Mounting mat
09650935 ยท 2017-05-16
Assignee
Inventors
Cpc classification
Y10T156/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/24777
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F01N2350/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01N3/2864
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B32B5/26
PERFORMING OPERATIONS; TRANSPORTING
B32B7/14
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/13
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F01N3/2853
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y10T428/192
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/14
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/24752
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B3/06
PERFORMING OPERATIONS; TRANSPORTING
B32B5/06
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
F01N3/28
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B32B3/06
PERFORMING OPERATIONS; TRANSPORTING
B32B5/26
PERFORMING OPERATIONS; TRANSPORTING
B32B7/14
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B5/06
PERFORMING OPERATIONS; TRANSPORTING
B32B37/14
PERFORMING OPERATIONS; TRANSPORTING
B32B3/08
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A mat for mounting a monolith, the mat comprising a first inorganic fiber layer, where the mat has a front edge intended to form a gas facing edge in use, a rear edge opposite thereto and side edges extending between the front and rear edges, wherein the first inorganic fiber layer at a first side edge of the mat, and/or at a second side edge of the mat is cut at an acute angle to the thickness direction of the mat.
Claims
1. A mat for mounting a monolith, the mat comprising a first inorganic fibre layer, where the mat has a front edge forming a gas facing edge in use, a rear edge opposite thereto and side edges extending between the front and rear edges, wherein the first inorganic fibre layer at a first side edge of the mat, and/or at a second side edge of the mat is cut at an acute angle to the thickness direction of the mat to provide a substantially trapezoidal cross section.
2. A mat according to claim 1 comprising a second inorganic fibre layer wherein at least a part of a major surface of the first layer is bonded to at least a part of a major surface of the second layer.
3. A mat according to claim 2, wherein the second layer at the first side edge of the mat, and/or the second layer at the second side edge of the mat is cut at an acute angle to the thickness direction of the mat to provide a substantially trapezoidal cross section.
4. A mat according to claim 3, wherein the sum of the cut angles of the second layer at the first and/or second side edges of the mat is 60 to 80, optionally 70 to the thickness direction of the mat.
5. A mat according to claim 2, further comprising a third layer and optionally a fourth layer of inorganic fibres.
6. A mat according to claim 2, wherein the first layer has a basis weight of around 1000 to 5000 g/m.sup.2 and the second layer has a basis weight of around 1000 to 7000 g/m.sup.2, where the basis weight of the first layer may be the same as or different from the basis weight of the second layer.
7. A mat according to claim 2, wherein the first and second layers are bonded to each other by securing means.
8. A mat according to claim 7, wherein the securing means extends from the front edge to the rear edge of the mat.
9. A mat according to claim 7, wherein the securing means comprises an adhesive, optionally an organic binder, a polyvinyl acetate, a pressure sensitive adhesive, an adhesive web, a polyester based thermoplastic web with a melting point in the range of 110130 C., a starch, a polymerisable material, a heat polymerisable material, an acrylate, a crosslinkable acrylate, and/or a saccharide.
10. A mat according to claim 9, wherein the adhesive is arranged in a plurality of regions between the major surfaces of the first and second layers.
11. A mat according to claim 9, wherein the adhesive has a shear strength over an area of 25 cm.sup.2 of at least 4N, optionally at least 8N, further optionally between 8N and 30 N.
12. A mat according to claim 2, wherein the first and second layers are secured to each other by needling.
13. A mat according to claim 2, wherein the interface between the major surfaces of the layers is smaller than one or both of the major surfaces, optionally wherein the first layer and the second layer are offset with respect to one another, further optionally in the canning direction and/or in the wrapping direction.
14. A mat according to claim 2, wherein at least one of the major surface areas of the second layer is at least equal to, or greater than at least one of the major surface areas of the first layer, optionally wherein the width of the second layer is greater than the width of the first layer.
15. A mat according to claim 14, wherein the first layer and the second layer are, at rest, discontinuously in contact, optionally wherein the second layer is attached to the first layer such that the mat forms a bow shape.
