Coating composition capable of embodying paper feel for food packing paper

Abstract

The present invention relates to a coating composition capable of embodying paper feel for food packing paper, comprising a resin mixture, additive and solvent, characterized in that said additive comprises 3 to 12% by weight of polyethylene-based wax.

Claims

1. A coating composition capable of embodying paper feel for food packing paper comprising a resin mixture; an additive; and a solvent, wherein the said additive comprises 3 to 12% by weight of polyethylene-based wax.

2. The coating composition according to claim 1, wherein the resin mixture is contained in an amount of 19.5 to 38% weight, based on the total weight of the coating composition.

3. The coating composition according to claim 1, wherein the resin mixture comprises vinyl chloride-vinyl alcoholvinyl acetate copolymer, polyvinyl butyral, acrylic polymer, polyurethane, rosin-modified maleic acid and polyester polyol.

4. The coating composition according to claim 1, wherein the resin mixture comprises 1 to 3% by weight of polyvinyl butyral, 1 to 5% by weight of vinyl chloride-vinyl alcoholvinyl acetate copolymer, 1 to 3% by weight of acrylic polymer, 15 to 20% by weight of polyurethane, 1 to 5% by weight of rosin-modified maleic acid and 0.5 to 2% by weight of polyester polyol, based on the total weight of coating composition.

5. The coating composition according to claim 1, wherein the additive is contained an amount of 4.9 to 19.5% by weight, based on the total weight of coating composition.

6. The coating composition according to claim 1, wherein the additive comprises a polyethylene wax, a polytetrafluoroethylene wax, a silica gel, chlorinated polypropylene, an anti-precipitating agent, and an anti-foaming agent.

7. The coating composition according to claim 6, wherein the additive comprises 1 to 4% by weight of a polyethylene wax, 2 to 8% by weight of a polytetrafluoroethylene wax, 1 to 5% by weight of a silica gel, 0.5 to 1% by weight of chlorinated polypropylene, 0.2 to 0.5% by weight of an anti-precipitating agent, and 0.2 to 1% by weight of an anti-foaming agent.

8. The coating composition according to claim 1, wherein the solvent is contained in an amount of 43 to 75% by weight, based on the total weight of the coating composition.

9. The coating composition according to claim 1, wherein the solvent comprises methyl ethyl ketone, ethyl acetate, isopropyl alcohol and propylene glycol methyl ether.

10. The coating composition according to claim 9, wherein the said solvent comprises 15 to 30% by weight of methyl ethyl ketone, 20 to 33% by weight of ethyl acetate, 5 to 7% by weight of isopropyl alcohol and 3 to 5% by weight of propylene glycol methyl ether.

11. The coating composition according to claim 1, wherein the coating composition has a viscosity of 180 to 250 centistokes.

Description

DESCRIPTION OF DRAWINGS

[0016] FIG. 1 is a side sectional view of the food packing paper (100) which is able to embody the paper feel of the present invention according to the preparation example 1, which comprises a substrate layer (110), printing layer (120) and coating layer (130) which can embody the paper feel, from the bottom.

[0017] FIGS. 2A-2C represent a conventional food packing paper which embodied the paper feel, wherein FIG. 2A shows a paper/plastic film laminate (210) comprising a substrate layer (211), adhesive layer (212) and paper layer (213) from the bottom, FIG. 2B shows a parchment paper (220), and FIG. 2C shows a food packing paper (230) comprising a substrate layer (231), printing layer (232) and matte coating layer (233) formed with a matter coating liquid.

[0018] FIG. 3 shows a perspective view of food packing paper which can embody the paper feel of the present invention according to the preparation example 1.

[0019] FIG. 4 is a photograph of food packing paper which can embody the paper feel of the present invention according to the preparation example 1.

BEST MODE FOR INVENTION

[0020] Hereinafter, an explanation on a coating composition according to the present invention will be described in detail.

[0021] As the first embodiment of the present invention, the present invention provides a coating composition for food packing paper, which can embody the paper feel, comprising a resin mixture, additive and solvent, characterized in that the additive comprises 3 to 12% by weight of polyethylene-based wax.

