METHODS FOR ISOLATION PROCESS CONTROL AND STRUCTURES THEREOF
20240404871 ยท 2024-12-05
Inventors
- Wei Che Tsai (Pingtung City, TW)
- Yuan Tsung Tsai (Tainan City, TW)
- Hsin-Yi Tsai (Tainan, TW)
- Ying Ming Wang (Tainan City, TW)
- Hsien Hua Tseng (Tainan City, TW)
- Shih-Hao Chen (Zhubei, TW)
Cpc classification
H01L27/088
ELECTRICITY
H01L21/3086
ELECTRICITY
H01L21/823481
ELECTRICITY
International classification
H01L21/762
ELECTRICITY
H01L27/088
ELECTRICITY
Abstract
Methods for forming a dielectric isolation region between two active regions are disclosed herein. A mandrel is formed on a substrate, then etched to form a trench. Spacers are formed on the sidewalls of the mandrel. The mandrel is removed, and the substrate is etched to form fins extending in a first direction in the two active regions, and of fins extending in a second direction. A mask is formed that exposes the substrate between the fins extending in the second direction. The substrate is etched to form a trench. The trench is filled with a dielectric material up to the top of the fins to form the dielectric isolation region. The methods provide better depth control during etching between the two active regions, and also permit the trench to extend deeper into the substrate due to reduced depth/width ratios during the etching steps.
Claims
1. A method for forming a dielectric structure between a first active region and a second active region, comprising: forming a mandrel extending in a first axis over a substrate; etching to form a trench in the mandrel in a second axis normal to the first axis in a desired location for the dielectric structure; forming spacers on sidewalls of the mandrel; removing the mandrel; etching into the substrate to form at least a first fin located in the first active region that extends in the first axis, a second fin located in the second active region that extends in the first axis, and a plurality of fins extending in the second axis; removing the spacers; forming a CPODE mask that exposes the substrate between the plurality of fins extending in the second axis; and etching into the substrate through the CPODE mask to form a trench; filling the trench with a dielectric material up to at least a fin height, to form the dielectric structure between the first active region and the second active region.
2. The method of claim 1, wherein the etching into the substrate also forms a third fin in the first active region that extends in the first axis and a fourth fin in the second active region that extends in the first axis, and wherein the method further comprises: forming a fin etch mask that exposes the third fin and the fourth fin; and etching to remove the third fin and the fourth fin.
3. The method of claim 2, wherein the third fin and the fourth fin are removed prior to forming the CPODE mask, or after filling the trench with the dielectric material.
4. The method of claim 2, wherein a portion of the plurality of fins extending in the second axis are also removed during the etching to remove the third fin and the fourth fin.
5. The method of claim 1, further comprising, prior to removing the mandrel: forming a spacer etch mask that exposes at least one spacer formed on one sidewall of the mandrel extending in the first axis; and etching to remove the exposed at least one spacer.
6. The method of claim 1, wherein the CPODE mask also exposes at least a portion of a fin extending in the second axis.
7. The method of claim 1, wherein the plurality of shorter fins extending in the second axis are not covered by the dielectric material that forms the dielectric structure.
8. The method of claim 1, wherein the dielectric structure has a depth of about 1100 angstroms to about 1300 angstroms.
9. The method of claim 1, wherein the dielectric structure has a width of about 150 angstroms to about 400 angstroms.
10. An integrated circuit, comprising: a substrate having a first active region and a second active region separated by a dielectric isolation region; and a first fin in the first active region that comprises a longer first portion normal to the dielectric isolation region and a shorter second portion that parallels the dielectric isolation region; and a second fin in the second active region that comprises a longer first portion normal to the dielectric isolation region and a shorter second portion that parallels the dielectric isolation region; wherein the longer first portion of the first fin and the longer first portion of the second fin are in-line with each other; and wherein the shorter second portion of the first fin and the shorter second portion of the second fin are parallel to each other.
11. The integrated circuit of claim 10, wherein the shorter second portion of the first fin and the shorter second portion of the second fin border the dielectric isolation region.
12. The integrated circuit of claim 10, wherein the dielectric isolation region has a depth of about 1100 angstroms to about 1300 angstroms.
13. A method for forming a first active region and a second active region, comprising: forming a mandrel over a substrate; etching to form a trench in the mandrel; etching into the substrate to form a first fin and a third fin located in the first active region, a second fin and a fourth fin located in the second active region, and a plurality of shorter fins separating the first active region and the second active region; forming a fin etch mask that exposes the third fin and the fourth fin; etching to remove the third fin and the fourth fin; forming a CPODE mask that exposes the substrate between the plurality of shorter fins; etching into the substrate through the CPODE mask to form a trench; and filling the trench with a dielectric material to form an isolation region between the first active region and the second active region.
