METHOD AND DEVICE FOR THE LASER-BASED WORKING OF TWO-DIMENSIONAL, CRYSTALLINE SUBSTRATES, IN PARTICULAR SEMICONDUCTOR SUBSTRATES
20170157700 · 2017-06-08
Inventors
Cpc classification
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
International classification
B23K26/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates to a method for laser-based machining of a planar, crystalline substrate in order to separate the substrate into a plurality of parts, in which the laser beam of a laser is directed, for machining the substrate, onto the latter, in which, with an optical arrangement positioned in the beam path of the laser, a laser beam focal surface which is expanded, viewed both along the beam direction and viewed in precisely a first direction perpendicular to the beam direction, but is not expanded in a second direction which is both perpendicular to the first direction and to the beam direction, is formed from the laser beam radiated onto said arrangement on the beam output side of the optical arrangement, the substrate being positioned relative to the laser beam focal surface such that the laser beam focal surface in the interior of the substrate, along an expanded surface portion of the substrate material, produces an induced absorption by means of which crack formations in the substrate material induced along this expanded surface portion are effected.
Claims
1. Method for laser-based machining of a planar, crystalline substrate in order to separate the substrate into a plurality of parts, in which the laser beam (2a, 2f) of a laser (3) is directed, for machining the substrate (1), onto the latter, in which, with an optical arrangement (6) positioned in the beam path of the laser (3), a laser beam focal surface (2f) which is expanded, viewed both along the beam direction (z) and in precisely a first direction (y) perpendicular to the beam direction (z), but which is not expanded in a second direction (x) which is both perpendicular to the first direction (y) and to the beam direction (z), is formed, from the laser beam (2a) radiated onto said optical arrangement (6), on the beam output side of the optical arrangement (6), the substrate (1) being positioned relative to the laser beam focal surface (2f) such that the laser beam focal surface (2f) produces, in the interior of the substrate (1) along an expanded surface portion (2c) of the substrate material, an induced absorption by means of which induced crack formations in the substrate material along this expanded surface portion (2c) are effected.
2. Method according to the preceding claim, characterised in that the planar, crystalline substrate is or comprises the following: a semiconductor substrate, in particular a 4-6 or 3-5 semiconductor substrate, preferably a GaAs substrate, or an elementary semiconductor substrate, preferably an Si substrate, an insulator substrate, in particular an oxide, preferably Al.sub.2O.sub.3 (sapphire) or SiO.sub.2 (quartz), or a fluoride, preferably CaF.sub.2 or MgF.sub.2, or a chloride, preferably NaCl, or a nitride, preferably Si.sub.3N.sub.4 or BN, and/or a substrate comprising or consisting of at least one carbon-based material with crystalline or quasi-crystalline basic order, in particular comprising or consisting of carbon nanotubes.
3. Method according to one of the preceding claims, characterised in that the expansion of the laser beam surface (2f), subsequently termed length l, in beam direction (z) is configured to be larger by at least times, preferably by at least 20 times, preferably by at least 50 times, preferably by at least 100 times, preferably by at least 500 times, than the expansion D of the laser beam focal surface (2f) in the second direction (x), and/or in that the expansion of the laser beam focal surface (2f), subsequently termed width b, in the first direction (y) is configured to be larger by at least 5 times, preferably by at least 10 times, preferably by at least 50 times, preferably by least 100 times, than the expansion D of the laser beam focal surface (2f) in the second direction (x).
4. Method according to one of the preceding claims, characterised in that the substrate (1) is positioned relative to the laser beam focal surface (2f) such that, viewed in beam direction (z), the expanded surface portion (2c) of the induced absorption in the material, i.e. in the interior of the substrate (1), extends up to at least one of the two oppositely situated substrate surfaces (1a, 1b).
