FOOTWEAR ITEM, IN PARTICULAR FOR PRACTISING A SPORT

Abstract

The present invention relates to a footwear article (10), comprising: a upper (30), a majority by mass of the upper or a majority of the surface of the upper is made of a main upper material and possibly of one or more auxiliary upper material(s); a sole (20), a majority by mass of the sole is made of a main sole material and possibly of one or more auxiliary sole material(s);
and the main upper material, and possibly the auxiliary upper material(s), and the main sole material, and possibly the auxiliary sole material(s), is/are selected among the following materials: the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers.

The present invention also relates to a method for manufacturing such a footwear article (10).

Claims

1. A shoe that comprises: an upper, wherein a majority by mass of the upper is made of a main upper material, and possibly of one or more auxiliary upper material(s); and a sole, wherein a majority by mass of the sole is made of a main sole material, and possibly of one or more auxiliary sole material(s); wherein the main upper material, and possibly the auxiliary upper material(s), is/are selected among the following materials: the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers; wherein the main sole material, and possibly the auxiliary sole material(s), is/are selected among the following materials: the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers.

2. The shoe according to claim 1, wherein the main upper material is selected among one of the following materials: a polyolefin or an olefinic thermoplastic elastomer.

3. The shoe according to claim 1, wherein the main sole material is selected among: a styrenic thermoplastic elastomer, or a polyolefin or a vulcanized thermoplastic elastomer chosen among: a mixture of a vulcanized olefin elastomer and of a polyolefin, and a mixture of a vulcanized olefinic elastomer and of a styrenic thermoplastic elastomer.

4. The shoe according to claim 3, wherein the main sole material is a styrenic thermoplastic elastomer.

5. The shoe according to claim 1, wherein the sole and the upper are manufactured individually and joined to each other.

6. The shoe according to claim 1, wherein the upper comprises a yarn comprising a material chosen among: a polyolefin or an olefinic thermoplastic elastomer.

7. The shoe according to claim 1, wherein the upper comprises a textile component, and in that wherein the textile component comprises a yarn comprising the main upper material.

8. The shoe according to claim 1, wherein the upper comprises a textile portion forming a foot-receiving area having an outer face, and at least one piece comprising an olefinic thermoplastic elastomer, said piece being secured to said outer face of the textile portion, and to said sole.

9. The shoe according to claim 1, wherein the sole comprises a cellular component comprising a material selected among at least one of: a styrenic thermoplastic elastomer, an olefinic thermoplastic elastomer, a mixture of a vulcanized olefinic elastomer and of a polyolefin, a mixture of a vulcanized olefinic elastomer and of a styrenic thermoplastic elastomer, and a polyolefin.

10. (canceled)

11. The shoe according to claim 1, wherein the upper comprises at least one passage eyelet for at least one lacing element, said at least one passage eyelet comprises a textile strip comprising at least one yarn comprising the main upper material.

12. The shoe according to claim 1, wherein the upper comprises a foam component comprising the main upper material.

13. (canceled)

14. The shoe according to claim 1, wherein the ratio of the mass of the main upper material to the total mass of the upper is greater than or equal to 40%.

15. (canceled)

16. The shoe according to claim 1, wherein the ratio of the mass of the main sole material to the total mass of the sole is greater than or equal to 40%.

17. (canceled)

18. The shoe according to claim 1, wherein the shoe comprises at most 10% by mass of one or more contaminant material(s) not chosen among the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers.

19. The shoe according to any one of claims 1 to 18, characterized in that the shoe comprises one or more contaminant material(s) chosen among the polyurethanes, said contaminant material(s) chosen among the polyurethanes represent(s) at most 10% by mass of said shoe, particularly the shoe comprises at most 10% by mass of one or more contaminant thermoplastic material(s) chosen among the polyurethanes and at most 5% by mass of one or more thermosetting contaminant material(s) chosen among the polyurethanes.

