Adjustable stand for holding a liquid explosive

Abstract

A low-cost, reliable and easy to use kit for neutralizing surface exposed landmine and unexploded ordnance for humanitarian demining is based on a liquid fuel and a solid/soluble fuel. Both fuels are premeasured in separate, sealed containers. The addition of a small quantity of solid/soluble fuel into the liquid creates an explosive. The resulting mixture is capable of detonating with a standard No. 8 blasting cap. The solid/soluble fuel can be in the form of a powder, tablet, or its saturated solution in water. The solid/soluble fuel is hexamethylenetetramine. The liquid fuel, nitromethane, is provided in premeasured quantities. User is provided instructions for choosing the appropriate quantity of liquid fuel, the corresponding solid/soluble fuel required, the method of mixing, placement and detonation of the kits. Also disclosed is a simple wooden stand to hold the bottle of explosive in place. A special fuel, liquid 2-ethylhexylnitrate, is provided to desensitize the mixed and sensitized explosive.

Claims

1. An adjustable stand for holding a bottle of liquid explosive having a molded socket to neutralize above ground or surface-laid landmines and unexploded ordnance, comprising: an elongated stake 45 cm long having dowel holes at regular intervals along its length; a dowel 20 cm long having an end for fitting to the molded socket and secure the bottle, and another end to insert the dowel through a dowel hole of the elongated stake, wherein said dowel has regularly spaced pin holes along its length; and pins to insert into selected pin holes to secure the dowel at an extension through said dowel hole of the elongated stake, said pin holes in the dowel allowing for adjustment of a horizontal distance between the elongated stake and the bottle containing the liquid explosive positioned near a neutralization target.

2. The adjustable stand according to claim 1, wherein said adjustment of a horizontal distance extends the bottle containing the liquid explosive over a mine as the neutralization target.

3. The adjustable stand according to claim 1, wherein said adjustable stand secures the bottle of explosive in place for properly neutralizing above ground or surface-laid landmines and unexploded ordnance.

4. The adjustable stand according to claim 1, wherein said elongated stake is a wooden stake having dimensions 45 cm long, 2 cm wide and 1 cm thick, the wooden stake having 0.5 cm diameter dowel holes along the length at 2.5 cm intervals for insertion of a dowel at various heights.

5. The adjustable stand according to claim 1, wherein the dowel is made from wood, 20 cm long and 0.5 cm diameter, and wherein said pin holes are 0.2 cm diameter, allowing for a pin to secure the dowel in the elongated stake.

6. The adjustable stand according to claim 1, wherein the molded socket is disposed on a side of the bottle.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Additional advantages and features will become apparent as the subject invention becomes better understood by reference to the following detailed description when considered in conjunction with the accompanying drawings wherein:

(2) FIG. 1A is a side view of a first small container containing premeasured flammable liquid nitromethane;

(3) FIG. 1B is a side view of the second container, a small reusable vial containing solid fuel powder or a tablet or saturated solution of solid/soluble fuel in water;

(4) FIG. 1C is a side view of combine kit mix of transferring the contents of FIG. 1B into container shown in FIG. 1A;

(5) FIG. 1D shows the electric blasting cap fixed to the outside of the mixed container of FIG. 1C;

(6) FIG. 1E is a side view of the combined kit, similar to FIG. 1C, with a changed screw cap that has a predrilled hole in center through which an electric basting cap has been inserted from top to dip into the liquid;

(7) FIG. 1F is a side view of the combined kit similar to FIG. 1C, with a changed top screw-cap that has a predrilled hole in center through which a detonation cord has been inserted from top and double knotted and then dipped into the solution and the screw cap tightened.

(8) FIG. 2A is a side view of a medium cylindrical container containing premeasured flammable liquid nitromethane;

(9) FIG. 2B is a side view of a second container, a small reusable vial containing solid fuel tablets;

(10) FIG. 2C is a side view of the combined kit, tablets from the small sample vial in FIG. 2B into the container in FIG. 2A;

(11) FIG. 2D is a view of the combined solution in the container of FIG. 2A with the top replaced with a pre-drilled hole in the center, though which an electric cap is inserted from top until it dips into liquid.

(12) FIG. 3A is a side view of a large container of premeasured flammable liquid nitromethane;

(13) FIG. 3B is a view of the second small container, a vial containing a saturated solution of solid fuel powder in water;

(14) FIG. 3C is a side view of the combined kit made by transferring the water solution of solid/soluble fuel into the container shown in FIG. 3A;

(15) FIG. 3D shows the completed kit of FIG. 3C with the cap replaced by one with a pre-drilled a central hole, through which an electric basting cap is inserted from top.