5. Method according to the preceding claim, characterised in that the substrate (1) is positioned relative to the laser beam focal surface (2f) such that, viewed in beam direction (z), the expanded surface portion (2c) of the induced absorption in the material, i.e. in the interior of the substrate (1), extends from one (1a) of the two oppositely situated substrate surfaces to the other (1b) of the two oppositely situated substrate surfaces, i.e. over the entire layer thickness d of the substrate (1), or in that the substrate (1) is positioned relative to the laser beam focal surface (2f) such that, viewed in beam direction (z), the expanded surface portion (2f) of the induced absorption in the material, i.e. in the interior of the substrate (1), starting from one (1a) of the two oppositely situated substrate surfaces, extends into the substrate (1), but not up to the other (1b) of the two oppositely situated substrate surfaces, i.e. not over the entire layer thickness d of the substrate (1), extends preferably over 80% to 98%, preferably over 85% to 95%, particularly preferably over 90%, of this layer thickness.
6. Method according to one of the preceding claims, characterised in that the induced absorption is produced such that the crack formation in the structure of the substrate (1) is effected without ablation and without melting of material of the substrate (1).
7. Method according to one of the preceding claims, characterised in that the length l of the laser beam focal surface (2f) is between 0.2 mm and 10 mm, preferably between 0.5 mm and 2 mm, and/or in that the width b of the laser beam focal surface (2f) is between 0.02 mm and 2.5 mm, preferably between 0.05 mm and 0.2 mm, and/or in that the layer thickness d of the substrate (1), measured perpendicular to the two oppositely situated substrate surfaces (1a, 1b), is between 2 m and 3,000 m, preferably between 100 m and 500 m, and/or in that the ratio V1=1/d of the length l of the laser beam focal surface (2f) and the layer thickness d of the substrate (1) is between and 0.5, preferably between 5 and 2, and/or in that the expansion D of the laser beam focal surface (2f) in the second direction (x) is between 1 m and 50 m, preferably between 5 m and 25 m.
8. Method according to one of the preceding claims, characterised in that a pulsed laser is used as laser (3), and/or in that the pulse duration t of the laser (3) is chosen such that, within the interaction time with the material of the substrate (1), the heat diffusion in this material is negligible, preferably no heat diffusion is effected, for which purpose preferably , F as surface expansion of the laser beam focal surface (2f) and the heat diffusion constant of the material of the substrate (1) are adjusted according to <<F/ and/or preferably is chosen to be less than ns, preferably less than 100 ps, and/or in that the pulse repetition frequency of the laser (3) is between 10 kHz and 1,000 kHz, preferably 100 kHz, and/or in that the laser (3) is operated as a single pulse laser or as a burst pulse laser, and/or in that the average laser power, measured directly on the beam output side of the laser (3), is between 5 watts and 100 watts, preferably between 15 watts and 30 watts.
9. Method according to one of the preceding claims, characterised in that the wavelength of the laser (3) is chosen such that the material of the substrate (1) is transparent at this wavelength or is substantially transparent, there being understood by the latter that the intensity reduction of the laser beam, effected along the beam direction (z), in the material of the substrate (1) is, per millimetre of penetration depth, 10% or less, the laser, in particular for crystals which are transparent in the visible wavelength range as substrate (1), is preferably an Nd:YAG laser with a wavelength of 1,064 nm or a Y:YAG laser with a wavelength of 1,030 nm, or, in particular for semiconductor substrates (1) which are transparent in the infrared wavelength range, is preferably an Er:YAG laser with a wavelength between 1.5 m and 2.1 m.
10. Method according to one of the preceding claims, characterised in that the laser beam (2a, 2f) is moved, relative to the surface (1a) of the substrate (1), along a line (5), preferably along a line (5) parallel to the first direction (y), along which the substrate (1) is to be separated in order to obtain a plurality of parts, a large number (2c-1, 2c-2, . . . ) of expanded surface portions (2c) of induced absorption in the interior of the substrate (1) being produced along this line (5), preferably the ratio V2=A/b of the average spacing A of directly adjacent expanded surface portions (2c) of induced absorption, i.e. of expanded surface portions (2c) of induced absorption being produced directly successively, and of the width b of the laser beam focal surface (2f) in the first direction (y) is between 1.0 and 1.3, preferably between 1.0 and 1.1.