16. A mat according to claim 14, wherein the first layer is divided into a plurality of pieces, optionally wherein the pieces of the first layer comprise a recessed portion for receiving a corresponding projected portion of an adjacent piece or a projecting portion for being received in a corresponding recessed portion of an adjacent piece.
17. A mat according to claim 14, wherein the first layer is attached to the second layer at one side edge, the other side edge being unattached; optionally wherein the mat comprises attachment means for attaching the first layer to the second layer at the other side edge, optionally to create a bow shaped mat, prior to installation; further optionally wherein the attachment means comprises a portion of adhesive tape or a region of adhesive on the first and/or second layer, optionally covered with a removable tab or release liner.
18. A mat according to claim 2, wherein the ratio of the thickness of the first layer to the second layer is 1-10:10-1.
19. A mat according to claim 2, wherein the first side edge of the first layer and/or the second layer of the mat and/or the second side edge of the first layer and/or the second layer of the mat opposite the first side edge is cut at an acute angle to the thickness direction of the mat to give the mat and/or either or both of the first layer or second layer a trapezoidal cross section.
20. A mat according to claim 19, wherein the sum of the cut angles at the first and/or second side edges of the mat is 60 to 80 to the thickness direction of the mat.
21. A mat according to claim 1, wherein the sum of the cut angles of the first layer at the first and/or second side edges of the mat is between 0 and 90, optionally from 60 to 80, further optionally 70 to the thickness direction of the mat.
22. A mat according to claim 1 having a basis weight of 3000 to 10000 g/m.sup.2.
23. A mat according to claim 1, wherein intended front and/or rear edges of the first and/or second layers, if present, of the mat are stepped, shaped, and/or cut such that at least a portion of the front edge of the mat effectively protrudes from the mat and/or at least a portion of the rear edge of the mat effectively recedes from the mat, optionally wherein the first and/or second layers are stepped such that the first and second layers are offset with respect to one another in the intended axial direction.
24. A mat according to claim 23, wherein the intended front and/or rear edges of the first and/or second layers, if present, of the mat are slant cut to provide a substantially trapezoidal cross section.
Description
(1) Embodiments of the invention will now be described in more detail with reference to the accompanying drawings.
(2)
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(12) An inner mat 10 is shown in
(13) The inner layer 12, intended to be positioned adjacent the can in use, comprises a needled nonwoven silica fibre mat. The outer layer 14, intended to be positioned adjacent the monolith in use, is comprised of non-woven alumina fibres and includes an organic, e.g. latex, binder which helps to maintain its structural integrity during handling. The total organic content of the mat 10, including the binder, is around 2.2 w/w %.
(14) The thickness T.sub.S of the inner layer 12 is around three times that of the thickness T.sub.A of the outer layer 14.
(15) The adhesive 16 comprises a PVA adhesive, such as may be applied by means of an aqueous solution.
(16) The adhesive 16 is arranged in a regular or random array or arrays of spots at the interface 24 between the inner layer 12 and the outer layer 14. A first array 16a is positioned toward a first side edge 10C of the mat, a second array 16b is positioned in a portion 22 approximately half way along the mat and a third array 16c is positioned toward the second side edge 10D of the mat.
(17) Ensuring that an effective and secure fit around the monolith 30, the inner and outer layers 12, 14 are offset with respect to one another. The inner layer 12 is secured atop the outer layer 14 such that the inner layer 12 directly overlays and aligns with the outer layer 14 along the front edge 10A and back edge 10B of the mat, but is staggered in the width direction, the width direction intended to be circumferential to the monolith 30 in use.
(18) At the first side edge 10C of the mat 10, a notch 26 is cut into the mat 10 for receiving a corresponding tongue 28 positioned at the second side edge 10D of the mat 10 when the mat is wrapped around a monolith 39, thereby helping to secure the mat 10 in place before canning.
