ELIMINATING FOULING IN HYDROCARBON PIPELINES BY ELECTRICAL TECHNIQUES

Abstract

A method for eliminating hydrocarbon fouling and reducing pumping power during hydrocarbon transportation. A dielectric layer covers the inner surface of a pipeline for transporting a water-hydrocarbon mixture. A proximity electrode is immersed in the water-hydrocarbon mixture, and an electrical voltage is applied across the dielectric layer. A buffer layer of water is formed on the dielectric layer since water is electrically attracted from the water-hydrocarbon mixture. This water layer, located between the dielectric layer and the water-hydrocarbon mixture, eliminates hydrocarbon fouling on the inner surface of the pipeline or any other internal surface that needs fouling protection. Alternatively, the dielectric layer covers an outer surface of the pipeline and is covered by an external conducting layer. Applying a potential difference between the proximity electrode and the external conducting layer still forms a water buffer layer between the inner surface and the water-hydrocarbon mixture, which eliminates hydrocarbon fouling.

Claims

1. A method for eliminating hydrocarbon fouling in transporting and storing a water-hydrocarbon mixture, the method comprising: covering an inner surface of a pipeline for transporting and storing said water-hydrocarbon mixture with a dielectric layer; applying a potential difference across said dielectric layer established by applying an electrical potential to a proximity electrode immersed in a solution of said water-hydrocarbon mixture and applying an electrical potential to said pipeline; and forming a buffer layer of water on top of said dielectric layer by electrically attracting water from said water-hydrocarbon mixture to said buffer layer by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said dielectric layer and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

2. The method as recited in claim 1, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes, hydrates and scales.

3. The method as recited in claim 1, wherein said dielectric layer has antifouling chemical properties and/or low surface energy.

4. The method as recited in claim 1, wherein said dielectric layer comprises one of the following: an oxide, a polymer and a ceramic.

5. A transportation mechanism for transporting hydrocarbons, the mechanism comprises: a pipeline for transporting a water-hydrocarbon mixture; a dielectric layer covering an inner surface of said pipeline; a proximity electrode immersed in said water-hydrocarbon mixture, wherein a potential difference is applied across said dielectric layer established by applying an electrical potential to said proximity electrode and applying an electrical potential to said pipeline; and a buffer layer of water on top of said dielectric layer, wherein said water buffer layer comprises water electrically attracted from said water-hydrocarbon mixture by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said dielectric layer and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on an inner surface of said pipeline.

6. The transportation mechanism as recited in claim 5, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

7. The transportation mechanism as recited in claim 5, wherein said dielectric layer has antifouling chemical properties and/or low surface energy.

8. The transportation mechanism as recited in claim 5, wherein said dielectric layer comprises one of the following: an oxide, a polymer and a ceramic.

9. A method for eliminating hydrocarbon fouling in transporting and storing a water-hydrocarbon mixture, the method comprising: covering an outer surface of a pipeline for transporting and storing said water-hydrocarbon mixture with a dielectric layer; covering said dielectric layer with an external conducting layer; applying a potential difference across said dielectric layer established by applying an electrical potential to a proximity electrode immersed in a solution of said water-hydrocarbon mixture and applying an electrical potential to said external conducting layer; and forming a buffer layer of water on top of an inner surface of said pipeline by electrically attracting water from said water-hydrocarbon mixture to said buffer layer by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said inner surface of said pipeline and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

10. The method as recited in claim 9, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

11. The method as recited in claim 9, wherein said dielectric layer comprises one of the following: an oxide, a polymer and a ceramic.

