Single photon device, apparatus for emitting and transferring single photon, and methods of manufacturing and operating the same

Abstract

Provided are single photon devices, single photon emitting and transferring apparatuses, and methods of manufacturing and operating the single photon devices. The single photon device includes a carrier transport layer disposed on a conductive substrate and at least one quantum dot disposed on the carrier transport layer. A single photon emitting and transferring apparatus includes a single photon device, an element that injects a single charge into the single photon device described above, a light collecting unit that collects light emitted from the single photon device, and a light transfer system that transmits light collected by the light collecting unit to the outside.

Claims

1. A single photon-emitting and transferring apparatus comprising: a single photon device; an element that injects a single charge into the single photon device; a light collecting unit that collects light emitted from the single photon device; and a light transfer system that transmits the light collected by the light collecting unit externally, wherein the single photon device comprises: a substrate; a carrier transport layer disposed on the substrate; and at least one quantum dot disposed on the carrier transport layer, wherein the carrier transport layer is disposed between the at least one quantum dot and the substrate; and wherein the single photon device and the element that injects the single charge into the single photon device are arranged such that the single charge is emitted directly into the at least one quantum dot in the single photon device.

2. The single photon emitting and transferring apparatus of claim 1, wherein the element that injects the single charge is a scanning tunneling microscope tip.

3. The single photon emitting and transferring apparatus of claim 1, wherein the light transfer system is an optical fiber.

4. The single photon emitting and transferring apparatus of claim 1, wherein the carrier transport layer is a hole transport layer.

5. The single photon emitting and transferring apparatus of claim 4, wherein the hole transport layer is one of a poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,40-(N-(4-sec-butylphenyl))diphenylamine (TFB) layer, a N,N-diphenyl-N,N-bis(3-methylphenyl)-(1,1-biphenyl)-4,4diamine (TPD) layer, a polyvinylcarbazole (PVK) layer, a p-TPD layer, an inorganic p-type oxide layer, and an inorganic p-type semiconductor layer.

6. The single photon emitting and transferring apparatus of claim 5, wherein the hole transport layer is an NiO layer.

7. The single photon emitting and transferring apparatus of claim 5, wherein the hole transport layer is a CuS layer or a ZnTe layer.

8. A method of operating a single photon device that comprises a conductive substrate and at least one quantum dot, the method comprising: injecting from an STM tip a single charge directly into the at least one quantum dot; and injecting a hole into the at least one quantum dot through a carrier transport layer, wherein the carrier transport layer is interposed between the conductive substrate and the quantum dot.

9. The method of claim 8, wherein the injecting of the single charge and the single hole into the at least one quantum dot comprises: placing the STM tip above the at least one quantum dot; and injecting the single charge and the single hole into the at least one quantum dot by applying a voltage between the STM tip and the conductive substrate.

10. The method of claim 8, wherein the carrier transport layer is one of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,40-(N-(4-sec-butylphenyl))diphenylamine (TFB) layer, a N,N-diphenyl-N,N-bis(3-methylphenyl)-(1,1-biphenyl)-4,4diamine (TPD) layer, a polyvinylcarbazole (PVK) layer, a p-TPD layer, an inorganic p-type oxide layer, and an inorganic p-type semiconductor layer.

11. The method of claim 8, wherein the at least one quantum dot is included in a quantum dot film that is formed on the carrier transport layer.

12. The single photon-emitting and transferring apparatus of claim 4, wherein the hole transport layer is an NiO layer, a CuS layer, or a ZnTe layer.

13. The single photon-emitting and transferring apparatus of claim 4, wherein an element of the single photon device that is closest to the element that injects a single charge into the single photon device is the at least one quantum dot disposed on the hole transport layer.

14. The single photon emitting and transferring apparatus of claim 4, wherein the hole transport layer is one of a poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,40-(N-(4-sec-butylphenyl))diphenylamine (TFB) layer, a N,N-diphenyl-N,N-bis(3-methylphenyl)-(1,1-biphenyl)-4,4diamine (TPD) layer, a polyvinylcarbazole (PVK) layer, and a p-TPD layer.