14. The method of claim 13, wherein the third fin and the fourth fin are removed prior to forming the CPODE mask, or after filling the trench with the dielectric material.
15. The method of claim 13, wherein a portion of the plurality of shorter fins extending in the second axis are also removed during the etching to remove the third fin and the fourth fin.
16. The method of claim 13, wherein the CPODE mask also exposes at least a portion of a shorter fin extending in the second axis.
17. The method of claim 13, wherein the plurality of shorter fins extending in the second axis are not covered by the dielectric material that forms the isolation region.
18. The method of claim 13, wherein a plurality of hardmask layers are located between the substrate and the mandrel.
19. The method of claim 13, wherein the isolation region has a depth of about 1100 angstroms to about 1300 angstroms.
20. The method of claim 13, wherein the isolation region has a width of about 20 nanometers to about 30 nanometers.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0003] Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
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DETAILED DESCRIPTION
[0028] The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
[0029] Further, spatially relative terms, such as beneath, below, lower, above, upper and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
[0030] Numerical values in the specification and claims of this application should be understood to include numerical values which are the same when reduced to the same number of significant figures and numerical values which differ from the stated value by less than the experimental error of conventional measurement technique of the type described in the present application to determine the value. All ranges disclosed herein are inclusive of the recited endpoint.
[0031] The term about can be used to include any numerical value that can vary without changing the basic function of that value. When used with a range, about also discloses the range defined by the absolute values of the two endpoints, e.g. about 2 to about 4 also discloses the range from 2 to 4. The term about may refer to plus or minus 10% of the indicated number.
[0032] The present disclosure relates to structures which are made up of different layers. When the terms on or upon or over are used with reference to two different layers (including the substrate), they indicate merely that one layer is on or upon the other layer. These terms do not require the two layers to directly contact each other, and permit other layers to be between the two layers. For example all layers of the structure can be considered to be on the substrate, even though they do not all directly contact the substrate. The term directly may be used to indicate two layers directly contact each other without any layers in between them.
[0033] The present disclosure relates to various methods for forming a continuous poly on diffusion edge (CPODE) structure. In this regard, a CPODE structure or pattern may be used as an electrically insulating or dielectric structure or feature on the wafer. This provides electrical isolation between neighboring active device regions, such as transistors. This may be useful for reducing parasitic capacitance between active device regions, which increases processing speed. A CPODE structure can also be used as a vertically-oriented capacitor.
[0034] The present disclosure uses mandrel-spacer techniques to form integrated circuit structures such as semiconductor devices or transistors. Such techniques include self-aligned double patterning (SADP), which reduces the pitch of the exposed pattern by half. The methods described herein reduce the depth/width ratio during etching, permitting better etching process control and more stable device isolation performance.
[0035]
[0036] First, in step 105, one or more hardmask layers is/are applied to the substrate. This is typically performed by deposition of appropriate materials. Referring to
[0037] Here, three hardmask layers 210, 212, 214 are shown already deposited over the substrate 202. The first hardmask layer 210 directly contacting the substrate is a pad oxide layer. The oxide used to form the pad oxide layer can be, for example, a silicon oxide such as silicon dioxide (SiO.sub.2), AlO.sub.x, HfO.sub.x, ZrO.sub.x, or other suitable material. The pad oxide layer can be formed by thermal oxidation, PVD, CVD, ALD, oxidation, or other suitable deposition technique. In some non-limiting examples, the pad oxide layer 210 may have a thickness or depth 211 of from about 10 angstroms to about 30 angstroms, although other values and ranges are also within the scope of this disclosure.
[0038] The second hardmask layer 212 is a nitride layer that is deposited upon the pad oxide layer 210. The nitride used to form the nitride layer can be, for example, silicon nitride or silicon oxynitride. The nitride layer can be formed by PVD, CVD, ALD, oxidation, or other suitable deposition technique. In some particular embodiments, the nitride layer 212 may have a thickness or depth 213 of from about 100 angstroms to about 1000 angstroms, although other values and ranges are also within the scope of this disclosure.
[0039] Finally, the third hardmask layer 214 is a capping oxide layer that is deposited upon the nitride layer 212. The capping oxide layer can also be formed, for example, a silicon oxide such as silicon dioxide (SiO.sub.2), AlO.sub.x, HfO.sub.x, ZrO.sub.x, or other suitable material. Again, the capping oxide layer can be formed by thermal oxidation, PVD, CVD, ALD, oxidation, or other suitable deposition technique. In some particular embodiments, the capping oxide layer 214 may have a thickness or depth 215 of from about 100 angstroms to about 1000 angstroms, although other values and ranges are also within the scope of this disclosure. Together, the pad oxide layer 210, the nitride layer 212, and the capping oxide layer 214 form a tri-layer patterning etch system, which allows for better control of subsequent etching steps.
