Product comprising a plastic container and a substance composition

Abstract

The present invention primarily relates to a product comprising or consisting of a plastic container (i) comprising or consisting of PE and/or PP and/or PET, and a specific composition (ii) contained in the container, wherein detrimental interactions between the container (i) and the composition (ii) contained therein are minimised.

Claims

1. A product comprising: (i) a container comprising at least one of polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET); and (ii) a composition contained in the container, the composition comprising at least one compound from group (A) and/or group (B); at least one compound from group (C); at least one compound from group (D); and optionally, at least one compound from group (E), wherein groups (A), (B), (C), (D), and (E) are defined below: (A) one or more compound(s) chosen from: hydrocarbon terpenes with an oxygen percentage of 0, with respect to the molar mass of the compound, methyl anthranilate derivates of formula (I) ##STR00077## with R.sub.1=H, methyl, benzylidene, (2,4-dimethylcyclohex-3-en-1-yl)methylene, 3-(4-tert-butylphenyl)-2-methyl-propylidene, 2,4-dimethylcyclohex-3-en-1-ylidene, [3-(1,3-benzodioxol-5-yl)-2-methyl-propylidene] or (7-hydroxy-3,7-dimethyl-octylidene), and with “N══R.sub.1”═“N═R.sub.1” or “NH—R.sub.1”; and phenolic derivatives of formula (II) ##STR00078## with R.sub.1=H, methoxy, ethoxy, or tert-butyl, R.sub.2/R.sub.4=H, R.sub.3═methyl, formyl, allyl, prop-1-enyl, hydroxy, or 3-oxobutyl, R.sub.5=H, or tert-butyl: (B) I one or more compound(s) chosen from: cyclic monoterpenes, chosen from bicyclic epoxy monoterpenes, monocyclic and bicyclic monoterpene alcohols and monoterpene ketones, and having formula (III): C.sub.10H.sub.xO (III), with X=14-18, and having a molar mass of 150-154 g/mol, methoxybenzene derivatives of formula (IV) ##STR00079## with R.sub.1═methyl, prop-1-enyl, allyl, 3-oxobutyl, acetoxymethyl, 2-methyl-3-oxo-butyl, or 3-(2-ethylhexoxy)-3-oxo-prop-1-enyl, 2-hydroxybenzoic acid derivatives of formula (V) ##STR00080## with R.sub.1═methyl, ethyl, amyl, isoamyl, hexyl, 2-ethyl hexyl, cyclohexyl, hex-3-enyl, 2-phenylethyl, or benzyl; benzoate derivatives of formula (VI) ##STR00081## with R.sub.1═methyl, ethyl, benzyl, or hexyl, R.sub.2=H, hydroxy, or ethoxycarbonyl, R.sub.3=H, or methyl, R.sub.4=H, or hydroxy, R.sub.5=H, R.sub.6=H, or methyl, oxomethylbenzene derivatives of formula (VII) ##STR00082## with R.sub.1=H, methyl, or phenyl, R.sub.2=H, methyl, isopropyl, or methoxy, 3-oxopropylbenzene derivatives of formula (VIII) ##STR00083## with R.sub.1=H, or methyl, R.sub.2=H, or methyl, R.sub.3=H, or methyl, R.sub.4=H, or methyl, R.sub.5=H, or methyl, R.sub.6=H, ethyl, or isopropyl, ligustral (mixture of (1R,2S)-2,4-dimethylcyclohex-3-ene-1-carbaldehyde and (18,2S)-2,4-dimethylcyclohex-3-ene-1-carbaldehyde), vertocitral (mixture of (1R,2S)-2,4-dimethylcyclohex-3-ene-1-carbaldehyde and (1S,2S)-2,4-dimethylcyclohex-3-ene-1-carbaldehyde), lyral (mixture of 4-(4-hydroxy-4-methyl-pentyl)cyclohex-3-ene-1-carbaldehyde and 3-(4-hydroxy-4-methyl-pentyl)cyclohex-3-ene-1-carbaldehyde), vertomugal (mixture of 4-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde and 3-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde), vernaldehyde (mixture of 3-isohexyl-1-methyl-cyclohex-3-ene-1-carbaldehyde and 4-isohexyl-1-methyl-cyclonex-3-ene-1-carbaldehyde), precyclemone B (mixture of 1-methyl-3-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde and 1-methyl-4-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde), styrene derivatives of formula (X) ##STR00084## with R.sub.1=H, methyl, or hydroxymethyl, R.sub.2=H, formyl, methoxycarbonyl, or benzyloxycarbonyl, acetals with a molar mass of >225 g/mol and calculated water solubility of <0.6 mg/L, and cyclic ethers with a calculated water solubility of <2.5 mg/L; (C) one or more compounds chosen from: terpene derivatives chosen from: cyclic diterpene ketones selected from methyl ionone alpha, methyl ionone beta, methyl ionone gamma, methyl ionone beta, dihydroionone beta, isoradeine, allylionone, damascenone alpha, damascenone beta, damascenone gamma, damascenone delta, damascone beta, damascone delta, acyclic monoterpene esters, cyclic monoterpene esters, sesquiterpene esters and alcohols, acyclic monoterpene aldehydes selected from 2,6,10-trimethylundec-9-enal (Farenal®), (5E)-2,6,10-trimethylundeca-5,9-dienal (profarenal®), hydroxyl citronellal, citral, eucalyptus oil citriodora, lemongrass oil cochin, and acyclic monoterpene alcohols selected from linalool, terpineol, citronellol, nerol, nerolidol, farnesol, hydroxyl citronellol, isoamyl alcohol, osyrol (7-methoxy-3,7-dimethyl-octan-2-ol), tetrahydro geraniol, tetrahydro muguol (mixture of tetrahydro myrcenol and tetrahydro linalool), tetrahydro myrcenol, ethyl linalool, isobornyl cyclohexanol, 1-[(1S,6S)-2,2,6-trimethylcyclohexyl]pentan-3-ol (madranol®), 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol (timberol®), thymol, mayol ((4-isopropylcyclohexyl)methanol), dihydro terpineol, menthol, menthol rac., pine oil, coriander oil, palmarosa oil: acetals with a molar mass of <225 g/mol and calculated water solubility of >0.6 mg/L, acids, alcohols chosen from phenylethyl alcohol, ambrinol ((2S 4aS)-2,5,5-trimethyl-1,3,4,4a,6,7-hexahydronaphthalen-2-ol), amber core (mixture of 1-[(1R,2R)-2-tert-butylcyclohexoxy]butan-2-ol, 1-[(1S,2R)-2-tert-butylcyclohexoxy]butan-2-ol and 2-(2-tert-butylcyclohexoxy)butan-1-ol), 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol (Branhmanol®), kohinool, mugetanol (mixture of cis-1-(4-isopropylcyclohexyl)ethanol and trans-1-(4-isopropylcyclohexyl)ethanol), polysantol ((E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol), alcohol C12, jasmol, sandalore (mixture of 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol and 6-(2,2,3-trimethylcyclopent-3-en-1-yl)nexan-3-ol), anisyl alcohol, hexanol, octanol, decanol, benzyl alcohol, butyl cyclohexanol para-tert, decenol-9, ebanol (mixture of (E,2S,3R)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol and (E,2R,3R)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol), florosa, furaneol, cis-3-hexenol, 2,2-dimethyl-3-(m-tolyl)propan-1-ol (Majantol®), methyl methoxy butanol-3,3, muguetalcohol (2,2-dimethyl-3-phenyl-propan-1-ol), phenoxanol (3-methyl-5-phenyl-pentan-1-ol), phenoxyethyl alcohol, phenyl dimethyl carbinol, phenylethyl methylethyl carbinol, phenylpropyl alcohol, (2-methyl-5-phenyl-pentan-1-ol) (Rosaphen®), sandal mysore core ((E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol), (E)-2-ethyl-4-(2 2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol (San-Dranol®), styralyl alcohol, 4-isopentylcyclohexanol (Symrose®), dihydro eugenol, propenyl quaethol, cresol para, ambrinolepoxide ((1aR,4aS,7S,8aS)-4,4,7-trimethyl-2,3,4a,5,6,8-hexahydro-1aH-naphtho[1,8a-bloxiren-7-ol), one or more of ethers and cyclic ethers with a calculated water solubility of >2.5 mg/L, aldehydes selected from aldehyde C12 MNA, neocyclo citral, aldehyde C11 MOA, hexyl cinnamic aldehyde alpha, cyclomyral, amyl cinnamic aldehyde, 2,6-dimethylhept-5-enal (Melonal®), nonanal, isononyl aldehyde S, octanal, aldehyde C11 iso, intreleven aldehyde (mixture of undec-10-enal, 9-undecenal and 8-undecenal), lilial(3-(4-tert-butylohenyl)-2-methyl-propanal), hexanal, heptanal, silvial (3-(4-isobutylphenyl)-2-methyl-propanal), 2-trans-hexenal, scentenal (octahydro-5-methoxy-4,7-methano-1H-indene-2-carboxaldehyde), phenylacetaldehyde, mandarin aldehyde (2E-dodecenal), esters chosen from pyroprunat ((2-cyclopentylcyclopentyl) (E)-but-2-enoate), hercolyn D-E (mixture of methyl 7-isopropyl-1,4a-dimethyl-2,3,4,5,6,7,8,9,10,10a-decahydrophenanthrene-1-carboxylate and methyl 7-isopropyl-1,4a-dimethyl-2,3,4,9,10,10a-hexahydrophenanthrene-1-carboxylate), fruitate, cyclabute (3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-5-yl 2-methyl propanoate), poivrol (mixture of methyl (1S,4R,5R)-4-isopropyl-1-methyl-bicyclo[2.2.2]oct-2-ene-5-carboxylate, methyl (1S,4R,5S)-4-isopropyl-1-methyl-bicyclo[2.2.2]oct-2-ene-5-carboxylate, methyl (1R,2S,4R)-4-isopropyl-1-methyl-bicyclo[2.2.2]oct-5-ene-2-carboxylate and methyl (1R,2R,4R)-4-isopropyl-1-methyl-bicyclo[2.2.2]oct-5-ene-2-carboxylate), guaiyl acetate, herbyl propionate (hexahydro-4,7-methanoinden-5(or 6)-yl propionate), vetiveryl acetate, nopyl acetate, hydroherbaflorat, herbaflorat (hexahydro-4,7-methanoinden-(5 and 6)-yl acetate), ethyl cinnamate, phenylethyl cinnamate, isoeugenyl methyl ether, isoeugenyl acetate, eugenyl acetate, ethyl benzoate, isobutyl salicylate, prenyl salicylate, dimethyl benzyl carbonyl butyrate, phenylethyl isovalerate, benzyl butyrate, benzyl isobutyrate, dimethyl benzyl carbonyl acetate, phenylethyl isobutyrate, benzyl propionate, phenylethyl acetate, (1,3-dimethyl-3-phenyl-butyl) acetate (Vetikolaceate®), benzyl acetate, ethyl phenyl acetate, methyl phenyl acetate, styralyl acetate, phenylethyl phenylacetate, benzyl formiate, 2-phenoxyethyl 2-methylpropanoate (Phenirate®), benzyl phenylacetate, aldehyde C16 so-called, allyl phenoxy acetate, cresyl phenyl acetate para, rosacetate, hexyl caproate, ethyl caprinate, decyl acetate, ethyl caprylate, hexyl butyrate, hexyl isobutyrate, ethyl heptoate, isoamyl butyrate, butyl butyrate, allyl heptoate, ethyl caproate, manzanate, neononyl acetate, ethyl methyl butyrate-2, frutinat, isopentyrate, ethyl butyrate, ethyl isovalerate, amyl acetate, hexyl acetate, ethyl isobutyrate, butyl acetate, isobutyl acetate, ethyl propionate, cis-3-hexenylacetate, [(Z)-hex-3-enyl]methyl carbonate (Leafovert®), prenyl acetate, methyl octin carbonate, allyl amyl glycolate, ethyl acetate, butyl butyryl lactate, diethylmalonate, ethyl acetoacetate, (3-hydroxy-2,2,4-trimethyl-pentyl) 2-methylpropanoate (Symfresh® NX), allyl cyclohexyl propionate, givescone (mixture of ethyl 2,3,6,6-tetramethylcyclonex-2-ene-1-carboxylate and ethyl 2-ethyl-6,6-dimethyl-cyclohex-2-ene-1-carboxylate), mintonat (mixture of [(1S,5S)-3,3,5-trimethylcyclohexyl]acetate and [(1R,5S)-3,3,5-trimethylcyclohexyl]acetate), oryclon ((4-tert-butylcyclohexyl) acetate), aphermate (1-(3,3-dimethylcyclohexyl)ethyl formate), cyclohexyl ethyl acetate, datilat (1-cyclohexylethyl (E)-but-2-enoate), helvetolide (2-[1-(3,3-dimethylcyclohexyl)ethoxy]-2-methyl-propyl]propanoate), myraldyl acetate (mixture of [38-(4-methylpent-3-enyl)cyclohex-3-en-1-yl]methyl acetate and [4-(4-methylpent-3-enyl)cyclohex-3-en-1-yl]methyl acetate), cyclohexyl acetate, allyl 2-(cyclohexoxy)acetate (Cyclogalbanate®), jasmopyrane ((3-pentyltetrahydropyran-4-yl) acetate), jessemal ((3-butyl tetrahydro-5-methyl-2H-pyran-4-yl) acetate, ethylene brassylate (1,4-dioxacyclohneptadecane-5,17-dione), ethylene dodecanedioate arova N, ethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate (Fragolane®), hedione (mixture of methyl 2-[(1S,2S)-3-oxo-2-pentyl-cyclopentyllacetate and methyl 2-[(1S,2R)-3-oxo-2-pentyl-cyclopentyllacetate, jasmaprunat (ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate), jasmopol AC 1300 (methyl 2-hexyl-3-oxo-cyclopentanecarboxylate), maltol isobutyrate, triethyl citrate, ethers and cyclic ethers with a calculated water solubility of >2.5 mg/L selected from the group consisting of anther, rose oxide HC (mixture of (2R,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran and (2S,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran), rose oxide L (mixture of (2R,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran and (2S,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran), rose oxide inactive (mixture of (2R,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran and (2S,4S)-4-methyl-2-(2-methylprop-1-enyl)tetrahydropyran), diphenyl oxide, phenylethyl methyl ether, dibenzyl ether, kephalis (4-(1-ethoxyvinyl)-3,3,5,5-tetramethyl-cyclohexanone), linalool oxide, dowanol DPM (3-(3-methoxypropoxy)propan-1-ol), heterocyclic compounds, ketones selected from cyclohexadecanone (Isomuscone®), vertofix, veloutone, muscenone, 4-[(3,3-dimethylnorbornan-2-yl)methyl]-2-methyl-cyclohexanone (Aldron®), isolongifolanon (octahydrotetramethyl methanoazulenone), (8E)-cyclohexadec-8-en-1-one (Globanone®), 2,4,4,7-tetramethyloct-6-en-3-one (Claritone®), iso e super (mixture of 1-[2R,3R)-2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yllethanone, 1-(2,3,8,8-tetramethyl-1,3,5,6,7,8a-hexahydronaphthalen-2-yllethanone and 1-[(2S 3S)-2,3,8,8-tetramethyl-1,3,5,6,7 8a-hexahydronaphthalen-2-yllethanone), (8E)-cyclonexadec-8-en-1-one (Aurelione®), projasmone P (2-heptylcyclopentanone), frescomenthe (2-sec-butylcyclohexanone), dynascone (mixture of 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one, 1-(3,3-dimethylcyclohexen-1-yl)pent-4-en-1-one and (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one), galbascone (1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one), undecanone-2, kKoavone (mixture of (E)-3,4,5,6,6-pentamethylhept-4-en-2-one, 3,5,6,6-tetramethyl-4-methylene-heptan-2-one and (E)-3,4,5,6,6-pentamethylhept-3-en-2-one), tonalide (1-(1,1,2,4,4,7-hexamethyltetralin-6-yl)ethanone), nerolione (1-(3-methylbenzofuran-2-yl)ethanone), octanone-2, cashmeran (1,1,2,3,3-pentamethyl-2,5,6,7-tetrahydroinden-4-one), orivone (4-(1,1-dimethylpropyl)cyclohexanone), azarbre (mixture of 3,5-diethyl-2,5-dimethyl-cyclohex-2-en-1-one and 3,5-diethyl-5,6-dimethyl-cyclohex-2-en-1-one), methyl heptenone-6,5,2, dihydro jasmine (3-methyl-2-pentyl-cyclopent-2-en-1-one), jasmine cis (3-methyl-2-[(Z)-pent-2-enyl]cyclopent-2-en-1-one), acetanisole, calone 1951 (7-methyl-1,5-benzodioxepin-3-one), acetyl methyl carbinol, crysolide (1-(6-tert-butyl-1,1-dimethyl-indan-4-yl)ethanone), ethyl maltol, maltol, methyl cyclopentenolone-3,2,2, lactones, and nitriles; (D) water and/or one or more solvent(s) chosen from ethanol, dipropylene glycol (DPG), diethylphtalate (DEP), propylene glycol (PG), isopropylmyristate (IPM), isopropylpalmitate (IPP) triethylcitrate (TEC), 2-propanol, triacetin (TRI), 1,2-propanediol, 1,3-propanediol, propanetriol, 1,2-pentanediol (Hydrolite®-5), 1,2-hexanediol (Hydrolite®-6), 1,2-octanediol (Hydrolite®-8), 1,2-decanediol (SymClariol®), dodecanol, 4-hydroxy-acetophenone (SymSave® H), glycerin, butylenes glycol, pentylene glycol, hexylene glycol, decylene glycol, propylene carbonate, butylenes carbonate, glycerin carbonate, 2-benzylheptanol, laurylalcohol, trimethyl-hydroxypentyl-isobutyrat, glycerylcaprylate, ethylhexylglycerin, benzylbenzoate (BB), Isoparaffine, glycol ether, and dowanol: and (E) optionally, one or more surface active compound(s) chosen from alkyl carboxylate, alkyl sulfonate, alkyl sulphate, alcohol polyglycol ether sulfate, quaternary ammonium cations, quaternary ammonium ester, alcohol polyglycol ether, N-(Acylaminoalkyl)-betaine, polyethylene glycol alkyl ether, alkyl benzene sulfonate, TEA-esterquat: wherein the total amount of compound(s) of group (A), if present, is 0.5 wt. % or less; and the total amount of compound(s) of group (B), if present, is less than 10 wt. %; and wherein the total amount of compound(s) of group (C) is 20 wt. % or less, in each case based on the total amount of the composition; and the composition contained in the container does not cause a visual and/or weight change to packaging consisting of PE, PP, or PET after 4 weeks at 40° C.

