Gas phase rust-resisting material for various metals and preparation method thereof

Abstract

A gas phase rust-resisting material for various metals includes, calculated in parts by weight, following components of: 78.5 to 95.5 parts of benzotriazole, 78.5 to 95.5 parts of dicycloethylamine nitrite, 500 to 800 parts of octadecylamine, 9000 to 11000 parts of ethanol, 33.5 to 38.5 parts of a reinforcing agent and 23.5 to 25.5 parts of a rust-resistant microcapsule. Further disclosed is a method for preparing the gas phase rust-resisting material which is suitable for various metals.

Claims

1. A gas-phase rust-resisting material for various metals, comprising: calculated by weight, 78.5 to 95.5 parts of benzotriazole, 78.5 to 95.5 parts of dicyclohexylamine nitrite, 500 to 800 parts of octadecylamine, 9000 to 11000 parts of ethanol, 33.5 to 38.5 parts of a reinforcing agent and 23.5 to 25.5 parts of a rust-resisting microcapsule.

2. The gas-phase rust-resisting material for various metals according to claim 1, wherein the reinforcing agent is a mixed solution of nano-graphene oxide dispersion and nano-silica dispersion; wherein a volume ratio of nano-graphene oxide dispersion to the nano-silica dispersion is in a range of 1:5-7.

3. The gas-phase rust-resisting material for various metals according to claim 2, wherein the nano-graphene oxide dispersion has a pH in a range of 5-7, a concentration of 5-8 mg/ml, a specific surface area of 1217 m.sup.2 /g, and a sheet diameter in a range of 2-4 μm; the nano-silica dispersion is an aqueous slurry; wherein the nano-silica dispersion has a silica content in a range of 18-20 wt % by weight, and a particle diameter D50 in a range of 50-80 nm , a pH in a range of 6-7, a viscosity in a range of 40-60 mpa.Math.s, and a density in a range of 1.2-1.21 gml.

4. A method for preparing the gas-phase rust-resisting material for the various metals according to claim 1, comprising a step of preparing rust-resisting microcapsules and a step of mixing; wherein the step of mixing comprises: mixing 78.5-95.5 parts of benzotriazole, 80.5-92.5 parts of dicyclohexylamine nitrite, 500-800 parts of octadecylamine, 9000-11000 parts of ethanol, 33.5-38.5 parts of reinforcing agent, 23.5-25.5 parts of rust-resisting microcapsules according to parts by mass of raw materials, stirring uniformly, then heating to a temperature in a range of 80-90° C. and maintaining the temperature for 110-150 min, cooling to a room temperature.

5. The method for preparing the gas-phase rust-resisting material for the various metals according to claim 4, wherein the step of preparing rust-resisting microcapsules comprises: (1) a sub-step of preparing a composite solution of nano-titanium dioxide and gelatin; (2) a sub-step of preparing a solution of modified casein; a sub-step (3) of preparing a first capsule substrate; a sub-step (4) preparing a second capsule substrate; and a sub-step (5) of synthesizing rust-resisting microcapsule.

6. The method for preparing the gas-phase rust-resisting material for the various metals according to claim 5, wherein the sub-step of preparing the composite solution of the nano-titanium dioxide and gelatin comprises preparing gelatin solution, adding the nano-titanium dioxide with a mass fraction of 0.5-1.1%; at a rotation speed in a range of 2000-2500 r/min, at a temperature in a range of 65-70° C., performing high speed emulsification dispersion by a homogenizer for 20-30 min.

7. The method for preparing the gas-phase rust-resisting material for the various metals according to claim 5, wherein sub-step (2) of preparing the solution of the modified casein comprises: adding casein to distilled water and stirring into a paste, adding NaoH solution with a concentration in a range of 0.10-0.16 mol/L until the casein is completely dissolved; then boiling for 5-15 min; dissolving succinic anhydride in ethanol to prepare a succinic anhydride solution with a mass fraction in a range of 8-10%; dropping the succinic anhydride solution prepared into a casein solution until a pH is in a range of 7.2-8.0; and then at a temperature in a range of 48-55° C., stirring with a magnetic stirrer for 5-25 min, and then cooling to a room temperature.