12. A transportation mechanism for transporting hydrocarbons, the mechanism comprises: a pipeline for transporting a water-hydrocarbon mixture; a dielectric layer covering an outer surface of said pipeline; an external conducting layer covering said dielectric layer; a proximity electrode immersed in said water-hydrocarbon mixture, wherein a potential difference is applied across said dielectric layer established by applying an electrical potential to said proximity electrode and applying said electrical potential to said external conducting layer; and a buffer layer of water on top of an inner surface of said pipeline, wherein said water buffer layer comprises water electrically attracted from said water-hydrocarbon mixture by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said inner surface of said pipeline and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

13. The transportation mechanism as recited in claim 12, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

14. The transportation mechanism as recited in claim 12, wherein said dielectric layer comprises one of the following: an oxide, a polymer and a ceramic.

15. A method for eliminating hydrocarbon fouling in transporting and storing a water-hydrocarbon mixture, the method comprising: covering an outer surface of a pipeline for transporting said water-hydrocarbon mixture with an external capacitance; applying a potential difference across said external capacitance established by applying an electrical potential to a proximity electrode immersed in a solution of said water-hydrocarbon mixture and applying an electrical potential to said external capacitance; and forming a buffer layer of water on top of an inner surface of said pipeline by electrically attracting water from said water-hydrocarbon mixture to said buffer layer by applying said potential difference across said external capacitance, wherein said water buffer layer is located between said inner surface of said pipeline and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

16. The method as recited in claim 15, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

17. The method as recited in claim 15, wherein said external capacitance comprises a solid-state capacitor.

18. A transportation mechanism for transporting hydrocarbons, the mechanism comprises: a pipeline for transporting a water-hydrocarbon mixture; an external capacitance covering an outer surface of said pipeline; a proximity electrode immersed in said water-hydrocarbon mixture, wherein a potential difference is applied across said external capacitance established by applying an electrical potential to said proximity electrode and applying an electrical potential to said external capacitance; and a buffer layer of water on top of an inner surface of said pipeline, wherein said water buffer layer comprises water electrically attracted from said water-hydrocarbon mixture by applying said potential difference across said external capacitance, wherein said water buffer layer is located between said inner surface of said pipeline and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

19. The transportation mechanism as recited in claim 18, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

20. The transportation mechanism as recited in claim 18, wherein said external capacitance comprises a solid-state capacitor.

21. A method for eliminating hydrocarbon fouling in transporting and storing a water-hydrocarbon mixture, the method comprising: covering an inner surface of a pipeline for transporting said water-hydrocarbon mixture with a dielectric layer; applying a potential difference across said dielectric layer established by applying an electrical potential to an electrode mesh covering said dielectric layer and applying an electrical potential to said pipeline; and forming a buffer layer of water on top of said electrode mesh by electrically attracting water from said water-hydrocarbon mixture to said buffer layer by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said electrode mesh and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on said inner surface of said pipeline.

22. The method as recited in claim 21, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

23. A transportation mechanism for transporting hydrocarbons, the mechanism comprises: a pipeline for transporting a water-hydrocarbon mixture; a dielectric layer covering an inner surface of said pipeline; an electrode mesh covering said dielectric layer, wherein a potential difference is applied across said dielectric layer established by applying an electrical potential to said electrode mesh and applying an electrical potential to said pipeline; and a buffer layer of water on top of said dielectric layer, wherein said water buffer layer comprises water electrically attracted from said water-hydrocarbon mixture by applying said potential difference across said dielectric layer, wherein said water buffer layer is located between said electrode mesh and said water-hydrocarbon mixture thereby eliminating hydrocarbon fouling on an inner surface of said pipeline.

24. The transportation mechanism as recited in claim 23, wherein hydrocarbons in said water-hydrocarbon mixture comprise one or more of the following: asphaltenes, waxes and hydrates.