(19) The end 32 of the tongue 28, the inner edge 34 of the notch 26 and the first side 10C and the second side 10D of the inner and outer layers 12, 14 are cut on a slant such that the width of the inner 12 and outer 14 layers is greater in the outer, can-facing surfaces than in their inner, monolith facing surfaces, each of the inner 12 and outer 14 layers thereby having a trapezoidal cross section. These slant cuts allow the mat 10 to be effectively wrapped around the monolith 30 and secured in place without leaving a typical V-shaped aperture 31 along the principal axis of the monolith 30 typical of straight-ended mats (see
(20) In another feature to ensure effective wrapping of the mat 10 around a monolith 30, the average width of the inner layer 12 is greater than that of the outer layer 14, the monolith facing surface 38 of the inner layer being substantially equal in width to the can facing surface 40 of the outer layer 14. The difference in width of the two layers 12, 14, particularly when combined with the slant cuts at the side edges of the mat 10 ensure that the mat completely encircles the monolith 30 in use, providing an effective holding pressure and preventing flow of gas other than through the monolith 30 itself.
(21)
(22) This arrangement ensures that when the mat 10 is canned in a direction A (relative to a static can) with a monolith by hard stuffing into a can of similar (or even smaller) diameter, with the front edge 10A of the mat 10 acting as the leading edge, the inner layer 12 is stretched into alignment and a substantially rectangular shape by friction forces on the internal walls of the can. In turn, this ensures a substantially uniform density of the mat 10 around the monolith in use.
(23) Of course, this feature could be applied to any mat, whether a laminate or single layered mat. Moreover, laminate mats may have one some or all of their layers slant cut in this manner.
(24) While in this embodiment, the slant cuts are provided such that the mat has a substantially rhomboid cross section, the cuts may be of differing shapes (e.g. stepped, parabolic or otherwise curved), provided that the front edge 10A of the mat 10 effectively protrudes from the mat at its intended outer face and the rear edge 10B of the mat effectively recedes (e.g. by substantially the same amount) at its intended outer face.
(25) This feature may be additionally or alternatively provided by using a longer (in the intended axial direction, i.e. between their respective front 10A and rear 10B edges) inner layer 12 than outer layer 14, to offer a protruding portion of the inner layer 12 at the front edge 10A and/or offsetting the layers 12, 14 to provide a protruding portion of the inner layer 12 at the front edge 10A and a protruding portion of the outer layer 14 at the rear edge 10B.
(26) The mat 10 is preferably made by application of the adhesive 16 to the surface of the inner layer 12 or outer layer 14, placing the outer layer 14 or the inner layer 12 thereupon, as appropriate, aligned as described above. The combined inner and outer layers 12, 14 are then placed in a hot press and held at 0.2 GBD at 180 C. (such that the interface 24 temperature is not allowed to exceed 140 C.) for 1 to 20 minutes.
(27) By curing the adhesive when the mat is held in a particular arrangement, e.g. rolled cylindrically as if wrapped around a monolith, the mat may substantially hold this shape after curing, as is shown in
(28) The adhesive may be a 0.01 w/w % to 50 w/w % aqueous PVA solution, having a viscosity between 1 cP and 10000 cP (as measured on a Brookfield DV-II rheometer set at 30 rpm), which may be a ready made solution or made by dissolving thermoplastic PVA fibres in hot water. The solution is applied on the surface of the inner layer 12 or the outer layer 14 in a first array 16a is positioned toward a first side 18 of the mat, a second array 16b is positioned in a portion 22 approximately half way along the mat and a third array 16c is positioned toward the second side 20 of the mat.
(29) More concentrated PVA solutions (e.g. 10 w/w % to 50 w/w %) are preferred when the inner layer 12 comprises silica fibres. However, in alternative embodiments, such as where the outer layer comprises alumina or alumina silica fibres, lower concentration PVA solutions (e.g. 0.01 w/w % to 10 w/w %) may be preferred.
(30) As would be understood by one skilled in the art, many other adhesives may provide appropriate means for securing the inner layer 12 to the outer layer 14. Such adhesives may include starch (e.g. starch wallpaper paste), thermoplastic web such as Bostik 30 GSM (available from Bostik Limited) and pressure sensitive adhesives.
(31) Such a thermoplastic web may, for example, be continuously fed between lines of inner 12 and outer 14 layers e.g. by sets of optionally heated nip rollers. The inner 12 and outer 14 layers may then be pressed into a laminate e.g. by further sets of optionally heated nip rollers.
