Tire with improved tread
09649883 ยท 2017-05-16
Assignee
- Compagnie Generale Des Etablissements Michelin (Clermont-Ferrand, FR)
- Michelin Recherche Et Technique S.A. (Granges-Paccot, CH)
Inventors
- Olivier Muhlhoff (Clermont-Ferrand, FR)
- Emmanuel IGIER (Clermont-Ferrand, FR)
- Jean-Claude Faure (Clermont-Ferrand, FR)
Cpc classification
B60C11/0058
PERFORMING OPERATIONS; TRANSPORTING
B60C11/0066
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A tire comprising a tread portion designed to be worn off during the life of the tire having a radial thickness T, an outer edge and an inner edge, the axial distance between the outer edge and the inner edge defining the axial width L of the tread, the tread comprising four adjacent portions made of a four rubber compounds, wherein the rubber compounds making up the first and third portions are predominantly filled with carbon black filler, wherein the rubber compounds making up the second and fourth portion are predominantly filled with non carbon black filler, wherein the rubber compounds making up the first and third portions have a value for tan at 0 C., at a stress of 0.7 MPa, that is lower than that of the rubber compounds making up the second and fourth portion, and wherein the axial width of the first portion decreases and the axial width of the second portion increases as a function of the distance from the rolling surface of the tread when unworn.
Claims
1. A tire adapted to be mounted on a mounting rim of a wheel of a vehicle and having a predetermined direction of mounting on the vehicle, wherein the tire comprises a tread having a rolling surface adapted to come into contact with a ground when the tire is rolling on the ground, and a tread portion adapted to be worn off during the life of the tire, this tread portion having a radial thickness T, wherein the tread, when unworn, has an outer edge and an inner edge, the outer edge being situated on that side of the tire which, when the tire is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle, the inner edge being situated on that side of the tire which, when the tire is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle, the axial distance between the outer edge and the inner edge defining the axial width L of the tread, the tread comprising, in any radial section: a first portion made of at least one first rubber compound, wherein the first portion extends from a first axial boundary position (B1) to a second axial boundary position (B2), the axial distance of said first axial boundary position from the inner edge being greater than or equal to 95% of the of the axial width L of the tread, a second portion axially adjacent to the first portion and made of at least one second rubber compound, wherein the second portion extends from a third axial boundary position (B3) to a fourth axial boundary position (B4), a third portion axially adjacent to the second portion and made of at least one third rubber compound, the third portion extending from a fifth axial boundary position (B5) to a sixth axial boundary position (B6), wherein the axial distance between said sixth axial boundary position and the outer edge is greater than or equal to 80% and smaller than or equal to 90% of the axial width L of the tread for DR=0.2.Math.T, where DR is the radial distance from the rolling surface of the unworn tread, and a fourth portion axially adjacent to the third portion and made of at least one fourth rubber compound, the fourth portion extending from a seventh axial boundary position (B7) to an eighth axial boundary position (B8), the axial distance of said eighth axial boundary position from the outer edge being greater than or equal to 95% of the of the axial width L of the tread, wherein said first, second, third and fourth portions each extend over the entire circumference of the tire and each have an intersection with the rolling surface when the tire is new or, at the latest, when the tread wear has reached 10%, wherein said at least one first rubber compound and said at least one third rubber compound contain at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler, and wherein said at least one second rubber compound and said at least one fourth rubber compound contain at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler, wherein said at least one first rubber compound and said at least one third rubber compound have a value for tan at 0 C., at a stress of 0.7 MPa, that is lower than the tan of said at least one second rubber compound and said at least one fourth rubber compound at the same temperature and stress conditions, and wherein at least one of the following conditions (C1) and (C2) is met: (C1) the first portion has, in any radial section, an axial width that decreases as a function of the radial distance DR from the rolling surface of the unworn tread, the second axial boundary position varying as a function of the radial distance DR, such that the axial distance between the second axial