Food Packaging Assemblies Comprising Composite Materials

Abstract

Food packaging assemblies of this invention comprise composite materials for food contact applications. Such composite materials include an absorbent layer and a non-absorbent layer, the absorbent layer having a textured surface for absorbing and trapping liquids, for example, oil, grease, or water, and the non-absorbent layer having an oleophobic surface that acts as an oil and grease specific liquid barrier. The material further includes one or more lamination layers. The lamination layer acts as a general liquid barrier between the absorbent layer and non-absorbent layer. This additional liquid barrier enhances the liquid repelling effect of the non-absorbent layer to more effectively trap liquids in the absorbent layer, thereby preventing liquids from seeping through the material onto an external surface.

Claims

1. A pizza box assembly comprising: a pizza box liner disposed in the pizza box, the pizza liner comprising: a composite material having an absorbent surface positioned face up in the pizza box and a non-absorbent surface positioned face up in the pizza box, the composite material is disposed in the pizza so that the absorbent layer directly contacts a bottom or top surface of a pizza disposed in the pizza box and the non-absorbent layer directly contacts one or more pizza box surfaces; one or more side panels positioned near the midpoint of the right and left sides of the liner, the side panels extended vertically from the absorbent surface of the liner, the side panels extending a distance from the absorbent surface that is slightly less than the height of a side wall of a pizza box so that the side panel can be disposed in the pizza box between a bottom surface and the top of a side wall of the box; two or more rear panels positioned near the midpoint of the back side of the liner, the rear panels further stack on top of each other so that the bottom rear panel is positioned below the top rear panel, the bottom rear panel extended vertically from the absorbent surface of the liner, the bottom rear panel extending a distance from the absorbent surface that is slightly less than the height of a rear panel of a pizza box so that the rear panel can be disposed in the pizza box between a bottom surface and a hinge above a rear wall of the box, the top rear panel extended out from the bottom rear panel toward the center of the absorbent surface, the top rear panel extending a distance above the rear wall of the pizza box so that the top rear panel contacts the top of the pizza box when the box is closed.

2. The pizza box assembly of claim 1, wherein the top rear panel of the pizza liner further comprises a printable surface that pops out from the rear wall of the pizza box when the box is opened, the printable surface is configured to receive an hold ink so that advertisements and other messages may be printed on the top rear panel and displayed when the box is open.

3. The pizza box assembly of claim 1, further comprising a scored edge at the base on at least one panel of the pizza box liner.

4. The pizza box assembly of claim 3, wherein the scored edge marks a pre-folded path for assembling the pizza liner from a flat configuration.

5. The pizza box assembly of claim 1, further comprising one or more front edges cut into one or more corners of the front side of the pizza liner, the edges distort the rectangular shape of the pizza liner at the front side so that the liner may be disposed in pizza boxes having a front wall with one ore more corners folded in toward the center of the pizza box.

6. The pizza box assembly of claim 5, further comprising a pizza box liner having one or more front panels positioned near the front edges, the front panels extended vertically from the absorbent surface of the liner, the front panels extending a distance from the absorbent surface that is slightly less than the height of the front wall of a pizza box so that the front panels can be disposed in the pizza box between a bottom surface and the top of the front wall of the box.

7. The pizza box assembly of claim 1, wherein the pizza liner is removable from the pizza box to allow the liner and the box to be disposed separately.

8. The pizza box assembly of claim 1, wherein the pizza liner further comprises one or more half circle tabs positioned on top of the side panels.

9. The pizza box assembly of claim 8, wherein the half circle tabs are positioned on the side panels to align with one or more holes in the side wall of the pizza box, in this configuration, the half circle tabs are accessible through the holes in the side wall of the box and provide a surface to mainplate the pizza liner when the box is partially or fully closed.

10. The pizza box assembly of the claim 1, wherein the pizza liner is disposed in the main body of the pizza box opposite the pizza box top.

11. The pizza box assembly of claim 10, further comprising a second pizza liner attached to the underside of the top of the pizza box, the second pizza liner is positioned to absorb liquid from the top surface of the pizza when the pizza box is closed.

12. A food bag assembly comprising: an inner surface for receiving take out food, the inner surface comprising an absorbent layer; an outer surface for handling the bag, the outer surface comprising a nonabsorbent layer; and one or more liquid barriers between the inner surface and the outer surface, the liquid barriers repel liquid and thereby prevent absorbed liquid in the absorbent layer from reaching the non-absorbent layer, wherein the inner surface, the outer surface and the liquid barriers are included in one sheet of composite material.

13. The food bag assembly of claim 12, further comprising an outer surface with an absorbent layer laminated to the nonabsorbent layer.

14. The food bag assembly of claim 13, wherein the absorbent layers contained in the inner surface and outer surface of the food bag have a surface texture comprising a system of ridges and valleys, the ridges are configured to adsorb liquid from a food surface and facilitate absorption of liquid by the absorbent layer, the valleys are configured to absorb liquid into the main body of the absorbent layer, the valleys further configured to trap and hold absorbed liquid in the absorbent layer.

15. The food bag assembly of claim 12, further comprising a first scored edge running down the middle of the side portions of the bag assembly and a second set of scored edges extended out from the mid point of the bottom of the bag toward the front and back surfaces of the bag assembly, the scored edges mark a pre-folded path for assembling the food bag from a flat configuration.

16. The food bag assembly of claim 12, wherein the food bag is dimensioned to receive lasagna, fries, nachos, burritos, tacos, fried rice, stir fry, macaroni and cheese, pasta, fried noodles, fried chicken, hot dogs, burgers, bbq, popcorn, dounuts, tater tots, corn dogs, biscuits, and other take out foods.

17. A baking sheet comprising: a top surface disposed face up in a baking pan, the top surface for receiving food to be cooked on the pan and comprising an absorbent layer; and a bottom surface disposed face down in a baking pan, the bottom surface for contacting the baking pan and comprising one or more liquid barriers, wherein the top surface and bottom surface are included in one sheet of composite material.

18. The baking sheet of claim 17, further comprising a scored edge set back some distance from the outer edge of the baking sheet, the scored edge marks a pre-folded path for assembling the baking sheet from a flat configuration.

19. The baking sheet of claim 18, wherein the scored edge is set back at least one quarter inch from the outer edge of the baking sheet.

20. The baking sheet of claim 17, wherein the liquid barriers included in the bottom surface comprise at least one of a lamination layer, a non-absorbent layer, or some combination.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0061] A full and complete description of the present storage system is provided herein with reference to the appended figures, in which:

[0062] FIG. 1 is a top plan view of one embodiment of a pizza liner comprising of a composite material.

[0063] FIG. 2 is a cross-sectional view of the pizza liner of FIG. 1, as taken along line II-II of FIG. 1.

[0064] FIG. 3 is a perspective view of a pizza box assembly containing the pizza liner of FIG. 1.

[0065] FIG. 4 is a perspective view of a sheet of a composite material. One aspect of the drawing includes a magnified view of the composite material.

[0066] FIG. 5 is a cross-sectional view of the sheet of composite material in FIG. 4, as taken along line 47 in FIG. 4.

[0067] FIG. 6 is a perspective view of a second embodiment of a pizza liner comprising a composite material.

[0068] FIG. 7 is a plan view of the pizza liner of FIG. 6.

[0069] FIG. 8 is a perspective view of a pizza box assembly containing the pizza liner of FIG. 6.

