METHOD FOR IRON MAKING BY CONTINUOUS SMELTING REDUCTION

Abstract

A method for iron making by continuous smelting reduction, including: (1) mixing iron- containing mineral powder with a reducing agent and a slag former to obtain mixed powder materials; (2) placing furnace startup materials in a reducing furnace, and heating the furnace startup materials to be in a molten state to form a furnace startup molten pool; (3) conveying the mixed powder materials into the reducing furnace, and blowing oxidizing combustibles into the reducing furnace for heating; (4) performing stirring by a stirring paddle to form a molten slag layer and a molten iron layer; and performing stirring so that a vortex is formed in the molten slag layer; and (5) adjusting a position of the stirring paddle, a stirring speed and a conveying quantity of the mixed powder materials to enable the molten iron and the reduced molten slag to be respectively continuously discharged.

Claims

1. A method for iron making by continuous smelting reduction, comprising the following steps: (1) uniformly mixing iron-containing mineral powder with a reducing agent and a slag former to obtain mixed powder materials, and placing the mixed powder materials in a continuous feeding system which is a device capable of metering conveyed materials, and selecting a screw feeder or a feeding bin with a metering pump, wherein the iron-containing mineral powder is iron ore powder, or iron-containing tailing powder or iron-containing smelt slag with full iron grade greater than or equal to 30%, the reducing agent is pulverized coal, the slag former is lime; in the mixed powder materials, the quantity of the reducing agent added is 1.1-1.3 times of a total quantity of C required for a complete reaction of Fe in the iron-containing mineral powder and C in the reducing agent the quantity of the slag former is 2-3 according to alkalinity of the mixed powder materials, and reaction formulas of the complete reaction are:
Fe.sub.xO.sub.y+yC=yCO+xFe,
Fe.sub.xO.sub.y+yCO=yCO.sub.2+xFe, and
Fe.sub.xO.sub.y+(y/2)C=(y/2)CO.sub.2+xFe; (2) placing furnace startup materials in a reducing furnace, wherein a seal cover is assembled at a top of the reducing furnace, a stirring device is arranged at the top of the reducing furnace, the stirring device and a lifting device outside the reducing furnace are assembled together, a shaft rod of the stirring device penetrates through the seal cover to be inserted in the reducing furnace, a stirring paddle is assembled at a bottom end of the shaft rod, an air inlet channel and an air exhaust opening are also formed in the seal cover, a feed pipe penetrates through the seal cover to be inserted in the reducing furnace, a molten slag overflow opening is formed in an upper part of a side wall of the reducing furnace, an iron notch is formed in a bottom of the reducing furnace and communicates with a siphon pipeline, and the siphon pipeline communicates with a buffer tank; heating the furnace startup materials to be in a molten state to form a furnace startup molten pool, wherein the furnace startup materials are pig iron, or the mixed powder materials in step (1), when the furnace startup materials are made into the furnace startup molten pool, a temperature of the furnace startup molten pool is controlled to be greater than or equal to 1450° C., a volume of the furnace startup molten pool is 20-30% of a total volume of the reducing furnace, when the furnace startup materials are the pig iron, the furnace startup materials are heated in an induced heating manner, when the furnace startup materials are the mixed powder materials, the furnace startup materials are heated in a manner that oxidizing combustibles are blown into the reducing furnace through the air inlet channel, the oxidizing combustibles are a mixture of pulverized coal and oxygen, or a mixture of natural gas and oxygen, a mass ratio of C elements to O elements in the oxidizing combustibles is 3 to (4-8), an outlet end of the feed pipe is located near the shaft rod, when a vortex is formed in a high-temperature molten pool in step (4), the mixed powder materials entering the reducing furnace fall into a center of the vortex, and at this time, the outlet end of the feed pipe is located above the vortex; (3) lowering the stirring paddle into the furnace startup molten pool through the lifting device, starting the stirring device to stir the furnace startup molten pool, adjusting a position of the stirring paddle through the lifting device, controlling a vertical distance between the stirring paddle and a liquid level of the furnace startup molten pool to be ⅓-½ of a height of the furnace startup molten pool, at the same time, enabling the continuous feeding system to continuously convey the mixed powder materials into the reducing furnace through the feed pipe, and blowing oxidizing combustibles into the reducing furnace through the air inlet channel to heat the mixed powder materials in the reducing furnace, wherein the oxidizing combustibles are the mixture of the pulverized coal and the oxygen, or the mixture of the natural gas and the oxygen, the mixed powder materials are heated to melt in the reducing furnace, the molten mixed powder materials and the furnace startup molten pool form the high-temperature molten pool together, at the same time, the mixed powder materials are subjected to a reduction reaction to generate molten iron and reduced molten slag, and an introduction quantity of the oxidizing combustibles is determined based on a standard of controlling a temperature of the high-temperature molten pool to be greater than or equal to 1450° C.; (4) under an action of a stirring centrifugal force and a coupling action of a gravity difference between the molten iron and the reduced molten slag, enabling the molten iron and the reduced molten slag to be separated quickly to form a molten slag layer in an upper part of the high-temperature molten pool and a molten iron layer in a lower part of the high-temperature molten pool, enabling the molten iron of the molten iron layer to enter the buffer tank from the iron notch through the siphon pipeline, along with an increase of a liquid level height of the high-temperature molten pool, when the molten iron is discharged out of an outlet of the buffer tank, adjusting the position of the stirring paddle through the lifting device, raising the stirring paddle into the molten slag layer, and performing vortex stirring on the molten slag layer through the stirring paddle so that the vortex is formed in the molten slag layer; and (5) adjusting a stirring speed of the stirring paddle and a conveying quantity of the mixed powder materials so that the molten iron is continuously and stably discharged, and at this time, a liquid level of the molten iron layer remains unchanged; when an upper edge of the vortex in the molten slag layer is located at the molten slag overflow opening, discharging the reduced molten slag through the molten slag overflow opening; adjusting the position of the stirring paddle through the lifting device, so that a vertical distance between the stirring paddle and the liquid level of the molten iron layer is ⅓-½ of a height of the molten iron layer; and adjusting the stirring speed and the conveying quantity of the mixed powder materials, so that the molten iron is continuously discharged out of the outlet of the buffer tank and the reduced molten slag is continuously discharged out of the molten slag overflow opening.

