Optoelectronic circuit with low-flicker light-emitting diodes
09854632 · 2017-12-26
Assignee
Inventors
Cpc classification
H05B45/00
ELECTRICITY
H10H20/857
ELECTRICITY
H10H29/142
ELECTRICITY
H10H29/10
ELECTRICITY
International classification
H01L33/62
ELECTRICITY
Abstract
An optoelectronic circuit for receiving a variable voltage having alternating increasing and decreasing phases. The optoelectronic circuit includes an alternating arrangement of resistive elements and light-emitting diode sets mounted in series. Each set contains two terminals. Each resistive element is inserted between two consecutive sets. The optoelectronic circuit includes, for each set among a plurality of said sets, a depletion mode metal oxide semiconductor field effect transistor, the drain and the source of which are coupled with the terminals of said set and the gate of which is coupled with one of the terminals of the next set. An additional resistive element is, for at least some of the transistors, coupled between the drain or the source of the transistor and one of the terminals of the set.
Claims
1. An optoelectronic circuit intended to receive a variable voltage containing an alternation of increase and decrease phases, the optoelectronic circuit comprising: an alternation of resistive elements and of sets of series-assembled light-emitting diodes, each set comprising two terminals, each resistive element being interposed between two successive sets, the resistive elements and the sets of series-assembled light-emitting diodes being mounted in series; for each set from among a plurality of said sets, a depletion metal-oxide gate field effect transistor having its drain and its source coupled to the terminals of said set and having its gate coupled to one of the terminals of the next set, an additional resistive element being, for at least some of the transistors, coupled between the drain or the source of the transistor and one of the terminals of said set.
2. The optoelectronic circuit of claim 1, comprising N sets, where N is an integer in the range from 2 to 200, and comprising for each of the N1 sets, a depletion metal-oxide gate field effect transistor having its drain and its source coupled to the terminals of said set and having its gate coupled to one of the terminals of the next set.
3. The optoelectronic circuit of claim 1, wherein at least some of the resistive elements have different resistance values.
4. The optoelectronic circuit of claim 1, where each resistive element comprises at least one electric resistor.
5. The optoelectronic circuit of claim 1, further comprising a fullwave rectifying circuit capable of supplying said voltage (VALIM).
6. The optoelectronic circuit of claim 1, comprising an integrated circuit comprising the sets of light-emitting diodes, the resistive elements, and the transistors.
7. The optoelectronic circuit of claim 1, wherein each light-emitting diode is a planar diode.
8. The optoelectronic circuit of claim 1, comprising an integrated circuit comprising a support, the sets of light-emitting diodes resting on the support, each light-emitting diode comprising at least one wire-shaped, conical, or frustoconical semiconductor element.
9. The optoelectronic circuit of claim 8, further comprising at least one insulating layer at least partially covering the support and, for each transistor, a semiconductor portion extending on the insulating layer and forming the source, the drain of the transistor, and the channel of the transistor, an insulating portion covering the semiconductor portion on the side opposite to the insulating layer and forming the gate insulator of the transistor.
10. The optoelectronic circuit of claim 8, wherein the support comprises a non-doped or doped semiconductor substrate of a first conductivity type, the optoelectronic circuit comprising, for each transistor, doped semiconductor regions of a second conductivity type, more heavily doped than the substrate, extending into the substrate and forming the source, the drain, and the channel of the transistor and an insulating portion extending on the substrate and forming the gate insulator of the transistor.
11. An optoelectronic circuit intended to receive a variable voltage containing an alternation of increase and decrease phases, the optoelectronic circuit comprising: an alternation of resistive elements and of sets of series-assembled light-emitting diodes, each set comprising two terminals, each resistive element being interposed between two successive sets; for each set from among a plurality of said sets, a depletion metal-oxide gate field effect transistor having its drain and its source coupled to the terminals of said set and having its gate coupled to one of the terminals of the next set, an additional resistive element being, for at least some of the transistors, coupled between the drain or the source of the transistor and one of the terminals of said set.
