CONNECTION STRUCTURE OF LAMINATE CELLS, BATTERY PACK, AND METHOD OF CONNECTING LAMINATE CELLS
20220344781 · 2022-10-27
Inventors
Cpc classification
B23K26/70
PERFORMING OPERATIONS; TRANSPORTING
B23K2101/36
PERFORMING OPERATIONS; TRANSPORTING
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B23K26/323
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A connection structure of laminate cells is provided. Each of the laminate cells includes a pouch including a laminate film, an electrode assembly enclosed in the pouch, and a plate-shaped terminal connected internally of the pouch to the electrode assembly and extending out of the pouch along one side edge of the pouch. The plate-shaped terminal includes a bent tip. The pouches are stacked on each other, the bent tips of the plate-shaped terminals are overlapped with each other, and the bent tips are intermittently joined together in an overlapped portion where the bent tips are overlapped with each other.
Claims
1. A connection structure of laminate cells, comprising: a plurality of laminate cells each comprising: a pouch including a laminate film; an electrode assembly enclosed in the pouch; and a plate-shaped terminal connected internally of the pouch to the electrode assembly and extending out of the pouch along one side edge of the pouch, the plate-shaped terminal including a bent tip, wherein the pouches are stacked on each other, the bent tips of the plate-shaped terminals are overlapped with each other, and the bent tips are joined together intermittently in an overlapped portion of the bent tips.
2. A battery pack comprising: a plurality of laminate cells, each of the plurality of laminate cells comprising: a pouch including a laminate film; an electrode assembly enclosed in the pouch; and a plate-shaped terminal being connected internally of the pouch to the electrode assembly and extending out of the pouch along one side edge of the pouch, the terminal including a bent tip, wherein: the plurality of laminate cells are arranged successively so that the pouches are stacked on each other; and adjacent ones of the plurality of laminate cells are configured so that the plate-shaped terminals are arranged opposite to each other, the bent tips are overlapped with each other, and the bent tips are intermittently joined together along a longitudinal axis of the laminate cells.
3. A method of connecting laminate cells, comprising: preparing laminate cells; and connecting the laminate cells to each other, wherein: each of the laminate cells prepared in the step of preparing the laminate cells comprises: a substantially rectangular-shaped pouch including a laminate film; an electrode assembly enclosed in the pouch; and a plate-shaped terminal connected internally of the pouch to the electrode assembly and extending out of the pouch along one side edge of the pouch, the terminal including a bent tip; and the step of connecting the laminate cells further comprises: arranging the plate-shaped terminal of one of two adjacent laminate cells and the plate-shaped terminal of the other one of the two adjacent laminate cells so as to be opposed to each other, and securely holding the bent tip of the plate-shaped terminal of the one laminate cell and the bent tip of the plate-shaped terminal of the other laminate cell in an overlapped condition with a jig; and laser welding together the bent tip of the plate-shaped terminal of the one laminate cell and the bent tip of the plate-shaped terminal of the other laminate cell in an overlapped portion where the bent tips are overlapped with each other, with the overlapped portion being securely held by the jig.
4. The method of connecting laminate cells according to claim 3, wherein: the overlapped portion where the bent tip of the plate-shaped terminal of the one laminate cell and the bent tip of the plate-shaped terminal of the other laminate cell are overlapped with each other includes mounting holes formed intermittently along a longitudinal axis of the laminate cells; and the jig comprises: a first member including an elongated part that is to be inserted into a gap space surrounded by opposing portions where the plate-shaped terminal of the one of the two laminate cells and the plate-shaped terminal of the other laminate cell are opposed to each other and by the overlapped portion where the bent tip of the plate-shaped terminal of the one laminate cell and the bent tip of the plate-shaped terminal of the other laminate cell are overlapped with each other; and a fastening member including a head portion and a shaft portion, the head portion being brought into contact with an outer surface of the overlapped portion, the shaft portion being inserted through the overlapped portion via a mounting hole and engaging with the elongated part of the first member, and the shaft portion including a fastening mechanism narrowing the gap between the head portion and the elongated part.
5. The method of connecting laminate cells according to claim 3, wherein: the jig comprises: a first member including an elongated part made of a magnetic material, the elongated part to be inserted into a gap space surrounded by opposing portions where the plate-shaped terminal of the one of the two laminate cells and the plate-shaped terminal of the other laminate cell are opposed to each other and by the overlapped portion where the bent tip of the plate-shaped terminal of the one laminate cell and the bent tip of the plate-shaped terminal of the other laminate cell are overlapped with each other; and a second member including a magnet that is to be brought into contact with an outer surface of the overlapped portion to attract the elongated part.