2. The product of claim 1, wherein the acetals with a molar mass of <225 g/mol and calculated water solubility of >0.6 mg/L are selected from 2-isobutyl-4-vinyl-1,3-dioxolane, 6,6-dimethoxy-2,5,5-trimethyl-hex-2-ene (Amarocit®), hyacinth body, floropal, magnolan, (2R,4S)-2-methyl-4-phenyl-1,3-dioxolane (Jacinthaflor®), phenylacetaldehyde dimethyl acetal, 4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine (Indoflor®), citral diethyl acetal, hydroxyl citronellal dimetacetal, phenylacetaldehyde glyceryl acet, heliotropin, and helional.

3. The product of claim 1, wherein the hydrocarbon terpenes with an oxygen percentage of 0, with respect to the molar mass of the compound, are selected from cedrene ((1S,2R,5S)-2,6,6,8-tetramethyltricyclo[5.3.1.01.5]undec-8-ene), caryophyllene, ginger oil chinese, gurjun balsam oil, gurjun balsam siam, limonene (4-isopropenyl-1-methyl-cyclohexene), terpinene, phellandrene, pepper black oil, pine needle oil chinese, grapefruit oil, tangerine cravo oil brazil, mandarin oil ital., orange oil brazil, lime oil terpenes, lemon oil terpenes, elemi oil, cymene para, citrylal, pinene alpha, carene delta-3, camphene, pinene beta, dipentene, turpentine oil portug., and myrcene.

4. The product of claim 1, wherein the methyl anthranilate derivates of formula (I) are selected from methyl anthranilate, dimethylanthranilate, vertosine (methyl 2-[(E)-(2,4-dimethylcyclohex-3-en-1-yl)methyleneamino]benzoate), verdantiol (methyl 2-[(E)-[3-(4-tert-butylphenyl)-2-methyl-propylidene]amino]benzoate), aurantiol (methyl 2-[(E)-(7-hydroxy-3,7-dimethyl-octylidene)amino]benzoate), amandolene (methyl N-benzylideneanthranilate), meaverte (methyl 2-[(2,4-dimethylcyclohex-3-en-1-ylidene)methylamino]benzoate), and heliosine (methyl 2-[(E)[3-(1,3-benzodioxol-5-yl)-2-methyl-propylidene]amino]benzoate).

5. The product of claim 1, wherein the phenolic derivatives of formula (II) are selected from ethyl vanillin, eugenol, vanillin, isoeugenol, BHT ionol, 4-(4-hydroxyphenyl)butan-2-one (Frambinon®), essential oils selected from the group consisting of clove leaves oil, cinnamon leaf oil, and cinnamon leaf oil discolored.

6. The product of claim 1, wherein the cyclic monoterpenes of formula (III) are selected from fenchol, isoborneol, borneol, eucalyptol, 1,4-cineol, eucalyptus oil, camphor, menthone, isomenthone, carvone, and spearmint oil 65% americ. native.

7. The product of claim 1, wherein the methoxybenzene derivatives of formula (IV) are selected from cresyl methyl ether para, estragole, 4-(4-methoxyphenyl)butan-2-one (Frambinon® methyl ether), anisyl acetate, canthoxal (3-(4-methoxyphenyl)-2-methyl-propanal), and 2-ethylhexyl (E)-3-(4-methoxyphenyl)prop-2-enoate (Neo Heliopan® AV).

8. The product of claim 1, wherein the 2-hydroxybenzoic acid derivatives of formula (V) are selected from methyl salicylate, ethyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, 2-ethyl hexyl salicylate, and 3-hexenyl salicylate.

9. The product of claim 1, wherein the benzoate derivatives of formula (VI) are selected from methyl benzoate, evernyl (methyl 2,4-dihydroxy-3,6-dimethyl-benzoate), benzyl benzoate, hexyl benzoate, diethylphtalate.

10. The product of claim 1, wherein the oxomethylbenzene derivatives of formula (VII) are selected from benzaldehyde, tolylaldehyde para, cuminic aldehyde, acetophenone, methyl acetophenone, benzophenone, and anisic aldehyde.

11. The product of claim 1, wherein the 3-oxopropylbenzene derivatives of formula (VIII) are selected from florazon (mixture of 3-(4-ethylphenyl)-2,2-dimethyl-propanal and 3-(2-ethylphenyl)-2,2-dimethyl-propanal), floralozone (mixture of 3-(4-ethylphenyl)-2,2-dimethyl-propanal and 3-(2-ethylphenyl)-2,2-dimethyl-propanal), 4-methyl-4-phenyl-pentan-2-one (Vetikon®) and benzylacetone, cyclamen aldehyde (3-(4-isopropylphenyl)-2-methyl-propanal), and florhydral (3-(3-isopropylphenyl)butanal).

12. The product of claim 1, wherein the styrene derivatives of formula (X) are selected from the group consisting of styrene, methyl cinnamic aldehyde, methyl cinnamate, benzyl cinnamate, and cinnamic alcohol.