12. The optoelectronic circuit of claim 11, comprising N sets, where N is an integer in the range from 2 to 200, and comprising for each of the N1 sets, a depletion metal-oxide gate field effect transistor having its drain and its source coupled to the terminals of said set and having its gate coupled to one of the terminals of the next set.
13. The optoelectronic circuit of claim 11, wherein at least some of the resistive elements have different resistance values.
14. The optoelectronic circuit of claim 11, where each resistive element comprises at least one electric resistor.
15. The optoelectronic circuit of claim 11, further comprising a fullwave rectifying circuit capable of supplying said voltage (VALIM).
16. The optoelectronic circuit of claim 11, comprising an integrated circuit comprising the sets of light-emitting diodes, the resistive elements, and the transistors.
17. The optoelectronic circuit of claim 11, wherein each light-emitting diode is a planar diode.
18. The optoelectronic circuit of claim 11, comprising an integrated circuit comprising a support, the sets of light-emitting diodes resting on the support, each light-emitting diode comprising at least one wire-shaped, conical, or frustoconical semiconductor element.
19. The optoelectronic circuit of claim 18, further comprising at least one insulating layer at least partially covering the support and, for each transistor, a semiconductor portion extending on the insulating layer and forming the source, the drain of the transistor, and the channel of the transistor, an insulating portion covering the semiconductor portion on the side opposite to the insulating layer and forming the gate insulator of the transistor.
20. The optoelectronic circuit of claim 18, wherein the support comprises a non-doped or doped semiconductor substrate of a first conductivity type, the optoelectronic circuit comprising, for each transistor, doped semiconductor regions of a second conductivity type, more heavily doped than the substrate, extending into the substrate and forming the source, the drain, and the channel of the transistor and an insulating portion extending on the substrate and forming the gate insulator of the transistor.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The foregoing and other features and advantages will be discussed in detail in the following non-limiting description of specific embodiments in connection with the accompanying drawings, among which:
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DETAILED DESCRIPTION
(10) For clarity, the same elements have been designated with the same reference numerals in the various drawings and, further, the various drawings are not to scale. In the following description, unless otherwise indicated, terms substantially, approximately, and in the order of mean to within 10%. Further, compound mainly made of a material or compound based on a material means that a compound comprises a proportion greater than or equal to 95% of said material, this proportion being preferably greater than 99%. Further, in the present description, term connected is used to designate a direct electric connection, with no intermediate electronic component, for example, by means of a conductive track, and term coupled or term linked will be used to designate either a direct electric connection (then meaning connected) or a connection via one or a plurality of intermediate components (resistor, capacitor, etc.).
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(12) For i varying from 1 to N, optoelectronic circuit 30 comprises a resistor R.sub.i in series with light-emitting diode D.sub.i. Resistances R.sub.i have different values. Each general light-emitting diode D.sub.1 to D.sub.N comprises at least one elementary light-emitting diode and is preferably formed of the series and/or parallel connection of at least two elementary light-emitting diodes. In the present embodiment, for i varying from 1 to N1, the cathode of general light-emitting diode D.sub.i is coupled to a terminal of resistor R.sub.i and the other terminal of resistor R.sub.i is coupled to the anode of light-emitting diode D.sub.i+1. The anode of general light-emitting diode D.sub.1 is coupled to node A.sub.1. The cathode of light-emitting diode D.sub.N is coupled to a terminal of resistor R.sub.N and the other terminal of resistor R.sub.N is coupled to node A.sub.2. General light-emitting diodes D.sub.i, with i varying from 1 to N, may comprise the same number of elementary light-emitting diodes or different numbers of elementary light-emitting diodes.
