Hot gas filtration system and process for regenerating said system
09669344 ยท 2017-06-06
Assignee
Inventors
Cpc classification
B01D46/71
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D46/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates to a hot gas filtration system and a process for regenerating such a hot gas filtration system, said filtration system comprising a filter vessel, a tubesheet separating the interior of said filter vessel into a raw gas section and a clean gas section, and a plurality of filter elements. Said filter elements, arranged in two or more groups, are connected to the tubesheet with a clean end and extend with a raw gas portion into the raw gas section. Two or more plenum chambers are accommodated in the clean gas section and groupwise accommodate the clean gas ends of the filter elements, each of said plenum chambers comprising a gas exchange opening providing a direct fluid communication with the clean gas section. The hot gas filtration system furthermore comprises a blowback arrangement comprising a blowback gas reservoir and a blowback gas pipe for each group of filter elements, said blowback gas pipes having an outlet positioned in said clean gas section of the vessel, said outlet of the blowback gas pipes being directed at the gas exchange opening of the plenum chambers, said outlet of said blowback pipe having a free cross-sectional area of from about 10% to about 90% of the free cross-sectional area of said gas exchange opening.
Claims
1. A hot gas filtration system comprising a filter vessel having an interior, a tubesheet separating the interior of the filter vessel into a clean gas section and a raw gas section, said filter vessel comprising at its raw gas section a raw gas inlet and at its clean gas section a clean gas outlet, a plurality of filter elements made of ceramic material or metal, and having a raw gas portion and a clean gas end, said plurality of filter elements being arranged in two or more separate groups of two or more filter elements, said filter elements being connected to the tubesheet with their clean gas ends and extending from the tube sheet with their raw gas portions into the raw gas section of the interior of said vessel, two or more separate plenum chambers accommodated in the clean gas section of the interior of the filter vessel, each separate plenum chamber accommodating the clean gas ends of the filter elements of a corresponding separate group of filter elements, each of said separate plenum chambers comprising a corresponding separate gas exchange opening providing a direct fluid communication of its interior with the clean gas section of the interior of the filter vessel, a blowback arrangement comprising a blowback gas reservoir, and a separate blowback gas pipe for each corresponding separate group of filter elements, the blowback arrangement delivering non-sonic jet pulses of blowback gas from the blowback gas reservoir via the separate blowback gas pipes into the separate plenum chambers via the corresponding separate gas exchange openings such that a volume of clean gas of the clean gas section is sucked into the separate plenum chambers, said separate blowback gas pipes each having a corresponding separate outlet positioned in said clean gas section of the vessel, said corresponding separate outlet of the separate blowback gas pipes being directed at the corresponding separate gas exchange opening of the separate plenum chambers, wherein said corresponding separate outlet of said corresponding separate blowback gas pipe is positioned flush with the upper end of the corresponding separate gas exchange opening of said separate plenum chamber, wherein a gap is present between each corresponding separate outlet of the corresponding separate blowback gas pipe and the upper end of the corresponding separate gas exchange opening of the separate plenum chamber, the gap allowing the non-sonic jet pulses of blowback gas from the blowback gas reservoir to pass via the separate blowback gas pipes into the separate plenum chambers via the corresponding separate gas exchange openings such that a volume of clean gas of the clean gas section is sucked into the separate plenum chambers, said corresponding separate outlet of said blowback pipe having a free cross-sectional area of from about 15% to about 50% of the free cross-sectional area of said corresponding separate gas exchange opening of said separate plenum chambers.
2. The hot gas filtration system of claim 1, wherein the plenum chamber has a non-circular configuration.
3. The hot gas filtration system of claim 1, wherein each blowback pipe has an inner diameter and wherein the blowback arrangement comprises blowback valves, each blowback valve having a nominal diameter, the ratio of the nominal diameter of each blowback valve to the inner diameter of each blowback pipe being from about 0.8 to about 1.1.
4. The hot gas filtration system of claim 3, wherein the blowback valves have an opening time of about 400 msec or less.
5. The hot gas filtration system of claim 4, wherein the blowback valves have an opening time of about 200 msec or less.
6. The hot gas filtration system of claim 3, wherein the ratio of the nominal diameter of each blowback valve to the inner diameter of each blowback pipe being from about 0.9 to about 1.1.
