Transparent rollable folded polysiloxane film and preparation and self-repairing method thereof

Abstract

This invention provides a scrollable and foldable transparent polysiloxane film and its preparation and self-healing method. 2-Hydroxyethyl disulfide, diisocyanate and alkane chloride were mixed and reacted to get disulfide-containing diisocyanate. α,ω-Aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride were mixed and reacted get linear chain-extended polydimethylsiloxane. Linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride were mixed and poured into a mould. After drying, the scrollable and foldable transparent polysiloxane film was obtained. The polysiloxane film described in this invention are constructed by dynamic physical crosslinking induced by hydrogen bond and permanent chemical crosslinking generated by hyperbranched polysiloxane. Hence, the polysiloxane film achieves both high stiffness and toughness. The good self-healing behavior of the polysiloxane films is originated from the temperature controlled dissociation of hydrogen bonds and exchange reaction rate of disulfide bonds.

Claims

1. A method for preparing a scrollable and foldable transparent polysiloxane film, comprising: (1) γ-aminopropyltriethoxysilane, water and alcohol solvent are mixed and reacted to afford multi-amino terminated hyperbranched polysiloxane; (2) 2-hydroxyethyl disulfide, diisocyanate and an alkane chloride are mixed and reacted to afford disulfide-containing diisocyanate; (3) α,ω-aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride are mixed and reacted to afford linear chain-extended polydimethylsiloxane; and (4) mixing the linear chain-extended polydimethylsiloxane, the multi-amino terminated hyperbranched polysiloxane, the disulfide-containing diisocyanate and an alkane chloride, followed by pouring the mixture into a mold, followed by drying, to afford the scrollable and foldable transparent polysiloxane film.

2. The method according to claim 1, wherein, the alcohol solvent is selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, and any combination thereof; the alkane chloride is selected from the group consisting of dichloromethane, trichloromethane, 1,2-dichloroethane, and any combination thereof; the diisocyanate is selected from the group consisting of diisocyanate compounds and any derivatives prepared from the diisocyanate compounds; the diisocyanate compounds are selected from the group consisting of 2,4-tolylene diisocyanate (TDI), isophorone diisocyanate (IPDI), 4,4′-diphenylmethane diisocyanate (MDI), 4,4′-dicyclohexylmethane diisocyanate (HMDI), hexamethylene diisocyanate (HDI), lysine diisocyanate (LDI), xylylene diisocyanate (XDI), 1,5-naphthalene diisocyanate (NDI), 1,3-bis(1-isocyanato-1-methylethyl)benzene (TMXDI), 4-methylcyclohexyl diisocyanate (HTDI), and any combination thereof.

3. The method according to claim 1, wherein, the mass ratio of γ-aminopropyltriethoxysilane, water and alcohol solvent in Step (1) is 100:(10 to 15):(100 to 200); the mass ratio of 2-hydroxyethyl disulfide, diisocyanate and alkane chloride in Step (2) is (75 to 80):(160 to 270):(1000 to 1500); the mass ratio of α,ω-aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride in Step (3) is 100:(10 to 25):(1000 to 1500); and the mass ratio of linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride in Step (4) is 50:(3 to 6):(10 to 15):(100 to 150).

4. The method according to claim 1, wherein, in Step (1), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 4 to 6 h; in Step (2), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 2 to 4 h; in Step (3), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 4 to 6 h; in Step (4), the mixture temperature is room temperature.

5. The method according to claim 1, wherein, in Step (1), multi-amino terminated hyperbranched polysiloxane is obtained by removing solvents under reduced pressure after the reaction is complete; in Step (2), disulfide-containing diisocyanate is obtained by removing solvents under reduced pressure after the reaction is complete; in Step (3), linear chain-extended polydimethylsiloxane is obtained by removing solvents under reduced pressure after the reaction is complete.