boundary position and the outer edge is greater than or equal to 20% and smaller than or equal to 40% of the axial width L of the tread for DR=0.2.Math.T, and greater than or equal to 10% and smaller than or equal to 38% of the axial width L of the tread for DR=0.8.Math.T, provided that the second axial boundary position for DR=0.2.Math.T is axially inside by at least 2% of the axial width L of the tread with respect to the second axial boundary position for DR=0.8.Math.T; (C2) the second portion has, in any radial section, an axial width that increases as a function of the radial distance DR from the rolling surface of the unworn tread, the fourth axial boundary position varying as a function of the radial distance DR, such that the axial distance between the fourth axial boundary position and the outer edge is greater than or equal to 50% and smaller than or equal to 60% of the axial width L of the tread for DR=0.2.Math.T, and greater than or equal to 52% and smaller than or equal to 70% of the axial width L of the tread for DR=0.8.Math.T, provided that the fourth axial boundary position for DR=0.2.Math.T is axially inside by at least 2% of the axial width L of the tread with respect to the fourth axial boundary position for DR=0.8.Math.T, wherein said at least one first rubber compound and said at least one third rubber compound have a value for tan at 10 C., at a stress of 0.7 MPa, that is higher than that of said at least one second rubber compound and said at least one fourth rubber compound.
2. The tire according to claim 1, wherein both conditions (C1) and (C2) are met.
3. The tire according to claim 1, wherein said portions made of said at least one first, second, third and fourth rubber compounds all have an intersection with the rolling surface when the tire is new.
4. The tire according to claim 1, wherein for at least some values of the radial distance DR said second axial boundary position and said third axial boundary position coincide, and/or said fourth axial boundary position and said fifth axial boundary position coincide, and/or said sixth axial boundary position and said seventh axial boundary position coincide.
5. The tire according to claim 1, wherein for at least some values of the radial distance DR said second axial boundary position and said third axial boundary position delimit an incision in the tread, and/or said fourth axial boundary position and said fifth axial boundary position delimit an incision in the tread, and/or said sixth axial boundary position and said seventh axial boundary position delimit an incision in the tread.
6. The tire according to claim 1, wherein said at least one third rubber compound is identical to said at least one first rubber compound and wherein said at least one fourth rubber compound is identical to said at least one second rubber compound.
7. The tire according to claim 1, wherein the difference between the value of tan for said at least one first rubber compound and said at least one second rubber compound is greater than or equal to 0.05, wherein the difference between the value of tan for said at least one second rubber compound and said at least one third rubber compound is greater than or equal to 0.05, and wherein the difference between the value of tan for said at least one third rubber compound and said at least one fourth rubber compound is also greater than or equal to 0.05.
8. The tire according to claim 1, wherein said sixth axial boundary position varies as a function of the radial distance DR from the rolling surface of the unworn tread, such that the axial distance of the sixth axial boundary position from the outer edge is greater or equal to 70% and smaller or equal than 95% of the axial width L of the tread for DR=0.8.Math.T, provided that the difference between (a) the sixth axial boundary position for DR=0.2.Math.T and (b) the sixth axial boundary position for DR=0.8.Math.T, is greater than or equal to 2% of the axial width L of the tread.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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(10) Each of
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DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS
(12) When using the term radial in connection with tires it is appropriate to make a distinction between various different uses that the person skilled in the art makes of this word. Firstly, the expression refers to a radius of the tire. It is in that sense that a point P1 is said to be radially inside a point P2 (or radially on the inside of the point P2) if it is closer to the axis of rotation of the tire than is the point P2. Conversely, a point P3 is said to be radially outside a point P4 (or radially on the outside of the point P4) if it is further from the axis of rotation of the tire than is the point P4. Progress radially inward (or outward) will mean progress toward smaller (or larger) radii. In terms of radial distances, it is this sense of the word that applies also.