(16) FIG. 4A illustrates the transferring of powder or tablets or solution of solid/soluble fuel in water from the small vial to the nitromethane liquid container.

(17) FIG. 4B illustrates tightening screw-cap on the nitromethane container;

(18) FIG. 4C-illustrates shaking the nitromethane container until the contents are mixed.

(19) FIG. 5 illustrates the inserting an electric blasting cap through the specially designed nozzle screw cap.

(20) FIG. 6 illustrates the specially fabricated bottle with a nozzle screw-cap and a molded socket on the side to hold the bottle on the stand.

(21) FIG. 7 illustrates the design of the wooden stand.

(22) FIG. 8 illustrates placing the assembled kit adjacent to but without touching an AP landmine.

(23) FIG. 9 illustrates placing the assembled kit adjacent to but without touching an AP wooden case blast landmine.

(24) FIG. 10 illustrates placing the assembled kit adjacent to but without touching an AP plastic case bounding mine.

(25) FIG. 11 illustrates placing the assembled kit using the specially designed stand to attack an AP stake land mine from an angle.

(26) FIG. 12 illustrates placing the assembled kit attacking a Claymore AP directional scatterable landmine using the specially designed stand.

(27) FIG. 13 illustrates placing the assembled kit directly on an AT plastic case landmine.

(28) FIG. 14 illustrates placing the assembled kit directly on an AT metal case landmine.

(29) FIG. 15 illustrates placing a large assembled kit directly on 155 mortar shell using specially designed large kit holder.

DETAILED DESCRIPTION

(30) A low-cost, reliable and easy to use kit for neutralizing surface exposed landmine and unexploded ordnance for humanitarian demining is provided. The kit contains two non-explosive materials: a liquid fuel and a solid/soluble fuel. Both fuels are pre-measured in separate, sealed containers. The addition of a small quantity of solid/soluble fuel of (about 1% by weight) into the liquid creates an explosive. The resulting mixture is capable of detonating with a standard No. 8 blasting cap inserted through a specially designed screw cap. The solid/soluble fuel can be in the form of a powder, tablet, or its saturated solution in water. The solid/soluble fuel is hexamethylenetetramine in 6 mL sample vial. The liquid fuel, nitromethane, is provided in pre-measured quantities in three sizes of plastic bottle, 2 oz., 4 oz., and 8 oz. User is provided instructions for choosing the appropriate quantity of liquid fuel, the corresponding solid/soluble fuel required, the method of mixing, placement and detonation of the kits for neutralizing landmines and unexploded ordnance. Also disclosed is a simple wooden stand to hold the bottle of explosive in place for properly neutralizing above ground or surface-laid landmines and unexploded ordnance. A special fuel, liquid 2-ethylhexylnitrate, is provided to desensitize the mixed (sensitized) explosive, should the prepared explosive not be used.

(31) The two-component liquid explosive of the present invention comprises a mixture of hexamethylenetetramine (HMTA), in the form of a powder, tablets or its saturated solution in water and nitromethane. In order to make the explosive compound, the two individual nonexplosive components, are simply added together in the proper proportion and shaken by hand. The resulting mixture is a clear, yellow liquid, and is detonable from 0-32 C. (32-90 F.) in a diameter of 1.5 cm or greater with a standard commercial No. 8 an electric blasting cap.

(32) The HMTA powder or tablet or its saturated solution in water acts as sensitizer to the nitromethane, causing the liquid to become a standard blasting cap sensitive explosive. The preferred HMTA powder is obtained from Alfa Aesar (A Johnson Matthey Company), Ward Hill, Mass. Alfa Aesar's Stock Number is A17213 and is also known as hexamine or methenamine. Hexamethylenetetramine (HMTA) has been known over 130 years. It was the first organic molecule on which X-ray crystallography was performed. It is a heterocyclic organic compound that can be prepared by the reaction of formaldehyde and ammonia. Methenamine is more common in its medical uses and hexamine is more common in commercial uses. It was evaluated for acceptable daily intake as a food additive (as a preservative for fish, meat and pickles and cheeses). It decomposes gradually yielding ammonia and formaldehyde. It is used in vulcanization as an accelerator, in synthetic resins, in medicine as a diuretic and urinary antiseptic, as curing agents for phenolic and resorcinol resins, in fuel tablets for cooking, in the photographic industry as a stabilizer, as a corrosion inhibitor, in fungicides, as protein modifiers, as reagents in chemical analysis, and in the manufacture of the explosive RDX. It is not an explosive and has no explosive power. However, it is used as a basic raw material in slurry explosive. Technical details follow:

(33) Chemical name: 1,3,5,7-tetraazatricyclo [3.3.1.13,7] decane

(34) Chemical family: Tricyclic amine

(35) CAS number: 100-97-0

(36) Chemical formula: C6H12N4

(37) Density: 1.33 g/mL at 20 C. (68 F.)