6. The scrollable and foldable transparent polysiloxane film prepared by the method described in claim 1.

7. A method of self-healing a damaged scrollable and foldable transparent polysiloxane film, comprising the following steps: fractured surfaces of the damaged scrollable and foldable transparent polysiloxane film are brought into contact and maintained at 100 to 140° C. for 0.5 to 2 h to undergo a self-healing process, wherein the scrollable and foldable transparent polysiloxane film is prepared by a method comprising the following steps: (1) γ-aminopropyltriethoxysilane, water and alcohol solvent are mixed and reacted to afford multi-amino terminated hyperbranched polysiloxane, (2) 2-hydroxyethyl disulfide, diisocyanate and an alkane chloride are mixed and reacted to afford disulfide-containing diisocyanate, (3) α,ω-aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride are mixed and reacted to afford linear chain-extended polydimethylsiloxane, (4) mixing the linear chain-extended polydimethylsiloxane, the multi-amino terminated hyperbranched polysiloxane, the disulfide-containing diisocyanate and an alkane chloride, followed by pouring the mixture into a mold, followed by drying, to afford a scrollable and foldable transparent polysiloxane film.

8. The method according to claim 7, wherein the damage refers to fracture.

9. The method according to claim 7, wherein, the alcohol solvent is selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, and any combination thereof; the alkane chloride is selected from the group consisting of dichloromethane, trichloromethane, 1,2-dichloroethane, and any combination thereof; the diisocyanate is selected from the group consisting of diisocyanate compounds and any derivatives prepared from the diisocyanate compounds; the diisocyanate compounds are selected from the group consisting of 2,4-tolylene diisocyanate (TDI), isophorone diisocyanate (IPDI), 4,4′-diphenylmethane diisocyanate (MDI), 4,4′-dicyclohexylmethane diisocyanate (HMDI), hexamethylene diisocyanate (HDI), lysine diisocyanate (LDI), xylylene diisocyanate (XDI), 1,5-naphthalene diisocyanate (NDI), 1,3-bis(1-isocyanato-1-methylethyl)benzene (TMXDI), 4-methylcyclohexyl diisocyanate (HTDI), and any combination thereof.

10. The method according to claim 7, wherein, the mass ratio of γ-aminopropyltriethoxysilane, water and alcohol solvent in Step (1) is 100:(10 to 15):(100 to 200); the mass ratio of 2-hydroxyethyl disulfide, diisocyanate and alkane chloride in Step (2) is (75 to 80):(160 to 270):(1000 to 1500); the mass ratio of α,ω-aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride in Step (3) is 100:(10 to 25):(1000 to 1500); and the mass ratio of linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride in Step (4) is 50:(3 to 6):(10 to 15):(100 to 150).

11. The method according to claim 7, wherein, in Step (1), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 4 to 6 h; in Step (2), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 2 to 4 h; in Step (3), the mixture temperature is room temperature and the reaction temperature is 60 to 80° C. and the reaction time is 4 to 6 h; in Step (4), the mixture temperature is room temperature.

12. The method according to claim 7, wherein, in Step (1), multi-amino terminated hyperbranched polysiloxane is obtained by removing solvents under reduced pressure after the reaction is complete; in Step (2), disulfide-containing diisocyanate is obtained by removing solvents under reduced pressure after the reaction is complete; in Step (3), linear chain-extended polydimethylsiloxane is obtained by removing solvents under reduced pressure after the reaction is complete.

Description

DESCRIPTION OF FIGURES

(1) FIG. 1 is .sup.1H-NMR spectrum of multi-amino terminated hyperbranched polysiloxane (HPSi) synthesized in Example 1 of this invention.

(2) FIG. 2 is .sup.29Si-NMR spectrum of multi-amino terminated hyperbranched polysiloxane (HPSi) synthesized in Example 1 of this invention.

(3) FIG. 3 is Fourier transform infrared (FTIR) spectra of disulfide-containing diisocyanate and scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(4) FIG. 4 is thermogravimetric analysis (TGA) curves of scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(5) FIG. 5 is dynamic mechanical analysis (DMA) curves of scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(6) FIG. 6 is digital images of scrolling and folding process of scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(7) FIG. 7 is UV-vis spectra of scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(8) FIG. 8 is tensile stress-strain curves of original and self-healed scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(9) FIG. 9 is digital images of self-healing process of scrollable and foldable transparent polysiloxane films synthesized in Example 1 of this invention.

(10) FIG. 10 is polarized optical microscope (POM) images of self-healing process of scrollable and foldable transparent polysiloxane films synthesized in Example 1 and polysiloxane films without disulfide synthesized in Control Example 1 of this invention.

EXAMPLES OF THE INVENTION

(11) The technical solutions of this invention will be further described below with the accompanying figures and examples.