(13) By contrast, a thread or a reinforcement is said to be radial when the thread or the reinforcing elements of the reinforcement make an angle greater than or equal to 80 and less than or equal to 90 with the circumferential direction. As used herein, the term thread is to be understood in a very general sense of the word and encompasses threads in the form of monofilaments, multifilaments, a cord, a yarn or an equivalent assembly, irrespective of the material of which the thread is made or of the surface treatment it has undergone to enhance its bonding with the rubber.
(14) Finally, a radial cross section or radial section here means a cross section or a section on a plane which contains the axis of rotation of the tire.
(15) An axial direction is a direction parallel to the axis of rotation of the tire. A point P5 is said to be axially inside a point P6 (or axially on the inside of the point P6) if it is closer to the median plane of the tire than is the point P6. Conversely, a point P7 is said to be axially outside a point P8 (or axially on the outside of the point P8) if it is further from the median plane of the tire than is the point P8. The median plane of the tire is the plane which is perpendicular to the axis of rotation of the tire and which lies equal distances from the annular reinforcing structures of each bead.
(16) Two portions A and B of the tread are said to be axially adjacent if there is at least one axial direction D connecting a point P1 of portion A and a point P2 of portion B so that the segment of direction D connecting points P1 and P2 does not intersect any portion of the tread other than portions A and B. The segment of direction D connecting points P1 and P2 may, however, have an intersection with an incision (groove, sipe, . . . ) separating portions A and B of the tread without this being detrimental to A and B being considered to be axially adjacent. In other words, two axially adjacent portions are positioned axially side by side, either in direct contact or separated by incisions only (but not by other tread portions).
(17) A circumferential direction is a direction perpendicular both to a radius of the tire and to the axial direction. A circumferential section is a section on a plane perpendicular to the axis of rotation of the tire.
(18) As used herein, the term rolling surface means all the points on the tread of a tire that can come into contact with the ground when the tire is rolling in its normal manner.
(19) The expression rubber compound denotes a compound of rubber containing at least one elastomer and at least one filler.
(20) Wear level of a tire tread means the ratio between the radial thickness that the tread has lost due to wear and the radial thickness of the tread portion that the tread is intended to lose before having to be changed or retreaded. In most tires there are wear indicators provided at the bottom of grooves that indicate that the tread has lost all the thickness it is intended to lose before replacement, so that it becomes apparent that the tire has to be changed or retreaded. A wear level of 25% means that the tread has lost a quarter of the rubber composition that can be worn away before changing (or retreading) becomes necessary. The wear level is generally expressed as a percentage; at a given moment not all the zones of the tread necessarily have the same wear level (uneven wear).
(21) The radial thickness T of the tread portion designed to be worn off during the life of the tire is determined as follows. For each axial position, one considers the radial depth PR (in mm) of the deepest incision that is found over the circumference of the tirethe radial thickness T at this axial position (in mm) is defined to be PR-1.6. This is because there are regulations that require a tire to have a minimum incision depth of 1.6 mm. If, for a given axial position, there is no incision over the whole circumference of the tire but there are axial positions on both sides (axially) of the axial position under consideration where incisions are found, then the radial thickness at the axial position under consideration is defined to be the interpolated thickness of the closest axial positions on both sides where there are incisions. If, for a given axial position, there is no incision over the whole circumference of the tire but there are axial positions axially inside the axial position under consideration where incisions are found, then the radial thickness at the axial position under consideration is defined to be identical to thickness of the closest axial positions axially inside it where there are incisions. See also
(22) It will be appreciated that there is a direct link between the wear level and the radial thickness T of the tread portion designed to be worn off during the life of the tire. Locally, a wear level of X % is reached when X % of the thickness T have been worn off.
(23) As used herein, the term trapezium means a quadrilateral having two parallel sides, i.e., as a synonym for the term trapezoid.
(24) To make the description of the variants shown with the figures easier to read, the same references are used to denote elements that have identical structures.
