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DISCHARGE CONTAINER

20170129690 ยท 2017-05-11

    Inventors

    Cpc classification

    International classification

    Abstract

    Provided is a multilayer-structured discharge container having a simple structure, capable of facilitating the loading of a substance to be contained and a pressurizing agent, and capable of facilitating the ejection of the pressurizing agent after use. A discharge container in which a valve mechanism is provided with a stem having two independent in-stem paths, one in-stem path communicates with an in-holder discharge path, the other in-stem path communicates with an in-holder gas path, a contained substance is discharged by closing the other in-stem path, and the pressurizing agent is ejected by opening the other in-stem path. The discharge container is capable of causing a pressurization chamber and the atmosphere to communicate by removing a push-button from a valve assembly and pressing down a stem of a valve mechanism (switching operation).

    Claims

    1. A discharge container comprising an outer container, an inner container accommodated in the outer container, and a valve assembly fixed by engaging with the outer periphery of the outer container, closing the outer container and the inner container, wherein a content is accommodated in an accommodating chamber between the outer container and the inner container, and a pressurizing agent is filled in a pressurizing chamber in the inner container, wherein the valve assembly is provided with a valve mechanism communicating/shutting off a discharge passage of the content which communicates the accommodating chamber and atmospheric air, a valve holder which accommodates the valve mechanism, and a cap which fixes the valve holder to the outer container so as to cover the valve holder and the outer container, wherein the valve holder has a housing to accommodate the valve mechanism and an annular flange arranged above the outer container, wherein the accommodating chamber and atmospheric air are communicated through the housing and the annular flange, and wherein it is possible to make the pressurizing chamber and atmospheric air communicated by applying a switching operation to the valve assembly.

    2. (canceled)

    3. A discharge container according to claim 1, wherein it is possible to make the pressurizing chamber and atmospheric air communicated through the valve mechanism by applying the switching operation to the valve assembly.

    4. A discharge container according to claim 1, wherein the valve mechanism is provided with a stem having two independent intra-stem passages, wherein the valve holder has an intra-holder discharge passage which communicates the accommodating chamber and atmospheric air, and an intra-holder gas passage which communicates the pressurizing chamber and atmospheric air, wherein the one intra-stem passage communicates with the intra-holder discharge passage, the other intra-stem passage communicates with the intra-holder gas passage and closes the other intra-stem passage to discharge the content, the other intra-stem passage is closed to discharge the content, and wherein the switching operation is the operation to make the other intra-stem passage open and to make the valve mechanism open.

    5. A discharge container according to claim 4, wherein a push button is attached to the stem detachably, the push button having a stem engaging portion to engage with the stem, a discharge hole to discharge the content, and an intra-button passage to connect the stem engaging portion and the discharge hole, wherein the stem engaging portion communicates the one intra-stem passage with the discharge hole, and shuts off the other intra-stem passage from atmospheric air, and wherein the switching operation is the operation to detach the push button and to open the valve mechanism.

    6. A discharge container according to claim 1, wherein the cap is made so as to be movable vertically to the outer container, an inner seal material being provided between the valve holder and the inner container, an outer seal material of circular cross section being provided between the outer cylindrical surface of the outer container and the inner cylindrical surface of the inner container, the cap being fixed to the fixed position of the outer container, a seal structure being made to be formed by the outer seal material and the inner seal material respectively to discharge the content, and wherein the switching operation includes to release the seal structure of the inner seal material, while the cap is moved to the temporary position upper than the fixed position to make the seal structure of the outer seal material maintained.

    7. A discharge container according to claim 6, wherein the valve holder and the cap are connected integrally.

    8. A discharge container according to claim 6, wherein when the cap is moved to the temporary position and the seal structure of the inner seal material is released, the pressurizing chamber and the discharge passage of the content are communicated, and wherein the switching operation is the operation to move the cap to the temporary position and to release the valve mechanism.

    9. A discharge container according to claim 6, wherein the inner seal material is compressed vertically.

    10. A discharge container according to any of claim 6, wherein the inner seal material is compressed horizontally.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0097] FIG. 1 A cross-sectional view showing the first embodiment of the discharge container of the present invention;

    [0098] FIG. 2A-2D is respectively a cross-sectional view of the valve assembly of the discharge container of FIG. 1, a cross-sectional view of the valve holder, a cross-sectional view of the cap, and a cross-sectional view of the push button;

    [0099] FIG. 3A is a partial cross-sectional view showing the use state of the discharge container of FIG. 1, FIG. 3B is a partial cross-sectional view showing the discarded state of the discharge container of FIG. 1;

    [0100] FIG. 4 A cross-sectional view showing the second embodiment of the discharge container of the present invention;

    [0101] FIG. 5A-5H are side cross-sectional views showing the manufacturing method of the discharge container of FIG. 4;

    [0102] FIG. 6 A plane-sectional view of the guide member;

    [0103] FIG. 7A-7F are side cross-sectional views showing further another embodiment of the manufacturing method of the discharge container of FIG. 4;

    [0104] FIG. 8A is a cross-sectional view showing the third embodiment of the discharge container of the present invention, FIG. 8B is another embodiment of the guide member usable therein;

    [0105] FIG. 9A-9C are cross-sectional views showing further another embodiment of the manufacturing method of the discharge container of FIG. 8A;

    [0106] FIG. 10 A cross-sectional view showing the fourth embodiment of the discharge container of the present invention;

    [0107] FIG. 11 A cross-sectional view showing the fifth embodiment of the discharge container of the present invention;

    [0108] FIG. 12A-12E is respectively a cross-sectional view of the valve assembly of the discharge container of FIG. 11, a cross-sectional view of the valve holder, a plain view of the valve holder, a cross-sectional view of the valve cover, and a cross-sectional view of the cap;

    [0109] FIG. 13A, 13B is respectively a cross-sectional view of the push button and the protection cap of FIG. 11;

    [0110] FIG. 14A, 14B is respectively a cross-sectional view of the use state and the discarded state of the discharge container of FIG. 11;

    [0111] FIG. 15A, 15B are cross-sectional views showing the use state and the discarded state of the sixth embodiment the discharge container of the present invention;

    [0112] FIG. 16A, 16B are cross-sectional views showing the use state and the discarded state of the seventh embodiment the discharge container of the present invention;

    [0113] FIG. 17 A cross-sectional view showing the eighth embodiment of the discharge container of the present invention;

    [0114] FIG. 18A, 18B is respectively a cross-sectional view showing the pressure adjustment mechanism, the operating state of the discharge container of FIG. 17;

    [0115] FIG. 19A, 19B are outline drawings showing the assembling process of the discharge container of FIG. 17;

    [0116] FIG. 20A is an outline drawing showing the use state of the discharge container of FIG. 17, FIG. 20B is an outline drawing showing the exhaust mechanism of the pressuring agent thereof;

    [0117] FIG. 21 A cross-sectional view showing the ninth embodiment of the discharge container of the present invention;

    [0118] FIG. 22A-22C is respectively a cross-sectional view of the valve assembly, a cross-sectional view of the valve holder, and a cross-sectional view of the push button of the discharge container of FIG. 21;

    [0119] FIG. 23 A cross-sectional view of the discarded state of the discharge container of FIG. 21;

    [0120] FIG. 24 A cross-sectional view showing the tenth embodiment of the discharge container of the present invention;

    [0121] FIG. 25A-25C is respectively a cross-sectional view of the valve assembly, a cross-sectional view of the valve cover, and a cross-sectional view of the cap of the discharge container of FIG. 24;

    [0122] FIG. 26A is a side cross-sectional view showing the outline of pressurizing agent filling process of the discharge container of FIG. 24, FIG. 26B is a side cross-sectional view showing the outline of pressurizing agent filling process using the pressurizing agent filling machine of another aspect.

    [0123] FIG. 27A is a cross-sectional view showing the eleventh embodiment of the discharge container of the present invention, FIG. 27B is an enlarged partial side view showing a part of the outer container;

    [0124] FIG. 28 A side cross-sectional view showing the valve assembly of the discharge container of FIG. 27A;

    [0125] FIG. 29A is a side view showing the use state of the discharge container of FIG. 27A, FIG. 29B is a side cross-sectional view showing the outline of the pressurizing agent filling process of the discharge container of FIG. 27A;

    [0126] FIG. 30 A cross-sectional view showing the twelfth embodiment of the discharge container of the present invention;

    [0127] FIG. 31A-31D are side cross-sectional views showing the manufacturing method of the discharge container of FIG. 30;

    [0128] FIG. 32 A cross-sectional view showing the thirteenth embodiment of the discharge container of the present invention;

    [0129] FIG. 33 A side cross-sectional view showing the valve assembly of the discharge container of FIG. 32;

    [0130] FIG. 34A, 34B is respectively a cross-sectional view showing the state prior to operation and the operating state of the pressure adjustment mechanism of the discharge container of FIG. 32;

    [0131] FIG. 35A, 35B are outline drawings of the assembling process of the discharge container of FIG. 32;

    [0132] FIG. 36A, 36B are outline drawings of the use state of the discharge container of FIG. 32;

    [0133] FIG. 37A is an outline drawing showing the exhaust mechanism of the pressurizing agent of the discharge container of FIG. 32, FIG. 37B is an outline drawing showing the exhaust mechanism of the pressurizing agent of the fourteenth embodiment of the discharge container of the present invention, FIG. 37C is a cross-sectional view showing the refill product of the discharge container of FIG. 32;

    [0134] FIG. 38 A cross-sectional view showing the fifteenth embodiment of the discharge container of the present invention;

    [0135] FIG. 39A, 39B are outline drawings of the assembling process of the discharge container of FIG. 38;

    [0136] FIG. 40 A cross-sectional view showing the sixteenth embodiment of the discharge container of the present invention;

    [0137] FIG. 41A-41D is respectively a cross-sectional view of the valve assembly, a cross-sectional view of the valve holder, a cross-sectional view of the moving valve, and the elastic valve of the multilayered discharge container of FIG. 40;

    [0138] FIG. 42A, 42B is respectively an outline drawing showing the concentrate passage and the gas passage of FIG. 40;

    [0139] FIG. 43A, 43B is respectively an outline drawing showing the filling process of the discharge container of FIG. 40;

    [0140] FIG. 44A, 44B is respectively an outline drawing showing the use state and the discarded state of the discharge container of FIG. 40.

    MODE FOR CARRYING OUT THE INVENTION

    [0141] The discharge container 10 of FIG. 1 is the first embodiment of the present invention, in which a valve mechanism is provided with a stem having two independent intra-stem passages, where one intra-stem passage is communicated with an intra-holder discharge passage, the other intra-stem passage is communicated with an intra-holder gas passage, closing the other intra-stem passage to discharge a content, opening the other intra-stem passage to exhaust a pressuring agent.

    [0142] In detail, the discharge container 10 of FIG. 1 comprises an outer container 11 made of synthetic resin, an inner container 12 made of synthetic resin accommodated inside thereof, and a valve assembly 13 closing the outer container 11 and the inner container 12, and is engagingly fixed to the outer periphery of the outer container, a content C is filled in an accommodating chamber S1 between the outer container 11 and the inner container 12, a pressurizing agent P is filled in a pressuring chamber S2 inside the inner container. This discharge container 10 is used by attaching a push button 14 to the valve assembly 13.

    [0143] In this discharge container 10, the pressurizing chamber S2 and atmospheric air can be communicated by detaching the push button 14 from the valve assembly 13, and pushing down a stem 21 of a valve mechanism 16 (refer to FIG. 3B).

    [0144] The outer container 11 is a pressure resistant container being transparent or translucent, inside of which is visible. In detail, it is a bottomed cylindrical pressure resistant container provided with a cylindrical body portion, a taper like shoulder portion, and a cylindrical neck portion. In the outer periphery of the neck portion, a screw 11a is formed. Below the screw 11a, a cylindrical outer seal holding portion 11b consisting of an outer cylindrical portion 11b1 and an annular protrusion 11b2 of the lower end thereof are formed. In this cylindrical outer seal holding portion 11b, an annular outer seal material A1 whose cross section is circular is held. The outer cylindrical portion 11b1 is a portion to compress the outer seal material A1 horizontally, the annular protrusion 11b2 is a portion to prevent the outer seal material A1 from dropping out from the outer cylindrical portion 11b1. Further, below the outer cylindrical portion 11b, an annular protrusion 11c is formed, which is for such as holding the outer container 11 when assembling the discharge container 10, and for hanging the outer container 11 when filling. The outer periphery shape of the annular protrusion 11c may be not only circular but also be shaped as being provided with a plane partially, for the prevention of the rotation of the discharge container 10, and further may be made to be rectangular.

    [0145] The inner container 12 has substantially an identical shape with the inner surface of the outer container 11, and is a flexible bottomed cylindrical container provided with a cylindrical body portion, a taper like shoulder portion and a cylindrical neck portion (refer to FIG. 5A). The inner surface of neck portion of the inner container 12 is shaped to be an inner cylinder portion 12a compressing an inner seal A2 horizontally. The portion upper than the neck portion of this inner container 12 does not deform, the portion lower than the body portion has flexibility and deforms. The shoulder portion is composed so that the flexibility gradually becomes higher toward the body portion from the neck portion. In this embodiment, it gradually becomes thin toward the lower portion from the upper portion of the shoulder portion. The inner container 12 is transparent or translucent, of which the inside is made to be visible. In the upper end of the inner container 12, a flange portion 12b protruding outward is formed. The flange portion 12b is arranged in the upper end of the outer container 11. In the inner container 12, a plurality of longitudinal passage grooves 12c extending vertically, formed continuously in the upper outer surface of the shoulder portion is arranged annularly at an equal interval through the outer surface of the neck portion from the lower surface of the flange portion 12b.

    [0146] In this embodiment, four longitudinal passage grooves 12c are provided. However, the number thereof is not particularly limited. Two to eight is preferable. Moreover, the longitudinal passage groove 12c may be sufficient as long as it is provided at least from the upper end of the inner container 12 to the non-deformable lower end of the neck portion. The longitudinal passage groove of the shoulder portion can be properly selected according to the flexibility (thickness) of the shoulder portion. This longitudinal passage groove 12c serves as a discharge passage of the content filled in the accommodating chamber S1 between the outer container 11 and the inner container 12. In addition, the longitudinal passage groove may be made to be provided in the upper surface of the neck portion, the inner surface of the neck portion and the shoulder portion of the outer container 11. Further, it may be made to be provided both in the inner surface of the outer container 11 and the outer surface of the inner container 12.

    [0147] Such outer container 11 and inner container 12 are made so that an outer preform for the outer container in which the screw 11a is formed in the neck portion, and an inner preform for the inner container in which the flange portion 12b and the longitudinal passage groove 12c are formed in the neck portion are molded individually by injection molding etc. that the inner preform for the inner container is inserted into the outer preform for the outer container to prepare a two-layer preform. Then this two-layer preform is molded simultaneously into a portion lower than the shoulder portion of the outer container 11 and the inner container 12 by biaxial stretch blow molding etc. Thereby, the outer shape of the inner container 12 becomes a shape to be contactable with the inner surface of the outer container 11, in other words, a substantially identical shape with the inner surface of the outer container 11.

    [0148] As the outer container 11, it is preferable to use thermoplastic synthetic resin such as polyethylene terephthalate, nylon. And, as the inner container 12, it is preferable to use thermoplastic synthetic resin such as polyethylene terephthalate, polyethylene, polypropylene. In addition, synthetic resin of the same quality of material may be used for the outer container 11 and the inner container 12, and synthetic resin of the different quality of material may be used for those. In this case, as the inner container 12, rubber or synthetic resin having elasticity may be used.

    [0149] In addition, if the accommodating chamber S1 and the valve assembly 13 are communicated by a longitudinal passage formed between the outer container 11 and the inner container 12, the outer shape of the inner container 12 may be made to be a different shape to the inner surface of the outer container 11.

    [0150] The valve assembly 13 is, as shown in FIG. 2A, provided with a valve mechanism 16 which lets through two fluids independently and shuts off/communicates those simultaneously, a valve holder 17 which closes the outer container 11 and the inner container 12, and a cap 18 which fixes the valve mechanism 16 to the inside of the valve holder, and fixes the valve holder 17 to the outer container 11.

    [0151] The valve mechanism 16 comprises a stem 21 in which two independent first intra-stem passage 21a and second intra-stem passage 21b, and a first stem hole 21a1 and a second stem hole 21b1 respectively communicated with those passages are formed, an annular first stem rubber 22a closing the first stem hole 21a1, an annular second stem rubber 22b closing the second stem hole 21b1, an elastic body 23 energizing the stem 21 upward always, and a cylindrical support member 24 provided between the first stem rubber 22a and the second stem rubber 22b supporting those.

    [0152] The stem 21 is that in which an inner cylindrical portion 25a and an outer cylindrical portion 25b whose lower end are closed are coaxially superimposed, the inner cylindrical portion 25a protrudes upper and also lower than the outer cylindrical portion 25b. And, an annular space between the inner cylindrical portion 25a and the outer cylindrical portion 25b composes the first intra-stem passage 21a, a columnar space in the inner cylindrical portion 25a coaxial with the first intra-stem passage 21a composes the second intra-stem passage 21b. The first stem hole 21a1 is a hole formed by penetrating the outer cylindrical portion 25a radially so as to communicate with the lower portion of the first intra-stem passage 21a. The second stem hole 21b is formed by penetrating the inner cylindrical portion 25a radially so as to communicate with the lower portion of the second intra-stem passage 21b in the lower portion than the first intra-stem hole 21a (in the inner cylindrical portion 25a protruding lower than the outer cylindrical portion 25b). Each outer end of the first stem rubber 22a and the second stem rubber 22b is supported to the inside of the valve holder 17 by a support member 24, the inner end plugs the first stem hole 21a1 and the second stem hole 21b1. And, the downward movement of the stem 21 makes the first stem hole 21a and the second stem hole 21b released from the inner ends of the first stem rubber 22a and the second stem rubber 22b.