Example 1

(12) 1) Synthesis of Multi-Amino Terminated Hyperbranched Polysiloxane (HPSi)

(13) By mass, at 20° C., 100 g γ-aminopropyltriethoxysilane (KH550), 10 g water and 100 g ethanol were mixed homogeneously; the mixture was heated to 60° C. and continued to react for 4 h; ethanol was removed under reduced pressure to get multi-amino terminated hyperbranched polysiloxane (HPSi). .sup.1H-NMR and .sup.29Si-NMR spectra of HPSi are shown in FIG. 1 and FIG. 2, respectively.

(14) 2) Synthesis of Disulfide-Containing Diisocyanate

(15) By mass, at 20° C., 77 g 2-hydroxyethyl disulfide, 224 g isophorone diisocyanate and 1000 g dichloromethane were mixed homogeneously; the mixture was heated to 60° C. and continued to react for 2 h; dichloromethane was removed under reduce pressure to get disulfide-containing diisocyanate. FTIR spectrum of disulfide-containing diisocyanate is shown in FIG. 3.

(16) 3) Synthesis of Linear Chain-Extended Polydimethylsiloxane

(17) By mass, at 20° C., 100 g α,ω-aminopropyl terminated polydimethylsiloxane (PDMS, M.sub.n=1000), 17.7 g isophorone diisocyanate and 1000 g dichloromethane were mixed homogeneously; the mixture was heated to 60° C. and continued to react for 2 h; dichloromethane was removed under reduced pressure to get linear chain-extended polydimethylsiloxane.

(18) 4) Synthesis of Scrollable And Foldable Transparent Polysiloxane Films

(19) By mass, at 20° C., 50 g linear chain-extended polydimethylsiloxane, 3.6 g multi-amino terminated hyperbranched polysiloxane, 10 g disulfide-containing diisocyanate and 100 g dichloromethane were mixed homogeneously and poured into a mould. After drying, scrollable and foldable transparent polysiloxane films were obtained. The FTIR spectra, TGA curves, DMA curves, digital images of scrolling and folding process, UV-vis spectra and tensile stress-strain curves of scrollable and foldable transparent polysiloxane films are shown in FIG. 3, FIG. 4, FIG. 5, FIG. 6, FIG. 7 and FIG. 8, respectively.

(20) 5) Self-Healing Method of Scrollable And Foldable Transparent Polysiloxane Films

(21) Fractured surfaces of damaged scrollable and foldable transparent polysiloxane films were brought into contact, held tightly by clamps, and maintained at 100° C. for 0.5 h to fulfill the self-healing process. The tensile stress-strain curves, digital images of self-healing process, polarized optical microscope (POM) images of self-healing process of self-healed scrollable and foldable transparent polysiloxane films are shown in FIG. 8, FIG. 9 and FIG. 10, respectively.

Control Example 1 Synthesis of Polysiloxane Films Without Disulfide

(22) By mass, at 20° C., 50 g linear chain-extended polydimethylsiloxane, 3.6 g multi-amino terminated hyperbranched polysiloxane, 4 g isophorone diisocyanate and 100 g dichloromethane were mixed homogeneously and poured into a mould. After drying, polysiloxane films without disulfide were obtained.

(23) Fractured surfaces of damaged polysiloxane films without disulfide were brought into contact, held tightly by clamps, and maintained at 100° C. for 0.5 h to fulfill the self-healing process.

(24) The POM images of self-healing process of polysiloxane films without disulfide described in Control example 1 are shown in FIG. 10.

(25) FIG. 1 gives the .sup.1H-NMR spectrum of multi-amino terminated hyperbranched polysiloxane prepared in Example 1. The characteristic signals at 1.21 ppm (b) represent methyl protons of ethoxy group. It could be deduced that the integration ratio of these methyl protons (b) to methylene protons of aminopropyl (c, d or e) is 1.5, which is much lower than the theoretical value (4.5) calculated from the stoichiometric ratio of KH550. This result reveals that ethoxy groups have been hydrolyzed and condensed to siloxane linkages.

(26) FIG. 2 gives the .sup.29Si-NMR spectrum of multi-amino terminated hyperbranched polysiloxane prepared in Example 1. The three characteristic signals at −64.3, −72.5 and −79.5 ppm are assigned to terminal units (T), linear units (L) and dendritic units (D), respectively. It is observed that the signal at −79.5 ppm is much more pronounced than other two signals, suggesting that dendritic units exist in HPSi, and KH550 has been completely hydrolysed. Degree of branching (DB) is an important parameter to describe the level of similarity between branching structures of hyperbranched polymers and common dendrimers, which is often determined by the integral areas of .sup.29Si-NMR spectrum according to Frey's equation (Eqn 1).