(13) For i varying from 1 to N1, optoelectronic circuit 30 comprises a MOS transistor T.sub.i comprising first and second power terminals, that is, the drain and the source, and a control terminal, that is, the gate. The first power terminal of transistor T.sub.i is coupled to the anode of general light-emitting diode D.sub.i and the second power terminal of transistor T.sub.i is coupled to the cathode of general light-emitting diode D.sub.i. The gate of transistor T.sub.i is coupled to the anode of light-emitting diode D.sub.i+1. The bulk, or channel-forming region, of transistor T.sub.i is connected to the second power terminal of transistor T.sub.i. In the following description, it is considered that the first power terminal of transistor T.sub.i corresponds to the drain and the second power terminal of transistor T.sub.i corresponds to the source. Call V.sub.GSi the voltage between the gate and the source of transistor T.sub.i. Voltage V.sub.GSi corresponds to the voltage across resistor R.sub.i.
(14) Each transistor T.sub.i is a depletion MOS transistor. This MOS transistor is called normally-on, which means that it is in the on state when voltage V.sub.GSi is equal to 0 V. Transistor T.sub.i is in the off state when voltage V.sub.GSi is negative and smaller than a negative threshold voltage, for example in the order of 1 V. According to an embodiment, transistors T.sub.i are identical for i varying from 1 to N1. In particular, the threshold voltages of transistors T.sub.i are identical. According to another embodiment, the transistors are different. In particular, the threshold voltages of transistors T.sub.i are different.
(15) When transistor T.sub.i is in the on state, it short-circuits the associated general light-emitting diode D.sub.i, which then does not conduct current I.sub.ALIM. When transistor T.sub.i is in the off state, the associated general light-emitting diode D.sub.i conducts current I.sub.ALIM.
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(18) General light-emitting diodes D.sub.2 to D.sub.N may have a structure similar to that of the general light-emitting diode D.sub.1 shown in
(19) Elementary light-emitting diodes 32 may correspond to discrete components. As a variation, all the elementary light-emitting diodes 32 or some of them may be formed in integrated fashion on a single circuit. The other electronic components of the optoelectronic circuit, particularly, the resistors and the transistors, may be discrete components or may be at least partly formed in integrated fashion.
(20) Elementary light-emitting diodes 32 may be formed on a first circuit which is separate from a second circuit having the other electronic components of the optoelectronic circuit formed thereon. The first circuit is for example, attached to the second circuit by a flip-chip connection.
(21) As a variation, elementary light-emitting diodes 32 may be formed in integrated fashion with the other electronic components of the optoelectronic circuit or part of them.
(22) Elementary light-emitting diodes 32 are for example planar light-emitting diodes or light-emitting diodes formed from three-dimensional elements, particularly semiconductor microwires or nanowires, comprising, for example, a semiconductor material based on a compound mainly comprising a group-III element and a group-V element (for example, gallium nitride GaN), called III-V compound hereafter, or mainly comprising at least one group-II element and one group-VI element (for example zinc oxide ZnO), called II-VI compound hereafter.
(23) The operation of optoelectronic circuit 30 will now be described for an example where voltage V.sub.ALIM supplied by rectifying bridge 12 is a rectified sinusoidal voltage comprising a succession of cycles, in each of which voltage V.sub.ALIM increases from the zero value, crosses a maximum value, and decreases to the zero value.
(24) At the initial time, at the beginning of a cycle, voltage V.sub.ALIM is zero. Current I.sub.ALIM is thus also zero and voltages V.sub.GSi are equal to 0 V for i varying from 1 to N1. All transistors T.sub.i then are in the on state. When the voltage across general light-emitting diode D.sub.N increases above the threshold voltage of general light-emitting diode D.sub.N, general light-emitting diode D.sub.N becomes conductive. As voltage V.sub.ALIM in creases, current I.sub.ALIM, which is set by resistors R.sub.i, with i varying from 1 to N, increases. Thereby, each voltage V.sub.GSi, which is negative, increases in absolute value. However, since resistors R.sub.i have different values, voltages V.sub.GSi are different. For i varying from 1 to N1, each time voltage V.sub.GSi becomes smaller, in absolute value, than the threshold voltage of transistor T.sub.i, the latter turns off. For i varying from 1 to N1, transistors T.sub.i turn off at successive times which depend on the values of resistors R.sub.i and on the variation of power supply voltage V.sub.ALIM. Resistor R.sub.i is further selected so that, when transistor T.sub.i turns off, the voltage applied across general light-emitting diode D.sub.i is greater than the equivalent threshold voltage of general light-emitting diode D.sub.i. This equivalent threshold voltage is equal to the sum of the threshold voltages of the series-connected light-emitting diodes forming general light-emitting diode D.sub.i. Thus, general light-emitting diode D.sub.i is on after the switching to the off state of the transistor. In a phase of decrease of voltage V.sub.ALIM, transistors T.sub.i successively switch from the off state to the on state by short-circuiting the associated general light-emitting diodes D.sub.i.