Description

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

[0014] A better understanding of the present invention can be obtained when the following detailed description is considered in conjunction with the following drawings, in which:

[0015] FIG. 1 is a method for preventing hydrocarbon fouling from an oil-water mixture, where the target surface is covered with a dielectric layer, in accordance with an embodiment of the present invention;

[0016] FIG. 2A is a schematic illustrating the method for preventing hydrocarbon fouling from an oil-water mixture, where the target surface is covered with a dielectric layer, in accordance with an embodiment of the present invention;

[0017] FIG. 2B is a schematic illustrating the application of a potential difference between the substrate and a proximity electrode in the liquid that selectively attracts water towards the surface thereby eliminating hydrocarbon fouling in accordance with an embodiment of the present invention;

[0018] FIG. 3 is an alternative method for preventing hydrocarbon fouling from an oil-water mixture, where the dielectric layer is not required to be placed between the target surface and the hydrocarbon-water mixture, in accordance with an embodiment of the present invention;

[0019] FIG. 4A is a schematic illustrating an alternative embodiment in which the dielectric layer is not coated on the target internal surface, but instead, on the corresponding external surface in accordance with an embodiment of the present invention;

[0020] FIG. 4B illustrates protecting the pipeline internal walls from hydrocarbon fouling in accordance with an embodiment of the present invention;

[0021] FIG. 5 is a schematic illustrating a further alternative embodiment in which the dielectric layer and the outer conducting layer are replaced with an external capacitance in accordance with an embodiment of the present invention;

[0022] FIG. 6 illustrates the use of an electrode mesh sleeve along the surface of a pipeline as opposed to using a proximity electrode in accordance with an embodiment of the present invention;

[0023] FIG. 7 illustrates the concept of core annular flow, where the viscous oil is transported as a core in a pipeline, surrounded in a lubricating layer of much less viscous water in accordance with an embodiment of the present invention; and

[0024] FIG. 8 is a graph illustrating the change in pressure drop versus the thickness of the water layer in accordance with an embodiment of the present invention.

DETAILED DESCRIPTION

[0025] While the following discusses the present invention in connection with eliminating hydrocarbon fouling and reducing the pumping power for pipeline oil transport, the principles of the present invention may be applied to other areas of technology, including, but not limited to, enhanced boiling heat transfer applications (e.g., eliminating film boiling by forcing water to wet the surface), fluid flow applications (enabling annular flows with water electrowetted walls) and nuclear applications (e.g., preventing dryout and controlling instability). A person of ordinary skill in the art would be capable of applying the principles of the present invention to such implementations. Further, embodiments applying the principles of the present invention to such implementations would fall within the scope of the present invention.

[0026] Furthermore, it is noted that the principles of the present invention described herein can be applied to protect any internal surface from fouling (e.g., surfaces inside pipelines, tubes, risers, valves, chokes, pumps, heat exchangers) regardless of the shape of the surface. A person of ordinary skill in the art would be capable of applying the principles of the present invention to such implementations. Further, embodiments applying the principles of the present invention to such implementations would fall within the scope of the present invention.

[0027] The principles of the present invention describe new methods to prevent fouling and contamination of surfaces by hydrocarbons during oil and gas production, transportation and refining. Hydrocarbon fouling in the oil and gas industry is a significant operational concern and has huge implications on efficiency, reliability and safety. The methods described herein can also be used to reduce the pumping power needed to transport highly viscous oils or other fluids via pipelines.

[0028] In one embodiment, the present invention relies on the contrast in the electrical properties of hydrocarbons and water to eliminate hydrocarbon contact with the surface that needs to be protected from fouling. By artificially forcing water to wet the surface (e.g., pipeline inner surfaces), hydrocarbon contact is eliminated (minimized) and the surface stays protected from fouling. Furthermore, in one embodiment, the present invention relies on electrically attracting water to form a water buffer layer at the surface which prevents hydrocarbon molecules from touching the surface. All types of hydrocarbon fouling (e.g., asphaltenes, waxes, hydrates) can be addressed by the methods described herein.

