METHOD OF MANUFACTURING SEMICONDUCTOR DEVICE AND SPUTTERING APPARATUS
20170345629 ยท 2017-11-30
Inventors
Cpc classification
H01L21/28052
ELECTRICITY
H10D84/017
ELECTRICITY
H10D64/66
ELECTRICITY
H10D30/601
ELECTRICITY
International classification
Abstract
Reliability of a semiconductor device is improved, and use efficiency of a sputtering apparatus is increased. When depositing thin films over a main surface of a semiconductor wafer using a magnetron sputtering apparatus in which a collimator is installed in a space between the semiconductor wafer and a target installed in a chamber, a region inner than a peripheral part of the collimator is made thinner than the peripheral part. Thus, it becomes possible to suppress deterioration in uniformity of the thin film in a wafer plane, which may occur as the integrated usage of the target increases.
Claims
1. A method of manufacturing a semiconductor device comprising a step of: depositing thin films containing components for configuring a target over a main surface of a semiconductor wafer with use of a sputtering apparatus which includes: a chamber; a wafer stage installed in the chamber and supporting the semiconductor wafer; the target so installed as to oppose the semiconductor wafer supported by the wafer stage; and a collimator installed in a space between the semiconductor wafer supported by the wafer stage and the target and having a plurality of through holes provided along its thickness direction, wherein a region inner than a peripheral part of the collimator is thinner than the peripheral part.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0037] Hereafter, embodiments of the present invention will be explained in detail based on the accompanying drawings. Also, components having the same function are denoted by the same or related reference symbols throughout all the drawings for describing the embodiments, and the repetitive description thereof will be omitted. In addition, the description of the same or similar portions is not repeated in principle unless particularly required in the embodiments described below. Furthermore, in some drawings used in the embodiments, hatching is omitted even in a cross-sectional view so as to make the configuration easy to understand in some cases.
First Embodiment
[0038]
[0039] The sputtering apparatus 40 includes a chamber 41 which is a film deposition container. An inner space of the chamber 41 is sealed with a shield 42 and a backing plate 43 covering an upper portion thereof, and is set to be under a desired pressure (degree of vacuum) by a vacuum pump 44, such as a cryopump and a dry pump. Into the chamber 41, a sputtering gas, such as an Ar (argon) gas, is supplied at a desired rate of flow through a mass flow controller 45.
[0040] In the center of the chamber 41, there are installed a support table (wafer stage) 46 for supporting a semiconductor wafer SW and a vertically movable lifter 53 for installing the semiconductor wafer SW over the wafer stage 46. The semiconductor wafer SW is mounted over an upper surface of the wafer stage 46 with its main surface facing upward and is fixed to the wafer stage 46 by a covering 47. The semiconductor wafer SW includes, for example, a single-crystal silicon substrate having a diameter of 300 mm and a thickness of about 0.7 to 0.8 mm, for example. The semiconductor wafer SW mounted over the upper surface of the wafer stage 46 is heated to a desired temperature by a heater (not shown) which is built in the wafer stage 46.
[0041] Above the wafer stage 46, there is arranged a target 48 supported by the backing plate 43 so as to oppose the semiconductor wafer SW over the wafer stage 46. The target 48 is a disc-like thin plate of a high purity metal or alloy having a thickness of about 3 mm, and is fixed to a bottom surface of the backing plate 43 by metal bonding or diffusion bonding. The target 48 fixed to the backing plate 43 and its bottom surface form a cathode (negative pole) to which a direct-current voltage or a high frequency voltage is impressed.
[0042] In an upper portion of the backing plate 43, there is installed a magnet part 49 in which a magnet (permanent magnet) is housed near the target 48 for producing a magnetic field perpendicularly to the electric field. The magnetic field produced by the magnet part 49 promotes ionization collision between electrons emitted from the target 48 forming the cathode and the Ar gas, and serves to efficiently draw Ar ions onto the surface of the target 48 and allow the surface to be sputtered. The magnet part 49 is attached to the upper portion of the backing plate 43 in a state of being rotatable in a horizontal plane so that the surface of the target 48 is uniformly sputtered.
