SYSTEM AND METHOD FOR ENERGY AND RESOURCE EXTRACTION WITH REDUCED EMISSIONS
20250067481 ยท 2025-02-27
Inventors
- Mariane PETER-BORIE (Saint Nexans, FR)
- Robert Crossley (Conwy, GB)
- Elisha DRUMM (Bridge of Weir, GB)
- Junior POTGIETER (Longfield, GB)
- Max NORMAN (Llandudno, GB)
- Mark WILLIAMS (LLandudno, GB)
Cpc classification
F24T10/17
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
E21B43/295
FIXED CONSTRUCTIONS
International classification
F24T10/17
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
E21B41/00
FIXED CONSTRUCTIONS
Abstract
A heat extraction system for extracting heat from a reservoir, the system including a co-axial tool configured to be placed underground, the co-axial tool having an outer pipe and an inner pipe located within the outer pipe, each of the outer pipe and the inner pipe being connected to a shoe so that a fluid flows through an annulus defined by the inner and outer pipes, reaches the shoe, and flows through a bore of the inner pipe; and a power generator fluidly connected to a chemical processing unit to receive a fluid, and also fluidly connected with a first port to the inner pipe and with a second port to the outer pipe of the co-axial tool. A temperature difference of the fluid at the power generator and at the co-axial tool drives the power generator to generate energy.
Claims
1. A heat extraction system for extracting heat from a reservoir, the system comprising: a co-axial tool configured to be placed underground, the co-axial tool having an outer pipe and an inner pipe located within the outer pipe, each of the outer pipe and the inner pipe being connected to a shoe so that a fluid flows through an annulus defined by the inner and outer pipes, reaches the shoe, and flows through a bore of the inner pipe; and a power generator fluidly connected to a chemical processing unit to receive a fluid, and also fluidly connected with a first port to the inner pipe and with a second port to the outer pipe of the co-axial tool, wherein a temperature difference of the fluid at the power generator and at the co-axial tool drives the power generator to generate energy.
2. The heat extraction system of claim 1, further comprising: a chemical processing unit configured to receive syngas from a burning coal seam located underground, and to extract CO.sub.2 and H.sub.2 from the syngas; and a compressor fluidly connected between the chemical processing unit and the power generator to make supercritical CO.sub.2 to be used as the fluid.
3. The heat extraction system of claim 1, wherein only the shoe is configured to be placed in the coal seam.
4. The heat extraction system of claim 1, further comprising: an additional compressor configured to pump air or oxygen into the coal seam for promoting burning of the coal.
5. The heat extraction system of claim 1, wherein the shoe is made of a material that withstands temperatures larger than 500 C., the outer pipe is attached to the shoe, the inner pipe is concentrically located within the outer pipe and forms the annulus with the outer pipe, and the co-axial tool further includes: a flexible connection configured to connect the outer pipe to the shoe so that the outer pipe is allowed to extend and contract without leaking the fluid inside the annulus, wherein the inner pipe and the outer pipe are configured to form an uninterrupted loop path for the fluid, between a top of the annulus and a top of the bore while also allowing the fluid to directly contact the shoe.
6. The heat extracting system of claim 5, wherein the co-axial tool further comprises: a strainer element located between the inner pipe and the shoe; and an additional flexible connection between the inner pipe and the strainer element, wherein the loop path extends from the annulus to the bore through plural holes formed in the strainer element.
7. A method for extracting heat from a reservoir, the method comprising: placing one or more co-axial tools underground, the co-axial tool having an outer pipe and an inner pipe located within the outer pipe, each of the outer pipe and the inner pipe being connected to a shoe so that a fluid flows through an annulus of the inner and outer pipes, reaches the shoe, and also flows through a bore of the inner pipe, wherein only the shoe is in contact with a coal seam located underground; fluidly connecting a power generator to a chemical processing unit to receive a fluid, and also fluidly connecting a first port of the power generator to the inner pipe and connecting a second port of the power generator to the outer pipe of the co-axial tool; and generating energy with the power generator based exclusively on a temperature difference of the fluid at the power generator and at the co-axial tool.
