COMBUSTOR FOR ROCKET ENGINE AND METHOD FOR MANUFACTURING IT
20230125860 · 2023-04-27
Assignee
Inventors
Cpc classification
F05D2230/238
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02K9/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2230/236
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2230/237
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A combustor which can be manufactured without requiring large-scale equipment and with a small number of processes and has a cooling fluid flow path sealed with high reliability. The combustor includes an inner cylinder made of metal constituting a combustion chamber, a cooling fluid flow path formed on an outer surface of the inner cylinder, and a sealing layer covering the outer surface of the inner cylinder to seal the cooling fluid flow path. The sealing layer is constituted by a bonded body of metal wires wound around the outer surface of the inner cylinder and metallurgically bonded to each other, and the sealing layer is bonded to the outer surface of the inner cylinder by metallurgical bonding.
Claims
1. A combustor for a rocket engine comprising: an inner cylinder made of metal constituting a combustion chamber; a cooling fluid flow path formed on an outer surface of the inner cylinder; and a sealing layer covering the outer surface of the inner cylinder to seal the cooling fluid flow path, wherein the sealing layer is: constituted by a bonded body of metal wires wound around the outer surface of the inner cylinder, the bonded body being bonded by metallurgically bonding; and bonded to the outer surface of the inner cylinder by the metallurgical bonding.
2. The combustor according to claim 1, wherein the metallurgical bonding is diffusion bonding.
3. The combustor according to claim 1, wherein the metallurgical bonding is brazing bonding.
4. The combustor according to claim 1, further comprising an outer cylinder adhering to a surface of the sealing layer to hold the inner cylinder.
5. A method for manufacturing a combustor for a rocket engine comprising: forming a cooling fluid flow path on an outer surface of an inner cylinder made of metal that constitute a combustion chamber; winding metal wires around the outer surface of the inner cylinder; and sealing the cooling fluid flow path by heating the inner cylinder, around which the metal wires are wound, to a temperature equal to or higher than a diffusion temperature of the metal wires to diffusion-bond the metal wires to each other and diffusion-bond the metal wires and the inner cylinder.
6. A method for manufacturing a combustor for a rocket engine comprising: forming a cooling fluid flow path on an outer surface of an inner cylinder made of metal that constitute a combustion chamber; sticking solder material to at least one of the outer surface of the inner cylinder and metal wires; winding the metal wires around the outer surface of the inner cylinder; and sealing the cooling fluid flow path by heating the inner cylinder, around which the metal wires are wound, to a temperature equal to or higher than a melting temperature of the solder material to braze the metal wires to each other and braze the metal wires and the inner cylinder.
7. The method according to claim 5, the method further comprising: forming a continuous groove on the outer surface of the inner cylinder for guiding the metal wires.
8. The method according to claim 6, the method further comprising: forming a continuous groove on the outer surface of the inner cylinder for guiding the metal wires.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
DETAILED DESCRIPTION
[0031] Hereinafter, embodiments of the present disclosure are described with reference to the accompanying drawings. Hereinafter, in embodiments described below, when a number like a number of a certain thing, quantity, amount, range, or the like of each element is referred to, the idea relating to the present disclosure is not limited to the number referred to, except when it is particularly clarified, or the number is clearly specified in principle. In addition, the structure and the like in the embodiments described below are not necessarily essential to the idea relating to the present disclosure, except when particularly clarified or explicitly specified in principle.
1. Overview
[0032] The present disclosure is applied to, for example, a regeneratively cooled combustor 4 schematically shown in
[0033] The combustor 4 comprises an inner cylinder 12 constituting a combustion chamber 10 and an outer cylinder 18 attached to the outside of the inner cylinder 12. The inner cylinder 12 is made of metal. A cooling fluid flow path 14 is formed inside the wall of the inner cylinder 12. A large number of cooling fluid flow paths 14 are formed from the rear end toward the front end of the combustor 4 at equal intervals around the entire circumference of the inner cylinder 12. Each cooling fluid flow path 14 is connected to doughnut-shaped manifolds 20 and 21 formed at a rear end and a front end of the outer cylinder 18 respectively. The manifold 20 at the rear end supplies the cooling fluid flow path 14 with liquid fuel having high pressure as cooling fluid. The cooling fluid flows through the cooling fluid flow path 14 exchanging heat with the wall of the inner cylinder 12 and is collected by the manifold 21 at the front end. The cooling fluid collected by the manifold 21 at the front end is jetted inside the combustion chamber 10 together with an oxidizing agent supplied from an injector, which is not shown in the drawings, attached to the front end of the combustor 4 through a separated system.
