MODIFIED FORWARD OSMOSIS MEMBRANE MODULE FOR FLOW REGIME IMPROVEMENT

20170072366 ยท 2017-03-16

    Inventors

    Cpc classification

    International classification

    Abstract

    To provide a modified forward osmosis (FO) membrane module for flow regime improvement, the FO membrane module includes but not limited to: a water inlet; a water outlet; a forward osmosis (FO) membrane; a frame; and folded plates for improving flow regime in which draw solution is introduced into the water inlet of membrane module, then flowed through flow channels composed by three opposite folded plates vertically arranged on upper and bottom portions of the frame alternatively along horizontal direction with equal space; and drawn out from the water outlet. The flow regime improvement is achieved by increasing number of flow-guide folded plate, which results in the decrease of internal concentration polarization and membrane fouling. Structure of frame is modified to improve flow regime and to satisfy requirement of convenient and reliable connections between numbers of membrane modules in the FO membrane system.

    Claims

    1. A forward osmosis membrane module, which is characterized in comprising: a water inlet; a water outlet; a forward osmosis membrane; a frame; at least one of internal folded plates for improving flow regime; an air vent; a intercommunicating hole; said water inlet, said forward osmosis membrane, said folded plates and said water outlet are set on the frame forming modularized membrane module; draw solution is introduced into the membrane module through said water inlet, and then through flow channels composed by three opposite folded plates vertically arranged on upper and bottom portions of said frame alternatively along horizontal direction with equal space; and then drawn out from the water outlet.

    2. A forward osmosis membrane module of claim 1, which is characterized in: said internal folded plates for improving flow regime using opposite folded plate mode aims to improve the flow regime and to generate vortex; said air vent is set on connecting part of upper folded plates and said frame of modularized membrane module; said intercommunicating hole is set on connecting part of bottom folded plates and said frame of modularized membrane module; Preferred, a folding angle of said internal folded plates for improving flow regime is 90, through which flow rate is preferred to be 20 cm.Math.s.sup.1 at peaks of said internal folded plates for improving flow regime, and flow rate is preferred to be 5 cm.Math.s.sup.1 at valleys of said internal folded plates for improving flow regime; vortex is formed in flow channel composed by said internal folded plates for improving flow regime to get better mixture of liquids.

    3. A forward osmosis membrane module of claim 1, which is characterized in: said frame of modularized membrane module using folded plate to promote flow regime of inlet flow channel and outlet flow channel; said frame of modularized membrane module has A and B surfaces matching each other to guarantee reliable joint of different FO membrane module; Preferred, said frame of modularized membrane module is strictly symmetry with the folded plates for improving flow regime; the A and B surfaces of the frame match each other.

    4. A forward osmosis membrane module of claim 2, which are characterized in: to said air vent and intercommunicating hole of the forward osmosis membrane module, Air inside the forward osmosis membrane module is vented through the air vent to avoid short-stream caused by air accumulation; Flow shock is reduced, flow regime in bottom of components of the FO membrane module is improved, and the dead angle is avoid by the setting of intercommunicating hole.

    Description

    BRIEF DESCRIPTION OF DRAWINGS

    [0015] FIG. 1 shows the scheme of a FO membrane module according to an embodiment of the present disclosure.

    [0016] FIG. 2 shows the scheme of the internal folded plates of FO membrane module according to an embodiment of the present disclosure.

    [0017] FIG. 3 shows the flow regime between membrane components such as internal folded plates of the FO membrane module according to an embodiment of the present disclosure.

    [0018] FIG. 4(a).(b) shows the structure and assembly of frame of the FO membrane module according to an embodiment of the present disclosure.

    LIST OF REFERENCE NUMBERS

    [0019] 1water input, 2water outlet, 3FO membrane, 4A surface of frame of modularized membrane module, 5B surface of frame of modularized membrane module, 6internal folded plate for improving flow regime, 7air vent, 8intercommunicating hole .

    DETAILED DESCRIPTION OF THE INVENTION

    [0020] The present disclosure relates to structure design of a forward osmosis (FO) membrane module for improving internal flow regime. Number of internal flow-guide folded plates is increased to get better flow regime by increasing the disturbance of flow and decreasing internal concentration polarization and membrane fouling. Described herein are improved designs of frame providing enhanced flow regime as well as reliable and convenient joint of numbers of membrane components.