8. The method of claim 7, further comprising: fluidly connecting a production well to a chemical processing unit, which is configured to receive syngas from burning the coal seam located underground, and configured to extract CO.sub.2 from the syngas; separating the CO.sub.2 from the syngas in the chemical processing unit; and compressing the CO.sub.2 to make supercritical CO.sub.2 to be used as the fluid.
9. The method of claim 8, further comprising: circulating the supercritical CO.sub.2 through the annulus and the bore of the co-axial tool to reach the shoe and extract heat from the burning coal seam; and circulating the heated supercritical CO.sub.2 through the power generator to produce electrical energy.
10. The method of claim 7, further comprising: injecting air or oxygen into the coal seam for sustaining the burning.
11. The method of claim 8, further comprising: extracting H.sub.2 from the syngas with the chemical processing unit.
12. The method of claim 8, further comprising: injecting the supercritical CO.sub.2 into a cavity formed in place of the burned coal seam; and sealing wells connected to the cavity for storing the CO.sub.2 underground.
13. A heat extraction system for extracting heat from a reservoir, the system comprising: a co-axial tool configured to be placed underground, the co-axial tool having an outer pipe and an inner pipe located within the outer pipe and configured so that a fluid flows through an annulus of the inner and outer pipes, reaches a closed end of the outer pipe, and also flows through a bore of the inner pipe; and a power generator fluidly connected to a chemical processing unit to receive the fluid, and also fluidly connected with a first port to the inner pipe and with a second port to the outer pipe of the co-axial tool, wherein a temperature difference of the fluid at the power generator and at the co-axial tool drives the power generator to generate energy.
14. The heat extraction system of claim 13, further comprising: a chemical processing unit configured to receive syngas from a burning coal seam located underground, and to extract CO.sub.2 and H.sub.2 from the syngas; and a compressor fluidly connected between the chemical processing unit and the power generator to make supercritical CO.sub.2 to be used as the fluid.
15. The heat extraction system of claim 13, wherein the inner and outer pipes are configured to be placed deviated from a vertical, under a bottom of the coal seam.
16. The heat extraction system of claim 13, further comprising: an additional compressor configured to pump air or oxygen into the coal seam for promoting burning of the coal.
17. The heat extraction system of claim 13, wherein the inner pipe and the outer pipe are configured to form an uninterrupted loop path for the fluid, between a top of the annulus and a top of the bore while also allowing the fluid to directly contact the closed end of the outer pipe.
18. A method for extracting heat from a reservoir, the method comprising: placing one or more co-axial tools underground, the co-axial tool having an outer pipe and an inner pipe located within the outer pipe, and configured so that a fluid flows through an annulus of the inner and outer pipes, reaches a closed end of the outer pipe, and also flows through a bore of the inner pipe; fluidly connecting a power generator to a chemical processing unit to receive the fluid, and also fluidly connecting a first port of the power generator to the inner pipe and connecting a second port of the power generator to the outer pipe of the co-axial tool; and generating energy with the power generator based exclusively on a temperature difference of the fluid at the power generator and at the co-axial tool.
19. The method of claim 18, further comprising: deploying the co-axial tool in a plane below a bottom of the coal seam, and the plane is making a non-zero angle with a horizontal plane.
20. The method of claim 19, further comprising: deploying the co-axial tool to follow a serpentine in the plane.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0022] For a more complete understanding of the present invention, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
DETAILED DESCRIPTION OF THE INVENTION
[0040] The following description of the embodiments refers to the accompanying drawings. The same reference numbers in different drawings identify the same or similar elements. The following detailed description does not limit the invention. Instead, the scope of the invention is defined by the appended claims. The following embodiments are discussed, for simplicity, with regard to a heat harvesting system that includes a co-axial tool provided with an end shoe for entering a high temperature reservoir for harvesting energy. The system can also be configured to extract and/or generate one or more raw materials for chemical plants. However, the embodiments to be discussed next are not limited to the co-axial tool with the end shoe, but may be applied with other tools for extracting the heat, for example, a tool with no end shoe.
