Mold release agent for water glass-containing sand mold molding

Abstract

[Task] There is provided a mold release agent for forming a water glass-containing sand mold with high release properties which can prevent attachment of a water glass to a flask and the accumulation of the water glass on the flask in the formation of the sand mold when using the water glass as a binder. [Solution] The mold release agent for forming the water glass-containing sand mold is structured to contain an organic compound, the organic compound having a proton-donating functional group that reacts with the water glass to produce silicon dioxide. The water glass contained in a raw material for the sand mold reacts with the proton-donating functional group contained in the mold release agent so as to produce silicon dioxide. Since silicon dioxide has no adhesion, it can prevent that the attachment (fixing) of the water glass contained in a formed sand mold to the flask and the accumulation of the water glass on the flask.

Claims

1. A mold release agent for forming a water glass-containing sand mold, the mold release agent being applied to an inner surface of a flask and raw material forming the water glass-containing sand mold being introduced into the flask, wherein the mold release agent contains an organic compound having a proton-donating functional group, wherein the proton-donating functional group is allowed to react with the water glass contained in the raw material of the sand mold, and the reaction performed between the proton-donating functional group and the water glass produces silicon dioxide preventing fixation between the sand mold containing the water glass therein and the inner surface of the flask.

2. The mold release agent for forming a water glass-containing sand mold according to claim 1, wherein the organic compound includes the proton-donating functional group selected from the group consisting of a carboxyl group, a carbonyl group and a hydroxyl group.

3. The mold release agent for forming a water glass-containing sand mold according to claim 2, wherein the organic compound is a chain organic compound having a carboxyl group in an amount of more than 0.0001 mol/kg and 0.0500 mol/kg or less.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a view showing a chemical reaction of a mold release agent for forming a water glass-containing sand mold according to an embodiment of the present invention.

(2) FIG. 2 is a view showing a structure and a chemical reaction of a mold release agent for forming a water glass-containing sand mold according to another embodiment.

MODES FOR CARRYING OUT THE INVENTION

(3) Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(4) As described in Problem to be Solved by the Invention, water glass is easily attached (fixed) to a flask due to its high affinity to another substance such as metal. In a case of a method for forming a casting mold through injection filling, a water-containing kneaded mixture (kneaded mixture obtained by adding water glass to foundry sand) is heated to evaporate water content, and then cured by causing a polymerization reaction of water glass. At that time, a pressure is kept being applied by an injection cylinder until the water content is gone, and as a result, an internal pressure due to steam is suppressed to prevent reflux of the kneaded mixture. Consequently, a pressure needs to be applied until the kneaded mixture is cured to prevent reflux. At that time, the kneaded mixture is pressed onto the surface of the flask, water glass is attached (fixed) to the flask, and the kneaded mixture may be extruded from the aperture of the flask. Thus, water glass is likely to accumulate on the flask. Accordingly, a high-performance mold release agent that prevents attachment and accumulation of water glass is necessary.

(5) The present inventors have intensively investigated and performed experiments to solve the problems, and as a result, invented a mold release agent containing an organic compound (e.g., fatty acid) having a proton-donating functional group that reacts with water glass to produce silicon dioxide for formation of a water glass-containing sand mold.

(6) When a substance having a proton-donating functional group that reacts with water glass to produce silicon dioxide, as shown in FIG. 1, is used for formation of a sand mold using water glass as a binder, water glass contained in a raw material for the sand mold reacts with the proton-donating functional group contained in a mold release agent to produce silicon dioxide. Since silicon dioxide has no adhesion, it can prevent attachment (fixing) of water glass contained in a sand mold formed to a flask and accumulation of water glass on the flask.

(7) Specifically, water glass contained in the kneaded mixture is heated to evaporate water content, resulting in a condensation reaction. This causes water glass to form a strong structure in which a bond of OSiO forms a three-dimensional net. This structure expresses strength of a casting mold. Before formation of the three-dimensional structure, the substance having a proton-donating functional group in the mold release agent reacts with water glass as an alkali, to produce silicon dioxide. Silicon dioxide is produced on the interface between the casting mold and the flask so as to be able to prevent formation of a three-dimensional net structure between the casting mold and the flask and eliminate adhesion. Further, due to its low-density crystalline structure, pressure contact is prevented, resulting in excellent release properties. Thus, a high-performance mold release agent can be obtained in which attachment and accumulation of water glass can be prevented.

(8) The present invention can particularly provide a high-performance mold release agent that exhibits high release properties when using an organic compound having a carboxyl group as the functional group (FIG. 2 is a representative example of a structural formula thereof and a chemical reaction formula) as described in Experimental Examples below, and prevents attachment and accumulation of water glass.