[0070] FIG. 9 is a perspective view of a third embodiment of a pizza liner comprising a composite material.

[0071] FIG. 10 is a plan view of the pizza liner of FIG. 9.

[0072] FIG. 11 is a perspective view of a pizza box assembly containing the pizza liner of FIG. 9.

[0073] FIG. 12 is a perspective view of a food bag assembly comprising a composite material.

[0074] FIG. 13 is a perspective view of the food bag assembly of FIG. 12 containing popcorn.

[0075] FIG. 14 is a plan view of the food bag assembly of FIG. 13.

[0076] FIG. 15 is a plan view of a baking sheet comprising a composite material. One aspect of the drawing includes baking pan having the baking sheet disposed inside of the pan. Another aspect of the drawing includes uncooked bacon on top of the baking sheet.

[0077] FIG. 16 is a plan view of the baking sheet of FIG. 15 after the bacon has been cooked on the sheet and removed from the baking pan. One aspect of the drawing includes a perspective view of one corner of the baking sheet after the corner has been peeled back away from the baking pan. Another aspect of the drawing includes a plan view of a baking sheet having a scored edge.

DETAILED DESCRIPTION

[0078] Reference is now made to the drawings for illustration of various embodiments of the composite material and food packaging assemblies. It should be understood that the composite material may be made in any shape, as needs dictate. The composite paper material may also be integrated into any type of food packaging, for example, bags, trays, boxes, plates and other dishes, wrappers, foils, or cartons. Further, it should be understood that the material described herein is equally well suited for absorbing oil from any greasy food including, for example, pizza, lasagna, fries, nachos, burritos, tacos, fried rice, stir fry, macaroni and cheese, pasta, fried noodles, fried chicken, hot dogs, burgers, bbq, bacon, sausage, and popcorn.

[0079] FIG. 4 is a sheet of composite material having an absorbent layer 40 joined to a non-absorbent layer 49. The layers 40, 49 may be joined by any suitable means, including, but not limited to, gluing, laminating, seaming, embossing, quilting, and surface bonding. In laminated embodiments, a degradable laminate may be applied to at least one surface of the absorbent layer, non-absorbent layer, or both. The lamination layer may be placed between the absorbent layer and non-absorbent layer or added to an exterior surface of the absorbent layer or non-absorbent layer. In one example, the absorbent layer 40 has a surface texture 48 configured to enhance the layer's ability to absorb liquid. In some examples the surface texture 48 is optimized to absorb viscous, oleophilic liquids, for example, fats, oils, and grease. In other examples, the surface texture 48 is optimized to absorb low viscosity, oleophobic liquids, for example, water.

[0080] One aspect of FIG. 4 includes a magnified portion 42 of the composite material sheet. The magnified portion 42 provides a high resolution view of a portion of the composite material sheet 41 to display one embodiment of the surface texture 48 in greater detail. In this example, the surface texture 48 includes a system of ridges 43, 46, shown by dark black lines, and valleys 44, 45, shown by the white space between the dark black lines. The ridges 43, 46 extend out from the surface of the composite material to form a network of narrow line segments elevated from the main body of the absorbent layer 40.

[0081] When applied to a greasy food surface, the ridges 43, 46 contact the surface before the main body of the absorbent layer. In this orientation, the ridges 43, 46 adsorb and absorb liquid from the food surface. Adsorbed liquid is absorbed into the absorbent layer by flowing from the ridges 43, 46 to the valleys 44, 45 in the main body. The valleys 44, 45 are wider than the ridges 43, 46 and have a greater capacity for holding liquid. In embodiments with polar liquids, for example, solutions having strong intermolecular forces and/or intramolecular forces, such as, hydrogen bonding or van der Waals interactions, the ridges 43, 46 may provide a capillary force for absorbing liquid from the food surface. The rates of adsorption and absorption, the flow rate of liquid from the ridges to the valleys, and the amount of capillary force necessary to absorb liquid from a food surface are dependent on the properties of the liquid, for example, viscosity and surface tension, and the absorbent layer, for example, porosity, ridge width, valley width, ridge height, and surface texture pattern.

[0082] In a preferred embodiment, the network of ridges 43, 46 and valleys 44, 45 is continuous across at least one full surface of the composite material so that the adsorbent and absorbent properties provided by material and surface texture of the absorbent layer pulls liquid across the surface of the composite material. Absorbent layers having a continuous network of adsorbent ridges 43, 46 extending out from an absorbent main body wick liquid away from saturated areas and distribute it to unsaturated portions. By distributing liquid more evenly throughout the absorbent layer, the surface texture prevents absorbed liquid from pooling on the surface of the composite material, thereby increasing the layer's overall liquid carrying capacity and local absorbance and absorbance capacity.

[0083] In one example, the ridges 43, 46 are in a loop like configuration with ridges 43, 46 on the head of the loop being spaced further apart than ridges 43, 46 on the neck of the loop. The wide valleys 44, 45 at the head of the loop are optimized for absorbing and holding liquid and while the high concentration of ridges 43, 46 at the narrow neck of the loop are optimized for adsorbing liquid. In other configurations, the surface texture 48 may include a continuous network of ridges 43, 46 laid out in straight or wavy line patterns and separated by valleys 44, 45 consistently or irregularly spaced between the ridges 43, 46. Additionally, the ridges 43, 46 may also overlap in a square, rectangular, curved, or diamond pattern with valleys 44, 45 dispersed between the ridge pattern.

[0084] FIG. 5 is a cross sectional view of the composite material sheet of FIG. 4, as taken along the dashed line 47. In this example, the composite material has three layers, a absorbent layer 52, a lamination layer 56, and a non-absorbent layer 57. The absorbent layer 52 includes a surface texture comprising a network of ridges and valleys 54. By attaching to ridges on one side of the absorbent layer 52, the lamination layer 56 seals the gap between the ridges and valleys on one side of the absorbent layer 52. The seal created by the lamination layer 56 is shown by a series of semi-circular bubbles 55 that protrude into the gap between the valleys 54 and ridges on the top side of the absorbent layer 56. The seal creates a network of pockets 50 between the top surface of the surface texture on the absorbent layer 52 and the bottom surface of the lamination layer 56. When the composite material contacts liquid, absorbed liquid is stored in the network of pockets 50 so that it does not drip or seep out of the absorbent layer 52. By compressing absorbed liquid into the network of pockets 50, the lamination layer 56 horizontally displaces absorbed liquid across a wider surface area. The horizontal displacement created by the network of pockets holds liquids in the composite material and prevents pooling. Additionally, by compressing absorbed liquid in the network of pockets 50, the lamination layer 56 creates a wicking effect that draws absorbed liquids across the surface of the absorbent layer 52 away from saturated areas with full pockets into unsaturated areas with empty pockets.

[0085] The lamination layer 56 joins the absorbent layer 52 to the non-absorbent 57 layer. In this example, the lamination layer 56 also provides a liquid barrier between the absorbent layer 52 and the non-absorbent layer 57. The lamination layer 56 comprises a non-biotoxic water based polymer emulsion coating with a flash point greater than 400 F. The lamination layer 56 may be applied as a surface coating to at least one of the absorbent layer 52 or non-absorbent layer 57. In one example, the lamination layer 56 forms a liquid barrier between the absorbent layer 52 and the non-absorbent layer 57. This liquid barrier traps liquid in the absorbent layer 52 and prevents absorbed liquids from seeping through top layers of the composite material into the non-absorbent layer 57. The lamination layer 56 allows the composite material to trap liquid in the absorbent layer 52 better than conventional materials because it forms a first liquid barrier that is augmented by a second liquid barrier, the non-absorbent layer 57. The sequence of liquid barriers prevents absorbed liquid held in the absorbent layer 52 from penetrating the composite material. Accordingly, materials in contact with the non-absorbent layer 57 are isolated from absorbed liquids held in the absorbent layer 52.