    [0153] In the support member 24, a slit 24a communicating the inside and the outside thereof is provided.

    [0154] The valve holder 17 is, as shown in FIG. 2B, is that in which an intra-holder discharge passage R1 communicating the accommodating chamber S1 with atmospheric air and an intra-holder gas passage R2 communicating the pressurizing chamber S2 with atmospheric air are independently provided. In detail, it has a cylindrical housing 26, an annular flange 27 extending outward from the central side of the housing 26, and a cylindrical plug portion 28 provided coaxially outward to the housing 26 in the lower surface thereof.

    [0155] The housing 26 has a first communicating hole 26a communicating the inside and the outside of the housing in the side surface, and has a second communicating hole 26b communicating the inside and the outside of the housing in the lower end. Moreover, in the upper end of the housing 26, a first rubber support portion 26c supporting the first stem rubber 22a of the valve mechanism 16 is formed, and a second stem rubber support portion 26d supporting the second stem rubber 22b of the valve mechanism 16 is formed between the first communicating hole 26a and the second communicating hole 26b, being the inner side surface.

    [0156] Further, the upper periphery of the first communicating hole 26a of the housing 26 is expanded in diameter through a step portion 26e. And, in the bottom portion of the housing 26, a plurality of leaf springs 26f is provided so as to protrude upward. This leaf spring 26f composes an elastic body 23 of the valve mechanism 16 (refer to FIG. 2A). In this embodiment, four leaf springs are annularly arranged at an equal interval. A nonmetal valve assembly can be composed by molding the elastic body 23 integrally with the housing 26.

    [0157] However, an independent spring may be arranged between the bottom portion of the housing 26 and the stem 21 of the valve mechanism 16. And, in the center of the bottom portion of the housing 26, a cylindrical portion 26g protruding downward, communicating with the second communicating hole 26b is formed. The inside of the housing 26 is divided into two spaces by the second stem rubber 22b of the valve mechanism 16. Stated differently, the inside of the housing 26 is divided into an upper space (a part of the intra-holder passage) between the first stem rubber 22a and the second stem rubber 22b, and a lower space (a part of the intra-holder gas passage) lower than the second stem rubber 22b (refer to FIG. 2A).

    [0158] The annular flange 27 protrudes outward from the housing 26 between the first communicating hole 26a and the second communicating hole 26b. In the upper surface of the annular flange 27, a plurality of lateral passage grooves 27a is radially provided at an equal interval. This lateral passage groove 27a is made to be the same number as the longitudinal passage groove 12c of the inner container 12, and is provided so that the arrangement thereof is superimposed with the longitudinal passage groove 12c in a planar view.

    [0159] The plug portion 28 is a cylindrical portion inserted along the inner surface of the neck portion of the inner container 12. In the lower side surface thereof, an annular inner seal holding portion 28a to hold the inner seal material A2 is formed. The bottom 28a1 of this inner seal material 28a compresses the inner seal material A2 horizontally.

    [0160] Since the valve holder 17 is composed as described above, the intra-holder discharge passage is communicated with the housing 26 through the annular flange 27. In other words, it is communicated with the housing 26 so as to circumvent the annular flange 27 passing through inside the housing 26. Further in detail, it is composed of the upper space inside the housing 26, the first communicating hole 26a, and the lateral passage groove 27a of the annular flange 27. Meanwhile, the intra-holder gas passage is composed of the lower space inside the housing 26 and the second communicating hole 26b of the housing 26.

    [0161] The cap 18 has, as shown in FIG. 2C, a circular plate like cover portion 31 closing the opening of the housing 26 of the valve holder 17, an upper cylindrical portion 32 arranged in the outer periphery of the housing 26 extending downward from the edge portion thereof, an annular ring portion 33 extending outward radially from the lower end thereof, and a lower cylindrical portion 34 extending downward from the outer end thereof.

    [0162] The cover 31 is that which prevents the first stem rubber 22a from jumping upward. In the center of the cover 31, a center hole 31a which lets through the stem 21 is formed.

    [0163] The upper cylindrical portion 32 is a portion which holds the housing 26 of the valve holder 17, and forms a discharge passage of the content across the housing 26. In the inner surface of the upper cylindrical portion 32, an engaging protrusion 32a engaging with the step portion 26e of the housing 26 is formed. By tucking the valve holder 17 between the cover 31 and the engaging protrusion 32a, the valve mechanism 16 is fixed to the valve holder 17 (housing 26) and holds the valve holder 17 (refer to FIG. 2A). In other words, the cap 18 and the valve holder 17 can be integrated. In addition, the lower inner surface (the inner surface lower than the engaging protrusion 32a) of the cylindrical portion 32 forms an annular gap G1 across the outer periphery of the housing 26 (refer to FIG. 2A). This gap G1 is communicated with the first communicating hole 26a of the housing 26, composing a discharge passage of the content.

    [0164] The ring 33 is a portion to cover the upper surface of the annular flange 27 of the valve holder 17 so as to prevent the valve holder 17 from dropping off from the outer container 11. In addition, since in the annular flange 27, the lateral passage groove 27a is formed, a plurality of passages extending radially is formed between the ring 33 and the annular flange 27. This passage composes a discharge pass (intra-holder discharge passage) of the content, and is communicated with the gap G1.

    [0165] The lower cylindrical portion 34 is a portion which is connected to the outer container 11, and composes a discharge passage of the content across the valve holder 17. The upper inner surface of the lower cylindrical portion 34 is designed so that the gap G2 is secured across the outer end of the annular flange 27 of the valve holder 17 (refer to FIG. 2A). In the middle inner surface of the lower cylindrical portion 34, a screw 34a engaging with the screw 11a of the outer container 11 is formed.

    [0166] And, in a position of the outer seal holding portion 11b of the outer container 11, being the lower inner surface of the lower cylindrical portion 34 beneath the screw 34a, an inner cylindrical portion 34b somewhat expanded in diameter than the annular step portion 11b2 is formed. This annular cylindrical portion 34b is a portion compressing the outer seal material A1 radially across the outer cylindrical portion 11b1 of the outer container 11 (refer to FIG. 1).

    [0167] The push button 14 is, as shown in FIG. 2D, provided with a cylindrical stem engaging portion 14a formed in the lower surface, a discharge hole 14b provided in the front surface, and an intra-button passage 14c which communicates the stem engaging portion 14a and the discharge hole 14b.

    [0168] The stem engaging portion 14a consists of a diameter-expanded hole 36 into which the outer cylindrical portion 25b of the stem 21 is inserted, and a diameter-reduced hole 37 into which the inner cylindrical portion 25a of the stem 21 is inserted, being provided in the upper portion thereof. The intra-button passage 14c is communicated with the upper portion of the diameter-expanded hole 36. And, the upper end of the diameter-reduced hole 37 is closed. The height of the diameter-reduced hole 37 is made to be smaller than the protruding amount in regard to the outer cylindrical portion 25b of the inner cylindrical portion 25a (refer to FIG. 1). Hence, when the stem 21 is inserted into the stem engaging portion 14a, the upper portion of the inner cylindrical portion 25a is arranged inside the diameter-reduced hole 37, the lower portion of the inner cylindrical portion 25a and the upper portion of the outer cylindrical portion 25b are arranged inside the diameter-expanded portion 36. Therefore, the upper end of the inner cylindrical portion 25a is closed by the upper end of the diameter-reduced portion 37, and the upper portion of the outer cylindrical portion 25b is communicated with the intra-button passage 14c, a space G3 surrounded by the diameter-expanded portion 36 and the inner cylindrical portion 25a is formed (refer to FIG. 1).

    [0169] Next, the discharge passage of the content connecting the accommodating chamber S1 and atmospheric air excepting the push button 14, and the gas passage (gas filling passage and gas exhaust passage) connecting the pressurizing chamber S2 and atmospheric air are described referring to FIG. 3. The accommodating chamber S1 is, as shown in FIG. 3A, communicated with atmospheric air through the longitudinal passage groove 12c, the gap G2 between the lower cylindrical portion 34 and the valve holder 17, the intra-holder passage (the lateral passage groove 27a between the ring portion 33 of the cap 18 and the annular flange portion 27 of the valve holder 17, the gap G1 between the lower inner surface of the upper cylindrical portion 32 of the cap 18 and the outer periphery surface of the housing 26 of the valve holder 17, and the first communicating hole 26a of the housing 26, and the upper space of the housing 26) and the first intra-stem passage 21a of the stem 21 of the valve mechanism 16. Meanwhile, the pressurizing chamber S2 is, as shown in FIG. 3B, communicated with atmospheric air through the intra-holder gas passage (the second communicating hole 26b of the housing 26 and the lower space inside the housing 26) and the second intra-stem passage 21b of the stem 21 of the valve mechanism 16.

    [0170] Next, the seal structure of the discharge container 10 is described referring to FIG. 1. In this discharge container 10, the outer seal material A1 is provided between the outer container 11 and the valve assembly 13, the inner seal material A2 is provided between the inner container 12 and the valve assembly 13. In detail, the outer seal material A1 is compressed horizontally and held between the outer cylindrical portion 11b1 of the outer container 11 and the inner cylindrical portion 34b of the cap 18 of the valve assembly 13. And, the inner seal material A2 is compressed horizontally between the inner cylindrical portion 12a of the inner container 12 and the bottom 33a1 of the inner seal holding portion 33a of the plug portion 33 of the valve assembly 13. Stated differently, since the outer seal material A1 and the inner seal material A2 are compressed in a perpendicular direction to the axis of the outer container 11 and the inner container 12, the seal is formed regardless of the degree of fitting of the cap 18 to the outer container 11. Hence, even if the engaging of the cap 18 with the outer container 11 becomes loose due to an external force etc., the seal is never released, making the risk of spouting the content and the pressurizing agent little. In addition, as the outer seal material A1 and the inner seal material A2, it is preferable to use a ring like gasket (O ring). The first aspect of the present invention is not limited to this seal structure. For example, as the discharge container 10a of FIG. 4, an annular plate seal material A3 may be provided between the flange portion 12b of the inner container 12 and the annular flange 27 of the valve holder 17. Or the inner seal material A2 may be replaced with the plate seal material A3. And so forth, as long as the pressurizing chamber S2 can be sealed, it is not limited to the seal structure of the inner seal material A2. Moreover, the outer seal material 17 is also provided beneath the screw 11a, but it may be provided above the screw 11a. And so forth, as long as the gap between the outer container 11 and the cap 18 can be sealed, the seal structure of the outer seal material A1 is not limited. However, the seal structure of the discharge container 10 can reduce costs and is easy to assemble.

    [0171] Next, the use method of the discharge container 10 is described. As the use method, by pushing down the push button 14, the content C can be discharged from the discharge hole 14b of the push button 14 (refer to FIG. 3A). In detail, by pushing down the stem 21 through the push button 14, the first stem hole 21a and the second stem hole 21b of the stem 21 are opened, the discharge passage of the content opens. However, since the closing portion (upper end of a diameter-reduced portion 37) of the push button 14 blocks the upper end opening of the second intra-stem passage 21b of the stem 21, only the passage of the content C of the valve assembly 13 is opened. In other words, the pressurizing agent P inside the inner container 12 (pressurizing chamber S2) presses the inner container 12 so as to expand, the accommodating chamber S1 is contracted, the content C is discharged from the discharge hole 14b from the accommodating chamber S1 through the discharge passage of the content. After discharging whole amount of the content C, the push button 14 is detached, the stem 21 is pushed down (refer to FIG. 3b). Thereby, the gas discharge passage is opened and the pressurizing agent P is exhausted from the pressurizing chamber S2. This discharge container 10 may be discarded in this state. However, by detaching the cap 18 from the outer container 11, each can be discarded separately.

    [0172] Next, the manufacturing method of the discharge product using the discharge container 10 is described. From a double preform, the outer container 11 and the inner container 12 are prepared. Then, the valve holder 17 and the cap 18 are integrated. The integrated valve assembly 13 is fixed to the outer container 11 to assemble the discharge container 10. Then, in the state that the second intra-stem passage 21b of the stem 21 is closed, the stem 21 is pushed down to fill the content C in the accommodating chamber S1. After that, in the state that the first intra-stem passage 21a of the stem 21 is closed, the stem 21 is pushed down to fill the pressurizing agent P in the pressurizing chamber S2. In addition, before attaching the valve assembly 13 to the outer container 11, the content C may be filled in the accommodating chamber S1 from the opening of the longitudinal passage groove 12c.

    [0173] As the content C, a content discharged in spray mist, a content discharged in foam, and a content discharged in creaminess or gel-like etc. can be cited. However, as the content C discharged in foam, it is preferable to use a uniform solution composed of a foaming agent dispersed uniformly in the content. In this case, since the foaming agent dispersed uniformly in the content expands the passage, it is possible to prevent the gap between the accommodating chamber S1 and the longitudinal passage groove 12c from being blocked by the inner container 12 expanding to make the outer surface of the inner container 12 and the inner surface of the outer container 11 contact precedently. Thereby, the content is preferably discharged to the last. This uniform solution exerts a similar effect, even if it is not used in the first aspect of the present invention (the eighth aspect of the present invention), as long as it is that in which a discharge container is provided with an outer container, an inner container, and a valve assembly, where the pressurizing agent P is filled in the pressurizing chamber of the inner container, the content C is filled in the accommodating chamber S1 between the outer container and the inner container.

    [0174] As such uniform solution, that which shows an external appearance of transparent or translucent is preferable. The content may be aqueous solution or oily solution. The gauge pressure of the content C at 25 C. is preferable to be 0.01-0.3 MPa, further, 0.02-0.2 MPa. When the gauge pressure is lower than 0.01 MPa, the effect of expanding the passage from the composition accommodating chamber S1 to the longitudinal passage groove 17b becomes insufficient, there may be a case that the discharge is hard to be done. When the gauge pressure becomes higher than 0.3 MPa, the force becomes too strong causing the discharged foam is easy to be spattered.

    [0175] As an example of the content in which a foaming agent is dispersed uniformly in the content, for example, the following four types can be cited.

    [0176] [Content 1]

    [0177] A composition composed of a surface-active agent 1-30% by mass, a monovalent alcohol 5-30% by mass, an oil dissolving in ethanol 1-10% by mass, an aqueous content 40-90% by mass, and a foaming agent 10-60% by mass can be cited. The content (1) is, regardless of containing the foaming agent so much as 10-60% by mass in the composition, since the aqueous content has a specific composition, the foaming agent is dispersed uniformly in the aqueous content, does not separate, and shows transparent or translucent appearance.

    [0178] As the foaming agent, for example, propane, normal butane, isobutene, normal pentane, isopentane, and aliphatic hydrocarbon whose carbon number is 3-5 being a mixture of those (for example, LPG etc.), hydrofluoroolefin such as dimethyl ether, trans-1,3,3,3-tetrafluoroprop-1-ene and the mixture of those, of which the steam pressure (gauge pressure) is 0.1-0.5 MPa at 25 C. can be cited. As the surface-active agent, for example, a nonionic surface-active agent, an anionic surface-active agent, a cationic surface-active agent, an amphoteric surface-active agent, a high-molecular surface-active agent, and a silicone surface-active agent can be cited.

    [0179] As the monovalent alcohol, for example, monovalent alcohol of carbon number 2-5 such as ethanol, propanol, isopropanol, isobutyl alcohol, and amyl alcohol can be cited.

    [0180] As the oil dissolving in ethanol, for example, silicone oil such as octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylphenylpolysiloxane, ester oil such as isopropyl myristate, myristyl myristate, decyl oleate, lauric acid isostearyl, myristic acid isocetyl, myristic acid isostearyl, octyldodecyl myristate, octyl palmitate, octyl stearate, oleic acid octyldodecyl, ethyl isostearate, isooctane acid cetyl, dioctanate ethylene glycol, dioleat ethylene glycol, propylene glycol dicaprylate, dioleate propylene glycol, glyceryl tricaprylate, glyceryl caprylate, glyceryl tricaprinate/tricaprylate, glyceryl triisostearate, try2-ethyl hexane trimethylol propane, octyldodecyl neopentanoate, dimethyl octanoic acid hexadecyl, cetyl lactate, triethyl citrate, dioctyl succinate, adipic acid diisopropyl, and diethoxyethyl succinate, liquid hydrocarbon oil such as liquid paraffin, and isoparaffin, higher fatty acid such as laulic acid, myristic acid, palmitic acid, stearic acid, oleic acid, and isostearic acid, higher alcohol such as lauryl alcohol, cetyl alcohol, stearyl alcohol, myristyl alcohol, oleyl alcohol, lanolin alcohol, and isostearyl alcohol can be used. Moreover, it is preferable to contain a polyhydric alcohol 1-15% by mass in the aqueous content for enhancing the dispersity of the aqueous content and the foaming agent.

    [0181] As the polyhydric alcohol, for example, divalent to trivalent polyhydric alcohol such as ethylene glycol, propylene glycol, 1-3 butylene glycol, and glycerin can be cited.

    [0182] Further, it is preferable to contain effective ingredients in the content according to the purpose and the use of the discharge products. As the effective ingredients, for example, a styling agent, a moisturizing agent, an ultraviolet absorber, an amino acid, a vitamin group, an antioxidant, a various extraction liquid, an antiseptic/microbicide, a deodorant, a deodorization agent, an antiphlogistic analgetic, a refrigerant, an astringent, an anti-inflammatory agent, a local anesthetic, an antihistamine, a whitening agent, and a perfume can be cited.

    [0183] [Content (2)]

    [0184] A composition composed of an aqueous content 90-99.5% by mass containing an nonionic surface-active agent 1-50% by mass, of which the HLB is 13-17, and an aliphatic hydrocarbon 0.5-10% by mass, of which the carbon number is 3-5 can be cited. Since the content (2) contains an aqueous content containing a predetermined quantity of nonionic surface-active agent having a predetermined HLB and a predetermined foaming agent at a predetermined ratio, the foaming agent disperses uniformly in the aqueous content, does not separate, and shows transparent to translucent appearance. Particularly, by containing a divalent to trivalent polyhydric alcohol 5-50% by mass in the aqueous content, it is easy to obtain a transparent and uniform composition.