8. The method for preparing the gas-phase rust-resisting material for the various metals according to claim 5, wherein sub-step (3) of preparing a first capsule substrate, comprises: mixing benzotriazole, dicyclohexylamine nitrite, octadecylamine and ethanol according to a proportion of 1:1:7:110-130 to prepare a rust-resisting core material, adding the composite liquid of nano-titanium dioxide and gelatin in the step (1) to the rust-resisting core material according to a certain proportion, stirring and mixing uniformly; wherein a proportion of the composite liquid of nano-titanium dioxide and gelatin to the rust-resisting core material is in a range of 35-40%.

9. The method for preparing the gas-phase rust-resisting material for the various metals according to claim 5, wherein the sub-step (4) preparing the second capsule substrate comprises: adding chitosan and cellulose derivative to the modified casein solution prepared in the step (2), mixing, and performing ultrasonic dispersion to form the second capsule substrate; wherein an ultrasonic frequency of the ultrasonic dispersion is in a range of 100-120 kHz; an ultrasonic power is in a range of 50-70 W; an ultrasonic time at an ultrasonic temperature is in a range of 15-20 min; and an ultrasonic frequency is 3 times; wherein an amount of the chitosan added is in a range of 3-5% of the modified casein solution; an amount of the cellulose derivative added is in a range of 5-6% of the modified casein solution; wherein the cellulose derivative is at least one member selected from the group consisting of carboxymethylcellulose; ethyl cellulose, hydroxyethyl cellulose and cyanoethyl cellulose.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

(1) Further description of the present invention is illustrated combining with the preferred embodiments of the present invention.

Example 1

(2) A method for preparing a gas phase rust-resisting material for various metals comprises steps of:

(3) Step <1>: Preparing Rust-Resisting Microcapsules:

(4) sub-step: (1) preparing a composite solution of nano-titanium dioxide and gelatin: preparing gelatin solution with a mass fraction of 13%, adding the nano-titanium dioxide with a mass fraction of 0.7%; at a rotation speed of 2000 r/min, at a temperature of 70° C., performing high speed emulsification dispersion by a homogenizer for 20 min, so as to obtain a composite liquid of nano-titanium dioxide and gelatin;

(5) sub-step (2) preparing a solution of modified casein: adding casein to distilled water and stirring into a paste, slowly adding NaoH solution with a concentration of 0.16 mol/L until the casein is completely dissolved; then boiling for 10 min; dissolving succinic anhydride in ethanol to prepare a succinic anhydride solution with a mass fraction of 8%; dropping the succinic anhydride solution prepared into a casein solution until a pH is 7.5; and then at a temperature of 50° C., stirring with a magnetic stirrer for 15 min, and then cooling to room temperature to prepare a modified casein solution;

(6) (3) preparing a first capsule substrate, comprising: mixing benzotriazole, dicycloethylamine nitrite, octadecylamine and ethanol according to a proportion of 1:1:7:120 to prepare a rust-resisting core material, adding the composite liquid of nano-titanium dioxide and gelatin in the step (1) to the rust-resisting core material according to a certain proportion, stirring and mixing uniformly to form the first capsule substrate;

(7) wherein a quality proportion of the composite liquid of nano-titanium dioxide and gelatin to the rust-resisting core material is 40%;

(8) (4) preparing a second capsule substrate, adding chitosan and cellulose derivative to the modified casein solution prepared in the step (2), mixing, and performing ultrasonic dispersion to form the second capsule substrate;

(9) wherein an ultrasonic frequency of the ultrasonic dispersion is 100 kHz; an ultrasonic power is 70 W; an ultrasonic time at an ultrasonic temperature is 15 min; an ultrasonic frequency is 3 times;

(10) wherein a quality amount of the chitosan added is 3% of the modified casein solution; a quality amount of the cellulose derivative added is 6% of the modified casein solution; wherein the cellulose derivative is carboxymethylcellulose;

