Methods for producing a cavity within a semiconductor substrate
09708182 ยท 2017-07-18
Assignee
Inventors
- Andreas Behrendt (Villach, AT)
- Kai-Alexander Schreiber (Villach, AT)
- Sokratis Sgouridis (Annenheim, AT)
- Martin Zgaga (Rosegg, AT)
- Bernhard WINKLER (Regensburg, DE)
Cpc classification
B81B3/0094
PERFORMING OPERATIONS; TRANSPORTING
B81C1/00626
PERFORMING OPERATIONS; TRANSPORTING
B81B3/0021
PERFORMING OPERATIONS; TRANSPORTING
B81C1/00619
PERFORMING OPERATIONS; TRANSPORTING
International classification
H01L21/00
ELECTRICITY
B81B3/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for producing at least one cavity within a semiconductor substrate includes dry etching the semiconductor substrate from a surface of the semiconductor substrate at at least one intended cavity location in order to obtain at least one provisional cavity. The method includes depositing a protective material with regard to a subsequent wet-etching process at the surface of the semiconductor substrate and at cavity surfaces of the at least one provisional cavity. Furthermore, the method includes removing the protective material at least at a section of a bottom of the at least one provisional cavity in order to expose the semiconductor substrate. This is followed by electrochemically etching the semiconductor substrate at the exposed section of the bottom of the at least one provisional cavity. A method for producing a micromechanical sensor system in which this type of cavity formation is used and a corresponding MEMS are also disclosed.
Claims
1. A method for producing at least one cavity within a semiconductor substrate, the method comprising: dry etching the semiconductor substrate from a surface of the semiconductor substrate at at least one intended cavity location in order to obtain at least one provisional cavity; depositing a protective material with regard to a subsequent wet-etching process at the surface of the semiconductor substrate and at cavity surfaces of the at least one provisional cavity; removing the protective material at least at a section of a bottom of the at least one provisional cavity in order to expose the semiconductor substrate; and electrochemically etching the semiconductor substrate at the exposed section of the bottom of the at least one provisional cavity, wherein the electrochemical etching comprises a first temporal segment, during which an electrical voltage applied to the semiconductor substrate is increased, and a second temporal segment, during which the electrical voltage applied to the semiconductor substrate is kept constant.
2. The method according to claim 1, further comprising: depositing an oxide mask for dry etching the semiconductor substrate prior to the dry etching.
3. The method according to claim 1, wherein the dry etching comprises at least one of the following processes: reactive ion etching (RIE), deep reactive ion etching (DRIE) and a Bosch process.
4. The method according to claim 1, wherein the protective material is an oxide, a silicon oxide or a spacer oxide.
5. The method according to claim 1, wherein depositing the protective material comprises a plasma deposition, a thermal oxide deposition or a combination thereof.
6. The method according to claim 1, wherein removing the protective material comprises plasma etching.
7. The method according to claim 1, wherein, prior to removing the protective material, furthermore comprises depositing a mask and patterning the deposited mask.
8. The method according to claim 1, wherein a basic etching medium is used for the electrochemical etching.
9. The method according to claim 1, wherein the electrochemical etching provides an etching stop technique.
10. The method according to claim 1, further comprising: carrying out a lithography process and a subsequent implantation in order to form a pn junction at a depth within the semiconductor substrate, wherein the depth of the pn junction is a function of a desired depth of the bottom of the at least one cavity.
11. The method according to claim 1, wherein an etching medium used for the electrochemical etching comprises tetramethylammonium hydroxide (TMAH), an aqueous solution of ethylenediamine and pyrocatechol (EDP), hydrazine, potassium hydroxide (KOH) or a combination thereof.
12. A method for producing a micromechanical sensor system comprising: providing a doped semiconductor substrate; redoping at least one redoped region within the doped semiconductor substrate; and carrying out a patterning process for producing microelectromechanical structures in the semiconductor substrate and at a substrate surface, wherein at least one portion of the microelectromechanical structures provided extends into the redoped region; and carrying out the method for producing at least one cavity within the semiconductor substrate according to claim 1, wherein the cavity adjoins the redoped region and the portion of the microelectromechanical structures which extends into the redoped region.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Exemplary embodiments are described in greater detail below with reference to the accompanying figures, in which:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
DETAILED DESCRIPTION
(14) Before exemplary embodiments are explained below with reference to the accompanying figures, it is pointed out that identical elements or elements having an identical function are provided with the same or similar reference signs, and that a repeated description of said elements is dispensed with. The descriptions of elements having identical or similar reference signs are therefore mutually interchangeable. One feature or a plurality of features of one exemplary embodiment can be combined with one feature or a plurality of features of another exemplary embodiment or be replaced thereby.
