METHOD OF PREPARING A WATER-BASED ADHESIVE WITH HIGH BINDING PROPERTY BASED ON POLYMER COMPOSITES

Abstract

A method of preparing a water-based adhesive with high binding property based on polymer composites is provided, belonging to the technical field of preparation of water-based adhesives. The present invention specifically relates to a method of forming a polymer composite by blending solutions and then preparing the water-based adhesive with high binding property. The preparation method of the present invention is simple, obtaining the composite polymer hydrogel merely by blending solutions, with the dense water-based adhesive produced by centrifugation. This water-based adhesive is formed based on multiple weak interactions among the polymers, with the forming process simple and efficient and involving no sophisticated instruments and equipment; no organic solvent needs to be added in the preparation process, odor free, non-toxic and environment-protective, and common raw materials are used that are inexpensive. This water-based adhesive can be used for bonding glass, metal, wood, plastic and other various materials, and has high binding strength, allowing the materials (except plastic) to be bonded directly without surface pretreatment or modification. It is expected that the water-based adhesive prepared by the present invention will be applied in a wide range of fields.

Claims

1. A method of preparing a water-based adhesive with high binding property based on polymer composites, comprising the following steps: (1) preparation of a building solution: dissolving a polymer in deionized water, treating with ultrasound for 20-60 minutes, and heating until complete dissolution, thus forming a polymer solution at a concentration of 1.0-10.0 mg/mL, with its pH value adjusted to 1-8; then dissolving a nanofiller in the deionized water, treating with ultrasound for 20-60 minutes, and heating until complete dissolution, thus forming a nanofiller solution at a concentration of 0.01-1 mg/mL; (2) preparation of a polymer composite solution: mixing the polymer solution and the nanofiller solution together that are obtained in the step (1), with the mass of the nanofiller being 0-5% of the total mass of the polymer; and (3) collection of the water-based adhesive: standing the polymer composite solution obtained in the step (2) to precipitate hydrogel sufficiently, and discarding supernatant by centrifugation to obtain the water-based adhesive with high binding property prepared based on polymer composites.

2. The method of preparing the water-based adhesive with high binding property based on polymer composites according to claim 1, characterized in that: the polymer is a combination of any two or more substances selected from a group consisting of hyaluronic acid, polymethacrylic acid, polyacrylic acid, polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, and polyvinyl pyridine.

3. The method of preparing the water-based adhesive with high binding property based on polymer composites according to claim 2, characterized in that: when the polymer used is a combination of two polymers, the mass ratio of them is 1:10 to 10:1.

4. The method of preparing the water-based adhesive with high binding property based on polymer composites according to claim 1, characterized in that: the nanofiller is one substance selected from a group consisting of graphene oxide, carbon nanotubes, montmorillonite and cellulose nanocrystals, with the grain size at 10-50 nanometers.

5. The method of preparing the water-based adhesive with high binding property based on polymer composites according to claim 1, characterized in that: in step (1) the pH value is adjusted to 1-8 with 0.5-2 M hydrochloric acid or sodium hydroxide aqueous solution.

6. The method of preparing the water-based adhesive with high binding property based on polymer composites according to claim 1, characterized in that: in the step (2) the polymer composite solution should be sufficiently stirred to get mixed.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0020] FIG. 1: a photo of the state of the water-based adhesive prepared based on the polymer composite, corresponding to Example 1;

[0021] FIG. 2a: a photo of the state of a small piece of the water-based adhesive taken out with a forceps, and FIG. 2b: a photo of the state of the water-based adhesive prepared based on the polymer composite that has strong adhesion to metal at normal temperature, corresponding to Example 1;

[0022] FIG. 3: a photo of the state of the water-based adhesive prepared based on the polymer composite that bonds two pieces of iron together, applicable to the lap shear tester, corresponding to Example 1;

[0023] FIG. 4: a photo of the state of the water-based adhesive prepared based on the polymer composite that bonds two pieces of wood together, applicable to the lap shear tester, corresponding to Example 2;

