Tire with groove reinforcement

Abstract

The present invention is directed to a tire comprising a tread comprising: a plurality of circumferential grooves separating circumferential ribs, each groove comprising a bottom and two sidewalls; one or more groove reinforcements, each groove reinforcement laterally spaced from any other of said one or more groove reinforcements; wherein each groove reinforcement is arranged adjacent one circumferential groove; wherein at least one circumferential groove has no groove reinforcement adjacent to it; and wherein each groove reinforcement extends from the radially inner surface of the tread in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove.

Claims

1. A tire comprising a tread comprising: a plurality of circumferential grooves separating circumferential ribs, each groove comprising a bottom and two sidewalls; one or more groove reinforcements, each groove reinforcement laterally spaced from any other of said one or more groove reinforcements; wherein each groove reinforcement is arranged adjacent one circumferential groove; wherein at least one circumferential groove has no groove reinforcement adjacent to it; and wherein each groove reinforcement extends from the radially inner surface of the tread in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove; wherein the groove reinforcement consists of a rubber composition, the rubber composition comprising: between about 50 phr and 120 phr of a filler, wherein at least 20 phr of the filler is a high surface area carbon black having an iodine adsorption number of at least 100 g/kg; and between 10 phr and 30 phr of a phenolic resin.

2. The tire of claim 1, wherein at least one groove reinforcement is an asymmetric groove reinforcement and extends in the radial direction to form at least part of at least one sidewall of the adjacent groove, a part of the asymmetric groove reinforcement on one sidewall extending radially further than any part of the asymmetric groove reinforcement on the other sidewall.

3. The tire of claim 1, the tread further comprising a radially innermost tread base, where each groove reinforcement extends from the radially outer surface of the tread base in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove.

4. The tire of claim 3, wherein each groove reinforcement extends from the radially inner surface of the tread base.

5. The tire according to claim 1, wherein each groove reinforcement forms the bottom of an adjacent groove and extends further in the radial direction to form at least the radially inner quarter and at most the radially inner three-quarters of the sidewalls of that groove.

6. The tire according to claim 1, wherein the lateral sides of each groove reinforcement has one of the following shapes: convex, concave, straight or step-like.

7. The tire according to claim 1, wherein the rubber composition has a higher stiffness than the rubber composition or rubber compositions in the remaining tread.

8. A tire comprising a tread comprising: a plurality of circumferential grooves separating circumferential ribs, each groove comprising a bottom and two sidewalls; one or more groove reinforcements, each groove reinforcement laterally spaced from any other of said one or more groove reinforcements; wherein each groove reinforcement is arranged adjacent one circumferential groove; wherein at least one circumferential groove has no groove reinforcement adjacent to it; wherein each groove reinforcement extends from the radially inner surface of the tread in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove; wherein each groove reinforcement consists of a rubber composition or of a thermoplastic material having a Shore A hardness of more than 80 and an elongation at break of at least 300%.

9. The tire of claim 1, wherein the high surface area carbon black has an iodine adsorption number of at least 200 g/kg.

10. The tire of claim 1, wherein at least 10 phr of the filler is a high surface area silica having a BET surface area of at least 150 m.sup.2/g.

11. The tire according to claim 10, wherein the high surface area silica has a BET surface area of at least 200 m.sup.2/g.

12. The tire according to claim 1, wherein the rubber composition comprises at least 15 phr of the phenolic resin.

13. The tire of claim 8, wherein at least one groove reinforcement is an asymmetric groove reinforcement and extends in the radial direction to form at least part of at least one sidewall of the adjacent groove, a part of the asymmetric groove reinforcement on one sidewall extending radially further than any part of the asymmetric groove reinforcement on the other sidewall.

14. The tire of claim 8, the tread further comprising a radially innermost tread base, where each groove reinforcement extends from the radially outer surface of the tread base in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove.

15. The tire of claim 14, wherein each groove reinforcement extends from the radially inner surface of the tread base.

16. The tire according to claim 8, wherein each groove reinforcement forms the bottom of an adjacent groove and extends further in the radial direction to form at least the radially inner quarter and at most the radially inner three-quarters of the sidewalls of that groove.