[0034] Specifically, the cooling fluid flow path 14 is a groove formed on an outer surface of the inner cylinder 12 and is sealed by a sealing layer 16 covering the outer surface of the inner cylinder 12. According to the combustor 4, to which the present disclosure is applied, the sealing layer 16 works as a sealing member that prevents the cooling fluid from leaking from the cooling fluid flow path 14. The outer cylinder 18 adheres to a surface of the sealing layer 16 to hold the inner cylinder 12 and protect the sealing layer 16 from the pressure of the cooling fluid flowing through the cooling fluid flow path 14. The outer cylinder 18 is made of metal such as, for example, stainless steel. A method for manufacturing the outer cylinder 18 is not limited, and it may be manufactured by, for example, a bisection method by machining, an integrated layer building method by plating or spraying, or the like. Since the outer cylinder 18 is not required to work as a sealing member, the cooling fluid is not likely to leak from the mating surfaces even when the outer cylinder 18 is formed by two parts.
[0035]
[0036] According to the combustor 4, to which the present disclosure is applied, an opening of the cooling fluid flow path 14 is covered with metal wires 30 wound around the outer surface of the inner cylinder 12 without a gap in a circumferential direction. However, in the example shown in
[0037] The metal wires 30 may be made of any material, but it is preferable that material close to the material of the inner cylinder 12 is selected, and it is particularly preferable that the same material as the material of the inner cylinder 12 is selected. This is because a brittle intermetallic compound may be possibly generated by a heat process depending on the combination of the material of the metal wires 30 and the material of the inner cylinder 12.
[0038] Likewise, the cross-sectional shape of a metal wire 30 is not limited to any shape. While metal wires 30 whose cross-sectional shapes are circles are used in the example shown in
[0039] While the metal wires 30 are wound in a single layer in the example shown in
[0040] The sealing layer 16 is formed by the metal wires 30 wound in a single layer or multiple layers as described above. However, the leakage of the cooling fluid cannot be prevented by merely wound metal wires 30 even when they are wound without any gap and in any number of layers. Therefore, according to the combustor 4, to which the present disclosure is applied, the sealing layer 16 is formed by a bonded body in which the metal wires 30 are bonded to each other by metallurgical bonding. In addition, the metal wires 30 constituting the sealing layer 16 are bonded to the inner cylinder 12 by metallurgical bonding. By metallurgically bonding the metal wires 30 to each other and metallurgically bonding the metal wires 30 and the inner cylinder 12, it is possible to seal the cooling fluid flow path 14 with high reliability.
[0041] Hereinafter, two embodiments of an example of a configuration of the sealing layer 16 of the combustor 4 and a method for manufacturing the combustor 4 are described specifically.
2. First Embodiment
[0042]
[0043] In the first embodiment, the metallurgical bonding to bond the metal wires 30 to each other and bond the metal wires 30 to the inner cylinder 12 is diffusion bonding. By heating the inner cylinder 12 around which the metal wires 30 are wound to a temperature equal to or higher than the diffusion temperature of the metal wires 30, the metal wires 30 are bonded to each other by diffusion sintering, meanwhile the metal wires 30 and the inner cylinder 12 are also bonded by diffusion sintering. Thus the sealing layer 16 is formed by a sintered body obtained by the diffusion sintering of the metal wires 30. Since the sealing layer 16 is also bonded to the inner cylinder 12 by diffusion sintering, it has no gap, and can seal the cooling fluid flow path 14 with high reliability.
[0044] In the first embodiment, the opening of the cooling fluid flow path 14 is covered with a sintered body of the metal wires 30 constituting the sealing layer 16. Since the cooling fluid flow path 14 has a cross section whose shape is narrow and vertically long, the ratio of area of the cover formed by the sealing layer 16 to entire area of the inner surface of the cooling fluid flow path 14 is low. Therefore, although the surface of the cover formed by the sealing layer 16 is not smooth, an increase in pressure loss due to the influence thereof does not cause a remarkable problem.
[0045]
[0046] In step S12, the cooling fluid flow path 14 is formed on the outer surface of the inner cylinder 12. The cooling fluid flow path 14 is formed by, for example, mechanical cutting. The cooling fluid flow path 14 is a groove extending in the axial direction of the inner cylinder 12, and large number of cooling fluid flow paths 14 are formed at equal intervals around the entire circumference of the inner cylinder 12.
