ALPHA-AL2O3 FLAKES

Abstract

The present invention relates to -Al.sub.2O.sub.3 flakes prepared by a process comprising (1) preparation of an aqueous solution of at least one water-soluble and/or insoluble aluminum salt which optionally contains at least one sulfate compound, (2) adding a basic solution and optionally at least one dopant to the aluminum salt solution (1), (3) drying of the obtained gel, followed by calcination to obtain Al2 03 flakes and alkali salts in a molten salt, and (4) removal of the water soluble parts of the calcined molten salt obtained in step (3).

Claims

1. Al.sub.2O.sub.3 flakes prepared by a process comprising the following steps: (1) preparation of an aqueous solution of at least one water-soluble and/or insoluble aluminum salt which optionally contains at least one sulfate compound, (2) adding a basic solution and optionally at least one dopant to the aluminum salt solution (1), (3) drying of the obtained gel, followed by calcination to obtain Al.sub.2O.sub.3 flakes and alkali salts in a molten salt, (4) removal of the water soluble parts of the calcined molten salt obtained in step (3).

2. Al.sub.2O.sub.3 flakes according to claim 1, wherein the sulfate compound is alkali metal sulfate.

3. Al.sub.2O.sub.3 flakes according to claim 1, wherein the sulfate compound is selected from sodium sulfate, potassium sulfate, lithium sulfate and combinations thereof.

4. Al.sub.2O.sub.3 flakes according to claim 1, wherein the basic solution is selected from ammonia, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and combinations thereof.

5. Al.sub.2O.sub.3 flakes according to claim 1, wherein the dopant is selected from TiO.sub.2, ZrO.sub.2, SiO.sub.2, SnO.sub.2, In.sub.2O.sub.3, ZnO and combinations thereof.

6. Al.sub.2O.sub.3 flakes according to claim 1, wherein amount of the dopant is 0.01-5% by weight based on the Al.sub.2O.sub.3 flake.

7. Al.sub.2O.sub.3 flakes according to claim 1, wherein the dopant is TiO.sub.2, SnO.sub.2 or ZnO.

8. Al.sub.2O.sub.3 flakes according to claim 1, wherein total molar ratio of the sulfate compound to Al.sub.2O.sub.3 is 1 to 3.5 after step (2).

9. Al.sub.2O.sub.3 flakes according to claim 1, wherein the calcination temperature is from 900 to 1400 C.

10. Al.sub.2O.sub.3 flakes according to claim 1 having a D.sub.50-value of 5-15 m and a D.sub.80-value of less than 20 m.

11. Al.sub.2O.sub.3 flakes according to claim 1, characterised in that they have a particle thickness of 500 nm.

12. Al.sub.2O.sub.3 flakes according to claim 1, characterised in that the Al.sub.2O.sub.3 flakes are -alumina flakes.

13. Al.sub.2O.sub.3 flakes according to claim 1, characterised in that the MIU value (MIU value measured by the KES friction tester) is less than 0.8.

14. Al.sub.2O.sub.3 flakes according to claim 1, characterised in that the flakes are coated with one or more metal oxides.

15. Al.sub.2O.sub.3 flakes according to claim 1, characterised in that the flakes are coated with the following layer sequence: Al.sub.2O.sub.3 flake+TiO.sub.2 Al.sub.2O.sub.3 flake+TiO.sub.2/Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+TiO.sub.2+Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+TiO.sub.2+Fe.sub.3O.sub.4 Al.sub.2O.sub.3 flake+TiO.sub.2+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+TiO.sub.2+SiO.sub.2 Al.sub.2O.sub.3 flake+TiO.sub.2+SiO.sub.2/Al.sub.2O.sub.3 Al.sub.2O.sub.3 flake+TiO.sub.2+Al.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SnO.sub.2 Al.sub.2O.sub.3 flake+SnO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+SnO.sub.2+Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2+Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+Fe.sub.3O.sub.4 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+SiO.sub.2 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+SiO.sub.2/Al.sub.2O.sub.3 Al.sub.2O.sub.3 flake+SiO.sub.2+TiO.sub.2+Al.sub.2O.sub.3 Al.sub.2O.sub.3 flake+TiO.sub.2+Prussian Blue Al.sub.2O.sub.3 flake+TiO.sub.2+Carmine Red

16. A method comprising including the Al.sub.2O.sub.3 flakes according to claim 1 as filler, as substrate for effect pigments, in formulations selected from paints, coatings, automobile coatings, automotive finishing, industrial coatings, paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, cosmetics, glasses, paper, paper coating, toners for electrophotographic printing processes, seeds, greenhouse sheeting and tarpaulins, thermally conductive, self-supporting, electrically insulating, flexible sheets for the insulation of machines or devices, as absorber in the laser marking of paper and plastics, as absorber in the laser welding of plastics, pigment pastes with water, organic and/or aqueous solvents, in pigment preparations and dry preparations.

17. A filler for cosmetic formulations comprising Al.sub.2O.sub.3 flakes according to claim 1.

18. A filler for decorative application and personal care applications comprising Al.sub.2O.sub.3 flakes according to claim 1.

19. Formulation containing Al.sub.2O.sub.3 flakes according to claim 1 in amounts of 0.01-95% by weight, based on the formulation as a whole.

20. Formulation containing Al.sub.2O.sub.3 flakes according to claim 19, characterised in that it contains at least one component selected from the group of water, polyols, polar and non-polar oils, fats, waxes, film formers, polymers, copolymers, surfactants, free-radical scavengers, antioxidants, stabilisers, odour enhancers, silicone oils, emulsifiers, solvents, preservatives, thickeners, rheological additives, fragrances, colorants, effect pigments, UV absorbers, surface-active assistants and/or cosmetic active compounds, fillers, binders, pearlescent pigments, color pigments and organic dyes.

Description

EXAMPLES

Example 1

[0111] In 450 ml of deionized water are dissolved 111.9 g of aluminum sulfate 18-hydrate by heating above 60 C. The resulting solution is designated as the aqueous solution (a).

[0112] In 150 ml of deionized water are dissolved 55.0 g of sodium carbonate. The resulting solution is designated as the aqueous solution (b).

[0113] The aqueous solution (b) is added with stirring to the aqueous solution (a) kept at about 60 C. Stirring is continued for 15 minutes. The resulting mixture of the two solutions is a gel. The gel is evaporated to dryness, and the dried product is heated at 1200 C. for 5 hours. Water is added to the heated product to dissolve free sulfate. Insoluble solids are filtered off, washed with water, and finally dried. The obtained alumina flake is examined by X-ray diffractometry. The diffraction pattern has only peaks attributed to corundum structure (-alumina structure).

[0114] D.sub.50 is 11.3 m and D.sub.80 is 16.2 m. The MIU value is 0.55 measured by the KES friction tester.

Example 2

[0115] 3.6 g of sodium sulfate is added in the aqueous solution (a) of Example 1. The obtained alumina flake is examined by X-ray diffractometry. The diffraction pattern has only peaks attributed to corundum structure (-alumina structure).

[0116] D.sub.50 is 12.3 m and D.sub.80 is 17.0 m. The MIU value is 0.59 measured by the KES friction tester.