13. The product of claim 1, wherein the one or more solvent(s) are selected from the group consisting of ethanol, DPG, PG, IPM, TEC, 1,2-propanediol, 1,3-propanediol, propanetriol, 1,2-pentanediol (Hydrolite®-5), 1,2-hexanediol (Hydrolite®-6), 1,2-octanediol (Hydrolite®-8), 1,2-decanediol (SymClariol®), dodecanol, 4-hydroxy-acetophenone (SymSave® H), glycerine, and isopar-L.

14. The product of claim 1, wherein the one or more surface active compound(s) are selected from the group consisting of lauryl ether sulfate, betaine, lauryl alkyl sulfate, PEG hydrogenated castor oil, laureth-5, laureth-6, laureth-7, Dialkylesterammoniumethosulfate, sodium stearate, sodium palmitate, polyethylene glycol, zinc stearate, sodium caprylate, lauric acid, Isopar-L, sodium dodecyl benzene sulfonate, and Dihydrogenated Tallowethyl Hydroxyethylmonium Methosulfate.

15. The product of claim 1, wherein the container comprises PE and/or PP.

16. The product of claim 1, wherein the container is in the form of a wrapping, an encasement, a packaging, a shell, a coating, or an envelope.

17. The product of claim 1, wherein the total amount of compound(s) of group (A), if present, is in the range of from 0.05 wt. % to 0.5 wt. % and the total amount of compound(s) of group (B), if present, is in the range of from 0.01 wt. % to less than 10 wt. %, in each case based on the total amount of the composition.

18. The product of claim 1, wherein the total amount of compound(s) of group (A), if present, is in the range of from 0.05 wt. % to 0.5 wt. % and the total amount of compound(s) of group (B), if present, is in the range of from 0.01 wt. % to 1.25 wt. %, in each case based on the total amount of the composition.

19. The product of claim 1, wherein the total amount of water according to component (D), if present, is in the range of from 35 wt. % to 99 wt. %, based on the total amount of the composition.

20. A method for producing a product according to claim 1 comprising: (I) providing a container (i) comprising at least one of polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET); (II) providing a composition (ii) of claim 1; (III) filling the container (i) with the composition (ii); (IV) optionally, adding one or more further substances into the container (i), and (V) optionally, closing and/or sealing the container (i).

Description

EXAMPLES

Example 1

(1) For the determination of the category and the behavior of the compounds, the influence of each compounds on the tree different plastic types LD-PE, PP and PET-G were investigated.

(2) Plastic Items:

(3) PET-G Polyethylene terephthalate glycol (Vivak, Rocholl GmbH) PP Polypropylen (Simona DWST, Rocholl GmbH) LD-PE Polyethylen with low density (Simona PEW, Rocholl GmbH)
Test Method:

(4) Each plastic item of 13 mm×43 mm×2 mm was weighted and stored for 4 weeks at 40° C. in a 10 mL glass jar filled with a 10% solution of the single test compound in DPG. After the storage, the plastic item was taken out of the jar and carefully rinsed by dipping in ethanol. The rinsed plastic item was dabbed gently with a paper towel and immediately weighted. The weight of the plastic item before the storage and after the storage was compared and the percentage weight increase or decrease determined.

(5) Furthermore the appearance of the plastic item was evaluated. The different evaluation qualities of the plastic items were classified as follows:

(6) TABLE-US-00001 evaluation quality appearance of the plastic item no change no changes of the plastic item observed colour change plastic items was yellow or brown opaque plastic items was opaque form change plastic item was crooked texture change plastic item was sticky, soaked or porous

(7) Category A compounds showed a weight increase of 5 wt. % and more, and/or colour changes after 4 weeks at 40° C.

(8) Category B compounds showed a weight increase in a range of from 2 wt. % to less than 5 wt. % and/or other changes of the appearance, like texture changes, form changes and opaque.

(9) Category C compounds showed a weight increase of less than 2 wt. % and no changes of the appearance.

(10) Table 1 below shows the results of several compounds and their assigned categories A and B, while the results of several compounds of category C are shown in table 2 below:

(11) TABLE-US-00002 TABLE 1 Compound results of categories A and B % Weight decrease/increase Appearance of the plastic after 4 weeks at 40° C. after 4 weeks LD- PET LD- PET Category PE PP G PE PP G Name A 10.2 2.4 −0.2 no change no change no change CEDRENE A 5.5 5.6 0.3 no change form opaque PHELLANDRENE L change A 6 5.7 0.9 no change form opaque LIMONENE D PURE change A 5.2 5.6 0 no change texture opaque MYRCENE change A 1.5 0.3 −0.2 colour colour colour VERTOSINE change change change A 0.1 0.1 0.1 colour no change no change EUGENOL change, form change B 3.1 1.7 0 no change no change no change EUCALYPTOL B 4.4 2.5 3.6 texture texture texture STYRENE change change change B 1.8 2 2.1 no change no change opaque CRESYL METHYL ETHER PARA B 2 1.9 1 no change form opaque HEXYL SALICYLATE change B 0.6 0.4 1 no change no change opaque BENZYL BENZOATE M B 0.6 0.5 1 form no change opaque CUMINIC change ALDEHYDE B 0.2 0.4 1.3 form no change opaque BENZYL ACETONE change B 2 1.2 0 no change no change no change VERNALDEHYDE B 4.5 1 −0.2 no change no change no change AMBERWOOD ® F B 4.1 0.4 −0.3 no change no change no change YSAMBER ® K B 2.9 0.4 −0.3 no change no change no change AMBROXIDE

(12) TABLE-US-00003 TABLE 2 Compound results of category C % Weight decrease/increase Appearance of the plastic after weeks at 40° C. after 4 weeks Category LD-PE PP PET G LD-PE PP PET G Name C 1.2 0.6 0 no change no change no change DYNASCONE C 1.5 0.3 −0.2 no change no change no change ISO E SUPER C 1.7 0.2 −0.2 no change no change no change ISOLONGIFOLANON C 1.5 0.9 0 no change no change no change CLARITONE ® C 1.4 0.2 −0.2 no change no change no change AURELIONE ® C 1.6 0.3 0 no change no change no change GLOBANONE ® C 0.5 0.2 −0.2 no change no change no change ISOBUTYL QUINOLINE DL C 1.2 1.5 1.4 no change no change no change PHENYLETHYL METHYL ETHER C 1.5 1.7 0.7 no change no change no change 2-ISOBUTYL-4-VINYL-1,3- DIOXOLANE C 0.6 0.2 −0.2 no change no change no change DAMASCENONE C 1 1 0 no change no change no change LINALYL ACETATE C 0.1 0.2 −0.2 no change no change no change LINALOOL C 0 0.1 −0.2 no change no change no change CITRONELLOL 950 C 0 0.1 −0.2 no change no change no change GERANIOL SUPER C 0 0.1 −0.3 no change no change no change MAYOL C 1.1 0.8 0.1 no change no change no change HYACINTH BODY C 0.9 0.3 0 no change no change no change MAGNOLAN C 0.8 0.5 0.5 no change no change no change JACINTHAFLOR ® C 0.4 0.3 0.4 no change no change no change INDOFLOR ® C 0.2 0.1 −0.2 no change no change no change CITRAL DIETHYL ACETAL C 0.1 0.2 0.6 no change no change no change HELIONAL C 0 0.1 −0.2 no change no change no change PHENYLACETIC ACID C 0.2 0.1 −0.3 no change no change no change BRAHMANOL ® C 0.2 0.2 −0.4 no change no change no change MUGETANOL C 0 0.1 −0.3 no change no change no change ALCOHOL C10 C 0 0 −0.3 no change no change no change FURANEOL C 0.1 0 −0.3 no change no change no change SANDALORE ® C 0 0 0 no change no change no change MAJANTOL ® C 0 0.1 −0.3 no change no change no change SYMROSE ® C 0.6 0.5 −0.2 no change no change no change ALDEHYDE C11 ISO C 0.4 0.4 0.3 no change no change no change STYRALYL ACETATE C 0 0 −0.3 no change no change no change SYMFRESH ® NX C 0.5 0.5 0.3 no change no change no change CYCLOGALBANAT ® C 1.1 1.8 0.6 no change no change no change ETHYL BUTYRATE C 1.4 0.4 −0.3 no change no change no change AGRUMEX HC C 0.2 0.1 0 no change no change no change ETHYLENE BRASSYLATE C 1.2 1.2 0 no change no change no change UNDECANONE-2 C 1.1 0.3 −0.3 no change no change no change KOAVONE C 0.9 0.2 −0.2 no change no change no change TONALIDE C 0.8 0.3 0.7 no change no change no change NEROLIONE C 0 0 −0.4 no change no change no change MALTOL C 1.8 0.3 −0.2 no change no change no change AMBRETTOLIDE C 0.5 0.2 0 no change no change no change CANTRYL ® C 0.8 0.8 0 no change no change no change OZONIL