(38) Particle sizes: 80-800 micron

(39) Solubility: soluble in water (0.85 g/mL), ethanol, acetone, chloroform and glycerin

(40) Boiling point: 285-295 C (545 F.-563 F.) (sublimes)

(41) Melting point: 280 C. (536 F.)

(42) Flash point: 250 C. (482 F.)

(43) Auto ignition: 410 C. (770 F.)

(44) Vapor pressure (mm Hg): 0.0035 at 20 C. (68 F.)

(45) Decomposition Temperature: 800 C. (1472 F.)

(46) Flammable solid Hazard class: 4.1 by the U.S. DOT.

(47) Nitromethane (NM) is a colorless, oily, and a highly polar and optically anisotropic molecule; it is liquid in temperature range 28.5 to 101 C. (19.3 to 213.8 F.) at room pressure, therefore, many complexities associated with solid materials can be avoided. It has mass density 1.13 g/mL at 25 C. (77 F.). All commercially available NM is never available at 100% of purity. It is an insensitive high explosive that serves as a good prototypical energetic material. It is also the simplest member of the family of nitrocompounds. NM was first prepared in 1872 by Kolbe and for many years was considered to be very stable compound. In 1938 Mckittrick and coworker reported that NM could be detonated under conditions of strong confinement. It has been known since the late 1940s that nitromethane can be sensitized toward detonation by the addition of small amounts of liquid amines. The mechanism of amine sensitization, although widely believed to be chemical in nature, is not well understood. Different hypotheses of sensitization were proposed but there is no agreement between these hypotheses. The sensitization of nitromethane mixtures decreases as the nitromethane aci-anion concentration increases. With small amounts of amines present, each amine molecule can form a complex with nitromethane molecules. The formation of this charge transfer complex weakens the nitrocompound CN bond. A match will not ignite NM. It is an oxygen donating fuel, not reliant completely upon atmospheric oxygen for combustion. It is one of several compounds that decomposes exothermically and may be used as a monopropellant in small rocket thruster and demand gas generators. NiO/alumina as catalyst is effective in causing NM decomposition. This versatile chemical is used in a wide range of industrial applications including as a stabilizer for chlorinated hydrocarbons, a component for special fuels in internal combustion engines, a solvent for many chemical reactions such as polymerization, a corrosion inhibitor and raw material in the synthesis of many useful chemicals. It is used in making dyes and resins, re-crystallization solvent, polar solvent in synthesis, textile, surfactants, insecticides, pharmaceuticals, and is an ingredient in known prescription ulcer medication. NM is an ingredient in making binary and some explosives; however, under normal use it is not an explosive itself. It is not a fuel oil, but a volatile chemical used in top-fuel drag racing. NM is fairly innocuous when unconfined/uncompressed. It has a relatively high flash point, but is extremely explosive when pressurized or highly confined or at high temperature. Its detonation velocity is near that of RDX with the same density.

(48) NM is one of the simplest organic explosives. The liquid explosives are homogenous in normal conditions. The activation energy of NM compressed by a shock wave is about 25 kcal/mole, i.e., half value for the gas-phase unimolecular decomposition. The detonation velocity of liquid explosives decreases linearly with respect to the reciprocal of the charge diameter and is nearly independent of the confinement nature. When inert particles are added to a liquid explosive such as NM, the detonation velocity and pressure are reduced since a portion of the chemical energy released goes to heating and accelerating the inert material. Adding a small number of inert heterogeneities such as solid particles or microballoons to NM also leads to a large increase in the sensitivity of NM. This sensitizing effect is due to the generation of hot-spots as a result of the interaction of the shock wave with the heterogeneities. The heterogeneous explosive is most insensitive (i.e., the failure diameter reaches a maximum). Pure NM packed with inert additives of small spherical glass and Al particles have reduced detonation velocities and critical diameter compared to the liquid explosive alone.

(49) NM is a very stable liquid but it can be detonated under extraordinary conditions. When it does detonate, it is extremely powerful and is useful in many special applications. However, the difficulty in initiating detonation has long been a problem, often requiring expensive primers and boosters.

(50) In NM, 19.3% by weight of water is miscible (soluble) at 70 C./158 F. Commercial NM is sometimes quite acidic. Due to the electron-withdrawing capability of the nitro group, the adjacent alpha-protons are acidic (pKa=10.2) and can be deprotonated with a strong base. It is a colorless, lucid liquid whose aqueous solution is acidic.