(27) $\begin{array}{cc}\mathrm{DB}=\frac{2D}{2D+L}& \left(1\right)\end{array}$

(28) DB of HPSi is calculated to be 0.86, close to the value of perfect dendrimers (DB=1), and is likely to resemble a completely branched structure. It means that HPSi possesses better solubility, lower viscosity and more highly reactive terminal aminos than linear analog.

(29) FIG. 3 gives the FTIR spectra of disulfide-containing diisocyanate and scrollable and foldable transparent polysiloxane films prepared in Example 1. After 2-hydroxyethyl disulfide is reacted with isophorone diisocyanate, the generation of urethane group results in the appearance of stretching vibration at 1720 cm.sup.−1 of carbonyl, and the characteristic peak of —NCO appears at 2260 cm.sup.−1.

(30) The appearance of the stretching (3318 cm.sup.−1) and bending (1560 cm.sup.−1) vibrations of secondary amino as well as the stretching vibration of carbonyl in urea (1630 cm.sup.−1) indicate the occurrence of the chain-extension of PDMS and subsequent reactions between disulfide-containing diisocyante and linear chain-extended polydimethylsiloxane or HPSi. The stretching and bending vibrations of methyl groups in PDMS and isophorone are located at 2960 cm.sup.−1 and 1260 cm.sup.−1, respectively. The sharp characteristic peak at 800 cm.sup.−1, and the broad stretching vibration between 1080 and 1025 cm.sup.−1 severally represent Si—C and Si—O in PDMS or HPSi. No obvious vibration assigned to —NCO (2260 cm.sup.−1) is found in the spectrum of films, so disulfide-containing diisocyante has thoroughly reacted with linear chain-extended polydimethylsiloxane or HPSi, and no isocyanate remains in films.

(31) FIG. 4 gives the TGA curves of scrollable and foldable transparent polysiloxane films prepared in Example 1 and the initial decomposition temperature (T.sub.di) is 282° C., indicating good thermal stability.

(32) FIG. 5 gives the DMA curves of scrollable and foldable transparent polysiloxane films prepared in Example 1. The tan δ-temperature curve has a symmetric pattern and its single peak value is regarded as glass transition temperature (T.sub.g). Hence, the T.sub.g of scrollable and foldable transparent polysiloxane films in Example 1 is 96° C., higher than that of currently existed self-healable polysiloxane resins (−120 to 65° C.).

(33) FIG. 6 gives digital images of scrolling and folding process of scrollable and foldable transparent polysiloxane films prepared in Example 1. A square scrollable and foldable transparent polysiloxane film with dimensions of 60 mm×60 mm was tailored, which can be reversibly changed from one shape to another among three shapes including folding, bending and scrolling, meaning its outstanding flexibility. PI and PET films with same dimensions were taken as references, and also reversibly folded twice. After that, there is a non-recoverable crease left on the surface of either PI film or PET film, while the crease on PI film is transparent but the crease on PET film is an obvious white trace which makes the letter “C” of the background paper not perfect to be shown. In contrast, the folded area of scrollable and foldable transparent polysiloxane film keeps transparent without obvious crease left, and the printed words are clear to be identified, meaning that this novel scrollable and foldable transparent polysiloxane film is able to overcome the disadvantages of PI and PET.

(34) FIG. 7 gives the UV-vis spectra of scrollable and foldable transparent polysiloxane films prepared in Example 1. From the digital photo (inset of FIG. 7), it can be directly seen that the film has good transparency. According to UV-vis spectra, the transmittances with different thicknesses are all larger than 80% within the visible region. Specially, the transmittance at 550 nm is increased from 86.09% (0.4 mm thickness) to 88.63% (0.2 mm thickness), which is consistent with the digital photo.