    [0185] As the nonionic surface-active agent of which the HLB is 3-17, for example, polyglycerin fatty acid ester such as penta glyceryl monolaurate, penta glyceryl monomiristate, penta glyceryl monooleate, penta glyceryl monostearate, hexa glyceryl monolaurate, hexa glyceryl monomiristate, deca glyceryl monolaurate, deca glyceryl monomiristate, and deca glyceryl monooleate, polyoxyethylenesorbitan fatty acid ester such as POE sorbitan monooleate, POE sorbitan monopalmitate, POE sorbitan monostearate, POE sorbitan monooleate, and POE sorbitan monoisostearate, polyoxyethylene alkyl ether such as POE lauryl ether, POE cetyl ether, POE oleyl ether, and POE behenyl ether, poluoxyethylene/polyoxypropylene alkyl ether such as POE/POP cetyl ether, polyoxyethlene sorbit fatty acid ester such as POE sorbit tetrastearate, POE sorbit tetraoleate, and POE sorbit monolaurate, polyoxyethylene glycerin fatty acid ester such as POE glyceryl monostearate, and POE glyceryl monooleate, polyoxyethlene castor oil/hardened castor oil such as POE hardened castor oil/can be cited.

    [0186] In addition, other than the nonionic surface-active agent, an anionic surface-active agent, a cationic surface-active agent, an amphoteric surface-active agent, and a polymeric surface-active agent, a silicone surface-active agent such as a polyoxyethylene/methyl polysiloxane copolymer can be added.

    [0187] As the monovalent alcohol, the polyvalent alcohol, the foaming agent of the content (2), that which is similar with the content (1) can be used. Moreover, same as the content (1), it is preferable to contain effective ingredients.

    [0188] [Content (3)]

    [0189] A composition composed of an aqueous content 80-98% by mass containing an amino acidic surface-active agent 0.1-10% by mass and a monovalent alcohol of carbon number 2-3 25-60% by mass, and an aliphatic hydrocarbon (foaming agent) of carbon number 3-5 2-20% by mass can be cited. In the content (3), the foaming agent disperses in the aqueous content uniformly and does not separate, the content (3) showing transparent to translucent appearance.

    [0190] As the amino acidic surface-active agent, for example, N-acyl glutamic acid salt such as N-coconut oil fatty acid acyl-L-glutamic acid toriethanolamine, N-coconut oil fatty acid acyl-L-glutamic acid potassium, N-coconut oil fatty acid acyl-L-glutamic acid sodium, N-lauroyl-L-glutamic acid sodium, N-lauroyl-L-glutamic acid toriethanolamine, N-lauroyl-L-glutamic acid potassium, N-lauroyl-L-glutamic acid sodium, N-myristoyl-L-glutamic acid potassium N-myristoyl-L-glutamic acid sodium, and N-stearoyl-L-glutamic acid sodium, N-acyl glutamic acid such as N-coconut oil fatty acid acyl-L-glutamic acid, N-lauroyl-L-glutamic acid, and N-stearoyl-L-glutamic acid, N-acyl glycine salt such as N-coconut oil fatty acid glycine potassium and N-coconut oil fatty acid glycine sodium, N-acyl alanine salt such as N-coconut oil fatty acid-DL-alanine toriethanol amine can be cited.

    [0191] As the monovalent alcohol, the foaming agent of the content (3), that which is similar with the content (1) can be used. Moreover, it is preferable to contain effective ingredients.

    [0192] [Content (4)]

    [0193] A composition composed of an oily content 85-99% by mass containing a surface-active agent 1-20% by mass and an oily base 50-99% by mass, and a foaming agent 1-15% by mass in the content can be cited.

    [0194] As the surface-active agent, it is possible to use the nonionic surface-active agent similar with the content (1), particularly, it is preferable to use those in order to ease the foaming of the oily content; polyglycerol fatty acid ester such as monooleate diglyceryl, monostearate diglyceryl, monolaurate diglyceryl, monocaprylate diglyceryl, monolaurate hexadiglyceryl, monoomyristate hexaglyceryl, monolaurate pentaglyceryl, monomyristate pentaglyceryl, monooleate pentaglyceryl, monostearate pentaglyceryl hexastearate pentaglyceryl, trimyristate pentaglyceryl, trioleate pentaglyceryl, monolaurate decaglyceryl, monomyristate decaglyceryl, monostearate decaglyceryl, monoisostearate decaglyceryl, monooleate decaglyceryl, monolinoleic decaglyceryl, pentastearate decaglyceryl, and pentaoleate decaglyceryl.

    [0195] As the oily base, similar with the content (1), such as ester oil, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, sesame oil, castor oil, linseed oil, safflower oil, jojoba oil, wheat germ oil, coconut oil, palm oil, and rice salad oil can be cited.

    [0196] In addition, in the oily content, water 1-20% by mass, a monovalent alcohol 1-20% may be contained. Moreover, same as the content (1), it is preferable to contain effective ingredients.

    [0197] As the foaming agent that which same as the content (1) can be used, but it is preferable to use that in which the steam pressure (gauge pressure) at 25 C. is 0.5-0.85 MPa so as to ease the foaming of the oily content.

    [0198] As the pressurizing agent, a compressed gas such as carbon oxide, nitrogen monoxide, nitrogen, oxygen, air, and the mixture of those, liquefied gas such as liquefied petroleum gas, dimethyl ether and the mixture of those can be cited.

    [0199] In addition, when using a uniform solution composed of a content and a foaming agent, it is preferable to use nitrogen gas, compressed air, carbon dioxide, nitrogen monoxide etc. Particularly, when using soluble compressed gas of which the solubility to a content is high such as carbon dioxide, nitrogen monoxide, it acts as a foaming agent when the pressurizing agent is permeated from the pressurizing chamber S2 to the composition accommodating chamber S1. Those are easy to foam even if the contained amount of the foaming agent is little, or the steam pressure of the foaming agent is low, which is preferable. In this case, for example, it is preferable that the pressure of the pressurizing agent is made to be 0.1-0.5 MPa. Stated differently, the steam pressure (gauge pressure) at 25 C. of the product pressure measured at the stem after filling the pressurizing agent is preferable to be 0.1-0.8 MPa so as to be 0.1-0.5 MPa higher than the steam pressure (gauge pressure) of the content before filling the pressurizing agent.

    [0200] When the steam pressure of the product pressure after filling the pressurizing agent is lower than 0.1 MPa, the effect of filling the pressurizing agent becomes difficult to obtain. When the steam pressure of the product pressure after filling the pressurizing agent is higher than 0.8 MPa, the momentum during discharge becomes too strong, causing the discharged foam easy to spatter.

    [0201] In the discharge container 10a of FIG. 4, the annular plate seal material A3 compressed vertically is provided between the upper surface of the flange portion 12b of the inner container 12 and the lower surface of the annular flange 27 of the valve assembly 13. Another composition is substantially same as the discharge container 10 of FIG. 1, and it has the outer container 11, the inner container 12 and the valve assembly 13. By providing the plate seal material A3 as described above, the plate material is compressed vertically by the fastening of the cap, the sealability of the pressurizing chamber in the inner container is further enhanced.

    [0202] The manufacturing method of the discharge product using the discharge container 10a may be made to be same as that of the above described discharge container 10. In FIG. 5A-5H, another manufacturing method using the discharge container 10a is described. This manufacturing method is characterized in that before filling the content C and the pressurizing agent P, the inner container is contracted by inserting the guide member, after that the content C and the pressurizing agent P are filled (the seventh aspect of the present invention). Hence, it is sufficient to be a multilayer structured discharge container comprising the outer container and the inner container having approximately an identical shape with the inner surface of the outer container, having flexibility, being accommodated in the outer container, and a lid body (a valve assembly) closing the mouth portion of the outer container and the mouth portion of the inner container, even if being not used in the first aspect of the present invention, the similar effects can be obtained. The manufacturing method using the guide member can be adopted in any embodiment of the discharge container later described.

    [0203] Next, using FIG. 5A-5H, it is described. First, same as the discharge container 10 of FIG. 1, a double preform consisting of the preform for the outer container 11 and the preform for the inner container 12 is prepared, by performing blowing (specifically biaxial stretch blowing) etc. the outer container 11 and the inner container 12 are simultaneously formed.

    [0204] Next, as shown in FIG. 5B, the guide member 40 is inserted into the inner container 12. The guide member 40 is, as shown in FIG. 5 and FIG. 6, an approximately rod like hollow elastic body, the lower end of which is made to be contacted with the bottom portion 12d of the inner container 12. Moreover, in the outer periphery surface, a convex portion (longitudinal rib) 40a and a concave portion (longitudinal groove) 40b are regularly formed alternately. Further, in the vicinity of the upper end portion is made to be smaller than the inner diameter of the mouth portion (the inner cylindrical portion 12a of the neck portion) of the inner container 12, so that even in the state that the guide member 40 is inserted into the inner container 12, the inside of the inner container 12 and atmospheric air are maintained to be communicated.

    [0205] Such guide member 40 is composed of an elastic material, for example, such as synthetic resin, silicone rubber.

    [0206] And, as shown in FIG. 5C, a supply and exhaust device etc. (not shown in the figure) is connected to the opening of the guide member 40, the guide member 40 is expanded to a degree not contacting the inner surface of the inner container 12.

    [0207] Next, as shown in FIG. 5D, a gas for contraction is filled in the accommodating chamber S1 through the longitudinal passage groove 12c of the inner container 12. When the gas is filled, the inner container 12 is contracted (contracted in the direction of reduced diameter), and contacts the outer surface of the guide member 40 expanded like a balloon. In addition, as the gas for contraction, that which is heated may be used. In this case, the inner container 12 is softened becoming easy to be contracted. The air in the inner container 12 is naturally exhausted to the exterior through the gap generated between the mouth portion (the inner cylinder portion 12a of the neck portion) and the guide member 40.

    [0208] Moreover, as shown in FIG. 5E, along with the contraction of the inner container 12 by the filling of the gas for contraction, air is evacuated from the guide member 40 to make it gradually contract (deflate). On this occasion, it is preferable that the inner surface of the inner container 12 is made to maintain the state to be contacted with the outer surface of the guide member 40 without a gap, the inner container 12 being supported from inside. By doing in this way, the irregular contraction of the inner container 12 is suppressed, making it easy to be contracted/deformed along the shape of the guide member 40.

    [0209] After contracting the guide member 40 completely, as shown in FIG. 5F, the guide member 40 is pulled out from the inner container 12. In addition, on this occasion, the inner container 12 is in the state that a regular slack 12h is formed along the irregularity provided in the outer periphery of the guide member 40, and this state is maintained.

    [0210] And, as shown in FIG. 5G, the valve assembly 13 is screwed to the outer container 11, the content C is filled in the accommodating chamber S1, the pressurizing agent P is filled in the inner container 12. The filling of the content C into the accommodating chamber S1 is carried out through the reversed root of the discharge passage of the content shown in FIG. 3A, by pushing downward the stem 21, in the state that the upper end of the second intra-stem passage 21b is closed. In this moment, since the inner container 12 is contracted, the passage to the accommodating chamber S1 is secured, the content C can be smoothly filled. Moreover, the filling of the pressurizing agent P in the inner container 12 is carried out through the reverse root of the gas exhaust passage shown in FIG. 3B, by pushing downward the stem 21, in the state that the upper end of the first intra-stem passage 21a is closed. In addition, before attaching the valve assembly 13 (FIG. 5F), the content C may be filled in the accommodating chamber S1 from the longitudinal passage groove 12c.

    [0211] In addition, after filling the content C (FIG. 5G), the air in the inner container 12 before the filling of the pressurizing agent P can be exhausted through the discharge passage of the content by pushing downward the stem 21, in the state that the upper end of the second intra-stem passage 21b is closed (refer to FIG. 3B). The air in the accommodating chamber S1 can be exhausted by leaving the upper end of the second intra-stem passage 21b opened, before the pressurizing agent P is filled.

    [0212] After filling the content C and the pressurizing agent P (FIG. 5H), the stem 21 is pushed down, in the state that the upper end of the second intra-stem passage 21b is closed, to exhaust the air remaining in the accommodating chamber S1, the accommodating chamber S1 is filled with the content C (to make it fluid-tight). Moreover, the removal of the content C and the pressurizing agent P remaining in the stem 21 is carried out to complete the manufacture of the discharge product.

    [0213] In the manufacturing method described above, since the inner container 12 is contracted in the state that the guide member 40 is inserted into the inner container 12, the inner container 12 can be contracted along the guide member 40, the inner container 12 can be deformed into an intended shape. Hence, the variation between the products can be suppressed, further, it becomes also possible to fill the content C in the accommodating chamber S1 between the outer container 11 and the inner container 12 at an approximately uniform thickness. Moreover, since the irregularity is formed in the outer surface of the guide member 40, the slack 12h by the contraction of the inner container 12 can be provided in an intended portion. Hence, for example, even if the outer container 11 has translucency, it makes a good appearance, further, by the slack 12h formed regularly, such an effect can be generated that the inner container 12 is easy to restore the original shape.

    [0214] Moreover, since the lower end of the guide member 40 contacts the bottom portion 12d of the inner container 12 before the contraction/deformation, such a deformation that the inner container 12 is raised, or the bottom portion 12d is rolled up can be suppressed, preventing the blocking of the longitudinal passage groove 12c by the shoulder portion of the inner container 12, allowing uniform filling of the content C in the accommodating chamber S1.

    [0215] Further, when contracting/deforming the inner container 12 (to form the accommodating chamber S1 between the outer container 11 and the inner container 12), since the gas whose viscosity is much lower compared with the content C is used, the fear that the contraction/deformation converges in the vicinity of the longitudinal passage groove 12c of the inner container 12 is small, allowing simple and uniform contraction of the inner container 12. Moreover, since the method to contract the guide member 40 along with contraction of the inner container 12 is adopted, the inner container 12 becomes easy to be contracted along the guide member 40, allowing more simple contraction of the inner container 12.

    [0216] The manufacturing method of FIG. 7 is characterized in that the guide member 42 is made to be a simple shape such as a columnar (rod-like) of which the cross section is, for example, circular, elliptic, polygonal.

    [0217] Even in this case, the shape of the inner container 12 after contraction becomes approximately constant, making it possible to suppress the irregular contraction of the inner container 12. The manufacturing method is same as the method using the guide member 40 other than not having the process to inflate the guide member 40 and the process to deflate the guide member 40. Therefore the process drawings are shown in FIG. 7A-FIG. 7F, omitting specific description. In addition, in the present embodiment also, the lower end of the guide member 42 is formed to be spherical, preventing such a case that the guide member 42 resultantly break (resultantly penetrate) the bottom portion 12d during the contraction of the inner container 12.

    [0218] The discharge container 10b of FIG. 8A is characterized in that a guide member 43 is attached to the lower end (the cylindrical portion 26g) of the valve holder 17. Another composition is substantially same as the discharge container 10a of FIG. 4. The guide member 43 of the discharge container 10b is, different to the guide member 40 of FIG. 5, not pulled out from the inside of the inner container 12, being left inside the inner container 12.

    [0219] This guide member 43 is composed of hard resin, for example, such as polybutylene terephthalate, polyacetal, as shown in FIG. 8B, and is of a hollow rod-like shape, the lower portion of which is formed to be spherical, and a convex portion 43a and a convex portion 43 b are formed spirally, in the surface of which, a plurality of communicating holes 43d communicating the inside of the inner container 12 and a hollow portion 43c are formed so as to be along the concave portion 43b. The hollow portion 43c can be communicated with atmospheric air through the gas passage of FIG. 3B in the state being attached to the cylinder portion 26g of the housing 26 of the valve assembly 13. Hence, when the stem 21 is pushed downward, the inside of the inner container 12 and atmospheric air are communicated through the guide member 43.

    [0220] In place of the guide 43, a guide member 44 of FIG. 8B may be used. The guide member 44 is characterized in that it is of a tubular shape, inside and outside of which is flat, having a hollow portion 44a, in the lower end thereof it has a spherical attachment 44b which makes the opening of the hollow portion 44a face laterally.

    [0221] The manufacturing method thereof is described. First, as shown in FIG. 9A, for example, the outer container 11 and the inner container 12 are formed by molding a double preform using biaxial stretch blow molding etc. To the mouth portion of those containers, the valve assembly 13 to which the guide member 43 is attached is screwed. On this occasion, although the lower portion of the guide member 43 is not contacted to the bottom portion 12d of the inner container 12, but is positioned near the bottom portion 12d. Next, in the state that the stem 21 is pushed downward, a supply and exhaust device (not shown in the figure) such as a pump is connected to the second intra-stem passage 21b, the air inside the inner container 12 is drained through a suction gas passage consisting of the communicating hole 43d of the guide member 43 and the hollow portion 43c. Since the communicating hole 43d is formed so that the opening size becomes larger toward downward, in the lower side of the inner container 12 also, the pressure reduction is made to be carried out smoothly. In addition, on the occasion of the pressure reduction of the inner container, the upper end of the first intra-stem passage 21a is made to open, along with the contraction of the inner container 12, air is made to be supplied between the outer container 11 and the inner container 12. But, instead, it may be sufficient to fill a gas for contraction (heated gas may be sufficient).

    [0222] When the air in the inner container 12 is sufficiently drained, as shown in FIG. 9B, the inner container 12 deforms along the outer shape of the guide member 43. In other words, it becomes a shape in which concavity and convexity are spirally formed.

    [0223] And, as shown in FIG. 9C, the manufacture of the discharge product 10b is completed by filling the content C in the accommodating chamber S1, filling the pressurizing agent P in the inner container 12, and exhausting the air in the accommodating chamber S1. In addition, the filling method is same as the embodiment described above. But, the point that the pressurizing agent P is filled in the inner container 12 through the hollow portion 43c of the guide member 43 and the communicating hole 43d is peculiar to the present embodiment.