[0086] In this example, the lamination layer prevents all liquids from passing through the absorbent layer 52 to the non-absorbent layer 57. In other embodiments, the lamination layer 56 may be configured to selectively trap certain types of liquid, for example, water based or oil based solutions, while allowing liquids with particular physical or chemical properties to pass through the absorbent layer.

[0087] Typical oil and grease and aqueous barrier coatings selected for the lamination layer 56, often comprise a higher polymer binder level compared to conventional print and binder coatings. Such coatings contaminate recycling streams by rendering otherwise recyclable materials not recyclable because complex, sticky polymer coatings are difficult to breakdown in conventional acidic pulping processes. When in a strongly acidic environment, for example, in a solution with a pH lower than 2, the coatings tend to clump and form stickies, and other particles that are larger than the acceptable size for paper making from recycled materials.

[0088] Conventional coatings also often comprise petroleum based polymers. Such coatings contaminate composting streams because they do not readily disintegrate in industrial scale composting processes. The high content specialty polymers, for example, a petroleum based polymer binder, present in these coatings makes meeting the >1% non-biodegradable composition requirement for the ASTM D6868-11 compostability standard extremely challenging.

[0089] In addition to the environmental concerns associated with conventional coatings, blocking is another common problem associated with coated paper materials. Blocking occurs when layers of coated paper material stick together either in the real or after being rewound into rolls. Blocking in the reel is especially problematic when residual heat from dryers dissipates slowly due to the large mass of the reel. Higher temperatures on the reel in turn can cause conventional coatings to stick or even melt as a result of thermal instability.

[0090] The lamination layer 56 described herein improves upon conventional liquid barrier coatings because it is non-blocking, recyclable, and compostable. In one example, the lamination layer 56 is made out of non-biotoxic materials that are safe for food contact applications and meet the >99% biodegradable composition requirement of the ASTM D6868-11 standard. Additionally, when placed between an absorbent layer 52 and a non-absorbent layer 57, the lamination layer 56 causes absorbed liquids to wick across the surface of the absorbent layer 52. This wicking effect is produced by applying an impermeable, semi-permeable, or oleophilic lamination layer 56 to an absorbent layer 52 with an uneven surface texture. In this example, the absorbent layer 52 is a crepe paper with ridges, valleys, and other small structures extending out fromand protruding intothe main body of the absorbent layer.

[0091] The lamination layer 56 may further contain a binding agent that increases the lamination strength of the lamination layer 56. Increasing the layer's lamination strength causes the laminated surface of the non-absorbent layer to better adhere to the absorbent layer 52. In one example, applying the lamination layer 56 to the absorbent layer 52 and waiting a period of one to five seconds before joining the non-absorbent layer 57, improves the thermal degradation properties of the composite material. This method of combining the layers into a composite gives the lamination layer 56 time to set-in and partially fill the valleys on the surface of the absorbent layer 52, thereby creating a uniform surface to join the non-absorbent layer 57. Pressing the non-absorbent layer 57 to a smooth surface of lamination layer 56 fortifies the bond between the layers of the composite thereby increasing the flash point of the composite and minimizing paper curl. The lamination layer 56 may also be applied as a print coating or can otherwise serve as a substrate for ink printing.

[0092] To further enhance the composite material's ability to trap liquid, the non-absorbent layer 57 forms a second liquid barrier. This additional liquid barrier prevents any liquid passing through the lamination layer 56 from penetrating the composite material. In one example, the non-absorbent layer 57 is an oil and grease resistant paper material that repels fats, oil, and grease. In other examples, the non-absorbent layer 57 is a water or liquid resistant paper material that repels at least one of water, water based solutions, or any type of liquid. Additionally, the non-absorbent layer 57 may also comprise plastics and other synthetic materials, for example, petroleum-based polymer materials including high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), polyhydroxyalkanoate (PHA), polyglycolic acid (PGA), polyethylene terephthalate (PET), polypropylene (PP), polystyrene, and polyvinyl chloride (PVC).

[0093] In the configuration shown in FIG. 5, the exposed surface of the absorbent layer is applied to a liquid surface. Liquid is adsorbed by the network ridges extending from the surface of the absorbent layer 52 and absorbed into the valleys comprising the main body of the absorbent layer. Absorbed liquid is then stored in the network of pockets 50 and spread evenly throughout the network of ridges and valleys 54. The lamination layer 56 seals one side of the absorbent layer 52 forming a first liquid barrier on the top side of the absorbent layer 52. The liquid barrier traps liquid in the absorbent layer and enhances the wicking effect of the absorbent layer by compressing liquid into the network of pockets between the absorbent layer and lamination layer. The non-absorbent layer 57 attaches to the top of the lamination layer 56 and provides a secondary liquid barrier to prevent any liquid that passes through the lamination layer 56 from penetrating the composite material.

[0094] Accordingly, the composite material makes food healthier and less messy by absorbing high calorie nutrients from the surface of greasy take out food into the absorbent layer. A sequence of two liquid barriers, one formed by the lamination layer and one formed by the non-absorbent layer, further traps liquid in the absorbent layer to prevent absorbed liquid from penetrating the composite material. By trapping and holding liquid absorbed from food surfaces, the composite material can prevent liquid contaminants from reaching cookware, food packaging assemblies, sewer systems, and the hands of individuals eating food.

[0095] FIG. 1 is a pizza liner embodiment 10 comprising a composite material having an absorbent layer 12 joined to a non-absorbent layer 14. As illustrated, the composite 10 has a perimeter edge 16, which results from the joining of the absorbent layer 12, and the non-absorbent layer 14. The composite 10 is dimensioned to cover a substantial portion of a surface of a pizza or other take out food and, accordingly, may be provided in a number of different sizes to accommodate foods of different sizes.

[0096] The absorbent layer 12 may be made of any suitable material that is capable of absorbing liquid in significant quantities. Such materials include, but are not limited to, bi-component micro-fibers, biodegradable fibers, bleached fibers, cellulosic fibers, sulphite bleached fibers, and kraft bleached fibers. The material of the absorbent layer 12 may include materials that are oleophilic, meaning that they have an affinity for oils and grease but not water. The absorbent layer 12 is FDA approved for food contact applications including manufacturing, packaging, processing, preparing, treating, cooking, packing, transporting, or holding foods. The layer is low-linting, such that absorbent layer 12 does not leave lint on food after contact.

[0097] In one example, the absorbent layer 12 is a grade of crepe paper having 94% biobased content and containing 5% water and up to 1% synthetic and non-bio based materials. Further, the absorbent layer 12 is fluorine free, non-biotoxic, and safe for food contact applications. The surface of the absorbent layer may also be textured to better absorb and trap liquid. In one example, the textured surface includes a continuous network of ridges and valleys covering the entire front and back surface of the absorbent layer 12. The ridges are narrow elevated segments extending out from the surface of the absorbent layer 12 that adsorb liquid from food surfaces. The valleys are wider low lying areas between the ridges that trap and hold absorbed liquid the main body of the absorbent layer.