(15) In MEMS technology, most of the microelectromechanical structures are usually formed at the substrate surface. In particular, in this case the substrate material itself can be patterned, and further materials can also be deposited at the substrate surface and patterned, with the result that the final microelectromechanical structure typically has a layer construction. In some microelectromechanical systems, however, it may furthermore be necessary or expedient to provide an access to the microelectromechanical structures from the opposite substrate surface, too. By way of example, a pressure sensor may require a feed channel via which the pressure to be measured is fed to the membrane patterned as a microelectromechanical component. In the case of an acceleration sensor, it may be necessary or expedient for the mechanical mass element, which serves for detecting the acceleration, to be able to be deflected far enough, for which purpose a sufficiently large free space around the mass element has to be provided in order not to impede this deflection. In these and further examples, it is possible to provide cavities in the semiconductor substrate which are shaped from a rear side of the substrate (that is to say opposite to the surface at which the microelectromechanical structures are formed).
(16) Exemplary embodiments serve for producing cavities on silicon wafers (or more generally: wafers composed of semiconductor material) which are used for producing MEMS components (e.g. pressure and acceleration sensors) of any type (sensors and actuators). In order to produce said cavities in the bulk material of ultra-pure silicon of MEMS components, a so-called combination process is used here, which comprises process steps that follow in the sequence typically on different process apparatuses:
(17) 1. Dry etching (DRIE Deep reactive ion etching/Bosch process) using an oxide hard mask
(18) 2. Depositing a spacer oxide and etching an oxide spacer structure as sidewall protection for the subsequent wet-chemical etching
(19) 3. Electrochemical anisotropic etching in TMAH
(20) The Bosch etch employed first (in step 1) yields etching sidewalls that are perpendicular as far as a certain etching depth, which in combination with the two subsequent process steps (2. and 3.) makes it possible to reduce the chip area required for the sensors. A process for producing the silicon components (generally semiconductor components) with a smaller total area is thus made possible.
(21) In this example described in an exemplary fashion here, the combination process in accordance with exemplary embodiments makes possible a chip size of 4.08 mm.sup.2; at the present time, the MEMS silicon sensor area is 6.49 mm.sup.2 for a comparable structure (37% area saving). The reduced sensor component area is made possible by using the Bosch etching process that yields etching sidewalls that run perpendicularly. Depending on the depth (etching process duration) of the Bosch etch, the area of the cavities and thus that of the silicon MEMS sensor components can be reduced further. There is a restriction in the etching depth in the Bosch etching process in that, starting from a specific etching depth, no downstream pn etch can be effected since the space charge zone (abbreviated to SCZ) of the pn junction is already reached in the depth of the substrate and a self-aligned etching stop is not obtained.
(22)
(23) As can be seen in the flowchart of
(24) Subsequently, the protective material is removed at least at a section of a bottom of the at least one provisional cavity in order to expose the semiconductor substrate there, as indicated in a step 106 of the schematic flowchart of
(25) The choice of the depth to which step 102 of dry etching is carried out and the further shaping of the cavity is subsequently continued by the electrochemical etching in accordance with step 108 can be adapted to the conditions and requirements of the respective process or of the microelectromechanical systems to be produced. This choice of the proportions of dry etching and of electrochemical etching can e.g. take account of the different etching rates and resultant process durations of the two etching processes, the costs thereof (both with regard to the required apparatuses and also with regard to the operating costs) and also a higher yield or number of chips per wafer which can be achieved on account of one with the proposed combination method. If the advantage of the higher yield per wafer is outweighed by the possibly higher costs for processing a wafer, consideration can be given, in particular, to carrying out the dry etching (step 102) for as long as possible. This depends, in particular, on how accurately the etching depth can be controlled and supervised during dry etching. The dry etching should generally stop before the desired final depth of the cavity is attained, since otherwise there is the risk of attacking or even destroying microelectromechanical structures which lie in an extension of the final cavity or at the bottom of the cavity. By way of example, the proportion of dry etching can be two thirds, relative to the final depth of the cavity. Alternatively, the proportion of dry etching can be between 30% and 90% and have in particular the following values: 30%, 50%, 75%, 80% or 90%, in each case relative to a final depth of the cavity to be produced.