    [0224] In the manufacturing method of the discharge product using the discharge container 10b, since the contraction of the inner container 12 is carried out in the state that the valve assembly 13 is attached, it has a merit that there is no need to pay attention to the return of air to the inner container 12, allowing simple contraction work of the inner container 12. Moreover, since the guide member 43 is not taken out, the work process is simplified to that extent.

    [0225] In the discharge container 10c of FIG. 10, a solid guide member 45 is attached to the lower end (the cylindrical portion 26g) of the valve holder 17, the second communicating hole 26b of the housing 26 is formed in the lower side surface of the housing 26. Another composition is substantially same as the discharge container 10a of FIG. 4. The guide member 45 of the discharge container 10c also is made to be left in the inner container 12 without being taken out from the inner container 12.

    [0226] In such guide member 45 also, the deformation such as the inner container 12 being raised, and the deformation such as the bottom portion 12d being rolled up can be suppressed. Moreover, since the lower end is spherical, it is prevented that the guide member 45 resultantly breaks (penetrates) the bottom portion 12d of the inner container 12.

    [0227] The discharge container 50 of FIG. 11 is that in which a protection cap 53 to assist the exhaust of the pressurizing agent is provided. In detail, it comprises the outer container 11, the inner container 12 accommodated in the outer container 12, a valve assembly 51 closing the outer container 11 and the inner container 12, and a push button (discharge member) 52 attached to the valve assembly 51. Moreover, to the valve assembly 51, the protection cap 53 to protect the stem 21 and the push button 52 of the valve assembly 51 are attached. Further, same as the discharge container 10a of FIG. 4, the annular plate seal material A3 is provided. In addition, the outer container 11 and the inner container 12 are substantially same as those of the discharge container 10 of FIG. 1.

    [0228] A valve assembly 51 is, as shown in FIG. 12A, provided with the valve mechanism 16 which independently shuts off/communicates two fluids, a cylindrical valve holder 56 accommodating the valve holder 16, a valve cover 57 covering the valve holder 56 so as to fix the valve mechanism 16 to the inside of the valve holder 56, and a cap 58 which fixes the valve mechanism 16, the valve holder 56, and the valve cover 57 to the outer container 11. The valve mechanism 16 is substantially same as the discharge container 10 of FIG. 1.

    [0229] The valve holder 56 is different to the discharge container 10 of FIG. 1 in the point that a plurality of elongated protrusions 27b, not the lateral passage groove 27a, protruding upward is formed in the upper surface of the annular flange 27 as shown in FIG. 12B, 12C.

    [0230] Another composition is substantially same as the discharge container 10 of FIG. 1, and is provided with the cylindrical housing 26, the annular flange 27, and the plug portion 28 provided coaxially outward to the housing. Between these elongated protrusions 27b serves substantially as the lateral passage.

    [0231] The valve cover 57 is, as shown in FIG. 12D, provided with a canopy portion 61 closing the opening of the housing 26 of the valve holder 57, a cylindrical portion 62 extending downward from the edge portion thereof, arranged in the outer periphery of the housing 26, and an annular hem portion 63 extending outward radially from the lower end thereof. The valve cover 57 is communicated with the first communicating hole 26a of the housing 26 between the hem portion 63 and the annular flange portion 27 of the valve holder 56, and forms the lateral passage communicated with the accommodating chamber S1 through the longitudinal passage groove 12c of the inner container 12.

    [0232] In the center of the canopy portion 61, a center hole 61a which let through the stem 21 of the valve mechanism 16 is formed.

    [0233] In the inner surface of the cylindrical portion 62, an engaging protrusion 62a engaging with the step portion 26e of the housing 26 is formed. And, by tucking the valve holder 56 with the canopy portion 61 and the engaging protrusion 62a, the valve mechanism 16 is fixed to the valve holder 56 (the housing 26) and holds the valve holder 56 (refer to FIG. 12A). In addition, the lower inner surface of the cylindrical portion 62 (inner surface lower than the engaging protrusion 62a) forms the annular gap G1 with the outer periphery surface of the housing 26 (refer to FIG. 12A). This gap G1 is communicated with elongated protrusion 27b of the above described valve holder 56 (intra-discharge passage).

    [0234] The hem portion 63 is provided with a first hem 63a, a step portion 63b extending downward from the end portion of the first hem 63a, and a second hem 63c extending outward radially from the lower end of the step portion 63b. The first hem 63a is arranged thereon so as to cover the annular flange portion 27 (the elongated protrusion 27b) of the valve holder 57 (refer to FIG. 12A). The second hem 63c is arranged thereon so as to cover the third seal material A3 (the flange portion 12b of the inner container 12) (refer to FIG. 12A). In addition, a plurality of downward grooves 63d formed continuously toward the lower surface of the second hem 63c is formed at an equal interval (refer to FIG. 3A, 3D).

    [0235] Being composed as described above, the lateral passage between the hem portion 63 of the valve cove 57 and the annular flange 27 of the valve holder 56 is composed by (the gap G1) between the cylindrical portion 62 of the valve cover 57 and the housing 26 of the valve holder 56, between the first hem 63a and the flange portion 27 (the lateral passage between the elongated protrusions 27b), and between the lower surface of the second hem 63c and the third seal material A3 (the downward groove 63d).

    [0236] In addition, the space (lateral passage) between the gap G1 and the elongated protrusion 27b may be communicated by extending the hem portion 63 of the valve cover 57 to the outer end of the third seal material A3.

    [0237] The cap 58 is, as shown in FIG. 12E, provided with an upper cylindrical portion 66 covering the outer periphery surface of the cylindrical portion 62 of the valve cover 57, an annular ring portion (pressing portion) 67 protruding radially outward from the lower end thereof, and a lower cylindrical portion 68 extending downward from the outer end thereof. The ring portion (pressing portion) 67 is arranged thereon so as to cover the hem portion 63 of the valve cover 57 (refer to FIG. 12A). The lower surface thereof is formed so as to contact the upper surface of the hem portion 63. The upper end of the upper cylindrical portion 66 is substantially made to be same height as the upper end of the cylindrical portion 62 of the valve cover 57. Hence, between the cap 58 and the valve cover 57 becomes an annular opening facing upward.

    [0238] In the inner surface of the lower cylindrical portion 68, a screw 68a engaging with the screw 11a of the outer container 11 is formed. And, in the position of the annular protrusion 11b2 of the outer seal holding portion 11b of the outer container 11, being beneath the screw 68a, an inner cylindrical portion 68b somewhat diameter-expanded than the protrusion of the screw 68a is formed. This inner cylindrical portion 68b compresses the first seal material 16 radially across the outer cylindrical portion 11b1 of the outer container 11 (refer to FIG. 11). Moreover, in the upper outer periphery of the lower cylindrical portion 68, a protection cap engaging step portion 68c engaging with the protection cap 53 is formed.

    [0239] For the valve holder 56, the valve cover 57, and the cap 53, it is preferable to use synthetic resin such as polyethylene terephthalate, nylon.

    [0240] Thereby, the nonmetal valve assembly 51 can be constructed.

    [0241] A push button 52 is, as shown in FIG. 13A, substantially same as the push button 14 of the discharge container of FIG. 1 other than that it is communicated with the intra-button passage 14c through a mechanical breakup mechanism 69 in the discharge hole 14b. In detail, a columnar core 69b is inserted into a nozzle inserting hole 69a formed in the front surface of the push button 14 so as to be communicated with the intra-button passage 14c, and a cup-like spray nozzle 69c in which the discharge hole 14b is formed in the center is attached to the front surface of the core 69b. Hence, the content passing through the intra-button passage 14c passes through the outer periphery of the core 69b, and passes through the groove of the rear surface of the spray nozzle 69c, goes to the discharge hole 14b while being given a turning force. However, another spray mechanism may be provided according to use.

    [0242] As described above, the push button 14 is, by being attached to the stem 21 of the valve assembly 51, closes the opening of the second intra-stem passage 21b of the stem 21, the upper end surface 20 of the diameter-reduced hole 37 serves as a closing portion.

    [0243] The protection cap 53 is, as shown in FIG. 13B, that which is cylindrical having a top surface 54. In the center of the top surface 54, the inner cylindrical portion 25a of the stem 21 can be inserted, and a stem inserting hole 54a for pressurizing agent exhaust locking the outer cylindrical portion 25b is formed. Hence, by turning inside out the protection cap 53 to insert the stem 21 into the stem inserting hole 54a, and pushing down the stem 21, the top surface 54 being the outer periphery edge of the stem inserting hole 54a engages with the upper end of the outer cylindrical portion 25b, the stem 21 can be pushed down, while closing the first intra-stem passage 21a.

    [0244] The double discharge container 50 composed as described above, same as the discharge container 10 of FIG. 1, can discharge the content C from the discharge hole 14b of the push button 52, by pushing down the push button 52 (refer to FIG. 14A).

    [0245] Meanwhile, when the discharge container 10 is discarded, the push button 52 is detached, as shown in FIG. 14B, the operation is carried out so that the inner cylindrical portion 25a of the stem 21 of the valve assembly 51 is inserted into the stem inserting hole 54a of the protection cap 53 of which the opening is placed facing downward. In this state, by pushing down the outer container 11, the pressurizing agent P can be exhausted downward. In this moment, since the top surface 54 of the protection cap 53 closes the upper end opening of the first intra-stem passage 21a of the stem 21, the pressurizing agent P in the inner container 12 (gas accommodating portion) only is exhausted from the stem 21. Since the first intra-stem passage 21a is closed, even if the content remains, it is not scattered. And, the pressurizing agent P is exhausted in the protection cap 53, preventing the scattering.

    [0246] Here, the gas passage (intra-holder passage) of the valve assembly 13 consists of the cylindrical portion 26g, the second communicating hole 26b, the lower space of the housing 26 of the valve holder 56, and the second intra-stem passage 21b of the stem 21.

    [0247] The discharge product using this discharge container 50 can be manufactured by any of the manufacturing method described above.

    [0248] The discharge container 50a of FIG. 15A is that in which an exhaust mechanism for pressurizing agent exhaust is provided in a push button 71. Another composition is substantially same as the double discharge container 50 of FIG. 11. FIG. 15A shows the use state of the discharge container 50a.

    [0249] In the push button 71 of the double discharge container 50a, a stem hole 72 for pressurizing agent exhaust is formed. The stem hole 72 comprises a diameter-expanded hole 72a into which the outer cylindrical portion 25b of the stem 21 is inserted, a diameter-reduced hole 72b into which the inner cylindrical portion 25a of the stem 21 is inserted, being provided in the upper portion thereof, and a step portion 72c connecting the diameter-expanded hole 72a and the diameter-reduced hole 72b. The upper end of the diameter-reduced hole 72b is opened. Another composition is same as the push button 52 of the discharge container 50 of FIG. 11.

    [0250] Being composed as described above, when discarding the discharge container 50a, as show in FIG. 15B, the push button 71 is detached from the stem 21, the push button 71 is placed so that the opening of the diameter-reduced hole 72b faces upward, the outer container 11 is turned upside down, the outer cylindrical portion 25b of the stem is inserted into the diameter-reduced hole 72b to engage the upper surface of the push button 72 and the upper end of the outer cylindrical portion 25b. In this state, by pushing down the outer container 11, the stem 21 is pushed down, the pressurizing agent P can be exhausted into the stem inserting hole 72 (switching operation). Moreover, even if the content remains, since the upper opening of the outer cylindrical portion 25b is closed by the upper surface of the push button 52, the content is never scattered.

    [0251] In addition, the use state is substantially same as the discharge container 10 of FIG. 1, by pushing down the push button 71 in which the stem 21 is inserted into the stem engaging hole 14a, the content C is discharged from the discharge hole 14b (refer to FIG. 6A).

    [0252] The discharge container 50b of FIG. 16 is also that in which the discharge mechanism for pressurizing agent exhaust is provided in a push button 74. Another composition is substantially same as the discharge container 50 of FIG. 11. FIG. 16A shows the use state of the discharge container 50b.

    [0253] To the push button 74 of the double discharge container 50b, an exhaust member 75 to assist the exhaust of the pressurizing agent is connected. In detail, in the upper surface of the push button 74, an exhaust member holding hole 74b to hold the exhaust member 75 is formed. Moreover, below the diameter-reduced hole 36 of the stem engaging hole 14a, an exhaust member engaging hole 74a further expanded in diameter is formed. Another composition is substantially same as the push button 52 of the double discharge container 50 of FIG. 11, and it is provided with the discharge hole 14b and the intra-button passage 14c.

    [0254] The exhaust member 75 is that which is of flat plate-like, a recessed portion 75b in which a center hole 75a is provided is formed. The center hole 75a has a dimension (shape) letting through the inner cylindrical portion 25a, and a dimension (shape) not letting through the outer cylindrical portion 25b, the recessed portion 75b has a dimension (shape) letting through the outer cylindrical portion 25b. The recessed portion 75b of the exhaust member 75 protrudes in the view from the back, and the protruding portion (the rear side of the recessed portion 75b) is engaged with the exhaust member holding portion 74b of the push button 74, and is held.

    [0255] Being composed as described above, when discarding the double discharge container 50b, as shown in FIG. 16B, the exhaust member 75 is detached from the push button 74, the rear surface of the recessed portion 75b is inserted into the exhaust member engaging hole 74a of the stem engaging hole 14a so that the recessed portion 75b faces downward, the stem 21 is inserted into the push button 74 being in this state (switching operation). Thereby, the upper end of the inner cylindrical portion 25a is not inserted into the diameter-reduced hole 37 of the push button 74, the second intra-stem passage 21b is not closed. Meanwhile, the recessed portion 75b of the exhaust member 75 closes the upper end opening of the outer cylindrical portion 25b, the first intra-stem passage 21a is closed. Hence, by pushing down the push button 74 in this state, the pressurizing agent P can be exhausted from the discharge hole 14b. In addition, the use state is substantially same as the discharge container 50 of FIG. 11, by pushing down the push button 74 in which the exhaust member 75 is attached to the exhaust member holding hole 74b, the content is discharged from the discharge hole 14b through the first intra-stem passage 21a.

    [0256] The discharge container 80 of FIG. 17 is that in which a pressure adjusting mechanism 81 to adjust the inner pressure of the inner container 12 is provided. In detail, it is provided with the outer container 11, the inner container 12 accommodated therein, the valve assembly 13 closing the outer container 11 and the inner container 12, fixed by being engaged with the outer periphery of the outer container, and a pressure adjusting mechanism 81 accommodated in the inner container 12 to adjust the inner pressure of the inner container 12.

    [0257] In this discharge container 80 also, the content C is filled in the accommodating chamber S1 between the outer container 11 and the inner container 12, and the pressurizing agent P is filled in the pressurizing chamber S2 inside the inner container. And, it is used by attaching the push button 14 to the valve assembly 13. And, by detaching the push button 14 from the valve assembly 13, and pushing down (switching operation) the stem 21 of the valve mechanism 16, the pressurizing chamber S2 and the atmospheric air can be communicated.

    [0258] In the discharge container 80, the outer container 11, the inner container 12, the push button 14 are substantially same as those of the discharge container 10 of FIG. 1. The valve assembly 13 is also same as the valve assembly 13 of the discharge container 10 of FIG. 1, other than the point that a cylindrical high pressure chamber 82 of the pressure adjusting mechanism 81 is provided in the lower end of the housing 26 of the valve holder 17 of the valve assembly 13.

    [0259] The pressure adjusting mechanism 81 is, as shown in FIG. 18A, provided with a cylindrical high pressure chamber body 82, a cylindrical cylinder portion 83 closing the lower end thereof, a valve rod 84 which communicates/shuts off between the high pressure chamber body 82 and the cylinder portion 83, a piston 85 interlocked with the valve rod 84, being accommodated inside the cylinder portion 83, a lower lid portion 86 closing the lower end of the cylinder portion 83, and a spring 87 provided between the piston 85 and the lower lid portion 86.

    [0260] In the pressure adjusting mechanism 81, the inside of the high pressure body 82 serves as a high pressure chamber HP, between the piston 85 inside the cylinder portion 83 and the lower lid portion 86 serves as a reference pressure chamber SP, the valve rod 84 serves as a valve. And, the pressure inside the reference pressure chamber is adjusted by the inner pressure of the reference pressure chamber and the force of the spring 87 pressing the piston 85. In addition, not providing the spring 87, it is sufficient that the inner pressure of the reference chamber is made to be constant.

    [0261] The high pressure chamber body 82 is a cylindrical body provided coaxially with the housing 26 in the lower end of the housing 26 of the valve assembly 13, and is communicated with the lower space of the housing 26 through the second communicating hole 26b. In this discharge container 80, the high pressure chamber body 82 is formed integrally in the lower end of the housing 26. However, it may be made to be separate members and to be connected.

    [0262] The cylinder portion 83 is a cylindrical body having an upper bottom for closing the lower end of the high pressure chamber body 82. In the side surface, a gas communicating hole 83a is formed. In the center of the upper bottom, a center hole (gas supply hole) 83b is formed, in the upper surface of the upper bottom, a cylindrical engaging portion 83c closing the high pressure chamber body 82, being inserted inside the high pressure chamber body 82 tightly is provided.

    [0263] The valve rod 84 is a rod body inserted into the center hole 83b of the cylinder portion 83, in the upper end of which a circular plate like clasping portion 84a is provided. A ring like valve seal 88 is provided between the lower surface of the clasping portion 84a and the upper bottom of the cylinder portion 83. Stated differently, when the valve rod 84 descends, the clasping portion 84a of the valve rod 84 presses the upper bottom of the cylinder 83 through the valve seal 88, thereby the center hole 83b is closed. Meanwhile, when the valve rod 84 ascends, the compression to the valve seal 88 by the clasping portion 84a is released, opening the center hole 83b. The piston 85 is that which is plate-like, and moves vertically on the inner surface of the cylinder portion 83 contacting tightly.

