Tire Having Improved Dynamic Properties
20170210172 ยท 2017-07-27
Inventors
Cpc classification
B60C9/185
PERFORMING OPERATIONS; TRANSPORTING
B60C9/1835
PERFORMING OPERATIONS; TRANSPORTING
B60C2009/1878
PERFORMING OPERATIONS; TRANSPORTING
C08K2201/006
CHEMISTRY; METALLURGY
B60C9/2006
PERFORMING OPERATIONS; TRANSPORTING
C08K9/02
CHEMISTRY; METALLURGY
B60C2001/0075
PERFORMING OPERATIONS; TRANSPORTING
B60C2001/0066
PERFORMING OPERATIONS; TRANSPORTING
International classification
B60C9/18
PERFORMING OPERATIONS; TRANSPORTING
B60C9/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Tire comprising a crown reinforcement formed of at least two working crown layers of reinforcing elements, crossed from one layer to the other making with the circumferential direction angles comprised between 10 and 45. A first layer S of polymer compound is in contact with at least one working crown layer and in contact with the carcass reinforcement, the said first layer S of polymer compound extending axially as far as at least the axial end of the tread and the complex dynamic shear modulus G*, measured at 10% and 60 C. on the return cycle, of the first layer S of polymer compound is greater than 1.35 MPa.
Claims
1. Tire with a radial carcass reinforcement comprising a crown reinforcement formed of at least two working crown layers of reinforcing elements, crossed from one layer to the other making with the circumferential direction angles comprised between 10 and 45, a first layer of polymer compound being in contact with at least one working crown layer and in contact with the carcass reinforcement, said first layer of polymer compound extending axially as far as at least the axial end of the tread, said tread radially capping the crown reinforcement and being connected to two beads by two sidewalls, wherein the complex dynamic shear modulus, measured at 10% and 60 C. on the return cycle, of said first layer of polymer compound is greater than 1.35 MPa.
2. The tire according to claim 1, wherein the crown reinforcement comprises at least one layer of circumferential reinforcing elements.
3. The tire according to claim 1, wherein the complex shear modulus, measured at 10% and 60 C. on the return cycle, of the first layer of polymer compound is less than 2 MPa.
4. The tire according to claim 1, wherein the maximum value of tan(), denoted tan()max, of the first layer of polymer compound is less than 0.100.
5. The tire according to claim 1, wherein said first layer of polymer compound comprises a reinforcing filler composed of: a) either carbon black with a BET specific surface area of between 30 and 160 m2/g, used in a content equal to or greater than 15 phr and less than or equal to 28 phr, b) or a white filler of the silica and/or alumina type comprising SiOH and/or AlOH surface functional groups selected from the group formed of precipitated or pyrogenated silicas, aluminas or aluminosilicates or alternatively carbon blacks modified during or after synthesis with a specific surface area of between 30 and 260 m2/g used at a content greater than or equal to 15 phr and less than or equal to 55 phr, c) or a blend of carbon black described at (a) and a white filler described at (b), in which the overall filler content is greater than or equal to 15 phr and less than or equal to 50 phr and the white filler phr content is greater than or equal to the phr content of carbon black minus 5.
6. The tire according to claim 1, the tire comprising a second layer of polymer compound axially in contact with the first layer of polymer compound radially between the carcass reinforcement and the radially innermost layer of reinforcing elements of the crown reinforcement, wherein the complex dynamic shear modulus, measured at 10% and 60 C. on the return cycle, of said second layer of polymer compound is greater than 1.35 MPa.
7. The tire according to claim 6, wherein the complex shear modulus, measured at 10% and 60 C. on the return cycle, of the second layer of polymer compound is less than 2 MPa.
8. The tire according to claim 6, wherein the maximum value of tan(), denoted tan()max, of the second layer of polymer compound is less than 0.100.
9. The tire according to claim 6, wherein said second layer of polymer compound comprises a reinforcing filler made up of: a) either carbon black with a BET specific surface area of between 30 and 160 m2/g, used in a content equal to or greater than 15 phr and less than or equal to 28 phr, b) or a white filler of the silica and/or alumina type comprising SiOH and/or AlOH surface functional groups selected from the group formed of precipitated or pyrogenated silicas, aluminas or aluminosilicates or alternatively carbon blacks modified during or after synthesis with a specific surface area of between 30 and 260 m2/g used at a content greater than or equal to 15 phr and less than or equal to 55 phr, c) or a blend of carbon black described at (a) and a white filler described at (b), in which the overall filler content is greater than or equal to 15 phr and less than or equal to 50 phr and the white filler phr content is greater than or equal to the phr content of carbon black minus 5.
10. The tire according to claim 2, wherein the layer of circumferential reinforcing elements is placed radially between two working crown layers.
