Lighting device for generating a light emission and method for generating a light emission
09709225 · 2017-07-18
Assignee
Inventors
- Ion Stoll (Tegernheim, DE)
- Dominik Eisert (Regensburg, DE)
- Britta Göötz (Regensburg, DE)
- Robert Schulz (Thalmassing, DE)
Cpc classification
H10K50/125
ELECTRICITY
F21V9/38
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21V9/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21V13/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F21K9/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21V13/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A lighting device, in various embodiments, for generating a light emission, has a light source designed to generate light with a first dominant wavelength, a first converter designed to absorb the light generated by the light source and to emit light with a second dominant wavelength, which is longer than the first dominant wavelength, and a second converter designed to absorb a portion of the light emitted by the first converter and to emit light such that the light emission has a third dominant wavelength, which is longer than the second dominant wavelength.
Claims
1. A lighting device for generating a light emission, the lighting device comprising: a light source configured to generate light with a first dominant wavelength, wherein the light source comprises a chip; a first converter configured to absorb the light generated by the light source and emit light with a second dominant wavelength, which is greater than the first dominant wavelength, wherein the second dominant wavelength is less than 610 nm; and a second converter configured to absorb a light component of the light emitted by the first converter and emit light such that the light emission has a third dominant wavelength, which is greater than the second dominant wavelength, wherein the second converter comprises an organic phosphor, wherein the second converter comprises a particle size that is smaller than the second dominant wavelength, wherein the first converter is arranged directly on the chip and the second converter is arranged directly on the first converter, wherein substantially no radiation of the light with the first dominant wavelength impinges on the second converter, and wherein at least 95% of the light with the first dominant wavelength is converted by the first converter.
2. The lighting device according to claim 1, wherein the first dominant wavelength lies in a spectral range of blue light, the first converter fully converts the light of the light source into yellowy-red light, and wherein the second converter emits light in a long-wave range of the first converter or in an infrared range, the first converter and the second converter comprising different phosphors.
3. The lighting device according to claim 1, wherein the light component contains up to 30% of a light output of the first converter.
4. The lighting device according to claim 1, wherein the second converter is configured to emit light with a fourth dominant wavelength, which is greater than the second dominant wavelength.
5. The lighting device according to claim 1, wherein the second converter is configured to absorb the light component of the light emitted by the first converter and emit light such that the light emission has a greater peak wavelength in comparison with the light emitted by the first converter.
6. The lighting device according to claim 1, further comprising a lens, wherein the second converter is contained in the lens of the lighting device or is arranged at least partially around the lens of the lighting device.
7. The lighting device according to claim 1, wherein the light source has a light-emitting diode component with a package, the package having a cavity for receiving the second converter.
8. The lighting device according to claim 7, wherein the second converter is contained in a matrix material, which is accommodated in the cavity.
9. The lighting device according to claim 1, wherein the chip is arranged on a substrate.
10. The lighting device according to claim 1, wherein the third dominant wavelength is in a range from 615 nm to 625 nm.
11. A method for generating a light emission, the method comprising: generating light with a first dominant wavelength by a light source comprising a chip; absorbing the generated light and emitting light with a second dominant wavelength, which is greater than the first dominant wavelength, by a first converter, wherein the second dominant wavelength is less than 610 nm; and absorbing a light component of the light emitted by the first converter and emitting light by a second converter such that the light emission has a third dominant wavelength, which is greater than the second dominant wavelength, wherein the second converter comprises an organic phosphor, wherein the second converter comprises a particle size that is smaller than the second dominant wavelength, wherein the first converter is arranged directly on the chip and the second converter is arranged directly on the first converter, wherein substantially no radiation of the light with the first dominant wavelength impinges on the second converter, and wherein at least 95% of the light with the first dominant wavelength is converted by the first converter.
12. The method according to claim 11, wherein the light component contains up to 30% of a light output by the first converter.
13. The method according to claim 1, wherein the light emitted by the second converter has a fourth dominant wavelength, which is greater than the second dominant wavelength.
