PHOTOVOLTAIC TOP MODULE
20250006855 ยท 2025-01-02
Assignee
Inventors
Cpc classification
H10F19/807
ELECTRICITY
H10F19/902
ELECTRICITY
International classification
H01L31/05
ELECTRICITY
Abstract
In accordance with one or more embodiments herein, a method of manufacturing a photovoltaic (PV) top module, to be used together with a PV bottom module, e.g. an SI-based PV bottom module, is provided. The method may include monolithically interconnecting a plurality of thin film based PV sub-cells, manufactured using a perovskite material and/or a CIGS material as solar absorbing material, in series on a substrate in order to create a PV top module including at least one first PV top sub-module, and arranging metal grid lines on top and bottom contact layers of the PV top module. The metal grid lines may be arranged either above or below the top and bottom contact layers of the PV top module.
Claims
1. A tandem photovoltaic module comprising: a top photovoltaic module including: a substrate; a first metal grid line residing over the substrate; a first transparent electrode material residing over the first metal grid line; a thin-film layer residing over the first transparent electrode material; a second transparent electrode material residing over the thin-film layer; a second metal grid line residing over the second transparent electrode material; a monolithic serially connected thin-film photovoltaic sub-cell residing within the thin-film layer, the sub-cell including: a solar absorbing material including perovskite, CIGS or a combination thereof; a bottom photovoltaic module including a silicon sub-cell; and an electrical parallel connection between the top and bottom photovoltaic modules.
2. The tandem photovoltaic module of claim 1, wherein the tandem photovoltaic module includes at least two output terminals.
3. The tandem photovoltaic module of claim 1, wherein: the sub-cell has a width in a range of 10-40 mm; and the top photovoltaic module has a width in a range of 80-120 cm.
4. The tandem photovoltaic module of claim 1, wherein the first metal grid line and second metal grid line have been formed using a photolithography method.
5. The tandem photovoltaic module of claim 1, wherein: an output voltage of the top photovoltaic module is in a range of 30-50 V; and an output voltage of the bottom photovoltaic module is in a range of 30-50 V.
6. The tandem photovoltaic module of claim 1, wherein the first grid line and the second grid line are partially aligned with each other.
7. The tandem photovoltaic module of claim 1, wherein the first grid line and the second grid line are wholly aligned with each other.
8. The tandem photovoltaic module of claim 1, wherein the first grid line and the second grid line are aligned by overlapping by at least one half a gridline width.
9. The tandem photovoltaic module of claim 1, wherein the thin-film layer is a semi-transparent material.
10. The tandem photovoltaic module of claim 1, wherein the substrate also a protective cover for the bottom photovoltaic module.
11. The tandem photovoltaic module of claim 10, wherein the protective cover is coated on the inside.
12. A tandem photovoltaic module comprising: the top photovoltaic module including: a width in a range of 80-120 cm; a substrate; a first metal grid line residing over the substrate; a first transparent electrode material residing over the first metal grid line; a semi-transparent thin-film layer residing over the first transparent electrode material; a second transparent electrode material residing over the thin-film layer; a second metal grid line residing over the second transparent electrode material; a monolithic serially connected thin-film photovoltaic sub-cell residing within the thin-film layer, the sub-cell including: a solar absorbing material including perovskite, CIGS or a combination thereof; a width in a range of 10-40 mm; the bottom photovoltaic module including a silicon sub-cell; and an electrical parallel connection between the top and bottom photovoltaic modules.
13. The tandem photovoltaic module of claim 12, wherein the photovoltaic module includes two output terminals.
14. The tandem photovoltaic module of claim 12, wherein: an output voltage of the top photovoltaic module is in a range of 30-50 V; and an output voltage of the bottom photovoltaic module is in a range of 30-50 V.
15. The tandem photovoltaic module of claim 12, wherein the first metal grid line and second metal grid line have been formed using a photolithography method.
16. The tandem photovoltaic module of claim 12, wherein the first grid line and the second grid line are partially aligned with each other.