(11) 5) synthesizing rust-resisting microcapsule, comprising: mixing the second capsule substrate prepared in the step (4) and the first capsule substrate prepared in the step (3) according to a ratio of 2:1, adjusting pH to 5.5 with boric acid, continuing to stir for 45 min after an agglomeration reaction, wherein a rotation speed of the stirring is 450 r/min, waiting until the agglomeration reaction is completely finished, and then cooling a solution at a rate of 1° C. per minute until a temperature is within 10° C., adjusting pH to 8 with sodium hydroxide, stirring, and then standing until the rust-resisting microcapsules are separated out, filtering, washing to neutral, and drying to obtain rust-resisting microcapsules.

(12) The rust-resisting microcapsules prepared in the process of preparing the rust-resisting material of the present invention has an embedding rate of 88%, a yield of 77%, and an average particle diameter of 13 μm, with good oxidation resistance and storage stability, and an oxidation resistance thereof is 0.756 mmol/g by ABTS method.

(13) Step <2>: Mixing, Comprising:

(14) mixing 87.5 parts of benzotriazole, 87.5 parts of dicyclohexylamine nitrite, 700 parts of octadecylamine, 10500 parts of ethanol, 33.5 parts of reinforcing agent, 25.5 parts of rust-resisting microcapsules according to parts by mass of raw materials, stirring uniformly, heating to 90° C. and maintaining a temperature at 90° C. for 110 min, cooling to a room temperature to manufacture a vapor phase rust-resisting material of the present invention;

(15) wherein the reinforcing agent is a mixed solution of nano-graphene oxide dispersion and nano-silica dispersion; wherein a volume ratio of nano-graphene oxide dispersion to the nano-silica dispersion is 1:6.

Example 2

(16) A method for preparing a gas phase rust-resisting material for various metals comprises steps of:

(17) Step <1>: Preparing Rust-Resisting Microcapsules:

(18) sub-step: (1) preparing a composite solution of nano-titanium dioxide and gelatin: preparing gelatin solution with a mass fraction of 12%, adding the nano-titanium dioxide with a mass fraction of 0.5%; at a rotation speed of 2000 r/min, at a temperature of 65° C., performing high speed emulsification dispersion by a homogenizer for 30 min, so as to obtain a composite liquid of nano-titanium dioxide and gelatin;

(19) (2) preparing a solution of modified casein: adding casein to distilled water and stirring into a paste, slowly adding NaoH solution with a concentration of 0.10 mol/L until the casein is completely dissolved; then boiling for 15 min; dissolving succinic anhydride in ethanol to prepare a succinic anhydride solution with a mass fraction of 8%; dropping the succinic anhydride solution prepared into a casein solution until a pH is 8.0; and then at a temperature of 48° C., stirring with a magnetic stirrer for 5 min, and then cooling to room temperature to prepare a modified casein solution;

(20) (3) preparing a first capsule substrate, comprising: mixing benzotriazole, dicycloethylamine nitrite, octadecylamine and ethanol according to a proportion of 1:1:7:130 to prepare a rust-resisting core material, adding the composite liquid of nano-titanium dioxide and gelatin in the step (1) to the rust-resisting core material according to a certain proportion, stirring and mixing uniformly to form the first capsule substrate;

(21) wherein a quality proportion of the composite liquid of nano-titanium dioxide and gelatin to the rust-resisting core material is 35%;

(22) (4) preparing a second capsule substrate, adding chitosan and cellulose derivative to the modified casein solution prepared in the step (2), mixing, and performing ultrasonic dispersion to form the second capsule substrate;

(23) wherein an ultrasonic frequency of the ultrasonic dispersion is 120 kHz; an ultrasonic power is 70 W; an ultrasonic time at an ultrasonic temperature is 16 min; an ultrasonic frequency is 2 times;

(24) wherein a quality amount of the chitosan added is 3% of the modified casein solution; a quality amount of the cellulose derivative added is 5% of the modified casein solution; wherein the cellulose derivative is carboxymethylcellulose;

