PRECIPITATION-HARDENED STAINLESS STEEL ALLOYS

Abstract

A precipitation-hardened stainless steel alloy is disclosed including, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe. The alloy has a ratio of Nb:(C+N) of at least 15:1.

Claims

1. A precipitation-hardened stainless steel alloy, comprising, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1.

2. The alloy of claim 1, comprising, by weight, 0.03-0.05% C.

3. The alloy of claim 1, comprising, by weight, up to 0.01% N.

4. The alloy of claim 1, consisting of, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; up to 0.5% incidental impurities of additional elements; and the balance of Fe, wherein the alloy has the ratio of Nb:(C+N) of at least 15:1.

5. The alloy of claim 4, consisting of, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and the balance of Fe, wherein the alloy has the ratio of Nb:(C+N) of at least 15:1.

6. The alloy of claim 1, comprising, by weight: 0.025-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.005% S; up to 0.01% As; and up to 0.002% Sb.

7. The alloy of claim 6, consisting of, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.1% Co; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.05% Al; up to 0.005% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.01% As; up to 0.002% Sb; up to 0.5% incidental impurities of additional elements; and the balance of Fe, wherein the alloy has the ratio of Nb:(C+N) of at least 15:1.

8. The alloy of claim 7, consisting of, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.1% Co; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.05% Al; up to 0.005% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.01% As; up to 0.002% Sb; and the balance of Fe, wherein the alloy has the ratio of Nb:(C+N) of at least 15:1.

9. The alloy of claim 6, wherein the alloy has reduced embrittlement relative to an otherwise identical comparative alloy having more than 0.045% C, more than 0.5% Mn, more than 0.5% Si, more than 0.05% V, more than 0.01% Sn, more than 0.01% N, more than 0.01% P, more than 0.005% S, more than 0.01% As, more than 0.002% Sb, or combinations thereof.

10. The alloy of claim 6, wherein the alloy has lower fracture appearance transition temperature relative to an otherwise identical comparative alloy having more than 0.045% C, more than 0.5% Mn, more than 0.5% Si, more than 0.05% V, more than 0.01% Sn, more than 0.01% N, more than 0.01% P, more than 0.005% S, more than 0.01% As, more than 0.002% Sb, or combinations thereof.

11. The alloy of claim 1, wherein the alloy has a reduced susceptibility to intergranular attack on reverted austenite adjacent to grain boundaries relative to an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1.

12. The alloy of claim 1, wherein the alloy forms less reverted austenite during heat treatment relative to an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1.

13. The alloy of claim 1, wherein the alloy has at least 25% less reverted austenite following heat treatment at 577° C. for 500 minutes than an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1 following heat treatment at 577° C. for 500 minutes.

14. The alloy of claim 1, wherein the alloy, following heat treatment at 577° C. for 500 minutes, comprises less than 16% reverted austenite.

15. The alloy of claim 1, wherein the alloy, following heat treatment at 577° C. for 1,000 minutes, comprises less than 25% reverted austenite.

16. The alloy of claim 1, wherein the alloy, following heat treatment at 577° C. for 3,000 minutes, comprises less than 35% reverted austenite.

17. The alloy of claim 1, wherein at least 90% of all C and N in the alloy are sequestered as Nb—C, Nb—N, and Nb—C—N species.

18. The alloy of claim 17, wherein at least 99% of all C and N in the alloy are sequestered as Nb—C, Nb—N, and Nb—C—N species.

19. The alloy of claim 1, wherein the ratio of Nb:(C+N) is between 15:1 and 34:1.

20. The alloy of claim 19, wherein the ratio of Nb:(C+N) is between 15:1 and 28:1.

21. The alloy of claim 20, wherein the ratio of Nb:(C+N) is between 15:1 and 18:1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0029] These and other features, aspects, and advantages of the present subject matter will become better understood when the following detailed description is read with reference to the accompanying drawings in which:

[0030] The sole FIGURE is a JMaPro software simulation comparing reverted austenite formation versus time at 577° C. with 0.001% N and 0.03% N content in a GTD 450 stainless steel alloy.