7. The hot gas filtration system according to claim 1, wherein the system comprises a plurality of safety fuses, each filter element being connected at its clean gas end to one of the safety fuses.
8. The hot gas filtration system of claim 1, wherein the free cross-sectional area of the blowback gas pipe amounts to about 20% to about 40% of the free cross-sectional area of the gas exchange opening of the plenum chamber.
9. A process for regenerating a hot gas filtration system, the system comprising: a filter vessel having an interior, a tubesheet separating the interior of the filter vessel into a clean gas section and a raw gas section, said filter vessel comprising at its raw gas section a raw gas inlet and at its clean gas section a clean gas outlet, a plurality of filter elements made of ceramic material or metal, and having a raw gas portion and a clean gas end, said plurality of filter elements being arranged in two or more groups of two or more filter elements, said filter elements being connected to the tubesheet with their clean gas ends and extending with their raw gas portions into the raw gas section of the interior of said vessel, two or more separate plenum chambers accommodated in the clean gas section of the interior of the filter vessel, each separate plenum chamber accommodating the clean gas ends of the filter elements of a corresponding separate group of filter elements, each of said separate plenum chambers comprising a corresponding separate gas exchange opening providing a direct fluid communication of its interior with the clean gas section of the interior of the filter vessel, a blowback arrangement comprising a blowback gas reservoir, and a separate blowback gas pipe for each corresponding separate group of filter elements, said separate blowback gas pipes each having a corresponding separate outlet positioned in said clean gas section of the vessel, said corresponding separate outlet of the separate blowback gas pipes being directed at the corresponding separate gas exchange opening of the separate plenum chambers, wherein said corresponding separate outlet of said corresponding separate blowback gas pipe is positioned flush with the upper end of the corresponding separate gas exchange opening of said separate plenum chamber, wherein a gap is present between each corresponding separate outlet of the corresponding separate blowback gas pipe and the upper end of the corresponding separate gas exchange opening of the separate plenum chamber, the process comprising the blowback arrangement delivering non-sonic jet pulses of blowback gas from the blowback gas reservoir via the separate blowback gas pipes into the separate plenum chambers via the corresponding separate gas exchange openings such that a volume of clean gas of the clean gas section is sucked into the separate plenum chambers, the gap allowing the non-sonic jet pulses of blowback gas from the blowback gas reservoir to pass via the separate blowback gas pipes into the separate plenum chambers via the corresponding separate gas exchange openings such that a volume of clean gas of the clean gas section is sucked into the separate plenum chambers, said corresponding separate outlet of said blowback pipe having a free cross-sectional area of from about 15% to about 50% of the free cross-sectional area of said corresponding separate gas exchange opening of said separate plenum chambers.
10. The process of claim 9, wherein the jet pulse is provided to a fraction of groups of filter elements during continued filtration operation of the remainder of the groups of filter elements.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
DETAILED DESCRIPTION OF THE INVENTION
(7)
(8) The filter vessel 12 comprises in its raw gas section 14 a raw gas inlet 20 which is in fluid communication with the raw gas section 14.
(9) On its upper portion, the filter vessel 12 comprises a clean gas outlet 22 which is in fluid communication with the clean gas section 16.
(10) The tubesheet 18 extending over the whole cross-sectional area of the filter vessel 12 comprises a plurality of openings (not shown in detail) each of which accommodates a filter element 24 and 25, respectively. The filter elements 24 comprise a clean gas end 26 and a raw gas portion 28, the clean gas ends 26 are connected to the tubesheet 18 whereas the raw gas portions 28 extend from the tubesheet 18 downwards into a raw gas section 14 of the filter vessel 12. Similarly, the filter elements 25 have clean gas ends 27 which are accommodated in the tubesheet 18 and raw gas portions 29 extending into the raw gas section 14 of the filter vessel 12.
(11) The plurality of filter elements 24, 25 is subdivided into a plurality of groups (in
(12) In the lower portion of the filter vessel 12, a conically shaped portion 34 is provided which closes the lower end of filter vessel 12 and comprises an outlet 35 for particulate contaminant matter.
(13) On top of the tubesheet 18, two plenum chambers 36, 38 are mounted each of which accommodates the clean gas ends 26, 27 of one group of filter elements 30 and 32, respectively.
(14) In a central position of the top wall of each plenum chamber 36, 38, a tubular extension 40, 42 is mounted the upper end of which provides a gas exchange opening 44 and 46, respectively.
