Hard disk double lubrication layer

Abstract

Systems and methods are illustrated for manufacturing hard disks with double lubrication layers that allow minimization of a HDD head DFH touchdown point while maintaining good tribology performance for HDD reliability. An exemplary hard disk includes a magnetic recording layer, a carbon overcoat, and a double lubrication layer: a bonded lubrication layer and a mobile lubrication layer. The bonded lubrication layer includes a high conformity and high density first lubricant. The mobile layer include a high lubricity lubricant that promotes HDI reliability.

Claims

1. A hard disk lubrication layer, comprising: a first lubrication layer bonded on a carbon overcoat of the hard disk, the first lubrication layer comprising a lubricant with chemical structure: ##STR00001## wherein Rc is a center connection structure with a connection number p, Re is a functional end group, and Rf is a fluorocarbon chain; and a second lubrication layer on the first lubrication layer, wherein the second lubrication layer is a mobile layer comprising a lubricant with chemical structure:
ReRfRe wherein Re is a functional end group and Rf is a fluorinated chain; wherein the first lubrication and the second lubrication layer comprise different lubricants; wherein the center connection structure Rc is selected from the group consisting of (Rc1 through Rc14): ##STR00002## wherein the fluorocarbon chain Rf of the first lubrication layer is selected from the group consisting of (Rf3 through Rf6):
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2 (m,n=525)R.sub.f3:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.pCF.sub.2CH.sub.2 (p=1040)R.sub.f4:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.qCF.sub.2CH.sub.2 (p=525)R.sub.f5:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.rCF.sub.2CH.sub.2 (r=525)R.sub.f6: wherein the functional end group Re of the lubricant of the first lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00003## wherein the functional end group Re of the lubricant of the second lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00004##

2. The hard disk lubrication layer of claim 1, wherein the first lubrication layer comprises per-fluoro-poly-ether (PFPE) lubricant.

3. The hard disk lubrication layer of claim 1, wherein the thickness of the first lubrication layer is 5 to 10 .

4. The hard disk lubrication layer of claim 1, wherein the thickness of the second lubrication layer is 2 to 4 .

5. A hard disk drive comprising: a disk drive base; a spindle motor attached to the disk drive base and configured to support a disk for rotating the disk with respect to the disk drive base surface; and a rotatable disk, comprising: a carbon overcoat on a magnetic recording layer; a first lubrication layer bonded on a carbon overcoat of the hard disk, the first lubrication layer comprising a lubricant with chemical structure: ##STR00005## wherein Rc is a center connection structure with a connection number p, Re is a functional end group, and Rf is a fluorocarbon chain; and a second lubrication layer on the first lubrication layer, wherein the second lubrication layer is a mobile layer comprising a lubricant with chemical structure:
ReRfRe wherein Re is a functional end group and Rf is a fluorinated chain; and wherein the first lubrication and the second lubrication layer comprise different lubricants; wherein the center connection structure Rc is selected from the group consisting of (Rc1 through Rc14): ##STR00006## wherein the fluorocarbon chain Rf of the first lubrication layer is selected from the group consisting of (Rf3 through Rf6):
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2 (m,n=525)R.sub.f3:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.pCF.sub.2CH.sub.2 (p=1040)R.sub.f4:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.qCF.sub.2CH.sub.2 (p=525)R.sub.f5:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.rCF.sub.2CH.sub.2 (r=525)R.sub.f6: wherein the functional end group Re of the lubricant of the first lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00007## wherein the functional end group Re of the lubricant of the second lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00008##

