according to claim 11, and the non-transitory storage medium having stored therein instructions that are executable by one or more hardware processors to perform operations comprising: opening the thermal bridge switch when no cryogenic fluid flows through the removal line; and closing the thermal bridge switch when cryogenic fluid flows through the removal line, at least when cryogenic fluid is actively removed through the removal line and also when cryogenic fluid is discharged from the cryogenic container through the removal line after a predetermined maximum pressure has been reached in the cryogenic container via the removal line.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0025] Advantageous and non-limiting embodiments of the invention are explained in further detail below with reference to the drawings.
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
DETAILED DESCRIPTION
[0032]
[0033] In order to keep the cryogenic fluid at low temperatures for as long as possible and to reduce the heat input into the cryogenic container 2, the cryogenic container 2 has an inner container 5 and an outer container 6 spaced apart therefrom on all sides. A vacuum can thereby be provided between the inner container 5 and the outer container 6.
[0034] Furthermore, the cryogenic container 2 comprises a cooling layer 7 that is known per se and is insulated both with respect to the inner container 5 and with respect to the outer container 6. In the simplest case, the cooling layer 7 is a rigid, i.e., self-supporting, metal shield, e.g., a metal sheet which is appropriately spaced apart from the inner container 5 and the outer container 6. The insulation of the metal shield with respect to the inner container 5 and the outer container 6 is thereby effected via the aforementioned vacuum. The cooling layer 7 can be a single layer or a multi-layer element such as an MLI (multi-layer insulation) wherein several metal foils, usually aluminium foils, are separated by poorly heat-conducting intermediate layers such as paper layers, glass fibre layers, etc. In a further embodiment, the cooling layer 7 can be a carbon layer vapour-plated with aluminium or a textile made of aluminium wire and/or glass fibre coated with aluminium. Therefore, the cooling layer 7 typically comprises metal for heat conduction, although other materials could also be used.
[0035] According to the invention, the cooling layer 7 serves, on the one hand, as a radiation shield and, on the other hand, as a thermal storage. If the cooling layer 7 is at the temperature of the cryogenic fluid, the cooling layer 7 will heat up first, before the cryogenic fluid heats up, in the event of heat being introduced from the outside. For this reason, it is also preferred if the thermal mass of the cooling layer 7 is as large as possible. For example, as mentioned above, the cooling layer 7 can be designed for this purpose as a rigid metal shield, i.e., as a metal sheet and in particular as an aluminium sheet or a copper sheet with a thickness of at least 0.1 mm, preferably of at least 0.5 mm, preferably of essentially 0.75 mm. For example, an aluminium sheet with a total mass of 10-20 kg can be used. Particularly preferably, for increasing the thermal mass, the cooling layer 7 can have a thickness also at end caps 8 of the cryogenic container 2 that is greater than at an area between the end caps 8. For example, a rigid metal shield can have a thickness of 0.75 mm in the jacket area and a thickness of 3 mm in the end cap area, wherein the transition can be continuous. The area between the end caps 8 is usually designed as a jacket 9 extending in the direction of a longitudinal axis L of the cryogenic container 2.
[0036] As a result of the thermal conductivity of the cooling layer 7, especially if it is made of aluminium or copper, heat introduced at any point can be distributed quickly across the entire cooling layer 7. Due to the insulation of the cooling layer 7 with respect to the inner container 5 and the outer container 6, it can thus be said that the thermal conductivity of the cooling layer 7 around the circumference of the cryogenic container 2 is significantly greater than into the cryogenic container 2, for example, at least 100,000 times or at least 1,000,000 times greater.
[0037] The cryogenic container 2 described herein is usually used as a fuel tank of a vehicle (not illustrated any further) and can be mounted for this purpose, for example, on the vehicle frame of the vehicle. For supplying the cryogenic fluid as a fuel to an engine of the vehicle, a removal line 10 is routed into the cryogenic container 2. The removal line 10 thereby passes through the cryogenic container 2, i.e., the removal line 10 passes through the inner container 5, the outer container 6 and the cooling layer 7 located between them. If the cooling layer 7 does not completely enclose the inner container 5, if it has, for example, an annular recess in the middle of the cryogenic container 2, the removal line 10 could be routed from the inner container 5 to the outer container 6 also in the area of the recess, which is herein understood to mean that the removal line 10 passes through the cooling layer 7.