(35) FIG. 8 gives the tensile stress-strain curves of original and self-healed scrollable and foldable transparent polysiloxane films prepared in Example 1. The tensile strength, elongation at break, Young's modulus and toughness of original film are 9.25±0.22 MPa, 224.21±2.79%, 214.89±18.27 MPa and 16.32±0.18 MPa, respectively, suggesting good stiffness and toughness. The tensile strength, elongation at break and toughness of healed film are 8.16±0.87 MPa, 211.59±5.63% and 14.91±0.72 MPa, respectively. Hence, the corresponding healing efficiencies are 94.99%, 94.37% and 91.36%, respectively. The healed polysiloxane sample could bend 180 degrees without generating cracks on its surfaces (inset of FIG. 8), suggesting that the healed film has good integrity. The Young's modulus and tensile strength of scrollable and foldable transparent polysiloxane films described in this invention are superior to those of existed technical solutions, and the elongation at break value is 22.4 times larger than that of existed technical solutions, meaning that this kind of scrollable and foldable transparent polysiloxane films can simultaneously achieve excellent stiffness and toughness.

(36) FIG. 9 gives digital images of self-healing process of scrollable and foldable transparent polysiloxane films prepared in Example 1. An intact film was cut into two pieces, and then brought into contact at the fractured surfaces. After maintained at 100° C. for 30 min on the heating stage, the two pieces of LP2-SS-HP fuse together as an integrity.

(37) FIG. 10 gives the POM images of self-healing process of scrollable and foldable transparent polysiloxane films prepared in Example 1 and polysiloxane films without disulfide prepared in Control Example 1. The surface morphology of damaged scrollable and foldable transparent polysiloxane films was examined by direct observing the healing process using POM. Cross-shaped scratches, each of which has a width of 20 μm, were first cut using a scalpel on the surface of the sample (black regions in FIG. 10); then the sample was placed on a heating stage and maintained at 100° C. for different length of time to get self-healing. With the extension of healing time, the cross-shaped scratches gradually narrow and shallow, and the black regions turn semi-transparent. When the healing time reaches 30 min, these scratches are totally recovered without obvious scars. In contrast, the cross-shaped scratches of polysiloxane films without disulfide do not recover their transparency, and the black regions of scratches are still clearly shown with slightly reduced width under the same self-healing condition. Therefore, it is reasonable to state that the permanent chemical crosslinked network formed by HPSi can restrain the segmental motion of flexible PDMS. Although the dissociation of hydrogen bonds upon heating at 100° C. can partially recover the chain diffusion, the introduction of dynamic disulfide is the key factor for the self-healing ability of scrollable and foldable transparent polysiloxane films.

Example 2

(38) 1) Synthesis of Multi-Amino Terminated Hyperbranched Polysiloxane (HPSi)

(39) By mass, at 25° C., 100 g γ-aminopropyltriethoxysilane (KH550), 12.5 g water and 150 g methanol were mixed homogeneously; the mixture was heated to 70° C. and continued to react for 5 h; methanol was removed under reduced pressure to get multi-amino terminated hyperbranched polysiloxane (HPSi).

(40) 2) Synthesis of Disulfide-Containing Diisocyanate

(41) By mass, at 20° C., 77 g 2-hydroxyethyl disulfide, 169 g hexamethylene diisocyanate and 1100 g trichloromethane were mixed homogeneously; the mixture was heated to 70° C. and continued to react for 2.5 h; trichloromethane was removed under reduce pressure to get disulfide-containing diisocyanate.

(42) 3) Synthesis of Linear Chain-Extended Polydimethylsiloxane

(43) By mass, at 25° C., 100 g α,ω-aminopropyl terminated polydimethylsiloxane (PDMS, M.sub.n=1000), 13.4 g hexamethylene diisocyanate and 1100 g trichloromethane were mixed homogeneously; the mixture was heated to 70° C. and continued to react for 2.5 h; trichloromethane was removed under reduced pressure to get linear chain-extended polydimethylsiloxane.

(44) 4) Synthesis of Scrollable And Foldable Transparent Polysiloxane Films

(45) By mass, at 25° C., 50 g linear chain-extended polydimethylsiloxane, 4 g multi-amino terminated hyperbranched polysiloxane, 12 g disulfide-containing diisocyanate and 125 g trichloromethane were mixed homogeneously and poured into a mould. After drying, scrollable and foldable transparent polysiloxane films were obtained.

(46) 5) Self-Healing Method of Scrollable And Foldable Transparent Polysiloxane Films

(47) Fractured surfaces of damaged scrollable and foldable transparent polysiloxane films were brought into contact, held tightly by clamps, and maintained at 110° C. for 0.6 h to fulfill the self-healing process.

