LOW LEAKAGE RESISTIVE RANDOM ACCESS MEMORY CELLS AND PROCESSES FOR FABRICATING SAME
20170179382 ยท 2017-06-22
Assignee
Inventors
- John L. McCollum (Orem, UT, US)
- Fethi Dhaoui (Mountain House, CA, US)
- Frank W. Hawley (Campbell, CA, US)
Cpc classification
G11C2213/54
PHYSICS
G11C2213/11
PHYSICS
H10N70/884
ELECTRICITY
G11C2213/51
PHYSICS
H10N70/826
ELECTRICITY
H10N70/245
ELECTRICITY
G11C2213/52
PHYSICS
G11C13/0011
PHYSICS
H10N70/011
ELECTRICITY
G11C2213/56
PHYSICS
H10N70/801
ELECTRICITY
H10N70/063
ELECTRICITY
International classification
Abstract
A resistive random access memory device is formed in an integrated circuit between a first metal layer and a second metal layer and includes a first barrier layer disposed over the first metal layer, a tunneling dielectric layer disposed over the first barrier layer, a solid electrolyte layer disposed over the tunneling dielectric layer, an ion source layer disposed over the solid electrolyte layer, and a second barrier layer disposed over the ion source layer.
Claims
1. A resistive random access memory device formed in an integrated circuit between a first metal layer and a second metal layer and comprising: a first barrier layer disposed over the first metal layer; a tunneling dielectric layer disposed over the first barrier layer; a solid electrolyte layer disposed over the tunneling dielectric layer; an ion source layer disposed over the solid electrolyte layer; and a second barrier layer disposed over the ion source layer.
2. A resistive random access memory device formed in an integrated circuit and comprising: a first metal layer; a first barrier layer disposed over the first metal layer; a tunneling dielectric layer disposed over the first barrier layer; a solid electrolyte layer disposed over the tunneling dielectric layer; an ion source layer disposed over the solid electrolyte layer; a second barrier layer disposed over the ion source layer; and a second metal layer disposed over the second barrier layer.
3. A resistive random access memory device formed in an integrated circuit between a first metal layer and a second metal layer and comprising: a first barrier layer disposed over the first metal layer; a solid electrolyte layer disposed over the first barrier layer; a dielectric layer disposed over the solid electrolyte layer; an ion source layer disposed over the dielectric layer; and a second barrier layer disposed over the ion source layer and beneath the second metal layer.
4. A resistive random access memory device formed in an integrated circuit between a first metal layer and a second metal layer and comprising: a first barrier layer disposed over the first metal layer; a tunneling dielectric layer disposed over the first barrier layer; a solid electrolyte layer disposed over the tunneling dielectric layer; a dielectric layer disposed over the solid electrolyte layer; an ion source layer disposed over the dielectric layer; and a second barrier layer disposed over the ion source layer and beneath the second metal layer.
5. A method for forming a resistive random access memory device in an integrated circuit between a first metal layer and a second metal layer comprising: forming a first barrier layer disposed over the first metal layer; forming a tunneling dielectric layer disposed over the first barrier layer; forming a solid electrolyte layer disposed over the tunneling dielectric layer; forming an ion source layer disposed over the solid electrolyte layer; and forming a second barrier layer disposed over the ion source layer.
6. The method of claim 5, further including: forming a dielectric layer over the solid electrolyte layer before forming the ion source layer.
7. A method for forming a resistive random access memory device in an integrated circuit between a first metal layer and a second metal layer comprising: forming a first barrier layer disposed over the first metal layer; forming a tunneling dielectric layer disposed over the first barrier layer; forming a solid electrolyte layer disposed over the tunneling dielectric layer; forming an ion source layer disposed over the solid electrolyte layer; forming a second barrier layer disposed over the ion source layer; and forming a second metal layer disposed over the second barrier layer.
8. A method for forming a resistive random access memory device in an integrated circuit between a first metal layer and a second metal layer comprising: forming a first barrier layer disposed over the first metal layer; forming a solid electrolyte layer disposed over the first barrier layer; forming a dielectric layer disposed over the solid electrolyte layer; forming an ion source layer disposed over the dielectric layer; and forming a second barrier layer disposed over the ion source layer and beneath the second metal layer.