    [0264] In the upper surface, a valve engaging portion 85a engaging with the lower end of the rod body of the valve rod 84 is formed. The lower surface receives the spring 87. In the side surface, a ring like seal material 89 is provided. In other words, by the vertical movement of the piston 85 inside the cylinder portion 83, the reference pressure chamber SP is compressed/expanded. The lower lid portion 86 is a member to close the lower end of the cylinder portion 83 tightly. In the upper surface, a cylindrical engaging portion 86a inserted inside the cylinder portion 83 tightly, closing the lower end opening of the cylinder portion 83 is formed. The upper surface of the lower lid portion 86 receives the spring 87.

    [0265] The pressure adjusting mechanism 81 composed as described above operates depending on the difference of the pressing force to the piston 85 by the inner pressure of the reference pressure chamber and the spring, and the pressing force to the piston 85 by the pressure of the inner container 12 (the pressurizing chamber S2).

    [0266] In detail, when the pressing force from the reference pressure chamber SP becomes larger than the pressing force from the inner container 12, the piston 85 moves so as to expand the reference pressure chamber SP, in other words, the piston 85 ascends (refer to FIG. 8B). Hence, the valve rod 84 ascends, the pressurizing agent P in the high pressure chamber HP is supplied to the inside of the inner container 12 through the center hole 83b and the gas communicating hole 83a. Meanwhile, when the pressing force from the inner container 12 becomes strong by the supply of the pressurizing agent P inside the inner container 12, the piston 85 moves so as to contract the reference pressure chamber SP. In other words, the piston 85 descends. Thereby, the valve rod 84 descends, the valve seal 88 between the clasping portion 84a of the valve rod 84 and the upper bottom of the cylinder portion 83 is compressed, the center hole 83b is shut off (refer to FIG. 18A).

    [0267] Next, the manufacturing method of the discharge product using the discharge container 80 is shown in FIG. 19.

    [0268] First, a double bottle consisting of the outer container 11 and the inner container 12 is formed. In this moment, so as to make the accommodating chamber S1 open securely when filling the content, for example, using the above described guide member (the seventh aspect of the present invention), the inner container 12 may be contracted once. Meanwhile, a lid material in which the valve assembly 13 and the pressure adjusting mechanism 81 are connected is prepared (refer to FIG. 19A). The connected portion is preferable to be integrated.

    [0269] This lid material is fixed to the double bottle. After that, the stem 21 is pushed down, the pressurizing agent P is filled from the second intra-stem passage 21b (refer to FIG. 19B). In this moment, it is preferable to fill while closing the first intra-stem passage 21a. Stated differently, before the pressurizing agent P is filled, since the force of pressing the piston 85 of the pressurizing chamber SP is larger than that of the inner container 12, the center hole 83b is opened, the pressurizing agent P is supplied to inside the inner container 12 through the center hole 83b and the gas communicating hole 83a. When the pressurizing agent P is filled in the inner container 12, the force of pressing the piston 85 of the inner container 12 becomes larger than that of the pressurizing chamber SP, the piston 85 descends together with the valve rod 84, the center hole 83b is shut off. After that also, by filling the pressurizing agent P inside the high pressure chamber HP, the pressure in the high pressure chamber HP is made to be sufficiently higher than the reference pressure chamber SP even in the expanded state (the state after the content C is discharged), where the outer surface of the inner container 12 contacts the inner surface of the outer container 11.

    [0270] In addition, the filling of the content to the accommodating chamber S1 may be carried out before the lid material in which the valve assembly 13 and the pressure adjusting mechanism 81 are connected is fixed to the double bottle, moreover, it may be filled from the first intra-stem passage 21a of the stem 21 after being fixed to the double bottle.

    [0271] Next, the use method of the discharge product is shown. The use method is that the stem 21 is pushed down by the push button 14 to open the valve mechanism 16, the content C can be discharged by the pressure inside the inner container 12 (refer to FIG. 20A). By the discharge of the content C, the inner container 12 expands, when the inner pressure of the inner container 12 decreases, the pressure adjusting mechanism 81 operates as described above, and the pressurizing agent P is replenished to the inner container 12 from the high pressure chamber HP. When the pressure inside the inner container 12 becomes high, the piston 85 descends downward to stop the supply of the pressurizing agent P. Since this supply process and the supply stop process is carried out every time when the content C is discharged, the content C can be discharged at the same momentum to the last.

    [0272] After discharging the content C, as shown in FIG. 20B, by detaching the push button 14 and pushing down (switching operation) the stem 21, the pressurizing agent P in the high pressure chamber can be exhausted to the exterior. Along with this, since the center hole 83b of the pressure adjusting mechanism 81 is opened, the pressurizing agent P in the inner container 12 can be also discharged from the second intra-stem passage 21b of the stem 21 through the gas communicating hole 83a and the center hole 83b. Further, by detaching the cap 18 from the outer container 11, it can be discarded according to the material sorted.

    [0273] The discharge container 100 of FIG. 21 is the first aspect of the present invention, and is that in which an inner seal material is provided between the valve holder and the inner container, an outer seal material whose cross section is circular is provided between the outer cylindrical surface of the outer container and the inner cylindrical surface of the cap, and by moving the cap to a temporary position upper than the fixed position, the seal structure of the inner seal material is released while maintaining the seal structure of the outer seal material.

    [0274] In detail, the discharge container 100 comprises the outer container 11 made of resin, the inner container 12 made of resin accommodated therein, a valve assembly 101 closing the outer container 11 and the inner container 12, fixed by being engaged with the outer periphery of the outer container. The outer container 11 and the inner container 12 are substantially same as the discharge container 10 of FIG. 1, the content C is filled in the accommodating chamber S1 between the outer container 11 and the inner container 12, and the pressurizing agent P is filled in the pressurizing chamber S2 in the inner container. A push button 102 is attached to the valve assembly 101.

    [0275] In this discharge container 100, the cap 18 of the valve assembly 101 is moved to the temporary position upper than the fixed position, and by pushing down (switching operation) the stem 106 of the valve mechanism 103, the pressurizing chamber S2 and atmospheric air can be communicated (refer to FIG. 23).

    [0276] The valve assembly 101 is, as shown in FIG. 22A, provided with a valve mechanism 103 which shuts off/communicates one fluid, a valve holder 104 closing the outer container 11 and the inner container 12, and the cap 18 which fixes the valve mechanism 103 to the inside of the valve holder 104, and fixes the valve holder 104 to the outer container 11. The cap 18 is substantially same as the cap 18 of the discharge container 10 of FIG. 1.

    [0277] The valve mechanism 103 comprises a stem 106 in which a stem hole 106a communicating the inside and the outside is formed in the lower portion, an annular stem rubber 107 closing the stem hole 106a, and an elastic body 108 energizing the stem 106 always upward.

    [0278] The valve holder 104 has, as shown in FIG. 22, a cylindrical housing 109, the annular flange 27 extending outward from the central side surface of the housing 109, and the cylindrical plug portion 28 provided in the lower surface thereof, being outward coaxially with the housing 109.

    [0279] The annular flange 27 and the plug portion 28 are substantially same as the annular flange 27 and the plug portion 28 of the discharge container 10 of FIG. 1. The inside of the housing 109 of the valve holder 104 is communicated with the accommodating chamber S1 through the annular flange 27. In detail, the inside of the housing 109 is communicated with the accommodating chamber S1 so as to circumvent the annular flange 27 out of the housing 109.

    [0280] The housing 109 is different to the housing 26 of the discharge container 10 of FIG. 1 in the point that it does not have a second communicating hole and the second rubber support portion. Another composition is substantially same as the housing 26 of FIG. 1, in the side surface of the housing 109, a communicating hole 109a is formed, a rubber supporting portion 109b supporting the stem rubber 107 is formed in the upper end of the housing 109, and a plurality of leaf springs 109c composing an elastic body 108 is formed protruding upward in the bottom portion of the housing 64. And, the upper periphery of the first communicating hole 109a of the housing 109 is expanded in diameter through a step portion 109d.

    [0281] Being composed as described above, the discharge passage of the content connecting the accommodating chamber S1 and atmospheric air excepting the push button 14 is, as shown in FIG. 22, communicated with atmospheric air through the longitudinal passage groove 12c of the inner container 12, the gap G2 between the lower cylindrical portion 34 of the cap 18 and the valve holder 104, the content passage (the lateral passage groove 27a between the ring portion 33 of the cap 18 and the valve holder 104, the gap G1 between the lower inner surface of the upper cylindrical portion 32 of the cap 18 and the outer periphery surface of the housing 109 of the valve holder 104, the first communicating hole 109a of the housing 109, and the inside of the housing 109) and the stem 106 of the valve mechanism 103.

    [0282] The push button 102 is, as shown in FIG. 22C, that which is publicly known attached to a one-fluid type stem, and is provided with a stem engaging portion 102a formed in the lower portion, a discharge hole 102b formed in front, and an intra-button passage 102c connecting those. In addition, a mechanical breakup mechanism etc. as the push button 52 of FIG. 11 may be adopted in the discharge hole 102b according to a discharge form.

    [0283] Next, the seal structure of the discharge container is described referencing to FIG. 21.

    [0284] In this discharge container 100 also, same as the discharge container 10 of FIG. 1, the outer seal A1 is provided between the outer container 11 and the valve assembly 101, and the inner seal material A2 between the inner container 12 and the valve assembly 101 (refer to FIG. 21). And, substantially same as the discharge container 10 of FIG. 1, since the outer seal material A1 and the inner seal material A2 are compressed to the axis of the inner and outer container vertically, the seal is formed regardless of the degree of fitting (degree of screwing) of the cap 18 to the outer container 11.

    [0285] Further, in this discharge container 100, the arrangement of the outer seal material A1 and the inner seal material A2 is made so that, when the cap 18 is ascended together with the valve assembly 101 in the state that the compression of the outer seal material A1 by the lower portion of the inner cylindrical portion 34b of the cap 18 is maintained, the inner seal material A2 ascends together with the valve assembly 101, and departs from the inner cylindrical portion 12a of the inner container 12 (refer to FIG. 23). Stated differently, when the cap 18 connected with the valve assembly 101 is ascended, the seal structure of the inner seal material A2 can be released (temporary fixed position), while the seal structure of the outer seal material A1 is maintained. In addition, in the discharge container 10 of FIG. 1, the arrangement may be made to be the same. Thereby, the under cup filling to fill the pressurizing agent at higher speed becomes possible.

    [0286] Next, the manufacturing method of the discharge container 100 is shown. The outer container 11 and the inner container 122 are prepared from a double preform. Then, the valve holder 104 and the cap 18 are integrated. Then, the seal structure of the outer seal material A1 is formed, and the integrated valve assembly 101 is fixed temporarily so that the seal structure of the inner seal material A2 is not formed (refer to FIG. 23). In this state, the housing 109 of the valve holder 104 and the pressurizing chamber S2 are communicated (refer to the thick line of FIG. 23). In this state, the stem 106 is pushed down, and from the stem 106, the pressurizing agent P is filled. After that, the cap 18 of the valve assembly 104 is fixed actually to the outer container 11 to form the seal structure of the inner seal material A2. In this state, the stem 106 is pushed down, and the pressurizing agent P invaded to the accommodating chamber S1 is exhausted. After that the content C is filled in the accommodating chamber S1. In this case also, as described above, it is preferable to carry out it after contracting the inner container 12 using the guide member.

    [0287] Next, the use method of the discharge product 100 is shown. The use method is same as the discharge container 10 of FIG. 1, pushing down the push button 102 to open the valve mechanism 103, the content C can be discharged from the discharge hole 102b of the push button 102. After discharging the whole amount of the content C, the cap 18 of the valve assembly 101 is moved to the temporary fixed position, the seal structure of the inner seal material A2 is released, while maintaining the seal structure of the outer seal material A1 (the temporary fixing position of FIG. 23). Thereby, since the pressurizing chamber S2 and the housing 109 are communicated, by pushing down the stem 106 (or the push button 102), the pressurizing chamber S2 and atmospheric air can be communicated, the pressurizing agent P can be discharged from the stem 106. Finally, by detaching the cap 18 from the outer container 11, each can be sorted and discarded.

    [0288] The discharge container 110 of FIG. 24 is that in which a valve assembly 111 is provided with a valve cover 115, and the pressurizing chamber S2 and atmospheric air are communicated only by moving the cap 113 of the valve assembly 111 to the temporary fixed position. In detail, it comprises the outer container 11, the inner container 12 accommodated therein, and the valve assembly 111 closing the outer container 11 and the inner container 12, being fixed by engaging with the outer periphery of the outer container 11. The outer container 11 and the inner container 12 are substantially same as the discharge container 10 of FIG. 1, the content C is filled in the accommodating chamber S2 between the outer container 11 and the inner container 12, the pressurizing agent P is filled in the pressurizing chamber S2. To this valve assembly 111 also, the push button 102 etc. of the discharge container 100 of FIG. 21 is attached.

    [0289] In this discharge container 110 also, the pressurizing chamber S2 and atmospheric air can be communicated by moving the cap 113 of the valve assembly 111 to the temporary position upper than the fixed position, and by pushing down (switching operation) the stem 106 of the valve mechanism 103 (refer to FIG. 23).

    [0290] The valve assembly 111 has a valve unit 112 to which the valve mechanism 103 is fixed, closing the outer container 11 and the inner container 12, and a cylindrical cap 113 fixing the valve unit 112 to the outer container 11. The valve unit 112 of the valve assembly 111 is, as shown in FIG. 25A, provided with the valve mechanism 103, the cylindrical valve holder 104 in which the annular flange (the first flange portion of the sixth aspect of the present invention) 27 arranged in the upper end of the outer container 11 is formed, accommodating the valve mechanism 103, and a valve cover 115 in which the hem portion (the second flange portion of the sixth aspect of the present invention) 118 arranged above the annular flange 27, fixing the valve mechanism 103 to the valve holder 104 is provided. Between the annular flange 27 of the valve holder 104 and the hem portion 118 of the valve cover 115, the passage (the lateral passage groove 27a) extending outward radially is formed. The valve mechanism 103 and the valve holder 104 are substantially same as the discharge container 100 of FIG. 21. In addition, the plate seal material A3 compressed in the vertical direction (the axis of the outer container) is provided across the flange portion 12d through the annular flange portion 27 of the valve holder 104 and the flange portion 12a of the inner container 12 (refer to FIG. 24).

    [0291] The valve cover 115 is, as shown in FIG. 25B, provided with a canopy portion 116 closing the opening of the housing 109 of the valve holder 104, a cylindrical portion 117 extending downward from the edge portion thereof, arranged in the outer periphery of the housing 109, and an annular hem portion 118 extending outward radially from the lower end thereof.

    [0292] In the center of the canopy portion 116, a center hole 116a letting through the stem 106 of the valve mechanism 103 is formed.

    [0293] In the inner surface of the cylindrical portion 117, an engaging protrusion 117a to engage with the lower end of a step portion 109d of the housing 109 is formed. And, by the canopy portion 116 and the engaging protrusion 117a, the valve mechanism 103 is fixed to the valve holder 104, the valve unit 112 is integrated. In addition, the lower inner surface of the cylindrical portion 117 (inner surface lower than the engaging protrusion 117a) forms the annular gap G1 with the outer periphery surface of the housing 109, and is communicated with the lateral passage groove 27a (refer to FIG. 25A). The hem portion 118 is arranged so as to over the annular flange 27 of the valve holder 104 in the upper portion thereof. In other words, the hem portion 118 is arranged in the upper end of the outer container 11 through the annular flange 27. And, the valve cover 115 closes the outer container 11.

    [0294] Since the valve cover 115 as described above is provided, the passage between the hem portion 118 of the valve cover 115 and the annular flange 27 of the valve holder 104 is securely formed regardless of the attached state of the cap 113.

    [0295] The cap 113 of the valve assembly 111 is, as shown in FIG. 25C, provided with an upper cylindrical portion 121 covering the outer periphery surface of the cylindrical portion 117 of the valve cover 115, an annular connecting portion (pressing portion) 122 protruding outward radially from the lower end thereof, and a lower cylindrical portion 123 extending downward from the outer end thereof. The connecting portion (pressing portion) 122 is arranged on the hem portion 118 of the valve cover 115, and presses the whole of the valve unit 112.

    [0296] The upper end of the upper cylindrical portion 121 is made to be the same height as the upper end of the cylindrical portion 117 of the valve cover 115 (refer to FIG. 25A). Hence, the gap between the cap 113 and the valve cover 15 opens facing upward.

    [0297] In the inner surface of the lower cylindrical portion 123, a screw 123a engaging with the screw 11a of the outer container 11 is formed. And, in the position of the annular outer seal holding portion 11b of the outer container 11, being beneath the screw 123a, an inner cylindrical portion 123b of which the diameter is somewhat reduced than the thread of the screw 123a is formed. This inner cylindrical portion 123b compresses the outer seal material A1 across the outer cylindrical portion 11b1 of the outer container 11.

    [0298] Moreover, above the screw 123a, a plurality of support protrusions (temporary support portion) 123c engaging with the lower surface of the hem portion 118 of the valve cover 115 is annularly formed.

    [0299] It is preferable that the arranged position of the longitudinal passage groove 12c of the inner container 12 comes between the adjoining support protrusions 123b in a planar view. This support protrusion 123c is formed in the position where a gap between the upper surface of the hem portion 118 of the valve cover 115 and the lower surface of the connecting portion 122 (pressing portion) is formed, when engaging with the lower surface of the hem portion 118 of the valve cover 115. This support protrusion 123c does not contact with the lower surface of the hem portion 118 after the discharge container 110 is assembled (after the cap 113 is fixed to the outer container 11). By providing the support protrusion 123c, before attaching the valve assembly 111 to the outer container 11, the valve unit 112 can be held with the cap 113, the valve assembly 111 (the valve unit 112 and the cap 113) can be handled as one body.

    [0300] Further, by providing the support protrusion 123c, as later described, during filling the pressurizing agent (temporary fixing in the position upper than the fixed position), the valve unit 112 moving downward to the cap 113 by the filling pressure of the pressurizing agent can be supported, the later described pressurizing agent filling passage can be secured, and it can be prevented that the opening of the outer container 11 is closed by the fall down of the valve unit 112.

