Natural Gas Liquid Pressure Regulating Vaporizer Sampling System

Abstract

Provided herein is a system and method for natural gas liquid sample conditioning including an insulated cabinet having a sample input, a vaporizer, a heated regulator, a gas sample outlet, and a control system for preventing phase separation and or re-liquification of the conditioned sample before entry into an associated analyzer and in a specific embodiment, featuring an automatic shutdown system to prevent sample liquid from further processing and passage to an associated analyzer.

Claims

1. A system for extracting and conditioning for analysis a non-cryogenic widegrade containing natural gas liquid sample, the system comprising: a) an insulated cabinet; b) a liquid sample input line; c) a vaporizer for flash vaporizing the liquid connected to the input line; d) a vaporized sample output line; e) a heated pressure regulator for receiving a vaporized sample from the vaporized sample output line; f) an output sample gas conduit line to a gas sample analyzer located outside the insulated cabinet, said output conduit line connected at one end to the heated pressure regulator; and g) a controller unit electrically connected to the vaporizer and the heated pressure regulator, said controller being connected to an electrical power source, the controller for monitoring the temperature and pressure of the vaporized sample outputted from the heated pressure regulator to fall within an acceptable operation range of the gas sample analyzer.

2. The system of claim 1 further comprising a speed loop associated with the vaporizer.

3. The system according to claim 2 further comprising a relief valve for pressure relief in the event of the gas sample outputted from the heated regulator being above the acceptable operational range of the gas sample analyzer.

4. The system according to claim 3 further comprising a communications facility associated with the controller unit.

5. The system according to claim 4 further comprising a liquid filter disposed in the sample input line and the vaporizer.

6. The system according to claim 5 further comprising a solenoid actuated valve disposed between the liquid filter and the input of the vaporizer for interrupting flow of the liquid sample to the vaporizer.

7. The system according to claim 1 further comprising a liquid filter disposed in the sample input line and the vaporizer and a solenoid actuated valve disposed between the liquid filter and the input of the vaporizer for interrupting flow of the liquid sample to the vaporizer.

8. A system for extracting and conditioning a non-cryogenic liquid sample for analysis by a downstream analyzer, the system comprising: a) an insulated cabinet; b) a sample input line; c) a vaporizer for flash vaporizing the sample connected to the input line; d) a vaporized sample output line; e) a heated pressure regulator for receiving a vaporized sample from the vaporized sample output line; f) an output sample gas conduit line to a gas sample analyzer located outside the insulated cabinet, said output conduit line connected at one end to the heated pressure regulator; and g) a controller unit for monitoring processing conditions in the insulated cabinet including activating a solenoid valve to interrupt liquid flow into the vaporizer upon detection of processing conditions deviating from pre-set ranges, the controller being in operation signal communication with the vaporizer, the heated pressure regulator, solenoid valve, and condition detection sensors, for monitoring sample temperature and pressure as the sample passes through the system to the vaporized sample output line to be within acceptable operation ranges, the controller being connected to an electrical power source, the controller and a communications module for remotely communicating monitored conditions.

9. The system according to claim 8 further comprising a filter and associated speed loop disposed in the sample input line.

10. The system according to claim 9 further comprising the solenoid valve being electrically connected to the controller unit and having a normally closed position which upon activation releases pressurized air to actuate a ball valve disposed liquid sample input line to shut off sample flow.

11. The system according to claim 9 further comprising a plurality of solenoid valves being electrically connected to the controller unit, each of the solenoid valves having a normally closed position which upon de-energizing each releases pressurized air to actuate an associated ball valve disposed in the liquid sample input line to shut off liquid flow to the vaporizer and in the vaporized sample output line to shut of vapor sample flow to the analyzer.

12. The system according to claim 11 further comprising a thermocouple input associated with the analyzer in communication with the controller unit to actuate the solenoid valves to shut off sample flow when the detected temperature of the analyzer falls below a pre-determined minimum.

13. The system according to claim 12 further comprising a pressure sensor associated with a carrier gas input for the analyzer in communication with the controller unit to idle the analyzer in the event the carrier gas level preset minimum.

