Body produced by an in-mold process and process for the production thereof
09753488 ยท 2017-09-05
Assignee
Inventors
- Martin Hahn (Herrieden, DE)
- Wolfgang Clemens (Puschendorf, DE)
- Rainer Sigritz (Nuremberg, DE)
- Ulrich Schindler (Furth/Bayern, DE)
- Gerald Golling (Oberasbach, DE)
Cpc classification
B29C45/14221
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14778
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14016
PERFORMING OPERATIONS; TRANSPORTING
H05K2201/0145
ELECTRICITY
B29C45/1418
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14377
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14
PERFORMING OPERATIONS; TRANSPORTING
G06F2203/04107
PHYSICS
B29C45/14754
PERFORMING OPERATIONS; TRANSPORTING
G06F3/045
PHYSICS
B29C45/14262
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14336
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14639
PERFORMING OPERATIONS; TRANSPORTING
G06F2203/04103
PHYSICS
B29C2045/1477
PERFORMING OPERATIONS; TRANSPORTING
H05K1/028
ELECTRICITY
International classification
H05K1/09
ELECTRICITY
B29C45/14
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A body (1, 1, 1) produced by an in-mold process has a first film (2, 2, 2) with at least one electrical or electronic functional layer (25). In a functional area (20a, 20a, 20a) of this functional layer, at least one electrical or electronic component is provided, and at least one electrical connection for this is provided in a contact area (20b, 20b, 20b). The first film is partially back-injection molded with a plastic main material (3, 3, 3) such that the contact area (20b, 20b, 20b) is at least partially free from this plastic main material (3). Suitable formation of the first film (2, 2, 2) guarantees that a tab (F) separated from the plastic main material (3, 3, 3) is provided which adjoins a back-injection molded part of the first film in an area of surface (20c, 20c, 20c) of the body which is at a distance from an edge (31, 31) of the body delimiting the surface (30) with the first film.
Claims
1. A body which has a first film with at least one electrical or electronic functional layer, wherein at least one electrical or electronic component is provided in a functional area of the functional layer, and wherein at least one electrical connection is provided in a contact area of the at least one functional layer, which electrical connection is galvanically coupled to at least one component, wherein the body furthermore comprises a plastic main material with which the first film is partially back-injection molded such that the contact area is at least partially free from plastic main material, wherein the first film is formed such that a tab separated from the plastic main material is provided by a non-back injection-molded part of the first film, which tab adjoins a back-injection molded part of the first film in an area of surface of the body, which is at a distance from an edge of the body delimiting the surface with the first film.
2. The body according to claim 1, wherein the plastic main material predefines a shape of the body which makes it possible at least partially to bring the tab up against the surface of the plastic main material on its side with the first film.
3. The body according to claim 1, wherein the body has a flat surface, on which the first film is arranged, and wherein the tab can be brought into a position or is located in a position in which it protrudes at an angle from the range of from 15 to 90 to the plane from an area of surface which is adjoined on all sides in respect of the surface by plastic main material.
4. The body according to claim 1, wherein the body has a curved surface, on which the first film is arranged, and wherein the tab can be brought into a position or is located in a position in which it protrudes at an angle from the range of from 75 to 0 to a surface normal of the curved surface at an area of surface which is adjoined on all sides in respect of the surface by plastic main material.
5. The body according to claim 1, wherein a transition from a back-injection molded part of the first film to a non-back-injection molded part of the film takes place along a line on the surface which is at a distance of at least 8 mm, from an edge contour of the body delimiting the surface with the first film.
6. The body according to claim 1, further comprising a second film or a lacquer package which is likewise back-injection molded with the plastic main material and has a decoration layer which is over the whole surface or partial and which provides at least one item of information in respect of the at least one electrical or electronic component.
7. The body according to claim 1, wherein the functional layer comprises capacitive components which provide a touch panel functionality.
8. The body according to claim 1, further comprising a stiffening element with a thickness from the range of from 140 to 580 m, or an additional contact element with a thickness from the range of from 1 to 15 m, on the tab.
9. The body according to claim 1, wherein the plastic main material is a thermoplastic which comprises polymethyl (meth)acrylate, acrylonitrile-butadiene-styrene, polycarbonate or polyamide.