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(28) The way in which the axial edges of a tread are determined is illustrated in
(29) Each layer of reinforcing elements 80 and 90 comprises thread-like reinforcing elements, coated in a matrix formed of rubber compound. The reinforcing elements of each layer are substantially mutually parallel; the reinforcing elements of the two layers cross from one layer to the next at an angle of about 20, as is well known to those skilled in the art for tires known as radial tires.
(30) The tire 10 further comprises a carcass reinforcement 60 which extends from the beads 20 through the sidewalls 30 as far as the crown 25. This carcass reinforcement 60 here comprises thread-like reinforcing elements that are directed substantially radially, that is to say that make an angle greater than or equal to 80 and less than or equal to 90 with the circumferential direction.
(31) The carcass reinforcement 60 comprises a plurality of carcass reinforcing elements; it is anchored in the two beads 20 between the annular reinforcing structures 70.
(32)
(33) The tread comprises a first portion 411 made of a first rubber compound, wherein the first portion extends from a first axial boundary position B1 to a second axial boundary position B2, and a second portion 412 that is axially adjacent to the first portion 411 and made of a second rubber compound. The second portion extends from the second axial boundary position B2 to a third axial boundary position B3 that is close to the inner edge 46. The first axial boundary position B1 and the third axial boundary position B3 vary slightly as a function of the radial distance DR from the rolling surface 47 whereas the second axial boundary position B2 does not vary as a function of the radial distance DR: the axial distance between the second axial boundary position B2 and the outer edge 45 is equal to 40% of the axial width L of the tread for all values of DR between DR=0 and DR=T. The first portion 411 and the second portion 412 both have an intersection with the rolling surface 47 when the tire is new (unworn). The second rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound, and a grip on dry ground that is inferior to the grip on dry ground of the first rubber compound.
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(36) In defining a tire according to the invention, a distinction has been made between that side of the tire which, when the tire is mounted on the vehicle in its predetermined direction of mounting, faces toward the outside of the vehicle (i.e., away from the vehicle), and that side of the tire that faces toward the inside of the vehicle when the tire is mounted on the vehicle in its predetermined direction of mounting. In the previous paragraph, by contrast, the physical effects have been explained with reference to the sides furthest from and closest to the centre of the bend. Of course, these distinctions do not correspond to one another, because reference to the centre of the bend depends on the direction of the bend (whether the vehicle is cornering to the left or to the right) whereas the side facing toward the outside of the vehicle and the side facing in toward the vehicle do not depend on this. This apparent difficulty may be explained using
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(38) The invention provides a way to improve the overall grip performance still further and, more particularly, to improve the compromise between grip on dry ground and grip on wet ground, both when the tire is new (unworn) or almost new and when the tire has undergone significant wear. This objective is achieved by, inter alia, using a tire that has a predetermined direction of mounting, in which a portion of that part of the tread that has previously been reserved for the rubber compounds that have better grip on wet ground is made of a rubber compound that has better grip on dry ground. In other words, a portion of that part of the tread that is situated on that side of the vehicle which faces toward the vehicle when the tire is mounted on the vehicle in the predetermined direction of mounting (that is to say on the inside of the tire; the corresponding sidewall commonly bearing the inscription inside and/or the opposite sidewall commonly bearing the inscription outside) is made of a rubber compound that has better grip on dry ground. The axial extension of this portion changes as a function of the radial distance from the rolling surface of the unworn tread. In addition, as the tire wears, the proportion of the rolling surface where rubber compounds having better grip on dry ground has replaced rubber compounds having better grip on wet ground is decreased.
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(41) Coming back to
(42) The tread comprises a first portion 411 made of a first rubber compound. The first portion 411 extends from a first axial boundary position B1 to a second axial boundary position B2, the axial distance of said first axial boundary position B1 from the inner edge 46 being greater than or equal to 95% of the of the axial width L of the tread.