Example 3

[0117] 11.9 g of sodium sulfate is added in the aqueous solution (a) of Example 1. The obtained alumina flake is examined by X-ray diffractometry. The diffraction pattern has only peaks attributed to corundum structure (-alumina structure).

[0118] D.sub.50 is 12.9 m and D.sub.80 is 17.8 m. The MIU value is 0.70 measured by the KES friction tester.

Example 4

[0119] 0.50 g of 3.44% solution of titanyl sulfate is added in the aqueous solution (a) of Example 1.

[0120] The obtained alumina flake is examined by X-ray diffractometry. The diffraction pattern has only peaks attributed to corundum structure (-alumina structure).

[0121] D.sub.50 is 11.5 m and D.sub.80 is 15.8 m measured by Malvern MS 2000. The MIU value is 0.56 measured by the KES friction tester.

Comparative Example 1

[0122] In 300 ml of deionized water are dissolved 111.9 g of aluminum sulfate 18-hydrate, 57.3 g of anhydride sodium sulfate, and 46.9 g of potassium sulfate by heating above 60 C. To resulting solution is added 4.06 g of 35.0% solution of zinc sulfate. The resulting solution is designated as the aqueous solution (a).

[0123] In 150 ml of deionized water are dissolved 0.45 g of sodium tertiary phosphate 12-hydrate and 55.0 g of sodium carbonate. The resulting solution is designated as the aqueous solution (b).

[0124] The aqueous solution (b) is added with stirring to the aqueous solution (a) kept at about 60 C. Stirring is continued for 15 minutes. The resulting mixture of the two solutions is a gel. The gel is evaporated to dryness, and the dried product is heated at 1200 C. for 5 hours. Water is added to the heated product to dissolve free sulfate. Insoluble solids are filtered off, washed with water, and finally dried. The obtained alumina flake is examined by X-ray diffractometry. The diffraction pattern has only peaks attributed to corundum structure (-alumina structure).

[0125] D.sub.50 is 22.3 m and D.sub.80 is 35.0 m. The MIU value is 1.00 measured by the KES friction tester.

[0126] Measurements

[0127] Evaluation for Particle Size D.sub.50 and D.sub.80

[0128] D.sub.50 and D.sub.80 of the alumina flakes according to the above given (comparative) examples are evaluated by using Malvern MS2000.

[0129] Evaluation for MIU Value

[0130] MIU value is evaluated by using KES friction tester (KES-SE-DC-tester by KATO TECH. Co., Ltd.).

[0131] Determination of the Thickness and Particle Size and the Thickness Distribution

[0132] 0.01 g/l of the alumina flake slurry is prepared and 0.1 ml of this slurry is dropped onto a flat substrate like a silicon wafer. The substrate is dried and cut to adequate size. The substrate is set with almost vertically tilted angle on the base of SEM (Scanning electronic microscope) and the thickness of the alumina flake is determined.

[0133] The thickness of more than 100 alumina flakes is measured for the calculation of the thickness distribution. The standard deviation of the thickness is calculated with the Gaussian distribution equation.

[0134] Al.sub.2O.sub.3 flakes according to the above given examples are summarized in the following table:

TABLE-US-00001 TABLE 1 Added Total molar ratio molar ratio of sulfate of sulfate compound to Particles size compound Al.sub.2O.sub.3 after step distribution (m) MIU to Al.sub.2O.sub.3 (2) D.sub.50 D.sub.80 value Example 1 3.0 11.3 16.2 0.55 Example 2 0.2 3.2 12.3 17.0 0.59 Example 3 0.5 3.5 12.9 17.8 0.70 Example 4 3.0 11.5 15.8 0.56 Comparative 4.0 7.3 22.3 35.0 1.0 Example 1

Application Examples

Use Example 1: Compact Powder

[0135]

TABLE-US-00002 Ingredients Supplier INCI (EU) [%] Phase A Pigment of Example 1 ALUMINA 5.00 Xirona Le Rouge Merck KGaA CI 77491, SILICA 8.00 Colorona Bordeaux Merck KGaA CI 77491, MICA 3.00 RonaFlair Balance Red Merck KGaA CI 77891, MICA, TIN OXIDE 3.50 RonaFlair Balance Blue Merck KGaA CI 77891, MICA, TIN OXIDE 3.50 Eusolex T-PRO Merck KGaA TITANIUM DIOXIDE, 5.00 ALUMINA, MANGANESE DIOXIDE Phase B Crodamol PMP Croda GmbH PPG-2 MYRISTYL ETHER 29.20 PROPIONATE Miglyol 812 N Sasol CAPRYLIC/CAPRIC 15.00 Germany TRIGLYCERIDE GmbH Syncrowax HGLC Croda GmbH C18-36 ACID 9.60 TRIGLYCERIDE Myritol 331 BASF AG COCOGLYCERIDES 9.50 Kester Wachs K 82 P Koster Keunen SYNTHETIC BEESWAX 6.00 Holland BV Antaron V-216 ISP Global PVP/HEXADECENE 2.40 Technologies COPOLYMER Propyl-4-hydroxybenzoate Merck KGaA PROPYLPARABEN 0.10 Phase C Oxynex K liquid Merck KGaA PEG-8, TOCOPHEROL, 0.10 ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID RonaCare Bisabolol Merck KGaA BISABOLOL 0.10

[0136] Heat phase B to 85 C. and stir until all ingredients are melted. Cool down to 75 C. and add the ingredients of phase A and C while stirring. Fill into godets while compact is still liquid.

[0137] It is further possible to use it as creamy eye shadow, as blush for cheeks and color for lips. The filler pigment of Example 1 improves the homogeneous application, supports a smooth and good gliding skin feel and promotes the pearl luster effect.

Use Example 2: Compact Powder

[0138]

TABLE-US-00003 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 5.00 Example 2 Xirona Merck KGaA CI 77491, SILICA 8.00 Le Rouge Colorona Merck KGaA CI 77491, MICA 3.00 Bordeaux RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Red TIN OXIDE RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Blue TIN OXIDE Eusolex Merck KGaA TITANIUM DIOXIDE, 5.00 T-PRO ALUMINA, MANGANESE DIOXIDE Phase B Crodamol PMP Croda GmbH PPG-2 MYRISTYL 29.20 ETHER PROPIONATE Miglyol 812 N Sasol CAPRYLIC/CAPRIC 15.00 Germany TRIGLYCERIDE GmbH Syncrowax Croda GmbH C18-36 ACID 9.60 HGLC TRIGLYCERIDE Myritol 331 BASF AG COCOGLYCERIDES 9.50 Kester Wachs Koster Keunen SYNTHETIC BEESWAX 6.00 K 82 P Holland BV Antaron V-216 ISP Global PVP/HEXADECENE 2.40 Technologies COPOLYMER Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate Phase C Oxynex K Merck KGaA PEG-8, TOCOPHEROL, 0.10 liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID RonaCare Merck KGaA BISABOLOL 0.10 Bisabolol

[0139] Heat phase B to 85 C. and stir until all ingredients are melted. Cool down to 75 C. and add the ingredients of phase A and C while stirring. Fill into godets while compact is still liquid.

[0140] It is further possible to use it as creamy eye shadow, as blush for cheeks and color for lips. The filler pigment of Example 2 improves the homogeneous application, supports a smooth and good gliding skin feel and promotes the pearl luster effect.