EXAMPLES

Experimental Example 1

(9) To obtain a high-performance mold release agent for forming a water glass-containing sand mold, an example of the experiment conducted to find an organic compound having a proton-donating functional group is shown below.

Experimental Method

(10) A mold release agent for forming a water glass-containing sand mold (sample) produced from each of 11 different organic chemicals, including materials having different proton-donating functional groups, was used in a test of forming a sand mold through the following procedures. An attached substance to a flask for forming a sand mold was observed.

(11) Procedure 1

(12) A cylindrical flask (cylindrical flask for forming a sand mold) was prepared. An upper flask and a lower flask (collectively referred to as a columnar flask) having a columnar shape, which can be inserted in the cylindrical flask by rubbing and are made of copper alloy, were also prepared. The cylindrical flask, the upper flask, and the lower flask were heated at a predetermined temperature, which was 260 C. here. The sample (mold release agent) was applied to the surfaces of the upper flask and the lower flask coming into contact with a formed object described below and the inner surface of the cylindrical flask with a pressure spray.

(13) Procedure 2

(14) Immediately after the application, the lower flask was inserted in the cylindrical flask, and a raw material for a sand mold (kneaded mixture obtained by adding water glass to foundry sand) was then added.

(15) Procedure 3

(16) The upper flask was inserted in the cylindrical flask from the top thereof, and the raw material for a sand mold was disposed between the upper flask and the lower flask.

(17) Procedure 4

(18) Immediately after the raw material was disposed between the flasks, the upper flask in the cylindrical flask was pressurized in a direction from the top to the bottom.

(19) Procedure 5

(20) After a predetermined period of time, which was one minute later here, the lower flask in the cylindrical flask was pulled out of the cylindrical flask from the bottom.

(21) Procedure 6

(22) Subsequently, the cylindrical flask was reversed (reversely turned), and the upper flask in the cylindrical flask was pulled out of the reversed cylindrical flask from the bottom.

(23) Procedure 7

(24) Then, a formed object remaining in the cylindrical flask (formed object obtained as a sand mold by heating and pressurizing the raw material for a sand mold) was then pressed downward by inserting an extrusion bar into the reversed cylindrical flask from the top, and pulled out of the cylindrical flask.

(25) Procedure 8

(26) The procedures 1 to 7 were repeated five times, to obtain five formed objects. Then, it was observed whether or not an attached substance to the flasks (the cylindrical flask and the columnar flask) was present when the formed object was obtained each time.

Experimental Results

(27) The following observation results are obtained in the experiments.

(28) a) In a case of a chain organic compound (fatty acid) having a proton-donating carboxyl group

(29) Water glass is attached to the side of the columnar flask.

(30) The material for the formed object is not attached to the contact surface of the columnar flask with the formed object.

(31) Water glass is not attached to the inner surface of the cylindrical flask.

(32) Carbide does not accumulate on the flask.

(33) b) In a case of a chain organic compound (polysiloxane) having a proton-donating carboxyl group

(34) Water glass is attached to the side of the columnar flask.

(35) A white powder that has been produced by a reaction with the carboxyl group is on the contact surface of the columnar flask with the formed object. The white powder can be easily removed by air and is not fixed on the contact surface.

(36) Water glass is not attached to the inner surface of the cylindrical flask.

(37) Carbide does not accumulate on the flask.

(38) c) In a case of a chain organic compound (polysiloxane) having a proton-donating carbonyl group

(39) Water glass is attached to the side of the columnar flask.

(40) The material for the formed object is not attached to the contact surface of the columnar flask with the formed object.

(41) Water glass is not attached to the inner surface of the cylindrical flask.

(42) Carbide does not accumulate on the flask.

(43) d) In a case of a chain organic compound (polysiloxane) having a proton-donating hydroxyl group

(44) Water glass is not attached to the side of the columnar flask.

(45) The material for the formed object is not attached to the contact surface of the columnar flask with the formed object.

(46) Water glass is not attached to the inner surface of the cylindrical flask.

(47) Carbide does not accumulate on the flask.

(48) e) In a case of only water

(49) Sand in the material for the formed object is attached to the side of the columnar flask.

(50) Sand in the material for the formed object is attached to the contact surface of the columnar flask with the formed object.

(51) Water glass is attached to the inner surface of the cylindrical flask.

(52) Carbide does not accumulate on the flask.

(53) f) In a case of a chain organic compound A (polysiloxane) having no proton-donating functional group

(54) Water glass is not attached to the side of the columnar flask.