(25) According to a variation, each resistor R.sub.i, or some of them, may be replaced with an electronic component or an assembly of electronic components having a resistance equivalent to R.sub.i. According to an embodiment, each resistor R.sub.i may be formed by a plurality of resistors, possibly of same value, assembled in parallel.
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(27) At a given time, during the variation of voltage V.sub.ALIM, the equivalent resistance of the conducting resistors of optoelectronic circuit 40 is substantially equal to the sum of all resistors R.sub.1 to R.sub.N and of each resistor R.sub.i series-connected with a transistor T.sub.i. Voltage V.sub.RES.sub._.sub.EQUIVALENTE across this equivalent resistor is equal to V.sub.ALIM decreased by the sum of the voltages across conducting general light-emitting diodes D.sub.i. The current flowing through optoelectronic circuit 40 is thus equal to the ratio of voltage V.sub.RES.sub._.sub.EQUIVALENTE to the equivalent resistance of the conducting resistors. This means that the equivalent resistance of optoelectronic circuit 40 is maximum when voltage V.sub.ALIM is zero, decreases in stages during a phase of increase of voltage V.sub.ALIM, each time one of transistors T.sub.i switches off, is minimum when voltage V.sub.ALIM is maximum and increases in stages during a phase of decrease of voltage V.sub.ALIM, each time one of transistors T.sub.i turns on. The resulting current is thus minimum when V.sub.ALIM is zero, increases in stages, each time one of transistors T.sub.i switches off, is maximum when voltage V.sub.ALIM is maximum, and decreases in stages during a phase of decrease of voltage V.sub.ALIM, each time one of transistors T.sub.i turns on. This advantageously enables to increase the power factor of optoelectronic circuit 40 with respect to optoelectronic circuit 30.
(28) An advantage of the previously-described embodiments is that optoelectronic circuit 30, 40 comprises no control unit capable of controlling the turning on or off of transistors T.sub.i. Indeed, the switching between the on and off states of each transistor T.sub.i is automatically performed during the variation of voltage V.sub.ALIM. The structure of optoelectronic circuit 30, 40 is thus particularly simple. Another advantage is that, since the control of light-emitting diodes is performed by MOS transistors and resistors, the electronic components may advantageously be formed in integrated fashion with the light-emitting diodes.
(29) The previously-described optoelectronic circuits 30 and 40 may be formed by an optoelectronic device comprising planar light-emitting diodes or formed from three-dimensional elements, for example, microwires, nanowires, conical elements, or frustoconical elements. In the following description, embodiments will be described for light-emitting diodes formed from microwires or nanowires. However, these embodiments may be implemented for three-dimensional elements other than microwires or nanowires, for example, pyramidal three-dimensional elements.
(30) Term microwire or nanowire designates a three-dimensional structure having an elongated shape along a preferred direction, having at least two dimensions, called minor dimensions, in the range from 5 nm to 2.5 m, preferably from 50 nm to 2.5 m, the third dimension, called major dimension, being at least equal to 1 time, preferably at least 5 times, and more preferably still at least 10 times, the largest minor dimension. In certain embodiments, the minor dimensions may be smaller than or equal to approximately 1 m, preferably in the range from 100 nm to 1 m, more preferably from 100 nm to 300 nm. In certain embodiments, the height of each microwire or nanowire may be greater than or equal to 500 nm, preferably in the range from 1 m to 50 m.