[0043] A collimator 50a is installed in a space between the target 48 fixed to the bottom surface of the backing plate 43 and the semiconductor wafer SW over the wafer stage 46. The collimator 50a is a disc-like metal plate of Ti (titanium), SUS (stainless steel), etc. in which numbers of through holes 51 are made and its diameter is larger than the semiconductor wafer SW. A peripheral part of the collimator 50a is screwed to the shield 42 of the chamber 41 so that it may be parallel to both an undersurface of the target 48 and a main surface of the semiconductor wafer SW.
[0044] When the collimator 50a is arranged in the space between the semiconductor wafer SW and the target 48, sputtered particles show the following behaviors. That is, among the sputtered particles kicked out from the surface of the target 48 due to the collision of the Ar ions, sputtered particles flying at an oblique angle greater than a prescribed angle with respect to the main surface of the semiconductor wafer SW collide with inner walls of the through holes 51 of the collimator 50a and do not reach the semiconductor wafer SW. In other words, only the sputtered particles flying vertically or at an angle close to it with respect to the main surface of the semiconductor wafer SW pass through the through holes 51 and reach the main surface of the semiconductor wafer SW. Thus, sputtered particles having many vertical components are allowed to enter the main surface of the semiconductor wafer SW. Therefore, it becomes possible to improve coverage, for example, at the bottom portion of a connection hole having a high aspect ratio. Also, the collimator 50a has a function of capturing charged particles (mainly electrons). Therefore, by arranging the collimator 50a in the space between the semiconductor wafer SW and the target 48, it is possible also to obtain an effect of reducing the plasma damage given to the semiconductor wafer SW.
[0045] Incidentally, in an ordinarily employed sputtering apparatus using a collimator, the present inventors have found out the following. That is, when the integrated usage of the target increases, as shown in
[0046] The first factor includes changes in the advancing direction and amount of the sputtered particles caused by a change in the form of erosion (electric erosion) produced while the target is in use.
[0047] The film thickness distribution of thin films deposited over the semiconductor wafer depends upon a distribution of erosion regions (a range where target forming elements are kicked out in a sputtering phenomenon and the target is consumed) over a surface of the target. In the case of the magnetron sputtering apparatus in which sputtering is performed while rotating the magnet arranged above the target, erosion peaks of the target are produced over concentric circles along a trajectory of the rotating magnet. However, when the integrated usage of the target increases and the erosion regions extend in a thickness direction of the target, the advancing direction and amount of the sputtered particles change from an initial state of the target. As a result, although depending on how the magnet is arranged, there are cases where thin films deposited on a central part side of the semiconductor wafer become thinner than those deposited on a peripheral part side.
[0048] The second factor includes changes in the advancing direction and amount of the sputtered particles caused by a change in the form of the through hole of the collimator brought about while the target 48 is in use.
[0049] As described above, among the sputtered particles kicked out from the surface of the target by the collision of the Ar ions, the sputtered particles (oblique-direction sputtered particles) flying at an oblique angle greater than the prescribed angle with respect to the main surface of the semiconductor wafer collide with the inner walls of the through holes of the collimator and do not reach the semiconductor wafer. In this regard, while such oblique-direction sputtered particles enter the through holes arranged near the central part of the collimator, oblique-direction sputtered particles enter the through holes arranged near the peripheral part of the collimator only from specific directions (from directions around the central part of the collimator).
[0050] As a result, when the integrated usage of the target increases, the amount of sputtered particles adhering to sidewalls of the through holes arranged near the central part of the collimator relatively increases. That is, diameters of the through holes arranged near the central part of the collimator become smaller (aspect ratios become higher) than those of the through holes arranged near the peripheral part. Consequently, as the integrated usage of the target increases, the number of the sputtered particles passing through the through holes arranged near the central part of the collimator and reaching the semiconductor wafer relatively decreases, and thin films deposited over a central part of the semiconductor wafer become thinner than those deposited over a peripheral part.
[0051] In view of the above, according to the present embodiment, arrangements as follows are worked out in the collimator 50a.