[0040] Next, referring to both step 110 of
[0041] The mandrel can be formed by depositing a mandrel material layer, forming a photoresist layer upon the mandrel material layer, exposing the photoresist to radiation and developing the photoresist layer to form a mandrel pattern, and then etching the mandrel material layer to form the mandrel.
[0042] The material used to form the mandrel may be, for example, a dielectric material, for example a silicon oxide such as silicon dioxide (SiO.sub.2), a nitride such as silicon nitride or silicon oxynitride, polysilicon, a high-k dielectric material, or a low-k dielectric material.
[0043] The photoresist layer may be applied, for example, by spin coating, or by spraying, roller coating, dip coating, or extrusion coating. Typically, in spin coating, the substrate is placed on a rotating platen, which may include a vacuum chuck that holds the substrate in plate. The photoresist composition is then applied to the center of the substrate. The speed of the rotating platen is then increased to spread the resist evenly from the center of the substrate to the perimeter of the substrate. The rotating speed of the platen is then fixed, which can control the thickness of the final photoresist layer.
[0044] The photoresist layer may then be baked or cured to remove the solvent and harden the photoresist layer. In some particular embodiments, the baking occurs at a temperature of about 90 C. to about 110 C., although other values and ranges are also within the scope of this disclosure. The baking can be performed using a hot plate or oven, or similar equipment.
[0045] The photoresist layer is then patterned via exposure to radiation. The radiation may be any light wavelength which carries a desired mask pattern. In particular embodiments, EUV light having a wavelength of about 13.5 nm is used for patterning, as this permits smaller feature sizes to be obtained. This results in some portions of the photoresist layer being exposed to radiation, and some portions of the photoresist not being exposed to radiation. This exposure causes some portions of the photoresist to become soluble in the developer and other portions of the photoresist to remain insoluble in the developer.
[0046] An additional photoresist bake step (post exposure bake, or PEB) may occur after the exposure to radiation. For example, this may help in releasing acid leaving groups (ALGs) or other molecules that are significant in chemical amplification photoresist.
[0047] The photoresist layer is then developed using a developer. The developer may be an aqueous solution or an organic solution. The soluble portions of the photoresist layer are dissolved and washed away during the development step, leaving behind a photoresist pattern. One example of a common developer is aqueous tetramethylammonium hydroxide (TMAH). Other developers may include 2-heptanone, n-butyl acetate, isoamyl acetate, cyclohexanone, 5-methyl-2-hexanone, methyl-2-hydroxyisobutyrate, ethyl lactate or propylene glycol monomethyl ether acetate, n-pentyl acetate, n-butyl propionate, n-hexyl acetate, n-butyl butyrate, isobutyl butyrate, 2,5-dimethyl-4-hexanone, 2,6-dimethyl-4-heptanone, propyl isobutyrate, or isobutyl propionate. Generally, any suitable developer may be used. Sometimes, a post develop bake or hard bake may be performed to stabilize the photoresist pattern after development, for optimum performance in subsequent steps.
[0048] Generally, any etching step used herein may be performed using wet etching, dry etching, or plasma etching processes such as reactive ion etching (RIE) or inductively coupled plasma (ICP), or combinations thereof, as appropriate. The etching may be anisotropic. Depending on the material, etchants may include carbon tetrafluoride (CF.sub.4), hexafluoroethane (C.sub.2F.sub.6), octafluoropropane (C.sub.3F.sub.8), fluoroform (CHF.sub.3), difluoromethane (CH.sub.2F.sub.2), fluoromethane (CH.sub.3F), trifluoromethane (CHF.sub.3), carbon fluorides, nitrogen (N.sub.2), hydrogen (H.sub.2), oxygen (O.sub.2), argon (Ar), xenon (Xe), xenon difluoride (XeF.sub.2), helium (He), carbon monoxide (CO), carbon dioxide (CO.sub.2), fluorine (F.sub.2), chlorine (Cl.sub.2), oxygen (O.sub.2), hydrogen bromide (HBr), hydrofluoric acid (HF), nitrogen trifluoride (NF.sub.3), sulfur hexafluoride (SF.sub.6), boron trichloride (BCl.sub.3), ammonia (NH.sub.3), bromine (Br.sub.2), or the like, or combinations thereof in various ratios. For example, silicon dioxide can be wet etched using hydrofluoric acid and ammonium fluoride. Alternatively, silicon dioxide can be dry etched using various mixtures of CHF.sub.3, O.sub.2, CF.sub.4, and/or H.sub.2.
[0049] Next, in step 112 of
[0050] In step 115 of
[0051] Next, in step 120 of
[0052] The resulting structure is shown in
[0053] Next, in step 125 of
[0054] Then, in step 130, etching is performed to transfer the spacer pattern through the hardmask layers 204, 206, 208 into the substrate 202 and form fins. Appropriate and suitable etchants are used to etch through each layer. It is noted that due to the SADP process, the fin pitch is half that of the original mask pattern used to form the mandrel.