(31) In the following description, term wire is used to mean microwire or nanowire. Preferably, the median line of the wire which runs through the centers of gravity of the cross-sections, in planes perpendicular to the preferred direction of the wire, is substantially rectilinear and is called axis of the wire hereafter.
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(36) A conductive layer, not shown, covering electrode layer 66.sub.1, 66.sub.2 between wires 60.sub.1, 60.sub.2 but which does not extend on wires 60.sub.1, 60.sub.2, may be provided. An encapsulation layer, not shown, covering the entire structure and particularly each electrode layer 66.sub.1, 66.sub.2 may be provided. Optoelectronic device 45 may further comprise a layer of phosphors, not shown, confounded with the encapsulation layer or provided on the encapsulation layer.
(37) Wire 60.sub.1 and the associated shell 62.sub.1 form an elementary light-emitting diode of general light-emitting diode D.sub.1 and wire 60.sub.2 and the associated shell 62.sub.2 form an elementary light-emitting diode of general light-emitting diode D.sub.2. In the present embodiment, the support supporting the light-emitting diodes comprises substrate 50 and seed pads 56.sub.1, 56.sub.2. Semiconductor portion 74 forms the gate of transistor T.sub.1. Insulating portion 72 forms the gate insulator of transistor T.sub.1. The channel of transistor T.sub.1 corresponds to the area of semiconductor region 70 covered with insulating portion 72. The drain and the source of transistor T.sub.1 correspond to the lateral areas of semiconductor region 70. Resistor R.sub.1 is formed by semiconductor portion 82. As a variation, resistor R.sub.1 may be formed by a semiconductor region formed in substrate 50.
(38) In the present embodiment, semiconductor substrate 50 corresponds to a monolithic structure. Semiconductor substrate 50 for example is a substrate made of silicon, of germanium, of silicon carbide, of a III-V compound such as GaN or GaAs, or a ZnO substrate. Preferably, substrate 50 is a single-crystal silicon substrate. Substrate 50 is non-doped or lightly-doped with a dopant concentration smaller than or equal to 5*10.sup.16 atoms/cm.sup.3, preferably substantially equal to 10.sup.15 atoms/cm.sup.3. Substrate 50 has a thickness in the range from 275 m to 1.5 mm, preferably 725 m. In the case of a silicon substrate 50, examples of P-type dopants are boron (B) or indium (In) and examples of N-type dopants are phosphorus (P), arsenic (As), or antimony (Sb). Preferably, substrate 50 is P-type boron-doped.
(39) Seed pads 56.sub.1, 56.sub.2, also called seed islands, are made of a material favoring the growth of wires 60.sub.1, 60.sub.2. As a variation, seed pads 56.sub.1, 56.sub.2 may be replaced with a seed layer covering surface 52 of substrate 50 in the area associated with each light-emitting diode D.sub.1, D.sub.2. Further, seed pads 56.sub.1, 56.sub.2 provide the electric continuity between wires 60.sub.1, 60.sub.2 and the underlying doped regions 54.sub.1, 54.sub.2. As an example, the material forming seed pads 56.sub.1, 56.sub.2 may be a nitride, a carbide, or a boride of a transition metal from column IV, V, or VI of the periodic table of elements or a combination of these compounds. Seed pads 56.sub.1, 56.sub.2 may be doped with the same conductivity type as substrate 50.
(40) Seed pads 56.sub.1, 56.sub.2 may be obtained by depositing a seed layer on surface 52 and by etching portions of the seed layer all the way to surface 52 of substrate 50 to delimit the seed pads. The seed layer may be deposited by a method such as chemical vapor deposition (CVD) or metal-organic chemical vapor deposition (MOCVD), also known as metal-organic vapor phase epitaxy (MOVPE). However, methods such as molecular beam epitaxy (MBE), gas-source MBE (GSMBE), metal-organic MBE (MOMBE), plasma-assisted MBE (PAMBE), atomic layer epitaxy (ALE), hydride vapor phase epitaxy (HVPE), or an atomic layer deposition (ALD), may be used. Further, methods such as evaporation or reactive cathode sputtering may be used.