[0052] As shown in
[0053] In addition, a planar shape of the through hole 51 arranged near the peripheral part of the collimator 50a may be, in accordance with a circumferential shape of the collimator 50a, a shape different from the regular hexagon. For example, as shown in
[0054] In the peripheral part of the collimator 50a, there are provided four screw holes 52 for screwing the collimator 50a to the shield 42 of the chamber 41 shown in
[0055] With regard to the collimator 50a shown in
[0056] Next, an explanation will be given to one example of a manufacturing method of a CMOS (Complementary Metal Oxide Semiconductor) type semiconductor including a process of depositing a metal film over the semiconductor wafer SW using the sputtering apparatus 40 including the above collimator 50a. In this regard, there are called a pair of field effect transistors (a pair of field effect transistors whose conductive types are different from each other) configuring the CMOS type integrated circuit an n channel type MISFET (Metal Insulator Semiconductor Field Effect Transistor) and a p channel type MISFET.
[0057] First, as shown in
[0058] Next, a p type well 13 is formed by ion implantation of boron (B) into part of the main surface (n channel type MISFET formation area) of the semiconductor substrate 10 and an n type well 14 is formed by ion implantation of phosphorus (P) into the other part of the main surface (p channel type MISFET formation area) of the semiconductor substrate 10. Then, by steam-oxidizing the semiconductor substrate 10, gate oxide films 15 are formed over surfaces of the p type well 13 and the n type well 14, respectively.
[0059] Next, as shown in
[0060] Next, an n.sup. type semiconductor region 17 having a low concentration of impurities is formed by ion implantation of phosphorus or arsenic (As) into a p type well 13, and a p.sup. type semiconductor region 18 having a low concentration of impurities is formed by ion implantation of boron into an n type well 14.
[0061] Next, as shown in
[0062] Then, an n.sup.+ type semiconductor region (source or drain of the n channel type MISFET) 20 having a high concentration of impurities is formed by ion implantation of phosphorus or arsenic into the p type well 13, and a p.sup.+ type semiconductor regions (source or drain of the p channel type MISFET) 21 having a high concentration of impurities is formed by ion implantation of boron into the n type well 14.
[0063] Next, the surface of the semiconductor substrate 10 is washed with a buffered hydrofluoric acid type washing liquid. Then, the semiconductor substrate 10 (semiconductor wafer SW) is brought into the chamber 41 of the sputtering apparatus 40 shown in
[0064] Subsequently, a negative voltage (negative potential) is impressed to the target 48 after introducing the Ar gas of a predetermined rate of flow (for example, about 70 to 110 sccm) into the chamber 41, while setting the inside of the chamber 41 to a predetermined degree of vacuum (for example, about 1 to 810.sup.6 Pa). As a result, an electric field is produced between the target 48 and the semiconductor wafer SW, and Ar ions in plasma are generated inside the chamber 41. The Ar ions collide with the surface of the target 48 forming the cathode and drive out Co atoms contained in the target 48. When part of the target atoms (sputtered particles) driven out passes through the through holes 51 of the collimator 50a and reaches the main surface of the semiconductor wafer SW, as shown in
[0065] Next, with reference to
[0066] As described above, in the case of the magnetron sputtering apparatus 40 in which the sputtering is performed while rotating the magnet arranged above the target 48, an erosion peak EP of the target 48 is produced near a circular region along the trajectory of the rotating magnet. For example, when the magnets are arranged right above a central part, a peripheral part, and an intermediate part thereof, respectively, of the target 48, the erosion peaks EP of the target 48 become three-fold concentric circles as shown in the drawing.
[0067] In
[0068] Depths of all the through holes 51 of the collimator 50a of First Embodiment are shallower (aspect ratios are lower) than those of the ordinarily employed collimator. As a result, the film deposition area DA1 of the sputtered particles passing through the through holes 51 of the collimator 50a of First Embodiment and deposited over the semiconductor wafer SW becomes larger, with respect to all over the semiconductor wafer SW, than the film deposition area DA2 of the sputtered particles passing through the through holes of the ordinarily employed collimator and deposited over the semiconductor wafer SW. In either case, however, in the semiconductor wafer SW, rates at which adjacent film deposition areas DA overlap can be described as follows:
[0069] Central part>Intermediate part>Peripheral part
[0070] Therefore, when using the collimator 50a of First Embodiment, as compared with the case of using the ordinarily employed collimator, the film thickness is expected to increase at a more centrally located portion of the semiconductor wafer SW. That is, when comparing the film deposition area DA1 of First Embodiment with the ordinarily employed film deposition area DA2, the film thickness difference thereof in the intermediate part is bigger than that in the peripheral part of the semiconductor wafer SW, and the film thickness difference in the central part is bigger than that in the intermediate part.