(51) 2-Ethylhexyl nitrate (2-EHN) is a high-boiling alkyl nitrate, in which the alkyl contains greater than 3 carbon atoms. It has a chemical formula CH.sub.3(CH.sub.2).sub.3CH(C.sub.2H.sub.5)CH.sub.2ONO.sub.2 and chemically related to nitroglycerin and ethylene glycol dinitrate. It undergoes a self-sustaining exothermic decomposition when it is heated above 100 C. (212 F.). Once established the decomposition reaction may be uncontrollable. It may contain traces of unreacted residual 2-ethylhexanol and/or water. It is colorless to pale yellow, a low viscosity liquid having a density of 0.96 g/mL at 20 C. (68 F.). It is combustible but it is not classified as a flammable liquid. It is stable at ambient temperature, however, it has a low autopignition temperature, and will decompose when heated above 100 C. (212 F.). It is mainly used in the petrochemical industry to increase the cetane number and the hexadecane value of diesel oil. It improves diesel engine performance, allowing quicker cold startup, diminution of engine startup noise, reduction in engine knock and wear, decrease or elimination of carbon build-up on injector nozzles and better fuel economy and engine life. Combustible liquid, Hazard class: 9 by the U.S. DOT.

(52) The liquid EHN is obtained from Aldrich Chemical Company, Milwaukee, Wis.

(53) Referring to FIGS. 1A and 1B, an exemplary kit according to the present invention includes the first container 4 with a capped opening 8, such as screw cap. The first container 4 is filled with a premeasured amount of nitromethane fuel, a light yellow liquid 12. The kit contains a second, smaller reusable container 16 with means of resealing 20 such as screw cap. In the embodiment shown FIGS. 1A and 1B, the second container 16 is a plastic vial containing solid fuel hexamethylene tetramine (HMTA), in the form of powder 24a, tablets 24b or its saturated solution in water 24c, which is capable of sensitizing flammable nitromethane to detonation.

(54) FIG. 1C illustrates the exemplary embodiments of FIGS. 1A and 1B in combined form resulting in yellow liquid, a sensitized nitromethane 28. The solid powder fuel HMTA, a powder 24a, or tablets 24b or saturated solution in water 24c has been transferred from the second container 16 into the first container 4 and the container has been resealed 8 and shaken.

(55) In FIG. 1D, an exemplary initiation system 32 has been affxed to the outside of the first container 4, using electrical tape 36. In this embodiment the initiation system 32 consists of an electric blasting cap of No. 8 strength.

(56) FIG. 1E illustrates another exemplary method of attaching the initiation system 32 to this embodiment, where screw cap 8 of the first container 4 has been replaced with a screw cap with a pre-drilled hole in the center 40. The initiation system 32 has been inserted through the hole 40 until it dips into the sensitized nitromethane 28.

(57) FIG. 1F illustrates a third exemplary method of initiation that may be used. Detonation cord 44, containing 55 grains (0.065 g) of pentaerythrol tetranitrate (PETN) explosive per foot, is inserted through the screw-cap hole 40 and knotted twice at the end of the cord and the knot is dipped into the sensitized NM 28.

(58) Referring to FIGS. 2A and 2B, an exemplary kit according to the present invention includes the first container 48 with a capped opening 8, such as screw-top cap. The first container 48 is filled with a premeasured amount of nitromethane fuel, a light yellow liquid 12. The exemplary kit contains a second, smaller reusable container 16 with means of resealing 20 such as top screw cap. In the embodiment shown FIGS. 2A and 2B, the second container 16 is a plastic vial containing solid fuel HMTA, in the form of tablets 24b, which is capable of sensitizing flammable nitromethane to detonation.

(59) FIG. 2C illustrates the exemplary embodiments of FIGS. 2A and 2B in combined form resulting in yellow liquid, a sensitized nitromethane 28. The solid fuel tablets of HMTA 24b has been transferred from the second container 16 into the first container 48 and the container has been resealed 8 and shaken.

(60) FIG. 2D illustrates an initiation system 32 embodiment to this exemplary embodiment, where screw cap 8 of the first container 48 has been replaced with a screw cap with a pre-drilled hole in the center 40. The initiation system 32 has been inserted through the hole 40 until it dips into the sensitized nitromethane.