10. The body according to claim 1, wherein the plastic main material is transparent at least in areas.
11. The body according to claim 1, wherein the functional layer has a plurality of conductor traces which consist of silver, copper, aluminum, chromium or of a metal alloy, and which have a width of between 1 m and 40 m and have a distance from each other of between 10 m and 5 mm and are provided in a layer thickness of from 30 to 60 nm.
12. The body according to claim 1, wherein the functional layer has a plurality of conductor traces which consist of silver, copper, aluminum, chromium or of a metal alloy, and which have a width of 100 m or more.
13. The body according to claim 1, wherein the functional layer comprises metal nanowires made of silver, copper, gold, metal nanoparticles made of silver, copper or gold, carbon nanotubes, carbon nanoparticles, graphene, or organic conductors or polyaniline or provides organic light-emitting diodes, inorganic or organic photovoltaic cells, display elements provided using electroluminescent materials, electrochromic materials or electrophoretic materials, integrated circuits or inorganic or organic memories.
14. The body according to claim 1, further comprising a substrate carrying the functional layer and made of polyethylene terephthalate, polypropylene, polycarbonate, or polyethylene naphthalate, which is provided in a thickness of between 35 and 60 m.
15. The body according to claim 14, wherein the substrate is arranged between the functional layer and the plastic main material.
16. The body according to claim 14, wherein the functional layer is arranged between the substrate and the plastic main material.
17. The body according to claim 1, further comprising an adhesion-promoter layer at least on the part of the first film back-injection molded with plastic.
18. The body according to claim 17, wherein the adhesion-promoter layer consists of two partial layers which are formed from different material.
19. An electrical device, with a housing, in or against which the body according to claim 1 is placed, wherein an electrical or electronic component is arranged in the housing, which component is galvanically coupled, via the tab protruding from the plastic main material, to the electrical or electronic functional layer.
20. A process for producing the body according to claim 1 wherein a first film is inserted into an injection mold, wherein the first film, in a first area, has adhesion properties in respect of a predetermined injection-molding material which are qualitatively better than the corresponding adhesion properties in a second area of the first film, wherein the second area has the form of a tongue protruding from the first area, wherein in the process the predetermined injection-molding material is injected into the injection mold with the first film, with the result that the first film is partially back-injection molded and then the produced body is removed, in which, because of the different adhesion properties, injection-molding material adheres to the first film in the first area, but injection-molding material adheres poorly or does not adhere to the first film in the second area.
21. The process according to claim 20, wherein a film is inserted which comprises an adhesion-promoter layer in the first area.
22. The process according to claim 20, wherein a film is inserted which comprises, in the second area, a layer suppressing the adhesion.
23. A process for producing the body according to claim 1, wherein a first film is inserted into an injection mold, which film has a first area from which a second area protrudes in the form of a tongue, and wherein in the process the second area is clamped between two clamping parts and wherein injection-molding material is injected into the injection mold and thus the first area of the first film is back-injection molded.
24. The process according to claim 23, wherein the injection mold is formed such that injection-molding material is provided on both sides of a transition area from the first area to the second area of the first film.
25. The process according to claim 23, wherein the clamping elements comprise a mold half of the injection mold and either a separate slide, an inclined ejector guided in the mold half of the injection mold or a spring-loaded ejector mounted in the mold half of the injection mold.
26. The process according to claim 23, wherein the clamping elements comprise two clamping jaws that can be separated from each other by a collapsible core.
27. The process according to claim 23, wherein a first film is inserted into an injection mold, wherein the first film, in a first area, has adhesion properties in respect of a predetermined injection-molding material which are qualitatively better than the corresponding adhesion properties in a second area of the first film, wherein the second area has the form of a tongue protruding from the first area, wherein in the process the predetermined injection-molding material is injected into the injection mold with the first film, with the result that the first film is partially back-injection molded and then the produced body is removed, in which, because of the different adhesion properties, injection-molding material adheres to the first film in the first area, but injection-molding material adheres poorly or does not adhere to the first film in the second area.
28. The process according to claim 20, wherein a second film is introduced into the injection mold, which film is likewise back-injection molded.
29. The process according to claim 28, wherein, as the second film, a film is inserted which comprises a carrier layer and a transfer layer and is supplied in a roll-to-roll process, wherein, after the back-injection molding, the transfer layer at least partially adheres to the injection-molding material and is detached from the carrier layer, and wherein the carrier layer is taken away in the roll-to-roll process.