6. The hard disk drive of claim 5, wherein the first lubrication layer comprises per-fluoro-poly-ether (PFPE) lubricant.

7. The hard disk drive of claim 5, wherein the thickness of the first lubrication layer is 5 to 10 .

8. The hard drive of claim 5, wherein the thickness of the second lubrication layer is 2 to 4 .

9. A method of lubricating a hard disk comprising a carbon overcoat, comprising: creating a first lubrication layer on top of the carbon overcoat, the first lubrication layer comprising a lubricant with chemical structure: ##STR00009## wherein Rc is a center connection structure with a connection number p, Re is a functional end group, and Rf is a fluorocarbon chain; and creating a second lubrication layer on top of the first lubrication layer wherein the second lubrication layer is a mobile layer comprising a lubricant with chemical structure:
ReRfRe wherein Re is a functional end group and Rf is a fluorinated chain; and wherein the first lubrication and the second lubrication layer comprise different lubricants; wherein the center connection structure Rc is selected from the group consisting of (Rc1 through Rc14): ##STR00010## wherein the fluorocarbon chain Rf of the first lubrication layer is selected from the group consisting of (Rf3 through Rf6):
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2 (m,n=525)R.sub.f3:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.pCF.sub.2CH.sub.2 (p=1040)R.sub.f4:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.qCF.sub.2CH.sub.2 (p=525)R.sub.f5:
(R.sub.c)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.rCF.sub.2CH.sub.2 (r=525)R.sub.f6: wherein the functional end group Re of the lubricant of the first lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00011## wherein the functional end group Re of the lubricant of the second lubrication layer is selected from the group consisting of (Re1 through Re6): ##STR00012##

10. The method of claim 9, wherein creating the first lubrication layer comprises: coating the disk with a first solution comprising a first lubricant and a fluorosolvent; and applying a bonding treatment to the disk to bond the first lubricant to the disk.

11. The method of claim 10, wherein coating the disk with the first solution comprises: dipping the disk into the first solution; and removing the disk from the first solution at a first predetermined speed.

12. The method of claim 11, wherein applying a bonding treatment comprises exposing the disk to UV light or heating the disk in a chamber.

13. The method of claim 11, wherein creating the second lubrication layer comprises: removing the non-bonding first lubricant from the disk using a strip solvent; and coating the disk with a second solution comprising a second lubricant and a fluorosolvent.

14. The method of claim 13, wherein coating the disk with the second solution comprises: dipping the disk into the second solution; and removing the disk from the second solution at a second predetermined speed.

15. The method of claim 14, wherein the first and second predetermined speeds are between 1 mm/second and 2 mm/second.

16. The method of claim 9, wherein the disk is a sputtered magnetic disk and the thickness of the carbon overcoat is between 10 and 30 .

17. The method of claim 9, wherein creating the first lubrication layer comprises: coating the disk with a vaporized first lubricant; and applying a bonding treatment to the disk to bond the first lubricant to the disk; and wherein creating the second lubrication layer comprises: removing the non-bonding first lubricant from the disk using a strip solvent; and coating the disk with a vaporized second lubricant.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The present application is illustrated by way of example, and not limitation, in the figures of the accompanying drawings in which:

(2) FIG. 1 is a schematic diagram illustrating a lubricated hard disk in accordance with the present disclosure.

(3) FIGS. 2A through 2D-6 illustrate molecular structures for exemplary lubricants that may be used as the lubricant in the bonded lubrication layer of the hard disk of FIG. 1.

(4) FIGS. 3A through 3B-6 illustrate molecular structures for exemplary lubricants that may be used as the lubricant in the mobile lubrication layer of the hard disk of FIG. 1.

(5) FIG. 4 is an operational flow diagram illustrating an exemplary dipping lubrication process for manufacturing the lubricated disk of FIG. 1.

(6) FIG. 5 is an operational flow diagram illustrating a vaporization lubrication process for manufacturing the lubricated disk of FIG. 1.

DETAILED DESCRIPTION

(7) In the following description, numerous specific details are set forth to provide a thorough understanding of various embodiment of the present disclosure. It will be apparent to one skilled in the art, however, that these specific details need not be employed to practice various embodiments of the present disclosure. In other instances, well known components or methods have not been described in detail to avoid unnecessarily obscuring various embodiments of the present disclosure.

(8) The terms over, under, between, and on as used herein refer to a relative position of one media layer with respect to other layers. As such, for example, one layer disposed over or under another layer may be directly in contact with the other layer or may have one or more intervening layers. Moreover, one layer disposed between two layers may be directly in contact with the two layers or may have one or more intervening layers. By contrast, a first layer on a second layer is in contact with that second layer. Additionally, the relative position of one layer with respect to other layers is provided assuming operations are performed relative to a substrate without consideration of the absolute orientation of the substrate.