[0047] In step S13, the metal wires 30 are wound around the outer surface of the inner cylinder 12, on which the cooling fluid flow path 14 is formed. The metal wires 30 are wound from the front end to the rear end of the inner cylinder 12 so as to cover all the openings of the cooling fluid flow path 14 and are repeatedly wound in layers until the thickness of the sealing layer 16 reaches required thickness. The metal wires 30 are wound under a predetermined tension so as to prevent the metal wires 30 from winding down. Particularly, the metal wires 30 are wound under tension around a curving section since the metal wires 30 can easily wind down at the section.
[0048] In step S14, the inner cylinder 12, around which the metal wires 30 are wound, is heated to a temperature equal to or higher than the diffusion temperature of the metal wires 30. It is heated in a reducing atmosphere such as a hydrogen atmosphere. By heated like this, the metal wires 30 are diffusion-bonded to each other and to the inner cylinder 12 to form the sealing layer 16 sealing the cooling fluid flow path 14. After the sealing layer 16 is formed, the outer cylinder 18 is attached so as to adhere to the surface of the sealing layer 16 to hold the inner cylinder 12.
3. Second Embodiment
[0049]
[0050]
[0051] In the second embodiment, the metallurgical bonding to bond the metal wires 30 to each other and bond the metal wires 30 to the inner cylinder 12 is brazing. In the first example shown in
[0052] In the second example shown in
[0053] In the second embodiment, the opening of the cooling fluid flow path 14 is covered with the metal wires 30 and the solder material 32 or 36 constituting the sealing layer 16. Since the cooling fluid flow path 14 has a cross section whose shape is narrow and vertically long, the ratio of area of the cover formed by the sealing layer 16 to entire area of the inner surface of the cooling fluid flow path 14 is low. Therefore, although the surface of the cover formed by the sealing layer 16 is not smooth, an increase in pressure loss due to the influence thereof does not cause a remarkable problem.
[0054]
[0055] In step S22, the cooling fluid flow path 14 is formed on the outer surface of the inner cylinder 12. The cooling fluid flow path 14 is formed by, for example, mechanical cutting. The cooling fluid flow path 14 is a groove extending in the axial direction of the inner cylinder 12, and large number of cooling fluid flow paths 14 are formed at equal intervals around the entire circumference of the inner cylinder 12.
[0056] In step S23, solder material is sticked to at least one of the outer surface of the inner cylinder 12 and the metal wires 30. The solder material 32 is sticked to the outer surface of the inner cylinder 12 in the example shown in
[0057] In step S24, the metal wires 30 are wound around the outer surface of the inner cylinder 12, on which the cooling fluid flow path 14 is formed. The metal wires 30 are wound from the front end to the rear end of the inner cylinder 12 so as to cover all the openings of the cooling fluid flow path 14 and are repeatedly wound in layers until the thickness of the sealing layer 16 reaches required thickness. The metal wires 30 are wound under a predetermined tension so as to prevent the metal wires 30 from winding down. Particularly, the metal wires 30 are wound under tension around a curving section since the metal wires 30 can easily wind down at the section.
[0058] In step S25, the inner cylinder 12, around which the metal wires 30 are wound, is heated to a temperature equal to or higher than the melting temperature of the solder material 32 and 34. However, the temperature is made to be lower than the diffusion temperature of the metal wires 30. It is heated in a reducing atmosphere such as a hydrogen atmosphere. By heated like this, the metal wires 30 are brazed to each other and to the inner cylinder 12 by the solder material 32 or 36 to form the sealing layer 16 sealing the cooling fluid flow path 14. After the sealing layer 16 is formed, the outer cylinder 18 is attached so as to adhere to the surface of the sealing layer 16 to hold the inner cylinder 12.
4. How to Wind Metal Wires
[0059] Here, it is described how the metal wires 30 are wound around the outer surface of the inner cylinder 12 with reference to
[0060] In
[0061] As shown in
[0062] In
[0063] In
Examples of Performance
(Water Pressure Resistance/Airtightness Test)
[0064] In each example and comparative example, a combustor in which a cooling fluid flow path was sealed was manufactured by metallurgically bonding metal wires to each other and metallurgically bonding metal wires to an inner cylinder. An outer cylinder made of stainless steel to hold the inner cylinder was manufactured by the bisection method by machining, and then an outer surface of the combustor was held by the outer cylinder. Then, water was made to flow through the cooling fluid flow path of the combustor, and it was kept under pressure of 2.0 MPa for 10 minutes and it was observed whether decrease in pressure occurred. In addition, thickness and sintering rate of a sealing layer were also measured.