11. The tire according to claim 10, wherein the axial widths of the working crown layers radially adjacent to the layer of circumferential reinforcing elements are greater than the axial width of the said layer of circumferential reinforcing elements.
12. The tire according to claim 11, wherein the working crown layers radially adjacent to the layer of circumferential reinforcing elements are, on each side of the equatorial plane and in the immediate axial continuation of the layer of circumferential reinforcing elements, coupled over an axial width and then decoupled by profiled elements made of rubber compound at least over the remainder of the width that the said two working layers have in common.
13. The tire according to claim 2, wherein the reinforcing elements of at least one layer of circumferential reinforcing elements are metallic reinforcing elements having a secant modulus at 0.7% elongation comprised between 10 and 120 GPa and a maximum tangent modulus less than 150 GPa.
14. The tire according to claim 1, wherein the reinforcing elements of the working crown layers are inextensible.
15. The tire according to one of the preceding claims, characterized in claim 1, wherein the crown reinforcement is supplemented radially on the outside by at least one additional ply, referred to as a protective ply, of reinforcing elements referred to as elastic elements, which are oriented with respect to the circumferential direction at an angle of between 10 and 45 in the same direction as the angle formed by the inextensible elements of the working ply radially adjacent to it.
16. The tire according to claim 1, wherein the crown reinforcement further comprises a triangulation layer formed of metallic reinforcing elements making angles greater than 60 with the circumferential direction.
Description
[0088] Further details and advantageous features of the invention will become apparent hereinafter from the description of exemplary embodiments of the invention, with reference to
[0089]
[0090]
[0091] In order to make them easier to understand, the figures are not shown to scale. The figures depict only half a view of a tire which extends symmetrically with respect to the axis XX that represents the circumferential meridian plane, or equatorial plane, of a tire.
[0092] In
[0097] The crown reinforcement is itself capped by a tread 6.
[0098] The maximum axial width of the tire is equal to 317 mm
[0099] The axial width L.sub.41 of the first working layer 41 is equal to 252 mm
[0100] The axial width L.sub.43 of the second working layer 43 is equal to 232 mm The difference between the widths L.sub.41 and L.sub.43 is equal to 15 mm
[0101] As for the axial width L.sub.42 of the layer of circumferential reinforcing elements 42, this is equal to 194 mm
[0102] The last crown ply 44, referred to as the protective ply, has a width L.sub.44 equal to 124 mm
[0103] According to the invention, a first layer S of rubber compound is placed between the carcass reinforcement 2 and the first working layer 41.
[0104] In
[0105] Tests have been conducted with various tires S1 and S2 produced according to the invention. The tire S2 is produced as depicted in
[0106] The various compounds used for the first layer S are listed below.
TABLE-US-00001 Compound Compound R = 1 1 NR 100 100 Black N326 5 Black N330 35 Silica 165G 40 Antioxidant (6PPD) 0.7 1.5 Stearic acid 1.4 1 Zinc oxide 2.1 5 Silane-on-black 5 Sulphur 2.15 1.75 PEG 2.5 Accelerator CBS 1 0.9 Coaccelerator DPG 0.34 Retarder CTP PVI) 0.08 MA.sub.10 (MPa) 3.4 4.3 tan().sub.max 0.074 0.087 P60 (%) 11.3 16.5 G* 10% at 60 C. 1.25 1.55 (return cycle)
[0107] The values for the constituent ingredients are expressed in phr (parts by weight per hundred parts of elastomer).
[0108] The reference tire T1 has a first layer S made of the compound R1.
[0109] The tires according to the invention S1 and S2 has a first layer S made of the compound 1.
[0110] First endurance tests were run on a test machine that forced each of the tires to run in a straight line at a speed equal to the maximum speed rating prescribed for the said tire (the speed index) under an initial load of 4000 kg progressively increased in order to reduce the duration of the test.
[0111] It was found that all the tires tested exhibited substantially comparable results.
[0112] Other endurance tests were conducted on a test machine that cyclically imposed a transverse loading and a dynamic overload on the tires. The tests were carried out for the tires according to the invention under conditions identical to those applied to the reference tires.
[0113] The distances covered varied from one type of tire to another, failures occurring as a result of degradation of the rubber compounds at the ends of the working layers. The results are set out in the table which follows with reference to a base 100 fixed for the reference tire T1.
TABLE-US-00002 Tire T1 Tire S1 Tire S2 100 125 135
[0114] These results show that the first layer S according to the invention, of which the complex dynamic s hear modulus G*, measured at 10% and 60 C. on the return cycle, is greater than 1.35 MPa, allows a very significant improvement in the endurance performance and, more particularly, the cornering stiffness properties of the tire, even when a layer of circumferential reinforcing elements is present.