2-5. (canceled)

6. The method for iron making by continuous smelting reduction according to claim 1, wherein in step (3), a mass ratio of C elements to O elements in the oxidizing combustibles is 3 to (4-8).

7. The method for iron making by continuous smelting reduction according to claim 1, wherein in step (4), a height-diameter ratio of the vortex is 0.5-2.5 when the vortex is formed, and after the vortex is formed, the mixed powder materials entering the reducing furnace are drawn and sucked into the high-temperature molten pool under an action of negative pressure of the center of the vortex, and are uniformly dispersed under an action of the vortex stirring.

8. The method for iron making by continuous smelting reduction according to claim 1, wherein the stirring speed is 50-200 r/min when the stirring paddle performs the vortex stirring.

9. The method for iron making by continuous smelting reduction according to claim 1, wherein an iron reduction rate of the iron-containing mineral powder is greater than or equal to 95.5%, and a mass percentage of iron in the reduced molten slag is less than or equal to 0.35%.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0031] The sole FIGURE is a schematic structural diagram of an iron making device by continuous melting reduction according to an embodiment 1 of the invention.

[0032] In the drawings, 1-1: screw feeder; 1-2: feeding bin; 1-3: feed pipe; 2-1: reducing furnace; 2-2: stirring device (comprising stirring paddle and shaft rod); 2-3: molten iron layer; 2-4: molten slag layer; 2-5: air compressor; 3-1: siphon pipeline; 3-2: buffer tank; 3-3: foundry ladle; 3-4: molten slag overflow opening; 3-5: slag ladle; 4-1: waste heat recovery system; 4-2: flue gas purifying system; 4-3: chimney.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

[0033] In the embodiments of the invention, oxidizing combustibles are blown and introduced through an air compressor.