(55) Sand in the material for the formed object is attached to the contact surface of the columnar flask with the formed object.

(56) Water glass is attached to the inner surface of the cylindrical flask.

(57) Carbide does not accumulate on the flask.

(58) g) In a case of a chain organic compound B (polysiloxane) having no proton-donating functional group

(59) Water glass is attached to the side of the columnar flask.

(60) Sand in the material for the formed object is attached to the contact surface of the columnar flask with the formed object.

(61) Water glass is attached to the inner surface of the cylindrical flask.

(62) Carbide does not accumulate on the flask.

(63) h) In a case of a cyclic organic compound (base oil: alkyl naphthalene) having no proton-donating functional group

(64) Water glass is not attached to the side of the columnar flask.

(65) Sand in the material for the formed object is attached to the contact surface of the columnar flask with the formed object.

(66) Water glass is not attached to the inner surface of the cylindrical flask.

(67) Carbide does not accumulate on the flask.

(68) i) In a case of a chain organic compound (base oil: poly--olefin) having no proton-donating functional group

(69) Water glass is not attached to the side of the columnar flask.

(70) The material for the formed object is not attached to the contact surface of the columnar flask with the formed object.

(71) Water glass is attached to the inner surface of the cylindrical flask. Carbide accumulates on the flask.

(72) j) In a case of a cyclic organic compound (base oil: naphthene-based oil) having no proton-donating functional group

(73) Water glass is attached to the side of the columnar flask.

(74) The material for the formed object is attached to the contact surface of the columnar flask with the formed object.

(75) Water glass is attached to the inner surface of the cylindrical flask.

(76) Carbide accumulates on the flask.

(77) k) In a case of a polyester organic compound (polyester) having no proton-donating functional group

(78) Water glass is attached to the side of the columnar flask.

(79) The material for the formed object is not attached to the contact surface of the columnar flask with the formed object.

(80) Water glass is attached to the inner surface of the cylindrical flask.

(81) Carbide accumulates on the flask.

(82) The experimental results are summarized in Table 1.

(83) TABLE-US-00001 TABLE 1 Evaluation Fixing to con- Fixing to Material type tact surface interior Accumu- Example/ Proton- of columnar surface of lation in Comparative Material donating Functional Classifi- flask with cylindrical flask Example No. ability group cation formed object flask (carbide) Example Material Yes Carboxyl Fatty acid None None None 1 group Example Material Yes Carboxyl Polysiloxane Powder None None 2 group (can be removed) Example Material Yes Carbonyl Polysiloxane None None None 3 group Example Material Yes Hydroxyl Polysiloxane None None None 4 group Comparative Material No Water Attached Attached (water None Example 5 (sand) * glass) Comparative Material No Methyl Polysiloxane Attached Attached (water None Example 6 group (sand) * glass) Comparative Material No Alkyl/ Polysiloxane Attached Attached (water None Example 7 aralkyl (sand) * glass) group Comparative Material No Lubricating Attached None None Example 8 oil (cyclic) (sand) * Comparative Material No Lubricating None Attached (water Present * Example 9 oil (chain) glass) Comparative Material No Lubricating Attached Attached (water Present * Example 10 oil (cyclic) (sand) * glass) Comparative Material No Lubricating None Attached (water Present * Example 11 oil (ester) glass) * represents that the material has a problem

(84) The amount of carboxyl group in Material 1 during the experiment is 0.0500 mol/kg.

(85) The amount of carboxyl group in Material 2 during the experiment is 0.0250 mol/kg.

(86) The amount of functional group in Material 3 during the experiment is 0.0450 mol/kg.

(87) The amount of functional group in Material 4 during the experiment is 0.0550 mol/kg.

(88) Based on the experimental results, the following evaluation results are obtained.

(89) I) For the materials of the samples having a proton-donating functional group, the material for the formed object is not attached (fixed) to the forming surface of the flask.

(90) II) For the materials of the samples having no proton-donating properties, some materials for the formed object are not attached (fixed) to the forming surface of the flask, but water glass is attached to the cylindrical flask, and a carbonated organic substance accumulates on the flask. Therefore, the materials of the samples are not suitable for continuous use as a material for a mold release agent.

(91) III) Based on I) and II), a result is obtained in which the organic compound having a proton-donating functional group can be provided as a mold release agent for forming a water glass-containing sand mold that can solve the problem described above.

Experimental Example 2

(92) To obtain a high-performance mold release agent for forming a water glass-containing sand mold containing an organic compound having a carboxyl group as a proton-donating functional group, an example of the experiment conducted to find a suitable amount of carboxyl group is shown below.