17. The tandem photovoltaic module of claim 12, wherein the first grid line and the second grid line are wholly aligned with each other.
18. The tandem photovoltaic module of claim 12, wherein the first grid line and the second grid line are aligned by overlapping by at least one half a gridline width.
19. The tandem photovoltaic module of claim 12, wherein the substrate is a protective cover for the bottom photovoltaic module and the protective cover is coated on the inside.
20. A tandem photovoltaic module comprising: the top photovoltaic module including: a width in a range of 80-120 cm; a top output terminal; an output voltage in a range of 30-50 V; a cover glass that is coated on the inside; a first metal grid line residing over the cover glass; a first transparent electrode material residing over the first metal grid line; a semi-transparent thin-film layer residing over the first transparent electrode material; a second transparent electrode material residing over the thin-film layer; a second metal grid line residing over the second transparent electrode material; a monolithic serially connected thin-film photovoltaic sub-cell residing within the thin-film layer, the sub-cell including: a solar absorbing material including perovskite, CIGS or a combination thereof; a width in a range of 10-40 mm; the bottom photovoltaic module including: a bottom output terminal; an output voltage of 30-50 V; a silicon sub-cell; and an electrical connection between the top and bottom photovoltaic modules.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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[0041] Embodiments of the present disclosure and their advantages are best understood by referring to the detailed description that follows. It should be appreciated that like reference numerals are used to identify like elements illustrated in one or more of the figures.
DETAILED DESCRIPTION
[0042] The present disclosure relates generally to PV top modules, and methods for manufacturing PV top modules. Embodiments of the disclosed solution are presented in more detail in connection with the figures.
[0043] According to the disclosure, a PV bottom module comprising Si-based PV sub-cells is connected in parallel with a PV top module comprising thin film based PV sub-cells. In this way, a regular PV bottom module comprising Si-based PV sub-cells and a cover glass may be used, by simply arranging a thin film based PV top module on the inside of the cover glass. The thin film based PV top module may also be called a PV power booster, since it boosts the power of the Si-based PV bottom module. This may significantly increase the efficiency of the Si-based PV bottom module, possibly by up to 50%. The solar absorbing material of the thin film based PV sub-cells is preferably a perovskite material and/or a CIGS material.
[0044] A perovskite material is a material with a three-dimensional crystal structure related to that of CaTiO.sub.3, or a material comprising a layer of material, wherein the layer has a structure related to that of CaTiO.sub.3. The structure of CaTiO.sub.3 can be represented by the formula ABX.sub.3, wherein A and B are cations of different sizes and X is an anion. In the unit cell, the A cations are at (0,0,0), the B cations are at (, , ) and the X anions are at (, , 0). The A cation is usually larger than the B cation. The skilled person will appreciate that when A, B and X are varied, the different ion sizes may cause the structure of the perovskite material to distort away from the structure adopted by CaTiO.sub.3 to a lower-symmetry distorted structure. The symmetry will also be lower if the material comprises a layer that has a structure related to that of CaTiO.sub.3. Materials comprising a layer of perovskite material are well known. For instance, the structure of materials adopting the K.sub.2NiF.sub.4-type structure comprises a layer of perovskite material. The skilled person will appreciate that a perovskite material can be represented by the formula [A][B][X].sub.3, wherein [A] is at least one cation, [B] is at least one cation and [X] is at least one anion. The symmetry of a perovskite comprising more than one A cation, more than one B cation or more than one X cation, will be lower than that of CaTiO.sub.3. A large number of different elements can form perovskite crystal structures. Perovskites that may be used as solar absorbing material in PV applications are typically inorganic-organic halide perovskites where [A] is typically methylammonium, formamidinium or Cs (or a mixture of these), [B] is typically Pb or Sn (or a mixture of these), and [X] is typically one or more elements from the halogen group, such as e.g. I, Br or Cl.