[0034] In the embodiments of the invention, iron-containing mineral powder is iron ore powder, or iron-containing tailing powder or iron-containing smelt slag with iron grade greater than or equal to 30%.

[0035] In the embodiments of the invention, the reaction formula of a complete reaction is:

Fe.sub.xO.sub.y+yC=yCO+xFe,

Fe.sub.xO.sub.y+yCO=yCO.sub.2+xFe, and

Fe.sub.xO.sub.y+(y/2)C=(y/2)CO.sub.2+xFe.

[0036] In the embodiments of the invention, the outlet end of a feed pipe is located near a shaft rod, when a vortex is formed in a high-temperature molten pool, mixed powder materials entering a reducing furnace fall into the center of the vortex, and at this time, the outlet end of the feed pipe is located above the vortex.

[0037] In the embodiments of the invention, after being discharged out of the outlet of a buffer tank, molten iron enters a foundry ladle, and secondary refining is performed on the molten iron, so that qualified molten iron is obtained for steel making.

[0038] In the embodiments of the invention, reduced molten slag mainly consists of components of CaO, SiO.sub.2 and Al.sub.2O.sub.3, after being discharged out of a molten slag overflow opening, the reduced molten slag enters a slag ladle, then hardening and tempering as well as annealing are performed, water quenching is performed, and cement clinkers are obtained.

[0039] In the embodiments of the invention, when a stirring paddle performs vortex stirring, the stirring speed is 50-200 r/min.

[0040] In the embodiments of the invention, the iron reduction rate of the iron-containing mineral powder is greater than or equal to 95.5%, and the mass percentage of iron in the reduced molten slag is less than or equal to 0.35%.

[0041] In the embodiments of the invention, the temperature of a furnace startup molten pool and the high-temperature molten pool is 1450-1550° C.

[0042] In the embodiments of the invention, the shaft rod is located at the axis of the reducing furnace.

Embodiment 1

[0043] The structure of the adopted device, as shown in the sole FIGURE, comprises a feeding bin 1-2, a screw feeder 1-1, a reducing furnace 2-1, a stirring device 2-2, a buffer tank 3-2, a waste heat recovery system 4-1, a flue gas purifying system 4-2 and a chimney 4-3, wherein a seal cover is assembled at the top of the reducing furnace 2-1, the stirring device 2-2 and a lifting device outside the reducing furnace 2-1 are assembled together, a shaft rod of the stirring device 2-2 penetrates through the seal cover to be inserted into the reducing furnace 2-1, and a stirring paddle is assembled at the bottom end of the shaft rod of the stirring device 2-2.

[0044] The outlet of the feeding bin 1-2 communicates with the inlet of the screw feeder 1-1, the outlet of the screw feeder 1-1 communicates with the inlet of the feed pipe 1-3, and the feed pipe 1-3 penetrates through the seal cover to be inserted into the reducing furnace 2-1.

[0045] An air exhaust opening is formed in the seal cover; a molten slag overflow opening 3-4 is formed in the upper part of the side wall of the reducing furnace 2-1, an iron notch is formed in the bottom of the reducing furnace 2-1 and communicates with a siphon pipeline 3-1, and the siphon pipeline 3-1 communicates with the bottom of the buffer tank 3-2.

[0046] A channel is arranged in the shaft rod of the stirring device 2-2 to be used as an air inlet channel, and the air inlet channel communicates with the air compressor 2-5.

[0047] The bottom end of a molten slag overflow opening 3-4 is opposite to a slag ladle 3-5, and the bottom end of a pipeline extending out of the outlet of the buffer tank 3-2 is opposite to the foundry ladle 3-3.

[0048] The air exhaust opening communicates with the waste heat recovery system 4-1 through a pipeline, the waste heat recovery system 4-1 communicates with the flue gas purifying system 4-2 through the pipeline, the flue gas purifying system 4-2 communicates with a draught fan, and the outlet of the draught fan communicates with the chimney 4-3.