30. A film element for use as part of the body according to claim 1, which has a substrate, and an electrical or electronic functional layer, wherein the film element has, on one surface side, a first area and a second area which differ from each other by their different adhesiveness in respect of a predetermined injection-molding material.
31. The film element according to claim 30, wherein the first area is provided with an adhesion-promoter layer and the second area is not.
32. The film element according to claim 30, wherein an adhesion-promoter layer is applied over the whole surface in the first and in the second area, wherein in the second area on the adhesion-promoter layer a layer suppressing the adhesion is provided.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Preferred embodiments of the invention are described in more detail below with reference to the drawing, in which:
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DETAILED DESCRIPTION OF THE INVENTION
(27) A body shown in
(28) In the present case, the first film is to be such a film which carries an electrical functional layer, for example in the form of capacitive elements for providing a touch panel functionality (with the result that the film 2 is a sensor film). Alternatively or in addition, it is possible for the film 2 to carry light-emitting diode elements, e.g. organic light-emitting diodes (OLEDs). The second area 20b, which in the present case has the form of a tab protruding from the first area 20a, can in particular be a contact area, comprise such a contact area or be only a part of a contact area; it is important that an electrical connection for the elements is provided in the electrical functional layer in the area of this tab, thus in the second area 20b, and the contact reinforcement 24 has the function of making it easier to contact this connection element with a counter contact.
(29) The significance of the protrusion of the tab results from the use of the body 1 in an electronic device 100, which is shown in
(30) The second film 4 can comprise a complete label, which is provided within the framework of an in-mold labeling. However, the second film 4 is preferably only the transfer layer of a transfer film which was detached from a carrier layer during the production process. In this case, the second film 4 can also be called a lacquer package.
(31) The second film 4 comprises a decoration layer or decoration sheet that is over the whole surface or partial and the function of which consists, in particular in addition to just decoration, in providing an item of information in respect of the first film 2 or the components contained therein, and in forming a protective layer against mechanical, physical and/or chemical actions. If the first film is a film with touch panel functionality, the individual touch panels can be displayed through the decoration layer. An operator then need only tap on the symbolically shown touch panels and, because of a capacitive interaction, the capacitive components in the first film 2 detect this tapping in cooperation with the electronic circuit board 6.
(32) Alternatively, the second film 4 can have exclusively the function of a protective layer. This is the case e.g. when a touchscreen is provided by the body 1, for instance for use in a smartphone; it is then desirable if the second film 4 is transparent. A display can then be arranged behind the touch panel sensor and show the item of information for operation. In this case the film need not be completely transparent, but rather can have a transparent area in the display area and a frame at the edge.
(33) There are now different possibilities for how a body in the style of the body 1 from
(34) The figures labeled B in each case display the section along the line A-A from the respectively associated figure labeled A.
(35) First the substrate 21 is provided (
(36) The first film 2 is then cut, wherein essentially the functional element just described is cut out. Here too, the first area 25a and the second area 25b and the corresponding mapping of the area in the substrate 21 lying underneath it are thus obtained.
(37) If such a film 2 is now back-injection molded, the body 1 from
(38) In a second embodiment of the process, the substrate 21 is again also provided first, see
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(40) With reference to
(41) An injection mold shown in
(42) Once the first film 2 has been put in place on the first mold half 9A and the second film 4 has been put in place on the second mold half 9B, the latter optionally with the aid of a sensor (not shown in the figure) that ensures registration accuracy, a closing force F.sub.S is exerted on the two mold halves 9A/B. Negative pressure is still applied to the first film 2, but negative pressure is not applied to the second film 4. The situation shown in
(43) Further subsequently injection-molding material 3 is injected between the first film 2 and the second film 4 via a supply line 91, with the result that both films 2 and 4 are back-injection molded, see
(44) In the alternative process, the film 2 is once again placed on the first injection mold 9A, but at the same time the second film 4, likewise in the already cut-out form, is manually placed in the second mold half 9B (
(45) After the representation of the production process for the body 1, the specification of a few important values now follows.