    [0301] Being composed as described above, as shown by the thick line of FIG. 25, a concentrate passage Z1 of the valve assembly 111 reaches to the stem 106 from the longitudinal passage 12c of the inner container 12 communicating with the accommodating chamber S1, through the gap G2 of the outside of the support flange 27, between the support flange (the first flange portion) 27 and the hem portion (the second flange) 118 (the lateral passage groove 27a), the gap G1 between the housing 109 and the valve cover 115, the first communicating hole 109a, and the inside of the housing 109.

    [0302] Stated differently, by pushing down the stem 106 of the valve mechanism 103, the stem rubber 107 bends, the inside of the housing 109 is communicated with the exterior, the concentration passage Z1 is opened. Hence, the concentration C pressurized by the pressurizing agent P in the inner container (the pressurizing chamber S2) is discharged from the stem 106 passing through the concentration passage Z1.

    [0303] Next, the use method of the discharge container 110 is shown. The use method is that, same as the discharge container 10 of FIG. 1, by pushing down the push button 102 to open the valve mechanism 103, the content C can be discharged from the discharge hole 102b of the push button.

    [0304] After discharging whole amount of the content C, same as the discharge container 100 of FIG. 21, the cap 113 of the valve assembly 111 is moved to the temporary fixed position, the seal structure of the inner seal material A2 is released, while maintaining the seal structure of the outer seal material A1. Thereby, since the pressurizing chamber S2 and atmospheric air are communicated, the pressurizing agent P can be exhausted from an annular opening between the valve cover 115 and the cap 113 (the reverse direction of the thick line of FIG. 26A). Similarly, in the end, by detaching the cap 113 from the outer container 1, each can be sorted and discarded.

    [0305] Next, an example of the filling method of the content C and the pressurizing agent P into the discharge container 110 (the manufacturing method of the discharge container) is described.

    [0306] First, a two-layer preform of the outer container 11 and the inner container 12 is prepared, the outer container 11 and the inner container 12 are simultaneously molded from the two-layer preform by biaxial stretch blow molding etc. (refer to FIG. 5A). In addition, the outer container 11 and the inner container 12 may be molded separately, and the inner container 12 is inserted into the outer container 12 while squeezing the inner container 12.

    [0307] Then, as shown in FIG. 26A, the outer container 11 is placed on a rotating table 126a. Meanwhile, a pressurizing agent filling machine 127 equipped with a pressurizing agent filling nozzle 127a is attached to the cap 113 of the valve assembly 111, the valve assembly 111 is arranged above the outer container 11. And, to the valve assembly 111 (pressurizing agent filling machine 127), the outer container 11 is rotated to fasten the cap 113, and the valve assembly 111 is held in the temporary fixed position upper than the fixed position. In other words, the cap 113 of the valve assembly 111 is not completely screwed to the outer container 11 to make the inner seal material A2 and the plate seal material A3 not exerting seal effect. In this moment, the pressurizing agent filling machine 127 holds the cap 113, and at the same time, is attached to the cap 113 so that a space PS between the cap 113 and the pressurizing agent filling machine 127 is sealed so that the pressuring agent P does not leak.

    [0308] In this temporary fixed state, the pressurizing agent P is supplied to the space PS from the pressurizing agent filling nozzle 127a. Thereby, the pressurizing agent P is filled inside the inner container 12 passing through a pressurizing agent filling passage PP from between the valve cover 115 and the cap 113. In detail, the pressurizing agent filling passage PP reaches from between the cylindrical portion 117 of the valve cover 115 and the upper cylindrical portion 121 of the cap 113 to between the hem portion 118 of the valve cover 115 and the connecting portion (pressing portion) 122 of the cap 113, the gap G2 outside of the annular flange 27 of the valve holder 104 between the mutual holding protrusion 123c, and between the annular flange 27 of the valve holder 104 and the flange portion 12b of the inner container 12 (the inner seal material A2). In this moment, the valve unit 112 descends somewhat to the cap 113 by the filling pressure of the pressurizing agent P, and is supported to the engaging protrusion 123c of the cap 113. Hence, the gap between the upper surface of the hem portion 118 of the valve cover 115 and the lower surface of the connecting portion 122 of the cap 113 (pressing portion) can be secured largely. Moreover, even if the filling pressure of the pressurizing agent P is applied to the valve unit 112, the opening of the outer container 11 is never closed by the valve holder 104 etc.

    [0309] And, during the pressurizing agent filling, since the outer seal material A1 seals between the lower portion of the cap 113 and the outer container 11, the pressurizing agent P does not leak to the exterior from the lower end of the cap 113.

    [0310] In addition, the cap 113 is covered by the pressurizing agent filling machine 127, whole of the cap 113 may be accommodated in the sealed space PS (for example, as the imaginary line, the lower end of the pressurizing agent filling machine 127 is sealed with the shoulder portion of the outer container 11). In this case, even in the state that the outer seal material A1 is omitted, or the outer seal material A1 does not seal between the lower portion of the cap 113 and the outer container 11, the pressurizing agent P can be filled.

    [0311] After filling the pressurizing agent P, the outer container 11 is further rotated to fix the valve assembly 111 to the outer container 11. Thereby, the inner seal material A2 and the plate seal material A3 are compressed to seal the inside of the inner container 12.

    [0312] After filling the pressurizing agent P, when the supply of the pressurizing agent P from the pressurizing agent filling machine 127a is stopped, the pressure inside the inner container 12 and the space PS becomes substantially equilibrium. Hence, when the outer container 11 is rotated and the cap 113 is descended to the outer container 11, the valve unit 112 and the outer container 11 (the inner container 12) are integrated by the plate seal material A3, the valve unit slides 112 against the cap 113. Thereby, the position between the lateral passage groove 27a of the valve unit 112 and the lateral passage groove 12c between the outer container 11 and the inner container 12 is hard to be misaligned. Further, the displacement, torsion, cutoff of the inner seal material A2 between the outer container 11 and the valve unit 112 can be prevented.

    [0313] In addition, without providing the inner seal material A2, the flange portion 12a may be made to be a substitute by compressing the flange portion 12a of the inner container 12. Moreover, the plate seal material A3 may be omitted.

    [0314] After that, the stem 106 is pushed down to exhaust a small amount of pressurizing agent P and air invaded into the accommodating chamber S1 (the space between the outer container 11 and the inner container 12). Finally, the content C is filled inside the accommodating chamber S1 from the stem 106 while contracting the inner container 12, the production of the discharge product is completed. Here, the outer container 11 is rotated to screw with the valve assembly 111, but the cap 113 may be rotated so as to fix the valve assembly 111. However, since the valve assembly 111 is connected to the pressurizing agent filling machine 127, it is preferable to rotate the outer container 11, because the equipment does not become complicated.

    [0315] As another example of filling method of the pressurizing agent (manufacturing method of discharge product) to the discharge container 110, when the valve assembly 111 is held in the temporary fixed position upper than the fixed position to the outer container 11, as shown in FIG. 26B, the outer seal material A1 is positioned lower than the lower end of the cap 113 to make the seal between the cap 113 and the outer container 11 not formed, the pressurizing agent filling machine 127 and the shoulder of the outer container 11 are sealed with a seal material 127c, the pressurizing agent P may be filled from the pressurizing agent filling nozzle 127a arranged near the lower end of the cap 113 through a pressurizing agent filling passage PP2. The pressurizing agent filling passage PP2 reaches from between the outer container 11 and the cap 113 to between the annular flange 27 of the valve holder 104 and the flange portion 12b of the inner container 12 (the inner seal material A2).

    [0316] In the case of this filling method, since the valve unit 112 (the valve cover 115) moves upward by the filling pressure of the pressurizing agent, the hem portion 118 contacts the inner surface of the connecting portion 122 of the cap 113, the pressurizing agent filling passage can be formed between the outer container 11 and the valve unit 112, the pressurizing agent can be filled safely. Hence, the engaging protrusion 123c of the cap 113 may be omitted. Moreover, even the cap 113 is rotated for fixing to the outer container 11, since the valve unit 112 and the outer container 11 (the inner container 12) are integrated by the plate seal material A3, and the valve unit 112 slides with the cap 113 and does not rotate against the outer container 11, the position of the lateral passage groove 27a of the valve unit 112 and the position of the longitudinal passage groove 12c between the outer container 11 and the inner container 12 is hard to become misalignment, and the displacement, torsion, cutoff of the inner seal A2 between the outer container 11 and the valve unit 112 can be prevented. When adopting this filling method, the cap 113 is fixed, and rotating the outer container 11, the cap 113 may be fixed to the outer container 11. Moreover, the filling from the both sides; the filling from between the cylindrical portion 117 of the valve cover 115 and the upper cylindrical portion 121 of the cap 113 (filling from the upper part, the passage PP of FIG. 26A); the filling from the lower end of the cap 113 (filling from the lower part), may be carried out.

    [0317] Further, in the case that this filling method is adopted, the outer seal material A1 and the inner seal material A2 may be arranged so that the cap 113 does not have the temporary fixed position. In other words, it is sufficient that when the outer seal material A1 and the inner seal material A2 make the cap 113 descend to the outer container 11, the seal structure is formed simultaneously.

    [0318] The discharge container 130 of FIG. 27A is that in which the valve assembly and the outer container are fitted with a clip, not by screw type. Moreover, it is the two-fluid discharge type discharge container in which a pouch is accommodated in the inner container, two concentrates are accommodated therein, and are discharged simultaneously.

    [0319] The discharge container 130 is provided with a bottomed outer container 131 and the inner container 12 accommodated in the outer container, an innermost container 132 accommodated in the inner container 12, and a valve assembly 133 closing the inner container 12 and the innermost container 132. The valve assembly 133 has a valve unit 135 closing the outer container 131 and the inner container 12 and the innermost container 132, to which the valve mechanism 16 is fixed, and a cylindrical cap 136 which fixes the valve unit 135 to the outer container 131. And, a first concentrate C1 is accommodated in the space (the first accommodating chamber S1) between the outer container 131 and the inner container 12 of the discharge container 130, a second concentrate C2 is accommodated in the innermost container 42 (the second accommodating chamber S3), the pressurizing agent P is filled in the inner container 12 (pressurizing chamber S2), the two-fluid discharge type discharge product is produced. The inner container 12 is substantially same as the inner container 12 of the discharge container 10 of FIG. 1.

    [0320] In the outer container 131, as shown in FIG. 27B, a first annular protrusion 131a is formed in the outer periphery of the neck portion. In the first annular protrusion 131a, an upper surface 131b is made to be a taper like surface expanded in diameter facing downward, a lower surface 131c is made to be a horizontal surface (perpendicular to the axis of the outer container 131). In this embodiment, two first annular protrusions 131a are provided, but it may be also one and more than three. Another composition is substantially same as the outer container 11 of the discharge container 10 of FIG. 1, an annular protrusion 11b2 and an outer cylindrical portion 11b1 are formed in the neck portion.

    [0321] The innermost container 132 is, as shown in FIG. 27A, provided with a pouch 132a whose lower end is closed, and a connecting member 132b fixed to the upper end opening thereof. The pouch 132a is that in which a plurality of sheets is welded or bonded together. As the sheet, synthetic resin sheet such as polyethylene, polyethylene terephthalate, nylon, eval, vapor deposition resin sheet in which silica, alumina are evaporated on the synthetic resin sheet, and that in which synthetic resin sheet etc. is laminated on a metal sheet such as aluminum foil are used. The connecting member 132b is that which is cylindrical, pasted on the opening of the pouch 132a, and is connected to the later described valve assembly 133. As the connecting member 132b, that in which synthetic resin such as polyethylene is injection-molded is used.

    [0322] The valve unit 135 of the valve assembly 133 is, as shown in FIG. 28, provided with the two-fluid type valve mechanism 16, the cylindrical valve holder 17 in which the annular flange (the first flange portion) 27 arranged in the upper end of the outer container 131 is formed, and the valve cover 115 in which the hem portion 118 (the second flange portion of the sixth aspect of the present invention) arranged above the annular flange (the first flange portion of the sixth aspect of the present invention) 27 fixing the valve mechanism 16 to the valve holder 17, being provided in the upper portion thereof is provided. The valve mechanism 16 and the valve holder 17 are substantially same as those of the discharge container 10 of FIG. 1. The valve cover 115 is substantially same as those of the discharge container 110 of FIG. 24.

    [0323] The cap 136 is, as shown in FIG. 28, has one or a plurality of second annular protrusions 136a engaging with a first annular protrusion 131a of the container body 131 in the inner surface of the lower cylindrical portion 123. A lower surface 136b of a second annular protrusion 136a is made to be a tapered surface expanded in diameter downward, an upper surface 136c is made to be a horizontal surface. Another composition is substantially same as the cap 113 of the discharge container 110 of FIG. 24, and it has the upper cylindrical portion 121, the connecting portion (pressing portion) 122 and the lower cylindrical portion 123.

    [0324] Being composed as described above, as shown in FIG. 29A, the first passage Z1 of the valve assembly 133 reaches from the longitudinal passage groove 12c of the inner container 12, to the gap G2 outside of the annular flange 27, between the annular flange 27 and the hem portion 118 (the lateral passage groove 27a), the gap G1 between the housing 26 and the valve cover 115, the first communicating hole 26a, the upper space of the housing 26 (between the first stem rubber 27a and the second stem rubber 27b), and the cylindrical hole of the first intra-stem passage 21a of the stem 21. Meanwhile, the second concentrate passage Z2 of the valve assembly 133 reaches to the second communicating hole 26b, the lower space of the housing 26 (the space lower than the second stem rubber 27b), and the center hole of the second intra-stem passage 21b of the stem 21. In other words, by pushing down the stem 21 of the valve mechanism 16, the first content C1 and the second content C2 are discharged from the stem 21 to the exterior through the first concentrate passage Z1 and the second concentrate passage Z2.

    [0325] Next, the filling method of concentrate and the pressurizing agent in the discharge container 130 (manufacturing method of discharge product) is described. First, the outer container 131 and the inner container 12 are molded same as the discharge container 10 of FIG. 1.

    [0326] Then, the innermost container 132 in which the second concentrate C2 is filled is connected to the cylindrical portion 26g of the housing 26 of the valve assembly 133. The cap 136 of the valve assembly 133 to which the innermost container 132 is connected is attached to the pressurizing agent filling machine 127 (refer to FIG. 29B) equipped with the pressurizing agent filling nozzle 127a, the valve assembly 133 is arranged above the outer container 131.

    [0327] After that, the valve assembly 133 is descended to the outer container 131, as shown in FIG. 29B, the taper like upper surface 131b of the first annular protrusion 131a of the outer container 131 and the taper like lower surface 136b of the second annular protrusion 136a are made to contact, the cap 136 is held upper than the fixed position to the outer container 131. In this temporary fixed state, same as the discharge container 110 of FIG. 24, the pressurizing agent P is filled from between the valve cover 17 and the cap 113 (the pressurizing agent filling passage PP). In this moment, since the outer seal material A1 seals between the lower portion of the cap 136 and the outer container 131, the pressurizing agent P does not leak to the exterior from the lower end of the cap 136. And, since the valve unit 135 is held by the support protrusion 123c, even if the filling pressure of the pressurizing agent P is applied, the valve unit 135 never closes the opening of the outer container 131, the pressurizing agent passage PP is secured.

    [0328] After filling the pressurizing agent P, the valve assembly 133 are further descended. In other words, the second annular protrusion 136a of the valve assembly 133 is made to override the first annular protrusion 131a, the upper surface 136c of the second annular protrusion 136a and the lower surface 131c of the first annular protrusion 131a are made to engage, making it to be a fixed state (refer to FIG. 27).

    [0329] After fixing the outer container 131 and the valve assembly 133, the first accommodating chamber S1 is deaired, the first concentrate C1 is filled from the stem 21 through the first concentrate passage Z1. In addition, the empty innermost container 132 is connected to the valve assembly 133, after filling the pressurizing agent P between (pressurizing chamber S2) the inner container 12 and the innermost container 132 in first, it may be filled through the second concentrate passage Z2 from the stem 21.

    [0330] In addition, in this discharge container 130 also, as another filling method of the pressurizing agent, same as the discharge container 110 of FIG. 24, by composing so that the outer seal A1 is not formed in the temporary fixed state as FIG. 26B, the pressurizing agent P may be filled from the lower end of the cap 136 (the tenth aspect of the present invention). Moreover, a slit may be provided in the first annular protrusion 131a of the outer container 131 of the discharge container 130 and the second annular protrusion 136a of the cap 136 so as to make each other let through. In other words, it is sufficient that between the adjoining first annular protrusions 131a, the second annular protrusion 136a can pass through. Forming the slit as described above, after discharging whole amount of the content (after use), by rotating the cap 136 to ascend the cap 136 up to the temporary fixed position, the pressuring chamber S2 is communicated with atmospheric air, the pressurizing agent P can be discharged from the opening of the upper end of the cap 136 and the valve cover 115.

    [0331] In the discharge container 130 also, the content and the pressurizing agent may be filled after the inner container becomes accustomed to be contracted uniformly by the insertion of the guide member into the inner container 12. Further, as the discharge container 140 shown in FIG. 30, a connecting portion 141b of an innermost container 141 is extended to the vicinity of the bottom portion of a pouch 141a, it may be made to be a guide member concurrently serving as a dip tube. Another composition is substantially same as the discharge container 130 of FIG. 27.

    [0332] The discharge product using the discharge container 140 is manufactured as described below.

    [0333] First, into the outer container 11 and the inner container 12 molded by blowing, the innermost container 141 attached to the valve assembly 133 (the pouch 141a and the connecting member 141b) is inserted (FIG. 31A). In this moment, the valve assembly 133 is made to be in a state of being suspended. In other words, the outer seal material A1 the inner seal material A2, and the plate seal material A3 are not exerted.