(32) When fitting the mat 10 around a monolith 30, the monolith 30 is placed on the outer layer 14 and the mat 10 is wound around the monolith 30, being secured by fitting the tongue 28 into the notch 26. Optionally, a quantity of adhesive tape or further liquid adhesive may be used to further secure together the first side 18 of the mat 10 and the second side 20 of the mat 10.
(33) The monolith 30 wrapped in the mat 10 may then be canned by known stuffing methods, loaded into a clamshell can, or by any other method as known by those skilled in the art.
(34) Further resistance to telescoping during stuffing may be provided by, for example, wrapping the mat 10, 200 itself with a scrim, e.g. a ligno-cellulosic or polypropylene scrim which burns away in use.
(35) A further embodiment is shown in
(36) Each section 406 of the outer layer 404 is adhered to the inner layer 402. As described above, the outer silica fibre layer 404 is longer than the inner alumina fibre layer 402, enabling an effective fit when wrapped around a monolith. Moreover, tongue and notch sections and slanted cut edges may be provided, as described above.
(37) The provision of the outer layer 404 in a plurality of sections 406 allows for improved flexibility of the mat 400 while each section 406 is individually adhered to the inner layer 402, thereby also reducing the likelihood of telescoping.
(38) As would be understood by those skilled in the art, the same effect could be achieved by providing a single piece alumina or silica fibre layer for a can-facing surface of a mat and a multi-section alumina fibre layer for a monolith-facing surface of that mat.
(39) Another embodiment is shown in
(40) The interfacing surfaces 306, 308 of the inner layer 302 and the outer layer 304 are adhered to each other in the region of side edges 302a, 302b, 304a, 304b of the layers such that those side edges 302a, 302b, 304a, 304b directly overlay each other. This adhesion arrangement causes the mat 300 to bow, providing for easier wrapping around a monolith.
(41) As the mat 300 is wrapped around a monolith, the gap 310 between the inner layer 302 and the outer layer 304 narrows, providing a snug fit around the monolith.
(42) The arcing of the mat in its unwrapped form imparts good flexibility, at least in part because the two layers 302, 304 are unable to support (and thus stiffen) each other as they would do when in direct interfacial contact.
(43) In order to allow this mat 300 to be efficiently stored, it may be provided to the user when the inner 302 and outer 304 layers are secured together at only one of the side edges 302a, 302b, 304a, 304b, and securing means such as a portion of adhesive tape may be used to secure together the other of the side edges 302a, 302b, 304a, 304b of the mat 300.
(44) Alternatively, the inner layer 302 may be provided in two parts 306a, 306b, securable together by engaging a projecting portion 308a of the first part 306a with a corresponding recessed portion 308b on the second part 306b.
(45) In a variation of this embodiment shown in
(46) In a further embodiment, a laminate mat is provided by adhering together successive layers alumina fibre mats of the same, different or progressively lighter basis weight. For example, a first mat may comprise a layer of 2600 gm.sup.2 alumina fibre material and a second layer of the same material. Alternatively, a second mat may comprise a layer of 3000 gm.sup.2 alumina fibre material and a second layer of 2200 gm.sup.2 alumina fibre material. Still alternatively, a mat may comprise an inner layer of 2700 gm.sup.2 alumina fibre material, an outer layer of 1250 gm.sup.2 alumina fibre material and a third layer of 1250 gm.sup.2 alumina fibre material.
(47) The relative ease with which the alumina fibre layers can be adhered together means that a strong bond can be provided between the layers and that the mat is thus resistant to telescoping during canning.
(48) In another embodiment, as is shown in
(49) The segments are shaped to each include interengagable tongues 104 and notches (106) at their side edges 108a, 108b. Moreover, the side edges are each shaped to define an angle of 35 with the thickness direction of the complete mat (i.e. the radial direction).
(50) When the segments 102 are brought together, a cylindrical mat 100 is formed.