DETAILED DESCRIPTION

[0031] Provided are exemplary precipitation-hardened stainless steel alloys. Embodiments of the present disclosure, in comparison to precipitation-hardened stainless steel alloys not utilizing one or more features disclosed herein, have decreased susceptibility to intergranular attack, have decreased formation of reverted austenite, have reduced embrittlement, have lower fracture appearance transition temperature, have increased sequestration of carbon and nitrogen, or combinations thereof.

[0032] In one embodiment, a precipitation-hardened stainless steel alloy includes, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1.

[0033] In a further embodiment, the precipitation-hardened stainless steel alloy consists of, by weight, 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; up to 0.5% incidental impurities of additional elements, alternatively up to 0.4% incidental impurities of additional elements, alternatively up to 0.3% incidental impurities of additional elements, alternatively up to 0.2% incidental impurities of additional elements, alternatively up to 0.1% incidental impurities of additional elements, alternatively up to 0.05% incidental impurities of additional elements, alternatively up to 0.01% incidental impurities of additional elements; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1. Incidental impurities of additional elements may include, but are not limited to, titanium.

[0034] In yet a further embodiment, the precipitation-hardened stainless steel alloy consists of, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1.

[0035] The ratio of Nb:(C+N) for any of the foregoing embodiments may be any suitable ratio of at least 15:1, such as, but not limited to, a ratio of 15:1 to 34:1, alternatively a ratio of 15:1 to 32:1, alternatively a ratio of 15:1 to 30:1, alternatively a ratio of 15:1 to 28:1, alternatively a ratio of 15:1 to 26:1, alternatively a ratio of 15:1 to 24:1, alternatively a ratio of 15:1 to 22:1, alternatively a ratio of 15:1 to 20:1, alternatively a ratio of 15:1 to 18:1, alternatively a ratio of 15:1 to 17:1, alternatively a ratio of 15:1 to 16:1, alternatively a ratio of 16:1 to 18:1, alternatively a ratio of 17:1 to 19:1, alternatively a ratio of 18:1 to 20:1, or any sub-range or combination thereof.

[0036] Austenite may occur in the precipitation-hardened stainless steel alloys of the present disclosure in two forms, retained austenite and reverted austenite. Retained austenite is austenite which survives formation of the precipitation-hardened stainless steel alloy, and is not converted to martensite during the formation process. Retained austenite may be reduced or eliminated from the precipitation-hardened stainless steel alloys by appropriate care in the thermal treatments during formation of the precipitation-hardened stainless steel alloys, or by a post-formation cryogenic thermal treatment. Retained austenite, while undesirable, may, as such, be addressed through conventional methods. Reverted austenite, however, is austenite which forms from martensite during heat treatments or other exposure to heat subsequent to initial formation of the precipitation-hardened stainless steel alloys, and which, following formation, does not revert to martensite upon cooling. Cryogenic treatments and other known methods do not successfully mitigate reverted austenite content, without a full re-solutioning of the alloy. Without being bound by theory, it is believed that reverted austenite is stabilized by the presence of carbon and nitrogen in the alloy, which thereby prevents reverted austenite from converting to martensite. Formation of reverted austenite, particularly adjacent to grain boundaries may increase susceptibility of precipitation-hardened stainless steel alloys to intergranular attack.

[0037] The precipitation-hardened stainless steel alloy may have a reduced susceptibility to intergranular attack on reverted austenite adjacent to grain boundaries relative to an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1. The precipitation-hardened stainless steel alloy may form less reverted austenite during heat treatment relative to an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1. At least 90%, alternatively at least 95%, alternatively at least 98%, alternatively at least 99%, alternatively at least 99.5%, alternatively at least 99.9%, alternatively all, of C and N in the precipitation-hardened stainless steel alloy may be sequestered as Nb—C, Nb—N, and Nb—C—N species.