[0098] The paper material comprising the absorbent layer further meets the 99% biodegradable composition requirement of the ASTM D6868-11 compostablility standard. The absorbent layer may comprise one or many sheets of 5 lbs to 70 lbs basis weight paper having a thickness of 1.0 mil to 7.0 mils and a Sheffield porosity of 150 to 300 units. The absorbent layer further has an autoignition temperature greater than 400 F. and a moisture percentage between 5.0% and 7.5%. The low moisture percentage minimizes paper curl and the autoignition temperature above 400 F. allows the material to be used in high temperature cooking applications.

[0099] As shown in FIG. 2 and FIG. 5, the non-absorbent layer 14 may be made of any suitable non-absorbent material that forms a liquid barrier. In this example, the non-absorbent layer 14 comprises a material that is not permeable by oils or grease. Such materials include oil and grease resistant papers (OGR), oleophobic fiber webs, polymeric films, and liquid barrier coatings. Advantageously, when the non-absorbent layer 14 is made of a flexible OGR paper, the composite 10 may have a desirable degree of malleability, such that the composite may be crumpled after use for convenient disposal without the user having to contact the oil-soaked absorbent layer 12.

[0100] In one example, the non-absorbent layer is an oil and grease resistant (OGR) material having a kit level between 3 and 8. The non-absorbent layer is further fluorine free, non-biotoxic, and safe for food contact applications. The non-absorbent layer has a flash point above 400 F. so it can be used in high temperature cooking applications. The non-absorbent layer 14 may be laminated to at least one surface of the absorbent layer 12 to form a liquid barrier between the absorbent layer in contact with a food surface and the non-absorbent layer in contact with an external surface, for example, a cooking surface, a customer holding food, or a recyclable material, such as, corrugated cardboard. The liquid barrier may repel water, polar liquids, oil, grease, organic, non-polar liquids, and mixtures thereof. The liquid barrier allows a first portion of the composite material to absorb and trap liquid and a second portion to prevent liquid from seeping through the first portion.

[0101] In a preferred example, the non-absorbent layer 14 is a compostable OGR paper material having over 90% biobased content. The non-absorbent layer meets the 99% biodegradable composition requirement of the ASTM D6868-11 compostability standard and contains no petroleum based polymers. In another example, the non-absorbent layer 14 is a liquid barrier coated material that repels OGR, water, and other liquids. The non-absorbent layer 14 may include petroleum-based polymer materials including, high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), polyhydroxyalkanoate (PHA), polyglycolic acid (PGA), polyethylene terephthalate (PET), polypropylene (PP), polystyrene, and polyvinyl chloride (PVC).

[0102] In one example, the absorbent layer 12 is a crepe paper comprising cellulosic fibers and the non-absorbent layer 14 is an OGR paper. More specifically, the absorbent layer 12 is a crepe paper made of four to six layers of cellulose wadding having a basis weight of 5 to 70 pounds. The material may be virgin material that is biodegradable and recyclable. The sheets of wadding may be pinned together initially in an embossing type process to form a friction connection that creates a self-supporting sheet of absorbent material. An example of such absorbent material is the cellulose sheeting sold by PREGIS CORPORATION under the trademark CUSHION PACK.

[0103] The absorbent layer 12 is backed by the non-absorbent layer 14 and optionally coated by a lamination layer. The non-absorbent layer 14 may be an OGR paper or polymeric film, such as polyethylene, that is glued, attached by a lamination film, or otherwise affixed to the absorbent layer to form the composite 10. In one embodiment, the non-absorbent layer is laminated 10 to provide additional oil and grease resistance.

[0104] The composite material may also disintegrate naturally and be biodegradable, non-toxic, and compostable under American Society for Testing and Materials (ASTM) or Biodegradable Products Institute (BPI) standards, for example, the ASTM D6400 testing criteria for plastic and the ASTM D6868 testing criteria for coated paper products.

[0105] For use as an oil and grease absorbing food packaging material, the composite 10 is placed against a pizza or other food item from which oil or grease is to be absorbed with the absorbent layer 12 in contact with the food item. The composite 10 may contact either an upper or lower surface of the food, as desired, to extract oil or grease without adversely affecting the food. In the case of pizza, which is commonly placed in a box for transportation, this leads to at least the following two potential positions of the composite 10 relative to the box.

[0106] FIG. 3 illustrates a pizza box assembly 30 that includes a pizza box 20 and the pizza liner 10 shown in FIGS. 1 and 2. The pizza box 20 is a standard collapsible box used commonly in the industry, having an inner cavity or receptacle 22 for holding the pizza such that the absorbent layer 12 faces the inner receptacle 22. The composite 10 may be attached to the interior top 24 of the box 20 by any suitable means, including adhesives. In one aspect, the composite 10 may be removed after use and the pizza box 20 may be recycled.

[0107] FIG. 6 illustrates an alternative pizza liner embodiment comprising the composite material of FIG. 4 and FIG. 5. The pizza liner includes an absorbent layer 60 laminated or otherwise attached to a non-absorbent layer 62. In this configuration, the pizza liner has an absorbent layer 60 on top of a non-absorbent layer 62 so that the absorbent layer 60 contacts the pizza and the non-absorbent layer 62 contacts the pizza box. In this example, the pizza liner is rectangularly shaped and dimensioned to fit inside of a rectangular pizza box.

[0108] The pizza liner includes two side panels 63, 65 configured to hold the pizza liner in place and prevent the sides of the pizza from contacting the sides of the pizza box. Further, the pizza liner includes two rear panels 66, 68. The bottom rear panel 68 prevents the back surface of the pizza from contacting the hinge of the pizza box and holds the pizza liner in place so it does not slide backward in the pizza box. Additionally, the bottom rear panel 68 props up the top rear panel 66 making it more visible when the pizza box is open. When the pizza box is closed, the top panel 66 prevents the top of the pizza from contacting the top of the pizza box.

[0109] The top rear panel 66 further includes a printable surface for placing advertisements, designs, and other printed writing or symbols. By providing a printable surface inside the pizza box, the top panel 66 allows advertisements to be seen when the pizza box is open. Since most consumers of pizza eat pizza from an open box, the top panel 66 offers an improvement over the current state of the art for advertising on a pizza box, attaching a paper flyer to the outer surface of the top of the pizza box. The base of the side panels 64, bottom rear panel 69, and top rear panel 67 includes a scored edge allowing the pizza liner to be shipped flat and conform to the shape shown in FIG. 6 when placed inside a pizza box without additional folding. The scored edges 64, 67, and 69 allow a pizza box assembly including a corrugated cardboard pizza box and the pizza liner of FIG. 6 to be assembled in less than one second.

[0110] FIG. 7 is a plan view of the pizza liner embodiment of FIG. 6. The pizza liner includes an absorbent layer 70 surrounded by two side panels 72, 74, a top rear panel 76, and a bottom rear panel 78. The plan view illustrates a front edge 71 cut into both front corners of the pizza liner. The edges 71 are configured to accommodate rectangular pizza boxes having the front corners folded in to accommodate a lid with a tapered ends, as shown in FIG. 8. Scored edges 73, 75, 77, and 79 at the base of each of panel are also visible in the plan view illustration.