[0041] Reference throughout the specification to one embodiment or an embodiment means that a particular feature, structure or characteristic described in connection with an embodiment is included in at least one embodiment of the subject matter disclosed. Thus, the appearance of the phrases in one embodiment or in an embodiment in various places throughout the specification is not necessarily referring to the same embodiment. Further, the particular features, structures or characteristics may be combined in any suitable manner in one or more embodiments.
[0042] According to an embodiment, a novel system for heat and raw material extraction from an underground coal oxidation process is introduced and this system is configured to reduce the amount of pollution associated with traditional coal exploitation. The system is configured to capture the heat generated during the UCG process with the use of one or more co-axial tools, each having a shoe end, also to capture the syngas generated by the UCG process and to separate from it various raw materials for industrial use, and to incorporate reinjection, recycling and underground sequestration of the Green House Gases (GHGs) in the syngas not used for industrial purposes.
[0043] In one application, the system uses complementary and adaptable solutions to produce power from the heat extracted from underground using the co-axial tools (for example, steel shoes of co-axial wells in the cavity, co-axial deviated wells in the underburden or serpentine wells in the underburden). The final products of this system, in one embodiment, are power from the underground heat, and hydrogen from the syngas. Depending on the commercial needs, other raw materials for the chemical industry, such as methanol, can also be extracted. The other syngas constituents will be reinjected into the ground. No GHGs are released to the atmosphere.
[0044] The system may be implemented with different configurations. Techno-economic modelling based on thermo-hydraulic simulations allow the definition of the best designs for the system for a given geological context. The designs can be tuned to the technology used for the UCG: shaft or shaftless methods, controlled retracting injection point, linked vertical wells, single well integrated flow tubing and methods associated with steeply dipping seams.
[0045] The system may include plural co-axial tools that are deployed in wells drilled into the reservoir. In one application, some or all the co-axial tools are driven into the ground without the need of drilling wells. Different patterns may be used for the plural wells/tools to extract the heat, i.e., the number and geographical distribution of the tools over the reservoir may be calculated based on the parameters of the reservoir. Each co-axial tool in the well uses a closed loop working fluid flow (where there is no contact between (1) the rock mass and its components and the coal and (2) the working fluid circulating in the wells). The heat is extracted from the medium by thermal conduction through the wellbore liner/outer pipe or along the stainless-steel shoes at the bottom of the tool. Convection may occur in high permeability zones (cavities, permeable strata and fractures); this enhances the rate of transfer of the extractable heat, and gives better performance of the system.
[0046] A range of working fluids can be used in the closed loops of the co-axial tools. However, in one application, supercritical CO.sub.2 (SCO.sub.2) is used as the working fluid as it presents several advantages. CO.sub.2 is one of the components of the syngas and appears to be a low-cost and a local solution. Supercriticality of the CO.sub.2 can be reached above its critical temperature (31 C.) and its critical pressure (7.4 MPa). In addition, SCO.sub.2 is chemically stable and non-flammable. SCO.sub.2 is a promising candidate for high-temperature plant topping cycle to improve thermal efficiency. Indeed, high temperature SCO.sub.2 (>500 C.) presents an excellent system performance (>50% thermal efficiency), in particular when used in Brayton cycles, but also in Rankin cycles, combined gas turbine (CCGT) and super-critical CO.sub.2 direct and indirect cycles.
[0047] Various scenarios for extracting the heat and/or raw material from an underground coal deposit are now discussed with regard to the figures.
[0048]
[0049] The chemical processing unit 410 separates the syngas 407 into its various components, for example, CO.sub.2, H.sub.2, CO, CH.sub.4, etc. As noted above, the CO.sub.2 may be used as the fluid 422 that flows into the co-axial tool 420. The fluid 422 may be CO.sub.2, which is first turned into supercritical CO.sub.2, for example, with the help of a compressor 412, and then injected into the piping 440. One way valves 442 may be present in the piping 440 for ensuring that the SCO.sub.2 flows along a desired path, i.e., from the power generator 430 to the inner pipe of the co-axial tools 420, and back to the power generator through the annulus formed by the inner and outer pipes of the tools 420. The direction of this flow can be reversed, i.e., it enters first the annulus, goes all the way into the coal seam, and then goes up through the bore of the inner pipe. In this way, the flow of SCO.sub.2 powers continuously the power generator as long as heat is extracted from the coal seam 401. After the compressor 412 starts the SCO.sub.2 flow, the flow is self-sustained even if the compressor is shut down (valve 412A is closed), as the temperature difference T2T1 maintains the flow, where T1 is the temperature of the SCO.sub.2 flow at the power generator 430 and T2 is the temperature of the SCO.sub.2 flow at the bottom of the co-axial tool 420. Note that the temperature difference T2T1 may be about 500 C. or larger.
