Membrane Filter Element With Multiple Fiber Types

Abstract

A membrane filter element includes at least two cylindrical-shaped, fiber bundles, one of the fiber bundles containing first fibers fabricated to provide a selected first gas selectivity, a selected first gas permeability, or a selected first gas selectivity and permeability performance and arranged so a first gas permeate exits the membrane element; another of the fiber bundles containing second fibers fabricated to provide a selected second, different gas selectivity, a selected second different gas permeability, or a selected second gas selectivity and permeability performance and arranged so a second different gas permeate exits the membrane element. The different performance characteristics can reduce the number of membrane elements required for gas separation and to improve gas separation performance due to changing gas composition as the gas travels through the membrane element.

Claims

1. A membrane element comprising: at least two concentric, cylindrical-shaped zones spanning a total height of the membrane element and surrounding a central longitudinal axis of the membrane element; one of the zones defined by first fibers fabricated to provide a selected first gas selectivity and arranged so a first gas permeate exits an end of the membrane element; another of the zones defined by second fibers fabricated to provide a selected second, different gas selectivity so a second different gas permeate exits an end of the membrane element.

2. A membrane element according to claim 1 wherein the first fibers are fabricated to provide a selected first gas permeability and the second fibers are fabricated to provide a second, different gas permeability.

3. A membrane element according to claim 2 wherein the first and second fibers are fabricated to provide, relative to one another, a different target CO.sub.2 permeability.

4. A membrane element according to claim 2 wherein the first and second fibers are fabricated to provide, relative to one another, a different target H.sub.2S permeability.

5. A membrane element according to claim 1 relative to one another, a different target CO.sub.2 selectivity.

6. A membrane element according to claim 1 wherein the first and second fibers are fabricated to provide, relative to one another, a different target H.sub.2S selectivity.

7. A membrane element according to claim 1 wherein the first and second fibers are fabricated to provide, relative to one another, a different target water dew pointing performance.

8. A membrane element according to claim 1 wherein the first and second fibers are fabricated to provide, relative to one another, a different target hydrocarbon dew pointing performance.

9. A membrane element according to claim 1 wherein depth of the zones differs from one another.

10. A membrane element according to claim 1 wherein at least one of zones is an innermost zone or an outermost zone of the membrane fiber element.

11. A membrane element according to claim 1 wherein the two zones are located adjacent one another.

12. A membrane element according to claim 1 further comprising the first and second fibers including hollow fibers.

13. A membrane element according to claim 1 wherein the first and the second different gas permeates exit a same end of the membrane element.

14. A membrane element according to claim 1 wherein the first and second different gas permeates mix with one another after exiting the same end.

15. A method of treating a gas, the method comprising: flowing the gas through a membrane element containing at least two concentric, cylindrical-shaped zones spanning a total height of the membrane element and extending around the membrane element; wherein one of the zones is defined by first fibers fabricated to provide a selected first gas selectivity and arranged so a first gas permeate exits an end of the membrane element; and wherein another of the zones is defined by second fibers fabricated to provide a selected second, different gas selectivity and arranged so a second different gas permeate exits an end of the membrane element.

16. A method according to claim 15 wherein the first and second fibers are fabricated to provide a selected first gas permeability and the second fibers are fabricated to provide a second, different gas permeability.

17. A method according to claim 15 wherein the first and second fibers are fabricated to provide, relative to one another, a different target water dew pointing performance.

18. A method according to claim 15 wherein the first and second fibers are fabricated to provide, relative to one another, a different target hydrocarbon dew pointing performance.

19. A method according to claim 15 wherein the first and second fibers include hollow fibers.

20. A method according to claim 15 further comprising mixing the first and second different gas permeates with one another after exiting a respective end of the membrane element.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0015] So that the manner in which the above recited features can be understood in detail, a more particular description may be had by reference to embodiments, some of which are illustrated in the appended drawings, wherein like reference numerals denote like elements. It is to be noted, however, that the appended drawings illustrate various embodiments and are therefore not to be considered limiting of its scope, and may admit to other equally effective embodiments.

[0016] FIG. 1 compares membrane filter element sizesranging in diameter from about 5 to 30 inches. For the purpose of this disclosure, the two smaller diameter membrane filter elements 10 are examples of prior art single fiber type filter elements. In many applications, several of these single fiber elements must be deployed in series or stages to treat an incoming natural gas stream. In some embodiments, a membrane element with a diameter greater than 12 inches is used for producing the multiple fiber membrane filter element of this disclosure. However, because of the greater bundle depth recently provided by large membrane elements, multiple fiber types may be used effectively in a single filter element, eliminating the need for several single fiber filter elements and multiple processing stages. Therefore, for the purpose of this disclosure, the two larger diameter membrane filter elements 20 are non-limiting examples of a multiple fiber type filter element.