[0111] FIG. 8 illustrates a pizza box assembly including the pizza liner example of FIG. 6 and FIG. 7. In this example, when the box is closed, each side panel 83 is configured to come between its corresponding side wall 80 on the top of the pizza box 88. Accordingly, the side panels prevent the sides of the bottom and top of the pizza box from contacting a pizza disposed inside the box. The pizza liner is removable from the pizza box to allow the liner and the box to be disposed separately. In use, the pizza liner absorbs fats, grease, oil and other liquids on the surface of the pizza and prevents the liquids from contacting the pizza box. When the pizza is consumed or removed from the box, the liner may be composed or otherwise disposed of and the pizza box, now without any absorbed grease or oils because of the protection provided by the liner, can be recycled or composted. Accordingly, the pizza liner makes food healthier by absorbing liquefied high calorie nutrients from a pizza surface while also allowing the pizza box to be disposed in a more sustainable way by protecting the box from grease, oil, and other contaminants.

[0112] FIG. 9 and FIG. 10 illustrate a third preferred pizza liner embodiment. Similar to the pizza liner of FIGS. 6-8, the liner includes an absorbent layer 90 laminated or otherwise attached on top of a non-absorbent layer 91, side panels 94, a bottom rear panel 98, a top rear panel 96, and scored edges at the base of each panel 97, 99, and 103. This example further includes two front panels 92 and half circle tabs 95 on the top of the side panels 94. Similar to the side 94 and rear panels 96, 98, the front panels 92 prevent the front surface of the pizza from contacting the front portion of the pizza box. The front panels 92 also hold the pizza liner in place so that it does not move forward when disposed inside the pizza box. The half circle tabs 95 provide a structure to manipulate the side panels 94 when the pizza box is closed.

[0113] FIG. 11 illustrates a pizza box assembly including the pizza liner example of FIG. 9 and FIG. 10. Similar to FIG. 8, the assembly includes a pizza box having a bottom portion 118 for disposing a pizza, a top portion 111 having a front portion with tapered ends 119, and side panels 110 positioned behind the liner's side panels 114. The assembly further includes a pizza liner having side panels 114, a bottom rear panel 116, a top rear panel 115 with a printable surface for placing advertisements, designs, and other printed writing or symbols, front panels, and scored edges at the base of the front, side, and rear panels.

[0114] The liner also includes a half circle tab 113 at the top of each side panel 114. In this example, when the box is closed the liner's side panels 113 may be re-positioned in front of the side walls 110 on the top portion of the pizza box by inserting one or more fingers into a pair of semi-circular holes on the side walls of the pizza box (not pictured) and moving the half circle tabs 113 on the liner's side panels 114 forward. Displacing the liner's side panels 114 by inserting one or more fingers to poke the half circle tabs 113 ensures the liner will not get crushed by the box top when the pizza box is closed. Accordingly, using the half circle tabs 113 to keep the liner intact and in position, enables the pizza liner to function as a device for preventing liquid from contacting the pizza box and for absorbing liquid from the pizza surface.

[0115] The pizza box assemblies of FIG. 3, FIG. 8, and FIG. 11 may also include an additional liner comprising the composite material attached to the underside of the top of the pizza box. The liners may be circular or rectangular shaped and dimensioned to cover the entire area of the inside of the pizza box or, alternatively, dimensioned to cover a substantial portion of the pizza. In a preferred embodiment, a pizza box liner comprising a composite material is disposed in the inner receptacle of the pizza box at a location beneath the pizza. When the pizza in the box is cut or scored oil and grease from the pizza is efficiently wicked to the underside by the absorbent layer without disturbing the upper surface of the pizza as can occur when a composite material is applied to the upper surface of the pizza. Therefore, an arrangement wherein the liner is disposed in the inner receptacle of the pizza box so that the absorbent layer contacts the bottom surface of the pizza operates advantageously in a surprisingly efficient manner to extract undesired oil and grease.

[0116] In use, when a pizza liner comprising the composite material is positioned beneath the pizza, the pizza may be cut prior to or after being placed on the composite. Due to the durable nature of the composite material, it is not normally severed when a rolling cutter is used on the pizza. Placement of a pizza liner comprising the composite material beneath the pizza enables excess oil and grease to pass downwardly to the composite for efficient absorption by the absorbent layer. Absorbed oil and grease cannot pass beneath the composite, however, because the non-absorbent layer and lamination layer act as liquid barriers. The bottom of the pizza box therefore remains oil and grease-free, enabling it to be recycled. Similarly, the front, rear, and side panels of the pizza liner protect the side, front, rear, and top walls of the pizza box from oil, grease, and other contaminants.

[0117] As illustrated in FIGS. 3, 8, and 11, pizza liners comprising the composite material may be square or any other suitable shape to cover the bottom of the pizza box. Particularly when the composite is placed beneath a pizza or other food item, it may be desirable to cover the entire bottom of the container in which the food item is placed. Alternatively, pizza liners comprising the composite material placed beneath a pizza may be circular and dimensioned to match the outline of the pizza.

[0118] In other instances, such as when pizza or other food items are consumed on the premises of a restaurant, the composite can still be used under the food to absorb oil and grease. In any case, once the pizza is finished, the composite may be folded inwardly onto itself without touching the grease-saturated absorbent layer by grasping the non-absorbent layer.

[0119] As shown in FIG. 2, when food packaging assemblies comprising the composite material are used to blot a pizza or other food item from above, the non-absorbent layer 14 may have a flexible tab, string, or other physical feature 32 enabling the user to lift the composite material away from the food without touching the saturated absorbent layer 12. The weight of the absorbed oil and grease then causes the composite material 10 to hang downwardly with the grease-impermeable non-absorbent layer 14 on the outside, facilitating disposal of the food packaging assembly without getting oil or grease on the user's hands.

[0120] When the non-absorbent layer 14 is metallic, a thick paper, or some combination, the composite 10 also serves an additional purpose of retaining heat within the pizza by reflection in either an up or down direction, depending on the position of the composite.

[0121] In another form, separate liners comprising the composite material 10 may be provided above and below a pizza with the absorbent layer 12 facing and in contact with the surfaces of the pizza to absorb oil and grease from both the top and the bottom of the pizza. Alternatively, the top and bottom layers of the composite material 10 may comprise a single sheet of the composite that extends underneath the pizza and is folded over to also engage the top of the pizza to absorb oil and grease from the top and bottom of the pizza simultaneously.

[0122] The foldable nature of the composite enables it to be packaged in a compact and inexpensive package, which may be in the form of a sealed plastic, paper, or foil-backed pouch, as illustrated in FIGS. 12-17. In this form, the composite is suitable for distribution with a take-out pizza or other food item for convenient use by the consumer in extracting oil and grease from the food item. In situations where a food packaging assembly comprising a composite material is used to distribute pizza, popcorn, burgers, or other take out foods, a stand alone sheet or napkin comprising the composite material may also be provided for manual use by the consumer to further reduce the quantity of oil and/or grease consumed.

[0123] FIGS. 12-14 illustrate a bag assembly comprising a composite material. In one example the bag assembly is used to distribute take out food. FIG. 12 illustrates an empty bag assembly having an inner surface 121 comprising an absorbent layer. The inner surface 121 is configured to absorb liquid, for example, fats, grease, oil, water, or some combination from the surface of food disposed in the bag. The bag assembly further includes an outer surface 120. In one example, the outer surface 120 comprises an absorbent layer for absorbing fats, grease, oil, water and other liquids from hands used to pick up and eat food disposed in the bag assembly. In this example, the bag assembly includes a liquid barrier 122 positioned between the inner surface 121 and the outer surface 120. The liquid barrier 122 traps liquid absorbed from the food surface in the absorbent layer of the inner surface 121 to prevent liquid absorbed by the inner surface 121 from reaching the outer surface 120. Similarly, the liquid barrier 122 traps liquid absorbed from hands used to pick up and eat the food in the outer surface 120 to prevent liquid absorbed by the outer surface 120 from reaching the inner surface 121. In this example, the liquid barrier 122 comprises a lamination layer, a non-absorbent layer, or some combination.