[0071] Consequently, by depositing the Co film 22 (see
[0072] Next, a manufacturing process subsequent to the one shown in
[0073] Consequently, as shown in
[0074] In addition, the silicide layers formed over the surfaces of the source or drain (n.sup.+ type semiconductor region 20, p.sup.+ type semiconductor region 21) and the gate electrodes 16 are not limited to the Co silicide layers 23. For example, the silicide layer may be a Ni (nickel) silicide layer. In such a case, a Ni film is deposited over the semiconductor substrate 10 (semiconductor wafer SW) with use of the target 48 containing a high purity Ni.
[0075] Next, as shown in
[0076] Next, as shown in
[0077] Next, as shown in
[0078] Next, as shown in
[0079] In this regard, the Ta film configuring the barrier conductive film 31a and the Cu film configuring the seed film 31b are deposited using the sputtering apparatus 40 having the collimator 50a described above. That is, a high purity Ta target is used as a target 48 when depositing the barrier conductive film 31a, and a high purity Cu target is used as a target 48 when depositing the seed film 31b.
[0080] Thus, even when the integrated usage of the target 48 has increased, it becomes possible to secure uniformity of the thickness of the Ta film (barrier conductive film 31a) and the Cu film (seed film 31b) in the wafer plane. Moreover, the use efficiency of the target 48 is improved and the number of semiconductor wafers SW which can be processed by a single target 48 is increased. As a result, the manufacturing cost of the CMOS type integrated circuit can be reduced.
[0081] Next, as shown in
Second Embodiment
[0082]
[0083] According to the collimator 50b of Second Embodiment also, as in the collimator 50a of First Embodiment, the film thickness is expected to increase at a more centrally located portion of the semiconductor wafer SW. However, the aspect ratio of the through holes 51 arranged near the peripheral part is relatively high. Therefore, it has characteristics that the extension of the film deposition area DA is relatively small in the peripheral part of the semiconductor wafer SW.
[0084] As to the collimator 50b shown in
[0085] In addition, the undersurface side (the side opposed to the semiconductor wafer SW) of the collimator 50b shown in FIG. 16 becomes thinner from the peripheral part to the central part. In contrast, however, the upper surface side (the side opposed to the target 48) may become thinner from the peripheral part to the central part.
Third Embodiment
[0086]
[0087] The collimator 50c according to Third Embodiment is characterized in that the diameters of the through holes 51 continuously decrease in size from the peripheral part to the central part but its thickness is uniform on the whole.
[0088] Thus, as in the collimator 50b of Second Embodiment, the aspect ratio of the through holes 51 of the collimator 50c in Third Embodiment continuously decreases from the peripheral part to the central part. Therefore, the effect similar to that of the collimator 50b in Second Embodiment can be obtained.
[0089] In addition, the thickness of the collimator 50c shown in
[0090] While the invention achieved by the present inventors has been specifically described above based on the embodiments thereof, the present invention is not limited thereto. It will be appreciated that various changes and modifications can be made in the invention within the scope not departing from the gist thereof.
[0091] The phenomenon in which the thin films deposited over the central part of the semiconductor wafer become thinner than those over the peripheral part grows prominent as the integrated usage of the target increases. Therefore, for example, an ordinarily employed collimator may be used at the time of starting to use the target, and it may be switched to one of the collimators of First to Third Embodiments when the integrated usage of the target has increased to a certain degree.
[0092] Moreover, although depending on a layout or a size of the magnet mounted to the sputtering apparatus, as the integrated usage of the target increases, there are times when thin films deposited over the central part of the semiconductor wafer become thicker that those deposited over the peripheral part. In the case of depositing a thin film using such a sputtering apparatus, by using a collimator in which a peripheral part is made thinner than an inner region thereof, even when the integrated usage of the target has increased, it becomes possible to secure uniformity in film thickness of the thin film in the wafer plane.