Transfer printing method of electronic image and transfer sheet

09643449 ยท 2017-05-09

Assignee

Inventors

Cpc classification

International classification

Abstract

A transfer sheet is provided, whereby a T-shirt or the like can be printed in few steps by means of an electronic image forming device that uses powdered toner, liquid ink, or the like containing a plastic resin. By means of mirror-image printing a picture pattern, which is an electronic image, onto a first sheet, aligning the first sheet and a second sheet, and heat-pressing, a coating is spread over a portion of the picture pattern printed onto the first sheet. The first sheet has a structure including a mold release layer, a resin layer, and a porous resin layer in a substrate, and the second sheet includes a mold release layer, a resin layer, an adhesive layer, and a colored porous resin layer in a substrate.

Claims

1. A method of manufacturing a transfer sheet, comprising: forming a first sheet by the steps of: providing a first release layer laminated on top of a first substrate layer, laminating a resin layer on top of said first release layer, laminating a porous resin layer on top of said resin layer, forming a colored ink or resin toner layer on said porous resin layer by laser printing mirror images of desired images with at least one colored ink or resin toner material, and forming a transparent ink or resin toner layer on said porous resin layer and said colored ink or resin toner layer by ink jet printing a transparent ink or resin toner material; arranging a second sheet comprising a second release layer laminated on top of a second substrate layer, an adhesive layer laminated on top of said second release layer, and a white porous resin layer laminated on top of said adhesive layer; superimposing said second sheet onto said first sheet such that said white porous resin layer of said second sheet contacts at least one of said colored ink or resin toner layer of said first sheet and said transparent ink or resin toner layer of said first sheet; heating and pressing said first sheet and said second sheet which have been superimposed; and separating and removing said second sheet from said first sheet such that said white porous resin layer and said adhesive layer remain partly adhered to at least one of said colored ink or resin toner layer of said first sheet and said transparent ink or resin toner layer of said first sheet, and are separated from said second release layer of said second sheet, so as to produce said transfer sheet including said first sheet, said white porous resin layer and said adhesive layer.

2. A method of manufacturing a transfer sheet comprising a first release layer laminated on top of a first substrate layer, a resin layer laminated on top of said release layer, a porous resin layer laminated on top of said resin layer, a transparent ink or resin toner layer laminated on top of said porous resin layer, a colored ink or resin toner layer configured to represent images and interposed between said porous resin layer and said transparent ink or resin toner layer, a white porous resin layer laminated on top of said transparent ink or resin toner layer, and an adhesive layer laminated on top of said white porous resin layer, said method comprising: forming a first sheet by the steps of: providing a first release layer laminated on top of a first substrate layer, laminating a resin layer on top of said first release layer, laminating a porous resin layer on top of said resin layer, forming a colored ink or resin toner layer on said porous resin layer by laser printing mirror images of desired images with at least one colored ink or resin toner material, and forming a transparent ink or resin toner layer on said porous resin layer and said colored ink or resin toner layer by ink jet printing a transparent ink or resin toner material; arranging a second sheet comprising a second release layer laminated on top of a second substrate layer, an adhesive layer laminated on top of said second release layer, and a white porous resin layer laminated on top of said adhesive layer; superimposing said second sheet onto said first sheet such that said white porous resin layer of said second sheet contacts at least one of said colored ink or resin toner layer of said first sheet and said transparent ink or resin toner layer of said first sheet; heating and pressing said first sheet and said second sheet which have been superimposed; and separating and removing said second sheet from said first sheet such that said white porous resin layer and said adhesive layer remain partly adhered to at least one of said colored ink or resin toner layer of said first sheet and said transparent ink or resin toner layer of said first sheet, and are separated from said second release layer of said second sheet, so as to produce said transfer sheet including said first sheet, said white porous resin layer and said adhesive layer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 illustrates a sheet A;

(2) FIG. 2 illustrates a sheet B;

(3) FIG. 3 illustrates the sheet A printed by ink/resin toner;

(4) FIG. 4 illustrates a state in which the sheet B is superimposed on the printed sheet A and is separated, so that a transfer sheet A is prepared;

(5) FIG. 5 is a state in which the transfer sheet A is placed on a T-shirt;

(6) FIG. 6 illustrates a state in which the transfer sheet A is separated and an ink/resin toner layer is transferred to the T-shirt in a state of being covered; and

(7) FIG. 7 is a state in which an electronic image of the Hinomaru flag, i.e. the national flag of Japan is printed on a T-shirt.