[0017] FIG. 2 is a graphical depiction of the hollow fibers that make up the multiple fiber membrane filter element 20 of FIG. 1. The hollow fibers are arranged about a perforated non-permeate pipe. Optionally, the fibers may be arranged in bundles and then wrapped about the pipe.

[0018] FIG. 3 is a graphical depiction of the several hollow fibers of one of the bundles of FIG. 2. The fibers are isolated to indicate the size of the individual fibers.

[0019] FIG. 4 is an end view of one of the hollow fibers of FIG. 3 as it might appear under magnification. The multiple fiber membrane filter element includes many hundreds of thousands of these hollow fibers.

[0020] FIG. 5 is an end view of the multiple fiber membrane filter element 20 of FIG. 1 as it experiences an outside-in gas flow. The fiber types are generally arranged in two circumferential zones. Bundles located in the first circumferential zone include hollow fibers of one type and bundles located in the second zone hollow fibers of another type. Because the hollow fiber types are intentionally fabricated to differ from one another and provide a different target selectivity and permeability, the first zone exhibits different performance than does the second zone. Alternatively, gas flow could occur inside out, flowing first through the second zone and then through the first zone.

[0021] FIG. 6 is a schematic illustrating a prior art process that makes use of single fiber filter elements arranged in series, or two different single fiber type membranes with one fiber type used in Stage 1 and the second fiber type used in Stage 2.

[0022] FIG. 7 is a schematic illustrating a process that makes use of a filter element embodiment. The multiple fiber type filter element allows for single-stage processing.

DETAILED DESCRIPTION

[0023] In the following description, numerous details are set forth to provide an understanding of some embodiments of the present disclosure. However, it will be understood by those of ordinary skill in the art that the system and/or methodology may be practiced without these details and that numerous variations or modifications from the described embodiments may be possible.

[0024] In the specification and appended claims: the terms connect, connection, connected, in connection with, and connecting are used to mean in direct connection with or in connection with via one or more elements; and the term set is used to mean one element or more than one element. Further, the terms couple, coupling, coupled, coupled together, and coupled with are used to mean directly coupled together or coupled together via one or more elements. As used herein, the terms up and down, upper and lower, upwardly and downwardly, upstream and downstream; above and below; and other like terms indicating relative positions above or below a given point or element are used in this description to more clearly describe some embodiments of the disclosure

[0025] Embodiments of a membrane element that has multiple hollow fiber types will now be described by making reference to the drawings and the following elements illustrated in the drawings:

TABLE-US-00001 10 Single fiber membrane element 20 Multiple fiber membrane element 21 Hollow fiber 23 Wall of 21 25 Bore of 21 27 Fiber bundle 29 Bundle depth 31 First circumferential zone of fibers 33 Second circumferential zone of fibers 35 Perforated non-permeate pipe 37 Central longitudinal axis of 20 & 35 41 Gas inlet or feed side of 20 43 Outlet or non-permeate side of 20 45 Membrane division

[0026] Referring now to FIG. 1, two prior art, single fiber membrane elements 10 are shown. Because membrane elements that have a diameter greater than 12 inches are useful for producing a multiple fiber membrane element, the larger diameter membranes of FIG. 1 are labeled as membrane 20. Membrane element 20 takes advantage of manufacturing improvements that have enabled the production of much larger diameter semi-permeable membrane filter elements for CO.sub.2/natural gas separation. Single fiber membrane elements 10 are available in sizes similar to that of membrane element 20, but membrane element 20 as disclosed herein is not a prior art membrane element. The cylindrical-shaped membrane 10, 20 is typically housed within a pressure vessel connected by way of piping to an inlet gas stream (not shown) and may be configured for an outside in flow or inside out flow. Regardless of the direction of flow, as the inlet gas stream travels through the membrane 10, 20, acid gas and other undesirable components are removed to the permeate.