[0050] The produced CO in the chemical processing unit 410 may be treated with oxygen from an oxygen supply 414 to increase the amount of available CO.sub.2, such that enough CO.sub.2 is pumped through the piping 440 for filing the one or more co-axial tools 420. At the end of the process, i.e., when the coal seam 401 has been all burned, the used CO.sub.2 may be injected back into the cavity 405 so that no CO.sub.2 is released into the atmosphere. Note that
[0051] In one application, the co-axial tools 420 are installed prior to the coal combustion and remain in place during the combustion. The shoe of the tool is inserted in the to-be-combusted coal seam as shown in
[0052] In one application, the wellbore is fully cased and insulated from the overburden rock mass. Cementation is not essential, and depending on the site-specific operational characteristics, the system could be removed after the process, if placed in a proper outer casing (in that case, the outer-casing shoe has to be above the coal seam, as discussed later). The shoe is directly in contact with the to-be-burnt coal. It makes the system more resilient to potential damage due to the ultra-high temperature and to corrosion processes occurring during the burning. The shoe is designed to resist thermo-mechanical strains due to thermal stress, ground movements during the linkage process and when roof spalling occurs. The shoe is made of alloys that must be resistant to high temperature (up to 1,000 C.), corrosive environments, thermal stress, burst strength, and with a sufficient thermal conductivity at the relevant temperatures. At very high temperature, thermal stability is the first factor considered, as this may set limits to a particular type of alloy from the standpoint of softening or, more commonly, embrittlement, and may induce a change in the thermal properties (thermal conductivity in particular). Note that the shoe is allowed to accommodate large deformations as it is not a supporting element but only the heat-transfer tool. Hence, the creep rupture strength at high temperature is the basis for alloy selection.
[0053] The co-axial tool 420 is now discussed with regard to
[0054] Note that for achieving the connection with the outer pipe 520, in one embodiment, the shoe 530 has threads 610 on an external surface 532, next to the top surface 536, as shown in
[0055] Returning to
[0056] In the embodiment shown in
[0057] In another embodiment, as illustrated in
[0058] In yet another embodiment, as illustrated in
[0059] In still another embodiment, as illustrated in
[0060] With regard to the shape of the shoe 530, the previous embodiments illustrated it as being shaped like a bullet, for example, a largest external diameter matching the external diameter of the outer pipe and then the body having a vertex 538, as shown in
[0061] In one application, as shown in
[0062] When the tool 420 is desired to be used (as illustrated in
[0063] The high thermal conductivity of the alloys at high temperature allows the heat transfer from the metal shoe 530 to the co-axial pipes 510/520. Thermo-hydraulic numerical simulations are run to optimize the design of the tool and the corresponding well (shoe length and diameter, well diameter, number and position of co-axial-well-with-shoe systems).