15. The method of claim 8, wherein the carrier transport layer is one of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,40-(N-(4-sec-butylphenyl))diphenylamine (TFB) layer, a N,N-diphenyl-N,N-bis(3-methylphenyl)-(1,1-biphenyl)-4,4diamine (TPD) layer, a polyvinylcarbazole (PVK) layer, and a p-TPD layer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The above and/or other aspects will become apparent and more readily appreciated from the following description of exemplary embodiments, taken in conjunction with the accompanying drawings of which:

(2) FIG. 1 is a cross-sectional view of a single photon device and an apparatus for emitting and transferring a single photon, according to an exemplary embodiment;

(3) FIG. 2 is a cross-sectional view of a single photon device and an apparatus for emitting and transferring a single photon, according to another exemplary embodiment;

(4) FIG. 3 is a cross-sectional view showing a quantum dot film formed on a carrier transport layer in the single photon devices of FIGS. 1 and 2; and

(5) FIG. 4 is a cross-sectional view showing the variation of energy level around a quantum dot located on a carrier transport layer in the single photon devices of FIGS. 1 through 3.

DETAILED DESCRIPTION

(6) Single photon devices, apparatuses for emitting and transferring a single photon, and methods of manufacturing and operating single photon devices according to exemplary embodiments will be described with reference to the accompanying drawings. In the drawings, lengths and sizes of layers and regions are not necessarily drawn to scale and may be exaggerated for the sake of clarity.

(7) First, a single photon device and an apparatus for emitting and transferring a single photon including the single photon device according to an exemplary embodiment will be described.

(8) FIG. 1 is a cross-sectional view of a single photon device and an apparatus for emitting and transferring a single photon including the single photon device, according to an exemplary embodiment. Referring to FIG. 1, a carrier transport layer 32 is formed on a substrate 30. The substrate 30 may be a conductive substrate, and for example, may be formed from gold or other metals, or may be a conductive substrate containing a metal component. The carrier transport layer 32 may be, for example, a hole transport layer. The carrier transport layer 32 may range in thickness from about 1 nm to about 500 nm. The hole transport layer may be, for example, a poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,40-(N-(4-sec-butylphenyl))diphenylamine (TFB) layer, a N,N-diphenyl-N,N-bis(3-methylphenyl)-(1,1-biphenyl)-4,4diamine (TPD) layer, a polyvinylcarbazole (PVK) layer, a p-TPD layer, an inorganic p-type oxide layer, or an inorganic p-type semiconductor layer. The inorganic p-type oxide layer may be, for example, an NiO layer. The inorganic p-type semiconductor layer may be, for example, a CuS layer or a ZnTe layer. A single quantum dot 34 is disposed on the carrier transport layer 32. The quantum dot 34 may be a colloidal quantum dot. The quantum dot 34 may include CdSe, CdS, CdTe, InP, ZnSe, ZnS, PbS, PbSe, PbTe, CdSe/CdS, or CdSe/CdS/ZnS. A light collecting unit 40 is formed on the carrier transport layer 32. The light collecting unit 40 is separated from the carrier transport layer 32. The light collecting unit 40 collects light emitted from the quantum dot 34 and delivers the light to a light transfer system 42. The light collecting unit 40 may include a light collecting element or an optical element (or an optical device) (not shown) for collecting the light emitted from the quantum dot 34. The light collecting element or the optical element may be, for example, a Near-Field Scanning Optical Microscope (NSOM). The light transfer system 42 may be connected to the optical element. Light collected by the light collecting unit 40 is transmitted to places where the light is needed through the light transfer system 42. A device or a system for handling an optical signal may be connected to the light transfer system 42. The light transfer system 42 may be an optical wave guide, for example, an optical fiber. For convenience, the light collecting unit 40 and the light transfer system 42 together are referred to herein as a light collection-transfer unit.