Example 2

Perfume Composition A

(13) TABLE-US-00004 TABLE 3 Perfume composition A Water Mass Solubility Molar calc. [g/ Mol. [mg/L] Name IUPAC name mol] formula Mol. structure g/100 g 0.1504 CEDRENE (1S,2R,5S)- 2,6,6,8- Tetramethyltricyclo [5.3.1.01.5] undec-8-ene 204 C.sub.15H.sub.24 0 0.0006 2.862 PHELLAN- DRENEL 5-isopropyl-2- methyl-cyclohexa- 1,3-diene 136 C.sub.10H.sub.16 0.0619 3.2 LIMONENE 4-isopropenyl-1- methyl- cyclohexene 136 C.sub.10H.sub.16 0.1238 6.9 MYRCENE 7-methyl-3- methylene-octa- 1,6-diene 136 C.sub.10H.sub.16 0.0619 1.3 VERTOSINE methyl 2-[(E)-(2,4- dimethylcyclohex- 3-en-1-yl) methyleneamino] benzoate 271 C.sub.17H.sub.21NO.sub.2 0.0001 754 EUGENOL 4-allyl-2- methoxy-phenol 164 C.sub.10H.sub.12O.sub.2 0.0309 532.4 EUCALYPTOL 2,2,4-trimethyl-3- oxabicyclo[2.2.2] octane 154 C.sub.10H.sub.18O 0.9283 343.7 STYRENE styrene 104 C.sub.8H.sub.8 0.0006 527.1 CRESYL METHYL ETHER PARA 1-methoxy-4- methyl-benzene 122 C.sub.8H.sub.10O 0.0006 6.1 HEXYL SALICYLATE hexyl 2- hydroxybenzoate 222 C.sub.13H.sub.18O.sub.3 1.8566 15.4 BENZYL BENZOATE M benzyl benzoate 212 C.sub.14H.sub.12O.sub.2 0 0.0062 152.8 CUMINIC ALDEHYDE 4-isopropyl- benzaldehyde 148 C.sub.10H.sub.12O 0.0062 1625 BENZYL ACETONE 4-phenylbutan-2- one 148 C.sub.10H.sub.12O 0.0062 1.2 VERNALDE- HYDE 4-isohexyl-1- methyl-cyclohex-3- ene-1-carbaldehyde 208 C.sub.14H.sub.24O 0.3094 0.5 AMBER- WOOD ® F ethoxymethoxy- cyclododecane 242 C.sub.15H.sub.30O.sub.2 0.0619 0.1 YSAMBER ® K 2′,2′,8′,8′- tetramethylspiro (1,3-dioxolane- 2,10′-octahydro- 1H- 2,4a-methan- onapthalene) 264 C.sub.17H.sub.28O.sub.2 0.0006 2.4 AMBROXIDE (3aS,5aR,9aR)- 3a,6,6,9a- tetramethyl- 2,4,5,5a,7,8,9,9b- octahydro-1H- benzo[e] benzofuran 236 C.sub.16H.sub.28O 0.0062 7.6 DYNASCONE 1-(5,5- dimethylcyclohexen- 1-yl)pent-4-en-1-one 192 C.sub.13H.sub.20O 0.3094 1.1 ISO E SUPER 1-[(2R,3R)- 2,3,8,8- tetramethyl- 1,3,4,5,6,7- hexahydro- naphthalen- 2-yl]ethanone 234 C.sub.16H.sub.26O 3.0943 21.1 ISOLONGI- FOLANON 2,2,8,8- tetramethyl- octahydro-1H- 2,4a- methanonapthalene- 10-one 220 C.sub.15H.sub.24O 0.0619 28.1 CLARITONE ® 2,4,4,7- tetramethyloct-6- en-3-one 182 C.sub.12H.sub.22O 0 0.0619 0.3 AURELIONE ® (8E)-cyclohexadec- 8-en-1-one 236 C.sub.16H.sub.28O 0.9283 0.3 GLOBANONE ® (8E)-cyclohexadec- 8-en-1-one 236 C.sub.16H.sub.28O 0.9283 16.7 ISOBUTYL QUINOLINE DL 7-isobutylquinoline 185 C.sub.13H.sub.15N 0.0006 1008 PHENYLETHYL METHYL ETHER 2- methoxyethyl- benzene 136 C.sub.9H.sub.12O 1.2377 800.3 2-ISOBUTYL- 4-VINYL-1,3- DIOXOLANE 2-isobutyl-4-vinyl- 1,3-dioxolane 156 C.sub.9H.sub.16O.sub.2 0.6189 12.48 DAMASCENONE (E)-1-(2,6,6- trimethylcyclohexa- 1,3-dien-1-yl)but- 2-en-1-one 190 C.sub.13H.sub.18O 3.0943 0.5 AMBER- WOOD ® F ethoxymethoxy- cyclododecane 242 C.sub.15H.sub.30O.sub.2 0.0619 8.2 LINALYL ACETATE (1,5-dimethyl-1- vinyl-hex-4-enyl) acetate 196 C.sub.12H.sub.20O.sub.2 9.2829 683.7 LINALOOL 3,7-dimethylocta- 1,6-dien-3-ol 154 C.sub.10H.sub.18O 6.1886 211.8 CITRONELLOL 950 3,7-dimethyloct-6- en-1-ol 156 C.sub.10H.sub.20O 0 3.0943 255.8 GERANIOL SUPER (2E)-3,7- dimethylocta-2,6- dien-1-ol 154 C.sub.10H.sub.18O 15.4714 258.2 MAYOL (4-isopropyl- cyclohexyl) methanol 156 C.sub.10H.sub.20O 0.0619 152.3 HYACINTH BODY 2-(1-ethoxyethoxy) ethylbenzene 194 C.sub.12H.sub.18O.sub.2 0.0619 217.1 MAGNOLAN (2R,4R,4aS,9bR)- 2,4-dimethyl- 4,4a,5,9b- tetrahydroindeno [1,2-d][1,3]dioxine 204 C.sub.13H.sub.16O.sub.2 0.0062 2119 JACINTHA- FLOR ® (2R,4S)-2-methyl- 4-phenyl-1,3- dioxolane 164 C.sub.10H.sub.12O.sub.2 0.0006 1549 INDOFLOR ® 4,4a,5,9b- tetrahydroindeno [1,2-d][1,3]dioxine 176 C.sub.11H.sub.12O.sub.2 0.0006 2.5 CITRAL DIETHYL ACETAL (2E)-1,1-diethoxy- 3,7-dimethyl-octa- 2,6-diene 226 C.sub.14H.sub.26O.sub.2 0.0619 342.6 HELIONAL 3-(1,3-benzodioxol- 5-yl)-2-methyl- propanal 192 C.sub.11H.sub.12O.sub.3 0.0619 13500 PHENYLACETIC ACID 2-phenylacetic acid 136 C.sub.8H.sub.8O.sub.2 6.1886 13.5 BRAHMANOL ® 2-methyl-4-(2,2,3- trimethylcyclopent- 3-en-1-yl)butan-1-ol 196 C.sub.13H.sub.24O 0 0.0062 97.8 MUGETANOL 1-(4- isopropylcyclohexyl) ethanol 170 C.sub.11H.sub.22O 0.0619 28.2 ALCOHOL C10 decan-1-ol 158 C.sub.10H.sub.22O 0.3094 18500 FURANEOL 4-hydroxy-2,5- dimethyl-furan-3- one 128 C.sub.6H.sub.8O.sub.3 0.062 5 SANDALORE ® 3-methyl-5-(2,2,3- trimethylcyclopent- 3-en-1-yl)pentan- 2-ol 210 C.sub.14H.sub.26O 0.0062 195.3 MAJANTOL ® 2,2-dimethyl-3- (m-tolyl)propan-1- ol 178 C12H18O 0.0619 84.67 SYMROSE ® 4-isopentylcyclo- hexanol 170 C.sub.11H.sub.22O 0.9283 22.3 ALDEHYDE C11 ISO (E)-undec-9-enal 168 C.sub.11H.sub.20O 9.2829 481.1 STYRALYL ACETATE 1-phenylethyl acetate 164 C.sub.10H.sub.12O.sub.2 6.1886 321.5 SYMFRESH ® NX (3-hydroxy-2,2,4- trimethyl-pentyl) 2-methylpropanoate 216 C.sub.12H.sub.24O.sub.3 3.0943 211.1 CYCLO- GALBANAT ® allyl 2- (cyclohexoxy) acetate 198 C.sub.11H.sub.18O.sub.3 0 0.0619 2745 ETHYL BUTYRATE ethyl butanoate 116 C.sub.6H.sub.12O.sub.2 1.8566 7.5 AGRUMEX HC [(1S,2S)-2-tert- butylcyclohexyl] acetate 198 C.sub.12H.sub.22O.sub.2 9.2829 0.1 ETHYLENE BRASSYLATE 1,4- dioxacyclo- heptadecane-5,17- dione 270 C.sub.15H.sub.26O.sub.4 3.0943 19.7 UNDECANONE- 2 undecan-2-one 170 C.sub.11H.sub.22O 0.0619 14.3 KOAVONE (E)-3,4,5,6,6- pentamethylhept-3- en-2-one 182 C.sub.12H.sub.22O 0.0619 0.1 TONALIDE 1-(1,1,2,4,4,7- hexamethyltetralin- 6-yl)ethanone 258 C.sub.18H.sub.26O 0.0006 414.7 NEROLIONE 1-(3- methylbenzofuran-2- yl)ethanone 174 C.sub.11H.sub.10O.sub.2 0.9283 79800 MALTOL 3-hydroxy-2-methyl- pyran-4-one 126 C.sub.6H.sub.6O.sub.3 0.0062 0.6 AMBRETTOLIDE (10E)-1- oxacycloheptadec- 10-en-2-one 252 C.sub.16H.sub.28O.sub.2 0.9283 59.8 CANTRYL ® 2-(2,2,3- trimethylcyclopent- 3-en-1-yl) acetonitrile 149 C.sub.10H.sub.15N 0 0.0062 1.3 OZONIL (E)-tridec-2- enenitrile 193 C.sub.13H.sub.23N 0.0062 — DPG — 134 C.sub.5H.sub.14O.sub.3 — 9.2829 7.37 IPM Isopropyl tetradecanoate 270 C.sub.5H.sub.12O.sub.2 0.0619 1.17 TEC ethyl citrate 276 C.sub.12H.sub.20O.sub.7 0.681 — Pentanediol 1,2-pentanediol 104 C.sub.5H.sub.12O.sub.2 0.0309 — Symsave H 4- hydroxy- acetophenone 136 C.sub.5H.sub.12O.sub.2 0.0062 — Propanediol 1,2-Propanediol  76 C.sub.3H.sub.8O.sub.2 0.0309 Sum 100.0000