Use Example 3: Compact Powder

[0141]

TABLE-US-00004 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 5.00 Example 3 Xirona Merck KGaA CI 77491, SILICA 8.00 Le Rouge Colorona Merck KGaA CI 77491, MICA 3.00 Bordeaux RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Red TIN OXIDE RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Blue TIN OXIDE Eusolex Merck KGaA TITANIUM DIOXIDE, 5.00 T-PRO ALUMINA, MANGANESE DIOXIDE Phase B Crodamol PMP Croda GmbH PPG-2 MYRISTYL 29.20 ETHER PROPIONATE Miglyol 812N Sasol CAPRYLIC/CAPRIC 15.00 Germany TRIGLYCERIDE GmbH Syncrowax HGLC Croda GmbH C18-36 ACID 9.60 TRIGLYCERIDE Myritol 331 BASF AG COCOGLYCERIDES 9.50 Kester Wachs Koster Keunen SYNTHETIC 6.00 K 82 P Holland BV BEESWAX Antaron V-216 ISP Global PVP/HEXADECENE 2.40 Technologies COPOLYMER Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate Phase C Oxynex Merck KGaA PEG-8, TOCOPHEROL, 0.10 K liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID RonaCare Merck KGaA BISABOLOL 0.10 Bisabolol

[0142] Heat phase B to 85 C. and stir until all ingredients are melted. Cool down to 75 C. and add the ingredients of phase A and C while stirring. Fill into godets while compact is still liquid.

[0143] It is further possible to use it as creamy eye shadow, as blush for cheeks and color for lips. The filler pigment of Example 3 improves the homogeneous application, supports a smooth and good gliding skin feel and promotes the pearl luster effect.

Use Example 4: Compact Powder

[0144]

TABLE-US-00005 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 5.00 Example 4 Xirona Merck KGaA CI 77491, SILICA 8.00 Le Rouge Colorona Merck KGaA CI 77491, MICA 3.00 Bordeaux RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Red TIN OXIDE RonaFlair Merck KGaA CI 77891, MICA, 3.50 Balance Blue TIN OXIDE Eusolex Merck KGaA TITANIUM DIOXIDE, 5.00 T-PRO ALUMINA, MANGANESE DIOXIDE Phase B Crodamol PMP Croda GmbH PPG-2 MYRISTYL ETHER 29.20 PROPIONATE Miglyol 812 N Sasol CAPRYLIC/CAPRIC 15.00 Germany TRIGLYCERIDE GmbH Syncrowax Croda GmbH C18-36 ACID 9.60 HGLC TRIGLYCERIDE Myritol 331 BASF AG COCOGLYCERIDES 9.50 Kester Wachs Koster Keunen SYNTHETIC BEESWAX 6.00 K 82 P Holland BV Antaron V-216 ISP Global PVP/HEXADECENE 2.40 Technologies COPOLYMER Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate Phase C Oxynex K Merck KGaA PEG-8, TOCOPHEROL, 0.10 liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID RonaCare Merck KGaA BISABOLOL 0.10 Bisabolol

[0145] Heat phase B to 85 C. and stir until all ingredients are melted. Cool down to 75 C. and add the ingredients of phase A and C while stirring. Fill into godets while compact is still liquid.

[0146] It is further possible to use it as creamy eye shadow, as blush for cheeks and color for lips. The filler pigment of Example 4 improves the homogeneous application, supports a smooth and good gliding skin feel and promotes the pearl luster effect.

Use Example 5: Eye Shadow

[0147]

TABLE-US-00006 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 13.75 Example 1 Timiron Merck KGaA ALUMINA, CI 77891, TIN 5.00 Glam Silver OXIDE RonaFlair Merck KGaA MICA, CI 77891 2.50 Extender W Timiron Merck KGaA CI 77891, MICA, SILICA 1.25 Splendid Violet Phase B Parteck Merck KGaA TALC 57.82 LUB Talc Corn Starch Dr. Hauser ZEA MAYS 8.76 GmbH Magnesium Merck KGaA MAGNESIUM STEARATE 2.92 Stearate Unipure Pink S. Goldmann CI 77742 3.00 LC 583 GmbH & Co. KG Phase C Ceraphyl 368 ISP Global ETHYLHEXYL 4.92 Technologies PALMITATE Propyl-4- Merck KGaA PROPYLPARABEN 0.08 hydroxybenzoate

[0148] Mix the ingredients of phase B until the blend is uniform. Add the pigments of phase A. Then add the presolved phase C while stirring strongly. The powder is pressed between 30-40 bar.

[0149] The filler pigment of Example 1 is improving the structure of the powder and the pay-off significantly. Furthermore it reduces the forming of greasy spots on the surface of the powderan effect frequently appearing when using an eye shadow often.

Use Example 6: Eye Shadow

[0150]

TABLE-US-00007 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 13.75 Example 2 Timiron Merck KGaA ALUMINA, CI 77891, TIN 5.00 Glam Silver OXIDE RonaFlair Merck KGaA MICA, CI 77891 2.50 Extender W Timiron Merck KGaA CI 77891, MICA, SILICA 1.25 Splendid Violet Phase B Parteck Merck KGaA TALC 57.82 LUB Talc Corn Starch Dr. Hauser ZEA MAYS 8.76 GmbH Magnesium Merck KGaA MAGNESIUM STEARATE 2.92 Stearate Unipure Pink S. Goldmann CI 77742 3.00 LC 583 GmbH & Co. KG Phase C Ceraphyl 368 ISP Global ETHYLHEXYL 4.92 Technologies PALMITATE Propyl-4- Merck KGaA PROPYLPARABEN 0.08 hydroxybenzoate

[0151] Mix the ingredients of phase B until the blend is uniform. Add the pigments of phase A. Then add the presolved phase C while stirring strongly. The powder is pressed between 30-40 bar.

[0152] The filler pigment of Example 2 is improving the structure of the powder and the pay-off significantly. Furthermore it reduces the forming of greasy spots on the surface of the powderan effect frequently appearing when using an eye shadow often.

Use Example 7: Eye Shadow

[0153]

TABLE-US-00008 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 13.75 Example 3 Timiron Merck KGaA ALUMINA, CI 77891, TIN 5.00 Glam Silver OXIDE RonaFlair Merck KGaA MICA, CI 77891 2.50 Extender W Timiron Merck KGaA CI 77891, MICA, SILICA 1.25 Splendid Violet Phase B Parteck Merck KGaA TALC 57.82 LUB Talc Corn Starch Dr. Hauser ZEA MAYS 8.76 GmbH Magnesium Merck KGaA MAGNESIUM STEARATE 2.92 Stearate Unipure Pink S. Goldmann CI 77742 3.00 LC 583 GmbH & Co. KG Phase C Ceraphyl 368 ISP Global ETHYLHEXYL 4.92 Technologies PALMITATE Propyl-4- Merck KGaA PROPYLPARABEN 0.08 hydroxybenzoate

[0154] Mix the ingredients of phase B until the blend is uniform. Add the pigments of phase A. Then add the presolved phase C while stirring strongly. The powder is pressed between 30-40 bar.

[0155] The filler pigment of Example 3 is improving the structure of the powder and the pay-off significantly. Furthermore it reduces the forming of greasy spots on the surface of the powderan effect frequently appearing when using an eye shadow often.