DETAILED DESCRIPTION OF THE INVENTION

Embodiment 1

(8) Examples of a substrate layer 1 of a sheet A illustrated in FIG. 1 include a paper sheet or a film. Here, on coated paper (for example, a coat 110 manufactured by Nippon Paper Industries Co., Ltd.), a release layer 2 (for example, Silicon KS3502 manufactured by Shin-Etsu Chemical Co., Ltd), a resin layer 3 (for example, a cover coat resin 300 manufactured by Goo Chemical Co., LTD), a porous resin layer 4 (for example, a mixture of FPS-2 silica manufactured by Shionogi & Co., Ltd. and a transparent urethane resin of UD710 manufactured by Dainichiseika Color & Chemicals MFG. CO., Ltd. or the like) were provided, and respective layers were laminated into a single sheet A.

(9) Although the lamination of the sheet A was transparent, by mixing white titanium oxide as a color material, into the resin layer 3 or the porous resin layer 4, the printed workpiece was finally covered with white and becomes white irrespective of the color of an ink/resin toner. Other color materials may also be mixed.

(10) Examples of the substrate layer 1 of a sheet B illustrated in FIG. 2 include paper or a film. Although ST600KT manufactured by Lintec Corporation, which is processed up to the release layer 2, may be used, here, coated paper (for example, the coat 110 manufactured by Nippon Paper Industries Co., Ltd.), the release layer 2 (for example, Silicon KS776L manufactured by Shin-Etsu Chemical Co., Ltd), an adhesive layer 5 (for example, CRISVON AH4555 manufactured by DIC Corporation), and a white porous resin layer 6 (for example, a mixture of FPS-2 silica and titanium oxide manufactured by Shionogi & Co., Ltd. and a urethane resin of UD710 manufactured by Dainichiseika Color & Chemicals MFG. CO., Ltd. or the like) were provided, and respective layers were laminated into a single sheet B. The sheet B becomes transparent if white titanium oxide, which is a color material, was not added. Other color materials may also be mixed. If the transparent ink/resin toner of the electronic image forming apparatus is the white ink/resin toner, the sheet B may remain transparent.

(11) When Hinomaru (disc of the sun), which is a main portion of the Japanese national flag, was printed with a color laser printer (for example, image PRESS C1+ manufactured by CANON Inc.) on the sheet A in FIG. 1 described above, the toner layer 7 which expresses a red disc was printed, while square white part of the flag around the disc was drawn by a transparent toner layer 8 and, as illustrated in FIG. 3, the toner layers 7 and 8 of the Hinomaru image of the Japanese flag of an electronic image was formed on the porous resin layer 4 on the sheet A.

(12) Subsequently, the sheet B was superimposed on the sheet A with the above-described toner layers 7 and 8 on which the image of the Hinomaru flag, which is the Japanese flag, was printed with the color laser printer interposed therebetween in a state in which the porous resin layer 4 and the white porous resin layer 6 faced each other. Then, in this state, the sheets were heated to a temperature in a range from 120 C. to 130 C. and pressed at a pressure on the order of 300 g/cm.sup.2 for 20 seconds, the toner was softened and the sheet A and the sheet B were adhered to each other. Subsequently, when an attempt was made to separate the sheet A and the sheet B, the separation was not started from the above-described toner layers 7, 8, but the adhesive layer 5 on the sheet B was separated from the release layer 2, and was adhered only to a portion of the sheet A side where a Hinomaru (red disc) image formed of the toner layer 7 of the electronic image of the Hinomaru flag was drawn and to a square flag portion formed of the transparent toner layer 8 formed around the Hinomaru image, thereafter the layers 2, 7 and 8 being separated apart from the release layer 2 (see FIG. 4).

(13) The white porous resin layer 6 and the adhesive layer 5 on the sheet B were transferred to the sheet A, resulting in that a transfer sheet A illustrated in FIG. 4a was formed. As illustrated in FIG. 5, in a state that the adhesive layer 5 of the transfer sheet A was placed on the black T-shirt 9, the sheets were heated to a temperature in a range from 120 to 130 C., and were pressed for approximately 20 seconds at a pressure on the order of 300 g/cm.sup.2. Thereby, the transfer sheet A was secured to the fabric surface via the adhesive layer 5. Subsequently, when the transfer sheet A was peeled off as illustrated in FIG. 6, a red Hinomaru image was clearly drawn on a white flag on the black T-shirt 9, and the national flag of Japan 10 was printed as illustrated in FIG. 7.

(14) Incidentally, when 25 g of Attack ALLin (a bleaching agent with a fabric softener contained therein) manufactured by Kao Corporation was put in 30 L of warm water at a temperature of 50 C. in a dual tub washing machine of Ginga 2.2 (VH-22083) of Toshiba Corporation, and the printed black T-shirt 9 was dipped therein and was subjected to washing for 15 minutes and rinsing for 15 minutes in a strong current of washing water, and to dehydrating for 5 minutes and drying repeatedly by three times. Then, it was recognized that no color loosing and no peeling of the transferred image occurred. Also, a clothes iron for family use heated to a medium temperature of 150 C. was placed directly on the Hinomaru flag image 10 printed on the black T-shirt 9 and was slid laterally as is after 5 seconds, the resin toner layers 7, 8 covered with the resin layer 3 and the porous resin layer 4 on the sheet A were not melted and the Hinomaru flag image 10 clearly remained on the black T-shirt 9.

Embodiment 2

(15) A red disc image of Hinomaru as of Japanese national flag was printed with ink 7 by an ink jet printer (Colorio PX-G5300 type manufactured by Seiko Epson Corp.) on the above-described sheet A illustrated in FIG. 1, and then the sheet A was set so that the Hinomaru image was aligned to the center, and a square flag image which corresponds to the white portion was drawn therearound with the transparent ink 8 with an ink jet printer (Colorio PX-V630 type manufactured by Seiko Epson Corp) in which gloss optimizer manufactured by Seiko Epson Corp., which is transparent ink, was filled in all of ink bottles thereof) (See FIG. 3).

(16) The ink layers 7 and 8 of the electronic image of the Hinomaru flag were formed on the porous resin layer 4 on the sheet A. Subsequently, the sheet B was superimposed on the sheet A in the state in which the porous resin layer 4 and the white porous resin layer 6 face each other with the ink layers 7 and 8 interposed therebetween and, in this state, the sheets were heated to a temperature in the range from 120 C. to 130 C. and was pressed for approximately for 20 seconds at a pressure on the order of approximately 300 g/cm.sup.2. The ink layers 7, 8 were softened and bonded the sheet A and the sheet B to each other. Then, when an attempt was made to separate the sheet A and the sheet B, the separation was not started from the above-described ink layers 7, 8, but the adhesive layer 5 on the sheet B was separated from the release layer 2 and was adhered only to a portion of the sheet A side where a Hinomaru (red disc) image formed of the ink layer 7 of the electronic image of the Hinomaru flag was drawn and to a square flag portion formed of the transparent toner layer 8 formed around the Hinomaru image, thereafter the layers 2, 7 and 8 being separated apart from each other (See FIG. 4).

(17) The white porous resin 6 and the adhesive layer 5 on the sheet B were transferred to the sheet A, resulting in that a transfer sheet A was formed. Then, as illustrated in FIG. 5, in a state that the adhesive layer 5 of the transfer sheet A was placed on the black T-shirt 9, the sheets were heated to a temperature in the range from 120 C. to 130 C., and were pressed for approximately 20 seconds at a pressure on the order of 300 g/cm.sup.2. Thereby, the transfer sheet A was secured to the fabric surface or the like via the adhesive layer 5. When the transfer sheet A was peeled off as in FIG. 6, a red Hinomaru was clearly drawn and printed on a white flag on the black T-shirt 9 (see FIG. 7).

(18) When 25 g of Attack ALLin (with bleaching agent and fabric softener contained therein) manufactured by Kao Corporation was put in 30 L of warm water at a temperature of 50 C. in a dual tub washing machine of Ginga 2.2 (VH-22083) of Toshiba Corporation, and the printed black T-shirt 9 was dipped therein and was subjected to washing for 15 minutes and rinsing for 15 minutes in a strong current of washing water, and to dehydrating for 5 minutes and drying repeatedly by three times. Consequently, it was recognized that no color loosing and separation occurred. Aso, a clothes iron for family use heated to a medium temperature of 150 C. was placed directly on the Hinomaru flag printed on the black T-shirt 9 and was slid laterally as is after 5 seconds, the ink covered with the resin layer 3 and the porous resin layer 4 on the sheet A was not melted and the Hinomaru flag 10 clearly remained on the black T-shirt 9.

REFERENCE SIGNS LIST

(19) 1 substrate layer 2 release layer 3 resin layer 4 porous resin layer 5 adhesive layer 6 white porous resin layer 7 ink/resin toner layer 8 transparent ink/resin toner layer 9 T-shirt 10 Hinomaru flag