[0065] In common to all examples and comparative examples, an inner cylinder constituting a combustor had a regularly designed shape. Size relating to an inner cylinder such as an outer diameter was common to all examples and comparative examples, and the number and cross-sectional shapes of cooling fluid flow paths formed on an inner cylinder were also common to all examples and comparative examples. After columnar material of copper alloy was machined into the designed shape of an inner cylinder, a plurality of cooling fluid flow paths were machined on an outer surface thereof. A shape (particularly, width) of a flow path varies depending on a position in axial direction of an inner cylinder, and width is narrowest at a constricted section between a combustion chamber and a nozzle. In the examples of performance, a flow path at a constricted section was formed into a shape 1.2 mm wide and 3.0 mm deep.
[0066] A metal wire for a seal was a phosphorus bronze wire because an inner cylinder was made of copper alloy. A cross-sectional shape of a metal wire was a circle, a rectangle, or an ellipse. Aspect ratio of a long side to a short side of a rectangular metal wire was 10:3. Aspect ratio of a long side to a short side of an elliptical metal wire was 10:3.
[0067] In an example in which the diffusion bonding process was performed, a temperature was raised in a hydrogen atmosphere for two hours with the highest temperature being 900 degrees C., which is a temperature equal to or higher than the diffusion temperature of a phosphor bronze wire. In an example in which the brazing process was performed, an outer surface of an inner cylinder in which a cooling fluid flow path was formed was plated with silver, which was solder material, with a thickness of 10 μm. Then, a temperature was raised in a hydrogen atmosphere for one hour with the highest temperature being 780 degrees C., which is a temperature equal to or higher than the melting temperature of silver.
EXAMPLE 1
[0068] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 0.5 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 2
[0069] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 1. 0 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 3
[0070] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 1.0 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 4
[0071] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 0.5 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 5
[0072] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 1.0 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 6
[0073] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 1.0 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
[0074] The details and evaluation results according to the methods of manufacturing the combustors of Examples 1 to 6 are shown in Table 1.
TABLE-US-00001 TABLE 1 Sealing wire Inner cylinder Cross- Outer Solder sectional Long Winding diameter Material material Material shape side direction Example 1 Φ226 Cu—Cr—Zr — Phosphorus Circular 0.5 mm — bronze wire (C5212W) Example 2 Φ226 Cu—Cr—Zr — Phosphorus Polygonal 1.0 mm Horizontal bronze wire (C5213W) Example 3 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 1.0 mm Horizontal bronze wire (C5214W) Example 4 Φ226 Cu—Cr—Zr Ag Phosphorus Circular 0.5 mm — solder bronze wire (C5215W) Example 5 Φ226 Cu—Cr—Zr Ag Phosphorus Polygonal 1.0 mm Horizontal solder bronze wire (C5216W) Example 6 Φ226 Cu—Cr—Zr Ag Phosphorus Elliptical 1.0 mm Horizontal solder bronze wire (C5217W) Evaluation results Water Heating condition Sealing Sintering pressure Temperature Time layer rate resistance/ (° C.) (hrs) Atmosphere thickness (%) Airtightness Example 1 900 2 H2 2.5 mm 0.88 Good Example 2 900 2 H2 2.0 mm 0.93 Good Example 3 900 2 H2 2.2 mm 0.9 Good Example 4 780 1 H2 3.0 mm 0.82 Good Example 5 780 1 H2 2.5 mm 0.87 Good Example 6 780 1 H2 2.8 mm 0.85 Good
EXAMPLE 7
[0075] The inner cylinder was made of Cu—Cr alloy. The metal wires having circular cross-sectional shapes and long sides of 20 μm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 8
[0076] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 200 μm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 9
[0077] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 380 μm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 10
[0078] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 2.0 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 11
[0079] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 3.4 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 12
[0080] The inner cylinder was made of Cu—Cr alloy. The metal wires having circular cross-sectional shapes and long sides of 5.1 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 13
[0081] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 6.6 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 14
[0082] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 8.1 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 15
[0083] The inner cylinder was made of Cu—Cr alloy. The metal wires having circular cross-sectional shapes and long sides of 9.5 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
[0084] The details and evaluation results according to the methods of manufacturing the combustors of Examples 7 to 15 are shown in Table 2.