(43) The tread further comprises a second portion 412 axially adjacent to the first portion 411 and made of a second rubber compound. The second portion 412 extends from a third axial boundary position B3 to a fourth axial boundary position B4. In the embodiment of
(44) The tread further comprises a third portion 413 axially adjacent to the second portion 412 and made of a third rubber compound. The third portion 413 extends from a fifth axial boundary position B5 to a sixth axial boundary position B6. The axial distance between the sixth axial boundary position B6 and the outer edge 45 is equal to 83% of the axial width L of the tread for DR=0.2.Math.T. In the embodiment of
(45) Finally, the tread comprises a fourth portion 414 axially adjacent to the third portion 413 and made of a fourth rubber compound. The fourth portion 414 extends from a seventh axial boundary position B7, which is the embodiment shown in
(46) The first, second, third and fourth portions 411-414 each extend over the entire circumference of the tire and have an intersection with the rolling surface 47 when the tire is new.
(47) Generally speaking, in a tire according to the invention, at least one of the following conditions (C1) and (C2) is met, wherein each condition in fact has four sub-conditions: (1) to (4) and (1) to (4), respectively:
(48) Condition (C1): (1) the first portion has, in any radial section, an axial width that decreases as a function of the radial distance DR from the rolling surface of the unworn tread, (2) the second axial boundary position B2 varies as a function of the radial distance DR [in more mathematical terms, B2=B2(DR)], such that the axial distance between the second axial boundary position B2 and the outer edge 45 is greater than or equal to 20% and smaller than or equal to 40% of the axial width L of the tread for DR=0.2.Math.T (indicated by dashed line Q2), and (3) greater than or equal to 10% and smaller than or equal to 38% of the axial width L of the tread for DR=0.8.Math.T (indicated by dashed line Q8), provided that (4) the second axial boundary position B2 for DR=0.2.Math.T is axially inside by at least 2% of the axial width L of the tread with respect to the second axial boundary position B2 for DR=0.8.Math.T [in more mathematical terms, B2(0.2.Math.T)B2(0.8.Math.T)0.02.Math.L]. Sub-conditions (2) and (3) have been visualised in
(49) Condition (C2): (1) the second portion has, in any radial section, an axial width that increases as a function of the radial distance DR from the rolling surface of the unworn tread, (2) the fourth axial boundary position B4 varying as a function of the radial distance DR [in more mathematical terms, B4=B4(DR)], such that the axial distance between the fourth axial boundary position B4 and the outer edge is greater than or equal to 50% and smaller than or equal to 60% of the axial width L of the tread for DR=0.2.Math.T, and (3) greater than or equal to 52% and smaller than or equal to 70% of the axial width L of the tread for DR=0.8.Math.T, provided that (4) the fourth axial boundary position B4 for DR=0.2.Math.T is axially inside by at least 2% of the axial width L of the tread with respect to the fourth axial boundary position B4 for DR=0.8.Math.T [in more mathematical terms, B4(0.8.Math.T)B4(0.2.Math.T)0.02.Math.L]. Sub-conditions (2) and (3) have been visualised in
(50) Both conditions (C1) and (C2) are satisfied for the tire of
(51) Moreover, the second portion 412 has, in any radial section, an axial width that increases as a function of the radial distance DR from the rolling surface 47 of the unworn tread. The fourth axial boundary position B4 varies as a function of the radial distance DR, such that the axial distance between the fourth axial boundary position B4 and the outer edge 45 is equal to 58% of the axial width L of the tread for DR=0.2.Math.T, and equal to 66% of the axial width L of the tread for DR=0.8.Math.T. Thus the fourth axial boundary position B4 for DR=0.2.Math.T is axially inside by 8% of the axial width L of the tread with respect to the fourth axial boundary position B4 for DR=0.8.Math.T. Thereby, condition (C2) as defined above is also satisfied in this tire.