[0038] Referring to the FIGURE, in one embodiment, the precipitation-hardened stainless steel alloy has at least 25% less reverted austenite following heat treatment at 577° C. for 500 minutes than an otherwise identical comparative alloy having a comparative ratio of Nb:(C+N) of less than 15:1 following heat treatment at 577° C. for 500 minutes. The precipitation-hardened stainless steel alloy, following heat treatment at 577° C. for 500 minutes, comprises less than 16% reverted austenite, following heat treatment at 577° C. for 1,000 minutes, comprises less than 25% reverted austenite, and following heat treatment at 577° C. for 3,000 minutes, comprises less than 35% reverted austenite.

[0039] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.018% N, alternatively up to 0.016% N, alternatively up to 0.015% N, alternatively up to 0.014% N, alternatively up to 0.012% N, alternatively up to 0.010% N, alternatively up to 0.010% N, alternatively up to 0.008% N, alternatively up to 0.005% N, or any sub-range or combination thereof.

[0040] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, 0.03-0.05% C, alternatively 0.025-0.045% C, alternatively 0.03-0.045% C, alternatively 0.035-0.05% C, alternatively 0.035-0.045% C, alternatively 0.04-0.05% C, alternatively 0.04-0.045% C, alternatively 0.045-0.05% C, or any sub-range or combination thereof.

[0041] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.9% Mn, alternatively up to 0.8% Mn, alternatively up to 0.7% Mn, alternatively up to 0.6% Mn, alternatively up to 0.5% Mn, alternatively up to 0.4% Mn, alternatively up to 0.3% Mn, alternatively 0.2-0.5% Mn, alternatively 0.2-0.3% Mn, alternatively 0.3-0.4% Mn, alternatively 0.4-0.5% Mn, or any sub-range or combination thereof.

[0042] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.9% Si, alternatively up to 0.8% Si, alternatively up to 0.7% Si, alternatively up to 0.6% Si, alternatively up to 0.5% Si, alternatively up to 0.4% Si, alternatively up to 0.3% Si, alternatively 0.2-0.5% Si, alternatively 0.2-0.3% Si, alternatively 0.3-0.4% Si, alternatively 0.4-0.5% Si, or any sub-range or combination thereof.

[0043] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.09% V, alternatively up to 0.08% V, alternatively up to 0.07% V, alternatively up to 0.06% V, alternatively up to 0.05% V, alternatively up to 0.04% V, alternatively up to 0.03% V, alternatively up to 0.02% V, alternatively up to 0.01% V, or any sub-range or combination thereof.

[0044] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.09% Sn, alternatively up to 0.08% Sn, alternatively up to 0.07% Sn, alternatively up to 0.06% Sn, alternatively up to 0.05% Sn, alternatively up to 0.04% Sn, alternatively up to 0.03% Sn, alternatively up to 0.02% Sn, alternatively up to 0.01% Sn, alternatively up to 0.005% Sn, alternatively up to 0.001% Sn, or any sub-range or combination thereof.

[0045] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.025% P, alternatively up to 0.02% P, alternatively up to 0.015% P, alternatively up to 0.01% P, alternatively up to 0.005% P, alternatively up to 0.001% P, or any sub-range or combination thereof.

[0046] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.007% S, alternatively up to 0.006% S, alternatively up to 0.005% S, alternatively up to 0.004% S, alternatively up to 0.003% S, alternatively up to 0.002% S, alternatively up to 0.001% S, or any sub-range or combination thereof.

[0047] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.09% As, alternatively up to 0.08% As, alternatively up to 0.07% As, alternatively up to 0.06% As, alternatively up to 0.05% As, alternatively up to 0.04% As, alternatively up to 0.03% As, alternatively up to 0.02% As, alternatively up to 0.01% As, alternatively up to 0.005% As, alternatively up to 0.001% As, or any sub-range or combination thereof.