    [0021] In the following content, aspects and features of the modified forward osmosis membrane module for flow regime improvement will be described in detail with reference numbers to the drawings:

    [0022] As shown in FIG. 1-4, a forward osmosis membrane module for improving flow regime includes but is not limited to: 1water input, 2water outlet, 3FO membrane, 4A surface of frame of modularized membrane module, 5B surface of frame of modularized membrane module, 6internal folded plate for improving flow regime, 7air vent, and 8intercommunicating hole. Said water input 1 and water outlet 2 are set on two ends of upper part of said frame of modularized membrane module respectively. FO membrane 3 is adhered to front and back surface of said frame of modularized membrane module, three folded plates for improving flow regime employs opposite folded plate mode and are vertically arranged inside of said frame of modularized membrane module alternatively along horizontal direction with equal space.

    [0023] Left and right ones of said three folded plates for improving flow regime are upper folded plates displaced on the upper part of the frame of FO membrane module, and air vent 7 is set on the connection part of these upper folded plates and said frame to exhaust air inside of membrane module and then to avoid short stream of flow caused by air accumulation. Middle one of said three folded plates for improving flow regime are bottom folded plate, and intercommunicating hole 8 is set on the connection part of bottom folded plate and said frame of FO membrane module to reduce flow shocks on folded plates, and to improve flow regime at the bottom of FO membrane module to avoid dead angle of flows. A folding angle of folded plates is set to be 60-120; and flow rate is preferred to be 20 cm.Math.s.sup.1 and 5 cm.Math.s.sup.1 at peaks and valleys of the folded plates, respectively. Materials of said folded plates are ABS plastic or PMMA.

    [0024] Said structure of frame of modularized membrane module is same with the folded plate as shown in FIG. 4, to improve flow regime in inlet channels and outlet channels, respectively. Surface A is designed to be matched with Surface B of the frame to firmly connect different modules in the FO membrane module.

    [0025] As shown in FIG. 1, draw solution is introduced into said inlet of membrane module, passed through the channels composed by the three opposite folded plates vertically arranged inside of frame of the modularized membrane module subsequently, and then drawn out through said water outlet. The peaks of two close folded plates are displaced to be face-to-face and so are valleys. Shrunken-enlarged flow is formed in turn to improve flow regimes in the channels of folded plates by generating vortex. The vortex promotes internal mixture of liquids and mitigates concentration polarization of membrane surfaces.

    EMBODIMENTS

    [0026] The present invention will be further described below with reference to specific examples. However, these examples should not be construed to limiting the scope of the present invention.

    Example 1

    [0027] Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A-surface of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B-surface of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sub.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1.

    [0028] Parameters of the FO membrane module in Example 1 are: folding angle is 60, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 4.6 cm.Math.s.sup.1.

    [0029] Operating parameters of the FO membrane module in Example 1 are: water temperature is 16.2 C., pH=6.5; draw solution is 1M NaCl; and stable operating flux is 7.4 LMH.

    [0030] Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sup.3N, and TP all are not detected.

    Example 2

    [0031] Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A-surface of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B-surface of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sup.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1

    [0032] Parameters of the FO membrane module in Example 2 are: folding angle is 90, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 5.4 cm.Math.s.sup.1.

    [0033] Operating parameters of the FO membrane module in Example 1 are: water temperature is 16.4 C., pH=6.4; draw solution is 1M NaCl; and stable operating flux is 8.0 LMH.

    [0034] Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sup.3N, and TP all are not detected.

    Example 3

    [0035] Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A-surface of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B-surface of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sub.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1

    [0036] Parameters of the FO membrane module in Example 3 are: folding angle is 120, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 6.7 cm.Math.s.sup.1.

    [0037] Operating parameters of the FO membrane module in Example 3 are: water temperature is 16.7 C., pH=6.4; draw solution is 1M NaCl; and stable operating flux is 7.6 LMH.

    [0038] Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sub.3N, and TP all are not detected.

    [0039] Although the above aspects and embodiments are described separately for convenience and clarity, it is contemplated that the above aspects and embodiments may be combined without departing from the scope of the present disclosure.

    [0040] It should be understood that the foregoing description is only illustrative of the present disclosure. Various alternatives and modifications can be devised by those skilled in the art without departing from the disclosure. Accordingly, the present disclosure is intended to embrace all such alternatives, modifications and variances. The embodiments described with reference to the attached drawing figures are presented only to demonstrate certain examples of the disclosure. Other elements, steps, methods and techniques that are insubstantially different from those described above and/or in the appended claims are also intended to be within the scope of the disclosure.