20. The shoe according to claim 1, wherein the main upper material and the main sole material have a density (g/cm3) less than or equal to 1.1, preferably less than or equal to 1.05.

21. (canceled)

22. (canceled)

23. (canceled)

24. (canceled)

25. (canceled)

26. (canceled)

27. (canceled)

28. The shoe according to claim 1, wherein the ratio of the mass of the main upper material and of the auxiliary upper material(s) to the total mass of the upper is greater than or equal to 40%.

29. The shoe according to claim 1, wherein the ratio of the mass of the main sole material and of the auxiliary sole material(s) to the total mass of the sole is greater than or equal to 40%.

30. The shoe according to claim 1, wherein the sole comprises foam beads comprising a material selected among: a styrenic thermoplastic elastomer; an olefinic thermoplastic elastomer; a mixture of a vulcanized olefinic elastomer and of a polyolefin; a mixture of a vulcanized olefinic elastomer and of a styrenic thermoplastic elastomer; and a polyolefin.

31. A shoe, wherein it comprises: an upper, a majority of the surface of the upper is made of a main upper material, and possibly of one or more auxiliary upper material(s); a sole, a majority by mass of the sole is made of a main sole material, and possibly of one or more auxiliary sole material(s); wherein the main upper material, and possibly the auxiliary upper material(s), is/are selected among the following materials: the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers; wherein the main sole material, and possibly the auxiliary sole material(s), is/are selected among the following materials: the polyolefins, the styrenic thermoplastic elastomers, the olefinic thermoplastic elastomers, and the vulcanized thermoplastic elastomers.

Description

DESCRIPTION OF THE DRAWINGS

[0308] The invention will be better understood upon reading the description of two embodiments of the invention given by way of non-limiting examples, with reference to the figures in which:

[0309] FIG. 1 illustrates schematically in perspective a first example of a shoe according to the invention;

[0310] FIG. 2 represents the shoe of FIG. 1 according to the longitudinal cutting plane II-II represented in FIG. 1;

[0311] FIG. 3 illustrates schematically in perspective a second example of a shoe according to the invention;

[0312] FIG. 4 schematically illustrates in perspective a third example of a shoe according to the invention;

[0313] FIG. 5 is a table summarizing the mechanical properties measured on examples of polymer mixtures resulting from the recycling of shoes according to the invention.

DESCRIPTION OF THE EMBODIMENT

[0314] The shoe 10 represented in FIG. 1 comprises an outsole 20 whose majority by mass is made of a main sole material, and an upper 30 whose majority by mass is made of a main upper material.

[0315] The main sole material is advantageously a styrenic thermoplastic elastomer, particularly chosen among the SEBS (optionally grafted), the SBS, the SBC, the SIS, and the SEPS, in this specific example the SEBS.

[0316] The sole 20 can comprise a first auxiliary sole material, particularly a polyolefin, more particularly it is polypropylene.

[0317] The main upper material is preferably a polyolefin, particularly the polyethylene or the polypropylene, in this specific example the polypropylene.

[0318] Advantageously, the upper 30 comprises a lace 35 made of polypropylene, particularly comprising yarns made of braided polypropylene.

[0319] Advantageously, the upper 30 comprises a component 40 folded on itself and comprising a foam laminated on its both sides with a textile. The textiles are preferably made of polypropylene and/or polyethylene, particularly a fabric or a knit with polypropylene yarns and/or polyethylene yarns, preferably polypropylene yarns. The foam is preferably polyethylene foam.

[0320] The upper 30 can also comprise a foam component 50 housed in the fold of the outer component 40, preferably made of polyethylene, said foam improves the accommodation of the hindfoot.

[0321] The edges of the component 40 folded on itself can be secured according to any technique known to those skilled in the art, for example using one or more stitch(es), preferably made with one or more polyolefin, particularly polypropylene, yarn(s).

[0322] Preferably, the upper component 40 is arranged in the hindfoot region 12 and partly in the medial 18 and lateral 16 foot regions.