(41) When seed pads 56.sub.1, 56.sub.2 are made of aluminum nitride, they may be substantially textured and have a preferred polarity. The texturing of pads 56.sub.1, 56.sub.2 may be obtained by an additional treatment performed after the deposition of the seed layer. It for example is an anneal under an ammonia flow (NH.sub.3).
(42) Insulating layers 58, 64 may be made of a dielectric material, for example, of silicon oxide (SiO.sub.2), of silicon nitride (Si.sub.xN.sub.y, where x is approximately equal to 3 and y is approximately equal to 4, for example, Si.sub.3N.sub.4), of silicon oxynitride (SiO.sub.xN.sub.y, where x may be approximately equal to and y may be approximately equal to 1, for example, Si.sub.2ON.sub.2), of aluminum oxide (Al.sub.2O.sub.3), of hafnium oxide (HfO.sub.2), or of diamond. As an example, the thickness of each insulating layer 58, 64 is in the range from 5 nm to 800 nm, for example, equal to approximately 30 nm.
(43) Wires 60.sub.1, 60.sub.2 are at least partly formed from at least one semiconductor material. The semiconductor material may be silicon, germanium, silicon carbide, a III-V compound, a II-VI compound, or a combination of these compounds.
(44) Wires 60.sub.1, 60.sub.2 may be at least partly formed of semiconductor materials mainly comprising a III-V compound, for example, III-N compounds. Examples of group-III elements comprise gallium (Ga), indium (In), or aluminum (Al). Examples of III-N compounds are GaN, AlN, InN, InGaN, AlGaN, or AlInGaN. Other group-V elements may also be used, for example, phosphorus or arsenic. Generally, the elements in the III-V compound may be combined with different molar fractions.
(45) Wires 60.sub.1, 60.sub.2 may be at least partly formed based on semiconductor materials mainly comprising a II-VI compound. Examples of group-II elements comprise group-IIA elements, particularly beryllium (Be) and magnesium (Mg), and group-IIB elements, particularly zinc (Zn) and cadmium (Cd). Examples of group-VI elements comprise group-VIA elements, particularly oxygen (O) and tellurium (Te). Examples of II-VI compounds are ZnO, ZnMgO, CdZnO, or CdZnMgO. Generally, the elements in the II-VI compound may be combined with different molar fractions.
(46) Wires 60.sub.1, 60.sub.2 may comprise a dopant. As an example, for III-V compounds, the dopant may be selected from the group comprising a group-II P-type dopant, for example, magnesium (Mg), zinc (Zn), cadmium (Cd), or mercury (Hg), a group-IV P-type dopant, for example, carbon (C), or a group-IV N-type dopant, for example, silicon (Si), germanium (Ge), selenium (Se), sulfur (S), terbium (Tb), or tin (Sn).
(47) The cross-section of wires 60.sub.1, 60.sub.2 may have different shapes, such as, for example, oval, circular, or polygonal, particularly triangular, rectangular, square, or hexagonal. It should thus be understood that term diameter mentioned in relation with a cross-section of a wire or of a layer deposited on this wire designates a quantity associated with the surface area of the targeted structure in this cross-section, corresponding, for example, to the diameter of the disk having the same surface area as the wire cross-section. The average diameter of each wire 60.sub.1, 60.sub.2 may be in the range from 50 nm to 2.5 m. The height of each wire 60.sub.1, 60.sub.2 may be in the range from 250 nm to 50 m. Each wire 60.sub.1, 60.sub.2 may have an elongated semiconductor structure along an axis substantially perpendicular to surface 52. Each wire 60.sub.1, 60.sub.2 may have a generally cylindrical shape. The axes of two adjacent wires of a same general light-emitting diode may be distant by from 0.5 m to 10 m and preferably from 1.5 m to 5 m. As an example, wires 60.sub.1, 60.sub.2 may be regularly distributed, particularly in a hexagonal network.