(52)
(53) TABLE-US-00001 TABLE I DR FIG. 12 FIG. 13 FIG. 14 B2 = B3 0.2 .Math. T 30% 27% 27% 0.8 .Math. T 24% 24% 24% B4 = B5 0.2 .Math. T 58% 59% 59% 0.8 .Math. T 66% 67% 64% B6 = B7 0.2 .Math. T 83% 81% 85% 0.8 .Math. T 78% 74% 91%
(54) The crown of the tire depicted in
(55) The crown of the tire depicted in
(56) When the crown comprises grooves (as most crowns indeed do; the tire of
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(59) When the tread of a tire according to an embodiment of the invention is obtained by extrusion, the boundaries between adjacent portions will, as a rule, be rectilinear in radial section, such as in
(60) In a tire according to embodiments of the invention, the first rubber compound and the third rubber compound are compounds that have good grip on dry ground. They contain at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler. The second rubber compound and the fourth rubber compound are compounds that have good grip on wet ground. They contain at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler.
(61) Moreover, the first rubber compound and the third rubber compound have a value for tan at 0 C., at a stress of 0.7 MPa, that is lower than that of the second rubber compound and the fourth rubber compound at the same temperature and stress conditions.
(62) Table II gives, by way of example, compositions of rubber compounds that can be used in tires according to the invention. The composition is given in pce (percent elastomer) that is to say in parts by weight for 100 parts by weight of elastomer.
(63) TABLE-US-00002 TABLE II Compound with better Compound with better grip on dry ground grip on wet ground SBR Elastomer [1] 100 100 N 234 [2] 100 Silica 100 TESPT coupling agent 8.0 (Degussa Si 69) Plasticizer [3] 50 50 Anti-ozone wax C32 ST 1.5 1.5 Antioxidant (6PPD) [4] 2.0 2.0 Diphenylguanidine 1.7 (DPG) ZnO 1.8 1.8 Stearic acid 2.0 2.0 Sulphur 1.3 1.3 Accelerator (CBS) 1.95 1.95 Notes for Table II: [1] SSBR with 40% styrene, 48% 1-4 trans polybutadiene groups [2] Carbon black series 230 (ASTM) [3] TDAE (treated distillate aromatic extract) oil [4] N-(1,3-dimethylbutyl)-N-phenyl-p-phenylenediamine
(64) The rubber compounds are preferably based on at least one diene elastomer, one reinforcing filler and a crosslinking system.
(65) What is meant by a diene elastomer (or interchangeably rubber) is, in the known way, an elastomer derived at least in part from (i.e. a homopolymer or a copolymer of) diene monomers, that is to say monomers bearing two carbon-carbon double bonds, conjugated or otherwise. The diene elastomer used is preferably chosen from the group consisting of polybutadienes (BR), natural rubber (NR), synthetic polyisoprenes (IR), styrene butadiene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR), butadiene-styrene-isoprene copolymers (SBIR) and blends of these elastomers.
(66) One preferred embodiment is to use as the diene elastomer an isoprene elastomer, that is to say a homopolymer or copolymer of isoprene, or in other words, a diene elastomer chosen from the group consisting of natural rubber (NR), synthetic polyisoprenes (IR), the various copolymers of isoprene and blends of these elastomers.
(67) The isoprene elastomer is preferably natural rubber or a synthetic polyisoprene of the cis-1,4 type. Of these synthetic polyisoprenes, use is preferably made of polyisoprenes that have a cis-1,4 bond content (mol %) in excess of 90%, or more preferably still, in excess of 98%. According to other preferred embodiments, the diene elastomer may consist, in full or in part, of another diene elastomer such as, for example, an SBR (E-SBR or S-SBR) elastomer used in combination or otherwise with another elastomer for example of the BR type.