[0038] As shown in
[0039] It is apparent from
[0040] The thermal bridge switch 11 enables that no thermal bridge exists between the cooling layer 7 and the removal line 10 in the opened state. The purpose of this is that, after heating, the cooling layer 7 should not transfer the heat directly to the cryogenic fluid via the removal line 10 or, respectively, the removal line 10 should transfer it directly from the outer container 6 into the cooling layer 7. For example, the vehicle with the cryogenic container 2 can be switched off. The heat input from the outside now heats the cooling layer 7, however, due to the opened thermal bridge switch 11, this heat is not released directly to the removal line 10 and thus to the cryogenic fluid. As a result, it is possible to increase the time after which the cryogenic fluid in the cryogenic container 2 reaches a certain temperature and thus a certain pressure upon completion of the final removal.
[0041] In the closed state, the thermal bridge switch 11 allows cryogenic fluid emerging from the cryogenic container 2 to absorb heat from the cooling layer 7, thus discharging it from the cryogenic container 2. The closing of the thermal bridge switch 2 thus serves for cooling the cooling layer 7. It is evident that the thermal bridge switch should only be closed if cryogenic fluid flows through the removal line 10.
[0042] The thermal bridge switch 11 is thus movable between the closed position and the opened position. For example, the thermal bridge switch 11 can thereby be operated manually, e.g., a user of the vehicle can open the thermal bridge switch 11 after ending the journey with the vehicle and can close the thermal bridge switch 11 at the start of the journey.
[0043] Alternatively or additionally, the thermal bridge switch 11 can be opened and closed automatically. For example, the thermal bridge switch 11 can be designed as a normally open switch, and a control line of the thermal bridge switch 11 can be connected to the engine, electronics of the vehicle and/or electronics of the cryogenic container 2 (which, for example, controls an economizer and/or a pressure management system of the cryogenic container 2). If a signal indicating the operation of the vehicle and thus the removal of cryogenic fluid from the cryogenic container 2 is now applied to the control line, a current is applied to the thermal bridge switch 11, whereby said switch is closed. For this purpose, a switching logic, which can be regarded as a simple control unit, can be implemented in the thermal bridge switch 11.
[0044]
[0045] With reference to
[0046] In the example illustrated in
[0047] At the point in time t1 of the completion of the removal of cryogenic fluid from the cryogenic container 2, the thermal bridge switch 11 is opened in order to prevent heat absorbed by the cooling layer 7 from being released to the cryogenic fluid located in the cryogenic container 2. If the thermal bridge switch 11 were closed, heat would additionally be introduced into the cooling layer 7 through the connection path supplementary in the closed state, namely thermal bridge switchremoval lineinner container, or respectively, through the path outer containerremoval linethermal bridge switch, whereby heating would occur more quickly than with the thermal bridge switch being opened, which is due to the freedom of local attachment as created by the thermal bridge switch 11. However, it is evident from
[0048] It can preferably be envisaged that the thermal bridge switch 11 re-closes at point in time t2, as illustrated in
[0049] It can be summarized that the thermal bridge switch 11 can close when the pressure in the cryogenic container 2 reaches a predefined threshold. This can be implemented in various ways, for example via a sensor on the pressure relief valve which detects the opening of the pressure relief valve. For example, the pressure relief valve can directly generate a mechanical, electrical or hydraulic signal which closes the thermal bridge switch 11, if necessary also without a control unit 12. Alternatively or additionally, various assumptions can be made, and the control unit 12 can open the thermal bridge switch 11 after a predetermined time span upon completion of the removal, for example, a specific numerical value for the expected time span t1-t2 can be stored in advance in the control unit 12.
[0050] Furthermore, the control unit 12 can be designed for determining a hold time of the cryogenic container 2, the hold time being the time span from the end of the removal to the point in time at which the pressure in the cryogenic container 2 reaches a predefined threshold, with the control unit 12 being designed for closing the thermal bridge switch 11 when the hold time is reached upon completion of the removal. For example, during the journey, i.e., during the period of time t0-t1, the control unit 12 continuously determines the current hold time, which can be calculated, for example, from the current fill level, pressure and/or temperature, for which purpose the control unit 12 can receive appropriate measured values via a measured value line 15. In case the control unit 12 now determines at the point in time t1 that the removal has been finished, the control unit 12 can use the last determined hold time and can open the thermal bridge switch 11 after this time.