14. The system according to claim 13 further comprising a relief valve for pressure relief in the event of the gas sample outputted from the heated regulator being above the acceptable operational range of the gas sample analyzer.

15. The system according to claim 14 where the sample is a liquid and a relief valve for pressure relief in the event of the gas sample outputted from the heated regulator being above the acceptable operational range of the gas sample analyzer.

16. A system for extracting and conditioning for analysis a non-cryogenic liquid sample, the system comprising: a) an insulated cabinet; b) a liquid sample input line; c) a vaporizer for flash vaporizing the liquid connected to the input line; d) a vaporized sample output line; e) a heated pressure regulator for receiving a vaporized sample from the vaporized sample output line; f) an output vaporized sample gas conduit line to a vaporized sample analyzer space apart and separate from the insulated cabinet, said output conduit line connected at one end to the heated pressure regulator; and g) a controller unit electrically connected to the vaporizer and the heated pressure regulator, said controller being connected to an power source, the controller for monitoring the temperature and pressure of the vaporized sample outputted from the heated pressure regulator to fall within an acceptable operation range of the vaporized sample analyzer.

17. The system according to claim 16 further comprising a relief valve for pressure relief in the event of the vaporized sample outputted from the heated regulator being above the acceptable operational range of the vaporized sample analyzer.

18. The system according to claim 17 further comprising a communications facility associated with the controller unit.

19. The system according to claim 18 further comprising a liquid filter disposed in the sample input line and the vaporizer.

20. The system according to claim 19 further comprising a liquid filter disposed in the sample input line and the vaporizer and a solenoid actuated valve disposed between the liquid filter and the input of the vaporizer for interrupting flow of the liquid sample to the vaporizer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0044] FIG. 1 is a schematic illustration of an embodiment of the natural gas liquid pressure regulating vaporizer system according to the invention.

[0045] FIG. 2 is schematic illustration of an alternative embodiment of the natural gas liquid pressure regulating vaporizer system according to the invention.

[0046] FIG. 3 is a schematic of automatic sample shutoff circuitry associated with the embodiment of FIG. 2.

[0047] FIG. 4 is a schematic illustration of an embodiment of a shutdown system in accordance with a further aspect of this invention.

DETAILED DESCRIPTION

[0048] FIG. 1 illustrates an embodiment of an inventive, single stream, natural gas liquid sample vaporizer system 10. The system comprises a cabinet 1 preferably conforming in standards to a Class 1, Division 1 Group C, D, t3 (<200 C.) requirements. The cabinet 12 is insulated fully with insulation 14 to maintain an internal elevated temperature. The internal cabinet components include gas lines 16, 18, and 20, in line pressure gauges 22 and 24, a sample NGL vaporizer 26 such as a 375 watt Mustang Vaporizer available from Mustang Sampling of Ravenswood, W. Va. US, and a 200 watt heated pressure regulator 28 both being securely mounted within the insulated cabinet 12.

[0049] Affixed to an appropriately dimensioned feedthrough in the exterior cabinet wall and projecting therefrom is an encased PID controller system 30 such as Watlow Single Controller (EZ-Zone) available from Watlow of St. Louis, Mo., US which is electrically interconnected and controls the sample system components. The controller 30 is electrically connected to an appropriate power source and incorporates a digital communication connection either providing standard hardwire connections, e.g., RS 485 or USB, or wireless communication technology.

[0050] The PID controller 30 is electrically connected to internal cabinet components through hard wiring passing through sealed feedthrough conduits 32 comprising appropriately-diametered, galvanized conduit (e.g., inch) with associated seal fittings reducers and the like. The construction of the feedthroughs and associated conduits must meet applicable standards such as NEC Sec. 500 (2011).