[0049] When the above device is adopted, iron-containing mineral powder, a reducing agent and a slag former are uniformly mixed to obtain mixed powder materials, the mixed powder materials are placed in a screw feeder of a continuous feeding system, the reducing agent is pulverized coal, the slag former is lime, in the mixed powder materials, the quantity of the reducing agent added is 1.1 times of the total quantity of C required for the complete reaction of Fe in the iron-containing mineral powder and C in the reducing agent, and the quantity of the slag former is 2 according to the alkalinity of the mixed powder materials.

[0050] The furnace startup materials are placed in the reducing furnace, and are heated to be in a molten state to form a furnace startup molten pool, the furnace startup materials are pig iron, when the furnace startup materials are made into the furnace startup molten pool, the temperature of the furnace startup molten pool is controlled to be greater than or equal to 1450° C., the volume of the furnace startup molten pool is 20% of the total volume of the reducing furnace, and the furnace startup materials are heated in an induced heating manner.

[0051] The stirring paddle is lowered into the furnace startup molten pool through the lifting device, the stirring device is started to stir the furnace startup molten pool, the position of the stirring paddle is adjusted through the lifting device, the vertical distance between the stirring paddle and the liquid level of the furnace startup molten pool is controlled to be ⅓ of the height of the furnace startup molten pool, at the same time, the continuous feeding system continuously conveys the mixed powder materials into the reducing furnace through the feed pipe, and the oxidizing combustibles are blown into the reducing furnace through the air inlet channel to heat the mixed powder materials in the reducing furnace, the oxidizing combustibles are a mixture of the pulverized coal and the oxygen, the mixed powder materials are heated to melt in the reducing furnace, the molten mixed powder materials and the furnace startup molten pool form the high-temperature molten pool together, at the same time, the mixed powder materials have a reduction reaction to generate molten iron and reduced molten slag, the introduction quantity of the oxidizing combustibles is determined based on the standard of controlling the temperature of the high-temperature molten pool to be greater than or equal to 1450° C., and the mass ratio of C elements to O elements in the oxidizing combustibles is 3 to 4.

[0052] Under the action of a stirring centrifugal force and the coupling action of a gravity difference between the molten iron and the reduced molten slag, the molten iron is quickly separated from the reduced molten slag, then a molten slag layer in an upper part of the high-temperature molten pool and a molten iron layer in a lower part of the high-temperature molten pool are formed, the molten iron of the molten iron layer enters the buffer tank from the iron notch through the siphon pipeline, along with the increase of the liquid level height of the high-temperature molten pool, when the molten iron is discharged out of the outlet of the buffer tank, the position of the stirring paddle is adjusted through the lifting device, the stirring paddle is raised into the molten slag layer, and vortex stirring is performed on the molten slag layer through the stirring paddle, so that the vortex is formed in the molten slag layer, and the height-diameter ratio of the vortex is 0.5 when the vortex is formed.

[0053] The stirring speed of the stirring paddle and the conveying quantity of the mixed powder materials are adjusted so that the molten iron can be continuously and stably discharged, and at this time, the liquid level of the molten iron layer remains unchanged; when the upper edge of the vortex in the molten slag layer is located at the molten slag overflow opening, the reduced molten slag is discharged through the molten slag overflow opening; the position of the stirring paddle is adjusted through the lifting device so that the vertical distance between the stirring paddle and the liquid level of the molten iron layer is ½ of the height of the molten iron layer, and the stirring speed and the conveying quantity of the mixed powder materials are adjusted so that the molten iron is continuously discharged out of the outlet of the buffer tank and the reduced molten slag is continuously discharged out of the molten slag overflow opening.

[0054] After refining tail gas produced through a reaction in the reducing furnace is exhausted through the air exhaust opening, the exhausted tail gas enters a waste heat recovery system for waste heat recovery; when temperature is reduced to 200-300° C., the tail gas after waste heat recovery enters a flue gas purifying system, and carried dust is removed; and finally, the tail gas after dust removal is conveyed into a chimney through a draught fan and is discharged.