(25) 5) synthesizing rust-resisting microcapsule, comprising: mixing the second capsule substrate prepared in the step (4) and the first capsule substrate prepared in the step (3) according to a ratio of 3:1, adjusting pH to 5.0 with boric acid, continuing to stir for 25 min after an agglomeration reaction, wherein a rotation speed of the stirring is 450 r/min, waiting until the agglomeration reaction is completely finished, and then cooling a solution at a rate of 1° C. per minute until a temperature is within 10° C., adjusting pH to 8 with sodium hydroxide, stirring, and then standing until the rust-resisting microcapsules are separated out, filtering, washing to neutral, and drying to obtain rust-resisting microcapsules.

(26) The rust-resisting microcapsules prepared in the process of preparing the rust-resisting material of the present invention has an embedding rate of 82%, a yield of 65%, and an average particle diameter of 16 μm, with good oxidation resistance and storage stability, and an oxidation resistance thereof is over 0.742 m mol/g by ABTS method.

(27) Step <2>: Mixing, Comprising:

(28) mixing 78.5 parts of benzotriazole, 80.5 parts of dicyclohexylamine nitrite, 500 parts of octadecylamine, 9000 parts of ethanol, 33.5 parts of reinforcing agent, 23.5 parts of rust-resisting microcapsules according to parts by mass of raw materials, stirring uniformly, heating to 90° C. and maintaining a temperature at 90° C. for 110 min, cooling to a room temperature to manufacture a vapor phase rust-resisting material of the present invention;

(29) wherein the reinforcing agent is a mixed solution of nano-graphene oxide dispersion and nano silica dispersion;

(30) wherein a volume ratio of nano-graphene oxide dispersion to the nano silica dispersion is 1:5.

Example 3

(31) A method for preparing a gas phase rust-resisting material for various metals comprises steps of:

(32) Step <1>: Preparing Rust-Resisting Microcapsules:

(33) sub-step: (1) preparing a composite solution of nano-titanium dioxide and gelatin: preparing gelatin solution with a mass fraction of 18%, adding the nano-titanium dioxide with a mass fraction of 1.1%; at a rotation speed of 2500 r/min, at a temperature of 70° C., performing high speed emulsification dispersion by a homogenizer for 30 min, so as to obtain a composite liquid of nano-titanium dioxide and gelatin;

(34) sub-step (2) preparing a solution of modified casein: adding casein to distilled water and stirring into a paste, slowly adding NaoH solution with a concentration of 0.16 mol/L until the casein is completely dissolved; then boiling for 15 min; dissolving succinic anhydride in ethanol to prepare a succinic anhydride solution with a mass fraction of 10%; dropping the succinic anhydride solution prepared into a casein solution until a pH is 8.0; and then at a temperature of 55° C., stirring with a magnetic stirrer for 25 min, and then cooling to room temperature to prepare a modified casein solution;

(35) sub-step (3) preparing a first capsule substrate, comprising: mixing benzotriazole, dicycloethylamine nitrite, octadecylamine and ethanol according to a proportion of 1:1:8:120 to prepare a rust-resisting core material, adding the composite liquid of nano-titanium dioxide and gelatin in the step (1) to the rust-resisting core material according to a certain proportion, stirring and mixing uniformly to form the first capsule substrate;

(36) wherein a quality proportion of the composite liquid of nano-titanium dioxide and gelatin to the rust-resisting core material is 40%;

(37) sub-step (4) preparing a second capsule substrate, adding chitosan and cellulose derivative to the modified casein solution prepared in the step (2), mixing, and performing ultrasonic dispersion to form the second capsule substrate;

(38) wherein an ultrasonic frequency of the ultrasonic dispersion is 120 kHz; an ultrasonic power is 70 W; an ultrasonic time at an ultrasonic temperature is 20 min; an ultrasonic frequency is 3 times;

(39) wherein a quality amount of the chitosan added is 3% of the modified casein solution; a quality amount of the cellulose derivative added is 6% of the modified casein solution; wherein the cellulose derivative is carboxymethylcellulose;