14. The method according to claim 11, wherein the third dominant wavelength is in a range from 615 nm to 625 nm.
15. A lighting device for generating a light emission, the lighting device comprising: a light source configured to generate light with a first dominant wavelength, wherein the light source comprises a chip; a first converter configured to absorb the light generated by the light source and emit light with a second dominant wavelength, which is greater than the first dominant wavelength; and a second converter configured to absorb a light component of the light emitted by the first converter and emit light such that the light emission has a third dominant wavelength, which is greater than the second dominant wavelength, wherein the second converter comprises an organic phosphor, wherein the second converter comprises a particle size that is smaller than the second dominant wavelength, wherein the first converter is arranged directly on the chip and the second converter is arranged directly on the first converter, wherein the first dominant wavelength lies in a spectral range of blue light, wherein the first converter fully converts the light of the light source into yellowy-red light with wavelengths of between at least 580 nm and less than 610 nm, wherein the second converter emits light in a long-wave range of the first converter or in an infrared range, wherein substantially no radiation of the light with the first dominant wavelength impinges on the second converter, and wherein the first converter and the second converter comprise different phosphors.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Exemplary embodiments of the invention are represented in the figures and explained in more detail below.
(2) In the drawings:
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
(17) In an exemplary embodiment, a blue semiconductor chip is fully converted with a red phosphor. Further along the light path there is a second converter. This converter has an absorption in the short-wave range of the emitted light of the first converter. Furthermore, the second converter has an emission in the long-wave range of the first converter or in the infrared range, for example, with a dominant wavelength that is greater than the dominant wavelength of the first converter. The second converter thus advantageously absorbs parts of the short-wave emission of the first converter and, as a result, shifts the dominant wavelength of the emission to longwave. In addition, the emission of the second converter may contribute to the long-wave shift both of the dominant wavelength and of the peak wavelength (that is to say the wavelength with the highest intensity) of the emission, and advantageously further increase the overall efficiency, in comparison with an identical wavelength shift due to an increase in concentration of the first converter.
(18) In various exemplary embodiments, a dominant wavelength is understood as meaning the wavelength that describes the shade of color of a light-emitting device, for example, a light-emitting diode (LED), as perceived by the human eye. The dominant wavelength may also be referred to as the main wavelength, centroid wavelength or dominance wavelength.
(19) The second converter is advantageously an organic converter. The particle size of organic converters is usually much smaller than the wavelength of light. As a result, there are advantageously no scattering losses or only small scattering losses. Organic converters usually have only low stability with respect to irradiation with short-wave visible light, that is to say with light, for example, in a range from approximately 420 nm to approximately 540 nm. These wavelengths correspond to an energy of approximately 2.3-3.1 eV, which is equivalent to weak carbon bonds (for example, carbon-carbon or carbon-halide bonds; 220-350 kJ/mol), and consequently can destroy them photochemically.
(20) Due to the full conversion of the light emitted by the blue semiconductor chip by means of the first converter, in an exemplary embodiment the second converter is only irradiated with light in a range from approximately 580 nm to approximately 650 nm. As a result, a high stability of the lighting device can advantageously also be achieved with organic converters.
(21) The exemplary embodiment of a lighting device 100 that is shown in
(22) The lighting device 100 also contains a second converter 110, which is configured to absorb a light component, for example, a short-wave light component, of the light 108 emitted by the first converter and emit light 112 with a wavelength that is increased in comparison with the light absorbed. For example, the second converter 110 has a dominant wavelength that is greater than the dominant wavelength of the first converter.
(23) In various exemplary embodiments, the absorbed light component may contain up to approximately 40% of the light output of the first converter 106, advantageously up to approximately 30%, more advantageously up to approximately 20%, more advantageously up to approximately 10%, and preferably approximately 5%. The amount of absorbed light output may be influenced, for example, by one or more of the following parameters:
(24) The length of the light path through the medium with the conversion material, the concentration of the light material and the molar extinction coefficient of the chosen conversion material (Lambert's law).
(25) The extinction coefficient may in turn be wavelength-dependent, that is to say the amount of absorbed light output can be obtained from the superposition of the emission and the extinction. Similarly, the molar extinction coefficient may be dependent on the dielectricity of the medium.