[0024] FIG. 5: a photo of the state of the water-based adhesive prepared based on the polymer composite that bonds two pieces of glass together, with two pieces of iron fixed on both sides of the bonded glass sample, respectively, applicable to the lap shear tester, corresponding to Example 3;

[0025] FIG. 6: a histogram of the lap shear strength of the water-based adhesive prepared based on the polymer composite that is applied to different materials, corresponding in turn to iron, wood and glass from left to right, corresponding to Examples 1, 2 and 3, respectively; and

[0026] FIG. 7: two hydrophilically-modified PTFE sheets bonded by the water-based adhesive prepared based on the polymer composite, allowing three 500 g weights to be hung at the total weight about 1500 g.

DETAILED DESCRIPTION OF THE EMBODIMENTS

[0027] The specific examples and results of the present invention will be further illustrated below through some examples, but the present invention is not limited by these examples.

Example 1

[0028] a. Preparation of the building solution: Preparing 10 mL solution of polyacrylic acid (PAA) in deionized water at a concentration of 1 mg/mL and 10 mL solution of polyvinyl pyrrolidone (PVPON) in deionized water at a concentration of 1 mg/mL, respectively, with the mass ratio of the polymers contained in the two solutions being 1:1, and adjusting the pH value of the polymer solutions to 4 with 1 M HCl aqueous solution, respectively.

[0029] b. Preparation of the polymer composite: Mixing the prepared solutions at a volume ratio of 1:1 at a speed of 10 mL/min, with the polymer composite solution needing to be sufficiently stirred in the mixing process so as to prevent the heterogeneous composite from being produced due to excessive local concentration of the polymer.

[0030] c. Collection of the water-based adhesive: Standing the polymer composite solution after they are mixed to precipitate the polymer composite hydrogel sufficiently, centrifugating to achieve dense hydrogel, and discarding the supernatant to obtain the needed water-based adhesive. As shown in FIG. 1, what is located at the top of the little bottle is the water-based adhesive just obtained by centrifugation, which is translucent hydrogel that will not flow even when being placed upside down; this water-based adhesive can be easily taken out. As shown in FIG. 2a, a small piece of the gel can be taken out conveniently with a forceps; with the two feet of the forceps apart, it can be found that this gel has strong adhesion to the stainless steel forceps, as shown in FIG. 2b.

[0031] d. Bonding of samples: Removing a proper amount of the prepared water-based adhesive, as shown in FIG. 2a, placing it at one end of a piece of iron, and overlaying the piece of iron with another piece of iron in parallel, as shown in FIG. 3, with the bonding area being 0.5 cm1 cm; applying pressure of 5 N to the bonded region to make the two pieces of iron contact closely, which can be bonded firmly after the water in the water-based adhesive is vaporized completely.

[0032] e. Applying these bonded pieces of iron to the lap shear tester to test the bonding strength of this water-based adhesive. The F.sub.max measured in this example is 215 N, and the lap shear strength F.sub.max/S calculated in this example when the water-based adhesive is applied to the surface of iron pieces is 4.3 MPa, as shown in FIG. 6.

Example 2

[0033] a. Preparation of a building solution: Preparing 10 mL solution of hyaluronic acid (HA) in deionized water at a concentration of 5 mg/mL and 10 mL solution of polyvinyl alcohol (PVA) in deionized water at a concentration of 1 mg/mL, and adjusting the pH value of the polymer solutions to 7 with 1 M NaOH aqueous solution, respectively. Preparing 10 mL solution of cellulose nanocrystal (CNC) in deionized water at a concentration of 0.12 mg/mL (2% of the total mass of HA and PVA), and treating with ultrasound for 40 minutes to uniformly disperse.

[0034] b. Preparation of the polymer composite: Mixing the prepared solutions at a volume ratio of 1:1:1 at a constant dripping rate of 5 mL/min, with the polymer composite solution needing to be sufficiently stirred in the mixing process so as to prevent the heterogeneous composite from being produced due to excessive local concentration.