(26) The step of electrochemical etching 108 generally stops automatically at a predefined depth, which is achieved by providing a corresponding etching stop (e.g. in the form of a pn junction with electrical voltage applied thereto).
(27) As a possible application, exemplary embodiments afford the possibility of significantly reducing the component area of an MEMS sensor (e.g. of a combined pressure and acceleration sensor) in order thus to accommodate as many sensor components as possible, each having as minimal an area as possible, on a wafer having a specific size (e.g. on a 6-inch wafer or an 8-inch wafer).
(28) In the case of the combined pressure and acceleration sensor mentioned here as an example, e.g. the focus can be directed at reducing the sensor area in the acceleration sensor, which is ultimately intended to be operated with the same sensitivity as its counterpart having a larger area. For this purpose, it will generally be endeavoured to ensure that the inertial mass of the sensor remains as far as possible identical, since it is only then that a largely identical resonant frequency with which the sensor is operated is obtained.
(29) This is achieved by the lithographically patterned wafer rear side (wafer material for example silicon) firstly being removed by means of a Bosch etch (using an oxide hard mask or a negative resist that is resistant to the etching medium). Substantially perpendicular etching sidewalls are obtained in the bulk silicon in this way. With the aid of the SPACER technique (plasma or thermal oxide deposition with subsequent anisotropic plasma etching), the perpendicular sidewalls of the Bosch-etched cavities are protected by means of an oxide layer and a subsequent electrochemical anisotropic etch (in TMAH, EDP, hydrazine, KOH or further customary basic etching media) leads the etching front as far as the depth of a space charge zone present in the p-type substrate (electrochemical etching stop before the reverse-biased pn junctionetching medium coming from the p-type region, stopping in the direction of the n-type region), which ultimately determines the membrane thickness (pressure sensor) or cantilever thickness (acceleration sensor).
(30) One feature of the method in accordance with embodiments is the low price of silicon basic material in comparison with SOI (silicon-on-insulator) basic material. A further possibility for obtaining small structure sizes in the case of MEMS sensor components by means of silicon bulk etching methods is the use of SOI basic material. However, no pn etching stop method and therefore no combination process is used in this case. This principle is usually based exclusively on the use of the Bosch etching process. In this case, an etching stop is effected on the oxide layer of the SOI material. MEMS products composed of SOI basic material and use of Bosch etching methods therefore have predominantly perpendicular etching sidewalls.
(31) Exemplary embodiments are therefore based on the combination process described herein (a variation of silicon micromachining) for producing MEMS silicon sensor components and also other MEMS components or electronic components on the basis of silicon wafers. Alternatively, other semiconductor materials are also conceivable. This technique makes it possible to reduce the required wafer area (in particular silicon wafer area) and accordingly the area of the components, in particular silicon sensor components (shrink).
(32) Exemplary embodiments comprise the described process sequence for producing cavity structures e.g. in the bulk ultra-pure silicon <100>:
(33) a) Bosch etching process (DRIE) using a positive or negative resist mask
(34) b) Plasma CVD deposition and anisotropic etching of an undoped silicon glass (SPACER technology) for protecting the perpendicular silicon sidewalls of the Bosch-etched cavities
(35) c) electrochemical anisotropic etching in a basic medium with an etching stop technique (the etching stop is effected in the depth profile before the space charge zone of a reverse-biased pn junction produced for example by means of lithography and implantation technology).
(36)
(37) This is followed by carrying out a plasma chemical vapour deposition (CVD) of a silicon oxide (or else of some other oxide) at the substrate surface and at cavity surfaces of the at least one provisional cavity. The silicon oxide is generally also deposited at areas which do not run parallel to the substrate surface, as is the case e.g. for the sidewalls of the provisional cavity. The silicon oxide serves in particular as a protective material for a subsequent etching step (see step 208 and the subsequent associated description).