(61) Referring to FIGS. 3A and 3B, another exemplary kit according to the present invention includes the first container 52 with a capped opening 8, such as screw cap. The first container 52 is filled with a premeasured amount of nitromethane fuel, a light yellow liquid 12. The exemplary kit contains a second, smaller reusable container 16 with means of resealing 20 such as screw cap. In the embodiment shown FIGS. 3A and 3B, the second container 16 is a plastic vial containing saturated solution of solid fuel HMTA in water 24c, which is capable of sensitizing flammable nitromethane to detonation.

(62) FIG. 3C illustrates the exemplary embodiments of FIGS. 3A and 3B in combined form resulting in light green liquid, a sensitized nitromethane 28. The saturated solution of solid fuel HMTA in water 24c has been transferred from the second container 16 into the first container 52 and the container has been resealed 8 and shaken.

(63) FIG. 3D illustrates initiation system 32 to this embodiment, where screw cap 8 of the first container 52 has been replaced with a screw cap with a pre-drilled hole in the center 40. The initiation system 32 has been inserted through the hole 40 until it dips into the sensitized nitromethane.

(64) In use, the second container 16 is transferred into the first container 4 as illustrated in FIG. 4A. The top screw-cap 8 is tightening as illustrated in FIG. 4B. The first container 4 is shaken to dissolve powder or tablets or mixing of saturated solution of powder in water as illustrated in FIG. 4C. On mixing color of solution changed from original light yellow to yellow when powder or tablets are used. If a saturated solution of powder in water is used, the original light yellow will change to light green. The nitromethane liquid is sensitized and ready for application. Now change screw cap with a cap with a center hole. An initiation system 32, such as an electric blasting cap No. 8 strength is then inserted through the screw cap as illustrated in FIG. 5.

(65) In the present invention consists of inexpensive commercially available products. In one exemplary embodiment, the first container 4, 48 and 52 is a commercially available plastic container (2, 4 and 8 oz. bottles) with a screw cap, with and without hole. The second reusable small container 16 with resealing means 20 may be plastic vial with screw cap.

(66) In an alternative exemplary embodiment commercially available container 4, 48 and 52 and chemical 24 and stand may be substituted with custom manufactured containers, solid chemical and stand.

(67) In the illustrated FIG. 6 another embodiment, the three sizes of plastic bottles will be custom manufactured to have capacity 75, 150 and 300 mL with dimension 9.2 cm height, 3.4 cm diameter, 11.6 cm height and 4.1 cm diameter, 15.4 cm height and 5.1 cm diameter, of container 56, 72 and 76 respectively. Each size of bottle has a plastic socket 60 on the side near the top, 1 cm long and 0.5 cm diameter. The molded socket, identical on each size of bottle, is the junction between the bottle and the stand. The three sized bottles have identical threaded openings, 2 cm diameter, in order that the screw caps 64 and screw cap with nozzle 68 may be exchanged among the bottles. Two types of threaded caps fit on the bottles. One is a closed cap 64 to seal the bottle. The second cap has a small tubed opening or nozzle 68, 2 cm in length. The nozzle, with an opening 0.7 to 0.75 cm, allows for the insertion and stabilization of an electric blast cap No. 8. The nozzle will ensure the electric blasting cap remains in the center of the solution, which is an important to get reliable performance of liquid explosive. The depth to which the blasting cap is inserted can be adjusted as needed and secured with a piece of tape to the nozzle and blasting cap.

(68) The chemical available in powder form can be pressed into tablets. Each tablet may weigh around one gram and the approximate diameter is one cm. The tablets can be bottled in appropriate quantities or packed individually in foil or blister packs similar to medicine tablets.

(69) Yet another objective of the present invention is to provide a delivery system for liquid explosive filled that does not introduce metal debris into mined area and allows the liquid explosive bottle to be electrically initiated remotely from a safe distance. This delivery system is a single shot apparatus. The stake is driven into the soil near the target. One end of the dowel is inserted into bottle socket as illustrated in FIG. 6 and other end of the dowel is inserted into the stake. The dowel's length is fixed by inserting a plastic pin into a hole in the dowel closest to the stake. Once the bottle distance is fixed, the bottle can rotate on the dowel to aim with respect to the neutralizing target. The delivery system will be useful to attack mines above ground or mines from the top. The custom-made delivery system or stand as illustrated FIG. 7 is comprised of three components: stake 80, dowel 84 and plastic pin 88. The stake may be made from wood having dimensions 45 cm long, 2 cm wide and 1 cm thick. The stake may have 0.5 cm diameter holes along the length at 2.5 cm intervals, designed for the insertion of the dowel at various heights. The dowel may be made from wood, 20 cm long and 0.5 cm diameter. The end of the dowel fits the molded socket 60 on the side of the bottles. The dowel may have several small holes around 0.2 cm diameter, allowing for the pin to secure the dowel in the stake. The several small holes in the dowel allow for adjustment of the horizontal distance between the stake and the bottle containing the liquid explosive positioned near the neutralization target.