(40) sub-step (5) synthesizing rust-resisting microcapsule, comprising: mixing the second capsule substrate prepared in the step (4) and the first capsule substrate prepared in the step (3) according to a ratio of 3:1, adjusting pH to 5.5 with boric acid, continuing to stir for 45 min after an agglomeration reaction, wherein a rotation speed of the stirring is 600 r/min, waiting until the agglomeration reaction is completely finished, and then cooling a solution at a rate of 1° C. per minute until a temperature is within 10° C., adjusting pH to 9 with sodium hydroxide, stirring, and then standing until the rust-resisting microcapsules are separated out, filtering, washing to neutral, and drying to obtain rust-resisting microcapsules.

(41) The rust-resisting microcapsules prepared in the process of preparing the rust-resisting material of the present invention has an embedding rate of 83%, a yield of 65%, and an average particle diameter of 15 μm, with good oxidation resistance and storage stability, and an oxidation resistance thereof is over 0.745 m mol/g by ABTS method.

(42) Step <2>: Mixing, Comprising:

(43) mixing 95.5 parts of benzotriazole, 92.5 parts of dicyclohexylamine nitrite, 800 parts of octadecylamine, 11000 parts of ethanol, 38.5 parts of reinforcing agent, 25.5 parts of rust-resisting microcapsules according to parts by mass of raw materials, stirring uniformly, heating to 90° C. and maintaining a temperature at 90° C. for 150 min, cooling to a room temperature to manufacture a vapor phase rust-resisting material of the present invention.

(44) wherein the reinforcing agent is a mixed solution of nano-graphene oxide dispersion and nano silica dispersion;

(45) wherein a volume ratio of nano-graphene oxide dispersion to the nano silica dispersion is 1:7.

Comparative Example

(46) A method for preparing a gas phase rust-resisting material for various metals which changes the preparation method of the composite liquid of titanium oxide/gelatin compared with the preparation method of the Example 1, omits the addition of the reinforcing agent, and omits the modification of casein, wherein the specific method is:

(47) Step <1>: Preparing Rust-Resisting Microcapsules:

(48) Sub-Step: (1) Preparing a Composite Solution of Gelatin:

(49) preparing gelatin solution with a mass fraction of 13%, at a rotation speed of 2000 r/min, at a temperature of 70° C., performing high speed emulsification dispersion by a homogenizer for 20 min, so as to obtain a gelatin solution;

(50) sub-step (2)) preparing casein solution:adding casein to distilled water and stirred into a paste, and slowly adding 0.16 mol/L of NaOH solution until the casein is completely dissolved, and adding ethanol to prepare a casein solution;

(51) (3) preparing a first capsule substrate, comprising: mixing benzotriazole, dicycloethylamine nitrite, octadecylamine and ethanol according to a proportion of 1:1:7:120 to prepare a rust-resisting core material, adding the composite liquid of nano-titanium dioxide and gelatin in the step (1) to the rust-resisting core material according to a certain proportion, stirring and mixing uniformly to form the first capsule substrate;

(52) wherein a quality proportion of the composite liquid of nano-titanium dioxide and gelatin to the rust-resisting core material is 40%;

(53) (4) preparing a second capsule substrate, adding chitosan and cellulose derivative to the modified casein solution prepared in the step (2), mixing, and performing ultrasonic dispersion to form the second capsule substrate;

(54) wherein an ultrasonic frequency of the ultrasonic dispersion is 100 kHz; an ultrasonic power is 70 W; an ultrasonic time at an ultrasonic temperature is 15 min; an ultrasonic frequency is 3 times;

(55) wherein a quality amount of the chitosan added is 3% of the modified casein solution; a quality amount of the cellulose derivative added is 6% of the modified casein solution; wherein the cellulose derivative is carboxymethylcellulose;

(56) (5) synthesizing rust-resisting microcapsule, comprising: mixing the second capsule substrate prepared in the step (4) and the first capsule substrate prepared in the step (3) according to a ratio of 2:1, adjusting pH to 5.5 with boric acid, continuing to stir for 45 min after an agglomeration reaction, wherein a rotation speed of the stirring is 450 r/min, waiting until the agglomeration reaction is completely finished, and then cooling a solution at a rate of 1° C. per minute until a temperature is within 10° C., adjusting pH to 8 with sodium hydroxide, stirring, and then standing until the rust-resisting microcapsules are separated out, filtering, washing to neutral, and drying to obtain rust-resisting microcapsules.