Use Example 8: Eye Shadow

[0156]

TABLE-US-00009 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 13.75 Example 4 Timiron Merck KGaA ALUMINA, CI 77891, TIN 5.00 Glam Silver OXIDE RonaFlair Merck KGaA MICA, CI 77891 2.50 Extender W Timiron Merck KGaA CI 77891, MICA, SILICA 1.25 Splendid Violet Phase B Parteck Merck KGaA TALC 57.82 LUB Talc Corn Starch Dr. Hauser ZEA MAYS 8.76 GmbH Magnesium Merck KGaA MAGNESIUM STEARATE 2.92 Stearate Unipure Pink S. Goldmann CI 77742 3.00 LC 583 GmbH & Co. KG Phase C Ceraphyl 368 ISP Global ETHYLHEXYL 4.92 Technologies PALMITATE Propyl-4- Merck KGaA PROPYLPARABEN 0.08 hydroxybenzoate

[0157] Mix the ingredients of phase B until the blend is uniform. Add the pigments of phase A. Then add the presolved phase C while stirring strongly. The powder is pressed between 30-40 bar.

[0158] The filler pigment of Example 4 is improving the structure of the powder and the pay-off significantly. Furthermore it reduces the forming of greasy spots on the surface of the powderan effect frequently appearing when using an eye shadow often.

Use Example 9: Cream

[0159]

TABLE-US-00010 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 2.00 Example 1 Timiron Merck KGaA SYNTHETIC 3.00 Synwhite 40 FLUORPHLOGOPITE, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE Water, Merck KGaA AQUA (WATER) 62.80 demineralized Eusolex Merck KGaA AQUA (WATER), 15.00 UV-Pearls OCTOCRYLENE, OB-S SORBITOL, BUTYL METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Phase B Miglyol 812 N Sasol CAPRYLIC/CAPRIC 3.00 Germany TRIGLYCERIDE GmbH Cetiol CC Cognis GmbH DICAPRYLYL 2.50 CARBONATE Sepinov P88 Seppic GmbH SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Phase C RonaCare Merck KGaA AQUA (WATER), 2.00 Cyclopeptide ALCOHOL DENAT., LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Euxyl PE 9010 Schlke & PHENOXYETHANOL, 1.00 Mayr GmbH ETHYLHEXYL GLYCERIN Fragrance Vgele PARFUM 0.20 Sensitive Touch

[0160] Add phase A slowly with vigorous stirring to phase B. Homogenize. Afterwards add phase C.

[0161] The filler pigment of Example 1 adds body and a pleasant skin feeling to this white emulsion. After application it leaves a nice silver shimmer on the skin.

Use Example 10: Cream

[0162]

TABLE-US-00011 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 2.00 Example 2 Timiron Merck KGaA SYNTHETIC 3.00 Synwhite 40 FLUORPHLOGOPITE, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE Water, Merck KGaA AQUA (WATER) 62.80 demineralized Eusolex Merck KGaA AQUA (WATER), 15.00 UV-Pearls OCTOCRYLENE, OB-S SORBITOL, BUTYL METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Phase B Miglyol 812 N Sasol CAPRYLIC/CAPRIC 3.00 Germany TRIGLYCERIDE GmbH Cetiol CC Cognis GmbH DICAPRYLYL 2.50 CARBONATE Sepinov P88 Seppic GmbH SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Phase C RonaCare Merck KGaA AQUA (WATER), 2.00 Cyclopeptide ALCOHOL DENAT., LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Euxyl PE 9010 Schlke & PHENOXYETHANOL, 1.00 Mayr GmbH ETHYLHEXYL GLYCERIN Fragrance Vgele PARFUM 0.20 Sensitive Touch

[0163] Add phase A slowly with vigorous stirring to phase B. Homogenize. Afterwards add phase C.

[0164] The filler pigment of Example 2 adds body and a pleasant skin feeling to this white emulsion. After application it leaves a nice silver shimmer on the skin.

Use Example 11: Cream

[0165]

TABLE-US-00012 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 2.00 Example 3 Timiron Merck KGaA SYNTHETIC 3.00 Synwhite 40 FLUORPHLOGOPITE, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE Water, Merck KGaA AQUA (WATER) 62.80 demineralized Eusolex Merck KGaA AQUA (WATER), 15.00 UV-Pearls OCTOCRYLENE, OB-S SORBITOL, BUTYL METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Phase B Miglyol 812 N Sasol CAPRYLIC/CAPRIC 3.00 Germany TRIGLYCERIDE GmbH Cetiol CC Cognis GmbH DICAPRYLYL 2.50 CARBONATE Sepinov P88 Seppic GmbH SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Phase C RonaCare Merck KGaA AQUA (WATER), 2.00 Cyclopeptide ALCOHOL DENAT., LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Euxyl PE 9010 Schlke & PHENOXYETHANOL, 1.00 Mayr GmbH ETHYLHEXYL GLYCERIN Fragrance Vgele PARFUM 0.20 Sensitive Touch

[0166] Add phase A slowly with vigorous stirring to phase B. Homogenize. Afterwards add phase C.

[0167] The filler pigment of Example 3 adds body and a pleasant skin feeling to this white emulsion. After application it leaves a nice silver shimmer on the skin.

Use Example 12: Cream

[0168]

TABLE-US-00013 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 2.00 Example 4 Timiron Merck KGaA SYNTHETIC 3.00 Synwhite 40 FLUORPHLOGOPITE, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE Water, Merck KGaA AQUA (WATER) 62.80 demineralized Eusolex Merck KGaA AQUA (WATER), 15.00 UV-Pearls OCTOCRYLENE, OB-S SORBITOL, BUTYL METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Phase B Miglyol 812 N Sasol CAPRYLIC/CAPRIC 3.00 Germany TRIGLYCERIDE GmbH Cetiol CC Cognis GmbH DICAPRYLYL 2.50 CARBONATE Sepinov P88 Seppic GmbH SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Phase C RonaCare Merck KGaA AQUA (WATER), 2.00 Cyclopeptide ALCOHOL DENAT., LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Euxyl PE 9010 Schlke & PHENOXYETHANOL, 1.00 Mayr GmbH ETHYLHEXYL GLYCERIN Fragrance Vgele PARFUM 0.20 Sensitive Touch

[0169] Add phase A slowly with vigorous stirring to phase B. Homogenize. Afterwards add phase C.

[0170] The filler pigment of Example 4 adds body and a pleasant skin feeling to this white emulsion. After application it leaves a nice silver shimmer on the skin.