Example 3

(48) 1) Synthesis of Multi-Amino Terminated Hyperbranched Polysiloxane (HPSi)

(49) By mass, at 30° C., 100 g γ-aminopropyltriethoxysilane (KH550), 15 g water and 200 g n-propanol were mixed homogeneously; the mixture was heated to 80° C. and continued to react for 6 h; n-propanol was removed under reduced pressure to get multi-amino terminated hyperbranched polysiloxane (HPSi).

(50) 2) Synthesis of Disulfide-Containing Diisocyanate

(51) By mass, at 30° C., 77 g 2-hydroxyethyl disulfide, 264 g 4,4′-dicyclohexylmethane diisocyanate and 1200 g 1,2-dichloroethane were mixed homogeneously; the mixture was heated to 80° C. and continued to react for 3 h; 1,2-dichloroethane was removed under reduce pressure to get disulfide-containing diisocyanate.

(52) 3) Synthesis of Linear Chain-Extended Polydimethylsiloxane

(53) By mass, at 30° C., 100 g α,ω-aminopropyl terminated polydimethylsiloxane (PDMS, M.sub.n=1000), 20.8 g 4,4′-dicyclohexylmethane diisocyanate and 1200 g 1,2-dichloroethane were mixed homogeneously; the mixture was heated to 80° C. and continued to react for 3 h; 1,2-dichloroethane was removed under reduced pressure to get linear chain-extended polydimethylsiloxane.

(54) 4) Synthesis of Scrollable And Foldable Transparent Polysiloxane Films

(55) By mass, at 30° C., 50 g linear chain-extended polydimethylsiloxane, 5 g multi-amino terminated hyperbranched polysiloxane, 15 g disulfide-containing diisocyanate and 150 g 1,2-dichloroethane were mixed homogeneously and poured into a mould. After drying, scrollable and foldable transparent polysiloxane films were obtained.

(56) 5) Self-Healing Method of Scrollable And Foldable Transparent Polysiloxane Films

(57) Fractured surfaces of damaged scrollable and foldable transparent polysiloxane films were brought into contact, held tightly by clamps, and maintained at 115° C. for 0.7 h to fulfill the self-healing process.

Example 4

(58) 1) Synthesis of Multi-Amino Terminated Hyperbranched Polysiloxane (HPSi)

(59) By mass, at 22° C., 100 g γ-aminopropyltriethoxysilane (KH550), 11 g water, 100 g methanol and 100 g ethanol were mixed homogeneously; the mixture was heated to 65° C. and continued to react for 4.5 h; methanol and ethanol were removed under reduced pressure to get multi-amino terminated hyperbranched polysiloxane (HPSi).

(60) 2) Synthesis of Disulfide-Containing Diisocyanate

(61) By mass, at 22° C., 77 g 2-hydroxyethyl disulfide, 125 g 4,4′-diphenylmethane diisocyanate, 106 g 1,5-naphthalene diisocyanate, 600 g dichloromethane and 700 g trichloromethane were mixed homogeneously; the mixture was heated to 65° C. and continued to react for 3.5 h; dichloromethane and trichloromethane were removed under reduce pressure to get disulfide-containing diisocyanate.

(62) 3) Synthesis of Linear Chain-Extended Polydimethylsiloxane

(63) By mass, at 22° C., 100 g α,ω-aminopropyl terminated polydimethylsiloxane (PDMS, M.sub.n=1000), 10 g 4,4′-diphenylmethane diisocyanate, 8.4 g 1,5-naphthalene diisocyanate, 600 g dichloromethane and 700 g trichloromethane were mixed homogeneously; the mixture was heated to 65° C. and continued to react for 3.5 h; dichloromethane and trichloromethane were removed under reduced pressure to get linear chain-extended polydimethylsiloxane.

(64) 4) Synthesis of Scrollable And Foldable Transparent Polysiloxane Films

(65) By mass, at 22° C., 50 g linear chain-extended polydimethylsiloxane, 6 g multi-amino terminated hyperbranched polysiloxane, 11 g disulfide-containing diisocyanate, 60 g dichloromethane and 60 g trichloromethane were mixed homogeneously and poured into a mould. After drying, scrollable and foldable transparent polysiloxane films were obtained.

(66) 5) Self-Healing Method of Scrollable And Foldable Transparent Polysiloxane Films

(67) Fractured surfaces of damaged scrollable and foldable transparent polysiloxane films were brought into contact, held tightly by clamps, and maintained at 120° C. for 0.8 h to fulfill the self-healing process.