Ultra-low water input oil sands recovery process
09738840 · 2017-08-22
Assignee
Inventors
Cpc classification
C10J2300/0946
CHEMISTRY; METALLURGY
C10G2/00
CHEMISTRY; METALLURGY
C10B49/16
CHEMISTRY; METALLURGY
C10J2300/1618
CHEMISTRY; METALLURGY
C10G1/002
CHEMISTRY; METALLURGY
Y02E50/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C10J3/62
CHEMISTRY; METALLURGY
C10L2270/026
CHEMISTRY; METALLURGY
International classification
C10G2/00
CHEMISTRY; METALLURGY
C10J3/62
CHEMISTRY; METALLURGY
Abstract
A method of processing raw oil sands material that includes bitumen. The method includes, in a predistillation process, heating the raw oil sands material to between approximately 535 C. and at least approximately 600 C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material that includes carbon-heavy hydrocarbons and sand. The coked oil sands material is heated to approximately 900 C., to produce a dry barren hot oil sands material and syngas including hydrogen and carbon monoxide gases. Heat energy is transferred from at least a portion of the barren hot oil sands material to the raw oil sands material.
Claims
1. A method of processing raw oil sands material comprising bitumen, the method comprising: (a) subjecting an oil sands material comprising the raw oil sands material to a predistillation process comprising: (i) heating the oil sands material to between approximately 350 C. and approximately 400 C., to produce atmospheric gas oil from the bitumen, and intermediate dried oil sands material; (ii) heating the intermediate dried oil sands material to between approximately 535 C. and at least approximately 600 C., to produce vacuum gas oil and coked oil sands material comprising carbon-heavy hydrocarbons and sand; (b) heating the coked oil sands material to approximately 900 C., to produce a dry barren hot oil sands material and syngas comprising hydrogen and carbon monoxide gases; and (c) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the oil sands material and the intermediate dried oil sands material.
2. A method according to claim 1 additionally comprising: (d) refining the atmospheric gas oil to provide at least one of liquefied petroleum gas and gasoline; and (e) refining the vacuum gas oil to provide at least one of jet fuel, diesel fuel, and gas oil.
3. A method according to claim 1 in which the syngas is further subjected to at least one gas-to-liquid process to provide at least one of gasoline, diesel fuel, naphtha, and petrochemical feedstock.
4. A method of processing raw oil sands material comprising free water and bitumen produced from a mine, comprising: (a) preheating a preheat oil sands material comprising the raw oil sands material to between approximately 100 C. and approximately 150 C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material; (b) in a first predistillation step, heating the dried oil sands material to between approximately 350 C. and approximately 400 C. to partially vaporize the bitumen, to provide atmospheric gas oil from the bitumen, and intermediate dried oil sands material; (c) in a second predistillation step, heating the intermediate dried oil sands material to between approximately 535 C. and at least approximately 600 C. to further at least partially vaporize the bitumen, to provide vacuum gas oil, and coked oil sands material comprising carbon-heavy hydrocarbons and sand; (d) in a gasifier, heating the coked oil sands material to approximately 900 C. for gasification thereof, to provide syngas comprising hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein; and (e) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material and the intermediate dried oil sands material.
5. A method according to claim 4 in which the steam is added to the coked oil sands material during the gasification thereof, to provide at least a portion of the hydrogen gas in the syngas.
6. A method according to claim 4 in which at least a part of the sand heat energy in the barren oil sands material is transferred to the dried oil sands material in the first predistillation step.
7. A method according to claim 4 in which at least a part of the sand heat energy in the barren oil sands material is transferred to the intermediate dried oil sands material in the second predistillation step.
8. A method according to claim 4 in which, prior to the gasification of the coked oil sands material, at least a portion of the syngas heat energy from previously produced syngas is transferred to the coked oil sands material, to heat the coked oil sands material to between approximately 650 C. and approximately 750 C.
9. A method according to claim 4 additionally comprising heating fresh water to between approximately 450 C. and approximately 500 C. to generate fresh water steam, and injecting the fresh water steam into the gasifier.
10. A method according to claim 4 additionally comprising heating air to between approximately 650 C. and approximately 750 C. to generate hot air, and injecting the hot air into the gasifier.