11. Method according to the preceding claim, characterised in that during and/or after production of the large number (2c-1, 2c-2, . . . ) of expanded surface portions (2c) of induced absorption in the interior of the substrate (1), mechanical forces are exerted on the substrate (1) and/or thermal stresses are introduced into the substrate (1), in particular the substrate is heated non-uniformly and cooled again in order to effect, respectively between directly adjacent (2c-1, 2c-2) expanded surface portions (2c) of induced absorption, a crack formation in order to separate the substrate into the plurality of parts.
12. Device for laser-based machining of a planar, crystalline substrate in order to separate the substrate into a plurality of parts, with which the laser beam (2a, 2f) of a laser (3), for machining the substrate (1), is directable onto the latter, characterised by an optical arrangement (6) positioned in the beam path of the laser (3), with which a laser beam focal surface (2f) which is expanded, viewed both along the beam direction (z) and in precisely a first direction (y) perpendicular to the beam direction (z), but which is not expanded in a second direction (x) which is both perpendicular to the first direction (y) and to the beam direction (z), can be formed, from the laser beam (2a) radiated onto said optical arrangement (6), on the beam output side of the optical arrangement (6), the substrate (1) being positionable or positioned relative to the laser beam focal surface (2f) such that the laser beam focal surface (2f) produces, in the interior of the substrate (1) along an expanded surface portion (2c) of the substrate material, an induced absorption, as a result of which crack formations in the substrate material induced along this expanded surface portion (2c) are effected.
13. Device according to the preceding claim, characterised in that the optical arrangement (6) for forming the laser beam focal surface (2f) which is expanded, viewed both along the beam direction (z) and viewed in precisely the first direction (y) perpendicular to the beam direction (z), but which is not expanded in the second direction (x), comprises an optical element (9), preferably a conical prism or axicon, with a non-spherical free surface which is formed to form the laser beam focal surface (2f) with a defined length l, i.e. with a defined expansion viewed in the beam direction (z), and also on the beam output side of this optical element (9) with the non-spherical free surface and also at a spacing z1 therefrom, a diaphragm (8) which cuts the expansion of the laser beam (2a) in the second direction (x), i.e. which is orientated with the preferential direction in the first direction (y), preferably a slit diaphragm (8) which is orientated in the first direction (y).
14. Device according to the preceding claim, characterised in that between the optical element (9) with the non-spherical free surface and the diaphragm (8), an optical element (12) collimating the laser beam (2a), in particular a plano-convex collimation lens (12), is positioned and orientated such that the laser radiation emanating from the optical element (9) with the non-spherical free surface is projected parallel onto the diaphragm (8).
15. Device according to one of the three preceding claims, characterised in that the optical arrangement (6) for forming the laser beam focal surface (2f) which is expanded, viewed both along the beam direction (z) and viewed in precisely the first direction (y) perpendicular to the beam direction (z), but which is not expanded in the second direction (x), comprises an optical element (9), preferably a conical prism or axicon, with a non-spherical free surface which is formed to form the laser beam focal surface (2f) with a defined length l, i.e. with a defined expansion viewed in beam direction (z), and also on the beam output side of this optical element (9) with the non-spherical free surface and also at a spacing z2 therefrom, an optical element (7) which focuses the laser beam (2a) in the first direction (y) but not in the second direction (x), preferably a cylindrical lens (7) orientated parallel to the second direction (x).