6. The method of connecting laminate cells according to claim 3, wherein the elongated part is recessed in regions opposing locations of the overlapped portion of the bent tips that are to be laser welded.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0014]
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
DETAILED DESCRIPTION
[0023] Embodiments of the invention according to the present disclosure will be described hereinbelow. It should be noted, however, that the disclosed embodiments are, of course, not intended to limit the invention. The present invention is not limited to the embodiments described herein unless specifically stated otherwise. The drawings are depicted schematically and do not necessarily reflect actual objects. The features and components that exhibit the same effects are designated by the same reference symbols as appropriate, and the description thereof will not be repeated.
[0024]
Laminate Cell 10
[0025] As illustrated in
[0026] In the present description, the term “laminate cell” refers to the smallest unit of electricity storage device that uses a laminate film as its outer casing material. The term “electricity storage device” refers to a device that is capable of charging and discharging. The electricity storage device may include lithium polymer battery and lithium-ion capacitor, in addition to a variety of batteries generally referred to as lithium-ion battery and lithium secondary battery. The secondary battery refers to a battery that is capable of charging and discharging repeatedly in association with transfer of charge carriers between positive and negative electrodes. The electricity storage device may use either an electrolyte solution or a solid electrolyte. For example, the secondary battery may be a secondary battery that uses what is called a liquid-type electrolyte solution, or may be what is called an all-solid-state battery. Note that each of the laminate cells 10 shown in
Laminate Film 50
[0027] The laminate film 50 is a film material that is used as an outer casing material of the electricity storage device. The laminate film 50 includes, for example, a metal sheet 51, an insulating resin layer 52 that covers the outer surface of the metal sheet 51, and a thermoplastic resin layer 53 that covers the inner surface of the metal sheet 51.
[0028] Here, the metal sheet 51 serves the role of imparting gas barrier properties for preventing entry of oxygen, moisture, and electrolyte solution to the laminate film 50. The metal sheet 51 may be a metal thin film, such as aluminum foil, copper foil, nickel foil, stainless steel foil, clad foil thereof, annealed foil thereof, or unannealed foil thereof. The metal sheet 51 may be a metal foil plated with an electrically conductive metal, such as nickel, tin, copper, and chromium. The metal sheet 51 may include a conversion coating as its undercoating. The conversion coating is a surface film that is formed by performing a conversion treatment on a surface of the metal sheet 51. Examples of the conversion treatment include a chromate treatment and a non-chromate conversion treatment using a zirconium compound.
[0029] The insulating resin layer 52 is an outside layer of the laminate film 50. The insulating resin layer 52 has electrically insulative properties and has a melting point such that it does not melt when melt-bonding the thermoplastic resin layer 53. Examples of the resin that is usable for the insulating resin layer 52 include resins having a sufficiently higher melting point than the resin used for the thermoplastic resin layer 53, such as polyamide and polyester. The insulating resin layer 52 may be a stretched film of these resins. In particular, from the viewpoint of moldability and strength, it is possible to use a biaxially-oriented polyamide film, a biaxially-oriented polyester film, or a multi-layer film including these films. It is also possible to use a multi-layer film in which a biaxially-oriented polyamide film and a biaxially-oriented polyester film are bonded together. Although not limited thereto, examples of the polyamide film include nylon 6 film, nylon 6, 6 film, MXD nylon film. Examples of the biaxially-oriented polyester film include a biaxially-oriented polybutylene terephthalate (PBT) film and a biaxially-oriented polyethylene terephthalate (PET) film.
[0030] The insulating resin layer 52 may contain a slip additive and/or solid microparticles. When a slip additive and/or solid microparticles are contained in the insulating resin layer 52, slippage of the surface of the insulating resin layer 52 is improved. The thickness of the insulating resin layer 52 may be, for example, from 9 μm to 50 μm. The insulating resin layer 52 may be a single layer or may include multiple stacked layers in order to improve the strength or the like.