[0035] c. Collection of the water-based adhesive: Standing the polymer composite solution after the composites are mixed to precipitate the hydrogel sufficiently, centrifugating to achieve dense hydrogel, and discarding the supernatant to obtain the applicable water-based adhesive, with the state of this water-based adhesive similar to that of the water-based adhesive in FIG. 1.

[0036] d. Bonding of samples: Removing a proper amount of the water-based adhesive to apply to a strip of wood 1 cm wide, and overlaying this strip of wood with another strip of wood in parallel under the guarantee that the bonding area is 1 cm1 cm and the requirement that the water-based adhesive should uniformly cover the entire bonding surface; with the sample fixed by an Elliot folder, the strip of wood can be bonded firmly after the water-based adhesive is dried, as shown in FIG. 4.

[0037] e. Applying these bonded strips of wood to the lap shear tester to test the bonding strength of this water-based adhesive. The F.sub.max measured in this example is 115 N, and the lap shear strength F.sub.max/S calculated in this example when the water-based adhesive is applied to the strip of wood is 11.5 MPa, as shown in FIG. 6.

Example 3

[0038] a. Preparation of a building solution: Preparing 10 mL solution of polymethacrylic acid (PMAA) in deionized water at a concentration of 1 mg/mL and 10 mL solution of polyethylene glycol (PEG) in deionized water at a concentration of 9 mg/mL and, after dissolving completely, adjusting the pH value of the polymer solutions to 1 with 1 M HCl aqueous solution. Preparing 10 mL solution of montmorillonite (MMT) in deionized water at a concentration of 0.4 mg/mL (4% of the total mass of PMAA and PVA), and treating with ultrasound for 60 minutes to uniformly disperse.

[0039] b. Preparation of the polymer composite: Mixing the prepared solutions at a volume ratio of 1:1:1 at a constant dripping rate of 1 mL/min, with the polymer composite solution needing to be sufficiently stirred in the mixing process so as to prevent the heterogeneous composite from being produced due to excessive local concentration.

[0040] c. Collection of the water-based adhesive: Standing the polymer composite solution after the composites are mixed to precipitate the hydrogel sufficiently, centrifugating to achieve dense hydrogel, and discarding the supernatant to obtain the applicable water-based adhesive, with the state of this water-based adhesive similar to that of the water-based adhesive in FIG. 1.

[0041] d. Bonding of samples: Removing a proper amount of the water-based adhesive to apply to a piece of glass 0.5 cm wide, and overlaying this piece of glass with another piece of glass in parallel under the guarantee that the bonding area is 0.5 cm0.5 cm and the requirement that the water-based adhesive should uniformly cover the entire bonding surface; with the sample fixed by an Elliot folder, the glass can be bonded firmly after the water-based adhesive is dried.

[0042] e. With the glass having no binding sites to have the lap shear test, the commercial cyanoacrylate glue is applied to both sides of the bonded glass sample to bond the pieces of glass and iron together, as shown in FIG. 5. Applying the bonded glass with fixed pieces of iron to the lap shear tester, and collecting the experimental data under the guarantee that the bond between the glass samples is broken, with the F.sub.max measured to be 172.5 N and the lap shear strength F.sub.max/S in this example when the water-based adhesive is applied to the surface of glass calculated to be 6.9 MPa, as shown in FIG. 6.

[0043] f. The surface of plastic materials can also be bonded with this water-based adhesive after being hydrophilically modified. As shown in FIG. 7, two hydrophilically-modified PTFE sheets (1 cm wide) are bonded with the water-based adhesive prepared by the present invention at the bonded area of 1 cm0.7 cm, with this bonding joint able to withstand a weigh about 1500 g after the water is evaporated.

[0044] These examples indicate that the method of preparing the water-based adhesive according to the present invention is simple, convenient and fast, uses materials that are safe and nonpoisonous, has a good bonding effect and a wide application range, and thus has a broad application prospect and high business value.