[0045] A CIGS material is a material in the material class chalcogenides having a crystal structure of the type chalcopyrite. CIGS materials may be represented by the formula Cu.sub.x(In.sub.1-y,Ga.sub.y)Se.sub.2, where x and y may be varied. The value of x should preferably be close to 1, such as e.g. between 0.7 and 0.95, but is preferably not higher than 1. Different values of y give different band gap in the material. It is possible to substitute some of the Cu with Ag, and such a CIGS material (sometimes called ACIGS) may be represented by the formula (Cu.sub.1-z,Ag.sub.z).sub.x(In.sub.1-y,Ga.sub.y)Se.sub.2. The Se may also, partly or completely, be replaced with S, and the In and/or Ga may, partly or completely, be replaced with Al. Moreover, small amounts of other elements, such as for example alkali metals (Na, K, Rb, Cs), may also be added.
[0046] The band gap of the Si material of the PV bottom module is normally 1.1 eV. In order for the efficiency of the tandem module to be as high as possible, it is advantageous if the band gap of the solar absorbing material in the thin film PV top module is higher than 1.3 eV, and more preferably higher than 1.5 eV. Both perovskites and CIGS-based materials can be synthesized to have band gaps in this range, while maintaining a high conversion efficiency, by tuning their composition appropriately. These materials are therefore particularly suitable to be used as solar absorbing material in the disclosed thin film based PV top module.
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[0052] A PV module 100 may comprise such an Si-based PV bottom module 110 and such a thin film based PV top module 120, where the thin film based PV top module 120 is stacked onto the Si-based PV bottom module 110, and the Si-based PV bottom module 110 and thin film based PV top module 120 are connected in parallel within the PV module 100. This means that the PV module 100 only comprises two output terminals. The cell width of the monolithically integrated thin film based PV sub-cells may be adapted in order to adjust the output voltage of the thin film based PV top module 120 to be similar to the output voltage of the Si-based PV bottom module 110, e.g. to a cell width of 10-40 mm, preferably 20-30 mm, for a module width of 80-120 cm.
[0053] A typical Si-based sub-cell with crystalline Si has an output voltage of about 0.5-0.7 V, and a number of such Si-based sub-cells are typically connected in series into an Si-based PV bottom module 110 having an output voltage of about 30-50 V. Since the PV top module 120 and the PV bottom module 110 are preferably connected in parallel, they preferably have similar output voltages. This may be achieved by adapting the cell width of the monolithically integrated thin film PV sub-cells in the PV top module 120 (thereby affecting the total number of thin film PV sub-cells in series). With a standard cell width of the monolithically integrated thin film PV sub-cells of about 5 mm, the output voltage of a thin film based PV top module 120 is normally much higher than 30-50 V. This is especially true for perovskite materials and CIGS materials suitable for being combined with Si-based PV bottom modules, as they are high-efficiency high band gap absorbers where the monolithic interconnection requires quite narrow thin film based PV sub-cells, in order for the parasitic resistive power loss not to be too large. For such materials, it is difficult to match the voltage of the thin film PV top module 120 with that of the Si PV bottom module 110, since for a thin film PV top module 120 to have the same width as a Si PV bottom module 110, there will be a much larger number of thin film based PV sub-cells than there are Si-based PV sub-cells in the Si PV bottom module 110. The metal grid lines improve the conductivity of the electrode material arranged on the thin film layer of the thin film based PV sub-cells, and thereby enable the use of wider thin film based PV sub-cells. The metal grid lines may be arranged either above or below the electrode material arranged on the thin film layer of the thin film based PV sub-cells.
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[0055] A PV module 100 may comprise any number of such parallel connected thin film based PV top sub-modules 130, 135, each connected in parallel with the Si-based PV bottom module 110 within the PV module 100.
[0056] This means that the PV module 100 only comprises two output terminals. In this way, each of the thin film based PV top sub-modules 130, 135 may be arranged to have the same output voltage as the Si-based PV bottom module 110. At the boundary between the thin film based PV top sub-modules 130, 135, there may be a non-active region (so called dead area). Such a dead area is preferably aligned with an existing dead area of the Si-based PV bottom module 110.