17. The tire according to claim 8, wherein the lateral sides of each groove reinforcement has one of the following shapes: convex, concave, straight or step-like.

18. The tire according to claim 8, wherein the rubber composition or thermoplastic material have a higher stiffness than the rubber composition or rubber compositions in the remaining tread.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The structure, operation, and advantages of the invention will become more apparent upon contemplation of the following description taken in conjunction with the accompanying drawings, wherein:

(2) FIG. 1 represents a schematic cross section through a tire comprising groove reinforcements according to a first aspect of the present invention;

(3) FIG. 1A represents a detail of a groove reinforcement from FIG. 1;

(4) FIG. 1B represents a detail of a groove reinforcement from FIG. 1;

(5) FIG. 2 represents a schematic cross section through a tire comprising groove reinforcements according to a second aspect of the present invention;

(6) FIG. 2A represents a detail of a groove reinforcement from FIG. 2;

(7) FIG. 3 represents a schematic cross section through a tire comprising groove reinforcements according to a third aspect of the present invention; and

(8) FIG. 3A represents a detail of a groove reinforcement from FIG. 3;

(9) FIG. 3B represents a detail of a groove reinforcement from FIG. 3;

(10) FIG. 4 represents a schematic cross section through a tire comprising groove reinforcements according to a fourth aspect of the present invention.

(11) FIG. 5 represents a schematic cross section through a tire comprising groove reinforcements according to a fifth aspect of the present invention.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(12) There is disclosed a tire tread comprising: a plurality of circumferential grooves separating circumferential ribs, each groove comprising a bottom and two sidewalls; one or more groove reinforcements, each groove reinforcement laterally spaced from any other of said one or more groove reinforcements; wherein each groove reinforcement is arranged adjacent one circumferential groove; wherein at least one circumferential groove has no groove reinforcement adjacent to it; and wherein each groove reinforcement extends from the radially inner surface of the tread in a radially outward direction at least to the bottom of the adjacent circumferential groove to form at least part of the bottom of that groove.

(13) There is further disclosed a pneumatic tire comprising the tire tread.

(14) FIG. 1 shows a schematic cross section of a tire 1 according to a preferred embodiment of the invention. The tire 1 has a tread 10, an inner liner 13, a belt structure 11 comprising four belts, a carcass ply 9, two sidewalls 2, and two bead regions 3 comprising bead filler apexes 5 and beads 4. The example tire 1 is suitable, for example, for mounting on a rim of a vehicle, e.g. a truck or a passenger car. The carcass ply 9 includes a pair of axially opposite end portions 6, each of which is secured to a respective one of the beads 4. Each axial end portion 6 of the carcass ply 9 is turned up and around the respective bead 4 to a position sufficient to anchor each axial end portion 6. The carcass ply 9 may be a rubberized ply having a plurality of substantially parallel carcass reinforcing members made of such material as polyester, rayon, or similar suitable organic polymeric compounds. The turned up portions 6 of the carcass ply 9 may engage the axial outer surfaces of two flippers 8 and axial inner surfaces of two chippers 7. As shown in FIG. 1, the example tread 10 has circumferential grooves 20, 24 each essentially defining a U-shaped opening in the tread 10. The main portion of the tread 10 may be formed of a tread compound, which may be any suitable tread compound or compounds. Each circumferential groove 20, 24 is defined by a bottom 21 or base laterally separating a pair of radially extending walls 22, 23.

(15) An area adjacent to each groove 24 comprises a groove reinforcement 30, 31. Grooves 20 have no groove reinforcement. The groove reinforcement 30, 31 may consist of a rubber compound or thermoplastic polymers which have a higher hardness than the compound of the remaining tread 10. Non-limiting examples of respective compounds are given below. Examples for respective thermoplastic polymers are also given below. As seen in FIG. 1, the groove reinforcement 30, 31 or reinforcing area 30, 31 forms at least a part of the groove's 24 sidewalls 22, 23 and of the base or bottom 21 of the groove 24. In particular and as seen in FIGS. 1A and 1B, each depicted reinforcement 30, 31 includes two radially extending portions, which form at least partially the opposing sidewalls 22, 23 of an adjacent groove 24. Reinforcement 30 is a symmetric reinforcement, as the portions 36 extend radially to the same extent. Reinforcement 31 is an asymmetric reinforcement, at the portion 36a extend further radially than does the portion 36b. Further, in the depicted example, each reinforcement 30, 31 has a radially inner base portion 35 which is in (direct) contact with a supporting structure radially under the tread 10. For example such a structure may be the overlay 12 as shown in FIG. 1. Alternatively, such a structure may, for example, be a radially outermost belt ply or an undertread. As depicted in FIG. 1, each groove 24 has its own reinforcing area 30, 31 wherein the reinforcements 30, 31 adjacent the different grooves 24 are distinct with respect to the lateral direction. As mentioned already above, the remaining tread 10 may be made of any suitable or common tread compound(s).

