Disk roll and substrate therefor

Abstract

A base material for a disk roll, the base material including: 5 to 9 wt % of ceramic fibers, 20 to 40 wt % of kibushi clay, 2 to 20 wt % of bentonite and 40 to 60 wt % of mica.

Claims

1. A base material for a disk roll, the base material comprising: 5 to 9 wt % of ceramic fibers, 20 to 40 wt % of kibushi clay, 2 to 20 wt % of bentonite and 40 to 60 wt % of mica, wherein the amount of shots having a diameter of 45 m or more in the ceramic fibers is 5 wt % or less.

2. The base material for a disk roll according to claim 1, wherein the ceramic fibers comprise 30 wt % or more and less than 70 wt % of alumina and more than 30 wt % and 70 wt % or less of silica.

3. The base material for a disk roll according to claim 1, which further comprises pulp and starch.

4. A method for producing a base material for a disk roll, the method comprising: providing ceramic fibers comprising 30 wt % or more and less than 70 wt % of alumina, more than 30 wt % and 70 wt % or less of silica, and 5 wt % or less of shots having a diameter of 45 m or more; mixing water, the ceramic fibers, kibushi clay, bentonite and mica to produce an aqueous slurry comprising, in solid content, 5 to 9 wt % of the ceramic fibers, 20 to 40 wt % of the kibushi clay, 2 to 20 wt % of the bentonite, and 40 to 60 wt % of the mica; and flowing the aqueous slurry in a forming chamber or a forming mold, followed by water filtration to produce a sheet.

5. A disk roll which comprises ring-like disk materials obtained from the base material according to claim 1.

6. A method for producing a disk roll, the method comprising: providing a base material according to claim 1; punching out a plurality of ring-like disk materials from the base material according to claim 1; and fitting by insertion the plurality of ring-like disk materials into a shaft, followed by compression to obtain a roll-like laminate.

7. A method for producing glass comprising conveying a glass melt by means of the disk roll according to claim 5, and cooling the glass melt.

8. The base material for a disk roll according to claim 2, which further comprises pulp and starch.

9. The base material for a disk roll according to claim 1, which further comprises pulp and starch.

10. The base material for a disk roll according to claim 2, which further comprises pulp and starch.

11. A disk material for a disk roll, the disk material comprising: 5 to 9 wt % of ceramic fibers, 20 to 40 wt % of kibushi clay, 2 to 20 wt % of bentonite and 40 to 60 wt % of mica, wherein the amount of shots having a diameter of 45 m or more in the ceramic fibers is 5 wt % or less.

12. A method for producing a disk material for a disk roll, the method comprising: providing a base material according to claim 1; and punching out a ring-like disk material from the base material according to claim 1.

13. The base material for a disk roll according to claim 1, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, and 40 to 54 wt % of the mica, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

14. The base material for a disk roll according to claim 1, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, 40 to 54 wt % of the mica, 2 to 10 wt % of pulp, and 1 to 10 wt % of starch, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

15. The base material for a disk roll according to claim 1, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, 44 to 54 wt % of the mica, 2 to 10 wt % of pulp, and 1 to 10 wt % of starch, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

16. The base material for a disk roll according to claim 1, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, 44 to 54 wt % of the mica, 5 to 10 wt % of pulp, and 1 to 4 wt % of starch, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

17. The base material for a disk roll according to claim 2, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, and 40 to 54 wt % of the mica, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

18. The base material for a disk roll according to claim 2, wherein the base material comprises 6 to 8 wt % of the ceramic fibers, 28 to 38 wt % of the kibushi clay, 5 to 14 wt % of the bentonite, 44 to 54 wt % of the mica, 5 to 10 wt % of pulp, and 1 to 4 wt % of starch, and wherein a total amount of the ceramic fibers, kibushi clay, bentonite and mica is 90 wt % or more.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a view showing one example of a method for producing glass by using a disk roll.