Description
BRIEF DESCRIPTION OF THE DRAWING FIGURES
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DETAILED DESCRIPTION
[0042] Persons of ordinary skill in the art will realize that the following description of the present invention is illustrative only and not in any way limiting. Other embodiments of the invention will readily suggest themselves to such skilled persons.
[0043] Referring now to
[0044] ReRAM device 110 is formed over a metal interconnect layer which, in the illustrative embodiment shown in
[0045] The tungsten via or damascene copper metal line 84 is shown surrounded by a barrier layer 86. A CMP stop layer may be formed over the top of the inter-metal dielectric layer 82 and is used in the process employed to planarize the top of damascene copper interconnect layer or tungsten via 84 as is known in the art. SiN or SiC are commonly employed as CMP stop layers.
[0046] Persons of ordinary skill in the art will appreciate that the CMP stop layers may not be required and are optional. Their use or non-use will depend on the CMP technology used by the manufacturer. Some CMP processes may be able to have a timed polish step and do not need the CMP stop layer. This is preferred because it makes the process of depositing the dielectric layers simpler. In addition, the removal of SiN which has a dielectric constant of 7 and its replacement with silicon oxide which has a dielectric constant of 4 is preferred and will reduce the coupling capacitance of the metal layers, thus improving the speed performance of the device.
[0047] In the ReRAM device depicted in
[0048] It is known that electrons can be made to tunnel across an ultra-thin dielectric layer, i.e., one that is less than 35 . According to one aspect of the present invention, an tunneling dielectric layer 102 formed from a material such as SiN, is deposited over the barrier metal layer 88, as an ultra-thin layer. This tunneling dielectric layer will reduce leakage in the off state. During the on state it will limit current flow through the ReRAM, although current sufficient to bias the switch node to the proper voltage will still flow.
[0049] A solid electrolyte layer 90 is formed above tunneling dielectric layer 102. The solid electrolyte layer 90 may be formed from a deposited layer of amorphous silicon. Other materials, such as chalcogenides (e.g., Ge.sub.2Sb.sub.2Te.sub.5 or AgInSbTe), NiO or TiO2, Ge or GeSe, TaOx may also be used. The thickness of the solid electrolyte layer 90 may range from about 50 to about 500 , a typical thicknesses being from about 200 to about 300 .
[0050] An ion source layer 92 is formed over the solid electrolyte layer 90 and is formed from a material such as Ag. Other materials, such as copper, and TiO.sub.2 may be used. The thickness of the ion source layer 92 may range from about 100 to about 2,000 , typical thicknesses being from about 300 to about 500 .
[0051] The stack of layers 88, 102, 90, and 92 is etched to form an aligned stack using conventional stack etching techniques. A dielectric barrier layer 94 formed from a material such as deposited SiN or SiC is formed over the defined stack. A via is formed in the dielectric barrier layer 94 to expose the upper surface of ion source layer 92. A barrier metal layer 100 is then formed over the dielectric barrier layer and makes contact with ion source layer 92. A top metal may be formed as a damascene copper or tungsten plug 98 or from Al or another metal used for interconnect layers in integrated circuits. The embodiment shown in
[0052] During the on state, the electrolyte is well populated with ions and has a relatively low resistance, allowing electrons to flow through it. Because electrons will tunnel through the tunneling dielectric layer 102, the tunneling dielectric layer 102 will act as a resistance. It is expected that, for a 1V cell, about 1 A will pass through the dielectric tunneling layer 102.
[0053] During the off state, the electrolyte layer 90 is not well populated with ions and has a relatively high resistance, so there will be few electrons flowing through it. Under these conditions, the tunneling dielectric layer 102 will then act as a very high resistance, thus reducing the off state leakage. It is important to note that the current through the tunneling dielectric 102 is a function of the number of electrons present at the potential barrier and the e-field across the barrier. The tunneling dielectric layer 102 presents a high resistance during the off state because the lower population of electrons at the potential barrier in the tunneling dielectric 102 causes a lower probability of electron tunneling. Conversely the tunneling dielectric 102 presents a much lower resistance during the on state because the presence of more electrons as a result of the ion density in the solid electrolyte 90 increases the probability of electron tunneling.