16. Device according to one of the three preceding claims, characterised in that the optical arrangement (6), on the beam output side of the diaphragm (8) or of the optical element (7) which focuses the laser beam (2a) in the first direction (y) but not in the second direction (x), comprises an optical element (11) which focuses the laser beam (2a) at least in the first direction (y), preferably a collimation lens which focuses the laser beam (2a) in the first (y) and in the second (x) direction, for particular preference a plano-convex collimation lens (11).
17. Device according to one of the five preceding claims, characterised in that the optical arrangement (6) for forming the laser beam focal surface (2f) which is expanded, viewed both along the beam direction (z) and viewed in precisely the first direction (y) perpendicular to the beam direction (z), but which is not expanded in the second direction (x), has an optical element (13), preferably has a double wedge (13), with which beam bundles (s1, s2) are deflectable from the two half spaces (y1, y2), which half spaces (y1, y2) are situated, viewed in the first direction (y), oppositely relative to the optical axis (6z) of the optical arrangement (6), respectively parallel and towards the optical axis (6z), and also comprises, on the beam output side of this optical element (13), an optical element which focuses the laser beam (2a) at least in the first direction (y), preferably a collimation lens which focuses the laser beam (2a) in the first (y) and in the second (x) direction, particularly preferably a plano-convex collimation lens (11).
18. Use of a method or of a device according to one of the preceding claims for separating a semiconductor substrate, in particular a 4-6 or 3-5 semiconductor substrate, preferably a GaAs substrate, or an elementary semiconductor substrate, preferably an Si substrate, separating an insulator substrate, in particular an oxide, preferably of Al.sub.2O.sub.3 (sapphire) or of SiO.sub.2 (quartz), or a fluoride, preferably of CaF.sub.2 or of MgF.sub.2, or a chloride, preferably of NaCl, or a nitride, preferably of Si.sub.3N.sub.4 or of BN, or separating a substrate comprising or consisting of at least one carbon-based material with crystalline or quasi-crystalline basic order, in particular comprising or consisting of carbon nanotubes.
Description
[0049] Subsequently, the present invention is now described with reference to some of the embodiments based on what was described above. There are thereby shown:
[0050]
[0051]
[0052]
[0053]
[0054]
[0055]
[0056]
[0057]
[0058]
[0059] The beam formation effected for this purpose via elements 8, 7 and 13 which are essential to the invention (cf.
[0060] By means of the beam formation according to the invention, which is described subsequently in more detail, the previously circular halo region (
[0061] As
[0062] As
[0063]
[0064] Subsequently, concrete optical arrangements 6 which can be used for the production of the focal surface 2f are described. All of the arrangements are thereby based on what has previously been described so that respectively identical references are used for components or features which are identical or correspond in their function. Subsequently, respectively only the differences are therefore described.
[0065] Since the separation surface leading ultimately to separation is or should, according to the invention, be of high quality (with respect to breaking resistance, geometric precision, roughness and avoidance of re-machining requirements), the individual (more precisely: produced by individual laser pulses) focal surfaces to be positioned along the separation line 5 (cf.
[0066]
[0067] In the case shown in
[0068] According to the invention, it is thereby particularly advantageous to produce the focal surface positioning such that at least one of the surfaces 1a, 1b is covered by the focal surface, the portion of induced absorption 2c begins hence at at least one surface. In this way, almost ideal cuts can be achieved by avoiding ablation, burr- and particle formation on the surface.