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[0059] In each of the illustrated embodiments, a top contact layer is created by a first layer of a transparent electrode material 124 being arranged onto the substrate 115 before the thin film layer 125 is arranged, and a bottom contact layer is created by a second transparent electrode material 126 being arranged onto the thin film layer 125. The transparent electrode materials 124, 126 are preferably transparent conducting oxide (TCO) materials such as e.g. indium tin oxide (ITO), doped zinc oxide (e.g. ZnO:Al) or doped indium oxide (e.g. In.sub.2O.sub.3:Zn, In.sub.2O.sub.3:W, or In.sub.2O.sub.3:H), and the layers 124, 126 may thus be called TCO layers. In order to separate the thin film based PV sub-cells from each other, isolation is arranged between the thin film based PV sub-cells, and between the TCO layers 124, 126 on different thin film based PV sub-cells. Further, connecting contacts 122 are arranged in order to series connect the thin film based PV sub-cells with each other.
[0060] In the embodiments schematically illustrated in
[0061] In the embodiment schematically illustrated in
[0062] In the embodiment schematically illustrated in
[0063] There is always a trade-off between the conductivity and the transparency of the TCO layers 124, 126. To avoid resistive losses when using wide cells in the thin film based PV top module 120, the TCO layers 124, 126 would have to be very thick and thereby have a lower transparency, which leads to reduced solar cell efficiency. To overcome these difficulties, metal grid lines 123, 127 are arranged on the top 124 and bottom 126 contact layers of the PV top module 120, in order to allow for wider cells and thereby lower the output voltage of the thin film based PV top module 120 without any major loss in efficiency. The metal grid lines 123, 127 may be arranged either above or below the top 124 and bottom 126 contact layers of the PV top module 120. The metal grid lines 123, 127 improve the conductivity of the top 124 and bottom 126 contact layers of the PV top module 120, and thereby enable the use of wider thin film based PV sub-cells. The metal grid lines 123, 124 may e.g. be defined using a photolithography method, and they are preferably aligned with each other, in order to reduce the loss caused by the shadowing of the grid lines. The alignment does not have to be perfectas long as at least a part of the grid lines are aligned, such as e.g. half the grid line width, this will reduce grid shadowing. The photolithography method may e.g. be the photolithography method described in WO2019164444 or WO2019164443, but other photolithography methods may also be used. The metal grid lines may alternatively be deposited in other ways, such as e.g. using screen-printing or by deposition through a shadow mask. In addition, since the Si-based cells of the Si-based PV bottom module 110 typically also have grid lines, it is advantageous if the grid lines of the thin film based PV top module 120 are at least partly aligned with the grid lines on the Si-based cells of a typical Si-based PV bottom module 110.
[0064] In the embodiments schematically illustrated in
[0065] In the embodiments schematically illustrated in
[0066] In the embodiment schematically illustrated in
[0067] In the embodiments schematically illustrated in
[0068] The metal layers 123, 127 are preferably arranged in the form of metal grid lines 123, 127. This may be achieved e.g. using photolithography. It is preferred for the metal grid lines 123, 127 to be aligned with each other in order to reduce the loss in efficiency due to grid shadowing. The alignment does not have to be perfectas long as at least a part of the metal grid lines 123, 127 are aligned, such as e.g. half the grid line width, this will reduce grid shadowing. The photolithography method may e.g. be the photolithography method described in WO2019164444 or WO2019164443, but other photolithography methods may also be used. The metal grid lines may however alternatively be deposited in other ways, such as e.g. using screen-printing or by deposition by PVD or evaporation in vacuum through a shadow mask.
[0069] The metal grid lines may be arranged in any suitable pattern, as long as they connect the thin film based PV sub-cells with each other. If the thin film based PV sub-cells are arranged in a row, as illustrated in
[0070] In addition to the layers illustrated in
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[0075] Step 910: monolithically interconnecting a plurality of thin film based PV sub-cells, manufactured using a perovskite material and/or a CIGS material as solar absorbing material, in series on a substrate 115 in order to create a PV top module 120 comprising at least one first PV top sub-module 130.