[0054] Referring now to
[0055] A thin dielectric layer 104 formed from a material such as SiO.sub.2 is placed between the top of the solid electrolyte layer 90 and the ion source layer 92. Other materials, such as SiN, doped SiO.sub.2, SiOxyNitride, may be used. The thickness of the thin dielectric layer 104 may range from about 5 to about 100 , typical thicknesses being from about 20 to about 30 .
[0056] The use of the thin dielectric layer 104 will reduce leakage of ReRAM device 120 in the off state, since the area of the metal/electrolyte interconnect is reduced, as described below.
[0057] In the off state, some electrons do pass through the solid electrolyte layer 90 as leakage. The number of electrons that get through the solid electrolyte layer 90 is a function of the interface between the ion source layer 92 and the solid electrolyte layer 90. Given the present state of integrated circuit fabrication technology, a square area of interface between ion source layer 92 and the solid electrolyte layer 90 having an area of about 32 nm32 nm is possible to achieve. By placing the thin dielectric layer 104 at this interface, a portion of the dielectric layer is punched through during the initial programming process. In particular, during initial programming some tunneling occurs, but some destructive punch through also occurs.
[0058] Because of the nature of the punch-through mechanism, the initial punch-through process occurs over only a portion of the thin dielectric layer 104, since the punch through follows the path of least resistance. This results in a reduced area of contact (much less than 32 nm32 nm) between the solid electrolyte layer 90 and the ion source layer 92.
[0059] Referring now to
[0060] ReRAM device 130 is a combination of the embodiments depicted in
[0061] ReRAM device 130 thus includes both the ultra-thin dielectric tunneling layer 102 of
[0062] Referring now to
[0063] The processes for fabricating the ReRAM devices shown in
[0064]
[0065] Next, as shown in
[0066] Next, as shown in
[0067] Next, as shown in
[0068] Next, as shown in
[0069] Next, as shown in
[0070] Next, as shown in
[0071] Persons of ordinary skill in the art will readily observe that
[0072] Referring now to
[0073] The table of
[0074] The voltages listed in
[0075] Before programming any of the ReRAM cells, they are all erased by placing both of the ReRAM devices in the ReRAM cells to their off states.
[0076] Column A represents the voltages applied to erase (turn off) all upper ReRAM devices in the cells. When the voltages listed in column A of the table are applied to the array of
[0077] Column B represents the voltages applied to erase all lower ReRAM devices in the cells. When the voltages listed in column B of the table are applied to the array of
[0078] Once all of the ReRAM cells have been erased, each ReRAM cell may be programmed to turn it on thereby turning on its associated switch transistor or to turn it off thereby turning off its associated switch transistor. As described below, the programming is accomplished responsive to the proper bias of the bitlines, word lines and respective programming transistor.
[0079] Column C represents the voltages applied to turn on the ReRAM cell at R1C1 by turning on the upper ReRAM device 12-1-1 in that cell to pull up the switch node to turn on the switch transistor. When the voltages listed in column C of the table are applied to the array of
[0080] Programming transistor 28-1-2 has 0V on its source, 2.5V on its gate and will be turned on, driving the switch node 22-1-2 in ReRAM cell R1C2 to 0V. Because both BL2 and BL2! have 0V on them, both ReRAM devices 12-1-2 and 14-1-2 in ReRAM cell R1C2 will have 0V across them and will not be programmed.
[0081] Programming transistors 28-2-1 and 28-2-2 each has 0V on its gate and will be turned off. The switch nodes 22-2-1 and 22-2-2 in ReRAM cells R2C1 and R2C2 will be either floating or at the potential on both bitlines BL2 and BL2! if one of the ReRAM devices in those cells has been programmed. Since bitlines BL2 and BL2! are both at 0V, no ReRAM devices in cells R2C1 and R2C2 in the second row of the array will be programmed.