[0124] The composite material described herein may be converted into bag assemblies, such as, square bottom bags and pinch bottom bags, as well as other food packaging assembles, for example, tray liners, sandwich and burger wrappers, basket liners, French fry and hash brown pouches, napkins, bowls, plates, trays, and boxes. The bag assembly of FIG. 12 is a square bottom bag further comprising scored edges running down the middle of the side portions of the bag assembly 123 and out from the mid point of the bottom of the bag toward the outer surfaces 124. The scored edges 123, 124 allow bag assemblies to be shipped flat and rapidly unfolded for use. FIG. 13 illustrates the bag assembly with popcorn 130 disposed inside the inner receptacle of the bag. Popcorn is one of many take out foods that can be distributed in the bag assembly containing a composite material. Other take out food suitable for distribution in this bag assembly include, for example, pizza, hamburgers, tater tots and French fries, corn dogs, doughnuts, and biscuits.

[0125] FIG. 14 is a top plan view of the bag assembly 140 that illustrates popcorn 144 and other take out food items disposed in the bag make direct contact with the absorbent layer 143 in the inner surface. Additionally, this view displays the separate components of this example including the inner absorbent layer 143, the middle liquid barrier 142, and the outer absorbent layer 141.

[0126] FIGS. 15-17 illustrate a baking sheet 150 comprising a composite material. In use, the baking sheet 150 may be placed in a baking pan 151 and used to cook food at high temperatures. In this example of FIG. 15, bacon 152 is placed on a baking sheet 150 disposed in a baking pan 151 and cooked at 450 F. FIG. 16 illustrates the baking sheet after the bacon is cooked and removed from the baking sheet. Dark colored areas 160, 165 on the top surface 162 of the baking sheet show fat, oil, grease, water, and other liquids that are absorbed into the baking sheet during and after cooking. Absorbed liquids are trapped in the absorbent layer so that the bottom surface 161 of the baking sheet 150 and the surfaces of the pan 164 covered by the baking sheet are not contacted by fats, oils, grease, water, and other liquids absorbed from the food. The baking sheet 150 is further removable from the baking pan so that it can be separately disposed. By preventing liquids excreted by the food during and after cooking from contaminating the baking pan 151, using the baking sheet comprising a composite material as a baking pan liner allows the baking pan 151 to be reused without washing. Using the baking sheet to absorb fats, oils, grease, sodium, and other high calorie nutrients from the surface of the food further makes food healthier by reducing consumption of high calorie nutrients contained in take out foods.

[0127] The baking sheet may be dimensioned to be disposed in a rectangular, square, or circular baking pan. Alternatively, it may be distributed on a roll so it can be cut to size. In one example, the baking sheet 167 has scored edges 168 around the outer surface 166 of the sheet. Scoring allows the outer edge 166 of the sheet 167 to be folded up to cover the side surfaces of the baking pan. In a preferred example, the outer edge of the sheet 166 has a width of a quarter inch beyond the scored edge 168. In this example, grease would have to travel a quarter inch above the bottom surface of the baking sheet 167 to contact the side surfaces or the rim of the baking pan 151. In other examples, the outer edge 166 of the baking sheet 167 is greater than a quarter inch. In these examples, the outer edge 166 may fold over the entire side surfaces and/or rim of the baking pan 151. In a preferred example, the outer edge 166 is wide enough to cover all surfaces of the baking pan 151. In this example, none of the surface area of the baking pan 151 is uncovered and open for contamination by liquid excreted from food during cooking.

[0128] In use, a baking sheet 161, 162 comprising the composite material is disposed in a baking pan 151. The absorbent layer is positioned facing upward so that it can directly contact the bottom surface of the food. One or more liquid barriers, for example, a lamination layer or non-absorbent layer, are attached to the absorbent layer so that the liquid barriers are positioned between the absorbent layer and the surface of the baking pan 163, 164. Food is then cooked on the surface baking sheet so that fats, grease, oils, water, and other liquids excreted from the food during cooking are absorbed by the baking sheet. Once absorbed, liquid is then trapped in the absorbent layer by one or more liquid barriers. These liquid barriers prevent absorbed liquid from contaminating the baking pan surfaces 163, 164.

[0129] An example baking sheet comprising the composite material illustrated in FIG. 5, includes a lamination layer 56 that forms the first liquid barrier and is coated directly on the back surface of the absorbent layer 52. A non-absorbent layer 57 forms the second liquid barrier and is attached to the rear surface of the lamination layer 56. In one example, the non-absorbent layer 57 is an OGR paper material. In other examples, the non-absorbent layer 57 comprises a synthetic polymer based liquid barrier material, for example, high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), polyhydroxyalkanoate (PHA), polyglycolic acid (PGA), polyethylene terephthalate (PET), polypropylene (PP), polystyrene, and polyvinyl chloride

Characterization

[0130] Samples of the embodiments described herein were tested for compostability and absorbance. The chemical composition of the sample embodiments was also discerned to evaluate the material's safety for food contact applications. Compostability tests were performed according to the American Society for Testing and Material (ASTM) International test for standard specification for labeling of end items that incorporate plastics and polymers as coatings or additives with paper and other substrates designed to be aerobically composted in municipal or industrial facilities or the ASTM 6868. Tests were performed under laboratory conditions at the University of Wisconsin-Stevens Point Institute for Sustainable Technology in Stevens Point, Wis.

[0131] The ASTM 6868 is a set of testing criteria used by the Biodegradable Products Institute (BPI) to certify compostable materials and products such as food packaging. BPI relies on the ASTM D6400 test for plastic and the ASTM 6868 test for coated paper products or paper materials polymer binding agents. To pass ASTM tests and become part of BPI's certified compostable program, a product must: i) disintegrate quickly leaving no visible residue that has to be screened out, ii) biodegrade fully or convert rapidly to carbon dioxide water and biomass, iii) result in compost that supports plant growth, and iv) not introduce high levels of regulated materials into the soil.

[0132] The ability of samples to absorb fat, calories, cholesterol, fatty acids, and sodium from the surface of cooked take-out pizzas was tested using pizzas obtained from PIZZA HUT, DOMINO's, PAPA JOHN's, LITTLE CAESARS, and SABARRO. Pizzas contacting samples included thin crust pizzas, thick crust pizzas, meat lovers pizzas, and veggie pizzas. Testing was performed under laboratory conditions by COVANCE LABORATORIES, INC. of Madison, Wis.

Compostability

[0133] Disintegration and biodegradation methodology for this experiment was based on a modified version of the ASTM method for compostability tested without humidified aeration and carbon dioxide capture (ASTM D5338). Industrial composition conditions were simulated in a laboratory incubator set to 58 C.2 for 7 weeks in the Wisconsin Institute for Sustainable Technology Compostability Laboratory at the University of Wisconsin Stevens Point College of Natural Resources. The composting vessels were 2-liter KIMAX glass bottles closed at the top by a rubber stopper fitted with a hole running through the center. An air-tight rubber sleeve was fitted around the threaded mouth of the bottles to avoid sticky glass on rubber contacts between the bottle and stopper. A plastic tube was inserted through the stopper hole into the glass bottle to limit moisture loss while providing for controlled gas exchange during composting.