(70) The explosive of the present invention preferably includes three sizes of bottles and three small vials to contain the nitromethane and HMTA powder or tablets or its saturated solution in water. The bottles are preferably recappable, so that they may be opened to receive the HMTA powder or tablets or its saturated solution in water and nitromethane and then be tightly recapped. The bottle may be constructed in various specific sizes and designs out of various materials, depending on specific use. The bottle may be cylindrical.

(71) The explosive may be designed as a mine clearing charge or an unexploded ordnance charge or may be used as a demolition charge or various military applications.

(72) The mixture should contain a minimum of 0.5% of HMTA powder in relation to NM by weight. The preferred mixture is about 0.7 to 1.4 g of HMTA powder to 100 g of nitromethane. Thymol blue a sensitive indicator dye is added into nitromethane for sensing basic compound. This mixture is a clear yellow liquid and is easily pourable. Several tests were conducted by preparing the mixture of NM and HMTA in two oz. plastic bottles by increasing concentration of HMTA 1.8, 9.24 and 18.15% by weight in NM. At lower concentrations of HMTA, the HMTA dissolved in NM to produce a clear yellow liquid. At 9.24% concentration, HMTA was partially dissolved in NM producing a green liquid with undissolved HMTA particles settling at the bottom. At a high concentration (18.15%) of HMTA in NM, HMTA was partially dissolved in NM, producing a pink-blue liquid with undissolved particles of HMTA settled at the bottom. Explosive tests were performed on these samples using thick aluminum witness plates and No. 8 blasting caps. For each test the witness plate was placed on 4 inch lengths of 24 wood and the bottle was placed in the center of the witness plate. The blasting cap was inserted through a drilled hole in the cap to dip into the liquid. The electric cap was connected to a demolition device via electric wires. When the electric cap was initiated, the NM liquid was detonated, penetrating the thick aluminum witness plate. This test was carried out on each of the three HTMA/NM concentration samples. The resulting holes in the witness plates were measured on the top side of the plate and the bottom side of the plate. From the measured data it is clear that as concentration of HMTA increases in NM, the penetration diameter decreases, especially the bottom diameter. The bottom diameters on the aluminum witness plates were 4.1, 1.7 and 0.5 cm for 1.81, 9.24 and 18.15% HMTA in NM, respectively. This invention suggests that as the concentration of HMTA in NM increases the performance of NM explosive decreases. Therefore selection of suitable concentration of HMTA is very important to ensure optimal performance of NM.

(73) The method of making the two component liquid explosives of the present invention includes steps of providing a premeasured tablet size and amount or quantity of HMTA powder or amount of saturated solution of HMTA powder in water and providing a premeasured quantity of NM and providing instructions for proper mixing.

(74) There is only one suitable method of mixing the composition. The first method is by packaging the proper amount of HMTA powder or number of HMTA tablets in the vial or certain amount of saturated solution of HMTA in water and the proper quantity of NM in the bottle. The user opens the screw cap of the NM-filled bottle, adds powder or tablets into the bottle, recaps the bottle tightly and shakes the bottle until the HMTA is dissolved in NM and the color of the mixture is light yellow to yellow. Then the mixture is an explosive and is ready for use. The size of the bottle and amount of NM and HMTA is important for various applications in humanitarian demining.

(75) It has been found that this explosive performed well when it is used in a cyclinderical plastic bottle with 3.5 cm diameter due to focusing energy in vertical direction. Prepared 1% solution of HMTA stock solution by dissolving 5 g of HMTA in 500 g NM in 16 oz. plastic bottle. Several experiments were conducted, transferring 70 g, 140 g, and 280 g of stock solution in 2, 4 and 8 oz. plastic bottles respectively. The 2 oz. bottle was placed on thick aluminum plate, the 4 oz. bottle was placed on thick steel witness plate and the 8 oz. bottle was placed on thick steel witness plate. The initiations of liquid explosive experiments were performed as described previously. The thick aluminum witness plate, and thick steel witness plates were penetrated completely by 70 g, 140 g and 280 g NM solution respectively.