(38) As indicated in a step 206 of the schematic flowchart of
(39) The method for producing at least one cavity within the semiconductor substrate is continued after the anisotropic etching of the silicon oxide with electrochemical anisotropic etching of the semiconductor substrate, as can be seen in step 208. The electrochemical anisotropic etching is effected using an electrochemically controlled pn etching stop, wherein the electrochemical anisotropic etching is effected at least at that section of the bottom of the at least one provisional cavity which had been exposed previously (step 206). In this way, the provisional cavity is extended, to be precise proceeding from the bottom of the provisional cavity with the etching profile which is characteristic of the electrochemical anisotropic etching method used. By way of example, the sidewalls of the cavity in the section produced by the electrochemical anisotropic etching can form a specific angle with the substrate surface, e.g. the crystal angle between the Si <100> and Si <111> planes of 54.7.
(40)
(41) Sub-FIG. a) of
(42) Sub-FIG. a) of
(43) In sub-FIG. b) of
(44) Sub-FIG. c) of the process sequence of
(45) Sub-FIG. d) of
(46) Sub-FIG. e) of
(47) The cavities 45 have a bottom 46 adjoining the redoped regions 15. This is owing to the fact that the redoped region 15 constitutes an etching stop for the pn etch.
(48) One possible embodiment of the invention chosen here as an example is implemented at a pressure and an acceleration sensor on a common sensor component area. Here the wafer-rear-side cavities are etched into the <100>-silicon basic material by means of the combination process described. The total depth can vary in this case; customary etching depths depend on the required membrane thickness or that of the cantilever of the acceleration sensor and here are approximately 375 m or 400 m, respectively. The etching depth is also dependent on the original wafer thickness.
(49) Furthermore, consideration is given to inserting two spring-mass systems situated antiparallel to one another in a cavity, in order to provide a so-called two-axis acceleration measuring system. On account of the use of the combination process in accordance with exemplary embodiments, these two structure elements can be integrated in a cavity in a space-saving manner and can also be patterned by this process.
(50) The masses of the acceleration sensors are small in terms of area, since the combination process makes possible a mass thickness corresponding to that of the silicon wafer.
(51) By varying an implantation depth of the second dopant, which is used to form the redoped region 15 in the substrate 10, it is possible to provide different etching stop depths for the pn etch. In this way, e.g. a plurality of cavities of different depths can be produced during the same pn etch. Furthermore, it is possible to pattern the bottoms 46 of the produced cavities 45 (
(52)
(53) In sub-FIG. b) of
(54) Between the states illustrated in sub-FIGS. b) and c) of
(55) Sub-FIG. d) of
(56) The method is then continued with a pn etch (electrochemical etch), whereby the provisional cavity 40 is extended in particular into the depth to form a final cavity 45. In this case, the sidewalls 42 of the provisional cavity 40 continue by means of obliquely running sidewall sections 47 as far as the redoped region 15. Upon reaching the redoped region 15, the pn etch stops and the final cavity 45 has a cavity bottom 46 at this location.
(57)
(58) It is taken into consideration that the bottom of the right-hand cavity has a structure which can be used for a microelectromechanical structure.
(59)
(60)
(61) The acceleration sensor part of the microelectromechanical sensor system is formed to the right of the pressure sensor.
(62) The covering wafer 790 is connected to the main wafer 710 by means of anodic (wafer) bonding 795.
(63) The acceleration sensor has a mass 750, which is connected to the substrate of the main wafer 710 via a cantilever arm 751. The cantilever arm 751 is delimited by the cavity bottom 746 on its side facing the cavity 745. On account of the cantilever arm suspension, the mass 750 can oscillate and thus react to an acceleration. A deformation of the cantilever arm 751 can be measured with the aid of surface resistors 748. A further cavity 745 is provided to the right of the mass 750. Said further cavity 745 passes through the main wafer 710 until it reaches one of the cavities 791 formed in the covering wafer 790. The cavities 745 situated to the left and right of the mass 750 are also connected to a cavity 782 implemented in the access wafer 780.
(64) The combined pressure and acceleration sensor is electrically connected via main contacts 702 and buried, horizontal feedthroughs 704. By way of example, the thickness of the main wafer 710 can be approximately 400 m, and the thickness of the covering and access wafers 790, 780 can be approximately 350 m.