(9) In accordance with the present disclosure, systems and methods are illustrated for manufacturing hard disks with double lubrication layers that allow minimization of the DFH touchdown point while maintaining good tribology performance for HDD reliability. These benefits are achieved by providing two lubrication layers comprising different lubricant materials to maximize the separate functions of: 1) conformity and 2) durability and mobility. The disclosed hard disks may be implemented in a high storage density HDD that includes a DFH adjust. In one embodiment, the disclosed hard disk may be implemented in a heat-assisted magnetic recording HDD.

(10) FIG. 1 is a schematic diagram illustrating an exemplary lubricated hard disk 100 in accordance with the present disclosure. Hard disk 100 comprises a magnetic recording layer 101, a carbon overcoat 102, and a double lubrication layer: bonded lubrication layer 103 and mobile lubrication layer 104. Hard disk 100 may be implemented in any high storage density HDD comprising a read/write head that reads and writes data to magnetic recording layer 101. In one embodiment the thickness of carbon overcoat layer 102 is between 10 and 30 .

(11) In this exemplary embodiment, the two lubrication layers 103-104 comprise different lubricants. In one embodiment, the different lubricants are per-fluoro-poly-ether (PFPE) lubricants. Bonded lubrication layer 103 comprises a highly condensed and conformal lubricant for maximizing the available spacing margin and thereby lowering the DFH touch-down point. In one embodiment, the thickness of bonded lubrication layer 103 is between 5 and 10 . The thinness and uniformity of bonded lubrication layer 103 provides the benefit of allowing a close fly-by of the HDD head.

(12) FIGS. 2A through 2D-6 illustrate molecular structures for exemplary PFPE lubricants that may be used in one embodiment of bonded lubrication layer 103. In this exemplary embodiment, the molecular structure 200 of bonded lubrication layer 103 comprises a functional end group 201, a center connection structure 202, and a fluorocarbon chain 203. These exemplary lubricants exhibit the property of a short branch length relative to conventional lubricants, thereby allowing for a smaller gyration diameter and lower physical thickness of bonded lubrication layer 103.

(13) FIGS. 2B-1 through 2B-8 illustrate center connection structures 202 that may be used in 2-chain embodiments of molecular structure 200. FIGS. 2B-9 through 2B-11 illustrate center connection structures 202 that may be used in 3-chain embodiments of molecular structure 200. FIG. 2B-12 illustrates a center connection structure 202 that may be used in 4-chain embodiments of molecular structure 200. FIGS. 2B-13 through 2B-14 illustrate center connection structures 202 that may be used in 6-chain embodiments of molecular structure 200.

(14) FIGS. 2C-1 through 2C-7 illustrate exemplary fluorocarbon chain structures 203 that may be used in embodiments of molecular structure 200. FIG. 2C-2, for example, illustrates a tri-fluoro methane molecular structure. FIG. 2C-7, for example, illustrates a tri-fluoro phenoxy benzene molecular structure. FIGS. 2D-1 through 2D-6 illustrate exemplary functional end groups 201 that may be used in embodiments of molecular structure 200.

(15) Mobile lubrication layer 104 comprises a low friction and high durability lubricant for improving tribology performance of the HDD, i.e. preventing dragging of a read/write head on disk 100. The high lubricity of mobile lubrication layer 104 provides the benefit of minimizing the wear of carbon overcoat layer 102, which protects the magnetic recording layer 101 of disk 100. Moreover, the high lubricity of mobile lubrication layer 104 provides the benefit of minimizing HDD head carbon overcoat wear. In one embodiment, the thickness of mobile lubrication layer 104 is between 2 to 4 .

(16) FIGS. 3A through 3B-6 illustrate molecular structures for exemplary lubricants that may be used as the lubricant in the mobile lubrication layer 104 of the hard disk of FIG. 1. In this exemplary embodiment, the molecular structure 300 of bonded lubrication layer 103 comprises a functional end group 301 and a fluorinated chain 302. FIGS. 3B-1 through 3B-6 illustrate exemplary functional end groups 301 that may be used in embodiments of molecular structure 300.

(17) In one embodiment, bonded lubrication layer 103 and mobile layer 104 comprise the same PFPE lubricant but with different molecular weights (MW). For example, in one embodiment mobile layer 104 may comprise a higher MW version of the PFPE lubricant. This provides the benefit of preventing the loss of mobile lubrication by evaporation during drive operations at high temperatures. In this embodiment, bonded lubrication layer 103 may comprise a lower MW version of the PFPE lubricant for a thin and conformal lubrication layer structure.