[0051] In the embodiments in which the control unit 12 opens the thermal bridge switch 11 after a predetermined or, respectively, calculated time span, it is advantageous that essentially no current is required over the period of time t1-t2. Actually, as a rule, no current will be available over the period of time t1-t2, since the vehicle is switched off and not in operation during this period of time. The current necessary for opening the thermal bridge switch 11 at the point in time t2 can be provided, for example, via a capacitance or the like. In these embodiments, the thermal bridge switch 11 is closed at the point in time t2 and, for example, remains closed indefinitely, which is indicated by the dashed line. In this case, the advantages of cooling using the boil-off gas outweigh the disadvantages of the heat input through the negative thermal bridge present from point in time t3, via the thermal bridge switch 11.
[0052] In another embodiment, the control unit 12 could also be supplied with power after point in time t1, via a battery, for example. In this embodiment, the control unit 12 could, for example, continuously receive measured values about a pressure in the cryogenic container 2 and could actuate the thermal bridge switch 11 specifically, i.e., could close the thermal bridge switch 11 over the period of time t2-t3 or, respectively, t4-t5 in case of an escape of boil-off gas and could open it over a period of time t3-t4, since, at this point in time, no cooling boil-off gas escapes, which is illustrated in
[0053] Even if no power is available, the aforementioned control unit 12 can be implemented, for example, if the control unit 12 comprises a pneumatic control line which is connected to the thermal bridge switch 11 and the cryogenic container 12 or, respectively, the pressure relief valve 14 and which closes the thermal bridge switch 11 as soon as or, respectively, shortly before or shortly after the maximum permissible pressure p.sub.max is/has been reached, and wherein the pneumatic control line re-opens the thermal bridge switch 11 if the pressure drops below a predetermined pressure or a predetermined time span has been reached.
[0054] In all the aforementioned embodiments, a computer, which is preferably implemented in the above-mentioned control unit 12, can be designed for running a computer program which actuates the thermal bridge switch 11 as follows: [0055] opening the thermal bridge switch 11 when no cryogenic fluid flows through the removal line 10; [0056] closing the thermal bridge switch 11 when cryogenic fluid flows through the removal line 10, at least when cryogenic fluid is actively removed through the removal line 10 and preferably also when cryogenic fluid is discharged from the cryogenic container 2 through the removal line 10 after a predetermined maximum pressure has been reached in the cryogenic container 2 via the removal line 10.
[0057] As already mentioned above, the thermal bridge switch 11 can be designed in a variety of ways. In particular, the thermal bridge switch 11 can comprise a connecting element made of metal, which can swivel as shown in
[0058] Usually, it is envisaged that the connecting element is connected only to the cooling layer 7 in the opened state of the thermal bridge switch 11 and is connected to both the cooling layer 7 and the removal line 10 in the closed state, or vice versa. Furthermore, it would also be possible for the connecting element to be separated from both the cooling layer 7 and the removal line 10 in the opened state.
[0059]
[0060] In order to design the device in a structurally particularly simple manner, it can also be envisaged that the thermal bridge switch 11 will not close after the active removal has ended, if boil-off gas escapes. In these cases, a boil-off line 18 separate from the removal line 10 and comprising a valve 19 could be provided, as schematically shown in
[0061] Moreover, it is evident from
[0062]
[0063] Such embodiments with a separate boil-off line 18 could also be designed without a thermal bridge switch 11. In this case, it is preferably envisaged that the removal line 10 is always insulated with respect to the cooling layer 7, i.e., that there is no thermal bridge between this removal line 10 and the cooling layer 7, with the removal line 10 being routed through the cooling layer 7 over the shortest possible distance, for example, perpendicular through it. In summary, this results in a device 1 comprising a cryogenic container 2, in particular a hydrogen container, comprising an inner container 5 and an outer container 6 enclosing the inner container 5, with a cooling layer 7 being arranged between the inner container 5 and the outer container 6, the cooling layer enveloping the inner container 5 at least partially and being insulated with respect to both the inner container 5 and the outer container 6, with a removal line 10 being routed through the inner container 5 as well as through the cooling layer 7 and the outer container 6, thereby passing through them, furthermore comprising a boil-off line 18 separate from the removal line 10 and comprising a valve 19 that opens at a predetermined overpressure, wherein the boil-off line 18 is attached to the removal line 10 in the insulated area between the inner container 5 and the outer container 6 and is routed through the inner container 5 as well as through the cooling layer 7 and the outer container 6, thereby passing through them, and is connected to the cooling layer 7 at least over a length of 0.2 m, 0.5 m or 0.8 m and has a cross-sectional area which corresponds at most to half of the cross-sectional area of the removal line and/or wherein the diameter of the boil-off line is preferably a maximum of 10 mm, a maximum of 6 mm or a maximum of 4 mm.