(65) In
(66)
(67)
(68)
(69) A structure indicating the mass element 750 (see
(70)
(71) The etching pattern which can be obtained by means of a pn etch will be considered first of all. On account of the relatively shallowly inclined sidewalls, the cross section of the cavity produced decreases with increasing depth. In the example illustrated in
(72) Furthermore,
(73) In the first combination process, firstly a provisional cavity is etched by means of the Bosch process with a depth d.sub.Bosch1. The Bosch etching proportion is therefore d.sub.Bosch1/d. In the case of the second variant, the Bosch etching proportion is higher, such that the provisional cavity produced in this way has a depth d.sub.Bosch2>d.sub.Bosch1 (Bosch etching proportion=d.sub.Bosch2/d in this case).
(74) In both cases, a pn etch follows. Two cases can be differentiated here: in the first case, the sidewalls of the provisional cavity are protected by a corresponding protective material during the pn etch and are therefore substantially not attacked. In the second case, the sidewalls are unprotected during the pn etch and are therefore likewise changed, which leads to a widening of the cavity in this region.
(75) The following values shall also be specified as examples: d=400 m, d.sub.Bosch1=200 m and d.sub.Bosch2=300 m. The numerical values specified below should also be regarded expressly as an example.
(76)
(77) Referring to the numerical values specified above, w.sub.B would in this case be e.g. 72 m.
(78) Precisely in MEMS technology, the required lateral extension of the bottom of the cavity determines the size of the cavity, in particular the maximum lateral extent thereof.
(79) In the first combination process, the lateral extension of the cavity bottom by the amount 2(w.sub.B+w.sub.C) is less than the lateral extension of the provisional cavity produced by the Bosch etch. Once again with reference to the numerical values specified above, w.sub.C would here be 68 m.
(80)
(81) The following table summarizes the exemplary numerical values for the dimensions shown in
(82) TABLE-US-00001 d 400 m d.sub.Bosch1 200 m d.sub.Bosch2 300 m w.sub.A 140 m w.sub.B 72 m w.sub.C 68 m w.sub.D 72 m w.sub.E 32 m
(83)
(84) Although some aspects have been described in connection with a device, it goes without saying that these aspects also constitute a description of the corresponding method, and so a block or a component of a device should also be understood as a corresponding method step or as a feature of a method step. Analogously thereto, aspects described in connection with or as a method step also constitute a description of a corresponding block or detail or feature of a corresponding device. Some or all of the method steps can be performed by a hardware apparatus (or using a hardware apparatus), such as, for example, a microprocessor, a programmable computer or an electronic circuit. In some exemplary embodiments, some or a plurality of the most important method steps can be performed by such an apparatus.
(85) The exemplary embodiments described above merely constitute an illustration of the principles of the present invention. It goes without saying that modifications and variations of the arrangements and details described herein will become apparent to other persons skilled in the art. Therefore, it is intended that the invention be restricted only by the scope of protection of the appended patent claims, rather than by the specific details presented on the basis of the description and the explanation of the exemplary embodiments herein.
(86) In the detailed description above it can be seen that different features are grouped together in exemplary embodiments. This manner of disclosure should not be understood as an intention that the claimed exemplary embodiments require more features than are explicitly mentioned in the respective claim. Rather, the situation is such that inventive content may reside in fewer than all features of an individual exemplary embodiment disclosed. Therefore, the following claims should hereby be deemed to be incorporated in the description, wherein each claim by itself can stand as a separate exemplary embodiment. Although each claim by itself can stand as a separate exemplary embodiment, it should be noted thatalthough a dependent claim can refer in the claims to a specific combination with one or a plurality of claimsother exemplary embodiments can also encompass or include a combination of said dependent claim with the subject matter of any other dependent claim or a combination of any feature with other dependent and independent claims. Such combinations are proposed herein, unless it is explicitly expressed that a specific combination is not intended. Furthermore, it is also intended that features of a claim can be included in any other independent claim, even if said claim is not directly dependent on the independent claim.
(87) It should furthermore be noted that methods disclosed in the description or in the claims can be implemented by a device comprising means for performing the respective steps or actions of this method.
(88) Furthermore, in some exemplary embodiments, an individual step/action can be subdivided into a plurality of sub-steps or contain a plurality of sub-steps. Such sub-steps can be contained in the disclosure of the individual step and be part of the disclosure of the individual step.