[0031] The thermoplastic resin layer 53 is a layer that is formed inside of the metal sheet 51. The thermoplastic resin layer 53 may be provided with excellent chemical resistance against corrosion, which is required for electricity storage devices such as lithium-ion secondary batteries. The thermoplastic resin layer 53 is one that is to be thermally bonded when the inner surfaces of laminate films 50 are overlapped and bonded together, and the thermoplastic resin layer 53 has heat sealability.
[0032] In terms of chemical resistance and heat sealability, the thermoplastic resin layer 53 may be composed of polyethylene, polypropylene, olefin-based copolymer, an acid modified product thereof, or an ionomer thereof. Examples of the olefin-based copolymer include EVA (ethylene-vinyl acetate copolymer), EAA (ethylene-acrylic acid copolymer), and EMAA (ethylene-methacrylic acid copolymer). In addition, polyamide films (for example, nylon 12) and polyamide films are also usable. The thermoplastic resin layer 53 may be, for example, a thermoplastic resin unstretched film. Although not limited thereto, the thermoplastic resin unstretched film may be composed of polyethylene, polypropylene, olefin-based copolymer, an acid modified product thereof, or an ionomer thereof, in terms of chemical resistance and heat sealability. Examples of the olefin-based copolymer include EVA (ethylene-vinyl acetate copolymer), EAA (ethylene-acrylic acid copolymer), and EMAA (ethylene-methacrylic acid copolymer). In addition, polyamide films (for example, nylon 12) and polyamide films are also usable. The thermoplastic resin layer 53 may contain a slip additive and/or solid microparticles, in order to increase the slippage of the surface.
[0033] The thickness of the thermoplastic resin layer 53 may be set to a thickness such as to be able to sufficiently prevent the occurrence of pinholes. From such a viewpoint, the thickness of the thermoplastic resin layer 53 may be greater than or equal to 20 μm. In addition, it is desirable that the amount of the resin used be smaller. From such a viewpoint, the thickness of the thermoplastic resin layer 53 may be less than or equal to 100 μm, for example, less than or equal to 80 μm, preferably less than or equal to 50 μm. The thermoplastic resin layer 53 may be a single layer or may include multiple layers. An example of multi-layer film is a three-layer film in which random polypropylene films are layered on opposite sides of a block polypropylene film.
Pouch 11
[0034] The pouch 11 is made of laminate film 50. In this embodiment, the pouch 11 includes two rectangular-shaped laminate films 50 overlapped with each other, and the thermoplastic resin layer 53 is melt-bonded at a peripheral edge portion 11a. As a result, a pouch-shaped outer casing, which includes the laminate films 50, is formed. The electrode assembly 20 is enclosed in the space of the pouch 11 that is surrounded by the peripheral edge portion 11a where the thermoplastic resin layer 53 is melt-bonded. Note that the embodiment of the pouch 11 is not limited to such a structure. For example, it is also possible that a sheet of rectangular-shaped laminate film may be folded in half, and the overlapped peripheral edge portions may be melt-bonded together. In the peripheral edge portion 11a of the laminate film to be melt-bonded, the thermoplastic resin layer 53 may be folded over and thermally bonded.
Electrode Assembly 20
[0035] The electrode assembly 20 is a member that is enclosed in the pouch 11. The configuration of the electrode assembly 20 is not particularly limited, and may be similar to or the same as one that is used for conventionally known electricity storage devices. The electrode assembly 20 includes a positive electrode sheet and a negative electrode sheet.