(15) Raw gas entering the raw gas inlet 20 of the filter vessel 12 is filtered by the plurality of filter elements 24, 25 and penetrates through the porous structure of the tubular filter elements 24, 25 whereby contaminants comprised in the raw gas are removed from the gas so that in the interior of the filter elements 24, 25 clean gas is accumulating which is discharged via the clean gas ends 26 and 27, respectively, into the plenum chambers 36 and 38, respectively. The filter elements may be made of a sintered ceramic material or of metal.
(16) From the plenum chambers 36, 38 the clean gas exits into the clean gas section 16 via the gas exchange openings 44 and 46. From the clean gas section 16, the clean gas is discharged via the clean gas outlet 22 from the filter vessel 12.
(17) Depending on the amount of contaminants contained in the raw gas fed into raw gas inlet 20, the filter elements 24 and 25 need to be regenerated more or less frequently in order to remove the contaminants attached to the upstream surface of the filter elements 24, 25 and avoid building of bridges of contaminant material between adjacent filter elements 24 and 25, respectively. For detaching a contaminant material adhering to the upstream surface of the filter elements 24 and 25, a blowback arrangement 50 is provided which comprises a blowback gas reservoir 52 which holds, for example, air at a high pressure of about, e.g., 1 to 5 bar. The blowback arrangement 50 comprises blowback pipes 54, 56 which are connected to the blowback gas reservoir 52 via blowback gas valves 58, 60.
(18) These blowback valves 58, 60 are separately operable and independent of each other, so that high pressure gas from the gas reservoir 52 may be delivered via the blowback gas pipes 54 and 56, respectively, via the outlet ends 62, 64 of the blowback gas pipes 54, 56 which are directed to the gas exchange openings 45, 46 of the plenum chambers 36 and 38, respectively.
(19) By operating the blowback gas valves 58 or 60, the groups 30 and 32 of filter elements 24 or 25 may be regenerated independently from one another by a blowback gas pulse delivered from the gas reservoir 52 via the blowback gas valves 58 and 60 and the blowback pipes 54 and 56. The gas pulses are delivered to the plenum chambers 36 and 38 through their gas exchange openings 44 and 46.
(20) The free cross-sectional area of the gas exchange openings 44 and 46 are larger than the free cross-sectional area of the outlet ends 62, 64 of the blowback gas pipes 44 and 46, respectively. The free cross-sectional area of the outlet openings of the blowback pipes 54 and 56 amount, e.g., to about 12% to 90% of the free cross-sectional area of the gas exchange opening of the respective plenum chamber. The outlet ends 62, 64 of the blowback gas pipes 54, 56 are not sealed to the gas exchange openings 44 and 46 so that a gap in between the outlet ends 62 and 64 and the respective gas exchange openings 44 and 46 exists which allows clean gas to exit the plenum chambers 36, 38 during normal filtration operation substantially unimpeded.
(21) By delivering a blowback gas pulse to the plenum chamber 36 or 38, gas from the clean gas section 16 is drawn into the plenum chamber 36 or 38 through the gap between the outlet ends 62, 64 and the gas exchange openings 44 and 46, respectively, thereby increasing the gas volume fed into the plenum chamber and subsequently into the group of filter elements 24 or 25.
(22) The present invention need not to make use of sonic or supersonic jet pulses when delivering the gas from the blowback gas reservoir 52 to the plenum chambers 36 and 38, but rather large confined pulses the volume of which is increased by the clean gas sucked in from the clean gas section 16 provide satisfactory regeneration effects.
(23) Because of this arrangement, very high cleaning intensities can be provided, and there is a high flexibility for adjusting the cleaning intensities over a wide range by modifying the blowback gas pressure.
(24) The particulate contaminants adhering to the filter elements 24 and 25 on their upstream surface is detached by the blowback gas pulses delivered to the plenum chambers 36 and 38 and subsequently to the interior space of the tubular filter elements 24 and 25. The contaminant material is detached from the upstream surfaces of these filter elements 24 and 25 conveyed by gravity into the lower conical portions 44 of the filter vessel 12 may be removed by a closeable particulate outlet 35 (not shown in detail).
(25)
(26) However, in addition to the structural characteristics of the hot gas filtration system 10 of
(27) The safety fuses 70 are mounted coaxially on the clean gas ends 26 and 27 of the filter elements 24 and 25, respectively.