(46) In the layer structure shown in
(47) The electrical functional layer in the present case is provided in the form of a metal layer which comprises silver, copper, aluminum, chromium or other metals or metal compounds and alloys. The layer thickness of this metal layer is between 10 and 150 nm, typically between 30 and 60 nm. The metal layer is in particular not continuous, but comprises metallic conductor traces in an either particularly regular or precisely irregular pattern, wherein the conductor traces in each case have a width of between 1 m and 40 m, preferably approximately 5 m and 20 m, and have a distance from each other of between 100 m and 5 mm, preferably of between 300 m and 1 mm. Such metallic conductor traces cannot be recognized by the human eye without an aid. The electrical functional layer 25 thereby has a transparent action, although electrical components are provided. For instance in the case of a touch panel functionality, the individual touch panels are formed by electrical conductor traces which are galvanically coupled to each other. The capacitive coupling takes place to other touch panels which are not galvanically coupled to these conductor traces and, for their part, have a plurality of metallic conductor traces which are galvanically coupled to each other one below another.
(48) The invention is not limited to the use of metallic conductor traces for providing a touch panel functionality. Any conductive and semi-conductive elements can contribute to the provision of electrical and electronic components. For example, metals can be provided in the form of nanowires (for instance made of silver, copper or gold) or nanoparticles (for instance made of silver, gold or copper), carbon nanotubes or carbon nanoparticles can be provided, or elements made of graphene can be provided. Moreover, organic conductors made of PEDOT/PSS (poly-3,4-ethylenedioxythiophene/polystyrenesulfonate) or of PAni (polyaniline) can be provided. In particular, active electrical components such as for example organic light-emitting diodes, inorganic or organic photovoltaic cells, other display elements such as for instance made of electroluminescent materials, electrochromic materials or electrophoretic materials can be provided, integrated circuits or inorganic or organic memories can be provided. All of these can equally be used within the framework of the present invention. This applies to all layer structures and sequences described in this application and all named production processes.
(49) The protective layer 27 on the electrical functional layer 25 consists for example of polyacrylate, polyvinyl chloride, polyvinyl acetate, polyurethane, polycarbonate, polyester, an ethylene vinyl acetate copolymer, a hydrocarbon resin, chlorinated polyolefin, polyvinyl alcohol, melamine resin, ketone/formaldehyde resin, polyvinylidene fluoride, epoxy resin, polystyrene, a polymeric cellulose compound, phenolic resin, polyamide, polymeric liquid crystals (LCPs), urea resin and synthetic resin or of a combination of these substances. This includes both thermally cured and radiation-cured lacquer systems.
(50) For better lacquerability and to increase the surface quality, such as e.g. the scratch resistance of the corresponding lacquer layers, various additives can be added to the base lacquer. Wetting additives, leveling additives, anti-foaming agents and fillers such as e.g. nanoscaled silicas are suitable.
(51) The layer thickness of the protective layer 27 is between 1 and 25 m, preferably between 2 and 6 m.
(52) The electrical contact reinforcement 24 consists for example of the material called carbon black or also of conductive silver in the contact area. The layer thickness typically lies between 1 and 15 m.
(53) The adhesion-promoter material 22 (primer) is shown in
(54) TABLE-US-00001 Component Proportion (%) Methyl ethyl ketone 60 Butyl acetate 15 MMA polymer (Tg: 100 C.) 7 MMA/EA copolymer (Tg: 35 C.) 13 Silica (SiO2) 5
(55) Tg here is the glass transition temperature (vitrification temperature) of the respective component.
(56) In an alternative, the adhesion-promoter layer 22 can also be two-layered. In this case, it comprises, in addition to the layer just described, a further layer with a layer thickness of between 1 and 8 m, preferably of between 1 and 4 m in the following composition:
(57) TABLE-US-00002 Component Proportion (%) Methyl ethyl ketone 25 Cyclohexanone 10 Ethyl acetate 32 MMA polymer (Tg: 105 C.) 15 Acrylic acid ester (thickness = 1.102 g/cm.sup.3) 15 Photoinitiator (melting point 45-49 C.) 3
(58) The first-named layer is always located at the boundary surface between the sensor film and the injection-molding material (i.e. it touches the injection-molding material). The additional layer here is arranged such that it is located between the first-named layer and the sensor film.
(59) The layer 26 suppressing the adhesion to the injection-molding material preferably comprises a suitable wax material or the like.
(60) All thermoplastics can be used as injection-molding material 3, these are preferably polymethyl (meth)acrylate, acrylonitrile-butadiene-styrene, polycarbonate or polyamide.