[0069] The optical arrangements shown in
[0070]
[0071] On the beam output side of the lens 12, a one-dimensional slit diaphragm 8 is positioned at the spacing z1 with z1>z1 (here: z1=1.3z1). The slit diaphragm 8 is orientated with its preferential direction (i.e. slit direction) in the first direction, i.e. the y-direction. The slit diaphragm (subsequently also termed alternatively slit diaphragm) 8 is thereby positioned such that the optical axis 6z, viewed in the second direction x, extends centrally between the two slit edges. The slit width is chosen such that it corresponds with the inner diameter 2i of the annular beam bundle 2r on the output side of the lens 12: as
[0072] On the beam output side of the diaphragm 8 and at a spacing from the latter, a further plano-convex collimation lens 11, which serves here as focusing lens, is positioned centred about the optical axis 6z: said focusing lens focuses all of the beam components, not occluded by the diaphragm 8, of the previously annular beam bundle 2r into the first y and into the second x direction towards the planar substrate 1 which is disposed on the beam output side of this lens 11, perpendicular to the optical axis 6z, i.e. in the x-y plane. The lens 11 (the planar side of which is orientated towards the substrate 1) hence focuses the beam components, not occluded by the diaphragm 8, of the previously annular beam bundle 2r at a defined spacing from the lens 11 onto a two-dimensional laser beam focal surface 2f with a defined expansion in the z-direction (due to the effect of the axicon 9) and also with a defined expansion in the y-direction (due to the effect of the diaphragm 8); see in this respect the beam formation illustrated in
[0073] The optical properties of the optical arrangement 6 which comprises the rotationally-symmetrical elements 9, 12 and 11, positioned on the optical axis 6z, and also the diaphragm 8 (in particular the geometric forming of elements 9, 12, 8 and 11 and the positioning thereof relative to each other along the main beam axis 6z) can thereby be chosen such that the expansion 1 of the laser beam focal surface 2f in z-direction is twice as large as the thickness d of the substrate in z-direction. If the substrate is then positioned centred relative to the focal surface 2f (cf.
[0074] Instead of the plano-convex lenses 11, 12 shown in
[0075]
[0076] In the beam path 2a, the plano-convex, focusing cylindrical lens 7 is positioned on the beam output side of the axicon 9 instead of the lens 12 in
[0077] At a defined spacing z2 behind the cylindrical lens 7, the focusing plano-convex collimation lens 11 is positioned in the beam path, centred about the optical axis 6z, as in the embodiment of
[0078] Also due to the combination of the rotationally-symmetrical axicon 9 with the cylindrical lens 7 and also the subsequent focusing by the rotationally-symmetrical plano-convex collimation lens 11, the beam formation from
[0082] A further example of a device according to the invention for producing an expanded focal surface 2f is shown in
[0083] In the beam path 2a of the laser 3 (not shown), firstly a non-rotationally-symmetrical optical element 13 provided with a preferential direction (here: x-direction) is positioned. This is configured as a planar element on the beam output side which deflects on the beam input side and is centred on the optical axis 6z. The planar side therefore points towards the substrate 1. The deflecting side situated opposite the planar side (i.e. pointing towards the laser 3) is configured as a pointed-roof-shaped double wedge, the central backbone of which extends along the x-direction and though the optical axis 6z. The element 13 is subsequently termed also double wedge for simplification.
[0084] As
[0085] Viewed in beam direction at a spacing from the wedge 13 (behind the intersection point of the two beam components s1 and s2), a cylindrical lens 7 is positioned, as in the example of
[0086] Viewed in beam direction, the plano-convex collimation lens 11 is positioned behind the cylindrical lens 7 i.e. at a defined spacing z3 on the beam output side of the double wedge 13 (as in the examples from
[0087]
[0088] As
[0089] The repetition rate of the laser pulses is coordinated to the feed speed of the laser such that the average spacing A of immediately adjacent expanded surface portions 2c of induced absorption, i.e. produced by temporally directly successive laser pulses, is slightly (e.g. by the factor larger than the width b of the laser beam focal surface 2f in feed direction or y-direction. Hence, without intensity overlapping, introduction of a large number of defect structures 2c which are placed immediately in a row along the channel axis 1k or the desired separation line 5 is effected and hence efficient separation of the substrate 1 along such channels 1k. The substrate residues which still remain between two adjacent defect structures 2c and are detectable here as gaps can readily effect crack formations due to the effect of mechanical forces and/or thermal stresses in order to separate finally from each other the substrate fragments produced on both sides of the separation line 5.