Gas chromatograph and methods for using air as a carrier gas

Abstract

The disclosure describes embodiments of an apparatus useful for the on-line analysis of gas and liquid samples including a gas compressor or pump, a sampling valve, a separation module, and one or more detectors. The detectors may include catalytic pellistors, thermal conductivity devices, or other sensors capable of detecting chemical substances in the presence of ambient air. These particular sensors in combination with reference elements allow direct use of ambient air as the carrier for analysis without pretreatment of the said air. Other embodiments are disclosed and claimed.

Claims

1. A gas chromatograph comprising: an inlet port for a sample gas; an air pump or air compression device for supplying air as a carrier gas into a sampling valve; a pressure or flow sensor useful for measuring flow of said carrier gas; an injection valve used to introduce a sample into a separation column; a gas separation column used to cause a flow delay depending on the gas component; temperature sensors and heaters to control the separation column temperature; a gas sensor system capable of detecting the separated components emitted from the separation column; an outlet port for venting waste gas; a microcontroller to control the gas flow, temperature, and pressure, and to transmit signals from the sensors to a recording or analysis device.

2. The gas chromatograph of claim 1, in which the gas sensor system consists of a catalytic pellistor and reference, in which sample gas is combusted on the catalytic surface of the pellistor and the resulting temperature rise is detected by the rise in temperature and change in electrical resistance relative to a reference sensor where no combustion occurs.

3. The gas chromatograph of claim 1, in which the gas sensor system consists of a thermal conductivity detector and reference system in which the thermal conductivity detector is exposed to the target gas and the reference detector only to carrier air, and the change in the thermal conductivity detector and thus resistance relative to the reference sensor is used to detect the presence of gases.

4. The gas chromatograph of claim 1, in which the carrier gas is air compressed by means of an air pump or air compressor with pressure modulated from feedback from a pressure sensor.

5. The gas chromatograph of claim 1, in which the sampling valve is manipulated by an actuator that causes it to transition from a load to an inject position.

6. The gas chromatograph of claim 1, in which the separation column consists of fused silica, metal, packed columns, microfluidic devices, or plot columns.

7. The gas chromatograph of claim 1, in which the column temperature is modified via heating wire or resistance wire or via resistive heating in the case of metal columns, wherein the temperature is monitored by a temperature sensor.

8. The temperature sensor of claim 7, which may consist of resistive temperature detectors, thermistors, or thermocouples.

9. The gas chromatograph of claim 1, characterized in that said gas chromatograph is a portable device.

10. The gas chromatograph of claim 1, wherein the signal output from the device may be transmitted to a computer or recording device by cable or by wireless communication.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0022] FIG. 1. Is a schematic diagram showing the entire gas chromatograph system wherein gas tubing is depicted by solid lines and electrical connections are depicted by dashed lines.

[0023] FIG. 2. Is a schematic of the injector valve in the load and inject positions

[0024] FIG. 3. Is a schematic diagram of the catalytic pellistor sensor with the active catalyst component and reference component used to correct for changes in air carrier temperature, pressure, and composition.

[0025] Gas chromatograph and methods for using air as a carrier gas