(16) In the embodiment shown in FIGS. 1, 1A, and 1B, the shape of portions 36, 36a, 36b of the reinforcements 30, 31 tapers in the outer radial direction. Thus, the groove reinforcements 30, 31 have the ability to improve the stability of the bottoms 21 of the grooves 24 but do not provide large amounts of reinforcement material in the tread blocks or ribs which might contact the road. However, in general it is also possible that the reinforcement tapers in the opposite direction or extends with parallel sides, i.e. without taper, in the radial direction. As seen in FIG. 1B, the height of a symmetric reinforcement 30 in each of its radially extending portion 36 extends from a radially inner base portion 35 (at the radially inner surface of the tread 10) to about half of the depth of the adjacent groove 24. As seen in FIG. 1A, the height of asymmetric reinforcement 31 in portion 36a extends radially to the radially outer surface of tread 10, while the height of portion 36b extends radially to about half the depth of the adjacent groove 24. In general, the radially extending portions 36, 36a, 36b of reinforcements 30, 31 may extend at least to the bottom 21 of groove 24, but may extend to the radially outer surface of the tread 10 with the understanding that portions 36a, 36b extend radially to different extents.

(17) Alternatively, the reinforcement may extend in the radial direction to at least the inner quarter of the sidewalls 22, 23 and to at most the inner three-quarters of the sidewalls 22, 23 to form the sidewalls in that area.

(18) The lateral width of a reinforcement 30, 31 at its radially inner base portion may preferably be between 1.1 and 4.0 times larger than the axial width of the adjacent groove's 20 bottom 21. Such a relative width may provide further stiffness and support for the adjacent groove 24.

(19) FIGS. 2, 2A show another embodiment of a tire 1 and a tread 10 according to the present invention in which laterally distinct reinforcements 130 extend from the overlay 12 in a radial direction to the sidewalls 22, 23 of the grooves 24. The depicted symmetric groove reinforcement 130 has again a tapering shape extending from a radially lower base portion 135 to a narrower upper portion 136. In the present embodiment the symmetric groove reinforcement 130 extends from the radially inner surface of the tread 10 to the radially outer surface of the tread 10. Thus, both sidewalls 22, 23 and also the bottom 21 of each groove 24 are formed or provided by the reinforcement 130.

(20) The sidewalls 22, 23 of the reinforcing material in contact with the remaining tread or tread compound may have a variety of shapes. The sidewalls of the reinforcing material may have straight shape (as e.g. depicted in FIG. 1) or convex or concave shapes (not shown).

(21) FIGS. 3, 3A, 3B depict a further preferred embodiment of a tire 1 and a tread 10 according to the present invention. In the shown cross section, each asymmetric groove reinforcements 33, 34 extend radially on only one side of adjacent groove 24 and form only half of the base of the groove 24. The asymmetric groove reinforcement 33 extends radially in portion 36a to the radially outer surface of tread 10 along only one sidewall of groove 24. The asymmetric groove reinforcement 34 extends radially in portion 36b along only one sidewall only to about half of the depth of the adjacent groove 24.

(22) FIG. 4 depicts a further preferred embodiment of a tire 1 and a tread 10 according to the present invention. In the shown cross section, each of two asymmetric groove reinforcements 33 extend radially on only one side of adjacent groove 24, and forms only half of the base of the groove 24. The asymmetric groove reinforcement 33 extends radially to the radially outer surface of tread 10 along only one sidewall of groove 24.