[0323] Advantageously, the upper 30 further comprises the upper component 42 arranged in the forefoot regions 14, and partly in the lateral 16 and medial 18 foot regions. The upper component 42 can comprise a knit or a fabric. The upper 30 can comprise other upper component(s). All of the upper components including the components 40 and 42 are preferably shaped in three dimensions using a mounting insole. Preferably, the mounting insole is a non-woven fabric made of polyolefin, in particular made of polypropylene. The mounting insole is advantageously hot-melt along all or part of its surface to improve its tearing resistance.

[0324] The upper 30 comprises, as well as preferably any upper according to the invention, a hindfoot region 12, a forefoot region 14, a lateral region 16, a medial region 18 and an instep region 19 comprising a tongue.

[0325] The shaping of the component 40, with optionally other upper component(s), on a foot-shaped preform (called lasting operation) is performed for example using a polypropylene cord (for example a circular braid not represented) tensioning the bottom edges of the textile component 40 and optionally of the other upper component(s).

[0326] The shoe 10 can also comprise lacing eyelets 55 in the main molded upper material, for example lacing eyelets 55 made of polypropylene.

[0327] The shoe 10 can also comprise a non-woven fabric made of polypropylene or polyethylene coated in whole or in part with a poly(ethylene-vinyl acetate) (EVA) coating making it possible to secure by bonding, when the EVA is activated by heating, the lacing eyelets 55 to the outer textile component 50.

[0328] The shoe 10 can comprise textile, in particular woven, strips 60 and 61 made of polyethylene and/or polypropylene, particularly comprising polypropylene yarns and/or polyethylene yarns, in particular polypropylene yarns. Each textile strip 60 and 61 comprises a lacing area 62 forming a sheath for the passage of a lace.

[0329] The textile strips 60 and 61 preferably each have a width 11 and 12 greater than or equal to 5 mm, particularly greater than or equal to 10 mm, more particularly greater than or equal to 15 mm.

[0330] Preferably, the textile strip 60 comprises a first end 64 and a second end 66 secured to the component 40. The first and second ends 64, 66 are spaced from each other so that the textile strip 60 forms an inverted V.

[0331] Preferably, the textile strip 61 comprises a first end 65 and a second end 67, substantially superimposed and secured to the component 40.

[0332] Preferably, the lacing area 62 comprises a portion folded on itself of the textile strip 60 or 61 and thus forming a sheath for the passage of a lace.

[0333] The textile strips 60 and 61 also form lateral reinforcement areas.

[0334] The upper 30 can comprise a rear counter 70 secured in the hindfoot region 14 of the component 40. This rear counter 70 is preferably a molded piece made of polypropylene.

[0335] The upper 30 can also comprise a hard toe box 90 in a molded material, for example in the main upper material, preferably in a polyolefin, an olefinic thermoplastic elastomer, or a vulcanized thermoplastic elastomer, or a styrenic thermoplastic elastomer, such as the SEBS.

[0336] For this specific embodiment, the main upper material of the upper 30 is a polyolefin, particularly the polypropylene. It is indeed the base thermoplastic material whose mass fraction constitutes the major part, that is to say is the largest mass fraction compared to the mass fractions of other materials.

[0337] The upper 30 also comprises a first auxiliary upper material, different from the main upper material, which in this specific example is the polyethylene.

[0338] In this specific example, the mass fraction of polyolefin in the upper is of the order of 55.17%, particularly the mass fraction of polypropylene (main upper material) in the upper is of the order of 44.83%, and the mass fraction of polyethylene (first auxiliary upper material) is of the order of 10.34%. The mass fraction of olefinic thermoplastic elastomer (TPO) in the upper is of the order of 27.59% (second auxiliary upper material), and finally the mass fraction of glue is of the order of 17.24%.