MODE FOR CARRYING OUT THE INVENTION

(2) The base material for a disk roll of the invention comprises ceramic fibers (alumina silicate fibers, or the like), kibushi clay, bentonite and mica.

(3) The ceramic fibers are contained in an amount of 5 to 9 wt %, preferably 6 to 9 wt %, more preferably 7 to 8 wt %. If the amount of ceramic fibers is less than 5 wt %, heat resistance is lowered when the base material is molded into a disk roll. If the amount of ceramic fibers exceeds 9 wt %, the density of a disk material before packing is lowered. Therefore, when adjusting to a specific packing density, the volume of a disk material is increased, whereby workability at the time of packing is lowered. In addition, if the amount of ceramic fibers is large, the cost is increased.

(4) The ceramic fibers used in the invention normally comprise 30 wt % or more and less than 70 wt %, preferably 40 wt % or more and less than 60 wt %, more preferably 45 wt % or more and less than 55 wt % of alumina. Further, the ceramic fibers normally comprise more than 30 wt % and 70 wt % or less, preferably more than 40 wt % and 60 wt % or less, and more preferably more than 45 wt % and 55 wt % or less of silica. Fibers may be used singly or in a mixture of two or more types.

(5) The ceramic fibers used in the invention contain shots (non-fibrous parts) having a diameter of 45 m or more preferably in an amount of 5 wt % or less, more preferably only 2 wt % or less. A disk roll produced by using fibers that contain a large amount of shots may cause the surface of glass to be scratched. The size of shots is normally about 45 to 5000 m. The amount of shots can be decreased by desulfurizing ceramic fibers as raw materials by a dry or wet method.

(6) The fiber diameter of ceramic fibers is normally about 2 to 5 m.

(7) The base material comprises kibushi clay in an amount of 20 to 40 wt %, preferably 25 to 40 wt %, and more preferably 28 to 38 wt %. Due to the presence of kibushi clay in this range, surface lubricity (smoothness) will be improved.

(8) Bentonite is contained in an amount of 2 to 20 wt %, preferably 2 to 15 wt %, more preferably 3 to 15 wt %, and further preferably 5 to 14 wt %. If bentonite is not contained, water filterability may be poor due to insufficient fixation and agglomeration. On the other hand, if the amount of bentonite is too large, viscosity of a slurry is increased, leading to poor water filterability.

(9) Mica is added in order to increase the followingness of a disk material to thermal expansion of the shaft. Since the shaft to which a disk material is fitted by insertion is made of a metal, when exposed to high temperatures, this shaft is thermally expanded and extended in the axial direction. At this time, due to a low thermal expansion as compared with that of a metal, the disk material cannot follow the extension of the shaft, resulting in peeling of disk materials. On the other hand, mica has a significantly thin layer structure. Therefore, when heated, mica undergoes crystal modification. At this time, mica tends to expand in the direction of a layer. Due to such expansion in the layer direction, followingness of a disk material to thermal expansion of the shaft is increased.

(10) As mica, white mica (muscovite; K.sub.2Al.sub.4 (Si.sub.3Al).sub.2O.sub.20(OH).sub.4), black mica, gold mica (phlogopite; K.sub.2Mg.sub.6(SiAl).sub.2O.sub.20(OH).sub.4), paragonite, lepidolite, synthetic fluorine mica or the like can be used. In respect of the above-mentioned followingness, white mica is preferable.

(11) The base material comprises mica in an amount of 40 to 60 wt %, preferably 44 to 54 wt %. If the amount of mica is less than 40 wt %, the followingness of a disk material to thermal expansion of the shaft is decreased. If the amount of mica exceeds 60 wt %, it becomes difficult to disperse it homogenously in a slurry. As a result, there is a concern that physical properties of the base material for a disk may vary widely.

(12) The base material of the invention may contain an agglomeration aid and an organic binder in addition to the above-mentioned components within a range that the advantageous effects of the invention are not impaired.