[0022] It is preferable that the said resin mixture is contained in an amount of 19.5 to 38% by weight, based on the total weight of the coating composition. The said resin mixture coats pigments sufficiently dispersed at the state having fluidity since it is dissolved in the solvent, separately from the particles, wherein the coating composition made by this is closely contacted with the subject side to be coated by adhesiveness that the said resin mixture has. If the content of said resin mixture is less than 19.5% by weight, the coating composition capable of embodying paper feel for the food packing paper is not closely contacted with the subject side to be coated, and thus the coating layer (130) can be cracked or peeled, and if the content of the resin mixture exceeds 38% by weight, there is a problem that the coating composition is easily coagulated and thus the coatability (coating ability) is lowered.

[0023] The said resin mixture may be a mixture of one or more species being selected from polyvinyl butyral, vinyl chloride-vinyl alcoholvinyl copolymer, acrylic polymer, polyurethane, rosin-modified maleic acid and polyester polyol.

[0024] Preferably, said resin mixture comprises 1 to 3% by weight of polyvinyl butyral, 1 to 5% by weight of vinyl chloride-vinyl alcoholvinyl copolymer, 1 to 3% by weight of acrylic polymer, 15 to 20% by weight of polyurethane, 1 to 5% by weight of rosin-modified maleic acid and 0.5 to 2% by weight of polyester polyol, based on the total weight of coating composition.

[0025] It is preferable that the said additive is contained in an amount of 4.9 to 19.5% by weight, based on the total weight of the coating composition.

[0026] Said additive may comprise polyethylene-based wax, silica gel, chlorinated polypropylene, anti-precipitating agent, and anti-foaming agent. Said polyethylene-based wax may be one or more species being selected from polyethylene wax and polytetrafluoroethylene wax.

[0027] Preferably, said additive may comprise 3 to 12% by weight of polyethylene-based wax, 1 to 5% by weight of silica gel, 0.5 to 1% by weight of chlorinated polypropylene, 0.2 to 0.5% by weight of anti-precipitating agent, and 0.2 to 1% by weight of anti-foaming agent, and more preferably said polyethylene-based wax may comprise 1 to 4% by weight of polyethylene wax, 2 to 8% by weight of polytetrafluoroethylene wax.

[0028] In the present invention, since the said polyethylene-based wax is contained in the coating composition in an amount of 3 to 12% by weight, a wear-resistance, slip-resistance, heat-resistance and paper feel can be embodied and also the phenomenon adhering on a guide roll and silicone roll which can be a problem in the lamination process (dry and T die) is solved. Also, if the polyethylene wax is used in an amount of less than 3% by weight, the paper feel cannot be embodied, and if it is used in an amount of exceeding 12% by weight, the tactile sensation of paper feel is improved but there is a problem that the coating precipitation is fast and thus the coating preserving ability is lowered.

[0029] It is preferable that the said solvent is contained in an amount of 43 to 75% by weight based on the total weight of the coating composition. The said solvent is that which the resin mixture is dissolved or diluted. If the content of the said solvent is less than 43% by weight, the coating process is not easy, and if the content of the said solvent exceeds 75% by weight, there is a problem that the coating quality is lowered.

[0030] In the present invention, one or more species being selected from ketone-based solvent, acetate-based solvent, alcohol-based solvent, and glycol ether-based solvent can be used as the said solvent. Preferably, said ketone-based solvent is methyl ethyl ketone, said acetate-based solvent is ethyl acetate, said alcohol-based solvent is isopropyl alcohol, and said glycol ether-based solvent is propylene glycol methyl ether.

[0031] More preferably, said solvent may comprise 15 to 30% by weight of methyl ethyl ketone, 20 to 33% by weight of ethyl acetate, 5 to 7% by weight of isopropyl alcohol, and 3 to 5% by weight of propylene glycol methyl ether.

[0032] The said coating composition of the present invention may comprise an anti-foaming agent, dispersing agent, labeling agent, diluents, slipping agent, plasticizer, coupling agent, ultraviolet-absorbing agent, dryer, etc, in order to improve the printing workability of the coating, and the printing effect, within the scope not impairing the desired function, if necessary.