(26) A dominant wavelength of the light 114 that is generated overall by the lighting device 100 and is obtained from the superposition of the non-absorbed light component 108 of the first converter 106 and the light 112 emitted by the second converter 110 may be in the range from approximately 615 nm to approximately 625 nm. Advantageously, both the dominant wavelength and the peak wavelength of the light 114 are shifted to longwave with respect to the light 108 emitted by the first converter 106.
(27) This cannot be achieved, for example, if only a component of the light emitted by the first converter were absorbed.
(28) The exemplary embodiment of a lighting device 200 that is shown in
(29) In this exemplary embodiment, a first converter 216 has been applied to the semiconductor chip 204, for full conversion or virtually full conversion (blue component in the spectrum advantageously less than approximately 5%). The first converter 216 may have been applied to the semiconductor chip 204, for example, by layer transfer, volume potting, electrophoretic deposition or spray coating.
(30) The second converter 210 may be contained in a matrix material 212 accommodated in the cavity 208. A lens 214 may be optionally mounted on the package 206 in the region of the cavity 208. In this exemplary embodiment, the cavity 208 is potted with the matrix material 212. The lens 214 may, for example, have been applied to the second converter 210 by an adhesive (for example, silicone). In other exemplary embodiments, the lens 214 may be applied as drops and the form of a lens may be formed by surface forces. In a further exemplary embodiment, the lens 214 may be formed by shaping methods such as molding or casting.
(31) In the case of structures other than those obtained by volume potting, this matrix may contain the second converter (for example, an organic converter or semiconductor nanoparticle). In the case of volume potting, separation of the first converter and the second converter would not be ensured.
(32) The exemplary embodiment of a lighting device 300 that is shown in
(33) In this exemplary embodiment, a first converter 316, configured for full conversion or virtually full conversion (blue component in the spectrum advantageously less than approximately 5%), has been applied to the semiconductor chip 304. The first converter 316 may have been applied to the semiconductor chip 304, for example, by layer transfer, volume potting, electrophoretic deposition or spray coating.
(34) A second converter 318 is arranged at least partially around the lens 314 or encloses the lens 314 substantially completely, as shown in the exemplary embodiment represented in
(35) The exemplary embodiment of a lighting device 400 that is shown in
(36) In this exemplary embodiment, a first converter 416, configured for full conversion or virtually full conversion (blue component in the spectrum advantageously less than approximately 5%), has been applied to the semiconductor chip 404. The first converter 416 may have been applied to the semiconductor chip 404, for example, by layer transfer, volume potting, electrophoretic deposition or spray coating. The material of a second converter 418 is contained in the lens 414.
(37) The exemplary embodiment of a lighting device 500 that is shown in
(38) The exemplary embodiment of a lighting device 600 that is shown in
(39) The exemplary embodiment of a lighting device 700 that is shown in
(40) The exemplary embodiment of a lighting device 800 that is shown in
(41) In the exemplary embodiments described above with reference to
(42) In the exemplary embodiments described, the following materials may be advantageously used, for example, as lens material:
(43) Polyacrylate, polyolefins (for example, high- or low-density polyethylene (PE) or polypropylene (PP)), polyvinylchloride (PVC), polystyrene (PS), polyester, polycarbonate (PC), polyethylene terephthalate (PET), polyether sulfone (PES), polyethylene naphthalate (PEN), polymethyl methacrylate (PMMA), polyimide (PI), polyether ketone (PEEK), polyamides, for example, polyphthalamides (PPA), polycyclohexylene dimethylene terephthalate (PCT), silicones, epoxides or a liquid-crystalline polymer (LCP).
(44) In other exemplary embodiments, the second converter may be formed as a component that is separate from the light source and the first converter. Consequently, the second converter can be used in a so-called remote approach.
(45) The exemplary embodiments are possible in the case of an organic light-emitting diode (OLED) with pumping wavelengths in the blue and white range, for example, with blue and white as the pumping wavelengths for the first converter and then red directly for the red-red conversion of the second converter.