Embodiment 2

[0055] The adopted device is the same as that in embodiment 1 except the following aspects:

[0056] (1) The air inlet channel is an independent air inlet channel.

[0057] (2) The continuous feeding system is a feeding bin with a metering pump.

[0058] The method is the same as that in embodiment 1 except the following aspects:

[0059] (1) The mixed powder materials are placed in the feeding bin, and after being conveyed into an air inlet pipeline through the metering pump, the mixed powder materials enter the reducing furnace.

[0060] (2) The quantity of the reducing agent added is 1.2 times of the total quantity of C required for the complete reaction of Fe in the iron-containing mineral powder and C in the reducing agent, and the quantity of the slag former is 2.4 according to the alkalinity of the mixed powder materials.

[0061] (3) The furnace startup materials are the mixed powder materials, the volume of the furnace startup molten pool is 25% of the total volume of the reducing furnace, the furnace startup materials are heated in a manner that oxidizing combustibles are blown into the reducing furnace through the air inlet channel, the oxidizing combustibles are a mixture of natural gas and oxygen, and the mass ratio of C elements to O elements in the oxidizing combustibles is 3 to 8; and the position of the stirring paddle is adjusted through the lifting device, and the vertical distance between the stirring paddle and the liquid level of the furnace startup molten pool is controlled to be ½ of the height of the furnace startup molten pool.

[0062] (4) When the high-temperature molten pool is formed, the introduced oxidizing combustibles are the mixture of natural gas and oxygen, and the mass ratio of C elements to O elements in the oxidizing combustibles is 3 to 8.

[0063] (5) The height-diameter ratio of the vortex is 1.

[0064] (6) The vertical distance between the liquid level of the molten iron layer and the stirring paddle is ⅓ of the height of the molten iron layer.

Embodiment 3

[0065] The adopted device is the same as that in embodiment 1.

[0066] The method is the same as that in embodiment 1 except the following aspects:

[0067] (1) The quantity of the reducing agent added is 1.2 times of the total quantity of C required for the complete reaction of Fe in the iron-containing mineral powder and C in the reducing agent, and the quantity of the slag former is 2.8 according to the alkalinity of the mixed powder materials.

[0068] (2) The volume of the furnace startup molten pool is 30% of the total volume of the reducing furnace; and the position of the stirring paddle is adjusted through the lifting device, and the vertical distance between the stirring paddle and the liquid level of the furnace startup molten pool is controlled to be ½ of the height of the furnace startup molten pool.

[0069] (3) The mass ratio of the C elements to the O elements in the oxidizing combustibles is 3 to 5.

[0070] (4) The height-diameter ratio of the vortex is 1.5.

Embodiment 4

[0071] The adopted device is the same as that in embodiment 1.

[0072] The method is the same as that in embodiment 1 except the following aspects:

[0073] (1) The quantity of the reducing agent added is 1.3 times of the total quantity of C required for a complete reaction of Fe in the iron-containing mineral powder and C in the reducing agent, and the quantity of the slag former is 3 according to the alkalinity of the mixed powder materials.

[0074] (2) The furnace startup materials are the mixed powder materials, the volume of the furnace startup molten pool is 30% of the total volume of the reducing furnace, the furnace startup materials are heated in a manner that oxidizing combustibles are blown into the reducing furnace through the air inlet channel, the oxidizing combustibles are a mixture of natural gas and oxygen, and the mass ratio of C elements to O elements in the oxidizing combustibles is 3 to 6; and the position of the stirring paddle is adjusted through the lifting device, and the vertical distance between the stirring paddle and the liquid level of the furnace startup molten pool is controlled to be ½ of the height of the furnace startup molten pool.

[0075] (3) When the high-temperature molten pool is formed, the introduced oxidizing combustibles are the mixture of natural gas and oxygen, and the mass ratio of C elements to O elements in the oxidizing combustibles is 3 to 6.

[0076] (4) The height-diameter ratio of the vortex is 2.5.

[0077] (5) The vertical distance between the liquid level of the molten iron layer and the stirring paddle is ⅓ of the height of the molten iron layer.