(48) As an example, the lower portion of each wire 60.sub.1, 60.sub.2 is mainly formed of the III-N compound, for example, gallium nitride, of same doping type as substrate 50, for example, of type N, for example, silicon-doped. Lower portion 60.sub.1, 60.sub.2 extends up to a height which may be in the range from 100 nm to 25 m.
(49) As an example, the upper portion of each wire 60.sub.1, 60.sub.2 is at least partially made of a III-N compound, for example, GaN. The upper portion may be doped with the same conductivity type as the lower portion of wire 60.sub.1, 60.sub.2, for example, of type N, and may possibly be less heavily doped than the lower portion or may not be intentionally doped. The upper portion extends up to a height which may be in the range from 100 nm to 25 m.
(50) Wires 60.sub.1, 60.sub.2 may be grown by a method of CVD, MOCVD, MBE, GSMBE, PAMBE, ALE, HVPE, ALD type. Further, electrochemical methods may be used, for example, chemical bath deposition (CBD), hydrothermal methods, liquid-feed flame spray pyrolysis, or electrodeposition.
(51) As an example, the wire growth method may comprise injecting into a reactor a precursor of a group-III element and a precursor of a group-V element. Examples of precursors of group-III elements are trimethylgallium (TMGa), triethylgallium (TEGa), trimethylindium (TMIn), or trimethylaluminum (TMAl). Examples of precursors of group-V elements are ammonia (NH.sub.3), tertiarybutylphosphine (TBP), arsine (AsH.sub.3), or unsymmetrical dimethylhydrazine (UDMH).
(52) According to an embodiment of the invention, in a first phase of growth of the wires of the III-V compound, a precursor of an additional element is added in excess, in addition to the precursors of the III-V compound. The additional element may be silicon (Si). An example of a precursor of silicon is silane (SiH.sub.4).
(53) The presence of silane among the precursor gases causes the incorporation of silicon within the GaN compound. A lower N-type doped portion of wires 60.sub.1, 60.sub.2 is thus obtained. This further translates as the forming of a silicon nitride layer, not shown, which covers the periphery of the portion of wires 60.sub.1, 60.sub.2, except for the top, as the lower portion grows.
(54) For the growth of the upper portion, the operating conditions used for the growth of the lower portion are, as an example, maintained, but for the fact that the flow of the precursor of the additional element, for example, silane, is decreased or stopped. Even when the silane flow is stopped, the upper portion of wires 60.sub.1, 60.sub.2 may be N-type doped due to the diffusion in this active portion of dopants originating from the adjacent passivated portions or due to the residual doping of GaN.
(55) Shell 62.sub.1, 62.sub.2 may comprise a stack of a plurality of layers, particularly comprising: an active layer covering the upper portion of the associated wire 60.sub.1, 60.sub.2; an intermediate layer having a conductivity type opposite to that of the lower portion of wire 60.sub.1, 60.sub.2 and covering the active layer; and a bonding layer covering the intermediate layer and covered with electrode 66.sub.1, 66.sub.2.
(56) The active layer is the layer from which most of the radiation delivered by the elementary light-emitting diode is emitted. According to an example, the active layer may comprise confinement means, such as multiple quantum wells. It is for example formed of an alternation of GaN and InGaN layers having respective thicknesses from 5 to 20 nm (for example, 8 nm) and from 1 to 10 nm (for example, 2.5 nm). The GaN layers may for example be N-type or P-type doped. According to another example, the active layer may comprise a single InGaN layer, for example having a thickness greater than 10 nm.
(57) The intermediate layer, for example, P-type doped, may correspond to a semiconductor layer or to a stack of semiconductor layers and allows the forming of a PN or PIN junction, the active layer being located between the intermediate P-type layer and the upper N-type portion of wire 60.sub.1, 60.sub.2 of the PN or PIN junction.