[0064]
[0065] After the heat from the coal seam has been extracted in step 1206, which can take months if not years, just prior to removing the casing 1110 and associated tool 420 from the well in step 1208, it is possible to store CO.sub.2 in the cavity 405, and then the well 1102 is sealed with cement plugs 1120 in step 1210, as illustrated in
[0066] Smart and safe implementation of this technology may be matched with monitoring methods, for example, focusing in particular on the temperature, the pressure, and the mechanical behaviour of the tool and of the hosting rock-mass. Additional specific monitoring may be required depending on the nature of the coal seam or of the UCG. For example, distributed acoustic sensing (DAS) systems 1103 cemented behind the sacrificial casing 1106 would allow monitoring of the temperature and the pressure at the interface between the rock-mass and the tool, while DAS fibres inserted in the coaxial tool 420 and fixed to the inner or outer tube give temperature and pressure evolution with the depth in the co-axial loop. In one application, seismic sensors network 1130 at the surface (or buried in noisy environments), as schematically illustrated in
[0067] By using the novel combination of technologies disclosed here, it is possible to harvest significant quantities of hydrogen from the syngas 407 and heat generated by underground oxidation of coal without releasing harmful emissions to the atmosphere. This opens the door to a greener use of the world's abundant coal resources. The technologies discussed herein can be configured to optimize the capture of heat generated, and then hosted in the rock or in the fluids, during oxidation of coal in the subsurface, for example, by determining how many wells 1102 are necessary for a given coal seam 401, and also the distribution of the wells, and implicit of the tools 420, over the coal seam 401. The amount of captured heat can deliver all the electrical power needed to supply onsite operational needs, including drilling, pumping, measurement, monitoring and validation, plus processing of the hydrogen. This means that these technologies can be applied on a standalone basis and there is no parasitic use of hydrogen for on-site energy needs. The excess power can be used locally for industrial activity or supplied to the grid.
[0068] Hydrogen delivery can be optimized to local market conditions, for example, to be delivered by pipeline, compression and cooling for export as liquid, or conversion to ammonia for export as fuel or fertilizer. One or more benefits of one or more embodiments discussed herein for the industries that currently burn coal is that these existing facilities do not need to be closed down, since rapid advances in technology are showing that coal-fired power stations can be converted to burn hydrogen, whilst cement manufacture and steel production can utilize hydrogen and green power.
[0069] While the embodiments of
[0070] In one application, the well 1302 is drilled prior to gasification. The upper part of the well 1302 may be insulated from the overburden rock using a thermally insulated grout 1304. The bottom of the well 1302, under the future cavity 405, may be cemented using thermally enhanced grout 1306. The working fluid 422, which can be, as discussed above, supercritical CO.sub.2 coming from the syngas 407, is injected through the inner pipe 510 and pumped out through the annulus formed between the inner pipe 510 and the outer pipe 520. The trajectory of the lower part of the well (which will harvest the heat) depends on the UCG method. When the gasification involves methods based on vertical wells 450 and 454, deviated co-axial tools 1320 are used for heat extraction as schematically illustrated in
[0071] If the gasification is realized using the CRIP method, another design may be used, for harvesting the heat from a well 1402. In this case, a system 1400 is based on a serpentine trajectory drilled in the underburden 404, in a plane 1410 parallel to the coal seam 401's bottom wall 1412, as shown in
[0072] Wells 450 and 454 are shown in
[0073] Clean and safe implementation of these technologies requires proper risk assessment and mitigation. The following risks in particular must be closely monitored: ground water pollution, gas leakage, and ground movement. Regarding the groundwater pollution, depending on the geological and hydrogeological context, pollutant elements trapped in the combustion ash 406 may be leached by underground water after cavity flooding by groundwater ingress. In one application, risk mitigation is based on keeping the cavity pressure below the surrounding hydrostatic pressure, to help retain contaminated fluid within the cavity. Regarding gas leakage, during and after the coal oxidation, there is a risk of gas release into the overlying strata and into the atmosphere if the cavity is not confined by impermeable overburden, or if discontinuities provide permeable connectivity from the cavity to the overburden and/or to the surface. Thus, these factors should be monitored. Regarding ground movement, depending on the geological context, including the depth and the thickness of the targeted coal seams, subsidence can be encountered. To mitigate this risk, a system of pillars and cavities may be used.
[0074] In addition to properly designing the operation to prevent these risks, it is desired to monitor these sites for risk prevention. In one application, it is possible to implement DAS systems, discussed above with regard to
[0075] Further, it is possible to use a seismic sensors network (see network 1130 in
[0076] A methodology to optimize the design of the heat extraction and monitoring systems is now discussed. The optimization of the heat extraction design is based on hydrothermal numerical simulations including site-specific data and using generic designs to be adjusted to the context in order to fast-track the workflow. A monitoring design is included in the workflow illustrated in
[0077] The simulations noted above may be run using a hydrothermal fully coupled software multiphase (liquid and gaseous phases) flow model as very high temperatures are involved. Fluid can flow in the rock matrix, in the faults/fractures if any, and in the cavity. The predefined generic models received in step 1504 may involve a generic geology (both horizontal and dipping coal seams) at an appropriate depth (such as 1 km) and generic petrophysical and thermal properties based on the data ranges available in the associated database.