(57) The rust-resisting microcapsules prepared in the process of preparing the rust-resisting material of the present invention has an embedding rate of 88%, a yield of 77%, and an average particle diameter of 13 μm, with good oxidation resistance and storage stability, and an oxidation resistance thereof is 0.756 mmol/g by ABTS method.

(58) Step <2>: Mixing, Comprising:

(59) mixing 87.5 parts of benzotriazole, 87.5 parts of dicyclohexylamine nitrite, 700 parts of octadecylamine, 10500 parts of ethanol, 25.5 parts of rust-resisting microcapsules according to parts by mass of raw materials, stirring uniformly, heating to 90° C. and maintaining a temperature at 90° C. for 110 min, cooling to a room temperature to manufacture a vapor phase rust-resisting material of the present invention.

(60) The vapor phase corrosion inhibitor prepared by the present invention can be directly coated on the rust-resisting base paper or directly coated on a surface of a metal product; in order to further test a rust-resisting effect of the gas-phase rust-resisting material prepared by the present invention, tests are carried out as follows.

(61) The gas phase rust-resisting material prepared by the present invention is separately coated to a surface of the surface-treated rebar HRB400, HRB335 and HRB500 to test rust-resisting performance thereof, Test 1 and Test 2 are performed, see Table 1 and Table 2 for details.

(62) Test 1: Salt Spray Test

(63) YW-1804 airflow salt spray test cabinet are adopted for neutral salt spray test. A corrosive medium is NaCl solution with a concentration of 8%, wherein pH=6.5-7.5; wherein temperature inside the salt spray cabinet is controlled at a range of (35±1) ° C., a relative humidity is about 98, the sample has an included angle of 30° with a perpendicular direction. After continuous spraying for 1 h, the spraying is stopped, and the sample is continuously placed in a salt spray cabinet for 1 hour or more for one cycle, and a rust trace of the sample is observed every other cycle to determine the corrosion resistance of a coating layer of the rust inhibitor.

(64) A blank test group is a test group without utilizing any rust inhibitor.

(65) TABLE-US-00001 TABLE 1 Neutral salt spray resistance of different types of screw thread steel after dip coating of the gas-phase rust-resisting materials prepared by the present invention Type HRB400 HRB335 HRB500 Time (d) 0-20 21-80 41-80 0-20 21-80 41-80 0-20 21-80 41-80 Example 1 No rust No rust Needle-like No rust No rust Needle-like No rust No rust Needle-like mark. mark. rust mark mark. mark. rust mark mark. mark. rust mark appears on appears on appears on 58.sup.th day. 45.sup.th day. 49.sup.th day. Example 2 No rust No rust Needle-like No rust No rust Needle-like No rust No rust Needle-like mark. mark. rust mark mark. mark. rust mark mark. mark. rust mark appears on appears on appears on 52.sup.nd day. 44.sup.th day. 46.sup.th day. Example 3 No rust No rust Needle-like No rust No rust Needle-like No rust No rust Needle-like mark. mark. rust mark mark. mark. rust mark mark. mark. rust mark appears on appears on appears on 55.sup.th day. 43.sup.th day. 47.sup.th day. Comparative No rust Needle-like Dot rust mark No rust Needle-like Dot rust mark No rust Needle-like Dot rust mark Example mark. rust mark appears on mark. rust mark appears on mark. rust mark appears on appears on 52.sup.nd day. appears on 46.sup.th day. appears on 42.sup.nd day. 22.sup.nd day. 26.sup.nd day. 31.sup.st day. Blank Test All red All red All red All red All red All red All red All red All red rust rust rust rust rust rust rust rust rust marks on marks. marks on marks on marks. marks. marks on marks. marks. 2.sup.nd day. 2.sup.nd day. 2.sup.nd day. 2.sup.nd day Conventional Needle-like Needle-like All red Needle-like Needle-like All red Needle-like Needle-like All red rust rust mark rust mark rust rust mark rust mark rust rust mark rust mark rust inhibitor appears on appears on marks on appears on appears on marks on appears on appears on marks on 20.sup.th day. 26.sup.th day. 53.sup.rd day. 18.sup.th day. 28.sup.th day. 50.sup.th day. 16.sup.th day. 23.sup.tnd day. 52.sup.tnd day.