(28) Raw gas entering the raw gas inlet 20 of filter vessel 12 is filtered by the plurality of filter elements 24, 25 and penetrates through the porous structure of the tubular filter elements 24, 25 whereby contaminants comprised in the raw gas are removed from the gas so that in the interior of the filter elements 24, 25 clean gas is accumulating, which is discharged via the clean gas ends 26 and 27, respectively. Before the clean gas exits from the filter elements 24, 25 into the plenum chambers 36 and 38, respectively, the clean gas has to pass through the safety fuses 70. Because of their larger porosity, the safety fuses 70 do not substantially increase the pressure drop.
(29) From the plenum chambers 36, 38, the clean gas exits into the clean gas section 16 via the gas exchange openings 44 and 46. From the clean gas section 16, the clean gas is discharged via the clean gas outlet 22 from the filter vessel 12 as is the case for the hot gas filtration system 10 of
(30) For detaching a contaminant material adhering to the upstream surface of the filter elements 24 and 25, the blowback arrangement 50 is operated the same way as it has been described for the hot gas filtration system 10 above.
(31) Blowback gas is delivered via the outlet ends 62, 64 of the blowback gas pipes 54, 56 which are directed to the gas exchange openings 45 and 46, respectively, of the plenum chambers 36, 38, respectively. The blowback gas penetrates through the safety fuses 70 and then enters into the interior of the filter elements 24, 25.
(32) Because of the larger porosity of the safety fuses 70, very high cleaning intensities can also be provided for the hot gas filtration system 10, and again a high flexibility for adjusting the cleaning intensities over a wide range by modifying the blowback gas pressure exists.
(33)
(34) The plenum chamber 100 is composed of two straight side walls 102, 104 and an outer and an inner arcuate side wall 106, 108. The side walls 102, 104, 106, 108 are arranged at a right angle to the surface of the tubesheet (not shown). The plenum chamber 100 is terminated at its upper end by a top wall 110. The top wall 110 of the plenum chamber 100 incorporates at a central position a gas exchange opening 112 which allows clean gas exiting from the clean gas ends of the group of filter elements accommodated within the plenum chamber 100 to exit from the plenum chamber 100 into the clean gas section of the interior of the filter vessel.
(35) On top of the plenum chamber 100, the lower part of a blowback gas pipe 120 is shown, the outlet 122 of which is directed to the gas exchange opening 112 of the plenum chamber 100.
(36) The opening 122 of the blowback gas pipe 120 is shown in
(37) In the present example, the cross-sectional area of the opening 122 of the blowback gas pipe 120 roughly amounts to about 70%.
(38) As may be derived from the top view of the plenum chamber 100 comprised in
(39)
(40) Two arcuate side walls 146 and 148 complement the basic structure of the plenum chamber 140. A top wall 150 closes the upper portion of the plenum chamber 140. The lower end of the plenum chamber 140 abuts the upper surface of a tubesheet (not shown).
(41) The plenum chamber 140 differs from the plenum chamber 100 shown in
(42) By having the side wall 140 bulging outwardly, additional area of the tubesheet is covered by the plenum chamber 140 and thereby additional filter elements of a group of filter elements can be accommodated within the plenum chamber 140.
(43) The alternative configuration of the side wall 108 in
(44) Another difference to the plenum chamber 100 is given in that the plenum chamber 140 comprises a gas exchange opening not as part of the top wall 150. Instead, at a central portion of the top wall 150, a tubular element 152 is mounted which extends upwardly from top wall 150. At its upper end, the tubular element 152 defines the gas exchange opening 154 of the plenum chamber 140. A blowback pipe 160 is extending in the direction to the gas exchange opening 154 of the plenum chamber 140, the lower end of which defining the outlet opening 162. Again, the free cross-sectional areas of the gas exchange opening 154 and the opening of the lower end of the blowback gas pipe 160 are such that the free cross-sectional area of the opening 162 amounts to about 70% of the free cross-sectional area of the gas exchange opening 154.
(45) In the
(46)
(47) The plenum chamber 200 is comprised of three different parts, the first, lowest part 202 is shaped as a truncated cone the lower end 204 of which typically rests on a tubesheet of a filter vessel and accommodates the clean gas ends of the filter elements mounted in the tubesheet.