(68) The rubber composition may also contain all or some of the additives conventionally employed in the rubber matrices used for the manufacture of tires, such as, for example, reinforcing fillers such as carbon black or inorganic fillers such silica, coupling agents for inorganic fillers, anti-aging agents, antioxidants, plasticizers or extender oils, whether the latter are of aromatic or non-aromatic nature (notably oils that are only very slightly aromatic or non-aromatic, for example of the naphthene or paraffin type, with a high or preferably low viscosity, MES or TDAE oils, plasticizing resins with a high T.sub.g in excess of 30 C.), agents that improve the processability of the compositions in the green state, tackifying resins, a crosslinking system based either on sulphur or sulphur donors and/or peroxides, accelerators, vulcanization activators or retarders, anti-reversion agents, methylene acceptors and donors such as, for example, HMT (hexamethylenetetramine) or H3M (hexamethoxymethylmelamine), reinforcing resins (such as resorcinol or bismaleimide), known adhesion promoting systems of the metal salt type, for example, notably cobalt or nickel salts.
(69) The compositions are desirably manufactured in appropriate mills, e.g., using two successive phases of preparation well known to those skilled in the art, namely a first phase of thermomechanical work or kneading (the so-called non-productive phase) at high temperature, up to a maximum temperature of between 110 C. and 190 C., preferably between 130 C. and 180 C., followed by a second phase of mechanical work (the so-called productive phase) down to a lower temperature, typically of less than 110 C., during which finishing stage the crosslinking system is incorporated.
(70) By way of example, the non-productive phase is conducted in a single thermomechanical step lasting a few minutes (for example between 2 and 10 min) during which all the required basic ingredients and other additives, apart from the crosslinking or vulcanizing system, are introduced into an appropriate mixer such as a conventional internal mixer. Once the mixture thus obtained has cooled, the vulcanizing system is then incorporated with it in an external mixer such as an open mill kept at a low temperature (for example between 30 C. and 100 C.). This is then blended (productive phase) for a few minutes (for example for between 5 and 15 min).
(71) Vulcanizing (or curing) may be performed in the known way at a temperature generally between 130 C. and 200 C., preferably under pressure, for a sufficient length of time which may vary, for example, between 5 and 90 min depending in particular on the curing temperature, on the vulcanizing system adopted and on the vulcanization dynamics of the composition considered.
(72) Table III gives the properties of the rubber compounds the composition of which is given in Table I
(73) TABLE-US-00003 TABLE III Compound Compound with better with better grip on dry ground grip on wet ground tan at 0 C., at 0.7 MPa 0.76 0.88 tan at 10 C., at 0.7 MPa 0.69 0.58
(74) These properties are measured with a viscoanalyser (Metravib VA4000), in accordance with standard ASTM D 5992-96. The response of a test specimen of vulcanized composition (a cylindrical test specimen 4 mm thick and 400 mm.sup.2 in section) subjected to simple alternating sinusoidal shear stresses at a frequency of 10 Hz, during a temperature sweep between 0 and 100 C., under a fixed stress of 0.7 MPa, is recorded, particularly the value of tan observed at 0 C. and the values of tan observed at 10 C.
(75) It will be recalled that, as is well known to those skilled in the art, the value of tan at 0 C. is representative of the potential to grip on wet ground: the higher tan at 0 C., the better the grip. The values of tan at temperatures higher than 10 C. are representative of the hysteresis of the material and of the potential to grip on dry ground.
(76) To return to the compounds the composition of which is given in Table II, it may be seen that the second composition has a value of tan at 0 C. (imposed stress 0.7 MPa) that is higher by comparison with the first composition, indicating that its grip on wet ground will be superior; and has a value of tan at 10 C. that is lower by comparison with the first composition, indicating that the grip on dry ground would be inferior.
(77) Tests were carried out using a Porsche 997 fitted with Pilot Super Sport tires, size 245/35 R20 (on the front) and 295/30 R20 (on the rear). A tire according to the invention and equipped with a tread as depicted in