[0027] For the purpose of comparison with multiple fiber membrane element 20, single fiber membrane element 10 may be generally less than 15 inches in diameter and from about 24 inches to about 48 inches in height. Because membrane 10 does not have sufficient depth to minimize bypassand because it employs a single fiber type that cannot account for the changes in gas volume and composition as the gas stream travels through the membrane 10two or more membranes 10 must be arranged in series (see FIG. 6) with separation being performed in at least two stages. Selection of the fiber type for use in membrane 10 at each stage typically involves a trade-off between permeability (known as flow capacity or flux) and selectivity (called permeation rate or alpha). By way of example, as permeability increases in a polymeric membrane fiber, selectivity decreases (and vice versa).

[0028] Because of the trade-off between permeability and selectivity, some membrane fibers are better suited to higher concentrations of permeable components, while others are better suited to higher grade separations at lower concentrations of permeable components. Membrane fibers that exhibit better hydrocarbon separation attributes (higher selectivity) and lower permeability may be selected for use in membrane 10 at the first stage of processing. Conditions at this stage are typically characterized by higher gas flow rates and higher CO.sub.2 concentrations. For hydrocarbon/CO.sub.2 separation applications, the majority of CO.sub.2 is permeated in this first stage, and the majority of hydrocarbon losses occur in this stage. Although the higher alpha fibers selected for use have a slightly lower flux, the fibers still operate efficiently due to the high CO.sub.2 concentrations. At the second stage, however, membrane fibers that exhibit higher permeability and lower selectivity may be used. Conditions at this stage are typically characterized by lower gas flow rates and lower CO.sub.2 concentrations. Therefore, element 10 can exhibit higher permeability at this stage in order to minimize the amount of membrane area and associated equipment required.

[0029] Turning now to FIGS. 5 & 7, a multiple fiber membrane element 20 replaces multiple single fiber membranes 10 and multiple stages of separation processing. The improved processing performance provided by membrane 20 is due in part to the use of different types of hollow fibers 21 in different zones 31, 33 of the membrane 20 and the increased surface area and bundle depth 29 provided by membrane 20. For example, in one embodiment membrane 20 is about 30 inches in diameter and 72 inches in height. Compared to a 12-inch diameter single fiber membrane 10, multiple fiber membrane filter element 20 generally has about 10 times the surface area and about 3 times the bundle depth 29 as that of membrane 10.

[0030] Referring now to FIGS. 2 to 5, membrane 20 includes hundreds of thousands of two or more different types of hollow fibers 21. The fibers 21 are wrapped about a perforated non-permeate tube or pipe 35 that shares a central longitudinal axis 37 with membrane 20. Alternatively, the fibers 21 may be arranged in bundles 27 and wrapped about pipe 35. Fibers 21 are arranged so permeate that permeates the wall 23 and enters the bore 25 of the hollow fibers 21 may exit through the top and bottom of membrane 20. Membrane 20 is fabricated as a divided membrane element with two distinct circumferential zones 31, 33, with line 45 indicating the division between the two zones. Fibers 21 located in a first circumferential zone 31 of the membrane 20 have a different type (or types) of hollow fibers 21 than fibers 21B located in a second circumferential zone 33. The performance characteristics of each zone 31, 33 differ because the hollow fibers 21 or combination of hollow fibers 21 fabricated and selected for use in zone 31 have been fabricated to achieve, for a composition and volume of the natural gas stream flowing through the zone 31, a different selectivity and permeability than the hollow fibers 21B or combination of hollow fibers 21B in zone 22 for the composition and volume of the natural gas stream flowing through the zone 33.

[0031] The hollow fibers 21 in each zone 31, 33 are selected in order to maximize the overall capacity and separation performance of membrane 20 as a gas stream passes through it, thereby reducing or eliminating the need for multiple processing or separation stages (see FIG. 7). For example, a higher separation, lower permeability hollow fiber 21 may be located nearest to the inlet or feed side 41 of the membrane 20, in circumferential zone 31, where maximum permeation flow volumes occur, in order to reduce the hydrocarbon losses to the permeate. A higher permeability but lower separation hollow fiber 21 may be located nearest to the outlet or non-permeate side 43 of the membrane 20, in circumferential zone 33, to improve capacity where CO.sub.2 is lower. Alternatively, a first hollow fiber 21 having a higher permeation of one component (e.g. H.sub.2S) may be bundled with a second hollow fiber 21 having higher permeation of another component (e.g. CO.sub.2 or hydrocarbon dewpointing) or vice versa.