(48) The upper end 206 can, in a first approach, form the gas exchange opening of the plenum chamber which would consist only of the plenum chamber part 202.
(49) In the present example, however, the upper end 206 supports a cylindrical plenum chamber part 208 the upper end 210 of which could also form a gas exchange opening for a plenum chamber which would consist of the plenum chamber parts 202 and 208.
(50) Again, in the example shown in
(51) Positioned above the plenum chamber 200, a blowback gas pipe 220 is positioned the lower end 222 of which projects into the upper end 214 of the plenum chamber part 212 forming the gas exchange opening. The free cross-sectional area of the plenum chamber part 212 at the level of the line at reference numeral 213 and the free cross-sectional area of the lower end 222 of the blowback pipe 220 serve for calculating the ratio. In the present case, the ratio is about 50%.
(52) It is noted that the vertical position of the lower end 222 of the blowback pipe 220 may be positioned at different levels as indicated by the double pointed arrow 215.
(53)
(54) The lowermost part of the plenum chamber 250 has a basically triangular shape as shown in the top view of
(55) The lowermost part 252 could serve, similarly to the lowermost part 202 of the plenum chamber 200, as a plenum chamber per se, whereas the uppermost end 256 would then form and define the gas exchange opening for such a plenum chamber.
(56) However, in the example of
(57) Again and for reasons which will be explained in connection with
(58) The free cross-sectional area to be calculated and compared to the free cross-sectional area of the blowback pipe would depend on the position of the end of the blowback pipe with respect to the upper end of the plenum chamber part 262.
(59)
(60) The testing device 300 comprises a vessel 302 the top of which is closed by a tubesheet 304 which accommodates a plurality of filter elements (in the following examples; 48 ceramic filter candles of the type DIA-SCHUMALITH 10-20 of a length of 1.5 m).
(61) On top of the tubesheet 304, a plenum chamber corresponding to the plenum chamber 200 of
(62) The test data reported in connection with
(63) The dimensions of the plenum chamber parts of the plenum chamber 200 were as follows: Chamber part 202, inner diameter at its lower end 204: 730 mm inner diameter at its upper end 206: 210 mm Chamber part 208, inner diameter: 210 mm Chamber part 212, inner diameter at its lower end 210: 210 mm inner diameter at its upper end 214: 270 mm
(64) The inner diameter of the blowgas pipe 306 corresponding to the inner diameter at the outlet was modified for the various test set-ups as listed in Table 1 below.
(65) The height of the plenum chamber parts amount to: 1175 mm for chamber part 202 250 mm for chamber part 208 155 mm for chamber part 212.
(66) The testing system 300 does not include a clean gas section, and the vessel 302 just provides an environment to the filter elements which corresponds to the raw gas section of a real-world hot gas filtration system. A clean gas section is not needed for obtaining meaningful test results.
(67) A blowback gas pipe 306 is directed to the gas exchange opening of the plenum chamber 200 which is represented in one testing environment by the upper end 210 of the plenum chamber part 208 (the upper most plenum chamber part 212 being removed; the test results are summarized in
(68) The blowback gas pipe 306 receives blowback gas from a blowback gas reservoir 310 of a volume of 1000 l which receives compressed air via feedline 312.
(69) The pressure conditions on the feed side of the blowback gas reservoir 310 are monitored by an optical pressure indicator 314 and a pressure monitoring device 316.
(70) The gas reservoir 310 is connected to the blowback pipe 306 via a feedline 320 of an inner diameter of 250 mm. The feedline 320 includes two 90 bends and is connected to the blowback gas pipe 306 via a pneumatically driven valve 322. The total volume of the feedline 320, the valve 322 and the blowback gas pipe 306 amounts to 130 l. The pneumatic device for operating the valve 322 is schematically shown at reference numeral 324.
(71) In order to monitor the pressure conditions during blowback experiments inside the plenum chamber 200 and the individual filter elements, a plurality of pressure-monitoring instruments 330, 332, 334 and 336 is mounted on the plenum chamber 200 and on one of the filter elements 340.
(72) The data including the pressure data from the pressure monitoring device 316, 330, 332, 334, 336 obtained during the experiments are collected in a computer system schematically shown as part 360.
(73) The test results shown in
(74) Test Set-Up for Prior Art System (Reference)
(75) The valve 322 used in the test set-up for the reference system was a DN80 Mller Coax valve (supplier: Mller Co-Ax AG, Germany) having an opening time of about 100 msec.