TABLE-US-00002 TABLE 2 Sealing wire Inner cylinder Cross- Outer Solder sectional Long Winding diameter Material material Material shape side direction Example 7 Φ226 Cu—Cr — Phosphorus Circular 20 μm — bronze wire (C5218W) Example 8 Φ226 Cu—Cr—Zr Ag Phosphorus Circular 200 μm — solder bronze wire (C5219W) Example 9 Φ226 Cu—Cr—Zr — Phosphorus Circular 380 μm — bronze wire (C5220W) Example 10 Φ226 Cu—Cr—Zr — Phosphorus Circular 2.0 mm — bronze wire (C5221W) Example 11 Φ226 Cu—Cr—Zr Ag Phosphorus Circular 3.4 mm — solder bronze wire (C5222W) Example 12 Φ226 Cu—Cr — Phosphorus Circular 5.1 mm — bronze wire (C5223W) Example 13 Φ226 Cu—Cr—Zr — Phosphorus Circular 6.6 mm — bronze wire (C5224W) Example 14 Φ226 Cu—Cr—Zr Ag Phosphorus Circular 8.1 mm — solder bronze wire (C5225W) Example 15 Φ226 Cu—Cr — Phosphorus Circular 9.5 mm — bronze wire (C5226W) Evaluation results Water Heating condition Sealing Sintering pressure Temperature Time layer rate resistance/ (° C.) (hrs) Atmosphere thickness (%) Airtightness Example 7 900 2 H2 2.0 mm 0.93 Good Example 8 780 1 H2 2.5 mm 0.91 Good Example 9 900 2 H2 2.8 mm 0.86 Good Example 10 900 2 H2 3.0 mm 0.82 Good Example 11 780 1 H2 3.1 mm 0.81 Good Example 12 900 2 H2 3.3 mm 0.79 Good Example 13 900 2 H2 3.4 mm 0.77 Good Example 14 780 1 H2 3.5 mm 0.76 Good Example 15 900 2 H2 3.6 mm 0.75 Good
EXAMPLE 16
[0085] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 30 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 17
[0086] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 250 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 18
[0087] The inner cylinder was made of Cu—Cr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 420 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 19
[0088] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 710 μm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 20
[0089] The inner cylinder was made of Cu—Cr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 3.3 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 21
[0090] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 5.0 mm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 22
[0091] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 6.4 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 23
[0092] The inner cylinder was made of Cu—Cr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 7.8 mm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 24
[0093] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having polygonal cross-sectional shapes and long sides of 9.3 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
[0094] The details and evaluation results according to the methods of manufacturing the combustors of Examples 16 to 24 are shown in Table 3.
TABLE-US-00003 TABLE 3 Sealing wire Inner cylinder Cross- Outer Solder section Long Winding diameter Material material Material Shape side direction Example 16 Φ226 Cu—Cr—Zr Ag Phosphorus Polygonal 30 μm Horizontal solder bronze wire (C5227W) Example 17 Φ226 Cu—Cr—Zr — Phosphorus Polygonal 250 μm Horizontal bronze wire (C5228W) Example 18 Φ226 Cu—Cr — Phosphorus Polygonal 420 μm Horizontal bronze wire (C5229W) Example 19 Φ226 Cu—Cr—Zr — Phosphorus Polygonal 710 μm Vertical bronze wire (C5230W) Example 20 Φ226 Cu—Cr — Phosphorus Polygonal 3.3 mm Horizontal bronze wire (C5231W) Example 21 Φ226 Cu—Cr—Zr Ag Phosphorus Polygonal 5.0 mm Vertical solder bronze wire (C5232W) Example 22 Φ226 Cu—Cr—Zr — Phosphorus Polygonal 6.4 mm Horizontal bronze wire (C5233W) Example 23 Φ226 Cu—Cr Ag Phosphorus Polygonal 7.8 mm Vertical solder bronze wire (C5234W) Example 24 Φ226 Cu—Cr—Zr — Phosphorus Polygonal 9.3 mm Horizontal bronze wire (C5235W) Evaluation results Water Heating condition Sealing Sintering pressure Temperature Time layer rate resistance/ (° C.) (hrs) Atmosphere Thickness (%) Airtightness Example 16 780 1 H2 1.8 mm 0.95 Good Example 17 900 2 H2 2.3 mm 0.92 Good Example 18 900 2 H2 2.7 mm 0.87 Good Example 19 900 2 H2 3.0 mm 0.85 Good Example 20 900 2 H2 3.0 mm 0.82 Good Example 21 780 1 H2 3.1 mm 0.8 Good Example 22 900 2 H2 3.2 mm 0.79 Good Example 23 780 1 H2 3.4 mm 0.78 Good Example 24 900 2 H2 3.4 mm 0.77 Good
EXAMPLE 25
[0095] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 50 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 26
[0096] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 280 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 27
[0097] The inner cylinder was made of Cu—Cr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 450 μm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 28
[0098] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 750 μm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 29
[0099] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 3.1 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 30
[0100] The inner cylinder was made of Cu—Cr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 4.8 mm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 31
[0101] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 6.1 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 32
[0102] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 7.5 mm were used with their winding direction being horizontal. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
EXAMPLE 33
[0103] The inner cylinder was made of Cu—Cr alloy. The metal wires having elliptical cross-sectional shapes and long sides of 7.5 mm were used with their winding direction being vertical. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was brazing. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure was not observed.