(13) As the organic binder, organic fibers (pulp) and starch are preferable. If organic fibers (pulp) are contained, compression properties can be developed. The amount thereof may be 2 to 10 wt % or 5 to 10 wt %, for example. If starch is contained, the strength of a disk material can be exhibited. The amount thereof may be 1 to 10 wt % or 1 to 4 wt %, for example.

(14) The base material of the invention may contain, as inorganic components, ceramic fibers, kibushi clay, bentonite and mica in a total amount of 85 wt % or more, 90 wt % or more, 95 wt % or more, 98 wt % or more, 99 wt % or more and 100 wt %.

(15) In the base material of the invention, due to the presence of the above-mentioned components within the above-mentioned range, it is possible to obtain a disk roll having heat resistance, strength and hardness in a well-balanced manner even if the amount of the inorganic fibers is small.

(16) The base material can be produced by forming an aqueous slurry that contains inorganic fibers, kibushi clay, bentonite and mica in a plate-like shape, followed by drying. At this time, it is preferable to use a paper-making method in respect of efficiency. Specifically, an aqueous slurry containing inorganic fibers, kibushi clay, bentonite, mica, an agglomeration aid, an organic binder or the like (if necessary) in a predetermined amount is prepared, the aqueous slurry is formed into a plate by a paper-making machine, followed by drying, whereby the base material can be obtained. The thickness of the base material can be set appropriately. The thickness is normally 2 to 10 mm.

(17) Next, an explanation will be made on the method for producing a disk roll. Normally, ring-like disk materials are punched out from the base material. A plurality of disk materials are fitted by insertion to a metal (for example, iron) shaft, whereby a roll-like laminate is obtained. The entire roll-like laminate is compressed from the both ends thereof through a flange provided at the both ends, and fixed by means of a nut or the like in the state where the disk materials are slightly compressed. The laminate is fired, if necessary. By grinding the outer peripheral surface of the disk materials such that a desired roll diameter can be obtained, a disk roll can be obtained.

(18) As for the shape of a disk roll, a full cover roll, a cantilever roll, a stub roll or the like can be mentioned.

(19) For example, as shown in FIG. 1, a glass melt 100 is conveyed while being disposed between disk rolls 10 of the invention. The glass melt 100 is cooled and hardened, whereby glass can be produced.

EXAMPLES

Example 1

Preparation and Evaluation of a Base Material for a Disk Roll

(20) An aqueous slurry comprising 7 wt % of ceramic fibers (alumina: 40 to 60 wt %, silica: 60 to 40 wt %), 30 wt % of kibushi clay, 10 wt % of bentonite, 45 wt % of white mica, 6 wt % of pulp and 2 wt % of starch was prepared. A sheet (a base material for a disk roll) was prepared by a paper-making method.

(21) For the resulting base material, measurement or evaluation of the properties was conducted by the following method. The results are shown in Table 1.

(1) Water Filterability

(22) Evaluation was conducted in terms of water filtering time by means of a TAPPI hand-made paper-making machine.

(23) : Shorter than 100 seconds : 100 to 200 seconds x: Longer than 200 seconds

(2) Appearance of a Sheet

(24) : Excellent : Uneven x: Cracked

(3) Heat Shrinkage

(25) The base material for a disk roll was cut into a width of 30 mm and a length of 150 mm. The base material was heated at 900 C. for 3 hours, and thereafter, the length in the line direction and the length in the thickness direction were measured. Heat shrinkage was evaluated based on the following formula:
[(Measurement value before heatingMeasurement value after heating)/Measurement value before heating]100

(4) Bending Strength Test of an Original Plate (Bending Strength and Bending Modulus of Elasticity)

(26) After retaining the base material for a disk roll in a heating furnace kept at 900 C. for 3 hours, the base material was naturally cooled to room temperature. From the base material before heating and from the base material after cooling, a test specimen having a width of 30 mm and a length of 150 mm was cut out, respectively. By using an Autograph AG-100 kND manufactured by Shimadzu Corporation, the bending strength and the flexural modulus of elasticity were evaluated in accordance with JIS K7171.