(23) FIG. 5 depicts a further embodiment of a tire 1 and a tread 10 according to the present invention. In the shown cross section, a single asymmetric groove reinforcements 33 extends radially on only one side of adjacent groove 24, and forms only half of the base of the groove 24. The asymmetric groove reinforcement 33 extends radially to the radially outer surface of tread 10 along only one sidewall of groove 24.

(24) The tire 1 according to the above embodiments has been shown with four circumferential grooves 20, 24. However, the tire 10 may have more or less of such grooves 20, 24. Further, the tire has been depicted with four belt plies and an overlay 12. Such an overlay 12 is merely an optional feature. Furthermore, the number of belt plies may be higher or lower. For example the tire may have two belt plies only.

(25) In general it is possible to provide reinforcement described herein also to lateral grooves. However, if the reinforcements are applied to circumferential grooves 24, it is possible to extrude the groove reinforcements 30, 31, 33, 34, 130 together with the remaining tread 10 or tread compound(s). Thus, a tread 10 comprising a reinforcement 30, 31, 33, 34, 130 according to the present invention may be easily, cost-effectively and quickly produced.

(26) In one embodiment, the reinforcement consists of a rubber composition, the rubber composition comprising between about 50 phr and 120 phr of a filler, wherein at least 20 phr of the filler is a high surface area carbon black, and between 10 phr and 30 phr of a phenolic resin. The filler may consist only of high surface area carbon black. The rubber composition may comprise 100 parts of at least one rubber component, such as natural rubber, polybutadiene, styrene-butadiene copolymer or other polymers. Alternatively, the reinforcement may comprise also or consist only of polymer reinforced rubbers and/or thermoplastic polymers. For example, thermoplastic polymers may be chosen from the groups of polyamides, polyesters, polyimides or from the group of polyesters and polyamides. The polyamides may be, for example, polyamides 4-6, 6, 6-6, 11 or 12. Polyesters may be, for example, PET (polyethylene terephthalate), PEN (polyethylenenaphthalate), PBT (polybutylene terephthalate), PBN (polybutylenenaphthalate), PPT (polypropylene terephthalate), PPN (polypropylenenapthalate). A further example of a possible thermoplastic polyester elastomer is a material sold under the name Hytrel by DuPont.

(27) Below TABLE 1 gives non-limiting examples of rubber compositions which, for example, may be used as material of the reinforcements 30, 31, 33, 34, 130.

(28) TABLE-US-00001 TABLE 1 EXAMPLE 1 EXAMPLE 2 EXAMPLE 3 EXAMPLE 4 phr Material phr Material phr Material phr Material 80 Natural rubber 45 Natural rubber 80 Thio- 80 Natural rubber functionalized high vinyl SSBR 20 Polybutadiene 55 Polybutadiene 20 Polybutadiene 20 Polybutadiene 50 N191 grade 60 N134 grade 60 N191 grade 70 N191 grade carbon black carbon black carbon black carbon black 20 Silica 0 Silica 20 Silica 20 Silica 15 TDAE Oil 0 TDAE Oil 20 TDAE Oil 35 TDAE Oil 2 Bis(triethoxysilyl- 0 Bis(triethoxysilyl- 2 Bis(triethoxysilyl- 2 Bis(triethoxysilyl- propyl)disulfan propyl)disulfan propyl)disulfan propyl)disulfan 2 Fatty acid soap 0 Fatty acid soap 2 Fatty acid soap 2 Fatty acid soap 3 Stearic acid 3 Stearic acid 3 Stearic acid 3 Stearic acid 1.5 Wax 1.5 Wax 1.5 Wax 1.5 Wax 3 Hexamethylene- 5.6 Hexamethylene- 3 Hexamethylene- 3.8 Hexamethylene- tetramine tetramine tetramine tetramine 3 Antioxidants 3 Antioxidants 3 Antioxidants 3 Antioxidants 20 Novolac type 10 Novolac type 20 Novolac type 25 Novolac type resin resin resin resin 1.6 Sulfur 1.6 Sulfur 1.6 Sulfur 1.3 Sulfur 2.5 Zinc oxide 2.5 Zinc oxide 2.5 Zinc oxide 2.5 Zinc oxide 0.3 N-Cyclohexyl- 0 N-Cyclohexyl- 0.3 N-Cyclohexyl- 0.3 N-Cyclohexyl- thiophthalimide thiophthalimide thiophthalimide thiophthalimide 2.4 N,N-dicyclo- 1.8 N-cyclohexyl- 1.6 N-cyclohexyl- 2.4 N,N-dicyclo- hexyl-2-bezo- 2- 2- hexyl-2-bezo- thiazolesulfen- benzothiazole- benzothiazole- thiazolesulfen- amide sulfenamide sulfenamide amide