    [0334] Next, a gas for contraction is filled in the first accommodating chamber S1 between the outer container 11 and the inner container 12 to contract the inner container 12. In this moment, the pouch 141a and the connecting member (tube) 141b functions as a guide member, the inner container 12 contracts/deforms along the outer surface of the pouch 141a (refer to FIG. 31B). In addition, when contracting the inner container 12, if air etc. is filled inside the pouch 141a, since the shape of contract and the size of the inner container can be adjusted, it is also possible to contract the inner container 12, while exhausting the air inside the pouch 141a.

    [0335] And, the pressurizing agent P is filled in the inner container from the lower end of the cap 136 through the gap between the inner container 12 and the housing 26, at the same time as the completion of filling, the valve assembly 133 is perfectly screwed to the outer container 11 and sealed (what is called undercup filling: FIG. 31C).

    [0336] After that, the first concentrate C1 is filled in the first accommodating chamber S1 through the first intra-stem passage 21a of the stem 21. Further, the second concentrate C2 is filled in the pouch 24 through the second intra-stem passage 21b and a hollow portion 141c of the connecting member 141b and a communicating hole 141d (FIG. 30 and FIG. 31D). And, by attaching a spray member 145 to the stem 21, the manufacture of the discharge product is completed. In addition, the spray member 145 is composed so that any of the first intra-stem passage 21a of the stem 21, the second intra-stem passage 21b of the stem 21 is not closed, by pushing down the spray member 145, both of the first concentrate C1 in the first accommodating chamber S1 and the second concentrate C2 in the pouch 24 are made to be discharged from the spray member 145. Moreover, it may be made so that each is discharged independently.

    [0337] In addition, here, the innermost container 142 of the pouch is cited, but it may be formed from a preform of more than triple (multiple preform).

    [0338] The discharge container 150 of FIG. 32 is that which is provided with a pressure adjusting mechanism 151 adjusting the inner pressure of the inner container 12. In detail, it is provided with the outer container 11, the inner container 12 accommodated therein, a valve assembly 101a closing the outer container 11 and the inner container 12, being fixed by engaging with the outer periphery of the outer container, and a pressure adjusting mechanism 151 adjusting the inner pressure of the inner container 12. The outer container 11 and the inner container 12 are substantially same as those of the discharge container 100 of FIG. 21, the content C is filled in the accommodating chamber S1 between the outer container 11 and the inner container 12, the pressurizing agent P is filled in the pressurizing chamber S2. The valve assembly 101a is substantially same as the valve assembly 101 of FIG. 21 other than that, as shown in FIG. 33, a cylindrical cylinder portion 152 is integrally formed in the lower end (the lower end of the plug portion 28) of the housing 109, and it has the valve mechanism 103, the valve holder 104, and the cap 18. In this discharge container 100, by moving the cap 18 of the valve assembly 101a to the temporary position upper than the fixed position, and pushing down (switching operation) the stem 106 of the valve mechanism 103, the pressurizing chamber S2 and atmospheric air can be communicated (refer to FIG. 37A).

    [0339] The pressure adjusting mechanism 151 is, as shown in FIG. 34A, provided with a cylinder portion 152 described above, a piston 153 accommodated inside the cylinder portion 152, an aerosol container (gas container) 154 in which high pressure gas is filled, being inserted into the lower end of the cylinder portion 152, and a container holder 155 hanged from the opening of the inner container. In addition, in the pressure adjusting mechanism 151, a space inside the cylinder potion 152 surrounded by the lower surface of the housing 109 and the piston 153 serves as the reference pressure chamber SP, the inside of the aerosol container 154 serves as the high pressure chamber HP, and the valve of the aerosol container 154 serves as a valve.

    [0340] The cylinder portion 152 extends further downward from the lower end of the plug portion 33. In the lower portion of the cylinder portion 152, a slit 152a going upward from the lower end is formed. Moreover, in the lower end, a holding claw 152b which holds the piston 153 so that the piston 153 of the later described pressure adjusting mechanism 151 does not fall before the valve assembly 101a is attached to the outer container 11 is formed. Stated differently, the pressure adjusting mechanism 151 is fixed to the lower end of the valve assembly 101a through the cylinder portion 152, and is hanged inside from the opening of the inner container 12. The piston 153 moves up and down contacting tightly the inner surface of the cylinder portion 152. In other words, the piston 153 seals the pressurizing chamber S2 and at the same time, seals the reference pressure chamber SP.

    [0341] And, by the up and down motion of the piston 153, the reference pressure chamber SP is compressed/expanded. In addition, by the inside of the reference pressure chamber SP being compressed, the air inside is compressed, and the piston 153 receives a reaction force.

    [0342] The aerosol container 154 comprises a pressure resistant container 154a, an aerosol valve 154b closing the opening thereof, and a push button 154c attached to a stem 154b1 of the aerosol valve 154b.

    [0343] By pushing down the push button 154c to descend the stem 154b1, the aerosol valve 154b is opened, the pressurizing agent P in the pressure resistant container 154a is sprayed from a discharge port 154c1 of the push button 154c. The aerosol container 154 may be fixed to the cylinder portion 152 by engaging the holding claw 152b of the cylinder portion 152 with an annular recessed portion 154d formed in the outer periphery of the aerosol valve 154b. In this moment, the piston 153 is arranged on the push button 154c of the aerosol container 154. In addition, the push button 154c is not necessary to be provided as long as it is composed so that the stem 154b1 and the piston 153 are made to be interlocked.

    [0344] The container holder 155 makes it easy to engage the valve assembly 101a with the cylinder portion 152 by stabilizing the position of the aerosol container 154, when the valve assembly 101a is attached to the outer container 11. After attaching the valve assembly 101a also, it holds the aerosol container 154 to make it easy for the piston 153 and the push button to operate. In detail, it comprises a cylindrical holder body 155a, a flange 155b formed on the upper end thereof, and a bottom portion 155c closing the lower end thereof. The inner upper surface of the holder boy 155a is made to be a cylinder, and is a portion to compress the inner container 12 radially. In the lower portion of the holder body 155a, a slit 155d communicating between the holder body 155a and the inner container 12 is formed. And, in the lower inner surface of the holder body 155a, a positioning rib 155e for positioning the aerosol container 154 is formed aligned radially. The container holder 155 is held by being clamped between the upper end (the flange portion of the inner container 12) of the outer container 11 and the annular flange 27 of the valve holder 17 of the valve assembly 101a. Moreover, the lower surface of the flange portion 155b is a portion to compress the annular plate seal material A3 downward.

    [0345] The pressure adjusting mechanism 151 composed as described above operates according to the difference of the pressure of the reference pressure chamber SP and the pressure of the inner container 12 (pressurizing chamber S2). In detail, as shown in FIG. 34B, when the pressure of the reference pressure chamber SP becomes larger than the pressure of the inner container 12, the piston 153 moves so as to expand, in other words, the piston 153 descends. In this moment, the inner pressure of the reference chamber SP decreases. Hence, the push button 154c of the aerosol container 154 is pushed, the pressurizing agent P is supplied to the inside of the inner container 12 from the aerosol container 154. And, when the pressurizing agent P is sufficiently supplied in the inner container 12, substantially equalizing the pressure of the reference pressure chamber SP and the pressure of the inner container 12, the piston 153 moves to the original position so as to contract the reference pressure chamber SP by the spring force of the aerosol valve, in other words, the piston 153 ascends. Hence, the push button 154c of the aerosol container 154 turns back, and the aerosol valve 154b is also shut off.

    [0346] In addition, a spring to press the piston 153 downward may be set in the cylinder 152. Moreover, in place of the piston, a pressure-position transducer such as a diaphragm may be used.

    [0347] Next, the assembling method of the discharge container 150 is shown. First, a double container (double bottle) consisting of the outer container 11 and the inner container 12 is molded. In this moment, it is preferable that the inner container 12 is once previously contracted with the guide member etc. so that the concentrate chamber S1 is securely formed when the content C is filled. Then, the container holder 155 in which the aerosol container 154 is accommodated is housed inside the inner container 12. Meanwhile, the cap 18 is fixed to the valve holder 17, and a lid member in which the piston 153 is inserted into the cylinder portion 152 of the valve holder 17 is prepared (refer to FIG. 35A). This lid member is fixed to the double container. In this moment, the aerosol container 154 is connected to the cylinder portion 152, and at the same time, the push button 154c of the aerosol container 154 pushes up the piston 153, the reference pressure chamber SP is sealed and compressed. However, since the pressurizing agent P is not still filled in the inner container 12, the piston 153 does not ascend higher than the height where the aerosol valve 154b of the aerosol container 154 is opened (the state that the push button 154 is somewhat pushed down). Stated differently, as shown in FIG. 35B, the aerosol valve 154b becomes an opened state, the pressurizing agent P is sprayed from the push button 152c of the aerosol container 154, and supplied to the inside of the inner container 12 through the slit 152a of the cylinder portion 152 and the slit 155d of the container holder 155. When the inside of the inner container 12 reaches a predetermined pressure, the piston 153 is pushed up to the height where aerosol valve 154b is closed, the pressure of the reference pressure chamber SP and the pressure of the inner container 12 substantially balance, the spray of the aerosol container 154 stops (refer to FIG. 33).

    [0348] As described above, in the discharge container 150, the pressurizing agent P can be filled inside the inner container 12 only by assembling, and a special filling facility of the pressurizing agent is not necessary. Moreover, after assembling the discharge container 150, as later described, the inner pressure of the inner container 12 can be controlled to be constant.

    [0349] In addition, the filling of the content C in the accommodating chamber S1 may be carried out before the valve assembly 101a is fixed to the double container, and also it may be filled from the stem 106 after fixing to the double container, opening the valve mechanism 103. Particularly, in the case that it is carried out before the valve assembly 101a is fixed, the double container (the outer container 11 and the inner container 12), the aerosol container 154, and the container holder 155 can be made to be a refill product. When making it to be the refill product, for, example, it is preferable to seal by a lid member 156, as shown in FIG. 37C. Thereby, the valve assembly 110a etc. can be reused. Moreover, it is possible to replace the aerosol container 154 only.

    [0350] Next, the use method of the discharge container is shown. The use method is that, as shown in FIG. 36A, by the push button etc. (not shown in the figure), the stem 106 is pushed down to open the valve mechanism 103, the content C can be discharged by the pressure of the inner container 12. By the discharge of the content C, the inner container 12 expands, decreasing the inner pressure of the inner container 12, making the pressure adjusting mechanism 151 operate automatically as shown in FIG. 36B. The pressurizing agent P is supplied to the inside of the inner container 12 from the aerosol container 154, when the pressure inside the inner container comes into balance with that of the reference pressure chamber SP, the supply of the pressurizing agent P stops automatically. Every time the content C is discharged, since this supply process and supply stop process of the pressurizing agent P is carried out automatically, the content C can be discharged at the same momentum to the last.

    [0351] After discharging the content C, as shown in FIG. 37A, the cap 18 is rotated to ascend the lid member (the pressure adjusting mechanism 151 excepting the container holder 155) to the double container (the outer container 11 and the inner container 12) and the container holder 155. In detail, while maintaining the seal structure of the outer seal material A1, the lid member is made to ascend so that the inner seal material A2 held by the inner seal holder 28a of the valve holder 17 comes off from the inner surface of the holder body 155a of the container holder 155. Thereby, the seal by the inner seal material A2 is released, the pressurizing chamber S2 and the inside of the housing 109 of the valve assembly 101a is communicated. Hence, it is possible to induce the pressurizing agent P of the pressurizing chamber S2 into the housing 109 without discharging to the exterior. After that, by pushing down the stem 106 by push button etc. the pressurizing agent P can be discharged to the exterior safely (refer to the thick arrow of FIG. 37A). In this moment, since the inner pressure of the pressurizing chamber S2 becomes lower than the inner pressure of the reference pressure chamber SP, the piston 153 descends, and the aerosol container 154 is also opened. Hence, the pressurizing agent P inside the gas container (the aerosol container 154) can be exhausted to the last. In addition, when the aerosol container 154 is not fixed to the holding claw 152a of the cylinder portion 152, as shown in FIG. 37B, the aerosol container 154 is supported to the bottom portion 155c of the container holder 155.

    [0352] Moreover, the piston 153 descends and goes across the slit 152a. Hence, the reference pressure chamber SP and the pressurizing chamber S2 are communicated, the pressuring chamber S2 can be exhausted without exhausting the pressurizing agent P of the aerosol container 154 (refer to the thick arrow of FIG. 37B). In this case, the aerosol container 154 can be reused.

    [0353] The discharge container 150a of FIG. 38 is different to the discharge container 150 of FIG. 32 in the point that the container holder is omitted, and the aerosol container 154 is placed in the bottom portion of the inner container 12. In detail, it is provided with the outer container 11, the inner container 12 accommodated therein, the valve assembly 101a closing the outer container 11 and the inner container 12, and the pressure adjusting mechanism 151a to adjust the inner pressure of the inner container, being accommodated in the inner container. The pressure adjusting mechanism 151a is attached to the lower end of the valve assembly 13. The outer container 11 and the inner container 12 are substantially same as the discharge container 100 of FIG. 21, the content C is filled in the accommodating chamber S1 between the outer container 11 and the inner container 12, the pressurizing agent P is filled in the pressurizing chamber S2 inside the inner container. The valve assembly 101a is substantially same other than that the cylinder portion 152 is made to be longer than the cylinder portion 152 of the valve assembly 101a of the discharge container 150 of FIG. 32. In addition, the length of the cylinder portion 152 of FIG. 38 may be made to be same as that of the cylinder portion 152 of FIG. 32, the pressure resistant container of the aerosol container 154 may be lengthened. The inner seal material A2 held in the inner seal holding portion 28a of the plug portion 28 of the valve assembly 101a is compressed between the bottom potion of the inner seal holding portion 28a and the inner cylindrical portion 12a of the inner container 12, and seals between the pressurizing chamber S2 and the valve assembly 101a.

    [0354] The pressure adjusting mechanism 151a is provided with the above described cylinder portion 152, the piston 153 accommodated inside the cylinder portion 34, and the aerosol container (gas container) 154 in which a high pressure gas is filled, being inserted into the lower end of the cylinder portion 153, the aerosol container 154 being placed in the bottom portion of the inner container 12. The piston 153 and the aerosol container (gas container) 154 are substantially same as the pressure adjusting mechanism 151 of FIG. 32. And, in the pressure adjusting mechanism 151a, the space inside the cylinder portion 152 serves as the reference pressure chamber SP, the inside of the aerosol container 154 serves as the high pressure chamber HP, the valve of the aerosol valve 154 serves as a valve. This pressure adjusting mechanism 151a also, same as the pressure adjusting mechanism 151 of the discharge container of FIG. 32, operates according to the pressure difference of the pressure of the reference pressure chamber SP and the pressure of the inner container 12 (the pressurizing chamber S2). In order to place the aerosol container 154 in the inner container 12, as later described, the aerosol container 154 is placed in the inner container 12, and after that, by attaching the valve assembly 101a, it can be assembled. In this occasion, the cylinder portion 152 and the aerosol container 154 are easy to be connected.

    [0355] The assembling method of the discharge container 150a is shown below.

    [0356] First, a double container consisting of the outer container 11 and the inner container 12 is molded. Then, the aerosol container 154 is housed inside the inner container 12. Meanwhile, the cap 18 is fixed to the valve holder 17, and a lid member in which the piston 153 is inserted into the cylinder portion 152 of the valve holder 17 is prepared (refer to FIG. 39A). This lid member is fixed to the double container. In this moment, the aerosol container 154 is connected to the cylinder portion 152, and at the same time, the push button 154c of the aerosol container 154 pushes up the piston 153, the reference pressure chamber SP is sealed and compressed (refer to FIG. 39B). Same as the discharge container 150 of FIG. 32, the aerosol valve 154b of the aerosol container 154 opens at the same time, the pressurizing agent P is supplied to the inside of the inner container 12 from the push button 154c of the aerosol container 154. When the inside of the inner container 12 reaches a predetermined pressure, the piston 153 is pushed up to the height where the aerosol valve 154b closes, the pressure of the reference pressure chamber SP and the pressure in the inner container 12 substantially balance, the spray of the aerosol container 154 stops.

    [0357] In this discharge container 150a also, as described above, same as the discharge container 150 of FIG. 1, the pressurizing agent P can be filled inside the inner container 12 by only assembling, making a special filling facility unnecessary. Moreover, after assembling the discharge container 150a, as later described, the inner pressure of the inner container 12 can be controlled to be constant. In addition, the filling of the content C in the concentrate chamber S1 may be carried out either before and after the fixing of the valve assembly 101a to the double container. In this discharge container 150a also, the outer container 11, the inner container 12, the aerosol container 154, and the content C filled in the concentrate chamber S1 can be made to be a refill product. In the case that it is made to be refill product, same as the discharge container 150 of FIG. 32, it is preferable to seal with the lid member 156 as shown in FIG. 36.

    [0358] In addition, in the discharge container 150a of FIG. 38, the aerosol container 154 is placed in the bottom portion of the inner container 12, but it may be hanged in the inner container 12 without being supported by the bottom portion of the aerosol container 154.

    [0359] The discharge container 160 of FIG. 40 is that in which a check valve for concentrate which shuts off a fluid going to the accommodating chamber S1 from the exterior and let through the fluid going to the exterior is provided in the discharge passage between the accommodating chamber S1 and atmospheric air. In detail, it is provided with the outer container 11, the inner container 12 accommodated in the outer container 11, and a valve assembly 161 closing the outer container 11 and the inner container 12, in which the above described check valve for concentrate is provided. The outer container 11 and the inner container 12 are substantially same as those of the discharge container 100 of FIG. 21, the content C is filled in the accommodating chamber S1 between the outer container 11 and the inner container 12, the pressurizing agent P is filled in the pressurizing chamber S2 inside the inner container. The valve assembly 161 has the concentrate passage Z1 (refer to FIG. 42A) which communicates the accommodating chamber S1 and the exterior, and the gas passage Z2 (refer to FIG. 42B) which communicates the pressurizing chamber S2 and the exterior. And, in the concentrate passage Z1, a check valve 163 for concentrate which shuts off the fluid going to the accommodating chamber S1 from the exterior, and let through the fluid going to the exterior from the accommodating chamber S1 is provided. In the gas passage Z2, a check valve 164 for gas which shuts off the gas going to the exterior from the pressurizing chamber S2, and let through the gas going to the pressurizing chamber S2 from the exterior is provided.