[0076] Step 960: arranging metal grid lines 123, 127 on top 124 and bottom 126 contact layers of the PV top module 120. The metal grid lines 123, 127 may be arranged either above or below the top 124 and bottom 126 contact layers.
[0077] The arranging 960 of the metal grid lines may comprise defining the metal grid lines 123, 127 using a photolithography method. The arranging 960 may comprise aligning the metal grid lines 123, 127 on the top 124 and bottom 126 contact layers of the PV top module 120 with each other. The alignment does not have to be perfectas long as at least a part of the grid lines are aligned, such as e.g. half the grid line width, this will reduce grid shadowing.
[0078] The method 900 may further comprise one or more of:
[0079] Step 920: coating the PV top module 120 on the inside of a cover glass 115 for a PV bottom module 110, using the cover glass as the substrate 115.
[0080] Step 930: manufacturing the thin film based second PV sub-cells to be semi-transparent, preferably by being as transparent as possible for photon energies below the band gap of the solar absorbing material used in the thin film based PV sub-cells.
[0081] Step 940: monolithically interconnecting a plurality of thin film based PV sub-cells, manufactured using a perovskite material and/or a CIGS material as solar absorbing material, in series on a substrate 115, in an area beside the first PV top sub-module 130, in order to create at least one additional PV top sub-module 135 beside the first PV top sub-module 130.
[0082] Step 950: connecting each additional PV top sub-module 135 in parallel with the first PV top sub-module 130 within the PV top module 120.
[0083] Step 970: series connecting a plurality of Si-based PV sub-cells in order to create a PV bottom module 110.
[0084] Step 975: adapting the cell width 160 of the thin film based monolithically integrated PV sub-cells in order to adjust the output voltage of the PV top module 120 to be similar to the output voltage of the PV bottom module 110, e.g. to a cell width 160 of 10-40 mm, preferably 20-30 mm, for a module width of 80-120 cm.
[0085] Step 980: stacking the PV top module 120 on the PV bottom module 110.
[0086] Step 990: connecting the PV bottom module 110 and the PV top module 120 in parallel to thereby create a PV module 100, where the PV module 100 only comprises two output terminals.
[0087] In such a method, the arranging 960 of the metal grid lines may comprise aligning the metal grid lines 123, 127 on the top 124 and/or bottom 126 contact layers of the PV top module 120 with metal grid lines on the Si-based PV sub-cells of the PV bottom module 110. The alignment does not have to be perfectas long as at least a part of the grid lines are aligned, such as e.g. half the grid line width, this will reduce grid shadowing.
[0088] The first PV top module 120 and the PV bottom module 110 are preferably laminated together.
[0089] Some of these steps are in practice carried out simultaneously. For example, steps 920, 930 and 940 are typically carried out simultaneously with step 910.
[0090] The above described method 900 may be performed by an arrangement comprising automation tools for e.g. placing, interconnecting, and/or stringing Si solar cells, thin film deposition equipment utilizing technologies like e.g. sputtering, thermal evaporation, e-beam evaporation, atomic layer deposition, chemical vapor deposition and/or different chemical solution-based approaches, and tools for patterning the thin films using e.g. mechanical and/or laser scribing. If a metal grid is used, the arrangement may further comprise equipment for depositing a metal grid e.g. using photolithography, screen-printing or by deposition through a shadow mask. The arrangement may further comprise tools for laminating the sub-modules together, and/or various tools for testing the resulting PV modules.
[0091] The foregoing disclosure is not intended to limit the present invention to the precise forms or particular fields of use disclosed. It is contemplated that various alternate embodiments and/or modifications to the present invention, whether explicitly described or implied herein, are possible in light of the disclosure. The disclosure describes a number of different embodiments, but further embodiments are of course also covered by the scope of the claims. Further, the steps may be carried out in any order that makes technical sense, and some steps may be carried out simultaneously. Accordingly, the scope of the invention is defined only by the claims.