HIGH-PERFORMANCE ANTI-FUNGAL, ANTI-BACTERIAL, INSECTICIDAL AND DEODORIZING MICROCAPSULE, AND APPLICATION THEREOF

Abstract

Disclosed are a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule and its application. The functional microcapsule includes the following raw materials in parts by weight: a constant-temperature sublimation agent of 4050 parts by weight, an anti-bacterial agent of 1015 parts by weight, a deodorant of 1015 parts by weight, an insecticide of 1015 parts by weight, an anti-fungal agent of 1015 parts by weight, a solvent of 100 parts by weight, a release agent of 6001000 parts by weight, a diluent of 600010000 parts by weight, and an emulsifier of 0.20.25 part by weight.

Claims

1. A high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule, comprising the following raw materials in parts by weight: a constant-temperature sublimation agent of 4050 parts by weight, an anti-bacterial agent of 1015 parts by weight, a deodorant of 1015 parts by weight, an insecticide of 1015 parts by weight, an anti-fungal agent of 1015 parts by weight, a solvent of 100 parts by weight, a release agent of 6001000 parts by weight, a diluent of 600010000 parts by weight, and an emulsifier of 0.20.25 part by weight.

2. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the anti-bacterial agent is one selected from the group consisting of hinokitiol, citronellal, thymol, bronopol, pyridine zinc sulfate, stable chlorine dioxide solution, and any mixture thereof.

3. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the anti-fungal agent is one selected from the group consisting of citral, bromo cinnamic aldehyde, clove oil, litsea oil, eucalyptus oil, propionate, O-phenylphenol, dodecyl guanidine hydrochloride, and any mixture thereof.

4. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the deodorant is one selected from the group consisting of chitin, chitosan, glyoxal, glutaraldehyde, maleate, and any mixture thereof.

5. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the insecticide is one selected from the group consisting of empenthrin, imiprothrin, D-phenothrin, and any mixture thereof.

6. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the constant-temperature sublimation agent is one selected from the group consisting of 2,4,6-triisopropylsilyl-1,3,5-three oxygen-dioxane, 2-hydroxy camphor, adamantane, and any mixture thereof.

7. The high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule as claimed in claim 1, wherein the release agent is one selected from the group consisting of -cyclodextrin, gelatin, gum Arabic, shellac, kerria, starch, dextrin, wax, turpentine, alginate, (hydroxyphenyl) methyl cellulose, ethyl cellulose, polyethylene, polystyrene, polybutadiene, polyether, polyurea, polyethylene glycol, polyvinyl alcohol, polyamide, polyacrylamide, polyurethane, polymethyl methacrylate, polyvinylpyrrolidone, epoxy resin, polysiloxane, and any mixture thereof.

8. An application of a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule, characterized in that a functional microcapsule is added into pulp, and the added amount is equal to 1020 parts by weight to manufacture paper or corrugated cardboards with different weights in grams, so as to produce sheets of a shoes box.

9. An application of a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule, characterized in that a functional microcapsule of 2025 parts by weight and a film former of 7075 parts by weight are thoroughly stirred and mixed at room temperature and then sprayed or coated onto the inner surface of a shoes box, and the sprayed or coated amount is equal to 600800 g per cubic meter.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0021] FIG. 1 is a sectional view of a preferred embodiment of this disclosure; and

[0022] FIG. 2 is a flow chart of the preparation in accordance with a preferred embodiment of this disclosure.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0023] The technical content of this disclosure will become apparent with the detailed description of preferred embodiments and the illustration of related drawings as follows.

[0024] The objectives of this disclosure can be achieved by the following three methods: 1. A layer of the mixture of a functional microcapsule and a film former is sprayed or coated on the inner surface of the original package box; 2. The functional microcapsule is added into pulp to manufacture paper or corrugated cardboards with different weights in grams and further manufacture shoes package boxes with different models and sizes; 3. The functional microcapsule and various polymer plastics, natural inorganic mineral powders, and functional additives are mixed, banburied, and processed by lamination and corona to manufacture sheets for making shoes package boxes with different models and sizes. The details are described below:

[0025] With reference to FIG. 1 for a specific structure with an application of a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule of a in accordance with a preferred embodiment of this disclosure, a layer of functional agent is sprayed or coated onto the inner wall of a containing space 11 of a main body 10 of a package box, wherein the functional agent includes an anti-bacterial agent, an anti-fungal agent, a deodorant, or an insecticide to work with a constant-temperature sublimation agent, and a release agent to prepare a functional microcapsule, and then the functional agent and the film former are mixed to product a mixture which can be sprayed or coated onto the inner surface of a shoes package box to form a thin film 20 capable of releasing an effective composition within a long term of validity. The sprayed/coated amount is calculated according to the volume of the containing space 11 of the package box, which is equal to 600800 g per cubic meter.