(5) Spalling Resistance

(27) From the base material for a disk roll, a disk material having an outer diameter of 60 mm and an inner diameter of 20 mm was punched out. The disk materials were assembled into a 20 mm-diameter stainless-made shaft in the form of a roll such that the length of the roll became 100 mm and the packing density of the roll became values shown in Table 1, whereby a disk roll was prepared.

(28) This disk roll was put in an electric furnace kept at 900 C. After the lapse of 15 hours, the disk roll was taken out and quenched to room temperature (25 C.). This cycle of heating and quenching was repeated until cracks were formed or disk separation occurred in the disk roll, and the number of cycles when cracks were formed or disk separation occurred was counted.

(29) In addition, the Shore D hardness of the disk material before the spalling resistance test and the hardness of the disk material after cracks were formed or disk separation occurred (after the test) were respectively evaluated.

(6) Amount of Load Deformation

(30) From the base material for a disk roll, a disk material having an outer diameter of 60 mm and an inner diameter of 20 mm was punched out. The disk materials were assembled to a 20 mm-diameter stainless-made shaft in the form of a roll such that the length of the roll became 100 mm and the packing density of the roll became values shown in Table 1, whereby a disk roll was prepared.

(31) As for the thus obtained disk roll, the both ends of the shaft were supported by a supporting stand, whereby a load of 10 kgf/cm was applied by means of a compressing element to the roll surface made of disk materials at 1 mm/min, and an amount of load deformation (room temperature) at that time was measured.

(32) As for the disk roll obtained by retaining in a heating furnace at 900 C. for 10 hours, taking out from the heating furnace, and cooling to room temperature, the amount of load deformation (900 C., 10 hours) was measured in the same manner as mentioned above.

Referential Example 1

(33) A base material and a disk roll were produced and evaluated in the same manner as in Example 1, except that an aqueous slurry comprising 30 wt % of ceramic fibers (alumina: 50 wt %, silica: 50 wt %), 20 wt % of kibushi clay, 10 wt % of bentonite, 32 wt % of white mica, 6 wt % of pulp and 2 wt % of starch was used. The results are shown in Table 1.

(34) TABLE-US-00001 TABLE 1 Refer- ential Example 1 Example 1 Composition Ceramic fibers % 7 30 White mica % 45 32 Kibushi clay % 30 20 Bentonite % 10 10 Pulp % 6 6 Starch % 2 9 Plate making Water filterability Water filtering 60 30 properties time (sec) Evaluation Appearance Evaluation of sheet Physical Density of g/cm.sup.3 1.00 0.7 properties original sheet of sheet Heat shrinkage Line direction 0.51 0.2 (%) 900 C. Thickness 0.96 1.6 3 hr direction Bending strength Unheated 10.76 4.7 (Mpa) 900 C. 6.34 2.8 900 C. 3 hr Bending modulus Unheated 4072 1377 of elasticity 900 C. 4373 1472 (Mpa) 900 C. 3 hr Physical Standard g/cm.sup.3 1.4 1.25 properties density of roll Spalling Number of 1 2 resistance tests Hardness 56 50 before test Hardness 58 52 after test Amount of load Unheated 0.15 deformation 900 C. 0.03 0.11

(35) From the results of Table 1, it can be understood that the disk roll of Example 1 had practically satisfactory heat resistance and strength that are equivalent to these of Referential Example 1 in spite of a small fiber amount.

INDUSTRIAL APPLICABILITY

(36) The disk roll of the invention can be used in production of plate glass, in particular for the production of a liquid crystal display, a plasma display and an organic EL display.

(37) Although only some exemplary embodiments and/or examples of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments and/or examples without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention.

(38) The documents described in the specification of a Japanese application on the basis of which the present application claims Paris convention priority are incorporated herein by reference in its entirety.