[0029] Referring now to the Figures, FIG. 1 is a method 100 for preventing hydrocarbon fouling from an oil-water mixture, where the target surface is covered with a dielectric layer, in accordance with an embodiment of the present invention. FIG. 1 will be discussed in conjunction with FIGS. 2A-2B. FIG. 2A is a schematic illustrating the method for preventing hydrocarbon fouling from an oil-water mixture, where the target surface is covered with a dielectric layer, in accordance with an embodiment of the present invention. FIG. 2B is a schematic illustrating the application of a potential difference between the substrate and a proximity electrode in the liquid that selectively attracts water towards the surface thereby eliminating hydrocarbon fouling in accordance with an embodiment of the present invention.

[0030] Referring to FIG. 1, in conjunction with FIGS. 2A and 2B, in step 101, an inner wall of a pipeline 201 for transporting a water-hydrocarbon mixture 202 is covered with a dielectric layer 203. As illustrated in FIGS. 2A-2B, a surface 201, such as an inner wall of a pipeline, needs fouling protection from water-hydrocarbon mixture 102 (typical of oil and gas production streams). In one embodiment, surface 201 is covered by dielectric layer 203 (e.g., oxide, polymer, ceramic, etc.). In one embodiment, dielectric layer 203 has a range in thickness from a few nanometers to a few inches depending on the application. Furthermore, dielectric layer 203 can be smooth, textured (rough) naturally or textured artificially. Additionally, the surface energy of dielectric layer 203 can range from very high to very low. Furthermore, the water wettability of dielectric layer 203 can range from superhydrophilic to superhydrophobic. The oil wettability of dielectric layer 203 can range from superoleophilic to superoleophobic. In one embodiment, dielectric layer 203 is made of a single material. In another embodiment, dielectric layer 203 is made from multiple materials. In one embodiment, dielectric layer 203 is multilayered. Furthermore, dielectric layer 203 may be corrosion resistant coating or an antifouling coating.

[0031] In step 102, an electrical potential difference is applied across dielectric layer 203 established by applying an electrical potential to a proximity electrode 204 immersed in the solution of the water-hydrocarbon mixture 202 and applying an electrical potential to surface 201. In one embodiment, the applied electrical potential corresponds to a DC voltage (positive or negative) or an AC voltage. Furthermore, the applied electrical potential can be any other complex electrical waveform. In one embodiment, proximity electrode 204 can be continuous (as shown in FIG. 2) or it can be intermittent. Proximity electrode 204 can be axially aligned with pipeline 201 (as shown in FIG. 2) or it could protrude radially into pipeline 201 via electrical feedthroughs. Proximity electrode 204 can be made of any conducting material. Furthermore, multiple proximity electrodes 204, as opposed to a single electrode, could be used to get the same performance and the spacing between the electrodes can vary greatly.

[0032] In step 103, a buffer layer 205 is formed of water on top of dielectric layer 203 by electrically attracting water from water-hydrocarbon mixture 202 to buffer layer 205 by applying the potential difference across dielectric layer 203. The externally applied voltage will selectively attract water from the water-hydrocarbon mixture 202 (shown in FIG. 2B) and maximize surface-water contact to form a water rich buffer layer 205 at surface 201.

[0033] The formation of this water buffer layer 205 is expected to significantly eliminate the propensity of hydrocarbon fouling on that surface 201. In other words, the application of an electrical voltage will make it energetically unfavorable for hydrocarbon molecules to touch dielectric layer 203. It should be noted that the principles of the present invention described herein can be applied for a variety of hydrocarbons, such as asphaltenes, waxes and hydrates, which have very different electrical properties than water. It should also be noted that the surface to be protected from hydrocarbon fouling requires the attachment of a dielectric layer 203 (which establishes the capacitive system for attracting water). In another embodiment of the present invention, dielectric layer 203 itself has antifouling chemical properties and low surface energy and will further aid the antifouling action of the present invention.