[0078] The technologies discussed above may be implemented as various methods in the field. For simplicity, only two such methods are discussed herein, but one skilled in the art would understand that variations of these methods are possible. The configuration shown in
[0079] More specifically, a method for extracting heat from a reservoir 401 includes, as schematically illustrated in
[0080] In step 1602, which is optional, the production well 454 is fluidly connected to a chemical processing unit 410, which is configured to receive syngas 407 from burning the coal seam located underground and is also configured to extract CO.sub.2 from the syngas 407. Note that the chemical processing unit may be refinery, a chemical plant, etc. In step 1604, a power generator 430 is fluidly connected to the chemical processing unit 410 to receive the fluid 422. The power generator is also fluidly connected, with a first port, to the inner pipe 510 and with a second port 430B to the outer pipe 520 of the co-axial tool 420. In step 1606, the power generator generates electrical energy, based exclusively on a temperature difference of the fluid 422 at the power generator 430 and at the co-axial tool 420.
[0081] The method may also include a step of separating CO.sub.2 from the syngas in the chemical processing unit, and a step of compressing the CO.sub.2 to make supercritical CO.sub.2 to be used as the fluid. The method may further include a step of circulating the supercritical CO.sub.2 through the annulus and the bore of the co-axial tool to reach the shoe and extract heat from the burning coal seam, and a step of circulating the heated supercritical CO.sub.2 through the power generator to produce electrical energy. Optionally, the method may include a step of injecting air or oxygen into the coal seam for sustaining the burning, and/or a step of extracting H.sub.2 from the syngas with the chemical processing unit. When the process is considered to not be any more economically viable, the method may include the step of injecting the supercritical CO.sub.2 into a cavity formed in place of the burned coal seam, and sealing wells connected to the cavity for storing the CO.sub.2 underground.
[0082] The configurations shown in
[0083] In step 1702, a production well 454 is fluidly connected to a chemical processing unit 410, which is configured to receive syngas 407 from burning the coal seam located underground, and configured to extract CO.sub.2 from the syngas 407. Note that this step is optional. In step 1704, a power generator 430 is fluidly connected to the chemical processing unit 410 to receive the fluid 422, and is also fluidly connected, with a first port of the power generator, to the inner pipe 510, and fluidly connected, with a second port of the power generator, to the outer pipe 520 of the co-axial tool 1320. In step 1706, energy is generated with the power generator based exclusively on a temperature difference of the fluid 422 at the power generator and at the co-axial tool.
[0084] The method may further include a step of deploying the co-axial tool in a plane below a bottom of the coal seam, and the plane is making a non zero angle with a horizontal plane, and/or a step of deploying the co-axial tool to follow a serpentine in the plane.
[0085] The term about is used in this application to mean a variation of up to 20% of the parameter characterized by this term. It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another. For example, a first object or step could be termed a second object or step, and, similarly, a second object or step could be termed a first object or step, without departing from the scope of the present disclosure. The first object or step, and the second object or step, are both, objects or steps, respectively, but they are not to be considered the same object or step.
[0086] The terminology used in the description herein is for the purpose of describing particular embodiments and is not intended to be limiting. As used in this description and the appended claims, the singular forms a, an and the are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will also be understood that the term and/or as used herein refers to and encompasses any possible combinations of one or more of the associated listed items. It will be further understood that the terms includes, including, comprises and/or comprising, when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. Further, as used herein, the term if may be construed to mean when or upon or in response to determining or in response to detecting, depending on the context.