(51) The segments 102 are formed by slurrying alumina fibres with pulp and an organic binder (e.g. latex) and up to 60 w/w % alumina sol. The organic binder optionally has a high Tg, e.g. between 20 C. and 60 C. The slurry is added to a mould dimensioned to provide a cylindrical segment having an internal diameter substantially equal to the diameter of the monolith 30 and a circumference portion of one fifth of the circumference of the monolith 30. Excess liquid is removed under compression and vacuum, the segment 102 being allowed to dry by optional heating under compression. The finished segments can be stacked for ease and efficiency of storage and transport.
(52) In loading the monolith 30 into a can, the segments 102 may be arranged around the outside of the monolith 30, thereby encircling the monolith 30 to provide a complete cylindrical mat 100, the tongues 104 each engaging the notches 106 of the adjacent segment 102. The segments 102 may, if necessary, be secured in place by a quantity of adhesive tape, or by tying with metallic, plastic or textile ties, e.g. straps. The monolith 30 and mat 100 may then be loaded into the can by e.g. stuffing or by a clamshell arrangement, as is understood by those skilled in the art. As the mat does not comprise a laminate material, it is less susceptible to problems of stuffing such as mat telescoping.
(53) Tests
(54) Thermal Conductivity Test
(55) In order to test the insulation properties of the mats, a directly controlled platen was provided at 800 C. The outer layer 14 of the mat was placed against the hot platen and an unheated cool platen was placed against the inner layer 12 of the mat. The mat was compressed to a fibre gap bulk density (FGBD) of 0.4. The temperature was measured at the interface of the inner layer 12 and the outer layer 14 of the mat 10, and at the interface of the inner layer 12 and the unheated platen.
(56) Laminar Shear Test
(57) In order to test the laminar shear strength, mats were loaded into apparatus comprising a fixed support, a movable support and a means for measuring the tensile force applied by the movable support. The inner layer 12 was attached at the second side 20 of the mat 10 to the stationary support and the outer layer 14 was attached at the first side 18 of the mat 10 to the movable support. The movable support was actuated to provide an increasing and measurable force pulling away from the stationary support. The force at which the laminar structure of the mat 10 failed, be it by failure of the adhesive or one or both of the layers or otherwise, was noted.
(58) Pressure Performance (PP) Test
(59) Mats are fired up to 800 C. to remove any remaining organic species and the organic binder. The mats are then cycled 2500 times in a spacer between a compression of FGBD 0.3 or 0.4 gcm.sup.3 and a 4%, 6%, 8% or 10% relative gap expansion (RGE). The holding pressure was then measured at 4%, 6%, 8% or 10% RGE at the 2500.sup.th cycle.
(60) In an ambient temperature version of the PP test, the spacer comprises a pair of plates held at ambient temperature. In a hot/ambient version of the PP test, one plate of the spacer is held at ambient temperature, the other plate being held at 800 C., the alumina fibre layer of the mat being adjacent the hot plate.
(61) Shape Retention Test
(62) Mat segments are tested for their rigidity when moulded into an arcuate shape by measuring the radius of the arc of the freestanding segment.
Example 1
(63) A laminate mat was manufactured as described above by joining an alumina fibre mat (for example a SAFFIL E200 alumina fibre mat available from Saffil Automotive Limited, UK) having a basis weight of around 1000 gm.sup.2 and a needled silica fibre mat having an average basis weight of around 4000 gm.sup.2 and an average thickness of around 25 mm.
(64) The mat was subjected to the thermal conductivity test, having the alumina silica layer adjacent the hot platen. The temperature at the interface of the alumina silica layer and the silica layer was 605 C. The temperature at the interface of the silica layer and the unheated platen was 160 C., well below 200 C.
(65) The following Examples demonstrate the efficacy of different adhesive regimes. The mats of Examples 2, 3 and 4 were manufactured as described in Example 1 above, using adhesives as described. Each was subjected to the Tensile Strength test
Example 2
(66) 25 w/w % aqueous PVA solution was used as an adhesive and applied to the alumina silica layer in a 16 dot matrix at 0.04 ml per dot. The silica fibre layer was then added to create the laminate mat, which was then pressed in a hot press at 180 C. until the temperature at the interface between the layers reached 140 C. at 0.2 GBD, around 6 to 8 minutes.