Use Example 13: Cream

[0171]

TABLE-US-00014 Ingredients Supplier INCI (EU) [%] Phase A Xirona Merck KGaA CI 77491, SILICA 8.00 Le Rouge Pigment of ALUMINA 5.00 Example 1 Colorona Merck KGaA CI 77491, MICA 3.00 Bordeaux RonaFlair Merck KGaA CI 77891, MICA, TIN 3.50 Balance Red OXIDE RonaFlair Merck KGaA CI 77891, MICA, TIN 3.50 Balance Blue OXIDE Eusolex Merck KGaA TITANIUM DIOXIDE, 5.00 T-PRO ALUMINA, MANGANESE DIOXIDE Phase B Crodamol PMP Croda GmbH PPG-2 MYRISTYL ETHER 29.20 PROPIONATE Miglyol 812 N Sasol CAPRYLYLIC/CAPRIC 15.00 Germany TRIGLYCERIDE GmbH Syncrowax Croda GmbH C18-36 ACID 9.60 HGLC TRIGLYCERIDE Myritol 331 BASF AG COCOGLYCERIDES 9.50 Kester Wachs Koster SYNTHETIC BEESWAX 6.00 K 82 P Keunen Holland BV Antaron V-216 ISP Global PVP/HEXADECENE 2.40 Technologies COPOLYMER Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate Phase C Oxynex Merck KGaA PEG-8, TOCOPHEROL, 0.10 K liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITIRC ACID RonaCare Merck KGaA BISABOLOL 0.10 Bisabolol

[0172] Heat phase B to 85 C. and stir until all ingredients are melted. Cool down to 75 C. and add the ingredients of phase A and C while stirring. Fill into godets while the 3-in-1 Compact is still liquid.

Use Example 14: Cream

[0173]

TABLE-US-00015 Ingredients Supplier INCI (EU) [%] Phase A Timiron Merck KGaA SYNTHETIC 3.00 Synwhite 40 FLUORPHLOGOPITE, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE Pigment of ALUMINA 2.00 Example 2 Water, Merck KGaA AQUA (WATER) 62.80 demineralized Eusolex Merck KGaA AQUA (WATER), 15.00 UV-Pearls OCTOCRYLENE, OB-S SORBITOL, BUTYL METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Phase B Miglyol 812 N Sasol CAPRYLYLIC/CAPRIC 3.00 Germany TRIGLYCERIDE GmbH Cetiol CC Cognis GmbH DICAPRYLYL 2.50 CARBONATE Sepinov P88 Seppic GmbH SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Phase C RonaCare Merck KGaA AQUA (WATER), 2.00 Cyclopeptide-5 ALCOHOL DENAT., LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Euxyl PE 9010 Schlke & PHENOXYETHANOL, 1.00 Mayr GmbH ETHYLHEXYL GLYCERIN Fragrance Vgele PARFUM 0.20 Sensitive Touch

[0174] Add phase A slowly with vigorous stirring to phase B. Homogenize. Afterwards add phase C.

Use Example 15: Eyeshadow

[0175]

TABLE-US-00016 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 13.75 Example 3 Timiron Merck KGaA ALUMINA, CI 77891, TIN 5.00 Glam Silver OXIDE RonaFlair Merck KGaA MICA, CI 77891 2.50 Extender W Timiron Merck KGaA CI 77891, MICA, SILICA 1.25 Splendid Violet Phase B Parteck Merck KGaA TALC 57.82 LUB Talc Corn Starch Dr. Hauser ZEA MAYS 8.76 GmbH Magnesium Merck KGaA MAGNESIUM STEARATE 2.92 Stearate Unipure Pink S. Goldmann CI 77742 3.00 LC 583 GmbH & Co. KG Phase C Ceraphyl 368 ISP Global ETHYLHEXYL 4.92 Technologies PALMITATE Propyl-4- Merck KGaA PROPYLPARABEN 0.08 hydroxybenzoate

[0176] Mix the ingredients of phase B until the blend is uniform. Add the pigments of phase A. Then add the presolved phase C while stirring strongly. The powder is pressed between 30-40 bar.

Use Example 16: Cream

[0177]

TABLE-US-00017 Ingredients Supplier INCI (EU) [%] Phase A RonaFlair Merck KGaAs CI 77891, MICA, TIN 1.00 Balance Blue OXIDE RonaFlair Merck KGaA CI 77891, MICA, TIN 1.00 Balance Red OXIDE Pigment of ALUMINA 1.00 Example 1 Water, Merck KGaA AQUA 70.50 demineralized Glycerol 85% Merck KGaA GLYCERIN, AQUA 4.00 Hydrolite-5 Cosnaderm PENTYLENE GLYCOL 2.00 GmbH RonaCare Merck KGaA UREA, DISODIUM 1.00 Biotin Plus PHOSPHATE, BIOTIN, CITRIC ACID D-Panthenol PANTHENOL 0.50 RonaCare Merck KGaA ECTOIN 0.30 Ectoin Methyl-4- Merck KGaA METHYLPARABEN 0.15 hydroxybenzoate Phase B Montanov 68 Seppic CETEARYL ALCOHOL, 4.00 GmbH CETEARYL GLUCOSIDE Dow Corning Biesterfeld CYCLOMETHICONE, 2.50 9040 Silicone DIMETHICONE Elastomer Blend CROSSPOLYMER Tegosoft DEC Evonik DIETHYLHEXYL 2.00 Goldschmidt CARBONATE GmbH Cosmacol ELI Nordmann, C12-13 ALKYL LACTATE 2.00 Rassmann GmbH & Co Arlamol HD Nordmann, ISOHEXADECANE 2.00 Rassmann GmbH & Co Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Span 60 Croda GmbH SORBITAN STEARATE 1.50 Lanette O BASF AG CETEARYL ALCOHOL 1.00 Olive Oil, bio OLEA EUROPAEA 0.50 RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.50 HYDROXYDIMETHOXY BENZYLMALONATE Propyl-4- Merck KGaA PROPYLPARABEN 0.05 hydroxybenzoate Phase C Rhodicare S Rhodia XANTHAN GUM 0.25 GmbH Phase D Fragrance 46235 Cosnaderm PARFUM 0.20 Grenadine GmbH

[0178] Heat phase A and B separately to 75 C. Add phase C slowly to phase A while stirring until a homogeneous mixture is obtained. At 75 C. add phase B to phase A/C and homogenize for 1 min. (Ultra Turrax T25 at 8000 rpm). Cool down to 35 C. and add perfume. Cool down to room temperature while stirring. The pH value should be between 5-5.5.

Use Example 17: Cream

[0179]

TABLE-US-00018 Ingredients Supplier INCI (EU) [%] Phase A Water, Merck KGaA AQUA 62.70 demineralized 1,2-Propanediol Merck KGaA PROPYLENE GLYCOL 4.00 Chelating Agent 0.10 RonaCare Merck KGaA ECTOIN 1.00 Ectoin Phase B RonaFlair Merck KGaA CI 77891, MICA, 3.00 Balance Red TIN OXIDE Pigment of ALUMINA 2.00 Example 4 Colorona Merck KGaA MICA, CI 77891, 1.00 Oriental Beige CI 77491 Lexfeel 7 NEOPENTYL GLYCOL 5.00 DIHEPTANOATE Ucon LB Mascot PPG-33 BUTYL 3.00 1145 fluid Universal ETHER Pvt. Ltd. Tegosoft Evonik OLEYL ERUCATE 3.00 OER Goldschmidt GmbH Talc TALC 2.00 Montanov 202 Seppic GmbH ARACHIDYL GLUCOSIDE, 2.00 ARACHIDYL ALCOHOL, BEHENYL ALCOHOL Eusolex Merck KGaA TITANIUM DIOXIDE 2.00 T-ECO (NANO), ALUMINA, SIMETHICONE Simulsol 165 Seppic GmbH PEG-100 STEARATE, 5.00 GLYCERYL STEARATE Ginol 16 Godrej CETYL ALCOHOL 1.00 Industries Limited Ginol 18 Godrej STEARYL ALCOHOL 0.50 Industries Limited Hostaphat Clariant GmbH TRILAURETH-4 2.00 KL 340 D PHOSPHATE Frescolet Symrise MENTHYL LACTATE 0.05 ML Crystal Phase C Phenonip Clariant GmbH PHENOXYETHANOL, 0.40 METHYLPARABEN, ETHYLPARABEN, ISOBUTYLPARABEN, BUTYLPARABEN, PROPYLPARABEN Fragrance PARFUM 0.25 (q.s.)