[0134] There were two treatments tested in this example: a paper composite material and untreated cellulose paper. A negative blank of mature compost was also tested as a control. The untreated cellulose paper and paper composite material were added to compost in a 6:1 or 16% paper to dry compost ratio. Each treatment and the control were replicated seven times with each vessel comprising a complete, distinct sampling unit. There were twenty one vessels at the beginning of the experiment, with three sampling units removed at the end of weeks 1, 2, 3, 4, 5, 6, and 7. The vessels were placed in the incubator in a complete randomized design.

[0135] The compost in this experience is municipal, deciduous left compost (mature 2-4 months) sourced from Hsu's Compost and Soils in Wausau, Wis. Hsu's leaf compost is certified through the United States Composting Council (USCC) according to the Seal of Testing Assurance (STA) program. The compost was composed of tree leaves from municipal collection in the Wausau and Appleton, Wis. areas. Each 2-liter vessel required required 615 g of as-received (moist) compost. The compost was sieved using an 8 mm sieve to remove large debris, which was then discarded. Mature compost was used based upon the D5338 method for coated paper disintegration.

[0136] The paper composite material was prepared using an absorbent crepe paper and a non-perfluorooctanoic acid (PFOA), non-perfluorooctane sulfuic acid (PFOO), non-perfluorinated carboxylic acid (PFCA), and non-perchlorate OGR paper from Expera Specialty Solutions in Moisinee, Wis. The papers laminated together using a non-hazardous water based polymer emulsion laminate supplied from- and applied by-Prolamina Flexible Packaging Solutions, a division of Proampac, in Neenah, Wis. The untreated cellulose paper was also obtained from Expera Specialty Solutions.

[0137] The paper treatments were incorporated into the compost by cutting the paper and paper composite material, by hand, into 2 cm2 cm squares according to the ASTM D5338. The squares were then weighted in a beaker to discern the number of squares added to each vessel to achieve the desired 6:1 (615 g: 98.4 g) compost to paper ratio. Compost (615 g) was weighed into each of the twenty one vessels and the pre-weighted paper was added. Distilled water was added to bring the entire compost and paper matrix up to 60%2% moisture content. Between 101 mL and 110 mL of distilled water was added to each vessel and moisture content of the initial compost was determined gravimetrically by weighing samples from each vessel and drying for 48 hours in a 105 C. oven. The compost, paper, and water were mixed thoroughly using 2-pronged forks until a uniform matrix was produced. Each vessel was labeled with the week of its removal, the treatment, and the paper addition.

[0138] Each week during the 7 week active composting period, the compost vessels were removed from the incubator and weighed. Moisture was maintained between 50% and 60% through the 7 week trial. Moisture additions were based on individual jar weight loss and visual observations of compost and paper structure. Moisture additions were made by adding distilled water to individual vessels based on weight and additional water was mixed in using a flat soil knife. Hand mixing was necessary to promote aeration and consistent moisture distribution through the compost matrix. Mixing occurred twice a week, once with moisture additions and once without.

[0139] During final sampling of vessels removed at various weeks, the paper was separated from the compost using a series of 3 brass sieves (8 mm, 4 mm, and 2 mm) and picked from the compost using tweezers. Paper too large to pass through the 2 mm sieve was weighted (including residual compost). Paper was further processed by washing with de-ionized water over a 2 mm sieve. With much of the residual compost removed, the paper was dried in an oven at 60 C. for 6 hours. Final paper mass was recorded once dry. Paper and compost, per vessel, from removed vessels, were stored separately in quart sized ZIPLOC freezer bags. The remaining vessels were returned to the incubator in a re-randomized order. Samples from removed vessels were frozen and stored in a 0 C. walk-in freezer.

[0140] Results of the compostability testing are shown below in Table 1.

TABLE-US-00001 TABLE 1 Start Final % Breakdown Material Weight Weight Theoretical Carbon Composite Material 98.4 g 19.1 g 80.6 Untreated Cellulose Paper 98.4 g 19.9 g 79.8

[0141] After 5 weeks, the composite paper material and the untreated cellulose paper were both ahead of the 90% breakdown benchmark (72% breakdown). After 12 weeks, the % breakdown theoretical carbon of the composite material was over the ASTM D6868 90% benchmark for biodegradation and more than 90% of the original material was lost to disintegration.

[0142] FIG. 6 illustrates the % breakdown of the composite material and the untreated cellulose paper over the first 5 weeks of the compostability testing. As shown in the figure, after 10 days, the composite material was in-line with or exceeded the 90% breakdown benchmark. Furthermore, after 35 days, the composite material out performed both the 90% benchmark (by 8.6%) and the untreated cellulose paper (0.8%) in biodegradation and disintegration.

Nutrient Absorbance

[0143] The composite material was evaluated for its ability to absorb excess nutrients from the surface of greasy takeout foods. Pads made from the composite material were placed in contact with pizzas obtained from five popular take out pizza chains-PIZZA HUT, DOMINO's, PAPA JOHN's, LITTLE CAESARS, and SABARRO in Madison, Wis. Pads weight ranged from 11.8 g to 7.3 g so that pads of various sizes could be evaluated for there ability to absorb nutrients from different types of take out pizza. Thin crust, thick crust, meat lovers, and veggie style pizzas were tested. Absorbance experiments were performed by Covance Laboratories, Inc. of Madison, Wis. Samples very prepared in the field in a mobile laboratory and nutrient extraction was performed under laboratory conditions using the Soxhlet extraction method.

[0144] Samples were prepared by applying pads to the top and bottom surfaces of the pizzas. Once in contact with the pizza, the composite material absorbed nutrients from the pizza surface into the pads. Soaked pads were stored on ice and transported to Covance Laboratories for nutrient extraction and absorbance analysis.

[0145] Nutrients were absorbed form the pizzas using this method: i) weigh composite paper material pad before use, ii) obtain a take out pizza in corrugated cardboard pizza box from a take out restaurant, iii) within 5 minutes of purchasing the pizza, insert the pad underneath the bottom surface of the pizza so that the pad is between the pizza surface and the cardboard box, iv) close the pizza box and weight 30 minutes, v) apply a second pad to the top surface of the pizza by pressing down lightly to assure contact between the pizza and the composite material, vi) remove both pads after 2 minutes of contact by the second pad, vii) remove any loose toppings of pizza material from the pads, and viii) weigh each pad separately immediately after use.

[0146] Nutrients were extracted from prepared samples using the Soxhlet extraction method. The extraction was conducted under laboratory conditions using the extraction method described in Official Methods of Analysis of AOAC INTERNATIONAL, Method 960.39 and 948.22 published by AOAC INTERNATIONAL of Gathersburg, Md. Excess nutrients were extracted from pads made from paper composite material by: i) obtain pads applied to take food in the field, ii) weigh pads into a cellulose thimble containing sea sand and dried to remove excess moisture, iii) extract nutrients from pads using penetne as a solvent for 5 hours, iv) evaporate pentene from the extract, v) dry and weigh the extract for analysis.