[0339] The ratio of the mass of the main upper material 30, in this specific example the polypropylene, and of the mass of the auxiliary upper materials 30, for example made of PE and TPO, relative to the total mass of the upper 30, is greater than or equal to 80%, in particular of the order of 82% or more if the used glue is made of EVA. This ratio preferably tends towards 100%. When the materials are recycled, there may remain one or more contaminant material(s) whose mass fraction however remains low, for example of the order of 5% or less.

[0340] The shoe 10 in this embodiment is manufactured according to a traditional Strobel type construction. The outsole 20 can be secured to the upper 30 by bonding. The outsole 20 and the upper 30 are therefore manufactured separately, then secured to each other.

[0341] Alternatively, it is possible for the outsole 20 to be manufactured at the same time as it is secured to the upper. In this case, the outsole is directly injected onto the upper that is to say onto the bottom upper portion 30. Advantageously, the main material of the upper 30 is compatible with, or in the same base thermoplastic material, the main sole material, so that the outsole adheres to the upper, preferably without the use of an outer binding agent.

[0342] Preferably, the mass fraction of the main sole material, particularly the SEBS, in the outsole is of the order of 65%. The mass fraction of polyolefin, in particular of polypropylene mixed with the SEBS, in the outsole is of the order of 20%. The mass fraction of filler (for example of calcium carbonate) in the outsole is of the order of 5%. Finally, the mass fraction of plasticizer in the outsole is of the order of 10%.

[0343] Advantageously, the shoe 10 essentially comprises polypropylene, polyethylene, a TPO and SEBS, the SEBS constituting the major part in the sole and the polypropylene constituting the major part in the upper. The recycling of the shoe is thus made easier since it is not necessary to separate the different components. The shoe is shredded then the shreds are transformed into thermoplastic granules able to be transformed by a traditional technique for shaping the thermoplastics. The thermoplastic granules therefore comprise a thermoplastic mixture comprising the materials selected in the present invention which are compatible with each other during their hot-transformation, and have good adhesion with each other.

[0344] The thermoplastic granules can thus be advantageously extruded and injected to manufacture all or part of an outsole or a midsole.

[0345] The thermoplastic granules can also be transformed to manufacture a front toe box or a rear counter or even lacing eyelets, a foam component or agglomerated or non-agglomerated foam beads.

[0346] FIG. 3 represents a second example mentioned without limitation of a shoe 100 according to the invention, particularly a football shoe, comprising an outsole 120 and an upper 130. The outsole 120 can be manufactured independently of the upper 130, and assembled to the latter by bonding for example or even be injected directly onto the upper 130. The main sole material is in this specific example a polyolefin, particularly the polypropylene.

[0347] Preferably, the mass fraction of the main sole material in the outsole 120 is of the order of 90-95%. The outsole 120 further comprises a filler, one or more pigment(s), and possibly one or more anti-UV agent(s). The main upper material is an olefinic thermoplastic elastomer, particularly an EPDM mixed with the polypropylene and optionally a plasticizer. The mass fraction and the surface fraction of the main upper material in the upper 130 are respectively of the order of 44.26% and 21.69%. The upper 130 also comprises several auxiliary material(s) according to the invention, and particularly polypropylene (first auxiliary material) whose mass fraction and surface fraction in the upper are respectively of the order of 37.40% and 51.97%, and polyethylene (second auxiliary material) whose mass fraction and surface fraction are respectively of the order of 3.58% and 26.40%. The upper 130 also comprises one or more adhesive element(s) whose mass fraction is of the order of 14.75%. The mass fraction and the surface fraction of polyolefins and of TPO in the upper are respectively of the order of 85% and 100%.

[0348] FIG. 4 represents a third example mentioned without limitation of a shoe 200 according to the invention, comprising an outsole 220 and an upper 230. The outsole 220 can be manufactured independently of the upper 230, and assembled to the latter by bonding for example or be injected directly onto the upper 230. The main sole material is in this specific example a SEBS. The main upper material is in this specific example a polyolefin, particularly the polypropylene.