(61) The injection-molding material can be colored or transparent. It can comprise fillers such as glass fibers or carbon fibers, or also be provided without fillers.
(62) The strengthening element preferably consists of plastic, wherein in particular polyethylene terephthalate, polypropylene, polycarbonate, polyethylene naphthalate are suitable, preferably in a thickness from the range of 12-150 m, particularly preferably from the range of 35-60 m.
(63) In addition to the layer structure shown in
(64) In another modification of the embodiment according to
(65) Several electrical functional layers can occur for example when capacitive components are used which are provided, not in one layer, for instance by the above-named metallic conductor traces, but rather in two layers.
(66) A first film 2 is represented in top view in
(67) The design of these elements is known per se and need not be explained in the present case.
(68) Alternatively, a touchscreen (touch panel unit) 204 can be provided, see
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(70) The previous description of the production process for the body 1 was based on the fact that an adhesion-promoter layer 22 and/or a layer 26 suppressing the adhesion is provided.
(71) Still further production processes are to be explained below, in which different tools are used, and in which it is ensured in a mechanical way that in the finished body 1 from
(72) In the embodiments described below, the second film 4 is not described. However, the processes can similarly also be provided when such a second film is to be back-injection molded according to a roll-to-roll process or manual insertion at the same time as the first film. The procedure described above in respect of
(73) Alternatively or in addition to the provision of the second film 4, the first film can also carry a decoration layer.
(74) In a third process for producing the body 1 according to
(75) While
(76) Subsequently, according to
(77) In a fourth process for producing the body 1, the injection mold 9 shown in
(78) At the same time, as indicated by the arrows in
(79) A fifth embodiment of the process for producing the body 1 makes use of the injection molding die 9 shown in
(80) In a sixth embodiment of the process according to the invention becoming clear with reference to
(81) In the injection molding of polymethyl methacrylate, injection pressure magnitudes of 800-1800 bar at a temperature of the injection mold halves 9A and 9B of 50-90 Celsius are usually implemented, the injection unit not shown in the figures has typical temperatures of between 250 and 280 Celsius. The injection can take place for example within one second. The cooling time can be 12 seconds. Overall, a body can be produced in a cycle of 25 seconds.
(82) In all of the previously described embodiments of the body 1, the latter is designed as a substantially flat plate, from which the tab F protrudes.
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(84) In this body, a curved surface is provided, over which the first film 2 at least partially extends. In particular, the first section 20a of the first film 2 is in part guided over a curvature, see the area 20d. Here too, there is a second area 20b, which protrudes in the style of a tongue from the first area 20a, wherein the transition area 20c is precisely the area where the adhesion of the first film 2 to the injection-molding material 3 located underneath it ends. The second area 20b can thus be moved back and forth like a tab. The pivot point of this movement is the transition area 20c, which has distance d from the edge 31 which delimits the surface 30 of the injection-molding material 3 with the first film 2.
(85) In an embodiment according to
(86) The three-dimensional body 1 or the three-dimensional body 1 from
(87) The production processes described above regarding the substantially plate-shaped body 1 can also correspondingly be implemented, with adaptation of the injection molds, in a three-dimensional body in the style of the bodies 1 and 1.
LIST OF REFERENCE NUMBERS
(88) 1, 1, 1 body 2, 2, 2 first film 3, 3, 3 plastic main material 4 second film 5 housing 6 electrical or electronic component 7 light-emitting elements 8 plug-in connection 9 injection mold 9A/B mold half 11a, 11b area at the edge of the housing part 5 20a, 20a, 20a functional area 20b, 20b, 20b contact area 20c, 20c, 20c area of surface 21, 21, 21 carrying substrate 21a first substrate 21b second substrate 22 adhesion-promoter layer 23 strengthening element 24 contact reinforcement 25 functional layer 26 suppressing layer 27 additional layer 30 surface 31, 31 delimiting edge 41 carrier layer 42 transfer layer 43a first roll 43b second roll 91 supply line 93 separate slide 94 stop 95 surface 98a, 98b clamping jaws that can be separated from each other 99 collapsible core 100 electrical device 201 rotary control 202 slide control 203 button 204 touchscreen (touch panel unit) 901 inclined ejector 902 spring-loaded ejector d, d distances F tab F.sub.S closing force F.sub. opening force