(66) It can be seen from the above Table that the gas-phase rust-resisting materials prepared by the present invention are respectively coated on screw thread steel HRB335, HRB400 and HRB500 with a cleanly treated surface. It can be concluded from the above Table that the gas-phase rust-resisting material prepared by the present invention is applied to the screw thread steel HRB400, and the needle-like rust mark first appears on a 52.sup.nd day; on the HRB335, the needle-like rust mark first appears on a 43.sup.rd day; and on the HRB500, the needle-like rust mark first appears on a 46.sup.th day. Thus, the gas-phase rust-preventing material prepared by the invention is suitable for the screw thread steel, especially for the HRB400 thread

(67) Meanwhile, it can be seen from the conclusions of Table 1 that the vapor-phase rust-resisting material prepared in Examples 1-3 of the present invention is applied to the IRB400 screw thread steel, and on the 58.sup.th day, the needle-like rust mark appears on the vapor-phase rust-resisting material prepared in the Example 1; on the 52.sup.nd day, the needle-like rust mark appears on the vapor-phase rust-resisting material prepared in the Example 2; and on the 5.sup.th day, the needle-like rust mark appears on the vapor-phase rust-resisting material prepared in the Example 3. Therefore, Example 1 is best mode of the present invention.

(68) Test 2: Exposure Test

(69) The gas-phase rust-resisting material prepared by the invention is respectively coated to the cleanly treated surface of the screw thread steel of HRB400, HRB35 and HRB500. In an outdoor environment from March to June, observe the rust-resisting performance of the sample. A specific observation results are shown in the Table 2.

(70) TABLE-US-00002 TABLE 2 Types HRB400 Time (d) 0-20 days 21-40 days 41-80 days 81-150 days Exam- No rust No rust No rust Needle-like ple 1 mark. mark. mark. rust mark appears on 138.sup.th day. Exam- No rust No rust No rust Needle-like ple 2 mark. mark. mark. rust mark appears on 115.sup.th day. Exam- No rust No rust No rust Needle-like ple 3 mark. mark. mark. rust mark appears on 128.sup.th day. Exam- No rust No rust No rust Needle-like ple 4 mark. mark. mark. rust mark appears on 96.sup.th day. Blank Dot rust mark All red All red All red Test appears on rust rust rust Group 4.sup.th day. marks. marks marks. on the 25.sup.th day. Conven- No rust All red All red All red tional mark. rust rust rust Rust marks. marks marks Inhibitor on the on the 38.sup.th day. 77.sup.th day.

(71) From the results observed in Table 2, it can be concluded that the gas-phase rust resisting material prepared by the present invention can basically satisfy application of the current screw thread steel, especially suitable for the prevention of gas-phase rust-resisting materials prepared by the present invention in the open air and in a harsh environment. The rust-resisting effect of the present invention is far superior to similar products.

(72) The gas-phase rust-resisting material prepared by the present invention can be used for stock rust prevention of screw thread steel, wire rod, coil screw, round steel, wire rod and pipe material, and can be used for rust prevention of various metals.

(73) One skilled in the art will understand that the embodiment of the present invention as shown in the drawings and described above is exemplary only and not intended to be limiting.

(74) It will thus be seen that the objects of the present invention have been fully and effectively accomplished. Its embodiments have been shown and described for the purposes of illustrating the functional and structural principles of the present invention and is subject to change without departure from such principles. Therefore, this invention includes all modifications encompassed within the spirit and scope of the following claims.