[0055] In step 135, the spacers are removed. The hardmask layers are also removed. The resulting structure is shown in
[0056] Two internal fins 245, 246 extend in the second axis adjacent the mandrel trench 226. These internal fins may also be described as a set or plurality of fins extending in the second axis 208. There are also two external fins 247 extending in the second axis spaced apart from the mandrel trench. Fins 241, 243, 245 are located in the first active region 252. Fins 242, 244, 246 are located in the second active region 254.
[0057] Next, in optional step 137 as illustrated in
[0058] After the fin etch mask is removed, the resulting structure is shown in
[0059] Next, referring to step 140 of
[0060] Referring now to step 145 of
[0061] Then, as seen in step 150 of
[0062] Referring to
[0063] In step 155 of
[0064] It is noted that as illustrated here, the dielectric material of the dielectric structure does not cover the shorter second portions 285 of the fins. However, other embodiments are contemplated where the dielectric material does cover the shorter second portions of the fins.
[0065] Some variations in this method are also described in
[0066] If step 137 is not performed, then the resulting structure after step 155 is shown in
[0067] As described in step 157 of
[0068] In another variation, rather than etching away the third fin and the fourth fin, the spacers used to form these fins are etched away. This is indicated in optional step 127, and begins after the mandrel is removed, as discussed in step 125 of
[0069] Referring now to
[0070] It is noted that although steps 127, 137, and 157 are individually identified as being optional steps in
[0071] It is also possible to completely etch away the internal fins 245, 246 that extend in the second axis. This could be done, for example, during any of the optional etching steps 127, 137, or 157, by appropriate patterning of the fin etch layer.
[0072] Alternatively, the internal fins 245, 246 could also be completely etched away during steps 140, 145, and 150 when the dielectric structure is formed. Such a variation is illustrated beginning in
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[0075] The CPODE structure is conventionally formed in one etching step, where continuous etching is performed through the fin and down into the substrate. The methods of
[0076] The methods of the present disclosure also permit the depth of the CPODE structure to be adjusted as desired through a combination of greater step etching rate control and Ultra-More-Etch (UME) depth. In addition, the depth of the overall CPODE structure can also be increased by about 10% to about 20%. This is illustrated in the example cross-sectional view of the integrated circuit 200 illustrated in
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[0079] The substrate with the CPODE structure may be further processed to obtain the desired integrated circuit. In addition, processing steps to form other structures on the substrate were omitted from the discussion above. For example, STI regions may have been formed between the fins before the hardmask layers were removed between
[0080] Some embodiments of the present disclosure thus relate to methods for forming a dielectric structure between a first active region and a second active region. A mandrel is formed that extends in a first axis over a substrate. Etching is performed to form a trench in the mandrel in a second axis normal to the first axis in a desired location for the dielectric structure. Spacers are formed on sidewalls of the mandrel. The mandrel is then removed. Etching into the substrate is done to form at least a first fin located in the first active region that extends in the first axis, a second fin located in the second active region that extends in the first axis, and a plurality of fins extending in the second axis. The spacers are then removed. A CPODE mask is formed that exposes the substrate between the plurality of fins extending in the second axis. Etching into the substrate through the CPODE mask is done to form a trench. The trench is then filled with a dielectric material up to at least a fin height, to form the dielectric structure between the first active region and the second active region.
[0081] The present disclosure also relates to integrated circuits comprising a substrate having a first active region and a second active region separated by a dielectric isolation region. A first fin is present in the first active region that comprises a longer first portion normal to the dielectric isolation region and a shorter second portion that parallels the dielectric isolation region. A second fin is present in the second active region that comprises a longer first portion normal to the dielectric isolation region and a shorter second portion that parallels the dielectric isolation region. The longer first portion of the first fin and the longer first portion of the second fin are in-line with each other. The shorter second portion of the first fin and the shorter second portion of the second fin are parallel to each other.
[0082] Other embodiments of the present disclosure also relate to methods for forming a first active region and a second active region. A mandrel is formed over a substrate. Etching is performed to form a trench in the mandrel. Etching into the substrate is then done to form a first fin and a third fin located in the first active region, a second fin and a fourth fin located in the second active region, and a plurality of shorter fins separating the first active region and the second active region. A fin etch mask is formed that exposes the third fin and the fourth fin. Etching is performed to remove the third fin and the fourth fin. A CPODE mask is formed that exposes the substrate between the plurality of shorter fins. Etching into the substrate through the CPODE mask is done to form a trench. The trench is then filled with a dielectric material to form an isolation region between the first active region and the second active region.
[0083] The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.