[0180] Heat phase A and B separately to 80 C. Ad d phase B slowly to A while stirring. Homogenize. Add the ingredients of phase C to adjust the pH value.

Use Example 18: Cream

[0181]

TABLE-US-00019 Ingredients Supplier INCI (EU) [%] Phase A Water, Merck KGaA AQUA 62.70 demineralized Chelating Agent 0.10 1,2-Propanediol Merck KGaA PROPYLENE GLYCOL 4.00 RonaCare Merck KGaA ECTOIN 1.00 Ectoin Phase B RonaFlair Merck KGaA CI 77891, MICA, 3.00 Balance Red TIN OXIDE Pigment of ALUMINA 2.00 Example 3 Colorona Merck KGaA MICA, CI 77891, 1.00 Oriental Beige CI 77491 Lexfeel 7 NEOPENTYL GLYCOL 5.00 DIHEPTANOATE Ucon LB Mascot PPG-33 BUTYL 3.00 1145 fluid Universal ETHER Pvt. Ltd. Tegosoft Evonik OLEYL ERUCATE 3.00 OER Goldschmidt GmbH Talc TALC 2.00 Montanov 202 Seppic GmbH ARACHIDYL GLUCOSIDE, 2.00 ARACHIDYL ALCOHOL, BEHENYL ALCOHOL UV-TITAN Merck KGaA TITANIUM DIOXIDE 2.00 M765 (NANO), TRIETHOXY- CAPRYLYLSILANE, ALUMINA Simulsol 165 Seppic PEG-100 STEARATE, 5.00 GLYCERYL STEARATE Ginol 16 Godrej CETYL ALCOHOL 1.00 Industries Limited Ginol 18 Godrej STEARYL ALCOHOL 0.50 Industries Limited Hostaphat Clariant TRILAURETH-4 2.00 KL 340 D GmbH PHOSPHATE Frescolet Symrise MENTHYL LACTATE 0.05 ML Crystal Phase C Phenonip Clariant PHENOXYETHANOL, 0.40 GmbH METHYLPARABEN, ETHYLPARABEN, ISOBUTYLPARABEN, BUTYLPARABEN, PROPYLPARABEN Fragrance PARFUM 0.25 (q.s.)

[0182] Heat phase A and B separately to 80 C. Add phase B slowly to A while stirring. Homogenize it well. Add the ingredients of phase C at 35 degrees. Neutralize to adjust the pH.

Use Example 19: Cream

[0183]

TABLE-US-00020 Ingredients Supplier INCI (EU) [%] Phase A Timiron Merck KGaA MICA, CI 77891, 2.00 BF-1001 SILVER OXIDE Colorona Merck KGaA MICA, CI 77891, 0.50 Oriental Beige CI 77491 Pigment of ALUMINA 0.50 Example 1 Phase B Miglyol Sasol CAPRYLIC/CAPRIC 59.55 812 N Germany TRIGLYCERIDE GmbH Kahlwax 6089 Kahl & Co. CERA 27.40 MICROCRISTALLINA Paraffin viscous Merck KGaA PARAFFINUM LIQUIDUM 10.00 Oxynex Merck KGaA PEG-8, TOCOPHEROL, 0.05 K liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID

[0184] Heat the ingredients of phase B to 85 C. Ad d phase A and stir until the melt is homogeneous. Cool down slowly to room temperature while stirring slowly and continuously without high shear forces to reach a smooth, homogeneous product.

Use Example 20: Cream

[0185]

TABLE-US-00021 Ingredients Supplier INCI (EU) [%] Phase A Eusolex Merck KGaA AQUA, OCTOCRYLENE, 15.00 UV-Pearls SORBITOL, BUTYL OB-S METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA Pigment of ALUMINA 1.00 Example 2 RonaFlair Merck KGaA CI 77891, MICA, 1.00 Balance Blue TIN OXIDE RonaFlair Merck KGaA CI 77891, MICA, 1.00 Balance Red TIN OXIDE RonaCare Merck KGaA ECTOIN 0.50 Ectoin 1.3-Butanediol Merck KGaA BUTYLENE GLYCOL 3.00 Water, Merck KGaA AQUA 68.00 demineralized Phase B Sepinov P88 SODIUM ACRYLATE, 2.00 ACRYLOYL DIMETHYLTAURATE, DIMETHYLACRYLAMIDE CROSSPOLYMER Miglyol Sasol CAPRYLIC/CAPRIC 3.00 812 N Germany TRIGLYCERIDE GmbH Cetiol CC BASF AG DICAPRYLYL CARBONATE 2.50 Xiameter Dow Corning CYCLOPENTASILOXANE, 2.00 PMX-0345 CYCLOHEXASILOXANE Xiameter Dow Corning DIMETHICONE 1.00 PMX-200 (100 cs) Phase C Preservatives 0.00 (q.s.) Fragrance PARFUM 0.00 (q.s.)

[0186] Mix phase A and add this phase slowly with vigorous stirring to phase B. Homogenize. Finally add phase C under stirring.

Use Example 21: Facepowder

[0187]

TABLE-US-00022 Ingredients Supplier INCI (EU) [%] Phase A Pigment of ALUMINA 15.00 Example 1 RonaFlair Merck KGaA MICA 15.00 Silk Mica Eusolex Merck KGaA TITANIUM DIOXIDE 5.00 T-S (NANO), ALUMINA, STEARIC ACID Titanium - Merck KGaA TITANIUM DIOXIDE, 3.00 (IV)- oxid TITANIUM DIOXIDE (NANO) Unipure Yellow S. Goldmann CI 77492 0.30 LC 181 GmbH & Co. KG Unipure Red S. Goldmann CI 77491 0.04 LC 381 GmbH & Co. KG Unipure Brown S. Goldmann CI 77491, 0.06 LC 889 GmbH & Co. CI 77499 KG Parteck Merck KGaA TALC 55.20 LUB Talc Parteck Merck KGaA MAGNESIUM STEARATE 2.00 LUB MST Phase B Eutanol G BASF AG OCTYLDODECANOL 3.70 all-rac-alpha- Merck KGaA TOCOPHERYL ACETATE 0.30 Tocopheryl acetate Fragrance Fragrance PARFUM 0.30 200 529 Resources Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate

[0188] Grind the ingredients of phase A until the blend is homogeneous. Then add the previously dissolved phase B and grind again until the whole phase A/B is homogeneous. Fill the bulk into pans and press with the desired pressure. The pressure for pans with 36 mm in diameter is approx. 25-35 bar.