(67) The resulting cured laminate mat was handleable and could be loaded into a can with a monolith by stuffing and clamshell type methods. The mat was found to tear in the silica fibre layer only when the tensile force applied exceeded 30 N.
Example 3
(68) 1 w/w % aqueous PVA solution, made by dissolving thermoplastic PVA flakes in water, was used as an adhesive and applied to the alumina silica layer in a 16 dot matrix at 0.04 ml per dot. The silica fibre layer was then added to create the laminate mat, which was then pressed in a hot press at 180 C. until the temperature at the interface between the layers reached 140 C. at 0.2 GBD, around 6 to 8 minutes.
(69) The resulting cured laminate mat was handleable and could be loaded into a can with a monolith by stuffing and clamshell type methods. The mat was found to tear in the silica fibre layer only when the tensile force applied exceeded 30 N.
Example 4
(70) A single layer of BOSTIK 30 gsm adhesive webbing was placed between the alumina silica and silica fibre layers as an adhesive. The laminate was then placed in a hot press at 180 C. until the temperature at the interface between the layers reached 140 C. at 0.2 GBD, around 4 minutes.
(71) The resulting cured laminate mat was handleable and could be loaded into a can with a monolith by stuffing and clamshell type methods. The mat was found to not tear when the tensile force exceeded 30 N. This appeared to be because the cured adhesive elongated with the mat.
Examples 5 TO 11
(72) Mats made according to Example 1 were tested according to the Pressure Performance test, yielding the following results:
(73) TABLE-US-00001 Example FGBD (gcm.sup.3) % RGE 2500 cycle holding pressure (KPa) 5 0.4 4 127.8 (Hot/ambient) 6 0.4 8 57.2 (Hot/ambient) 7 0.4 10 37.08 (Hot/ambient) 8 0.4 4 149.85 (Ambient) 9 0.4 6 87.37 (Ambient) 10 0.3 4 67.55 (Ambient) 11 0.3 6 51.16 (Ambient)
(74) The results show excellent holding pressures after 2500 cycles. The graphs shown in
Example 12
(75) 2700 gm.sup.2 moulded mat segments were manufactured by slurrying 6.75 parts by weight alumina fibres with 1 part by weight of a binder composition, the binder comprising 27 w/w % Al sol (AlSol 520 (20 w/w % alumina solids) available from Marybeni) and 73 w/w % latex binder (Dicrylan AC available from Huntsman) in an arcuate mould having an internal radius of 210 mm and a thickness of 20 mm. The solvent was driven off and the mat was cured to give curved mat segments.
(76) The mat segments had a thickness of 26 mm, a freestanding radius of 270 mm and a Pressure Performance of 76.8 kPa.
Example 13
(77) Moulded mat segments were made according to Example 12, but having a reduced quantity of latex in the binder solution.
(78) The mat segments had a thickness of 24 mm, a freestanding radius of 240 mm and a Pressure Performance of 88.6 kPa.
Example 14
(79) Moulded mat segments were made according to Example 12, but having 53 w/w % Al sol in the binder composition.
(80) The mat segments had a thickness of 27 mm, a freestanding radius of 270 mm and a Pressure Performance of 81.6 kPa.
Example 15
(81) Moulded mat segments were made according to Example 14, but having a reduced quantity of latex in the binder solution.
(82) The mat segments had a thickness of 21 mm, a freestanding radius of 220 mm and a Pressure Performance of 94.4 kPa.
Example 16
(83) Moulded mat segments were slurried according to Example 12, but including 80 w/w % alumina fibres and 20 w/w % silica fibres, and moulded in a mould having an internal radius of 152 mm and a thickness of 100 mm.
(84) The mat segments had a thickness of 103 mm, a freestanding radius of 152 mm and a Pressure Performance of 87.4 kPa.
(85) While mats according to the present invention may be used in catalytic convertors and diesel particulate filters as described above, it is understood by persons skilled in the art that such mats may also be used in insulation applications, whether automotive or otherwise, e.g. in furnace insulation.
(86) No doubt many other effective alternatives will occur to the skilled person. It will be understood that the invention is not limited to the described embodiments and encompasses modifications apparent to those skilled in the art lying within the spirit and scope of the invention.