    [0360] The valve assembly 161 is, as shown in FIG. 41A, has a valve holder 165 arranged so as to close the opening of the outer container 11 and the inner container 12, having a first communicating hole 165a (the concentrate passage Z1) communicating the exterior and the accommodating chamber S1, and a second communicating hole 165b communicating the exterior and the pressurizing chamber S2, the valve mechanism 103 accommodated in the valve holder 17, an annular moving valve 166 (the check valve 163 for concentrate) opening/closing the concentrate passage Z1, an elastic valve 167 (the check valve 164 for gas) opening/closing the gas passage Z2 (the son communicating hole 165b), and a cap 168 which holds the valve mechanism 106 in the valve holder 165, and fixes the valve holder 165 to the outer container 11. The valve mechanism 106 is substantially same as the discharge container 100 of FIG. 21.

    [0361] The valve holder 165 is, as shown in FIG. 41B, is provided with a cylindrical valve housing 171 in which a first communicating hole 165a is formed in the side surface, a second communicating hole 165b is formed in the side surface lower than the first communicating hole 165a, and an annular support flange 172 provided in the outer periphery of the valve housing 171 so as to protrude outward radially.

    [0362] The valve holder 165 is molded by injection molding etc. from synthetic resin such as polypropylene, polyacetal, polyethylene terephthalate.

    [0363] The valve housing 171 comprises a cylindrical housing body 173 in which the valve mechanism 106 is accommodated, and a cylindrical gas supply portion 174 protruding downward so as to communicate with the housing body 173.

    [0364] The housing body 173 has a rubber holding portion 173a supporting the stem rubber 107 of the valve mechanism 106 provided in the upper end thereof, a plurality of the first communicating holes 165a provided radially in the side surface at an equal interval, an annular bottom portion 173b provided beneath the first communicating hole 165a. Moreover, in the upper outer periphery spaced upper than the first communicating hole 165a, an annular engaging groove 173c engaging with the cap 168 is formed. The first communicating hole 165a is provided more than two, for example, 2-8. The gas supply portion 174 is a cylindrical body in which the second communicating hole 165b is provided, and is a portion to which the elastic valve 167 is attached, and communicates with the annular bottom portion 173b of the valve holding portion 174. In detail, the outer shape is that in which a large diameter portion 174a, a medium diameter portion 174b, a small diameter portion 174c are provided coaxially beginning at the top. The lower portion of the small diameter portion 174c is closed, and the second communicating hole 165b is formed in the side surface thereof. By forming the outer shape with a plurality of step portions as the large diameter portion 174a, the medium diameter portion 174b, the small diameter portion 174c, the falling off of the elastic body 167 is prevented. The outer surface of the gas supply portion 174 (for example, the outer surface of the medium diameter portion 174b and the lower surface of the large diameter portion 174a) and the inner surface of the elastic valve 167 (for example, the medium diameter portion 167b and flange portion 167c) may be adhered by an adhesive etc. so that the second communicating hole 165b opens to the fluid going to the pressurizing chamber S2 from the gas supply portion 174.

    [0365] The support flange 172 is provided with a cylindrical valve guide portion 172a extending downward from the first communicating hole 165a of the valve housing, and an annular flange portion 172b extending outward radially from the lower end thereof, and a cylindrical seal material holding portion 172c extending downward from the central lower surface of the flange portion 172b.

    [0366] The moving valve 166 is arranged in the outer periphery of the valve guide portion 172a. The moving valve 166 moves vertically in the outer periphery of the valve guide portion 172a. Moreover, in the lower end inner surface of the valve guide portion 172a, an annular engaging protrusion 172a1 engaging with the tip of the flange portion 167c of the later described elastic valve 167 is provided.

    [0367] In the upper surface of the flange portion 172b, a plurality of the lateral passage grooves 27a is provided radially at an equal interval. The number of this lateral passage grooves 27a is made to be the same as that of the longitudinal passage groove 12c of the inner container 12, and it is positioned at the same angle with the longitudinal passage groove 12c at planar view. Thereby, the lateral passage grooves 27a and the outer end side of the flange portion 172b compose a part of the above described concentrate passage Z1, and are communicated with the longitudinal passage groove 12c of the inner container 12 (refer to FIG. 42).

    [0368] Moreover, the flange portion 172b is composed so that the outer diameter is made to be somewhat smaller than the outer diameter of the flange portion 12b of the inner container 12 (refer to FIG. 40). Thereby, the gap G2 is made to be formed in the outer periphery of the flange portion 172b, and is easy to be communicated with the lateral passage grooves 27a.

    [0369] However, it may be substantially same as the outer diameter of the flange portion 12b of the inner container 12. In this case, the inner surface diameter of the cap 168 is adjusted so that the gap G2 is formed in the outer periphery of the flange portion 12b.

    [0370] And, a seal locking portion 172d protruding downward is formed in the outside of the seal material support portion 172c, being the lower surface of the flange portion 172b.

    [0371] A ring like seal material A2 is arranged in the outer periphery of the seal support portion 172c (refer to FIG. 40, 42). This seal material A2 is a member to seal between the inner container 12 and the exterior by being compressed vertically. In this embodiment, the outer surface of the valve guide portion 172a and the outer surface of the valve housing 171 (gas supply portion 174) is made to be inside and outside surfaces provided coaxially, but it may be made to be an identical surface, for example, as shown in FIG. 46. As this embodiment, by making the gas supply portion 174 of the valve housing 171 to be reduced in diameter than the valve guide portion 172a and to be provided inside, it becomes possible to miniaturize the valve holder 165 wholly.

    [0372] The moving valve 166 is, as shown in FIG. 41C, a ring like cylindrical body. In the inside and outside surface of the upper portion, an annular skirt portion 166a formed to be taper like so as to expanded in diameter upward is formed. The cross section thereof presents an approximate Y character. Moreover, in the lower end inner surface, an annular notched portion 166b formed taper like so as to be reduced in diameter upward is formed. Further, in the center of the upper end surface, an annular groove 166c is formed.

    [0373] In the moving valve 166, the skirt portion 166a slightly bends so as to close the annular groove 166c against a fluid flowing from underneath, the skirt portion 166a slightly bends so as to open the annular groove 166c against the fluid flowing from above. Since being composed as described above, the fluid from above is stopped and the fluid from underneath is let through. The moving valve 166 like this is molded from, for example, synthetic resin such as low molecular mass poly ethylene, and silicone rubber etc.

    [0374] The elastic valve 167 is that which covers the outer periphery of the above described gas supply portion 174. In detail, as shown in FIG. 41D, it is provided with a small diameter portion 167a covering the small diameter portion 174c of the gas supply portion 174, a medium diameter portion 167b covering the medium diameter portion 174b of the gas supply portion 174, being continuous with the small diameter portion 167a, and a flange portion 167c arranged along the lower surface of the large diameter portion 174a of the gas supply portion 174. The tip of the flange portion 167c engages with the engaging protrusion 172a1 of the support flange 172 of the valve holder 165. In addition, the shape of the elastic valve 167 may be selected according to the shape of the gas supply portion 174 taking into consideration the attaching state to the gas supply portion 174. Being composed as described above, against the fluid going to the exterior (inside the inner container 12) of the gas supply portion 174 from the second communicating hole 165b of the gas supply portion 174, the small diameter portion 167a deforms so as to expand, letting through the fluid to the exterior of the gas supply portion 174, against the fluid going to the second communicating hole 165b from the exterior of the gas supply portion 174, the gas supply portion 174 disturbs the deformation of the elastic valve 167 to stop the fluid. The elastic valve 167 is molded from, for example, the rubber such as nytril rubber, butyl rubber, silicone rubber.

    [0375] The cap 168 is, as shown in FIG. 41A, comprises a cylindrical cover portion 176 covering the valve holder 165, and a fixing portion 177 attached to the outer container 11. The cover cap 168 forms the gap G1 with the inside surface thereof and the outer surface of the valve holder.

    [0376] The cover cap 168 is molded by the injection molding of synthetic resin, for example, such as polyacetal, polybutylene terephthalate.

    [0377] The cover portion 176 comprises a circular plate like top surface 181, a cylindrical valve fitting portion 182 extending downward from the edge portion thereof, and a cylindrical diameter-expanded portion 183 extending downward, being expanded in diameter than the valve fitting portion 182. In the top surface 181, a center hole 181a to let through the stem 109 is formed. In the lower portion of the valve fitting portion 182, an annular engaging protrusion 182a protruding inward radially is formed. This engaging protrusion 182a engages with, as described above, the annular engaging groove 173c of the valve holder. Thereby, the valve holder 165 is fixed to the cover cap 168.

    [0378] The diameter-expanded portion 183 is a portion, the inner surface of which is expanded in diameter than the inner surface of the valve fitting portion 182. Stated differently, between the inner surface of the diameter-expanded portion 183 and the valve guide portion 172a (the outer periphery of the valve housing 171) of the valve holder 165, the cylindrical gap G1 extending vertically is formed. Moreover, a first step portion 183a between the valve fitting portion 182 and the diameter-expanded portion 183 becomes upper than the first communicating hole 165a at intervals. The space G1 consists of an evacuation passage space G1a upper side than the first communicating hole 165a, and a passage space G1b lower side than the first communicating hole 165a. And, the evacuation passage space G1a serves as an evacuation passage, the passage space G1b serves as a part of the concentrate passage Z1 (refer to FIG. 42A, 42B).

    [0379] The fixing portion 177 is, as shown in FIG. 41A, presents a shape expanded in diameter from the cover portion 176 thereof. In detail, it comprises a ring like medium top face 186 extending outward radially from the lower end of the diameter-expanded portion 183 and a cylindrical locking cylinder portion 187 extending downward from the edge portion thereof. The diameter of the inner surface of the locking cylinder portion 187 is made to be larger than the diameter of the outer end of the flange portion 172b of the valve holder 165. The lower surface of the medium top face 186 is arranged so as to contact the upper surface of the flange portion 172b of the valve holder 165. However, as described above, a plurality of passages is formed radially at an equal interval by the lateral passage groove 27a formed in the flange portion 172b. In addition, this lateral passage groove may be formed in the lower surface of the medium top face 186. This lateral passage groove 27a is, as described above, arranged so as to communicate with the longitudinal passage groove 12a. Moreover, in the inner surface of the locking cylinder portion 187, a screw 187a engaging with the screw 11a of the outer container 11 is formed. Further, beneath the screw 187a, an inner cylindrical portion 187b expanded in diameter is formed so as to cover the seal holding portion 11b, and it compresses radially the outer seal material (O ring) A1 held by the outer seal material holding portion 11b of the outer container 11 between the outer surface of the neck portion of the outer container and the inner cylinder portion 187b, and seals between the outer container 11 and the exterior (refer to FIG. 40).

    [0380] The concentrate passage Z1 of the valve assembly 161 is, as shown in FIG. 42A, passes through the inside of the housing body 173 from the stem 106 communicating with the exterior, goes out to the exterior of the valve housing 171 from the first communicating hole 165a, and reaches to the passage space G1b (lower side than the first communicating hole 165a between the valve holder 165 and the cap 168), the lateral passage groove 27a, and the gap G2 of the outside of the flange portion 172b of the valve holder.

    [0381] Stated differently, the concentrate passage Z1 consists of the stem 106 of the valve mechanism, the inside of the valve housing 171 of the valve holder 165, the first communicating hole 165a, the passage space between the outer periphery of the valve housing 171 and the cover cap 168, and the passage (the gap G2 of the lateral passage groove 27a and the outside of the support flange) between the support flange 172 of the valve holder and the cover cap 168. And, this concentrate passage Z1 communicates with the accommodating chamber S1 between the outer container 11 and the inner container 12 through the longitudinal passage groove 12c.

    [0382] The check valve for concentrate 163 of the concentrate passage Z1 consists of the passage space G1b which is a part of the concentrate passage Z1 (lower side than the first communicating hole 165a between the valve holder 165 and the cover cap 168), the evacuation passage space G1a being the evacuation passage (upper side than the first communicating hole 165a of the gap G1a between the valve holder 165 and the cap 168) and the moving valve 166 accommodated in the gap G1. Stated differently, when the fluid going to the accommodating chamber S1 from the exterior is supplied to the concentrate passage Z1, the skirt portion 166a of the moving valve 166 slides inside the space G1, and moves to the passage space G1b side (refer to FIG. 42B). After that, the fluid presses the annular groove 166c of the moving valve 166 supported to the flange 172b, the skirt portion 166a bends slightly so as to open the annular groove 166c, and seals the concentrate passage Z1. Meanwhile, when the fluid going to the exterior from the accommodating chamber S1 is supplied to the concentrate passage Z1, since the skirt portion 166a receives pressure from below, the annular groove 166c bends slightly to so as to close, the seal across the space G1 is released, or becomes to be slidable, and it slides in the space G1 and moves to the evacuation passage G1a side. Thereby, the concentrate passage Z1 becomes communicated.

    [0383] Meanwhile, the gas passage Z2 of the valve assembly 161 is, as shown in FIG. 42B, reaches to the second communicating hole 165b from the gas supply portion 174, passing through inside the housing body 173 from the stem 106 communicated with the exterior.

    [0384] In other words, this gas passage Z2 consists of the stem 106, the inside of the valve housing 171 of the valve holder 65 of the valve assembly 161, and the second communicating hole 165b.

    [0385] And, this gas passage Z2 is communicated with the pressurizing chamber S2 directly.

    [0386] The check valve 164 for gas of the gas passage Z2 consists of the gas supply portion 174, the second communicating hole 165b thereof, and the elastic valve 167. Stated differently, the fluid going to the pressurizing chamber S2 from the exterior is supplied to the gas passage Z2, the small diameter portion 167a of the elastic valve 167 deforms to open the second communicating hole 165b. Meanwhile, the fluid going to the exterior from the pressurizing chamber S2 is supplied to the gas passage Z2, the outer periphery surface of the gas supply portion 174 disturbs the deformation of the elastic body 167, the second communicating hole 165b is maintained to be in the state being closed by the elastic valve 167.

    [0387] Next, the filling process of the concentrate and the pressurizing agent into the two-layer discharge container 160 is shown in FIG. 43.

    [0388] As shown in FIG. 43A, the outer container 11 and the inner container 12 are molded, and the concentrate C is filled between the outer container 11 and the inner container 12 (the accommodating chamber S1). Thereby, the inner container 12 is crushed (refer to FIG. 43B). In this moment, as described above, it is preferable to carry out the filling after contracting the inner container 12 previously using the guide member.

    [0389] Next, the valve assembly 161 is fixed to the outer container 11 and the inner container 12.

    [0390] After that, as shown in FIG. 43B, it is manufactured so that at the same time with the pushing down of the stem 106, the pressurizing agent P is filled in the pressuring chamber S2 from the stem 106 through the gas passage Z2. In this moment, the pressurizing agent P is also supplied to the first communicating hole 165a, but as described above, since the moving valve 166 of the check valve 163 for concentrate shuts off the concentrate passage Z1, the pressurizing agent P is not filled in the accommodating chamber S1 (refer to Z2 of FIG. 42B). Once, the pressurizing agent P is filled in the pressurizing chamber S2, the inside of the pressurizing chamber S2 becomes higher pressure than the exterior. Hence the pressurizing agent P tends to go to the exterior. But, the check valve for gas 164 shuts off the passage Z2 for gas (the second communicating hole 165b), the flowing back of the pressurizing agent P is prevented.

    [0391] The use state of this two-layer discharge container 160 is shown in FIG. 44A, 44B.

    [0392] As shown in FIG. 44A, by the operation of pushing down the stem 106, the concentrate C is discharged to the exterior through the concentrate passage Z1. Meanwhile, when the concentrate C of the accommodating chamber S1 is discharged wholly, as shown in FIG. 44B, the inner container 12 expands, to contact tightly the inner surface of the outer container 11. Particularly, in this two-layer discharge container 160, in the case that the outer container 11 and the inner container 12 are made to be transparent or translucent, since the inner container 12 has substantially the identical shape with the inner surface of the outer container 11, and the space between the outer container 11 and the inner container 12 serves as the accommodating chamber S1, when using that which is opaque, particularly cream as the concentrate C, the appearance of the outer container varies suddenly in the conditions between the state that the concentrate C remains and the state the concentrate C does not remain. Stated differently, when the concentrate C remains in the accommodating chamber S1, in the outer container 11, the presence of the concentrate C can be identified, when the concentrate C disappears from the inside of the accommodating chamber S1, the outer container 11 becomes transparent suddenly. Hence, the run out of the concentrate C can be visually identified.

    [0393] Moreover, after discharging the concentrate C wholly, by turning the cap 168, it can be separated into each part. Particularly, since it is provided with the inner seal material A2 which seals by compressing between the inner container 12 and the valve assembly 13 vertically, and the outer seal material A1 (O ring) which seals by compressing between the outer container and the valve assembly right and left (horizontally), and since the cap 168 is made to be screw type, when the cap 168 is loosened by turning in the direction of unsealing, the seal of the inner seal material A2 can be released while maintaining the seal of the outer seal material A1 (temporary fixing).

    [0394] Stated differently, the pressurizing agent P in the inner container 12 opens the check valve for concentrate 163, passing through a part (the outer periphery of the flange portion 172b of the valve holder 165, the lateral passage groove 27a, the space G1) of the concentrate passage Z1, the pressurizing agent P can be discharged to the exterior from the stem 106 by operating the valve assembly 161.

    [0395] Moreover, even in the case that consumers loosen the cap 168 accidently in a state that the concentrate C remains in the accommodating chamber S1, since the seal between the outer container 11 and the cap 168 is maintained by the outer seal material A1, the concentrate C does not spout from the lower end of the cap 168.