[0036] In the embodiment shown in
Plate-Shaped Terminals 31 and 32
[0037] Each of the plate-shaped terminals 31 and 32 is connected internally of the pouch 11 to the electrode assembly 20. In this embodiment, the plate-shaped terminal 31 is connected to the current collector 22 of the positive electrode sheet. The plate-shaped terminal 32 is connected to the current collector 23 of the negative electrode sheet. Each of the plate-shaped terminals 31 and 32 extends out of the pouch 11 along one side edge of the pouch 11. The tips of the plate-shaped terminals 31 and 32 are bent in the manner as shown in
[0038] In this embodiment, each of the plate-shaped terminals 31 and 32 is a rectangular-shaped plate member, as illustrated in
[0039] The other one of the longer sides of each of the plate-shaped terminals 31 and 32 juts out of the pouch 11. Along the longitudinal axis of the plate-shaped terminals 31 and 32, the peripheral edge portion 11a of the laminate film 50 is melt-bonded to opposite surfaces of each of the plate-shaped terminals 31 and 32 at an intermediate position of the shorter side axis thereof. The tips of the plate-shaped terminals 31 and 32, which extend out of the pouch 11, are bent in the manner as shown in
[0040] As illustrated in
[0041] A method of connecting laminate cells 10 includes the steps of preparing laminate cells 10 and connecting the laminate cells 10. Here, each of the laminate cells 10 that is prepared in the step of preparing laminate cells 10 includes a pouch 11, an electrode assembly 20, and plate-shaped terminals 31 and 32, as illustrated in
Step of Connecting Laminate Cells 10
[0042]
[0043] The step of connecting laminate cells 10 involves arranging a plate-shaped terminal 31 of one laminate cell 10(a) of two adjacent laminate cells 10 and a plate-shaped terminal 32 of the other laminate cell 10(b) so as to be opposed to each other, and securely holding the bent tip of the plate-shaped terminal 31 of the one laminate cell 10(a) and the bent tip of the plate-shaped terminal 32 of the other laminate cell 10(b) in an overlapped condition with a jig 60. Then, with the bent tips 31b and 32b being securely held by the jig 60, the bent tip 31b of the plate-shaped terminal 31 of the one laminate cell 10(a) and the bent tip 32b of the plate-shaped terminal 32 of the other laminate cell 10(b) are laser welded together.
[0044] In the embodiment shown in
[0045] The first member 61 includes an elongated part 61a. The elongated part 61a is inserted into a gap space 34, which is surrounded by opposing portions 31a and 32a, where the plate-shaped terminal 31 of the one laminate cell 10(a) and the plate-shaped terminal 32 of the other laminate cell 10(b) are opposed to each other, and by the overlapped portion 33, where the bent tip 31b of the plate-shaped terminal 31 of the one laminate cell 10(a) and the bent tip 32b of the plate-shaped terminal 32 of the other laminate cell 10(b) are overlapped with each other. The elongated part 61a is inserted into the gap space 34 surrounded by the plate-shaped terminals 31 and 32 of the two laminate cells 10(a) and 10(b) from one direction.
[0046]
[0047] Each of the fastening members 62 in this embodiment includes a head portion 62a and a shaft portion 62b. The head portion 62a is a portion that comes in contact with the outer surface of the overlapped portion 33 of a pair of plate-shaped terminals 31 and 32 of adjacent ones of the laminate cells 10. The shaft portion 62b is a portion that is inserted through the overlapped portion 33 through the mounting hole 33a (see
[0048] The jig 60 may cause the plate-shaped terminal 31 of one of two adjacent laminate cells 10 and the plate-shaped terminal 32 of the other laminate cell 10 to be arranged so as to be opposed to each other, and may securely hold the bent tip 31b of the one laminate cell 10 and the bent tip 32b of the other laminate cell 10 in an overlapped condition. In the step of connecting laminate cells 10, the jig 60 securely holds the bent tip 31b of the plate-shaped terminal 31 of the one laminate cell 10(a) and the bent tip 32b of the plate-shaped terminal 32 of the other laminate cell 10(b) in an overlapped condition. As illustrated in
[0049] In this embodiment, as illustrated in
[0050] Thus, the pouches 11 of the adjacent laminate cells 10(a) and 10(b) are stacked on each other. In addition, the bent tips 31b and 32b of the pair of plate-shaped terminals 31 and 32 of the adjacent laminate cells 10(a) and 10(b) are overlapped with each other, and the bent tips 31b and 32b intermittently joined together in the overlapped portion 33 where the bent tips 31b and 32b are overlapped with each other. In this case, the pair of plate-shaped terminals 31 and 32 are directly welded together without use of a bus bar. As a result, the bus bar becomes unnecessary, so that weight reduction can be achieved. Accordingly, it is possible to achieve weight reduction of a battery pack in which a plurality of laminate cells 10 are combined. In addition, the bent tips 31b and 32b of the pair of plate-shaped terminals 31 and 32 are intermittently joined together in the overlapped portion 33. As a result, sufficient strength is ensured in connecting the pair of plate-shaped terminals 31 and 32. The connection structure of laminate cells disclosed herein may be used as the connection structure for connecting at least some or all of the plurality of laminate cells that constitute a battery pack.