(76) A test was conducted on three samples of HMTA/NM using same quantity of powder HMTA in and two placements of the blasting cap and detonator cord. Three samples were prepared by adding about 0.8 g of HMTA powder into 70 g of NM in each 2 oz. plastic bottle. The samples were numbered 1, 2, and 3. Each sample bottle was closed with screw cap and shaken until the HMTA power was dissolved in the NM. Explosive tests were performed on these samples using thick aluminum witness plates and #8 blasting caps and detonator cord. For each test the witness plate was placed on 4 inch lengths of 24 wood and the bottle was placed in the center of the witness plate. For the first sample, the blasting cap was attached to side of the bottle with electrical tape (FIG. 1-D). In the second sample, the blasting cap was inserted through a drilled hole in the cap to dip into the liquid (FIG. 1-E). In the third sample, the cap was removed, detonation cord was inserted through a drilled hole in the cap and double knotted at the end, and then the cap was replaced on the bottle, dipping the knotted detonation cord into the liquid contents. The detonation cord was connected to a blasting electric cap, which was then connected to the demolition device via electric wires (FIG. 1-F). The blasting caps of sample 1 and 2 were connected to the demolition device via electric wires. When the blasting cap was initiated on each sample, the NM liquid detonated, penetrating the thick aluminum witness plate. The resulting holes in the witness plates were measured on the top and bottom surfaces of each plate. The top and bottom diameters of the three witness plates were nearly identical, suggesting that the resulting explosive is equally powerful regardless of the placement of the blasting cap and the initiation method. The testing also suggests that both placements of the blasting cap or detonator cord are equally effective.

(77) A test was conducted on three samples of HMTA/NM using same quantity of HMTA in various forms, powder, tablet and liquid. Three samples were prepared using about 70 g of NM in each 2 oz. plastic bottle. Into the three bottles was added 0.8 g of HMTA powder, 0.8 g of HMTA tablet and 0.8 g of HMTA powder dissolved in 1 ml of water; sample number 1, 2 and 3, respectively. Each sample bottle was closed with the screw cap and shaken until the HMTA (power, tablet or water solution) was dissolved or mixed in the NM. Explosive tests were performed on these samples using thick aluminum witness plates and #8 blasting caps. For each test the witness plate was placed on 4 inch lengths of 24 wood and the bottle was placed in the center of the witness plate. In all samples of HTMA in NM, the blasting cap was inserted through a drilled hole in the cap to dip into the liquid, which was then connected to the demolition device via electric wires. When electric cap was initiated on each sample, the NM liquid detonated, penetrating the thick aluminum witness plate. The resulting holes in the witness plates were measured on the top and bottom surfaces of each plate. The top and bottom diameters of the three witness plates were nearly identical, suggesting that the resulting explosive is equally powerful using the powder, tablet or water solution of HMTA.

Example 1

(78) The screw cap of a two oz. plastic cylindrical bottle containing 70.0 g of NM was removed and one gram powder of HMTA or one tablet from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablet dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The bottle was placed next to, but not touching (FIG. 8), the most widely used mine in the world, a surface-exposed large round plastic case AP blast mine containing 249 g (0.249 kg) of TNT. The bottle's screw cap was replaced with a second screw cap with center hole for inserting a No. 8 blasting cap. The blasting cap was inserted from the top until it dipped into the NM liquid. The blasting cap was connected to a demolition device via electrical wires. On remote initiation of the blasting cap, the NM detonated creating an intense shock wave that detonated the AP mine by sympathetic detonation. The blast of the mine created a medium sized crater.

Example 2

(79) A 2 oz. cylindrical plastic bottle contained 70 g of NM. The screw cap of the bottle was removed and HMTA powder or tablet added from the vial. Recapped the bottle and shook the bottle a few times until tablet or powder was dissolved in the NM. On dissolving powder or tablet of HMTA, the NM original color was changed from light yellow to yellow. The screw cap was replaced with one with a center hole for inserting the blasting cap. The bottle was placed against, without touching mine case (FIG. 9), a rectangular wooden case AP mine containing 200 g (0.2 kg) of TNT. A blasting cap was inserted from top into the NM liquid and it was connected to demolition firing device via electrical wires. On initiation of electric cap, the NM detonated, generating a powerful shock wave that detonated the mine sympathetically and created a medium size crater.

Example 3

(80) In this example, the screw cap of a four oz. plastic cylindrical bottle containing 140 g of NM was removed and two gram powder of HMTA or two tablets from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablets dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The surface exposed a large cylindrical plastic case bounding AP mine containing 420 g (0.42 kg) of comp. B was attack from the side of the mine without touching the pressure fuse (FIG. 10). The bottle's screw cap was replaced with a second screw cap a center hole for inserting a No. 8 blasting cap. The blasting cap was inserted from the top until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On initiation of the blasting cap remotely, the NM detonated creating an intense shock wave that detonated the AP bounding mine without bounding by sympathetic detonation. The blast of the mine created a medium sized crater.