[0104] The details and evaluation results according to the methods of manufacturing the combustors of Examples 25 to 33 are shown in Table 4.
TABLE-US-00004 TABLE 4 Sealing wire Inner cylinder Cross- Outer Solder section Long Winding diameter Material material Material Shape side direction Example 25 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 50 μm Horizontal bronze wire (C5236W) Example 26 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 280 μm Horizontal bronze wire (C5237W) Example 27 Φ226 Cu—Cr Ag Phosphorus Elliptical 450 μm Vertical solder bronze wire (C5238W) Example 28 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 750 μm Horizontal bronze wire (C5239W) Example 29 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 3.1 mm Horizontal bronze wire (C5240W) Example 30 Φ226 Cu—Cr Ag Phosphorus Elliptical 4.8 mm Vertical solder bronze wire (C5241W) Example 31 Φ226 Cu—Cr—Zr — Phosphorus Elliptical 6.1 mm Horizontal bronze wire (C5242W) Example 32 Φ226 Cu—Cr — Phosphorus Elliptical 7.5 mm Horizontal bronze wire (C5243W) Example 33 Φ226 Cu—Cr—Zr Ag Phosphorus Elliptical 9.0 mm Vertical solder bronze wire (C5244W) Evaluation results Water Heating condition Sealing Sintering pressure Temperature Time layer rate resistance/ (° C.) (hrs) Atmosphere Thickness (%) Airtightness Example 25 900 2 H2 1.9 mm 0.94 Good Example 26 900 2 H2 2.4 mm 0.91 Good Example 27 780 1 H2 2.8 mm 0.86 Good Example 28 900 2 H2 3.0 mm 0.84 Good Example 29 900 2 H2 3.1 mm 0.81 Good Example 30 780 1 H2 3.3 mm 0.79 Good Example 31 900 2 H2 3.3 mm 0.78 Good Example 32 900 2 H2 3.5 mm 0.77 Good Example 33 780 1 H2 3.6 mm 0.76 Good
COMPARATIVE EXAMPLE 1
[0105] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 5 μm were used. However, a metal wire was broken because of the tension when the metal wires were wound around the inner cylinder, and the metal wires could not be wound around the inner cylinder.
COMPARATIVE EXAMPLE 2
[0106] The inner cylinder was made of Cu—Cr—Zr alloy. The metal wires having circular cross-sectional shapes and long sides of 12 mm were used. A method for bonding the metal wires to each other and bonding the metal wires to the inner cylinder was diffusion bonding. As a result of performing the airtightness test after the water pressure resistance test, decrease in pressure due to pressure leakage occurred.
[0107] The details and evaluation results according to the methods of manufacturing the combustors of Comparative Examples 1 and 2 are shown in Table 5.
TABLE-US-00005 TABLE 5 Sealing wire Inner cylinder Cross- Outer Solder section Long Winding diameter Material material Material Shape side direction Compar- Φ226 Cu—Cr—Zr — Phosphorus Circular 5 μm — ative bronze wire example 1 (C5246W) Compar- Φ226 Cu—Cr—Zr — Phosphorus Circular 12 mm — ative bronze wire example 1 (C5247W) Evaluation results Water Heating condition Sealing Sintering pressure Temperature Time layer rate resistance/ (° C.) (hrs) Atmosphere Thickness (%) Airtightness Compar- — — — Wire breakage during winding ative example 1 Compar- 900 2 H2 11 mm — Occurrence ative of leakage example 1
DISCUSSION
[0108] According to the above-described Examples and Comparative Examples, it can be determined that one preferable range of a long side is from 10 μm to 10 mm with respect to thickness of a metal wire regardless of a cross-sectional shape of the metal wire and whether metal wires are diffusion-bonded or brazed.