11. A method according to claim 4 additionally comprising: mixing the syngas with at least one additional gas to produce a balanced syngas comprising preselected gases in predetermined proportions.
12. A method according to claim 11 in which said at least one additional gas comprises a natural gas-derived syngas resulting from combustion of natural gas.
13. A method according to claim 11 in which the balanced syngas is subjected to a gas-to-liquids process to provide at least one of gasoline, diesel fuel, naphtha, and petrochemical feedstock.
14. A method according to claim 4 in which the raw oil sands are comminuted, prior to preheating, and screened such that only particles of the raw oil sands material below a predetermined particle size are included in the oil sand material.
15. A method according to claim 4 additionally comprising, before step (d), comminuting the coked oil sands material such that only the coked oil sands material below a preselected particle size is subjected to the gasification.
16. A method according to claim 4 in which at least a part of the barren hot oil sands material is transported to the mine for backfilling therein.
17. A method of processing raw oil sands material comprising free water and bitumen produced from a mine, comprising: (a) preheating a preheat oil sands material comprising the raw oil sands material to between approximately 100 C. and approximately 150 C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material; (b) in a predistillation process, heating the dried oil sands material to between approximately 535 C. and at least approximately 600 C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material comprising carbon-heavy hydrocarbons and sand; (c) in a gasifier, heating the coked oil sands material to approximately 900 C. for gasification thereof, to provide syngas comprising hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein; and (d) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material.
18. A method according to claim 17 in which the steam is added to the coked oil sands material during the gasification thereof, to provide at least a portion of the hydrogen gas in the syngas.
19. A method according to claim 17 in which at least a part of the sand heat energy in the barren oil sands material is transferred to the dried oil sands material in the predistillation process.
20. A method according to claim 17 in which, prior to the gasification of the coked oil sands material, at least a portion of the syngas heat energy from previously produced syngas is transferred to the coked oil sands material, to heat the coked oil sands material to between approximately 650 C. and approximately 750 C.
21. A method according to claim 17 additionally comprising, before step (c), comminuting the coked oil sands material such that only the coked oil sands material below a preselected particle size is subjected to the gasification.
22. A method according to claim 17 in which at least a part of the barren hot oil sands material is transported to the mine for backfilling therein.
23. A method of processing raw oil sands material comprising bitumen, the method comprising: (a) in a predistillation process, heating the raw oil sands material to between approximately 535 C. and at least approximately 600 C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material comprising carbon-heavy hydrocarbons and sand; (b) heating the coked oil sands material to approximately 900 C., to produce a dry barren hot oil sands material and syngas comprising hydrogen and carbon monoxide gases; and (c) transferring heat energy from at least a portion of the barren hot oil sands material to the raw oil sands material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention will be better understood with reference to the attached drawings, in which:
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DETAILED DESCRIPTION
(13) In the attached drawings, like reference numerals designate corresponding elements throughout. Reference is first made to
(14) In one embodiment, the atmospheric gas oil 156 preferably is refined (
(15) Because of the temperature gradient of the predistillation process 152, the atmospheric gas oil 156 and the vacuum gas oil 162 are produced sequentially in the process. The atmospheric gas oil 156 and the vacuum gas oil 162 therefore may be captured substantially separately, and subsequently processed (i.e., refined) separately, in steps 172 and 174 respectively.
(16) Alternatively, it is possible to subject the oil sands material 151 to a predistillation process in which the atmospheric gas oil and the vacuum gas oil are not captured separately. For example, the oil sands material 151 may be heated to between approximately 535 C. and at least approximately 600 C., producing a mixture of the volatiles (i.e., a mixture of the atmospheric gas oil and the vacuum gas oil). In these circumstances, the atmospheric gas oil would be produced when the oil sands material is heated to between approximately 350 C. and approximately 400 C., and the vacuum gas oil would be produced when the oil sands material is further heated to between approximately 535 C. and at least approximately 600 C. In this alternative arrangement, the atmospheric gas oil and the vacuum gas oil would then be subjected to further processing together, to produce various petroleum products. Although this alternative may impose some limitations or additional requirements in the further processing of the atmospheric gas oil and the vacuum gas oil, it may be acceptable in some circumstances.