Example 3

Softener

(14) TABLE-US-00005 Material Manufacturer Chemical name wt.-% Deoinised water Water 72.4 Rewoquat WE Evonic Goldschmidt Dialkylesterammon- 16.6 18 GmbH iumethosulfate Mergal K9N Honeywell Austria 5-Chloro-2-methyl-3- 0.10 GmbH (2H)-isothiazolone and 2-methyl-3-(2H)- isothiazolone Dow Corning Dow Corning Polydimethyl siloxane 0.30 1520 Antifoam GmbH, Germany Magnesium — Magnesium chloride 10.00 chloride 1% solution solution Perfume Symrise — 0.60 composition A

Example 4

Soap

(15) TABLE-US-00006 Material Manufacturer Chemical name wt.-% Deionised water Water 2.0 Soap Base Mix diverse Sodium tallowates/ 96.95 palmitates Titandioxid Kronos Titan Titanium Dioxide 1.0 GmbH, Deutschland Perfume Symrise 1.5 composition A

Example 5

Powder Detergent

(16) TABLE-US-00007 Material Manufacturer Chemical name wt.-% Natrium Metasilicat Akzo Nobel Sodium Metasilicate 48.0 Pentahydrate Chemicals, Pentahydrate Deutschland Natriumhydrogen- diverse Sodium hydrogen 15.0 carbonate carbonate Natriumpercarbonat diverse Sodium carbonate 15.0 peroxyhydrate Peractive AC Blue Clariant GmbH, TAED/Na- 5.00 Deutschland Carboxymethylcellulose Genapol OA-080 Clariant GmbH, Oxoalkohol C14-15, 3.00 Deutschland 8EO Texapon K12 Pulver Cognis Sodium Lauryl 7.00 Deutschland Sulphate C12 GmbH Tinopal CBS-X Ciba, Deutschland 0.50 Savinase 6.0 T, Novozymes Protease 0.40 Type W

Example 6

Cleaner, Liquid

(17) TABLE-US-00008 Material Manufacturer INCI wt.-% Demineralized water aqua 93.2 Kelzan ASX-T CP Kelco Germany Xanthan gum 0.5 GmbH HOESCH NAS 60 Hoesch Julius Sulfonic acid, 1.0 C13-17-sec-Alkyl-, sodium salt Citric acid Symrise Citric acid 5.0 Perfume composition A Parfum 0.3 Sum 100.00

(18) Heat water to about 35° C. Sprinkle kelzan onto water while stirring and maintain agitation for another 30 min. to complete hydration. Add and dissolve the remaining components in the given order. Use of either blade or propeller mixer should yield good results.

Example 7

Make-Up Remover

(19) TABLE-US-00009 Material INCI wt.-% Phase A Glycerin Glycerin 9.30 Surfhope ® C-1216 Sucrose Laurate 3.00 Surfhope ® C-1616 Sucrose Palmitate 3.00 Water Water (Aqua) 4.70 Phase B Neutral oil Caprylic/Capric Triglyceride 48.71 Dragoxat ® 89 Ethylhexyl Isononanoate 30.00 lonol CP BHT 0.05 Phase C Symdiol ® 68 1,2-Hexanediol, Caprylyl Glycol 0.80 Phase D Perfume composition A Parfum 0.15 Colour system I Colour 0.15 Colour system II Colour 0.14 Sum 100.00

(20) The production takes place in a Becomix.

(21) For production of phase A, the glycerin and Surfhope® C1216 are put into the Becomix and are stirred at −0.5 bar with 0.3 m/s, then they are homogenized with the aid of a Turrax at 3 m/s for 4 minutes. When the Surf Hope® C1216 is completely dissolved, the Surf Hope® C1616 is added, whereby the stirring is continued at 0.3 m/s. The subsequent homogenization takes place at 3 m/s for 4 minutes with the aid of a Turrax. Then water is added and again homogenized with the aid of a Turrax at 3 m/s for 6 minutes. This mixture is heated to 80° C. under stirring at 0.3 m/s, then brought to 50° C. and again homogenized with the aid of a Turrax with 3 m/s for 2 minutes. Subsequently, the temperature is raised to 80° C. and a pressure of −0.6 bar is adjusted.