[0034] An alternative method for preventing hydrocarbon fouling from an oil-water mixture is discussed below in connection with FIG. 3. FIG. 3 is an alternative method 300 for preventing hydrocarbon fouling from an oil-water mixture, where the dielectric layer is not required to be placed between the target surface and the hydrocarbon-water mixture, in accordance with an embodiment of the present invention. FIG. 3 will be discussed in conjunction with FIGS. 4A-4B, using the same element numbers for the same elements described in FIGS. 2A and 2B. FIG. 4A is a schematic illustrating an alternative embodiment in which the dielectric layer is not coated on the target internal surface, but instead, on the corresponding external surface in accordance with an embodiment of the present invention. FIG. 4B illustrates protecting the pipeline internal walls from hydrocarbon fouling in accordance with an embodiment of the present invention.

[0035] Referring now to FIG. 3, in conjunction with FIGS. 4A-4B, in step 301, an outer surface of a pipeline wall 201 is covered with a dielectric layer 203. In this manner, surface 201 to be protected can be in intimate contact with hydrocarbon-water mixture 202.

[0036] In step 302, dielectric layer 203 is covered with an external conducting (metallic) layer 401. In this manner, the side of dielectric layer 203 opposite pipeline wall 201 can be protected.

[0037] In step 303, an electrical potential difference is applied across dielectric layer 203 established by applying an electrical potential to a proximity electrode 204 immersed in a solution of the water-hydrocarbon mixture 202 and applying an electrical potential to external conducting layer 401.

[0038] In step 304, a buffer layer of water 205 is formed on top of an inner surface of pipeline wall 201 by electrically attracting water from water-hydrocarbon mixture 202 to buffer layer 205 by applying the potential difference across dielectric layer 203 thereby protecting surface 201 from fouling.

[0039] The embodiment shown in FIGS. 4A and 4B has clear benefits over the embodiment shown in FIGS. 2A and 2B. The embodiment of FIGS. 4A and 4B does not rely on dielectric layer deposition directly on the target surface (e.g., surface 201); this has benefits for antifouling applications for internal surfaces, like the insides of pipelines. Dielectric layer deposition on such internal surfaces is often a manufacturing challenge. Such surfaces can still be protected from hydrocarbon fouling by coating the corresponding external surfaces with the dielectric layer and then forming the water buffer layer as illustrated in FIGS. 4A and 4B. Other practical issues (e.g., dielectric degradation) associated with hydrocarbon-dielectric interaction are also completely avoided as dielectric layer 203 is never in intimate contact with liquid 202. The embodiment of FIGS. 4A and 4B also makes this technology very amenable to retrofitting existing equipment and pipelines since no changes to internal surfaces are needed (making changes to external surfaces is relatively easier and less expensive).

[0040] A further alternative embodiment for preventing hydrocarbon fouling from an oil-water mixture is discussed below in connection with FIG. 5. FIG. 5 is a schematic illustrating a further alternative embodiment for preventing hydrocarbon fouling from an oil-water mixture in which the dielectric layer 203 and the outer conducting layer 401 of FIGS. 4A and 4B are replaced with an external capacitance 501 in accordance with an embodiment of the present invention. In this manner, a dielectric layer is no longer needed to be deposited to the inner or outer surface. The principles of the present invention as discussed above in connection with FIGS. 3 and 4A-4B apply to the embodiment of FIG. 5 except that a potential difference is applied across external capacitance 501 established by applying an electrical potential to proximity electrode 204 immersed in a solution of the water-hydrocarbon mixture 202 and applying an electrical potential to external capacitance 501. All the other aspects discussed above in connection with FIGS. 3 and 4A-4B apply to FIG. 5 and will not be reiterated for the sake of brevity.

