Voltage matched multijunction solar cell

Abstract

A voltage matched multijunction solar cell having first and second solar cell stacks that are electrically connected parallel to each other. The first solar cell stack is optimized for absorption of incoming solar light in a first wavelength range and the second solar cell stack is optimized for absorption of incoming solar light in a second wavelength range, wherein the first and the second wavelength range do not or at most only partially overlap each other.

Claims

1. A method for the manufacture of a solar cell, which comprises: providing a first solar cell stack; providing a second solar cell stack; attaching the first solar cell stack on a first surface of a conduction layer; attaching the second solar cell stack on a second surface of the conduction layer opposite to the first surface; and electrically connecting the first and the second solar cell stacks parallel to each other; and wherein electrically connecting the first and the second solar cell stacks parallel to each other comprises: forming an insulation layer on edges or side faces of the first solar cell stack and the second solar cell stack and the conduction layer; and forming on the insulator layer, a metal layer connecting a contact, not already connected by the conduction layer, of the first solar cell stack and a contact of the second solar cell stack; and removing the insulation layer afterwards, leaving a bridge interconnect.

2. The method of claim 1, wherein the conduction layer comprises a semiconductor layer.

3. The method of claim 1, wherein electrically connecting the first and the second solar cell stacks parallel to each other comprises: forming an insulator layer on edges or side faces of the first solar cell stack and the second solar cell stack and the conduction layer; and forming on the insulator layer, a metal layer connecting a contact, not already connected by the conduction layer, of the first solar cell stack and a contact of the second solar cell stack.

4. The method of claim 3, wherein the metal layer is formed by vapor deposition.

5. The method of claim 1, wherein electrically connecting the first and the second solar cell stacks parallel to each other comprises connecting a contact of the first solar cell stack and a contact of the second solar cell stack that is electrically connected to a cooling substrate by a conductive wire.

6. The method of claim 1, wherein electrically connecting the first and the second solar cell stacks parallel to each other comprises connecting a front contact of the first solar cell stack and a backside contact of another solar cell stack that is connected to a cooling substrate by a conductive wire.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Additional features and advantages of the present disclosure will be described with reference to the drawings. In the description, reference is made to the accompanying figures that are meant to illustrate preferred embodiments of the present disclosure. It is understood that such embodiments do not represent the full scope of the present disclosure.

(2) FIG. 1 illustrates a voltage matched multijunction solar cell according to an example of the present disclosure. The voltage matched multijunction solar cell comprises two stacks of solar cells and a conduction layer arranged between the two stacks.

(3) FIG. 2 illustrates a voltage matched multijunction solar cell according to another example of the present disclosure. The voltage matched multijunction solar cell comprises two stacks of solar cells and a conduction layer arranged between the two stacks.

DETAILED DESCRIPTION

(4) As shown in FIG. 1 according to an exemplary realization of the present disclosure, a voltage matched multijunction solar cell 100 comprises a first solar cell stack 1 provided on a conduction layer 2 provided on a second solar cell stack 3. Each of the first and the second solar cell stacks 1 and 3 comprise one or more solar cells. The solar cells of the first solar cell stack 1 are electrically connected in series and the solar cells of the second solar cell stack 3 are electrically connected in series. In each of the solar cell stacks 1 and 3, current matching is performed. For example, the first solar cell stack 1 is adapted for absorption of photons of incoming solar light in the wavelength range of 300 nm to 750 nm (within a tolerance of some ±70 nm). The second solar cell stack 3 is adapted for optimal absorption at larger wavelengths (infrared regime).

(5) According to the present disclosure, the first solar cell stack 1 is electrically connected parallel to the second solar cell stack 3. Relative intensity shifts between the wavelength ranges suitable for the first and the second solar cell stacks 1 and 3, therefore, do not significantly affect the performance of the voltage matched multijunction solar cell 100. In order to achieve a high conversion efficiency, both solar cell stacks 1 and 3 advantageously have the same or a similar open-circuit voltage. Moreover, in order to save the complexity and expensiveness of the wiring, the first solar cell stack 1 and the second solar cell stack 3 show opposite (p-n) polarities and are connected by the conduction layer 2.

(6) The conduction layer 2 can be made of or comprise a doped semiconductor material. Due to the higher mobility of electrons compared to holes, an n doped semiconductor, for instance, an n++ doped semiconductor, may be provided for the conduction layer 2.

(7) According to an alternative embodiment, an embedded grid is provided rather than the conduction layer 2. The conduction layer 2 shows a higher integrated transparency than 80% over the wavelength range that is converted by the second solar cell stack 3.