(29) The compositions according to the above mentioned Examples 1 to 4 given in above TABLE 1 comprise all natural rubber, polybutadiene and/or styrene-butadiene copolymer. However, other polymers could be used instead. Further, N191 or N134 grade carbon black is given in the above examples. However, carbon black having other grades could be used, as for example, other N1 and N2 series carbon blacks. The combination of a high surface area carbon black and a large amount of reinforcing resin results in high hardness (e.g. a Shore A hardness over 80) and high elongation at break (e.g. more than 300%). Although a high Shore A hardness may be known for some other rubber compositions like those for apexes, it is not known in the state of the art to produce the above mentioned combination. In particular, it is preferable that the carbon black has a high surface area with an iodine adsorption number of at least about 100 g/kg or preferably at least 180 g/kg. As known in the art, the iodine adsorption number is a measure of the surface area of carbon black which is high in the present case.

(30) According to Examples 1 to 4 silica has been used in the composition between 0 phr and 20 phr. Preferably the silica has a BET surface area of at least 100 m.sup.2/g or more preferably of at least 180 m.sup.2/g. The definition of the BET surface area is also well-known to the person skilled in the art.

(31) Further, some of the suggested tire compositions comprise parts of TDAE Oil. The amount of that component may also vary. Moreover, it may be replaced by alternative substances, as for example by MES, RAE, naphthenic oil, vegetable oil, or other plasticizers.

(32) According to the above examples a Novolac type resin is used. However, other non-self curing phenolic resins could be used. According to the above examples the resin is cross-linked using hexamethylene tetramine or hexamethoxymethylmelamine. However, other cross-linking agents could be used as well.

(33) The further components listed with amounts of less than 5 phr constitute components which are common in multiple rubber compositions and may vary as known to a person skilled in the art. For example, other silanes could be used instead of the mentioned Bis(triethoxysilylpropyl)disulfan, e.g. bis(3-triethoxysilylpropyl)tetrasulfide, Evonik Si363 from Evonik, NXT, NXT Z100, NXT Z60, NXT Z45 from Momentive Performance Materials. Instead of N-Cyclohexylthiophthalimide other prevulcanization inhibitors may be used. Further, N,N-dicyclohexyl-2-benzothiazolesulfenamide could e.g. be replaced by other known accelerators.

(34) Tests of the inventors have shown that the above compositions have each a Shore A hardness >80. In other words, the reinforcing composition is considerably harder than common tread compounds. Further, the inventors have tested the elongation at break which is indeed larger than 300%.

(35) A composition having a high Shore A hardness, as e.g. suggested in Examples 1-4, may on the one hand provide stability and a high cornering stiffness to the tire 1, if provided adjacent the grooves 20 as described herein above. On the other hand, a high elongation at break provides durability and crack resistance to the tread 10 in the region of the grooves 24.

(36) As mentioned above, tire components having a high Shore A hardness, as e.g. apexes may be known. However, such components have a considerably lower elongation at break (e.g. less than 150%).

(37) The present invention may be used for any type of tire, e.g. for passenger car tires, especially sports vehicle tires, truck tires or airplane tires. The tires may be pneumatic or non-pneumatic.

(38) Variations in the present invention are possible in light of the description. While certain representative example embodiments, examples and details have been shown for the purpose of illustrating the subject invention, it will be apparent to those skilled in this art that various changes and modifications can be made therein without departing from the scope of the subject invention. It is, therefore, to be understood that changes may be made in the particular example embodiments described which will be within the fully intended scope of the invention as defined by the following appended claims.

(39) In any case the above described embodiments and examples shall not be understood in a limiting sense. In particular, the features of the above embodiments may also be replaced or combined with one another.