(22) The production of phase B takes place at 80° C. At a temperature of 80° C., the components of phase B are very slowly and consecutively mixed with each other and then stirred at 0.5 m/s as well as homogenized with the aid of a Turrax at 3 m/s for 2 minutes. When one quarter of the oil has been put into the boiler, a homogenization step takes place with the aid of a Turrax at 5 m/s for 4 minutes. After half of the oil has been added, it is homogenized again with the aid of a Turrax at 5 m/s for 4 minutes and the stirring speed is raised to 0.8 m/s. When three quarters of the oil have been added, a homogenization step with the aid of a Turrax at 5 m/s for 4 minutes and an increase of the stirring speed to 1 m/s follow. Then the remaining amount of the oil is added and stirred at 1.2 m/s.

(23) After addition of phase C, the pressure is raised to −0.8 bar and it is homogenized with the aid of a Turrax at 5 m/s for 4 minutes. The preparation is cooled under stirring at 0.5 m/s to 25° C., whereby the stirring speed is reduced. Then phase D is added at 40° C.

(24) Colour system I: 0.1% solution in isopropyl palmitate of D&C Red N °17 C.I. 26100

(25) Colour system II: 0.1% solution in isopropyl palmitate of Phat Brown DC 8206: C.I. 47000, C.I. 26100, C.I. 60725

(26) The final preparation has a viscosity of 69280 cP.

Example 8

Shampoo

(27) TABLE-US-00010 Material INCI wt.-% Water Water 71.3000 Citric acid Citric acid 0.1000 Euperlan PK 771 Glycol Distearate, Sodium Laureth Sulfate, Cocamide 6.0000 MEA, Laureth-10 Sodium Chloride Sodium Chloride 1.4000 Plantacare PS 10 Sodium Laureth Sulfate, 20.0000 Lauryl Glucoside Preservative 0.5000 Perfume composition A Perfume 0.7000 Sum 100.0000

(28) In the tank, at room temperature introduce all the ingredients in the listed order while stirring until homogenization. If necessary, adjust the pH to 6 with citric acid or sodium hydroxide.

Example 9

Lip Care Stick

(29) TABLE-US-00011 Component INCI wt.-% Medium mineral oil Paraffinium Liquidum 26.00 Permulgin 3220 Ozokerite 20.00 Paraffin 52-54 Paraffin 12.00 Neutral oil Caprylic/Capric Triglyceride 10.00 Prisorine Sqs 3758 Hydrogenated Polyisobutene 5.00 Cetiol 868 Ethylhexyl Stearate 5.00 Softisan 100 Hydrogenated Cocoglycerides 5.00 Xiameter ® PMX-0245 Cyclopentasiloxane 4.00 Cyclosiloxane Elfacos E 200 Methoxy PEG-22 and 4.00 Dodecyl Glycol Copolymer Permulgin 3430 Copernicia Cerifera 2.00 (Carnauba) Wax Ivarlan 3360 Glyceryl Lanolate 3.00 Super Hartolan Lanolin Alcohol 1.40 Cutina ® FS 45 Stearic acid, Palmitic acid 1.50 Jojoba oil 1.00 Titanium dioxide Titanium Dioxide 0.10 Perfume composition A Perfume 0.01 Sum 100.00

(30) For production, all of the components in the order of the list without the perfume are melted and homogenized during warming to 70° C. At a temperature of 50° C., the perfume is added and homogenized.

Example 10

Dishwash, Liquid Manual

(31) TABLE-US-00012 Component INCI wt.-% Water, demin. Water (aqua) 41.7 Glucopon 650 EC BASF Coco Glucoside 4.0 Zetesol NL-2 Zschimmer Sodium Laureth & Schwarz sulfate 45.0 Dehyton AB 30 BASF Coco-Betaine 8.0 Ethanol 96% Symrise Ethanol 1.0 Parmetol MBX Hoesch Benzisothiazolinone, Julius Methylisothiazolinone, Laurylamine Dipropylenediamine 0.1 Perfume composition A Symrise Perfume 0.2 Sum 100.00

(32) Mix ingredient 1 to 7 in the given order. Make sure that each ingredient is completely solved before adding the next. Adjust pH-value with citric acid.

Example 11

Night Cream

(33) TABLE-US-00013 Component INCI wt.-% Phase A Dragosan W/O P Sorbitan Isostearate, Hydrogenated 5.00 Castor oil, Beeswax (Cera Alba) Medium Mineral Oil Paraffinium Liquidum 15.00 Vaseline Petrolatum 4.50 Tece Ozokerit N 325/II Ozokerite 2.30 Dragoxat ® 89 Ethylhexyl Isononanoate 5.00 Phase B Water Water (Aqua) 64.60 Glycerin, 99.5 P. Glycerin 3.00 Magnesiumsulfate Magnesium Sulfate 0.70 Heptahydrate Preservative Complex Triethylene Glycol, Imidazolidinyl 0.30 (ND Liquid) Urea, Methylparaben, Propylparaben, Dehydroacetic acid Phase C Perfume composition A Perfum 0.10 Sum 100.00

(34) For production, phase A and phase B are separately warmed to 80° C., respectively. Then phase B is added to phase A while using an Ultra-Turrax and emulsified. While stirring with a paddle agitator, this mixture is cooled and then emulsified again at 60° C. When the mixture has reached a temperature of about 35° C., phase C is added.

Example 12

Liquid Soap

(35) TABLE-US-00014 Material INCI wt.-% water Water 77.4360 Plantacare PS 10 Sodium Laureth sulfate, 20.0000 Lauryl Glucoside Preservative 0.5000 Sodium chloride Sodium Chloride 1.4000 Citric acid monohydrate Citric Acid 0.1640 Perfume composition A Perfume 0.5000 Sum 100.0000

(36) In the tank, at room temperature introduce all the ingredients in the listed order while stirring until homogenization. If necessary, adjust the pH with citric acid or sodium hydroxide to a final pH of 6.

Example 13

Detergent Soap Bar

(37) TABLE-US-00015 material INCI wt.-% Britesil H 20 Sodium Silicate 14.6500 Dolomite Sudesan 25.0000 Basic soap HTS Sodium Tallowate, sodium Cocoate, 45.0000 sodium Palm Kernelate Marlon ARL C-10-13, ABS-Na, Powder 6.7000 Texapon Z HK Powder Sodium fatty alcohol C12-C18 6.6000 Titanium dioxide Titanium dioxide 1.0000 Color Acid blue 7, 0.2000 C.I.42080 Powder Perfume composition A Perfume 0.8500 Sum 100.0000

Example 14

Dishwashing Liquid

(38) TABLE-US-00016 material INCI Gew.-% Water, demineralisiert Water 41.8000 Glucopon 650 EC Coco Glucoside 4.0000 Zetesol NL-2 Sodium Laureth Sulfate 45.0000 Dehyton AB 30 Coco-Betaine 8.0000 Ethanol 96% Ethanol 1.0000 Parmatol MBX Benisothiazolinone, 0.1000 Methylisothiazolinone, Laurylamine, Dipropylenediamine Perfume composition A Perfume 0.1000 Sum 100.0000

(39) Mix all ingredients in the given order. Make sure that each ingredient is completely solved before adding the next. Adjust the pH-value with citric acid to pH value of 7.

Example 15

Hair Conditioner

(40) TABLE-US-00017 Material INCI wt.-% Phase A Hostaphat Kw 340 D Trieteareth-4 Phospate 10.0000 Medium Mineral Oil Paraffinium Liquidum 6.0000 Lunacera M Ozocerite 5.0000 Isopropylmyristate Isopropyl myristate 5.0000 Xiameter ® PMX-200 Silicone Fluid Dimethicone 0.5000 Lanolin Alcohol Lanolin Alcohol 0.5000 Phase B Water Water (Aqua) 29.1000 Preservative 0.8000 Glycerin, 99.5 P. Glycerin 12.0000 Citric acid 20% aqu. Solution Citric acid 1.3000 Phase C Water Water (Aqua) 28.9000 Carbopol ® Ultrez-10 Caromer 0.2000 Triethanolamin 99% Triethanolamine 0.3000 Phase D Perfume composition A Perfume 0.4000 Sum 100.0000 Phase A: Mix and heat all ingredients of phase A to 75° C. Phase B: Heat the water at 80° C., add the rest of phase B. Homogenize. Add the phase A to B stirring. Phase C: Swell Ultrez 10 in water with strong stirring. Add Triethanolamine to obtain a limpid gel.