[0032] Configuring membrane 20 with multiple types of hollow fibers 21 can optimize performance by taking advantage of the performance characteristics of the different types of hollow fibers 21 included in each zone 31, 33 relative to the gas composition and more than two zones 31, 33 may be deployed. For example: [0033] 1. Combining larger bore hollow fibers 21 on the high CO.sub.2 zone nearest the feed gas side 41 of element 20 and smaller bore fibers 21 on the low CO.sub.2 zone nearest the non-permeate side 43 of element 20 to add more relative surface area in low CO.sub.2 conditions. [0034] 2. Combining hollow fibers 21 that have greater CO.sub.2 partial pressure resistance in the zone nearest the feed gas side 41 with hollow fibers 21 having higher flux in the zone nearest the non-permeate side 43. [0035] 3. Combining hollow fibers 21 that exhibit different separations, such as combining a hollow fiber 21 for dehydration with a fiber 21 for CO.sub.2/hydrocarbon separation or combining a fiber 21 for CO.sub.2 removal with a fiber 21 for H.sub.2S removal or for hydrocarbon dewpointing.

[0036] Membrane 20 results in fewer stages of membrane elements because it performs a much greater CO.sub.2 removal duty than its single fiber predecessor membrane 10. A greater amount of CO.sub.2 can be removed in membrane 20 because there is more permeation of CO.sub.2, which results in a greater differential between inlet CO.sub.2 and exiting non-permeate CO.sub.2 inside of membrane 20. Because of this, the gas passing through membrane 20 now has a higher percentage of CO.sub.2 on the feed side 41 of membrane 20 than it does in the middle or on the exiting non-permeate side 43.

[0037] By way of example, consider an inlet gas stream entering membrane 20 that contains about 50% inlet CO.sub.2. As the gas passes through membrane 20 and travels toward the inner core or central longitudinal axis 37, CO.sub.2 is permeated. As a result, the hollow fibers 21 located closer to the central longitudinal axis 35 of element 20 (that is, the non-permeate side 43) are presented with gas having successively lower and lower amounts of CO.sub.2. For example, depending on the type of hollow fibers 21 selected for use, non-permeate gas may exit the membrane 20 with about 10% CO.sub.2. In this example, although the removal of CO.sub.2 through the membrane 20 is a continuous process, for simplification purposes zone 31 is a labeled a high-CO.sub.2 zone where CO.sub.2 is removed from about 50% to 25%. The hollow fibers 21 located farther away from the feed side 41 and toward the non-permeate side 43 reside in zone 33 or the low-CO.sub.2 zone, where CO.sub.2 is removed from about 25% to 10%. Again, these values are simply illustrative ones.

[0038] A membrane 20 can provide a number of benefits. Because of the increased fiber bundle depth 29, the larger membrane 20 may replace two stages of smaller conventional membranes 10. Equivalent scale-up is not possible with spiral wound membrane elements due to the restriction in gas flow paths between layers of the membrane. CO.sub.2 is selectively separated within the membrane element 20 as the flowing mixed CO.sub.2/hydrocarbon gas comes in contact with the fibers 21. CO.sub.2 passes through the wall 23 of each fiber 21 into the bore 25 of each fiber 21 and exits through the ends of the membrane element 20 as permeate gas. The inlet gas is reduced in CO.sub.2 as the gas travels through membrane 20, resulting in the exiting non-permeate gas having a lower CO.sub.2 concentration than the inlet gas.

[0039] As gas passes through membrane element 20, each successive array of fibers 21 actually processes gas with progressively lower and lower CO.sub.2 content. The actual CO.sub.2 content that each individual hollow fiber 21 is exposed to depends on the position of the fiber 21 in the membrane 20 relative to the feed gas side 41, with fibers 21 located near the inlet operating on higher CO.sub.2 gas than fibers 21 that are located downstream, nearer to the gas outlet or non-permeate side 45. The larger bundle depth 29 thus enables the use of multiple fiber types in a single membrane element 20 and provides separation performance similar to that which previously required gas to pass through two or more membranes 10 in series. Furthermore, within membrane 20 there is a greater change in gas volume and composition due to permeation than with previous smaller membranes 10. Therefore, membrane 20 is not only processing more gas but is also operating with a greater differential in gas composition between the feed gas side 41 and the non-permeate side 43 enabling the use of multiple fiber types. With current single fiber membranes 10, the resulting membrane performance over the range of gas conditions present in the membrane 10 may be sub-optimal.

[0040] While a membrane filter element having multiple fiber types and a method for its use has been described with a certain degree of particularity, many changes may be made in the details of construction and the arrangement of components and steps without departing from the spirit and scope of this disclosure. A filter element and method according to this disclosure, therefore, is limited only by the scope of the attached claims, including the full range of equivalency to which each element thereof is entitled.