(46) In the exemplary embodiments described, the first converter may, for example, be configured to emit light in a range from approximately 580 nm to approximately 650 nm, for example, with a dominant wavelength less than approximately 610 nm. The light emitted/converted altogether by the lighting device may, for example, have a dominant wavelength in a range from approximately 610 nm to approximately 625 nm. The second converter may, for example, have its absorption maximum at approximately 575 nm. In an exemplary embodiment, the light from the first converter may have a dominant wavelength of approximately 606 nm and the dominant wavelength of the light emitted/converted altogether may be approximately 612 nm.
(47)
(48)
(49) The Eu.sup.2+-doped converter in
(50)
(51) For the curve 1100, a peak wavelength, that is to say the wavelength with the highest intensity, of approximately 624 nm was measured, while for the curves 1102, 1104 and 1106 a dominant wavelength of approximately 628 nm, approximately 629 nm and approximately 627 nm was respectively measured. The material of the second converter in the exemplary embodiments of the curves 1102, 1104 and 1106 was BASF Lumogen F red 305, with approximately the same layer thicknesses.
(52)
(53)
(54) As can be seen from a comparison of
(55) The exemplary embodiments described may advantageously have one or more of the following effects:
(56) A converted spectrum with a dominant wavelength in a range from approximately 615 nm to approximately 625 nm can be obtained.
(57) By the second conversion of low-energy photons (red), materials that would not have the necessary stability in the customary conversion of blue light can be used for the conversion (such as, for example, organic converters and semiconductor nanoparticles). These materials can be obtained in particle sizes well below the wavelength of visible light, and consequently further scattering losses do not occur.
(58) The first converter emits at a shorter wavelength than is necessary without a second conversion. As a result, there is less emission in the infrared range.
(59) A converted spectrum with a dominant wavelength in a range from approximately 615 nm to approximately 625 nm can be obtained.
(60) A higher overall efficiency can be achieved than, for example, with a single-phosphor system.
(61) The spectrum becomes narrower, and as a result a better color saturation is achieved.
(62) A purer shade of red is obtained.
(63) A material-system-dependent chromaticity point shift with increasing temperature can be compensated, or at least minimized, by the second converter. Some converters, such as, for example, phosphors, shift with higher temperatures in the direction of yellow. Furthermore, at higher temperatures, conversion is not as great. By the second converter, for example, phosphor, the yellow shift can be arrested, since more light is absorbed and converted back into red. Furthermore, the strong remains of blue light occurring can be absorbed by the second converter. Otherwise, the desired color range would be abandoned at high temperatures.
(64) Possible, but not restrictive, materials for the first converter in the exemplary embodiments described are Eu.sup.2+-doped converters, such as, for example, Eu.sup.2+-doped nitrides, for example, CaAISiN3:Eu.sup.2+, (Ba, Sr)2Si5N8:Eu.sup.2+; Eu.sup.2+-doped sulfides; Eu.sup.2+-doped SiAIONe and SiONe.
(65) Possible, but not restrictive, materials for the second converter in the exemplary embodiments described are organic dyes and luminescent dyes, for example, the following substance classes: acridine dyes, acridinone dyes, anthraquino dyes, anthracene dyes, cyanine dyes, dansyl dyes, squaryllium dyes, spiropyrans, boron-dipyrromethenes (BODIPY), perylenes, pyrenes, naphthalenes, flavins, pyrroles, porphyrins and the metal complexes thereof, diarylmethane dyes, triarylmethane dyes, nitro and nitroso dyes, phthalocyanine dyes and metal complexes of phthalocyanines, quinones, azo dyes, indophenol dyes, oxazines, oxazones, thiazines and thiazoles, xanthenes, fluorenes, flurones, pyronines, rhodamines, coumarins.
(66) Advantageous organic materials are, for example, perylene imides and perylene carboxylates.
(67) The invention is not restricted by the description on the basis of the exemplary embodiments to these embodiments. Rather, the invention comprises every novel feature and every combination of features, which includes in particular any combination of features in the patent claims, even if this feature or this combination itself is not explicitly specified in the patent claims or exemplary embodiments.