[0051] Turning to the gas sample pathway in respect to the cabinet 1 contemplated by the illustrated embodiment, the gas sample typically travels from a NGL extraction point through a small, sample gas line, generally consisting of small diameter stainless steel tubing connecting to a feedthrough 32 formed in a wall of the cabinet 12. Upon entry into the cabinet interior, the heavy hydrocarbon containing sample travels through the line to heated liquid sample vaporizer 26. The vaporizer 26 maintains the sample liquid below its bubble point pressure and temperature until it enters a low volume flash chamber having a very large heat transfer surface area where the sample is instantaneously vaporized. Heat for vaporization is transferred from an electrical cartridge heater associated with the vaporizer and connected to the controller 30. The flash chamber serves to maintain a homogeneous sample vapor that is representative of the actual liquid sample composition.

[0052] The junction of the vaporizer input may incorporate a pressure remediating speed loop or vent 36 to prevent sample over pressurization during the vaporizing step. That speed loop/vent which may incorporate an intermediate one-way check valve, is connected to the cabinet exterior via feedthrough vent. Such a speed loop and its function are described in Assignee's earlier issued U.S. Pat. No. 7,844,404, the content of which is incorporated in its entirety herein by reference. The particular form, diaphragm or piston, of the regulator is selectable by a user for a particular installation. Notably, diaphragm regulators are believed to provide superior performance in the case of liquid sample streams.

[0053] The vaporized sample is output through line 18 to the heated pressure regulator 28 where it is subject to both pressure and temperature conditioning and exits the heated regulator through a T connector 27 that feeds the vaporized sample to sample output line 20 and internal vent line 25 for venting vaporized samples exceeding an analyzer-safe pressure as measured by the gauge 24. and the properly heated and, pressurized vapor sample is communicated to an associated analyzer through the sample output 33 disposed in an appropriately isolated feedthrough feeding through the cabinet exterior that may include a venting capability featuring bug/insect resistant vent.

[0054] In ordinary operation, the vaporized liquid sample passes from the vaporizer to the heated regulator at high temperature and pressure to prevent dew point drop out/Joules-Thompson condensation of heavy hydrocarbons in the vaporized sample stream by maintaining heating the sample during the pressure reduction, the sample stream has been properly condition for passage out of the cabinet via sample analyzer feedthrough. The system itself preferably incorporates a communications facility to permit remote monitoring and control system allowing for changes to the system when deemed appropriate.

[0055] Turning to a variant of the above-described embodiment, the embodiment of FIG. 2 incorporates a sample conditioner shutdown system to prevent liquid incursion from the system output to an associated chromatograph for protection of the analyzer. In this embodiment, the PID controller 37 is an encased dual controller available again from Watlow as a Watlow Dual Controller (EZ-Zone). The illustrated embodiment features three solenoid controlled shut off valves disposed at select points along the sample pathway which are activated upon detection of an abnormal conditioning system parameter, e.g., heat, pressure, flow rate, back pressure, post-vaporization liquid detection, and even loss of system power. The redundancy of the shutoff valves is employed to maintain the system components at in operational readiness until the deviant parameter is corrected. This shutdown system valves off the flow of liquid if the temperatures monitored falls below a set point in either the sample conditioner cabinet components and even of the analyzer (i.e., the oven of a gas chromatograph) monitored through a thermocouple 46 connected to the controller (See FIG. 3). Pressures are monitored using conventionally disposed pressure transmitters that may be associated for example with the illustrated pressure gauges 16 and 24. Back pressure sensor/transmitters may also be included to compare against supply pressures. A further pressure switch 44 electrically controlled by the dual controller 37 may be incorporated into the system to insure that the analyzer carrier gas is sufficient for GC operation. In the event the carrier gas falls below a threshold pressure, e.g., 75 psig, the normally closed contact opens and idles the chromatograph and sample input thereto until the issue is corrected. Although not illustrated, the system can readily incorporate one or more electronic flow meters disposed along the sample pathway to insure that vaporized sample flow rates fall within acceptable parameters.

[0056] Upon detection of undesirable conditions or deviations capable of disabling an associated analyzer, i.e., too high a sample pressure, too low a sample temperature, or detection of liquid and resulting analyzer flooding, the shutdown embodiment of this invention electronically links the 30 controller which signals solenoids 38, 40, and 42 that control for example a conventional pneumatically actuated ball valve to shut down fluid sample input to the vaporizer, vaporized sample input to the heated regulator and sample output from the conditioner to the associated analyzer.