Experimental Method

(93) A mold release agent for forming a water glass-containing sand mold (sample) produced from each of 6 different amounts of carboxyl group (mole amount per unit weight of mold release agent) was used in a test of forming a sand mold through the same procedures as in Experimental Example 1. An attached substance to a flask for forming a sand mold was observed.

Experimental Results

(94) The following observation results are obtained in the experiments.

(95) a) In a case where the amount of carboxyl group (mole amount of carboxyl group per unit weight of the mold release agent, the same applies hereinafter) is 0.1500 mol/kg

(96) A large amount of component containing a carboxyl group accumulates due to the organic chain.

(97) A white substance that has been produced by a reaction with the carboxyl group is attached to the formed object.

(98) b) In a case where the amount of carboxyl group is 0.1000 mol/kg

(99) A large amount of component containing a carboxyl group accumulates due to the organic chain.

(100) A white substance that has been produced by a reaction with the carboxyl group is attached to the formed object.

(101) c) In a case where the amount of carboxyl group is 0.0500 mol/kg

(102) A large amount of water glass is attached to the side of the columnar flask. Water glass is not attached to the inner surface of the cylindrical flask.

(103) A white substance that has been produced by a reaction with the carboxyl group is attached to the formed object.

(104) d) In a case where the amount of carboxyl group is 0.0100 mol/kg

(105) Water glass is attached to the side of the columnar flask.

(106) Water glass is not attached to the inner surface of the cylindrical flask.

(107) e) In a case where the amount of carboxyl group is 0.0010 mol/kg

(108) Water glass is attached to the side of the columnar flask.

(109) Water glass is not attached to the inner surface of the cylindrical flask.

(110) f) In a case where the amount of carboxyl group is 0.0001 mol/kg

(111) Sand is attached to the side of the columnar flask.

(112) Water glass is attached to the inner surface of the cylindrical flask.

(113) The experimental results are summarized in Table 2.

(114) TABLE-US-00002 TABLE 2 Material type Evaluation Amount of Fixing to Example/ carboxyl inner surface Formed object Comparative Material Functional group Attachment to side of cylindrical (release Example No. group [mol/kg] of columnar flask flask properties) Example Material Carboxyl 0.1500 Attached (dirt) * None Attached reactant 12 group (large amount) Example Material Carboxyl 0.1000 Attached (dirt) * None Attached reactant 13 group (large amount) Example Material Carboxyl 0.0500 Attached (water None Attached reactant 14 group glass) (large amount) Example Material Carboxyl 0.0100 Attached (water None Attached reactant 15 group glass) (small amount) Example Material Carboxyl 0.0010 Attached (water None Attached reactant 16 group glass) (small amount) Example Material Carboxyl 0.0001 Attached (sand) * Present * Release failure * 17 group * represents that the material has a problem

(115) Based on the experimental results, the following evaluation results are obtained.

(116) I) For the amount of carboxyl group of 0.0001 mol/kg or less, sand in the material for the formed object is attached to the columnar flask, water glass is attached (fixed) to the cylindrical flask, and an effect of the reaction (release properties) is not obtained. From this, the amount of carboxyl group is assumed to be insufficient.

(117) II) For the amount of carboxyl group of more than 0.0001 mol/kg and 0.0500 mol/kg or less, water glass is not attached (fixed) to the inner surface of the cylindrical flask. Attachment of water glass to the columnar flask is caused by an increase in the amount of water glass. This increase is for markedly exhibiting attachment difference (test results). The effect of the reaction of the formed object (release properties) is good, and the amount of carboxyl group is preferred.

(118) III) For the amount of carboxyl group of more than 0.0100 mol/kg, a substance derived from thermal properties other than the carboxyl group accumulates, and the effect of thermal degradation is remarkable. Another factor needs to be confirmed to use the carboxyl group as a preferable mold release agent, although the carboxyl group reacts with the water glass component.

(119) IV) According to I) to III), it was verified that the suitable amount of carboxyl group was more than 0.0001 mol/kg and 0.0500 mol/kg or less. Specifically, a result is obtained in which a mold release agent for forming a water glass-containing sand mold containing an organic compound having the amount of carboxyl group described above can be provided as the mold release agent for forming a water glass-containing sand mold that can solve the problem.

(120) As described above, the embodiments of the present invention can provide a high-performance mold release agent for forming a water glass-containing sand mold, which has high release properties, so that attachment (fixing) of water glass to the flask and accumulation of water glass on the flask are prevented when forming the sand mold (main mold and core) using water glass as a binder.