[0051] According to the method of connecting laminate cells 10 disclosed herein, the bent tips 31b and 32b of the pair of plate-shaped terminals 31 and 32 are welded together in an overlapped condition, with the bent tips 31b and 32b being securely held by the jig 60. As a result, precision of joining is improved in the overlapped portion 33 of the bent tips 31b and 32b of the plate-shaped terminals 31 and 32, and accordingly, product yield and product quality are improved. It is possible that a clad material may be adopted appropriately for the pair of plate-shaped terminals 31 and 32, and the same material may be used for the portions that are to be laser welded together. For example, lithium-ion secondary batteries use aluminum material for the positive electrode terminal and copper material for the negative electrode terminal. In this case, either one of the terminals may use a clad material so that the portions to be laser welded are made of the same material. For example, a clad material may be used for the negative electrode terminal. When this is the case, it is possible that the portion of the electrode assembly 20 to which the current collector 23 of the negative electrode sheet is connected may be made of copper, and the portion to be laser welded may be made of aluminum.
[0052] In the above-described embodiment, the elongated part 61a of the first member 61 and the fastening members 62 of the jig 60 are fastened together by a screw thread structure to narrow the gap the between the elongated part 61a and the head portions 62a of the fastening members 62. The fastening mechanism of the jig 60 is, however, not limited to such a screw thread structure.
[0053] In the embodiment shown
[0054] Thus, the overlapped portion 33 where the plate-shaped terminal 31 of one laminate cell 10 and the plate-shaped terminal 32 of another laminate cell 10 are overlapped with each other may be fastened intermittently along their longitudinal axis. Also, the plate-shaped terminals 31 and 32 may be laser welded together intermittently in the regions between the head portions 62a of the fastening members 62, with the overlapped portion 33 of the plate-shaped terminals 31 and 32 being fastened intermittently along their longitudinal axis.
[0055] Thus, the jig 60 may include a fastening member 62 and a first member 61 including an elongated part 61a. The elongated part 61a is inserted into the gap space 34, which is surrounded by opposing portions 31a and 32a, where the plate-shaped terminal 31 of the one laminate cell 10(a) and the plate-shaped terminal 32 of the other laminate cell 10(b) are opposed to each other, and the overlapped portion 33, where the bent tips 31b and 32b are overlapped with each other. The head portion 62a of the fastening member 62 comes into contact with the outer surface of the overlapped portion 33. The shaft portion 62b of the fastening member 62 is inserted through the overlapped portion 33 via the mounting hole 33a. The shaft portion 62b is provided with a fastening mechanism that engages with the elongated part 61a and narrows the gap between the head portion 62a and the elongated part 61a. Examples of the fastening mechanism include a screw thread structure and an engaging structure as described above.
[0056]
[0057] In the embodiment shown in
[0058]
[0059] According to the method of connecting laminate cells, the bent tips 31b and 32b of the plate-shaped terminals 31 and 32 of two adjacent laminate cells 10(a) and 10(b) are laser welded in the overlapped portion 33, with the bent tips 31b and 32b being securely held by the jig 60. As a result, the pair of plate-shaped terminals 31 and 32 of the laminate cells 10 are directly welded together without use of a bus bar. Moreover, because the elongated part 61a is inserted on the back side of the locations to which laser L is applied, the laser L is caught by the elongated part 61a even when the laser L penetrates the overlapped portion 33. This serves to prevent the pouches 11 of the laminate cells 10 from being damaged by the laser L.
Battery Pack 100
[0060] The connection method and the connection structure described above are applicable to a battery pack 100 in which a plurality of laminate cells 10(a) to 10(h) are connected together, as illustrated in
[0061] The battery pack 100 to which the connection method and the connection structure described above are applied includes, as illustrated in
[0062] As described above, this battery pack 100 may be able to eliminate the need for the bus bar for joining adjacent laminate cells 10 together. As a result, weight reduction of the battery pack 100 is achieved. In addition, the bent tips 31b and 32b of the pair of plate-shaped terminals 31 and 32 are intermittently joined together in the overlapped portion 33. As a result, sufficient strength is ensured in connecting the pair of plate-shaped terminals 31 and 32.
[0063] Various embodiments of the invention have been described hereinabove according to the present disclosure. Unless specifically stated otherwise, the embodiments described herein do not limit the scope of the present invention. It should be noted that various other modifications and alterations may be possible in the embodiments of the invention disclosed herein. In addition, the features, structures, or steps described herein may be omitted as appropriate, or may be combined in any suitable combinations, unless specifically stated otherwise.