[0057] Referring now to FIG. 4, it illustrates a shutdown system incorporated into liquid sample conditioning system. The system is contained in a housing 50 which features a standard configuration sample vaporizer 52 and heated pressure regulator 54. In this embodiment, a sample from a select sampling point passes into the cabinet 50 via process sample inlet 56 and ultimately passes to the analyzer via sample output 57. The liquid sample pathway first leads from the input 56 to a filtered liquid speed loop featuring a filter member 58, preferably a self-cleaning 0.5 micron particulate filter such as a 602 T Tornado Filter, a bypass flow indicator 60, pressure gauge references 62 disposed both upstream and downstream of the filter member 58, with a return to process 64 and metered inlet and outlet. The filtered sample moves through appropriate tubing from the filter member 58 to a coalescing filter 66 for removal of aerosol and large droplets of liquids in sample stream (via a drain) which is particularly important when an oil may be present. The incorporation of filtering elements is optional unless particular circumstances so require, i.e., high oil content, large aerosol droplets, etc.

[0058] From the coalescing filter, the sample path lead to the vaporizer 52 which itself, as disclosed above, can feature a liquid speed loop featuring a built-in bypass. However, before the sample path reaches the vaporizer a solenoid actuated liquid interrupt valve 68 is interposed in the line. The interrupt valve 68 preferably is air actuated valve and blocks liquid flow into the vaporizer from the filters. The air is provided from an external source (e.g., nitrogen cylinder) through air line 69 from an instrument air port 70. The valve 68 is actuated by instrument air supplied by through pneumatic line 69 from a solenoid valve 70 electrically connected to the PID Controller 72. The solenoid valve 70 is normally closed when de-energizedthat is, it shuts off flow automatically in the event of a power loss. The PID controller can also de-energize the solenoid in the event a monitored system parameter deviates beyond a select threshold, e.g., the controller signal the solenoid to opens its contacts if the temperature drops below the application specific set point. In the case of multiple analyzer arrays disposed along a processing pathway, by continuously monitoring the temperatures, the sample conditioner 50, utilizing an integrated communication facility 73, i.e., a RS485 communication port, can send discrete alarm signals to downstream analyzers or digital control systems.

[0059] Accordingly, liquids or phase-separated vapor samples are blocked from entering the analyzer, which serves to prevent both distorted sample component analysis and/or analyzer damage. The shutoff embodiment also contemplates conditioner system sample flow shutdown in the event of a power failure. Power failures inevitably create pressure issues and significant temperature losses for samples just exiting the heated regulator. In the event of a power failure complete vaporization is impacted and phase separation readily occur for samples exiting the vaporizer flash chamber. Consequently, the present invention provides analyzer and data protection that has not been available in this application.

[0060] Although most applicable to NGL sample processing, the shutoff system contemplated herein is also applicable to monitor conditioning parameters in a variety of vaporized sample streams processed for introduction to analyzers.

[0061] The illustrated embodiments of the invention have been provided in the forgoing specification. It should be understood by those skilled in the art that many modifications and embodiments of the invention will come to mind to which the invention pertains, having benefit of the teaching presented in the foregoing description and associated drawing. Therefore, it also should understood that the invention is not limited to the specific embodiments disclosed herein, and that many modifications and other embodiments of the invention are intended to be included within the scope of the invention. Moreover, although specific terms are employed herein, they are used only in generic and descriptive sense, and not for the purposes of limiting the description invention.

INDUSTRIAL APPLICABILITY

[0062] The invention combines an system for properly collecting, conditioning and communicating uniform vaporized samples from a non-cryogenic liquid source such widegrade containing Natural Gas Liquid (NGL) from liquid input to an associated analyzer minimizing phase separation and reliquification that skew qualitative and quantitative constituent analysis and/or flood and damage the analyzer. In one embodiment, the invention also incorporates a shutdown system to isolate sample introduction to the analyzer while allowing for operational conditions to be maintained in the conditioner system.