(58) The bonding layer may correspond to a semiconductor layer or to a stack of semiconductor layers and enables to form an ohmic contact between the intermediate layer and electrode 66.sub.1, 66.sub.2. As an example, the bonding layer may be very heavily doped, of a type opposite to that of the lower portion of each wire 60.sub.1, 60.sub.2, to degenerate the semiconductor layer(s), for example, P-type doped at a concentration greater than or equal to 10.sup.20 atoms/cm.sup.3.
(59) The stack of semiconductor layers may comprise an electron barrier layer formed of a ternary alloy, for example, aluminum gallium nitride (AlGaN) or aluminum indium nitride (AlInN) in contact with the active layer and the intermediate layer, to provide a good distribution of electric carriers in the active layer.
(60) Electrode 66.sub.1, 66.sub.2 is capable of biasing the active layer of each wire 60.sub.1, 60.sub.2 and of letting through the electromagnetic radiation emitted by the light-emitting diodes. The material forming electrode 66.sub.1, 66.sub.2 may be a transparent conductive material such as indium tin oxide (ITO), aluminum zinc oxide, or graphene. As an example, electrode layer 66.sub.1, 66.sub.2 has a thickness in the range from 5 nm to 200 nm, preferably from 20 nm to 50 nm.
(61) The encapsulation layer may be made of an at least partially transparent insulating material. The minimum thickness of the encapsulation layer is in the range from 250 nm to 50 m so that the encapsulation layer fully covers electrode 66.sub.1, 66.sub.2 at the top of the sets of light-emitting diodes D.sub.1, D.sub.2. The encapsulation layer may be made of an at least partially transparent inorganic material. As an example, the inorganic material is selected from the group comprising silicon oxides of SiO.sub.x type, where x is a real number between 1 and 2, or SiO.sub.yN.sub.z type, where y and z are real numbers between 0 and 2, and aluminum oxides, for example, Al.sub.2O.sub.3. The encapsulation layer may be made of an at least partially transparent organic material. As an example, the encapsulation layer is a silicone polymer, an epoxide polymer, an acrylic polymer, or a polycarbonate.
(62) Semiconductor portion 68 may be made of the same materials as substrate 50. It may be formed by epitaxy or by deposition after opening of insulating layers 58 and 64.
(63) Semiconductor region 70 may be made of the same materials as substrate 50. Semiconductor region 70 may have a thickness in the range from 10 nm to 500 nm. Semiconductor region 70 may be formed by deposition and then shaped by etching after a photolithography step.
(64) Insulating portion 72 may be made of silicon oxide of SiO.sub.x type, where x is a real number in the range from 1 to 2, or SiO.sub.yN.sub.z type, where y and z are real numbers in the range from 0 to 2, of hafnium oxide HfO.sub.2, of lanthanum oxide La.sub.2O.sub.3, of zirconium oxide ZrO.sub.2, of tantalum oxide Ta.sub.2O.sub.3, or of a compound of the previous materials. Insulating portion 72 may have a thickness in the range from 1 nm to 25 nm. Insulating portion 72 may be formed by deposition or by oxidation of semiconductor region 70.
(65) Semiconductor portion 74 may be made of polysilicon, of titanium nitride (TiN), of tungsten (W), of tantalum nitride (TaN), of tantalum (Ta), or of platinum (Pt), or of a multilayer of these materials. Semiconductor portion 74 may have a thickness in the range from 10 nm to 200 nm. Semiconductor portion 74 may be formed by CVD, by physical vapor deposition (PVD), or by plasma-enhanced CVD (PECVD).
(66) Semiconductor or metal portion 82 may be made of polysilicon, tungsten, copper, nickel, molybdenum, silver, gold, palladium, platinum, or an alloy, for example, of iron-nickel (FeNi) or of iron-nickel-cobalt (FeNiCo). Semiconductor or metal portion 82 may have a thickness in the range from 10 nm to 150 nm. Semiconductor portion 82 may be formed by deposition and then patterned by photolithography and etch steps.
(67)
(68)
(69) Various embodiments with different variations have been described hereabove. It should be noted that those skilled in the art may combine various elements of these various embodiments and variations without showing any inventive step.