(17) In one embodiment, the syngas 170 preferably is further subjected to one or more gas-to-liquid processes (step 115) to provide one or more of gasoline, diesel fuel, naphtha, and petrochemical feedstock.
(18) In summary, in the method of the invention, volatiles (in the form of the atmospheric gas oil and the vacuum gas oil) are removed from oil sands material including bitumen by heating the oil sands material, in a predistillation process. The volatiles may be further processed to produce petroleum products. Coked oil sands material is also produced from the predistillation process. The coked oil sands material is subjected to a gasification process, in which molecule-changing chemical reactions provide a syngas that also may be further processed to produce petroleum products. Advantageously, the invention does not require the large inputs of water that are required in the prior art. Once the methods of the invention are functioning in a steady state, the energy requirements may be satisfied to a large extent by recovering energy from different products and by-products of the methods.
(19) It will be understood that the oil sands material 151 preferably includes raw oil sands material 178, produced from a mine 180 (
(20) Preferably, and as illustrated in
(21) Those skilled in the art would also appreciate that the sand component of the oil sands may include various rock and soil materials, e.g., both sand (i.e., relatively small rock and/or mineral particles) and clay. As is also well known in the art, in addition to the bitumen thereof, the oil sands material typically also includes free water. The free water content varies, depending on a number of factors. For example, the free water content may be approximately 4 percent by weight.
(22) An embodiment of a system 194 of the invention is schematically illustrated in
(23) As will be described, in embodiments of the invention, heat energy is at least partially recoverable from certain products of the methods of the invention, and utilized elsewhere in the invention. Also, in certain circumstances (described below), the introduction of additional materials or substances retaining heat energy (e.g., hot air, or steam) may be advantageous. The recovery of part of the heat energy from certain products of the invention, and the utilization of heat energy from steam or hot air introduced into the system, preferably is effected via an energy recovery system (ERS).
(24) In an alternative embodiment of the system 294 (
(25) For instance, in one embodiment, the appropriately sized raw oil sands material 178 preferably is mixed in the mixer/preheater 286 (
(26) In an alternative embodiment schematically illustrated in
(27) It is also preferred that the method 250 additionally includes the step of, in the gasifier 184 (
(28) In one embodiment, the steam 290 preferably is added to the coked oil sands 164 during the gasification thereof, to provide at least a portion of the hydrogen gas in the syngas 170 (
(29) In another embodiment, and as noted above, the oil sands material 151 preferably also includes at least a portion of the barren hot oil sands material 168, and the preheating is at least partially effected by transfer of a portion of the sand heat energy to the raw oil sands material 178 (
(30) In another alternative embodiment, at least a portion of the heat energy in the barren hot oil sands material 168 preferably is transferred to the dried oil sands material 288 (
(31) It will be understood that, in connection with the method 150 of the invention, the barren hot oil sands material 168 may be recycled to the first predistillation step 154, to recover at least a portion of the heat energy retained in the barren hot oil sands material 168. In
(32) It is also preferred that at least a portion of the heat energy in the barren hot oil sands material 168 is transferred to the intermediate dried oil sands material 158 (
(33) It will be understood that a portion of the heat energy in the barren hot oil sands material 168 may also be utilized in the second predistillation step 160 of the method 150. In
(34) It is also preferred that, prior to the gasification of the coked oil sands material 164, at least a portion of the syngas heat energy from previously produced syngas 170 is transferred to the coked oil sands material 164, to heat the coked oil sands material 164 to between approximately 650 C. and approximately 750 C. (
(35) It will be understood that a portion of the heat energy in the barren hot oil sands material 168 may also be utilized to heat the coked oil sands material 164 in the method 150, illustrated in
(36) Other means for adding heat energy at selected points in the method of the invention may be advantageous, depending on the circumstances. For instance, in one embodiment, the method of the invention preferably also includes heating fresh water (
(37) In another embodiment of the method of the invention, air preferably is heated to between approximately 650 C. and approximately 750 C. (
(38) Those skilled in the art would appreciate that the composition of the syngas 170 as generated by gasification may not be consistent with a desired composition (i.e., desired for purposes of further processing). The composition of the syngas 170 may be altered in a syngas balancer 109 (
(39) However, it has been determined that, in one embodiment, the additional gas(es) 111 preferably includes a natural gas-derived syngas resulting from combustion of natural gas.