Example 16

Detergent, Liquid, Heavy Duty

(41) TABLE-US-00018 Material INCI wt.-%  1 Water Water 39.7000  2 Tinopal CBS-X Disodium Distyrylbiphenyl 0.1000 Disulfonate  3 Edenor K 12-18 Cocos fatty acids 7.5000  4 Potassium hydroxide Potassium Hydroxide 4.3000 50% solutio  5 Propylene glycol 1,2 Propan-1,2-diol 5.0000  6 Hoesch T 9 90% Trideceth-9 12.0000  7 Parmatol A 26 Mixture of 5-Chloro-2- methyl-2H-isothiazol-3- 0.2000 one and 2-Methyl-2H- isothiazol-3-one  8 Hoesch NAS 60 Sulfonic acid, C 13-17-sec- 17.0000 Alkyl-, Sodium salt  9 Triethanolamine pure C Triethanolamine 2.0000 10 Trisodium citrate dihydrat Tri-sodiumcitrate-dihydrate 5.0000 11 Hoesch Phos DET 32 D Diethylenetriamine 3.0000 Pentamethylene Phosphonic acid Sodium salt 12 Ethanol 96% Ethanol 3.0000 13 Alcalase 2.5 L Protease 0.4000 14 Termamyl 300L Alpha-Amylase 0.3000 15 Perfume composition A Perfume 0.5000 Sum 100.0000

(42) Mix ingredients 1 and 2. Heat up to 50° C. Add ingredient 3 and 4, stir until soap has formed. Add ingredients 5 to 10 in the given order. Cool down to 30° C.

(43) Add ingredients 11 to 14 in the given order. Adjust pH to 8.5, if necessary.

Example 17

Detergent, Liquid

(44) TABLE-US-00019 material INCI wt.-%  1 Water, demineralized Water 48.3000  2 Edenor K 12-18 Cocos fatty acids 3.0000  3 Sodium hydroxide 50% Sodium Hydroxide 2.5000 solution  4 Novethix L-10 Polymer NRC Nordmann, Rassmann 2.5000  5 Zetesol NL-2 Sodium Laureth Sulfate 30.0000  6 Hoesch AE 50 sodium Dodecylbenzenesulfonate 3.0000  7 Dehydol LT 7 3.0000  8 Hoesch Phos DET 32 D Diethylenetriamine Pentamethylene Phosphonic 1.0000 acid Sodium salt  9 Ethanol 96% Ethanol 2.0000 10 Propylene glycol 1,2 Propan-1,2-diol 2.0000 11 Trisodium citrate dihydrat Tri-sodiumcitrate-dihydrate 2.0000 12 Perfume composition A Perfume 0.5000 13 Parmatol A 26 Mixture of 5-Chloro-2-methyl- 2H-isothiazol-3-one and 2- 0.2000 Methyl-2H-isothiazol-3-one Sum 100.0000

(45) Add all other ingredients in the given order. Make sure that every ingredient is solved before adding the next. If it is necessary, adjust pH to 9 with citric acid.

Example 18

Transparent Deo-Stick (A) & Cream-Deo-Stick (B)

(46) TABLE-US-00020 A B material wt.-% wt.-% Water, demineralized 36.5500 54.8500 Aluminium Zirconium Tetrachlorohydrate- 25.0000 25.0000 Glycin Komplex Dimethicon (10 Cst) — 5.0000 Cyclopentasiloxan — 1.0000 Petrolatum 5.0000 5.0000 Ozokerit 1.0000 — Stearylalcohol 12.0000 — 2-Butyloctanic acid 0.5000 0.5000 Wax — 1.2500 PPG-14 Butylether 9.0000 — hydrogenated rapeseed oil — 5.0000 Silicium dioxide — 1.0000 Farnesol 0.2500 0.2500 Paraffin oil 0.5000 — Castor wax 3.5000 — Tallow 4.0000 — Behenylalcohol 0.2000 — d-Panthenyltriacetate 1.0000 — Perfume composition A 1.5000 1.1500 Sum 100.0000 100.0000

Example 19

Aerosol Spray

(47) TABLE-US-00021 A material wt.-% ethanol 96.2000 octyldodecanol 0.5000 1,2-pentanediol 1.0000 1,2-hexanediol 0.2500 1,2-octanediol 0.2500 Farnesol 0.5000 ethylhexylglycerin 0.5000 perfume composition A 0.8000 Sum 100.0000

Example 20

Sun Protection Spray

(48) TABLE-US-00022 Material INCI wt.-% Phase A Water, demineralized Water (Aqua) 68.9000 Glycerin Glycerin 4.0000 1,3-Butylene glycol Butylene Glycol 5.0000 D-Panthenol Panthenol 0.5000 Lara Care A-200 Galactoarabinan 0.2500 Phase B Baysiloneöl M 10 Dimethicone 1.0000 Edeta BD Disodium EDTA 0.1000 Copherol 1250 Tocopheryl Acetate 0.5000 Cetiol OE Dicaprylyl Ether 3.0000 Neo Heliopan ® HMS Homosalate 5.0000 Neo Heliopan ® AV Ethylhexyl Methoxycinnamate 6.0000 Neo Heliopan ® 357 Butyl Methoxydibenzoylmethane 1.0000 Corapan TQ Diethylhexylnaphthalate 2.0000 Alpha Bisabolol Bisabolol 0.1000 Pemulen TR-2 Acrylates/C10-30 Alkyl 0.2500 Acrylate Crosspolymer Phase C Phenoxyethanol Phenoxyethanol 0.7000 Solbrol M Methylparaben 0.2000 Solbrol P Propylparaben 0.1000 Phase D NaOH, 10% ig Sodium Hydroxide 0.6000 Phase E 0.5000 Perfume composition A Perfume 0.3000 Sum 100.0000

(49) Solve Lara Care A-200 in the ingredients of phase A by stirring. Mix all ingredients of phase B except the Pemulen and slightly heat until everything is solved. Add the Pemulen and homogenise. Then mix phase A and phase B and homogenise for 1 minute. Add phase C, D and E and homogenise with Ultra turrax for 1-2 minutes.

Example 21

Sun Protection Milk

(50) TABLE-US-00023 Material INCI wt.-% Phase A Dehymuls PGPH Polyglyceryl-2 Dipolyhydroxystearate 3.0000 Beeswax 8100 Beeswax 1.0000 Monomuls 90-0-18 Glyceryl Oleate 1.0000 Zinc stearate Zinc stearate 1.0000 Cetiol SN Cetearyl lsononanoate 5.0000 Cetiol OE Dicaprylyl Ether 5.0000 Tegosoft TN C12-15 Alkyl Benzoate 4.0000 Vitamin E Tocopherol 0.5000 Solbrol P Propylparaben 0.1000 Neo Heliopan ® OS Ethylhexyl Salicylate 5.0000 Neo Heliopan ® AV Ethylhexyl Methoxycinnamate 7.5000 Uvinulâ T150 Ethylhexyl Triazone 1.5000 Phase B Water Water 43.5500 Trilon BD Disodium EDTA 0.1000 Glycerin Glycerin 5.0000 Solbrol M Methylparaben 0.2000 Phenoxyethanol Phenoxyethanol 0.7000 Neo Heliopan ® AP Disodium Phenyl Dibenzimidazole 15.0000 10% ige solution, Tetrasulfonate neutralised with NaOH Phase C 0.5000 Alpha Bisabolol Bisabolol 0.1000 Perfume composition A Perfume 0.2500 Sum 100.0000