[0041] Referring to FIG. 5, the capacitive action of a dielectric layer (either on the inside or outside) can be obtained by adding a solid state capacitor 501 to surface 201 to be protected. In one embodiment, capacitor 501 would be electrically connected in series to surface 201, and would have the same working action as the capacitance of a dielectric layer. As a result, such an embodiment is advantageous since the deposition and durability of dielectric layers can be expensive and often needs development of new manufacturing technologies. Also, the technical risks due to dielectric layer degradation are completely eliminated with this embodiment. Furthermore, capacitor 501 can be mounted far away from the actual surface 201 which makes this technology more practical in certain applications (e.g., boiler tubes, wherein having a capacitor mounted on a hot surface is not desirable). This embodiment of adding a solid state capacitor 501 has been tested and the obtained results are similar to the results obtained by a surface dielectric layer.

[0042] A further alternative embodiment is to replace proximity electrode 204 of FIGS. 2A-2B, 4A, 4B and 5 with an electrode mesh sleeve along the pipeline as illustrated in FIG. 6.

[0043] FIG. 6 illustrates the use of an electrode mesh sleeve 601 along the surface of pipeline 201 as opposed to using proximity electrode 204 in accordance with an embodiment of the present invention. The use of an electrode mesh sleeve 601 is easier to implement than the use of a proximity electrode 204 and hence will aid in the implementation of this technology. As illustrated in FIG. 6, a potential difference is applied across dielectric layer 203 established by applying an electrical potential to electrode mesh sleeve 601 and applying an electrical potential to surface 201. As a result, a buffer layer 205 of water is formed on top of electrode mesh sleeve 601 by electrically attracting water from water-hydrocarbon mixture 202 to buffer layer 205. The externally applied voltage will selectively attract water from the water-hydrocarbon mixture 202 and maximize surface-water contact to form a water rich buffer layer 205 at surface 201.

[0044] While FIG. 6 illustrates the replacement of proximity electrode 204 in FIGS. 2A and 2B with electrode mesh sleeve 601, proximity electrode 204 may be replaced with the use of electrode mesh sleeve 601 in any of the embodiments discussed herein, including the embodiments of FIGS. 4A, 4B and 5.

[0045] Furthermore, the principles of the present invention can also be utilized to reduce the pumping power required to transport viscous oils through pipelines. The viscosity of certain heavy oils can be 1,000 times greater than the viscosity of water, which leads to very high pressure drop requirements and power consumption by the pipeline. By electrically forcing water to wet the surface (e.g., surface 201 of FIGS. 2A-2B, 4A-4B, 5 and 6), a buffer water layer (e.g., water buffer layer 205 of FIGS. 2B, 4A-4B, 5 and 6) can be created at the pipeline walls which will act as a lubricant for oil transport as shown in FIG. 7.

[0046] FIG. 7 illustrates the concept of core annular flow, where viscous oil 701 is transported as a core in a pipeline 700, surrounded in a lubricating layer 702 of much less viscous water in accordance with an embodiment of the present invention. As illustrated in FIG. 7, pipeline 700 will still transport oil 701 in its core, but the pumping power will be substantially reduced because of the lubricating aspect of water layer 702. This concept of transporting oil in a water sheath is termed herein as core annular flow. A practical challenge in present day core annular flow technology is the generation and maintenance of water buffer layers. The present invention can generate and maintain a stable water layer at the interface by keeping the interior walls of the pipeline water wetted using any of the three configurations depicted in FIGS. 2A-2B, 4A-4B, 5 and 6.

[0047] Furthermore, by generating and maintaining a lubricating water layer at the wall to enable low pumping power transport of viscous oil, the pumping pressure drop can be reduced 10 times by using a core annular flow pumping scheme (water-oil) as compared with pumping of viscous oil alone as shown in FIG. 8. FIG. 8 is a graph 800 illustrating the change in pressure drop versus the thickness of the water layer (water layer 702 of FIG. 7) in accordance with an embodiment of the present invention. As illustrated in FIG. 8, in conjunction with FIG. 7, depending on the thickness of the lubricating water layer 702, significant reduction in pressure drop can be realized for the core annular flow (2 fluid) pumping scheme as compared to the baseline oil pumping scheme.

[0048] The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.