Example 4

(81) In this example, the screw cap of a four oz. plastic cylindrical bottle containing 280 g of NM was removed and 4 g powder of HMTA or four tablets from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablets dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The bottle has on its side a specially designed plastic socket to attach the wooden stand as shown in FIG. 11. The target AP stake mine has a very thick, flat-topped wooden stake that acts as the picket and allows the mine to be positioned above ground level. The body is cast iron and contains 75-100 g (0.75-0.1 kg) of TNT. The attack must be from the side of mine at an angle without touching the case. The bottle's screw cap was replaced with a second screw cap specially designed to hold in position a No. 8 blasting cap. The blasting cap was inserted from the top until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On initiation of the blasting cap remotely, the NM detonated creating an intense shock wave that detonated the AP stake mine by sympathetic detonation. The blast of the mine created a blast above ground, therefore no crater in the ground.

Example 5

(82) In this example, the screw cap of a two oz. plastic cylindrical bottle containing 70.0 g of NM was removed and one gram powder of HMTA or one tablet from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablet dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The side of the bottle has a specially designed plastic socket to attach it to a wooden stand, as shown in FIG. 12. The bottle was positioned on the concave side of a Claymore mine, at a 45 degree angle without touching the case of the mine. The Claymore, an AP Fixed Direction Fragmentation mine often used for protective and ambush purposes, has a molded plastic case with a convex front and concave rear and contains 628 g (0.628 kg C-4) plastic explosive. The bottle's screw cap was replaced with a second screw cap specially designed to hold in position a No. 8 blasting cap. The blasting cap was inserted in the top until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On remote initiation of the blasting cap, the NM detonated creating an intense shock wave that detonated the AP fixed directional fragmentation mine by sympathetic detonation. The blast of the mine was above ground, therefore no crater in the ground was found.

Example 6

(83) In this example, the screw cap of a four oz. plastic cylindrical bottle containing 140.0 g of NM was removed and two gram powder of HMTA or two tablets from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the tablets or powder dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The bottle's screw cap was replaced with a second screw cap specially designed to hold in position a No. 8 blasting cap. The bottle was placed on top of mine case as shown in FIG. 13 of surface exposed unfused AT plastic case mine which contains approximately 9530 g (9.53 kg) Comp B as a main charge. The basting cap was inserted in the top of the bottle until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On remote initiation of the blasting cap, the NM detonated creating an intense shock wave that detonated the AT blast mine by sympathetic detonation. The blast of the AT mine generated a large crater in the ground due to the large quantity of explosive present in the mine.

Example 7

(84) In this example, the screw cap of a four oz. plastic cylindrical bottle containing 140.0 g of NM was removed and two gram of HMTA or two tablets from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablets dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow, the NM is sensitized and is ready to use as an explosive. The bottle's screw cap was replaced with a second screw cap with a center hole for inserting a No. 8 blasting cap. The bottle was placed on the top of surface exposed unfused AT metallic case mine as shown FIG. 14 which contains approximately 5700 g (5.7 kg) of TNT as main charge. The basting cap was inserted in the top of the bottle until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On remote initiation of the blasting cap, the NM detonated creating an intense shock wave that detonated the AT blast mine by sympathetic detonation. The blast of the AT mine generated a large crater in the ground due to the large quantity of explosive present in the mine.

Example 8

(85) In this example, the screw cap of an eight oz. plastic cylindrical bottle containing 280.0 g of NM was removed and four gram powder of HMTA or four tablets from the vial was added into the bottle. The bottle was recapped and the bottle was shaken until the powder or tablets dissolved in NM. On dissolving HMTA in NM, the NM liquid color changed from light yellow to yellow. The bottle's screw cap was replaced with a second screw cap with center hole for inserting a No. 8 blasting cap. A specially designed bottle holder (5.5 cm diameter and 2.5 cm length) of PVC tube was placed and taped to the side of a surface-exposed unfused 155 mm artillery projectile, as shown in FIG. 15 The projectile contains 6530 g (6.53 kg) Comp B or TNT as main charge. The thickness of the projectile metal case varies from to 1. The bottle was placed in the bottle holder. The basting cap was inserted in the top until it dipped into the NM liquid. The blasting cap was connected to a demolition firing device via electrical wires. On remote initiation of the blasting cap, the NM detonated creating an intense shock wave that detonated the artillery projectile by sympathetic detonation. The blast of the artillery projectile generated a large crater on ground due to the large quantity of explosive present in the artillery projectile.

(86) It is obvious that many modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as described.