(76) The blowback pipe 306 had an inner diameter of about 80 mm. At the outlet end of the blowback gas pipe 306 a nozzle with an inner diameter of 40 mm was used. The nozzle was positioned at about 200 mm above the gas exchange opening 214 of the plenum chamber.
(77) The ratio of the free cross-sectional areas was 2.2%.
(78) The blowback gas pulse created by the reference system was of sonic velocity.
(79) Test Set-Up for the Inventive System
(80) The valve 322 used was a DN 150 butterfly valve (supplier: TYCO Valves & Controls Distribution GmbH, Mnchengladbach, Germany) having a nominal diameter of 150 mm and an opening time of about 200 msec.
(81) The blowback gas outlet 308 was positioned flush with the gas exchange opening 210 and 214, respectively.
(82) The blowback gas pulse had roughly a velocity of 90 m/sec for a blowback gas pressure of 1.3 bar in the gas reservoir.
(83) TABLE-US-00001 TABLE 1 inner diameter of inner diameter of ratio of free cross- outlet of blowback gas exchange sectional areas gas pipe [mm] opening [mm] [%] FIG. 5 set-up 1 100 210 22 set-up 2 150 210 51 FIG. 6 set-up 3 100 270 13 set-up 4 120 270 19 set-up 5 150 270 30
(84) The pressure differential at the filter candles created in a set-up according to the present invention at different levels of gas reservoir pressure can be varied considerably. About the same pressure differential obtained by a conventional design (reference set-up) where sonic jet pulses are created with a gas reservoir pressure of 4 bar, could be achieved with an inventive set-up with a gas reservoir pressure of 1 bar only. An increase of the gas reservoir pressure up to 5 bar increases dramatically the pressure differential, depending to some extent on the ratio of the free cross-sectional areas of the blow pipe end and the gas exchange opening of the plenum up to significantly more than 220 mbar (set-up 5) while in the reference set-up an increase of the pressure of the gas reservoir from 4 to 7 bar leaves the differential pressure observed at the filter elements substantially unchanged.
(85) As shown in
(86) When the free cross-sectional ratio is increased to 51%, the differential pressure may be increased up to more than 200 at a gas reservoir pressure of 5 bar.
(87) For ease of comparison, the prior art test results (reference set-up) are reported in both graphs of
(88) In case of the data represented in
(89) The tests have been performed with three different cross-sectional ratios of the free cross-sectional area of the blowback pipe outlet 308 as compared to the free cross-sectional area of the gas exchange opening 214, and these ratios were 13% for set-up 3, 19% A for set-up 4 and 30% for set-up 5.
(90) Again, the differential pressure could be varied from about 50 mbar with a pressure of the gas reservoir of 1 bar to up to more than 220 mbar at a pressure of the gas reservoir of 5 bar when the cross-sectional ratio was selected to be 30%.
(91) It is noted that the cleaning effect according to the present invention not only can be varied over a very broad range of differential pressures by selecting the gas reservoir pressure, but also a similar amount of cleaning gas volume is needed as compared to the conventional sonic jet pulse system (reference set-up):
(92) For creating a pressure differential of 65 mbar at the filter elements the following conditions were required in set-up 5 and the reference set-up:
(93) Reference set-up: pressure 7.0 bar
(94) Set-up 5: pressure 1.5 bar
(95) For obtaining comparable regeneration results, comparable volumes per filter element of blowback gas had to be delivered to the system.
(96) All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein.
(97) The use of the terms a and an and the and at least one and similar referents in the context of describing the invention (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The use of the term at least one followed by a list of one or more items (for example, at least one of A and B) is to be construed to mean one item selected from the listed items (A or B) or any combination of two or more of the listed items (A and B), unless otherwise indicated herein or clearly contradicted by context. The terms comprising, having, including, and containing are to be construed as open-ended terms (i.e., meaning including, but not limited to,) unless otherwise noted. Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., such as) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention.
(98) Preferred embodiments of this invention are described herein, including the best mode known to the inventors for carrying out the invention. Variations of those preferred embodiments may become apparent to those of ordinary skill in the art upon reading the foregoing description. The inventors expect skilled artisans to employ such variations as appropriate, and the inventors intend for the invention to be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the invention unless otherwise indicated herein or otherwise clearly contradicted by context.