[0026] In another application of a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule, the anti-bacterial agent, anti-fungal agent, deodorant, and insecticide together with a constant-temperature sublimation agent and a release agent are used to manufacture a functional microcapsule, and then the functional microcapsule is mixed with pulp to manufacture paper or corrugated cardboards with different weights in grams, and then manufacture shoes package boxes with different models and sizes. The added amount of functional microcapsule is equal to 1020% of the weight of the package box.

[0027] In another application of a high-performance anti-fungal, anti-bacterial, insecticidal and deodorizing microcapsule, a functional microcapsule of 1020% parts by weight and various polymer plastics, natural inorganic mineral powders such as calcium carbonate, calcium sulfate, barium sulfate, mica, zinc oxide, dolomite, or tulcom and a functional additive such as a coupling agent, a lubricant, an anti-oxidant, an anti-static agent or a brightener are mixed, banburied, and processed by lamination and corona to manufacture sheets for making shoes package boxes with different models and sizes.

[0028] In this disclosure, the constant-temperature sublimation agent is one selected from the group consisting of 2,4,6-triisopropylsilyl -1,3,5-three oxygen-dioxane, 2-hydroxy camphor, adamantane, and any mixture thereof; the anti-bacterial agent is one selected from the group consisting of hinokitiol, citronellal, thymol, bronopol, pyridine zinc sulfate, and any mixture thereof; the deodorant is one selected from the group consisting of chitin, chitosan, glyoxal, glutaraldehyde, maleate, and any mixture thereof; the insecticide is one selected from the group consisting of empenthrin, imiprothrin, D-phenothrin, and any mixture thereof; the anti-fungal agent is one selected from the group consisting of citral, bromo cinnamic aldehyde, clove oil, litsea oil, eucalyptus oil, propionate, and any mixture thereof; the solvent is one selected from the group consisting of ethanol; the release agent is one selected from the group consisting of -cyclodextrin, gelatin, gum Arabic, shellac, kerria, starch, dextrin, wax, turpentine, alginate, (hydroxyphenyl) methyl cellulose, ethyl cellulose, polyethylene, polystyrene, polybutadiene, polyether, polyurea, polyethylene glycol (molecular weight: 4,0008,000), polyethylene glycol, polyvinyl alcohol, polyamide, polyacrylamide, polyurethane, polymethyl methacrylate, polyvinylpyrrolidone, epoxy resin, polysiloxane, and any mixture thereof; the diluent is one selected from the group consisting of deionized water or distilled water; and the film former is one selected from the group consisting of water-soluble polyurethane resin, alcohol-soluble acrylic acid resin, rosin resin, water-soluble alkyd resin, water-soluble epoxy resin, polyvinyl alcohol, (hydroxyphenyl) methyl cellulose, (hydroxyphenyl) ethyl cellulose, (hydroxyphenyl) propyl cellulose, polyvinylpyrrolidone, starches adhesive, and any mixture thereof.

[0029] In this disclosure, the constant-temperature sublimation agent of 4050 parts by weight, the anti-bacterial agent of 1015 parts by weight, the deodorant of 1015 parts by weight, the insecticide of 1015 parts by weight, the anti-fungal agent of 1015 parts by weight, and the solvent of 100 parts by weight are mixed to produce a functional mixture prepared for use. Add a release agent of 6001000 parts by weight, into a diluent of 600010000 parts by weight, and heat uniformly until they are dissolved, and then cooled to 60 C. before adding an emulsifier of 0.20.25 parts by weight and the functional mixture for embedment overnight at a 500 W supersonic condition, and homogenization takes place at the condition of 30 MPa for 45 times, and then the spray-drying process is conducted to obtain the functional microcapsule.

[0030] 1. A functional microcapsule of 1020% parts by weight and pulp are mixed to manufacture paper or corrugated cardboards with different weights in grams, and further manufacture shoes package boxes with different models and sizes.

[0031] 2. A functional microcapsule of 1020% parts by weight and various polymer plastics, natural inorganic mineral powders, and functional additives are mixed, banburied, and processed by lamination and corona to manufacture sheets for making shoes package boxes with different models and sizes.

[0032] 3. A functional microcapsule of 2530% parts by weight and a film former of 7075% parts by weight are thoroughly stirred and mixed at room temperature, and then sprayed or coated onto the inner surface of a shoes box, wherein the sprayed or coated amount is equal to 600800 g per cubic meter.