Use Example 22: Nail Polish

[0189]

TABLE-US-00023 Ingredients Supplier INCI (EU) [%] Xirona Merck KGaA SILICA, CI 77891, 2.00 Golden Sky TIN OXIDE Pigment of ALUMINA 1.00 Example 2 RonaFlair Merck KGaA MICA, CI 77891 1.00 Extender W Colorona Merck KGaA CI 77499, MICA, 0.15 Mica Black CI 77891 Coloring Durlin/France ETHYL ACETATE, 0.40 Base Ref. 696 BUTYL ACETATE, NITROCELLULOSE, CI 47005, PHTHALIC ANHYDRIDE/TRIMELLITIC ANHYDRIDE/GLYCOLS COPOLYMER, ACETYL TRIBUTYL CITRATE, ISOPROPYL ALCOHOL, STEARALKONIUM HECTORITE Coloring Durlin/France ETHYL ACETATE, 0.20 Base Ref. 695 BUTYL ACETATE, NITROCELLULOSE, PHTHALIC ANHYDRIDE/ TRIMELLITIC ANHYDRIDE/GLYCOLS COPOLYMER, CI 42090, ACETYL TRIBUTYL CITRATE, ISOPROPYL ALCOHOL, STEARALKONIUM HECTORITE Thixotropic Durlin/France BUTYL ACETATE, 95.25 Nail Lacquer ETHYL ACETATE, Base 155 NITROCELLULOSE, ACETYL TRIBUTYL CITRATE, PHTHALIC ANHYDRIDE/TRIMELLITIC ANHYDRIDE/GLYCOLS COPOLYMER, ISOPROPYL ALCOHOL, STEARALKONIUM HECTORITE, ADIPIC ACID/FUMARIC ACID/ PHTHALIC ACID/ TRICYCLODECANE DIMETHANOL COPOLYMER, CITRIC ACID

[0190] Mix all ingredients by stirring at 1000 rpm for 10 min. Avoid introducing air.

Use Example 23: Nude Lipstick

[0191]

TABLE-US-00024 Ingredients Supplier INCI (EU) [%] Phase A Timiron Merck KGaA SYNTHETIC 5.00 SynBeam Red FLUORPHLOGOPITE, CI 77891, TIN OXIDE Pigment of ALUMINA 5.00 Example 1 Colorona Merck KGaA SYNTHETIC 0.10 SynBerry Pink FLUORPHLOGOPITE, CI 77891, CI 75470, TIN OXIDE Phase B Oxynex Merck KGaA PEG-8, TOCOPHEROL, 0.05 K liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID Oxynex Merck KGaA DIETHYLHEXYL 0.10 ST Liquid SYRINGYLIDENE MALONATE, CAPRYLIC/CAPRIC TRIGLYCERIDE Sensiva Schlke & PHENETHYL ALCOHOL, 1.00 PA 20 Mayr GmbH ETHYLHEXYL GLYCERIN Paraffin Merck KGaA PARAFFINUM LIQUIDUM 2.10 viscous Adeps Lanae Henry Lamotte LANOLIN 3.50 Oils GmbH Paracera Azelis COPERNICIA CERIFERA, 5.25 C 44 Germany CERESIN GmbH Isopropyl BASF AG ISOPROPYL MYRISTATE 5.60 Myristate Wax white Merck KGaA CERA ALBA 8.75 Castor Oil Henry Lamotte RICINUS COMMUNIS 63.35 Oils GmbH (CASTOR) SEED OIL Phase C Fragrance Pearl Cosnaderm PARFUM 0.20 GmbH

[0192] Heat the ingredients of phase B to 75 C. Ad d phase A and stir until the melt is homogeneous. Transfer the mixture into a moulding machine, which is heated up to 65 C., add the perfume and stir about 15 minutes. Fill into a lipstick mould which has been preheated to about 55 C. Cool down the mould and transfer the cold bullets to mechanisms. A highly glossy appearance can be obtained by subsequent flaming if desired.

Use Example 24: Cream

[0193]

TABLE-US-00025 Ingredients Supplier INCI (EU) [%] Phase A RonaCare Merck KGaA ALLANTOIN 0.00 Allantoin RonaCare Merck KGaA ECTOIN 0.00 Ectoin Eusolex Merck KGaA AQUA, ETHYLHEXYL 0.02 UV-Pearls METHOXYCINNAMATE, 2292 SILICA, PVP, CHLORPHENESIN, DISODIUM EDTA, BHT Eusolex Merck KGaA AQUA, OCTOCRYLENE, 0.02 UV-Pearls SORBITOL, BUTYL OB-S METHOXYDIBENZOYL- METHANE, SILICA, PVP, CHLORPHENESIN, PHENOXYETHANOL, DISODIUM EDTA Water, Merck KGaA AQUA 0.04 demineralized Carbopol Gattefoss ACRYLATES/C10-30 0.00 Ultrez 21 GmbH ALKYL ACRYLATE CROSSPOLYMER Glycerol 85% Merck KGaA GLYCERIN, AQUA 0.01 Rhodicare S C. H. Erbslh XANTHAN GUM 0.00 Titriplex III Merck KGaA DISODIUM EDTA 0.00 Phase B RonaCare AP Merck KGaA BIS-ETHYLHEXYL 0.00 HYDROXYDIMETHOXY BENZYLMALONATE RonaCare Merck KGaA BISABOLOL 0.00 Bisabolol Olivem 1000 Erbslh CETEARYL OLIVATE, 0.00 SORBITAN OLIVATE Isostearyl Gattefoss ISOSTEARYL 0.01 Isostearate GmbH ISOSTEARATE Organic sweet IES Labo PRUNUS AMYGDALUS 0.01 almond oil DULCIS OIL Phase C Sodium Hydroxide, Merck KGaA AQUA, SODIUM 0.00 10% HYDROXIDE Phase D Pigment of Merck KGaA ALUMINA 0.00 Example 3 RonaFlair CI 77891, MICA, 0.00 Balance Green TIN OXIDE Phase E Microcare Thor Personnal PHENOXYETHANOL, 0.00 PM2 Care SAS ETHYLPARABEN, METHYLPARABEN

[0194] Disperse Carbopol ultrez 21 in the water. Add the xanthane gum premixed with glycerin. Add the active ingredients and the titriplex. Add the UV-pearls. Prepare phase B and heat A and B up 80 C. Emulsion B in A. Neutralise with C. At temperature <60 C. add D. At temperature <30 C. add E.

Use Example 25: Cream

[0195]

TABLE-US-00026 Ingredients Supplier INCI (EU) [%] Phase A Tego Care 450 Evonik POLYGLYCERYL-3 3.00 Goldschmidt METHYLGLUCOSE GmbH DISTEARATE Tegin M Evonik GLYCERYL STEARATE 2.00 Goldschmidt GmbH Lanette 18 BASF AG STEARYL ALCOHOL 2.00 Miglyol 812 Sasol CAPRYLIC/CAPRIC 7.50 Germany TRIGLYCERIDE GmbH Avocado Oil Gustav Heess PERSEA GRATISSIMA OIL 2.00 GmbH Arlamol HD Croda GmbH ISOHEXADECANE 9.50 Phase B Water, Merck KGaA AQUA 64.50 demineralized Glycerol 85% Merck KGaA GLYCERIN, AQUA 3.00 Pigment of ALUMINA 2.50 Example 1 Phase C RonaCare Merck KGaA AQUA, ALCOHOL, 4.00 Cyclopeptide-5 LECITHIN, ECTOIN, CYCLOTETRAPEPTIDE-24 AMINOCYCLOHEXANE CARBOXYLATE Preservatives 0.00 (q.s.) Fragrance PARFUM 0.00 (q.s.)