(8) If an n doped semiconductor is provided for the conduction layer 2, the first solar cell stack 1 shows a p on n polarity, whereas, in this case, the second solar cell stack 3 shows an n on p polarity. Thereby, the base of the lowermost cell of the first solar cell stack 1, as well as the emitter of the uppermost cell of the second solar cell stack 3, contribute to the lateral current in the conduction layer 2.

(9) The second solar cell stack 3 comprises a lower cell-substrate 4 that either has a very good electrical conductivity or contains a contact layer that is used for the die-attach to the cooling substrate 6, for example, using solder or electrically conductive adhesive 5. The cooling substrate 6 can be provided in the form of a thermally and electrically conductive cooling substrate 6 and functions as a plus pole of the voltage matched multijunction solar cell. It is preferred that the bonding pad 5 and the cooling substrate 6 are made of the same material. According to an example, this material is an aluminum alloy, in particular, a 99.5% aluminum alloy. Thermal stresses between the bonding pad 5 and the cooling substrate 6 are largely avoided by the choice of the same material.

(10) In principle, the cooling substrate 6 may consist of a plane metal and shall provide thermal heat spreading and may also serve as an electric conductor. The dimensions and, particularly, the thickness of the plane metal (as well as the thickness of the bonding pad 5) can be selected in accordance with the desired cooling performance.

(11) An n contact 7 is provided on the lateral conduction layer 2. As already mentioned, the first and second solar cell stacks 1 and 3 are electrically connected parallel to each other. In the example shown in FIG. 1, the parallel connection is realized by connecting the p contacts 8 and 8′ of the first solar cell stack 1 and the second solar cell stack 3, respectively, by means of a metal connection 9 formed on an insulator material 10. For example, the insulator material 10 may be formed of polyimide and the metal connection 9 is formed by vapor deposition. Alternatively, a temporary insulator could be used, that is, removed after forming the metal connection, leaving an interconnection bridge. Thus, the parallel connection is established during the manufacture of the configuration comprising the two solar cell stacks 1 and 3 sandwiching the conduction layer 2.

(12) An alternative example of the inventive voltage matched multijunction solar cell is shown in FIG. 2. This exemplary voltage matched multijunction solar cell 200 also comprises the solar cell stacks 1 and 3, the conduction layer 2 and the bonding pad 5, as well as the cooling substrate 6 shown in FIG. 1. However, the electric parallel connection of the first solar cell stack 1 and the second solar cell stack 3 is realized differently. Rather than by depositing a metal layer on an insulator wherein the metal layer connects the p pole of the first and second solar cell stacks 1 and 3, according to the example shown in FIG. 2, wire bonding between the p contact of the first solar cell stack 1 and the p contact provided on the cooling substrate 6 establishes the parallel connection. In this case, connecting the first solar cell stack 1 and the second solar cell stack 3 in parallel is performed after mounting cell chips to the electrically conductive cooling substrate 6 by means of a thin wire 11. The thin wire 11 may be made of gold or aluminum.

(13) Whereas, in FIG. 1, a first p on n cell stack 1 and a second n on p cell stack 3 are shown, according to another example, the first solar cell stack 1 may be an n on p cell stack and the second solar cell stack 3 may be a p on n cell stack. In this case, the lateral conduction layer 2 may be an embedded grid. Moreover, in this case, the insulator material 10 is removed after the metal connection 9 has been formed, leaving a bridge interconnect formed by metal connection 9. In this configuration, the better conductivity of the n-doped semiconductor can be employed for the emitter layer of the uppermost solar cell of p on n cell stack 1.

(14) In both the example of a voltage matched multijunction solar cell 100 shown in FIG. 1 and the example of a voltage matched multijunction solar cell 200 shown in FIG. 2, the first solar cell stack 1 may comprise or consist of a GaInP cell and the second solar cell stack 3 may comprise or consist of a GaInAs top cell and a Ge bottom cell. For the voltage matched multijunction solar cells 100 and 200, a metamorphic Ga.sub.0.35In.sub.0.65P/Ga.sub.0.83In.sub.0.17As/Ge material may be chosen, for example. Voltage matching of the GaInP top cell and the GaInAs/Ge double cell may be optimized by an appropriate choice of the particular stoichiometric relations.

(15) All previously discussed embodiments are not intended as limitations but serve as examples illustrating features and advantages of the present disclosure. It is to be understood that some or all of the above-described features can also be combined in different ways.