(18) FIGS. 4-5 are operational flow diagrams illustrating exemplary processes for manufacturing lubricated disk 100. In both processes, a sputtered magnetic disk with magnetic recording layer 101 and carbon overcoat 102 is provided prior to lubrication. FIG. 4 illustrates an exemplary dipping lubrication process 400 for manufacturing lubricated disk 100. At operation 402, the disk is coated with a first solution comprising a first lubricant and a fluorosolvent. In this exemplary dipping lubrication process 400, operation 402 is performed by dipping the disk in the first solution and removing the disk from the first solution at a predetermined speed, for example, 1 to 2 mm/second. In one embodiment, the fluorosolvent has a concentration of 0.01-0.02 wt %.

(19) At operation 404, a bonding treatment is applied to the disk to bond the first lubricant to the disk, thereby creating the first lubrication layer, bonded lubrication layer 103. The bonding treatment increases the bonding strength between the lubricant molecules and the carbon overcoat 102. In one embodiment, the bonding treatment comprises exposing the disk to ultraviolet (UV) light. For example, the disk may be exposed to a low-pressure Mercury UV lamp between 20 and 40 seconds. In an alternative embodiment, the bonding treatment comprises heating the disk in a chamber above a predetermined temperature, for example 100 C. The second lubrication layer may then be formed at operations 406-408.

(20) Before coating the disk with a second lubricant after bonding operation 404, any non-bonding lubricant may be removed at operation 406. This removal process provides the benefit of preventing mixing of non-bonded first lubricant with the second lubricant, thereby maximizing the effect of the second lubricant. Moreover, operation 406 provides the benefit of keeping the subsequent coating process contamination free. In one embodiment, non-bonded lubricant is removed or stripped using a stripping solvent. For example, the disk may be soaked in fluorinated solvent for 5 to 10 minutes to dissolve un-bonded first lubricant material into the solvent. After soaking, the disk may be removed from the solvent at a predetermined speed, for example, 1 to 2 mm/second.

(21) At operation 408, the disk is coated with a second solution comprising a second lubricant and a fluorosolvent. In exemplary dipping lubrication process 400, operation 408 is performed by dipping the disk in the second solution and removing the disk from the first solution at a predetermined speed (e.g. 1 to 2 mm/second), thereby creating a second lubrication layer, mobile layer 104. In one embodiment, the fluorosolvent has a concentration of 0.01-0.02 wt %.

(22) FIG. 5 is an operational flow diagram illustrating an exemplary vaporization lubrication process 500 for manufacturing lubricated disk 100. At operation 502, the disk is coated with a first lubricant by applying a vapor lubrication process. In one exemplary implementation of the vapor lubrication process, a high conformity lubricant is coated on the disk without solvent by vaporizing the lubricant via direct heating inside a vacuum chamber. The first lubricant may then be bonded to the disk's carbon overcoat 102 at operation 504 by applying a bonding treatment (as described above) to the disk to bond the first lubricant to the disk, thereby creating the first lubrication layer, bonded lubrication layer 103.

(23) At operation 506, prior to coating the disk with a second lubricant via a second vaporization process, any non-bonding first lubricant is removed using any suitable removal process such as for example, the strip removal process described above in operation 406. The disk is then coated with a second lubricant at operation 508 by applying a vapor lubrication process. In one exemplary implementation of the vapor lubrication process, a high lubricity lubricant is coated on the disk without solvent by vaporizing the lubricant via direct heating inside a vacuum chamber. A second lubrication layer, mobile layer 104, is thereby creating.

(24) In alternative embodiments, a combination of dipping and vaporization processes may be implemented in the manufacture of the double lubrication layer (e.g. dipping to create first lubrication layer and vaporization to create second lubrication layer or vice-versa). In yet other embodiments, the disk may comprise more than two lubrication layers, whereby the plurality of lubrication layers improve the head touchdown point and overall HDI reliability.

(25) In the foregoing specification, embodiments of the disclosure have been described with reference to specific exemplary features thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the disclosure. The specification and figures are, accordingly, to be regarded in an illustrative rather than a restrictive sense.