TABLE-US-00001 Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Composition 1 2 3 4 5 6 7 8 Constant- 2,4,6-triisopropyl- 4 4.2 4.6 temperature silyl-1,3,5-three sublimation oxygen-dioxane agent 2-hydroxy camphor 4.5 0.1 4.5 5 Adamantine 5 4.8 Anti- Hinokitiol 1.5 0.5 bacterial Citronellal 1.2 agent Thymol 1.1 0.7 Bronopol 1.3 0.8 Pyridine zinc sulfate 1.4 0.5 Stable chlorine 1.4 dioxide solution Deodorant Chitosan 1.3 1 1.1 1 Glyoxal 1.5 0.5 0.5 Glutaraldehyde 1.2 0.6 Maleate 1.4 Insecticide Empenthrin 1.2 1.5 1.1 1 Imiprothrin 1 0.5 0.3 D-phenothrin 1.4 1.3 0.7 Anti-fungal Citral 0.5 agent Bromo cinnamic 1.4 1 aldehyde Clove oil 1.3 1 Litsea oil 1.1 0.3 Propionate 1 Eucalyptus oil 1.2 0.2 Dodecyl guanidine 1.5 hydrochloride Release -cyclodextrin 80 70 agent Gum Arabic 60 100 Gelatin 80 90 Polyethylene 70 80 glycol-8,000 Solvent Ethanol 10 10 10 10 10 10 10 10 Emulsifier Polysobate-80 0.02 0.021 0.022 0.024 0.025 0.023 0.02 0.02 Diluent Distilled water or 800 600 800 700 1000 900 800 700 deionized water

EMBODIMENTS 18

[0033] The constant-temperature sublimation agent, the anti-bacterial agent, the deodorant, the insecticide, the anti-fungal agent, and the solvent are uniformly mixed at room temperature to produce a functional mixture prepared for use. A release agent is weighed and a diluent is added, heated and uniformly stirred until it dissolves, and then cooled to 60 C. An emulsifier and the functional mixture are added and embedded in the 500 W supersonic condition for 3045 min. and then kept overnight, and a homogenization is conducted at the condition of 30 MPa for 45 times, and then a spray-drying process is conducted to obtain the functional microcapsule.

[0034] After the functional microcapsule is mixed with pulp to manufacture paper or corrugated cardboards with different weights in grams; or the functional microcapsule and various polymer plastics, natural inorganic mineral powders, and functional additives are mixed, banburied, and processed by lamination and corona to manufacture sheets for making anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package boxes with different models and sizes.

TABLE-US-00002 Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Embodiment Composition 9 10 11 12 13 14 15 16 Embodiment 1 25 Embodiment 2 20 Embodiment 3 22 Embodiment 4 21 Embodiment 5 24 Embodiment 6 22 Embodiment 7 23 Embodiment 8 25 Film Water-soluble 75 former polyurethaneresin (Solid Content 35%) Alcohol-soluble 70 52 acrylic acid resin Rosin resin 30 42 Polyvinyl alcohol 20 59 (Hydroxyphenyl) 41 15 36 methyl cellulose Ethyl cellulose 30 Modified starch 58 15 Polyvinylpyrrolidone 35 Solvent Ethanol 45 45 45 20 Diluent Distilled water or 80 75 75 20 deionized water

EMBODIMENT 9

[0035] The functional microcapsule manufactured in accordance with Embodiment 1 is added into the water-soluble polyurethaneresin solution and uniformly stirred and mixed at room temperature, and then sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 10

[0036] The alcohol-soluble acrylic acid resin and the solvent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 2 is added and uniformly stirred and mixed at room temperature, and then sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 11

[0037] Rosin resin and the solvent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 3 is added and uniformly stirred and mixed at room temperature, and then sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 12

[0038] Polyvinyl alcohol and the diluent are stirred at 95 C. until they are completely dissolved, and then cooled to 40 C., and the functional microcapsule manufactured in accordance with Embodiment 4 is added and then uniformly stirred and mixed at room temperature, and sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 13

[0039] (Hydroxyphenyl) methyl cellulose and the diluent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 5 is added and uniformly stirred and mixed at room temperature and sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 14

[0040] Ethyl cellulose and the solvent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 6 is added and uniformly stirred and mixed at room temperature and sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 15

[0041] Modified starch and the diluent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 7 is added and uniformly stirred and mixed at room temperature and sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

EMBODIMENT 16

[0042] Polyvinylpyrrolidone, the diluent, and the solvent are stirred at room temperature until they are completely dissolved, and the functional microcapsule manufactured in accordance with Embodiment 8 is added and uniformly stirred and mixed at room temperature and sprayed or coated onto the inner surface of a shoes box to obtain the anti-fungal, anti-bacterial, insecticidal and deodorizing shoes package box.

[0043] While the invention is described in some detail hereinbelow with reference to certain illustrated embodiments, it is to be understood that there is no intent to limit it to those embodiments. On the contrary, the aim is to cover all modifications, alternatives and equivalents falling within the spirit and scope of the invention as defined by the appended claims.