[0349] The upper 230 comprises a textile portion 240 forming a foot-receiving area having an outer face 245, and four strips 250, 251, 252 in an olefinic thermoplastic elastomer secured to the outer face 245 and to said outsole 220. A portion of each of the strips is disposed between the outsole 220 and the outer face 245 of the textile portion 240. A strip 250 is disposed along the front edge 205 of the shoe 200, and extends from a lateral side to a medial side of the shoe 200. A strip 251 is disposed along the rear edge 206 of the shoe 200, and extends from a lateral side to a medial side of the shoe 200. A strip 252 is disposed partly along the medial side 207 of the shoe 200, and extends between the front strip 250 and the rear strip 251. A strip, not visible in the photography of FIG. 4, is disposed partly along the medial side of the shoe 200, and extends between the front strip 250 and the rear strip 251.

[0350] Advantageously, the textile portion 240 forming a foot-receiving area comprises a textile component which comprises a yarn comprising the main upper material, particularly the main upper material is a polyolefin or an olefinic thermoplastic elastomer.

[0351] Preferably, the four strips, including the strips 250-252, are imitation leather type strips.

[0352] Advantageously, each strip comprises a polymer layer based on an olefinic thermoplastic elastomer, said polymer layer being disposed on a textile substrate. Said strips are thus advantageously compatible with the polymer material(s) of the textile portion 240 and of the outsole 220 so that they can be at least partially bonded by fusion of their structures to the textile portion 240 and to the outsole 220. Said strips including the strips 250-252 are bonded to the outer face 245 of the textile portion 240 so that the textile substrates are oriented facing the outer face 245.

[0353] The strip, such as one of the strips 250 to 252, may have a configuration different from that of a strip depending on the functions to be performed on the shoe. Generally, said strip can be a piece of imitation leather type having a shape determined according to its final function. In this specific example, the outer faces of the strips 250 to 252 are substantially smooth, but they may comprise one or more relief pattern(s) imparted to the polymer layer, for example by calendering.

[0354] The table in FIG. 5 summarizes the mechanical properties measured on examples of polymer mixtures resulting from the recycling of shoes according to the invention. The mixture of example 1 results from the recycling of a shoe not comprising any contaminant material within the meaning of the present text. The recycled shoe to obtain the mixture of Example 1 thus comprises 50 g of polypropylene (PP), 12 g of polyethylene (PE), 250 g of styrene-ethylene-butadiene-styrene (SEBS), and 25 g of a vulcanized thermoplastic elastomer (TPV, in this specific example the EPDM (ethylene-propylene-diene)/PP (polypropylene)).

[0355] The shoe recycled to obtain the mixture of Example 2 is identical to the shoe of Example 1 with the difference that the sole of the shoe recycled in this Example 2 comprises thermoplastic polyurethane whose mass fraction is 2%.

[0356] The shoe recycled from the mixture of Example 3 is identical to the shoe of Example 2 with the difference that the mass fraction of thermoplastic polyurethane in the shoe is 5%.

[0357] The shoe recycled from the mixture of Example 4 is identical to the shoe of Example 2 with the difference that the mass fraction of thermoplastic polyurethane in the shoe is 10%.

[0358] The shoe of the mixture of Example 5 is identical to the shoe of Example 1 with the difference that the shoe of Example 5 comprises 2% by mass of thermoplastic polyamide coming from a polyamide hook-and-loop fastening system of the recycled shoe.

[0359] It is noted that the presence of polyurethane and polyamide, at most 10% by mass of the shoe, makes it possible to improve the breaking strength, but also, surprisingly, the abrasion resistance. Beyond 10% by mass of polyurethane, a reduction in the abrasion resistance is observed.

[0360] Furthermore, the recycled mixtures obtained are perfectly hot-transformable (extrusion-injection or blow-molding, or by hot-pressing, extrusion molding, etc.) while maintaining final properties allowing them many new applications.