[0087] The disclosed embodiments provide various methods for placing one or more co-axial tools with or without a shoe in a reservoir, for extracting heat, when the reservoir exhibits one or more extreme parameters, like high temperature. It should be understood that this description is not intended to limit the invention. On the contrary, the embodiments are intended to cover alternatives, modifications and equivalents, which are included in the spirit and scope of the invention as defined by the appended claims. Further, in the detailed description of the embodiments, numerous specific details are set forth in order to provide a comprehensive understanding of the claimed invention. However, one skilled in the art would understand that various embodiments may be practiced without such specific details.
[0088] Although the features and elements of the present embodiments are described in the embodiments in particular combinations, each feature or element can be used alone without the other features and elements of the embodiments or in various combinations with or without other features and elements disclosed herein.
[0089] This written description uses examples of the subject matter disclosed to enable any person skilled in the art to practice the same, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the subject matter is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims.
REFERENCES
[0090] The entire content of all the publications listed herein is incorporated by reference in this patent application. [0091] [1] Jiang, L., Xue, D., Wei, Z., Chen, Z., Mirzayev, M., Chen, Y. and Chen, S. (2022). Coal decarbonization: A state-of-the-art review of enhanced hydrogen production in underground coal gasification. Energy Reviews, 1(1). doi.org/10.1016/j.enrev.2022.100004. [0092] [2] Yang, L., Zhang, X. Y. and Zhu, K. J. (2016). Hydrogen production in underground coal gasification (UCG). Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38(3), pp. 376-383. doi.org/10.1080/15567036.2013.770106. [0093] [3] Olateju, B. and Kumar, A. (2013). Techno-economic assessment of hydrogen production from underground coal gasification (UCG) in Western Canada with carbon capture and sequestration (CCS) for upgrading bitumen from oil sands. Applied Energy, 111, pp. 428-440. doi.org/10.1016/j.apenergy.2013.05.014. [0094] [4] Staczyk, K., Kapusta, K., Wiatowski, M., wiadrowski, J., Smoliski, A., Rogut, J. and Kotyrba, A. (2012). Experimental simulation of hard coal underground gasification for hydrogen production. Fuel, 91(1), pp. 40-50. doi.org/10.1016/j.fuel.2011.08.024. [0095] [5] Jiang, L., Chen, Z., Farouq Ali, S. M., Zhang, J., Chen, Y. and Chen, S. (2022). Storing carbon dioxide in deep unmineable coal seams for centuries following underground coal gasification. Journal of Cleaner Production, 378, p. 134565. doi.org/10.1016/j.jclepro.2022.134565. [0096] [6] Otto, C., Kempka, T., Kapusta, K. and Staczyk, K. (2016). Fault Reactivation Can Generate Hydraulic Short Circuits in Underground Coal Gasification-New Insights from Regional-Scale Thermo-Mechanical 3D Modeling. Minerals, 6(4), pp. 101-119. doi.org/10.3390/min6040101. [0097] [7] Chinese Patent no. CN106121617. [0098] [8] Chinese Patent no. CN102434143. [0099] [9] Chinese Patent no. CN109779600. [0100] [10] Chinese Patent no. CN209586351. [0101] [11]U.S. Pat. No. 4,019,577. [0102] [12] Chinese Patent no. CN215408574. [0103] [13] Chinese Patent no. CN108534380. [0104] [14] Chinese Patent no. CN114837648. [0105] [15] Chinese Patent no. CN113863910. [0106] [16] Chinese Patent no. CN111022026. [0107] [17] Burchart-Korol, D., Korol, J. and Czaplicka-Kolarz, K., 2016. Life cycle assessment of heat production from underground coal gasification. Int J Life Cycle Assess, 21:1391-1403, DOI 10.1007/s11367-016-1102-0. [0108] [18] Jouhara, H., Khordehgah, N., Almahmoud, S., Delpech, B., Chauhan, A. and Tassou, S. A. (2018). Waste heat recovery technologies and applications. Thermal Science and Engineering Progress, [online]6, pp. 268-289. [0109] [19]U.S. patent Ser. No. 10/816,241. [0110] [20] Chinese Patent no. CN106026778A. [0111] [21] Chinese Patent no. CN212867523. [0112] [22] International Application Publication WO 2017/103950.