POWERFUL HAIR TREATMENT AGENT WITH ANTI-WASHOUT EFFECT

Abstract

Hair treatment agent containing a) at least one fatty alcohol, b) at least one cationic surfactant, c) at least one divalent or trivalent metal salt, d) at least one silver salt selected from silver acetate, silver adipate, silver citrate, silver galactarate, silver gluconate, silver lactate, silver malate, silver mandelate, silver salicylate, silver succinate, silver sulfate, silver tartrate, e) at least one organic acid selected from adipic acid, succinic acid, citric acid, acetic acid, galactaric acid, gluconic acid, hydroxysuccinic acid, mandelic acid, lactic acid, salicylic acid, sulfuric acid, tartaric acid,
reduces or prevents the fading of color from dyed hair.

Claims

1. Hair treatment agent, comprising: a) at least one fatty alcohol, b) at least one cationic surfactant, c) at least one divalent or trivalent metal salt, d) at least one silver salt chosen from silver acetate, silver adipate, silver citrate, silver galactarate, silver gluconate, silver lactate, silver malate, silver mandelate, silver salicylate, silver succinate, silver sulfate, and/or silver tartrate, and e) at least one organic acid chosen from adipic acid, succinic acid, citric acid, acetic acid, galactaric acid, gluconic acid, hydroxysuccinic acid, mandelic acid, lactic acid, salicylic acid, sulfuric acid, and/or tartaric acid.

2. The hair treatment agent according to claim 1, wherein at least one of the a) fatty alcohol(s) have the formula (II):
H.sub.3C(CH.sub.2).sub.kCH.sub.2OH(II) where k is an integer from 4 to 28.

3. The hair treatment agent according to claim 1, wherein at least one of the b) cationic surfactant(s) is behenyl trimethylammonium chloride.

4. The hair treatment agent according to claim 1, wherein the c) at least one divalent or trivalent metal salt is chosen from the group of organic or inorganic copper, zinc, iron(II), calcium, magnesium, iron(III), and/or aluminum salts.

5. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent, about 0.01 to about 2% by weight of d) silver salt(s).

6. The hair treatment agent according to claim 1, comprising silver ions in a total amount of about 1 to about 100 ppm based on the weight of the hair treatment agent.

7. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent, about 0.01 to 3% by weight e) organic acid(s) chosen from the group of adipic acid, succinic acid, citric acid, acetic acid, galactaric acid, gluconic acid, hydroxysuccinic acid, mandelic acid, lactic acid, salicylic acid, sulfuric acid, and/or tartaric acid.

8. The hair treatment agent according to claim 1, comprising d) silver citrate-citric acid complexes of the form ##STR00028## where x+y=3 with a water content of up to about 90% by weight based on the total weight of the complex in combination with one or more passivating agents chosen from the group of silicic acids.

9. A method for treating hair, comprising applying a hair treatment agent to dry or damp hair, wherein the hair treatment agent comprises: a) at least one fatty alcohol, b) at least one cationic surfactant, c) at least one divalent or trivalent metal salt, d) at least one silver salt chosen from silver acetate, silver adipate, silver citrate, silver galactarate, silver gluconate, silver lactate, silver malate, silver mandelate, silver salicylate, silver succinate, silver sulfate, and/or silver tartrate, and e) at least one organic acid chosen from adipic acid, succinic acid, citric acid, acetic acid, galactaric acid, gluconic acid, hydroxysuccinic acid, mandelic acid, lactic acid, salicylic acid, sulfuric acid, and/or tartaric acid, where the hair treatment agent is left on the hair for a period of about 30 to about 300 seconds and then rinsed out.

10. The method according to claim 9, wherein the hair treatment agent is applied to chemically dyed hair.

11. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent, about 0.01 to about 10 wt % of c) divalent or trivalent metal salt(s).

12. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent, about 0.1 to 20% by weight of a) fatty alcohol(s).

13. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent, about 0.05 to 20% by weight of b) the least one cationic surfactant.

14. The hair treatment agent according to claim 8, comprising, based on the total weight of the agent, about 0.01 to about 2% by weight of the silver citrate-citric acid complexes.

15. The hair treatment agent according to claim 1, comprising, based on the total weight of the agent: about 0.1 to 20% by weight of a) fatty alcohol(s); about 0.05 to 20% by weight of b) the least one cationic surfactant; about 0.01 to about 10 wt % of c) divalent or trivalent metal salt(s); and about 0.01 to about 2% by weight of d) silver salt(s).

16. The hair treatment agent according to claim 15, comprising: a) fatty alcohol(s) of the formula (II):
H.sub.3C(CH.sub.2).sub.kCH.sub.2OH(II) where k is an integer from 4 to 28; b) behenyl trimethylammonium chloride as at least one of the cationic surfactant(s); c) at least one divalent or trivalent metal salt is chosen from the group of organic or inorganic copper, zinc, iron(II), calcium, magnesium, iron(III), and/or aluminum salts; and d) silver citrate-citric acid complexes of the form ##STR00029## where x+y=3 with a water content of up to about 90% by weight based on the total weight of the complex in combination with one or more passivating agents chosen from the group of silicic acids.

Description

EXAMPLES

[0336] All amounts given in percent % by weight

TABLE-US-00001 Hair treatments 1 2 3 4 5 6 Cetearyl alcohol 7.0 7.0 7.0 7.0 7.0 7.0 Quaternium-87 0.9 0.9 0.9 0.9 0.9 0.9 Cetrimonium chloride 1.5 1.5 1.5 1.5 1.5 1.5 Distearoylethyl hydroxyethyl- 2.0 2.0 2.0 2.0 2.0 2.0 monium methosulfate Polyquaternium-10 0.1 0.1 0.1 0.1 0.1 0.1 Baobab seed oil 0.1 0.1 0.1 0.1 0.1 0.1 Polyquaternium-37 0.4 0.4 0.4 0.4 0.4 0.4 Hydrolyzed keratin 0.5 0.5 0.5 0.5 0.5 0.5 Glycol distearate 1.0 1.0 1.0 1.0 1.0 1.0 Silver citrate 0.1 0.1 0.1 0.1 0.1 0.1 Citric acid 1.5 1.5 1.5 1.5 1.5 1.5 Dimethicone 1.0 1.0 1.0 1.0 1.0 1.0 Calcium chloride 1.0 1.0 1.0 1.0 1.0 1.0 Propionic acid 0.2 0.2 0.2 0.2 0.2 o-Phenyl phenol 0.2 0.2 0.2 0.2 0.2 o-Cymen-5-ol 0.06 0.06 0.06 0.06 0.06 Ethyl lauroyl arginate 0.3 0.3 0.3 0.3 0.3 Dimethyloxazolidine 0.05 0.06 0.07 0.08 0.1 Ethyl lauroyl arginate 0.4 0.3 0.2 0.1 0.05 Glutaraldehyde 0.05 0.06 0.07 0.08 0.1 Hexetidine 0.05 0.06 0.07 0.08 0.1 Phenoxyethanol 0.05 0.05 0.05 0.05 0.05 Phenoxyisopropanol 0.05 0.1 0.25 0.05 0.05 Undecylenic acid 0.1 0.2 0.1 0.2 0.1 Dye 0.2 0.2 0.2 0.2 0.2 0.2 Perfume 0.1 0.1 0.1 0.1 0.1 0.1 Water to a total of 100

TABLE-US-00002 Hair rinses 1 2 3 4 5 6 Cetearyl alcohol 5.0 5.0 5.0 5.0 5.0 5.0 Quaternium-87 0.75 0.75 0.75 0.75 0.75 0.75 Behentrimonium chloride 1.0 1.0 1.0 1.0 1.0 1.0 Behenoyl PG trimonium 1.5 1.5 1.5 1.5 1.5 1.5 chloride Glycol distearate 1.0 1.0 1.0 1.0 1.0 1.0 Distearoylethyl hydroxyethyl- 0.3 0.3 0.3 0.3 0.3 0.3 monium methosulfate Amodimethicone/ 0.1 0.1 0.1 0.1 0.1 0.1 morpholinomethyl silsesquioxane copolymer Silver citrate 0.3 0.3 0.3 0.3 0.3 0.3 Citric acid 0.5 0.5 0.5 0.5 0.5 0.5 Shea butter 1.5 1.5 1.5 1.5 1.5 1.5 Lactic acid 0.1 0.1 0.1 0.1 0.1 0.1 Magnesium chloride 0.5 0.5 0.5 0.5 0.5 0.5 Sodium propionate 0.5 0.5 0.5 0.5 0.5 Phenoxyethanol 0.5 0.5 0.5 0.5 0.5 Dimethyloxazolidine 0.05 0.06 0.07 0.08 0.1 Glutaraldehyde 0.05 0.06 0.07 0.08 0.1 Hexetidine 0.05 0.06 0.07 0.08 0.1 Ethyl lauroyl arginate 0.05 0.05 0.05 0.05 0.05 Sodium-o-phenylphenolate 1.0 0.5 0.25 0.2 0.1 o-Cymen-5-ol 0.2 0.1 0.2 0.1 0.1 Phenoxyisopropanol 0.05 0.1 0.25 0.05 0.05 Undecylenic acid 0.1 0.2 0.1 0.2 0.1 Dye 0.2 0.2 0.2 0.2 0.2 0.2 Perfume 0.1 0.1 0.1 0.1 0.1 0.1 Water to a total of 100