[0048] The precipitation-hardened stainless steel alloy of any of the foregoing embodiments may have, by weight, up to 0.009% Sb, alternatively up to 0.008% Sb, alternatively up to 0.007% Sb, alternatively up to 0.006% Sb, alternatively up to 0.005% Sb, alternatively up to 0.004% Sb, alternatively up to 0.003% Sb, alternatively up to 0.002% Sb, alternatively up to 0.0015% Sb, alternatively up to 0.001% Sb, or any sub-range or combination thereof.

[0049] It is specifically disclosed that any of the narrowed ranges of C, Mn, Si, V, Sn, N, P, S, As, and Sb disclosed herein may be combined with the narrowed ranges of the others of these elements in any combination, and that the resulting combinations of ranges may be applied to any of the embodiments of precipitation-hardened stainless steel alloy disclosed herein.

[0050] Without limiting the scope of this disclosure, one exemplary precipitation-hardened stainless steel alloy includes, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.045% C, alternatively 0.030-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.1% Co; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.05% Al; up to 0.005% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1. Another exemplary precipitation-hardened stainless steel alloy consists of, by weight, 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.045% C, alternatively 0.030-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.1% Co; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.05% Al; up to 0.005% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; up to 0.5% incidental impurities of additional elements, alternatively up to 0.4% incidental impurities of additional elements, alternatively up to 0.3% incidental impurities of additional elements, alternatively up to 0.2% incidental impurities of additional elements, alternatively up to 0.1% incidental impurities of additional elements, alternatively up to 0.05% incidental impurities of additional elements, alternatively up to 0.01% incidental impurities of additional elements; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1. Yet another exemplary precipitation-hardened stainless steel alloy consists of, by weight, 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.045% C, alternatively 0.030-0.045% C; 0.2-0.5% Mn; 0.2-0.5% Si; up to 0.05% V; up to 0.1% Co; up to 0.01% Sn; up to 0.01% N; up to 0.01% P; up to 0.05% Al; up to 0.005% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe, wherein the alloy has a ratio of Nb:(C+N) of at least 15:1.

[0051] In one embodiment, wherein the precipitation-hardened stainless steel alloy includes up to 0.045% C, up to 0.5% Mn, up to 0.5% Si, up to 0.05% V, up to 0.01% Sn, up to 0.01% N, up to 0.01% P, up to 0.005% S, up to 0.01% As, and up to 0.002% Sb, the alloy has reduced embrittlement relative to an otherwise identical comparative alloy having more than 0.045% C, more than 0.5% Mn, more than 0.5% Si, more than 0.05% V, more than 0.01% Sn, more than 0.01% N, more than 0.01% P, more than 0.005% S, more than 0.01% As, more than 0.002% Sb, or combinations thereof.

[0052] In one embodiment, wherein the precipitation-hardened stainless steel alloy includes up to 0.045% C, up to 0.5% Mn, up to 0.5% Si, up to 0.05% V, up to 0.01% Sn, up to 0.01% N, up to 0.01% P, up to 0.005% S, up to 0.01% As, and up to 0.002% Sb, the alloy has lower fracture appearance transition temperature relative to an otherwise identical comparative alloy having more than 0.045% C, more than 0.5% Mn, more than 0.5% Si, more than 0.05% V, more than 0.01% Sn, more than 0.01% N, more than 0.01% P, more than 0.005% S, more than 0.01% As, more than 0.002% Sb, or combinations thereof.

[0053] While the precipitation-hardened stainless steel alloys have been described with reference to preferred embodiments, it will be understood by those skilled in the art that various changes may be made, and equivalents may be substituted for elements thereof without departing from the scope of the present disclosure. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the present disclosure without departing from the essential scope thereof. Therefore, it is intended that the present disclosure not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this technology, but that the present disclosure will include all embodiments falling within the scope of the appended claims.