(40) As an example, it may be intended to direct the syngas 170 to a gas-to-liquids facility 113 (
(41) Those skilled in the art would appreciate that the syngas 170 and/or the balanced syngas 170 may be processed in any suitable way, in any suitable facility. The gas-to-liquids facility is one example of a facility in which the syngas and/or balanced syngas may be further processed.
(42) It may be necessary or advisable to utilize one or more secondary crushers 117, to provide the coked oil sands material 164 in a form suitable for gasification. As illustrated in
(43) It will also be understood that, in one embodiment, the barren hot oil sands material 168 preferably is transported to the mine 180 for backfilling therein. Those skilled in the art would appreciate that the barren hot oil sands material 168 would have the advantage (i.e., over backfilling using the prior art materials) that it is accompanied by virtually no water.
(44) The method 250 of the invention was modeled, and the results are provided in Tables 1 and 2 below. The results are also schematically illustrated in
(45) TABLE-US-00001 TABLE 1 Material and Energy Balance for an embodiment of the Method of the Invention Including Temperature Ranges. Temperature Pressure Range, No. Streams T, C Range, C. M (kg/h) kPa 1 Bitumen 25 25 5,000 100 2 Sand 25 25 45,000 100 3 Hot Sand 900 800-900 5,032 100 4 Air 25 25 100 5 Water Vapor 100 100-150 2,000 80-100 6 Bitumen-H.sub.2O 100 100-150 5,000 100 7 Sand 100 100-150 48,032 100 8 Hot Sand 900 800-900 37,022 100 9 Hot Sand 100 100-150 37,022 100 10 AGO 350 350-400 850 80-100 11 VGO 535 535-600 1,550 80-100 12 Resid 700 700-750 2,600 100 13 Sand 700 700-750 48,032 100 14 H.sub.2O (Steam) 500 450-500 2,000 100-150 15 H.sub.2O (Steam) 500 450-500 820 100-150 16 Air 700 700-750 6,507 100-150 17 Syngas 900 800-900 11,927 100 18 Hot Sand 900 800-900 48,032 100 19 Hot Sand 900 800-900 5,978 100 20 Water Pond 100 70-100 80-100
(46) TABLE-US-00002 TABLE 2 Energy Stream and Exit Temperature Ranges of Inlet and Outlet Streams of Heat Recovery. Heat Energy Stream, No. Exchanger MJ/h Exit Temperature Range, C. 1 E-101 970-1,846 57-87.3 2 E-102 485-521 71.2-104.8 3 E-103 3,032-3,318 173-214.4 4 E-104 85-87 Air: 150-186 Water: 90-100 5 E-105 260-275 Air: 153-188.9 Water: 25-100 6 E-106 327-515 Air: 162-197.4 Steam: 160-204 7 E-107 6,375 Water Phase Change@ 100 C. Syngas: 232-231.9 8 E-108 3,885-3,765 Air: 700-747.7 Syngas: 900-176 9 E-109 9,510 10 E-110 1,940 Steam: 500-540 Syngas: 160-197.4
(47) The method 150 of the invention is also schematically illustrated in
(48) Among the benefits and advantages of the processes of the invention are the following. (a) Overall water use is significantly reduced, resulting in the elimination of large tailings ponds. (b) Carbon dioxide emissions to the atmosphere are significantly reduced. (c) Maintenance costs incurred due to abrasion by the sand are reduced, because most of the processing is done in the vicinity of the mine. (d) With sand recovery from processing occurring relatively close to the mine, the sand can be transported to the mine as landfill, facilitating reclamation at the mine. (e) High-value products are not needed for use as diluents, for dilbit transport. (f) Energy consumption during processing is reduced. (g) The long-distance transportation of dilbit is eliminated.
(49) It will be appreciated by those skilled in the art that the invention can take many forms, and that such forms are within the scope of the invention as claimed. The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole.