Precursors for CVD silicon carbo-nitride films
09640386 ยท 2017-05-02
Assignee
Inventors
Cpc classification
H01L21/02167
ELECTRICITY
H01L21/02271
ELECTRICITY
H01L21/02211
ELECTRICITY
International classification
H01L21/02
ELECTRICITY
Abstract
Classes of liquid aminosilanes have been found which allow for the production of silicon carbo-nitride films of the general formula Si.sub.xC.sub.yN.sub.z. These aminosilanes, in contrast, to some of the precursors employed heretofore, are liquid at room temperature and pressure allowing for convenient handling. In addition, the invention relates to a process for producing such films. The classes of compounds are generally represented by the formulas: ##STR00001## and mixtures thereof, wherein R and R.sup.1 in the formulas represent aliphatic groups typically having from 2 to about 10 carbon atoms, e.g., alkyl, cycloalkyl with R and R.sup.1 in formula A also being combinable into a cyclic group, and R.sup.2 representing a single bond, (CH.sub.2).sub.n, a ring, or SiH.sub.2.
Claims
1. An aminosilane compound selected from the group having the following formulas: ##STR00011##
2. The aminosilane of claim 1 comprising: ##STR00012##
3. A composition comprising: ##STR00013## and at least one member selected from the group consisting of nitrogen, ammonia, hydrazine, and dimethylhydrazine.
4. The aminosilane of claim 1 comprising: ##STR00014##
5. The aminosilane of claim 1 comprising: ##STR00015##
6. The aminosilane of claim 1 comprising: ##STR00016##
7. A composition comprising the compound of claim 1 and at least one aminosilane compound selected from the group consisting of: ##STR00017## and where n is 4 or 5.
8. The composition of claim 7 comprising: ##STR00018##
9. The composition of claim 7 comprising: ##STR00019##
10. The composition of claim 7 comprising: ##STR00020##
11. The composition of claim 7 comprising: ##STR00021## wherein n is 4 or 5.
12. A composition comprising the compound of claim 1 and at least one member selected from the group consisting of: ##STR00022##
13. The composition of claim 12 comprising: ##STR00023##
14. The composition of claim 12 comprising: ##STR00024##
15. The composition of claim 12 comprising: ##STR00025##
16. A composition comprising at least one aminosilane selected from the group consisting of: ##STR00026## and at least one member selected from the group consisting of nitrogen, ammonia, hydrazine, and dimethylhydrazine.
17. A composition comprising the compound of claim 1 and at least one member selected from the group consisting of bis-tert-butylaminosilane, tris-iso-propylaminosilane, bis-diethylaminosilane, tris-dimethylaminosilane, and bis-iso-propylaminosilane.
18. A composition comprising the compound of claim 1 and at least one member selected from the group consisting of nitrogen, ammonia, hydrazine, and dimethylhydrazine.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
DETAILED DESCRIPTION OF THE INVENTION
(4) It has been found that classes of liquid organo aminosilanes having an NSiH.sub.3 group as a key feature in the molecular structure are suitable as precursors for producing silicon carbo-nitride films via CVD in the electronics industry. These compounds lend themselves to the production of Si.sub.xC.sub.yN.sub.z films under a variety of conditions.
(5) The compounds herein are liquid at atmospheric pressure and room temperature, i.e., 25 C. and thus provide a significant advantage over the reported usage of the trimethyl substituted aminosilane. They are substituted with organo groups having at least 2 carbon atoms in the chain on the amino group providing for stability under conventional handling and processing conditions.
(6) One class of amino silane is resented by formula A as follows:
(7) ##STR00004##
In this class of compounds R is selected from C.sub.1-C.sub.10 alkyl groups, linear, branched, or cyclic, saturated or unsaturated; aromatic, heterocyclic. R.sup.1 is selected from C.sub.2-C.sub.10 alkyl groups, linear, branched, or cyclic, saturated or unsaturated; aromatic, heterocyclic, hydrogen, silyl groups, with or without substituents, and R and R.sup.1 also being combinable into a cyclic group. Representative substituents are alkyl groups and particularly the C.sub.2-4 alkyl groups, such as ethyl, propyl and butyl, including their isomeric forms, cyclic groups such as cyclopropyl, cyclopentyl, and cyclohexyl. Illustrative of some of the preferred compounds within this class are represented by the formulas:
(8) ##STR00005##
where n is 1-6, preferably 4 or 5.
(9) The second class of aminosilane has two silyl groups pendant from a single nitrogen atom as represented by formula B.
(10) ##STR00006##
As with the R groups of the Class A compounds, R is selected from C.sub.2-C.sub.10 alkyl groups, linear, branched, or cyclic, saturated or unsaturated; aromatic, heterocyclic. Specific R groups include methyl, ethyl, propyl, allyl, and butyl; and cyclic groups such as cyclopropyl, cyclopentyl, and cyclohexyl. Illustrative compounds are represented by the formulas:
(11) ##STR00007##
(12) The third class of aminosilane compound is represented by formula C. These are generally diaminodisilyl compounds with R is same as R and R.sup.1 in formulas A and the R.sup.2 group bridging the nitrogen atoms. Sometimes the R.sup.2 group is nothing more than a single bond between the nitrogen atoms or it may be a bridging group, such as SiR.sub.2, SiH.sub.2, a chain, or a ring. The formula is as follows:
(13) ##STR00008##
(14) Specific examples include those represented by the formulas:
(15) ##STR00009##
(16) These compounds are synthesized in general by the following reactions, which are also demonstrated by Examples 1, 2, 3, and 4.
(17) ##STR00010##
(18) Although the above series of reactions illustrate a route to the aminosilanes as described, other sources of a silane precursor may be used. This route allows for a rather straight forward control as to whether mono and disilyl compounds are produced using the reaction stoichiometry and the use of a wide variety of amines.
(19) Some of these compounds can also be synthesized by the reaction of monohalosilanes with corresponding amines, as described in The Preparation and Properties of Dimethylamino and Diethylamino Silane [Aylett and Emsley, J. Chem. Soc. (A) p 652-655, 1967].
XSiH.sub.3+2RR.sup.1NH.fwdarw.RR.sup.1NSiH.sub.3+RR.sup.1NH.HX
(20) Representative amines well suited for the reaction are the alkyl, cyclic, and heterocyclic. Preferred amines are the lower alkyl amines, e.g., ethyl, iso-propyl, t-butyl, and cyclohexyl. Further the amines may be primary or secondary depending upon the product desired.
(21) In the formation of silicon carbo-nitride films, the mono or diaminosilanes, optionally with ammonia or nitrogen source, are allowed to react in a deposition chamber at conventional deposition temperatures. Such films may be formed in deposition chambers designed for chemical vapor deposition (CVD), low pressure chemical vapor deposition (LPCVD) plasma enhanced CVD (PECVD), atomic layer deposition (ALD), and so forth. The term CVD as used herein is intended to include each of these processes which are employed in semiconductor deposition.
(22) As stated in the advantages, the liquid aminosilanes described herein, in many cases offer the fabricator the ability to form silicon carbo-nitride films via CVD at relatively low temperatures, although a general temperature range is from 500 to 700 C. Unexpectedly, Si.sub.xC.sub.yN.sub.z film deposition can be achieved presumably because of the high activity of the SiH.sub.3 group(s). It is believed the low steric hindrance for the ammonia transamination reaction on the silicon center, allows these compounds to react with ammonia and deposit films with increasing nitrogen concentrations at relatively low temperatures.
(23) The deposition of the aminosilane precursors may be carried out in the absence of, or in the presence of, an active nitrogen source such as hydrazine, dimethylhydrazine, or ammonia. Molar ratios of the nitrogen source to aminosilane generally are broadly within the range of from 0: to >10:1. The upper limit is restricted by the dilution effect on the precursor and the dilution effect will significantly diminish the deposition rate. Preferred ranges are from 0.1 to 4:1. The formation of films via deposition may also be carried out with or without other gases including with inert gases, such as nitrogen and helium. The use of gases by the fabricator to achieve corresponding dilution of the precursor may improve the conformality of the deposition or improve the penetration for chemical vapor infiltration.
(24) Low pressure chemical vapor deposition processes (LPCVD) involve chemical reactions that are allowed to take place on a variety of substrates, e.g., silicon, within a pressure range of 20 mTorr to 20 Torr. High pressure CVD may result in gas phase nucleation or predeposition before the desired substrate is reached. Dilution of the aminosilane precursor may be required for such high pressure reactions. Low pressure deposition with some of the aminosilane precursors may exhibit rates of deposition to non-commercially usable levels. However, such aminosilanes may be suitable for atomic layer deposition.
(25) In carrying out deposition processes, the aminosilanes described herein can be blended with other silyl precursors to alter film properties. Examples of other precursors include bis-tert-butylaminosilane, tris-iso-propylaminosilane, bis-diethylaminosilane, tris-dimethylaminosilane, and bis-iso-propylaminosilane.
(26) The following examples are intended to illustrate various embodiments of the invention including the synthesis of various silanes and the LPCVD of silicon carbo nitride film forming precursors.
Example 1
Synthesis of Diethylaminosilane
(27) 50 grams (0.33 mol) of trifluoromethanesulfonic acid and 100 ml of toluene were added to a 250 ml flask. Under the protection of nitrogen, the flask was cooled to 40 C. 40.6 grams (0.33 mol) of tolylsilane was added slowly. Then the flask was cooled to 60 C. 33.5 grams of triethylamine was added slowly, followed by addition of 24 grams of diethylamine. After addition, the temperature of the flask was allowed to warm to room temperature gradually. Two layers of liquid were formed. The upper layer was separated using a separation funnel. 25 grams of diethyaminolsilane was obtained by vacuum distillation. The boiling point of the diethyaminolsilane was 40-42 C. at 210 mmHg.
Example 2
Synthesis of Di-Iso-Propylaminosilane
(28) 50 grams (0.33 mol) of trifluoromethanesulfonic acid and 80 ml of pentane were added to a 250 ml flask. Under the protection of nitrogen, the flask was cooled to 40 C. 35.6 grams (0.33 mol) of phenylsilane was added slowly. Then the flask was cooled to 60 C. 33.3 grams (0.33 mol) of triethylamine was added slowly, followed by addition of a solution 33.3 grams (0.33 mol) of di-iso-propylamine in 15 ml of pentane. After addition, the temperature of the flask was allowed to warm to room temperature gradually. Two layers of liquid were formed. The upper layer was separated using a separation funnel. The solvent and by product benzene were removed by distillation. 30 grams of di-iso-propylaminosilane was obtained by vacuum distillation. The boiling point of the di-iso-propylaminosilane was 55 C. at 106 mmHg.
Example 3
Synthesis of Cyclohexyldisilylamine and 2,4-Dicyclohexyl-2,4-Diaza-1,3,5-Trisilapentane
(29) 62.5 grams of trifluoromethanesulfonic acid and 100 ml of pentane were added to a 500 ml flask. Under the protection of nitrogen, the flask was cooled to 40 C. 45 grams of phenylsilane was added slowly. Then the flask was cooled to 60 C. 42 grams of triethylamine was added slowly, followed by addition of a solution 20.6 grams of cyclohexylamine in 15 ml of pentane. After addition, the temperature of the flask was allowed to warm to room temperature gradually. Two layers of liquid were formed. The upper layer was separated using a separation funnel. The solvent and by product benzene were removed by distillation. 15 grams of cyclohexyldisilylamine was obtained by vacuum distillation. The boiling point of the cyclohexyldisilylamine was 54-55 C. at 17 mmHg. The remaining high boiling point portion contains 96.6% 2,4-dicyclohexyl-2,4-diaza-1,3,5-trisilapentane.
Example 4
Synthesis of Cyclohexyldisilylamine and 2,4-Di-Tert-Butyl-2,4-Diaza-1,3,5-Trisilapentane
(30) 50.0 grams (0.33 mol) of trifluoromethanesulfonic acid and 100 ml of pentane were added to a 500 ml flask. Under the protection of nitrogen, the flask was cooled to 40 C. 35.6 grams (0.33 mol) of phenylsilane was added slowly. Then the flask was cooled to 60 C. 33.3 grams (0.33 mol) of triethylamine was added slowly, followed by addition of a solution 28.7 grams (0.165 mol) of bis-t-butylaminosilane in 15 ml of pentane. After addition, the temperature of the flask was allowed to warm to room temperature gradually. Two layers of liquid were formed. The upper layer was separated using a separation funnel. The solvent and by product benzene were removed by distillation. 21 grams of 2,4-di-tert-butyl-2,4-diaza-1,3,5trisilapentane was obtained by vacuum distillation.
Example 5
Formation of Silicon Carbo Nitride Film Using Diethylaminosilane Precursor
(31) General Procedure
(32) The aminosilane precursors are tested in an LPCVD reactor used to qualify experimental precursors for silicon carbo-nitride depositions. The precursors are degassed and metered into the reactor through a low-pressure mass flow controller (MFC) as required. The MFC flows are calibrated against weight losses of the chemicals vs. time of flow. Additional reactants, such as ammonia, and diluents, such as nitrogen and helium, as specified are also metered into the reactor through calibrated MFCs, as required. The reactor is connected to a roots blower/dry pump combination capable of evacuating the reactor to below 10.sup.4 Torr (0.013 Pa). The temperature across a load of silicon wafers, during deposition, is within 1 C. of the set point.
(33) Silicon wafers are loaded onto a quartz boat and inserted in the reactor. The reactor is pumped to base pressure and checked for leaks. The system is ramped to the process temperature with gas flows that would dilute any residual oxygen or moisture to prevent any oxidation of the silicon wafers as the reactor heats up. The reactor is then stabilized for a predetermined time to bring all wafer surfaces to an equal temperature (as had been determined by previous measurements on wafers with attached thermocouples).
(34) The gases and vapors are injected into the reactor for a predetermined deposition time at a controlled pressure. Next, the gases are shut off, and the reactor is pumped to a base pressure. The reactor, then, is pump-purged, pumped down, and pump-purged to clear any reactive gases or vapors as the reactor is cooled down. The reactor is backfilled to atmospheric pressure; the wafers are removed and allowed to cool to room temperature. The deposited films are then measured for film thickness, film refractive index, film stress (
(35) In forming the deposited films, 10 sccm of diethylaminosilane (DEAS) was flowed into a reactor at 570 C. along with 20 sccm NH.sub.3 and 20 sccm N.sub.2 at 1.3 Torr (173.3 Pa) for a deposition time of 60 minutes.
(36) The average film thickness was 69 nm and refractive index was 2.045. The film stress was measured as 1.0710.sup.10 dynes/cm.sup.2 (1.07 GPa).
(37) The infrared spectra were dominated by SiC and SiN absorptions. CH or CN absorptions were in the noise illustrating, as shown in
Example 6
Formation of Silicon Carbo-Nitride Film Using Diethylaminosilane Precursor Using N2 without NH3
(38) The procedure of Example 4 was followed with the exception of process conditions. Nitrogen was used in place of NH.sub.3. In this example, 10 sccm of diethylaminosilane (DEAS) was flowed into a reactor at 600 C. with 40 sccm N.sub.2 at 1.0 Torr (133 Pa) for a deposition time of 40 minutes.
(39) The average film thickness was 42 nm and refractive index was 2.288. The film stress was measured as 1.3410.sup.10 dynes/cm.sup.2. These films have even higher stresses and lower etch rates than those obtained with ammonia (See Table 1 for etch rates). The conformalities of such films were found to be 100% on isolated structures.
Example 7
Formation of Silicon Carbo-Nitride Film Using Diisopropylaminosilane Precursor Using N2 without NH3
(40) The procedure of Example 5 was followed with the exception of the precursor. 10 sccm of diisopropylaminosilane (DIPAS) was flowed into a reactor at 570 C. with 20 sccm He and 20 sccm N.sub.2 at 1.0 Torr (133 Pa) for a deposition time of 70 minutes.
(41) The average film thickness was 46 nm and refractive index was 2.056. The film stress was measured as 1.0710.sup.10 dynes/cm.sup.2. Surprisingly, the refractive index and stress were similar for diisopropylaminosilane to that of the precursor of Example 6. These results show excellent stress values within this class of materials can be achieved.
Example 8
Formation of Silicon Carbo-Nitride Film Using Bis(Tertiary Butylamino)Silane Precursor as a Control Using N2 without NH3
(42) The procedure of Example 5 was followed with the exception of the precursor and it was used as a control. BTBAS is a precursor used in production processes worldwide and it was chosen as the representative aminosilane comparison because of its well accepted performance characteristics.
(43) 10 sccm of bis(tertiary butylaminosilane) (BTBAS) was flowed into a reactor at 570 C. with 20 sccm He and 20 sccm N.sub.2 at 1.0 Torr (133 Pa) for a deposition time of 70 minutes. These films have only 20% of the stress and less than 10% of the etch resistance of the mono-aminosilanes (See Table 1).
(44)
(45) Precursors such as bis(tertiarybutylamino)silane and dichlorosilane produce films that have decreasing stresses as the ammonia to chemical ratio is decreased. At a low NH3:BTBAS ratio stress results are poor. Reducing the ammonia for these precursors creates a silicon rich film and this reduces the thermal expansion coefficients of these films relative to the silicon substrate. Although not intending to be bound by theory, reducing the ammonia:DEAS ratio in the deposition process increases the Si to N atomic ratio, the effect is that the C to Si atomic ratio increases. Apparently, then, there is some replacement of SiN with SiC bonds and these bonds result in producing films having similar stress.
(46) A second component of the example was the measurement of film hardness. It was measured by indentation using a Hysitron system.
Example 9
Etch Resistance of Silicon Nitride and Silicon Carbo-Nitride Films
(47) In this example, the results of etching of various silicon nitride and silicon carbo-nitride films are set forth in Table 1. Table 1 displays the results of etching films from several precursors in 1% (of 49%) HF. The etch rates are given relative to those of thermally grown silicon dioxide that were etched at the same time. The lower the etch rate of a film, the better it is for maintaining geometries and protecting underlying layers as undesired silicon dioxide is removed.
(48) TABLE-US-00001 TABLE 1 1% HF Etch Deposition Rate NH.sub.3 Temperature, Relative Chemical ratio C. to SiO.sub.2 BTBAS 2:1 570 0.188 BTBAS 0 570 0.018 DEAS 2:1 570 0.006 DEAS 4:1 570 0.008 DEAS 1:1 570 0.009 DEAS 0 570 0.001 DIPAS 2:1 570 0.006 DIPAS 0 570 0.006 BTBAS = bis(tertiarybutylamino)silane DEAS = diethylaminosilane DIPAS = diisopropylaminosilane Comparison of film etch rates in 1% of 49% HF at 24 C.
(49) From the above Table 1, DEAS is shown to have excellent low etch rates at NH.sub.3 to precursor ratios of from 0 to 2. On the other hand, a ratio of NH.sub.3:BTBAS, even at an NH.sub.3:BTBAS ratio of 0:1:1 gave higher etch rates, than DEAS at a 2:1 ratio. Excellent low etch rates are shown at low NH.sub.3:BTBAS ratios, but recall with BTBAS stress levels are poor at the low NH.sub.3:BTBAS level.
(50) Summarizing, dielectric silicon carbo-nitride films of the formula, Si.sub.xC.sub.yN.sub.z, can be produced from the classes of aminosilanes as described, by CVD and other deposition processes. It is believed the high activity of the SiH.sub.3 group allows for the production of Si.sub.xC.sub.yN.sub.z film depositions at temperatures as low as 550 C. whereas many of the precursors for forming Si.sub.xC.sub.yN.sub.z films do not perform well.
(51) It is believed, also, the low steric hindrance for the ammonia transamination reaction on the silicon center allows these compounds to react with ammonia and form films with increasing nitrogen concentrations at relatively low temperatures. Ligands such as ethyl, isopropyl, butyl, etc. act as good leaving groups as they become volatile byproducts by beta-hydride elimination. Any carbon left behind is bonded to silicon. In contrast, aminosilane precursors which have methyl groups as reported in the past do not have this dissociation route. They remain bonded to the nitrogen and can be incorporated and trapped in the growing film. The presence of such trapped methyl groups are easily distinguished in infrared spectra (see