[0147] Upon extraction, the composition of extracted nutrients was determined by Inductively coupled plasma atomic emission spectroscopy (ICP-AES). This technique produces an inductively coupled plasma to excite atoms into emitting a electromagnetic radiation response that is characteristic of a particular element or combination of elements. Measured sodium and fat content of the extract absorbed by the composite paper material pads was then used to calculate the fat and sodium content of the nutrients absorbed by the pad from the pizzas. The percent of the pizza's total sodium and fat content absorbed by the composite material was determined using the nutrient content analysis to provide an estimate for the paper composite materials ability to remove fat and sodium from take out foods.

[0148] Results of the fat absorbance analysis including are displayed below in Table 2.

TABLE-US-00002 TABLE 2 Absorbed Absorbed Absorbed % Fat Sample Nutrients Fat Calories Reduction Pad 1 11.80 g 10.49 g 94.4 Cal 9.5% Pad 2 9.60 g 9.09 g 81.8 Cal 8.8% Pad 3 9.10 g 8.12 g 73.1 Cal 7.4% Pad 4 10.60 g 7.97 g 71.8 Cal 6.1% Pad 5 11.10 g 9.42 g 84.8 Cal 8.1% Pad 6 8.60 g 6.88 g 61.9 Cal 5.6% Pad 7 8.60 g 6.48 g 58.3 Cal 5.0% Pad 8 9.60 g 8.70 g 78.3 Cal 8.0% Pad 9 7.30 g 6.77 g 60.9 Cal 6.4% Pad 10 8.90 g 8.29 g 74.6 Cal 7.9% Average 9.52 g 8.22 g 69.2 Cal 7.3%

[0149] Fat in this analysis includes saturated fatty acids, monounsaturated fatty acids, polyunsaturated fatty acids, and trans fatty acids. The fatty acids measured in this analysis include, Butyric Acid, Caproic Acid, Caprylic Acid, Capic Acid, Lauric Acid, Myristic Acid, Myristoleic Acid, Pentadecanoic Acid, Pentadecenoic Acid, Palmitic Acid, Heptadecanoic Acid, Heptadecenoic Acid, Stearic Acid, Oleic Acid, Linoleic Acid, Arachidic Acid, Gamma Linolenic Acid, Elcosadienoic Acid, Behenic Acid, Erucic Acid, Elcosatrienoic Acid, Arachidonic Acid, Arachidonic Acid, and Lignoceric Acid. On average, 86.5% of all Absorbed Nutrients were Fat leaving only 13.5% for sodium, cholesterol, an other nutrients. % Total Fat was calculated assuming a pizza with 98 g fat per serving.

[0150] Results of the sodium absorbance analysis are shown below in Table 3.

TABLE-US-00003 TABLE 3 Absorbed Absorbed % Sodium % Daily Sample Nutrients % Sodium Sodium Reduction Value Pad 11 10.2 g 0.56% 57.6 mg 1.0% 1.6% Pad 12 15.6 g 0.10% 15.3 mg 0.27% 0.64% Pad 13 34.6 g 0.07% 25.5 mg 0.45% 1.06% Average 21.0 g 0.24% 32.8 mg 0.57% 1.1%

[0151] Sodium measured in this analysis includes chloride and sodium chloride salt. % Sodium Reduction was based on a total sodium value of 5,610 mg per serving and % Daily Value was calculated using a 3,400 mg sodium daily value.

Thermal Insulation

[0152] The composite material was evaluated for its ability to thermally insulate food. Specifically, the material's tendency to reduce heat loss from cooked food while inside conventional food packaging was evaluated relative to a control sample. Temperature data was gathered on large pizzas obtained from five popular take out pizza chains-PIZZA HUT, DOMINO's, PAPA JOHN'S, LITTLE CAESARS, and SABARRO in Madison, Wis. In order to isolate the thermal insulation character of the composite material, pizzas were kept in corrugated cardboard boxes throughout the experiment for both the control samples and the samples containing the composite material. Thermal insulation experiments were performed by COVANCE LABORATORIES, INC. of Madison, Wis. Samples were prepared and temperature data was collected in the field in a mobile laboratory using an infrared thermometer.

[0153] Samples containing the composite material were prepared by placing a first pad composed of the composite paper material under the pizza and a second pad over the top surface of the pizza 10 minutes after obtaining the pizza. Temperature measurements were made for the control samples 5 minutes after receiving the pizza and 30 minutes after receiving the pizza. The total time for the control experiment was 25 minutes. For the composite material samples, temperature measurements were made 5 minutes after obtaining the pizza (5 minutes before placing the sheet) and 30 minutes after applying the pads to the pizza. The total time for the composite material experiment was 35 minutes. To obtain the thermal insulation property, the initial temperature of the pizza was subtracted from the final temperature of the pizza. Each experiment was repeated seven times to collect data across multiple trials.

[0154] Results of the thermal insulation experiments for the control samples are displayed below in Table 4.

TABLE-US-00004 TABLE 4 Sample Initial Temperature Final Temperature Temp. Difference Control 1 58.9 C. 47.9 C. 11.0 C. Control 2 69.0 C. 58.8 C. 10.2 C. Control 3 69.9 C. 61.7 C. 8.2 C. Control 4 75.6 C. 63.2 C. 12.4 C. Control 5 69.3 C. 59.2 C. 10.1 C. Control 6 70.4 C. 54.2 C. 16.2 C. Control 7 69.5 C. 46.2 C. 23.3 C. Average 68.9 C. 55.9 C. 13.1 C.

[0155] Results of the thermal insulation experiment for the composite material samples are displayed below in Table 5

TABLE-US-00005 TABLE 5 Sample Initial Temperature Final Temperature Temp. Difference Pad 1 61.6 C. 54.4 C. 7.2 C. Pad 2 59.0 C. 54.4 C. 4.6 C. Pad 3 66.1 C. 59.5 C. 6.6 C. Pad 4 64.4 C. 53.1 C. 11.3 C. Pad 5 67.2 C. 53.8 C. 13.4 C. Pad 6 66.1 C. 54.4 C. 11.7 C. Pad 7 66.4 C. 47.3 C. 19.1 C. Average 64.4 C. 53.8 C. 10.6 C.

[0156] The preceding discussion merely illustrates the principles of the present pizza-blotting composites and pizza box assemblies containing such pizza-blotting composites. It will thus be appreciated that those skilled in the art may be able to devise various arrangements, which, although not explicitly described or shown herein, embody the principles of the inventions and are included within their spirit and scope. Furthermore, all examples and conditional language recited herein are principally and expressly intended to be for educational purposes and to aid the reader in understanding the principles of the invention and the concepts contributed by the inventor to furthering the art and are to be construed as being without limitation to such specifically recited examples and conditions.

[0157] Moreover, all statements herein reciting principles, aspects, and embodiments of the invention, as well as specific examples thereof, are intended to encompass both structural and functional equivalents thereof. Additionally, it is intended that such equivalents include both currently known equivalents and equivalents developed in the future, i.e., any elements developed that perform the same function, regardless of structure. Terms such as upper, top, and lower are intended only to aid in the reader's understanding of the drawings and are not to be construed as limiting the invention being described to any particular orientation or configuration.

[0158] This description of the exemplary embodiments is intended to be read in connection with the figures of the accompanying drawings, which are to be considered part of the entire description of the invention. The foregoing description provides a teaching of the subject matter of the appended claims, including the best mode known at the time of filing, but is in no way intended to preclude foreseeable variations contemplated by those of skill in the art.