[0082] Column D represents the voltages applied to turn off the ReRAM cell at R1C1 by turning on the lower ReRAM device 14-1-1 in that cell to pull down the switch node 22-1-2 to turn off the associated switch transistor. When the voltages listed in column D of the table are applied to the array of
[0083] Programming transistor 28-1-2 has 1.8V on its source, 2.5V on its gate and will be turned on, driving the switch node 22-1-2 in ReRAM cell R1C2 to 1.8V. Because BL2 and BL2! both have 1.8V on them, both ReRAM devices 12-1-2 and 14-1-2 in ReRAM cell R1C2 will have 0V across them and will not be programmed.
[0084] Programming transistors 28-2-1 and 28-2-2 each has 0V on its gate and will be turned off. The switch nodes 22-2-1 and 22-2-2 in ReRAM cells R2C1 and R2C2 will be either floating or at the potential on both bitlines BL2 and BL2! if one of the ReRAM devices in those cells has been programmed. All bitlines are at 1.8V, but because the switch nodes 22-2-1 and 22-2-2 are either floating or at the potential of bitlines BL2 and BL!2, no ReRAM devices in cells R2C1 and R2C2 in the second row of the array will be programmed.
[0085] Column E represents the voltages applied to turn on the ReRAM cell at R1C2 by turning on the upper ReRAM device 12-1-2 in that cell to pull up the switch node 22-1-2 to turn on the associated switch transistor. The conditions are similar to those for column C, except that the source of programming transistor 28-1-2 is now at 1.8V and is turned on (and the source of transistor 28-1-1 is now at 0V) and ReRAM device 12-1-2 is programmed because it has 0V at its top end and 1.8V on its bottom end. ReRAM device 14-1-2 will also have a voltage of 1.8V across it, but its bottom end is more negative than its top end and therefore ReRAM device 14-1-2 will not be programmed. Persons of ordinary skill in the art will appreciate that the ReRAM cells in the second row of the array are not programmed for the reasons set forth in the explanation of the column C conditions.
[0086] Column F represents the voltages applied to turn off the ReRAM cell at R1C2 by turning on the lower ReRAM device 14-1-2 in that cell to pull down the switch node 22-1-2 to turn off the associated switch transistor. When the voltages listed in column F of the table are applied to the array of
[0087] Programming transistor 28-1-1 has 1.8V on its source, 2.5V on its gate and will be turned on, driving the switch node 22-1-1 in ReRAM cell R1C1 to 1.8V. Because BL1 and BL1! both have 1.8V on them, both ReRAM devices 12-1-1 and 14-1-1 in ReRAM cell R1C1 will have 0V across them and will not be programmed.
[0088] Programming transistors 28-2-1 and 28-2-2 each has 0V on its gate and will be turned off. The switch nodes 22-2-1 and 22-2-2 in ReRAM cells R2C 1 and R2C2 will be either floating or at the potential on both bitlines BL1 and BL1! if one of the ReRAM devices in those cells has been programmed. All bitlines are at 1.8V, but because the switch nodes 22-2-1 and 22-2-2 are either floating or at the potential of bitlines BL1 and BL2!, no ReRAM devices in cells R2C1 and R2C2 in the second row of the array will be programmed.
[0089] Column G represents the voltages applied to turn on the ReRAM cell at R2C1 by turning on the upper ReRAM device 12-2-1 in that cell to pull up the switch node 22-2-1 to turn on the associated switch transistor. Column H represents the voltages applied to turn off the ReRAM cell at R2C1 by turning on the lower ReRAM device 14-2-1 in that cell to pull down the switch node 22-2-1 to turn off the associated switch transistor. Column I represents the voltages applied to turn on the ReRAM cell at R2C2 by turning on the upper ReRAM device 12-2-2 in that cell to pull up the switch node 22-2-2 to turn on the associated switch transistor. Column J represents the voltages applied to turn off the ReRAM cell at R2C1 by turning on the lower ReRAM device 14-2-2 in that cell to pull down the switch node 22-2-1 to turn off the associated switch transistor. From the conditions described with reference to columns C through F for programming the ReRAM cells in the first row of the array to either their on or off states, persons of ordinary skill in the art will readily appreciate from
[0090] While embodiments and applications of this invention have been shown and described, it would be apparent to those skilled in the art that many more modifications than mentioned above are possible without departing from the inventive concepts herein. The invention, therefore, is not to be restricted except in the spirit of the appended claims.