[0033] The said coating composition according to the present invention comprises 1 to 3% by weight of polyvinyl butyral, 1 to 5% by weight of vinyl chloride-vinyl alcoholvinyl copolymer, 1 to 3% by weight of acrylic polymer, 15 to 20% by weight of polyurethane, 1 to 5% by weight of rosin-modified maleic acid and 0.5 to 2% by weight of polyester polyol as the resin mixture, and 1 to 4% by weight of polyethylene wax, 2 to 8% by weight of polytrafluoroethylene wax, 1 to 5% by weight of silica gel, 0.5 to 1% by weight of chlorinated polypropylene, 0.2 to 0.5% by weight of anti-precipitating agent and 0.2 to 1% by weight of anti-foaming agent as the additive, and comprises 15 to 30% by weight of methyl ethyl ketone, 20 to 33% by weight of ethyl acetate, 5 to 7% by weight of isopropyl alcohol, and 3 to 5% by weight of propylene glycol methyl ether.

[0034] Said coating composition may have 180 to 260 centistokes (cSt), preferably 192.4 to 251.6 cSt. If it is less than 180 cSt, the adhesiveness and binding force are low, and thus, the printing quality can be lowered, and if it exceeds 260 cSt, the viscosity is high and thus the coating process is not easy.

[0035] It is preferable that the particle size of said coating composition is 3 m or less. If the particle size of the coating composition exceeds 3 m, there is a problem that the coatability is lowered due to the particle size of the wax.

[0036] Hereinafter, the constitution of the present invention will be described in detail, and the following examples are only to illustrate the present invention, but the content of the present invention is not limited to the following examples.

EXAMPLE

Example 1

Preparation of the Coating Composition According to the Present Invention

[0037] The present invention obtained a coating composition whose viscosity is 202 SEC (measured with RIGOSHA ZHAN CUP #4 at 25 C.) and whose mean particle size is 3 m or less, by combining a resin mixture, additive and solvent in the component and content as described in the below Table 1.

TABLE-US-00001 TABLE 1 (Combination component and content of the coating composition of the present invention) Example 1 (% Constitutive components by weight) Resin Polyvinyl butyral 1 mixture Vinyl chloride-Vinyl alcoholvinyl 1 acetate copolymer Acryl polymer 1 Polyurethane 15 Rosin modified maleic acid 1 Polyester polyol 0.5 Additives Polyethylene wax 1 Polytetrafluoroethylene (PTFE) wax 5 Silica gel 1 Chlorinated polypropylene (CPP) 0.5 Antiprecipitating agent 0.2 Antifoaming agent 0.2 Solvent Methyl ethyl ketone (MEK) 30 Ethyl acetate 32.6 Isopropyl alcohol 5 Propylene glycol methyl ether 5

Preparation Example 1

Preparation of Food Packing Paper Embodying Paper Feel According to the Present Invention

[0038] The preparation of food packing paper embodying the paper feel according to one example of the present invention produced the food packing paper embodying the paper feel by coating (dry lamination) of the coating composition prepared from Example 1.

[0039] The produced food packing paper embodying the paper feel has the laminated structure as represented in FIG. 3, and it can be ascertained from FIG. 4 that, like a real photograph of food packing paper embodying the paper feel according to the present invention as shown, the food packing paper embodying the paper feel wherein the coating composition for food packing paper is applied has a matte effect and paper-like feel. Also, upon comparing the gloss and roughness of the present invention with a real paper, the results as represented in the below Table could be obtained.

EXPLANATION OF REFERENCE NUMERAL

[0040] 100: Food packing paper which can embody the paper feel of the present invention [0041] 110, 211, 231: Substrate layer [0042] 120, 232: Printing layer [0043] 130: Coating layer [0044] 210: Paper/plastic film laminate [0045] 212: Adhesive layer [0046] 213: Paper layer [0047] 220: Parchment paper [0048] 230: Food packing paper coated with a matte coating liquid [0049] 233: Matte coating layer

[0050] While the present invention has been described with reference to the particular illustrative embodiments, it is not to be restricted by the embodiment but only by the appended claims. It is to be appreciated that those skilled in the art can change or modify the embodiments without departing from the scope and spirit of the present invention.