[0196] Heat phase A and phase B separately to 75 C. Incorporate phase A into phase B while stirring and homogenize. Cool down to 30 C. while stirring and add ingredients of phase C.

Use Example 26: Eyeshadow Gel

[0197]

TABLE-US-00027 Ingredients Supplier INCI (EU) [%] Phase A Colorona Merck KGaA MICA, CI 77891, 9.70 Precious Gold SILICA, CI 77491, TIN OXIDE Ronastar Merck KGaA CALCIUM ALUMINUM 2.00 Golden Jewel BOROSILICATE, CI 77891, SILICA, CI 77491, TIN OXIDE Colorona Merck KGaA CI 77499, MICA, 1.00 Mica Black CI 77891 Pigment of ALUMINA 3.00 Example 1 Carbopol Gattefoss ACRYLATES/C10-30 0.30 Ultrez 21 GmbH ALKYL ACRYLATE CROSSPOLYMER Citric Acid Merck KGaA CITRIC ACID 0.00 Monohydrate Water, Merck KGaA AQUA 63.20 demineralized Phase B RonaCare Merck KGaA ALLANTOIN 0.10 Allantoin RonaCare Merck KGaA TRIETHANOLAMINE 0.70 Triethanolamine Preservatives 0.00 (q.s.) Glycerol, Merck KGaA GLYCERIN 2.00 anhydrous Water, Merck KGaA AQUA 13.00 demineralized Phase C Lubrajel Azelis PROPYLENE 5.00 DV Germany GLYCOL, POLYGLY- GmbH CERYLMETHACRYLATE

[0198] Disperse all pigments and the filler in the water of phase A. Add some drops of citric acid solution to lower the viscosity if necessary, then add the Carbopol Ultrez 21 while stirring. Mix with high agitation until thoroughly dispersed. Mix the ingredients of phase B until a complete solution is obtained. Add phase B slowly to phase A while stirring (not homogenizing), then add phase C while stirring and adjust pH to 7.0-7.5 with citric acid solution, if necessary.

Use Example 27: Lipstick

[0199]

TABLE-US-00028 Ingredients Supplier INCI (EU) [%] Phase A Timiron Merck KGaA CI 77891, MICA, 8.00 Splendid Gold SILICA Colorona Merck KGaA MICA, CI 77891, 2.50 Magenta CI 75470 RonaFlair Merck KGaA, CI 77891, MICA, 2.00 Balance Gold Darmstadt, TIN OXIDE Germany/EMD Chemicals Pigment of ALUMINA 2.00 Example 1 Colorona Merck KGaA MICA, CI 77891, 0.50 Oriental Beige CI 77491 Phase B Castor Oil Henry RICINUS COMMUNIS 59.45 Lamotte Oils (CASTOR) SEED OIL GmbH Wax white Merck KGaA CERA ALBA 8.75 Paracera C 44 Azelis COPERNICIA CERIFERA, 5.25 Germany CERESIN GmbH Adeps Lanae Henry LANOLIN 3.50 Lamotte Oils GmbH Isopropyl BASF AG ISOPROPYL MYRISTATE 5.60 Myristate Paraffin viscous Merck KGaA PARAFFINUM LIQUIDUM 2.10 Propyl-4- Merck KGaA PROPYLPARABEN 0.10 hydroxybenzoate Oxynex Merck KGaA PEG-8, TOCOPHEROL, 0.05 K liquid ASCORBYL PALMITATE, ASCORBIC ACID, CITRIC ACID Phase C Fragrance Cosnaderm PARFUM 0.20 Pearl FC10599 GmbH

[0200] Heat the ingredients of phase B to 75 C. Ad d phase A and stir until the melt is homogeneous. Transfer the mixture into a moulding machine, which is heated up to 65 C., add the perfume and stir about 15 minutes. Fill into a lipstick mould which has been preheated to about 55 C. Cool down the mould and transfer the cold bullets to mechanisms. A highly glossy appearance can be obtained by subsequent flaming if desired.

Use Example 28: Loose Powder Eye Shadow

[0201]

TABLE-US-00029 Ingredients Supplier INCI (EU) [%] Phase A Colorona Merck KGaA MICA, CI 77163, 30.00 Imperial CI 77491, CI Topaz 77492, CI 77499 Supra H Luzenac 27.80 America Dry Flo PC Azelis ALUMINUM STARCH 16.00 Germany OCTENYLSUCCINATE GmbH Pigment of ALUMINA 12.00 Example 1 Timiron Merck KGaA SYNTHETIC 3.00 Ice Crystal FLUORPHLOGOPITE, CI 77891, TIN OXIDE Kaolin Merck KGaA KAOLIN 4.00 Magnesium Whittaker, MAGNESIUM STEARATE 2.00 Stearate Clark & Daniels Propylparaben Sutton PROPYLPARABEN 0.20 Phase B Eutanol G BASF AG OCTYLDODECANOL 5.00

[0202] Combine Phase A with gentle agitation. Spray Phase B onto batch while agitating bulk. Pass entire batch through a jump gap.

Use Example 29: O/W Soft Face Cream

[0203]

TABLE-US-00030 Ingredients Supplier INCI (EU) [%] Phase A RonaCare Merck KGaA METHOXYPHENYL 2.00 Pristine T-BUTYLPHENYL Bright PROPANEDIOL RonaCare AP Merck KGaA BIS-ETHYLHEXYL 1.00 HYDROXYDIMETHOXY BENZYLMALONATE Montanov 202 Seppic GmbH ARACHIDYL ALCOHOL, 2.00 BEHENYL ALCOHOL, ARACHIDYL GLUCOSIDE Tegosoft DEC Evonik DIETHYLHEXYL 5.00 Goldschmidt CARBONATE GmbH Cetiol A BASF AG HEXYL LAURATE 5.00 Phase B RonaCare Merck KGaA ECTOIN 0.50 Ectoin Pigment of ALUMINA 2.00 Example 1 Glycerol 85% Merck KGaA GLYCERIN, AQUA 5.00 Water, AQUA demineralized Phase C RonaFlair Merck KGaA BORON NITRIDE 3.00 Boroneige SF-6 Sepigel 305 Seppic GmbH LAURETH-7, 2.00 POLYACRYLAMIDE, C13-14 ISOPARAFFIN Phase D RonaCare Merck KGaA SORBITOL, DIHYDROXY 0.50 Luremin METHYLCHROMONE Water, AQUA 1.00 demineralized Phase E Preservatives PARFUM 0.00 (q.s.) Fragrance 0.00 (q.s.) Citric acid AQUA, CITRIC ACID 0.00 solution 10% (q.s.)

[0204] Heat phases A and B separately to 80 C. Add phase A and B while stirring. Homogenize. At 60 C. add the ingredients of phase C in the given order while strong mixing. Homogenize. Disperse RonaCare Luremin in the water of phase D and add to the batch while stirring. Finally add preservative sand fragrance below 40 C. Check pH and adjust to 5-5.5 with citric acid solution if necessary. Cool down to room temperature.