(9) A scanning tunneling microscope (STM) tip 36 may be provided in the light collecting unit 40. The STM tip 36 may be disposed so as to face the quantum dot 34. For example, the STM tip 36 may be disposed directly above the quantum dot 34. The STM tip 36 may be present in a position not directly above the quantum dot 34, if necessary. For example, the STM tip 36 may be disposed so as to horizontally face the quantum dot 34. When the quantum dot 34 is disposed on the carrier transport layer 32, as depicted in FIG. 4, an energy level (E) around the quantum dot 34 is changed. The position of the single quantum dot 34 may be found by detecting the variation of the energy level using the STM tip 36, and accordingly, the STM tip 36 may be positioned close to the single quantum dot 34. The STM tip 36 may be formed from a material selected from the group consisting of, for example, tungsten, molybdenum, gold, aluminum, and silver.

(10) Next, the STM tip 36 is connected to an end of a power source 38. The power source 38 may be disposed outside the light collecting unit 40. The other end of the power source 38 is connected to the substrate 30.

(11) In FIG. 1, the configuration that includes the substrate 30, the carrier transport layer 32, and the quantum dot 34 (in the case of FIG. 3, a quantum dot film 60) may be a configuration of a device that emits a single photon, i.e., a single photon device. A configuration that further includes the STM tip 36, the light collecting unit 40, and the light transfer system 42 may be a configuration of a single photon emitting and transferring apparatus.

(12) Hereinafter, the injection of a carrier into the quantum dot 34 and the process of emitting light from the quantum dot 34 by injecting the carrier will be briefly described.

(13) When a potential difference is formed between the STM tip 36 and the substrate 30 by the power source 38, charges, for example, electrons, are emitted from the STM tip 36, and are injected into the quantum dot 34. At this point, a single charge (electron) may be injected into the quantum dot 34 by controlling the current.

(14) In this way, when a single charge is injected into the quantum dot 34 from the STM tip 36, a hole is simultaneously injected into the quantum dot 34 from the substrate 30 through the carrier transport layer 32. The electron and the hole that are injected into the quantum dot 34 form an exciton in the quantum dot 34. When the exciton disappears, light having energy corresponding to a band gap of the quantum dot 34 is emitted from the quantum dot 34.

(15) When a single charge is injected into the quantum dot 34 by controlling the bias and current of the STM tip 36, a single exciton is formed in a single quantum dot 34. That is, a single photon may be emitted from the single quantum dot 34 by controlling the bias and current of the STM tip 36. The STM tip 36 is one of various elements that may inject a single charge into the single quantum dot 34. Accordingly, any element (a device, an apparatus, or a system) that may inject a single charge into the single quantum dot 34 may be used as an alternative to the STM tip 36.

(16) FIG. 2 is a cross-sectional view of a single photon device according to another exemplary embodiment. For the sake of brevity, only differences from the single photon device of FIG. 1 are described below.

(17) Referring to FIG. 2, a plurality of light collection-transfer units 50 is provided on the carrier transport layer 32. The light collection-transfer units 50 may form a light collection-transfer array 70. In FIG. 2, for convenience of explanation, three light collection-transfer units 50 are depicted, but the light collection-transfer array 70 may include more or less than three light collection-transfer units 50. Each of the light collection-transfer units 50 includes a light collecting unit 52 and a light transfer system 54 that is connected to the light collecting unit 52. The light transfer system 54 may be the same as the light transfer system 42 of FIG. 1. The configuration and performance of the light collecting unit 52 may be the same as that of the light collecting unit 40 of FIG. 1. An STM tip may be included in each light collecting unit 52 as in the light collecting unit 40 of FIG. 1. However, for convenience of explanation, the STM tip is not shown in FIG. 2. A plurality of quantum dots 34 are adsorbed on the carrier transport layer 32. The light collecting units 52 respectively correspond to the quantum dots 34. That is, the STM tips respectively correspond to the quantum dots 34. Accordingly, single charges may be individually injected into the quantum dots 34 through the STM tips, and simultaneously, holes may be each injected into the quantum dots 34 through the carrier transport layer 32. As a result, excitons are formed in each of the quantum dots 34, and when the excitons disappear, light having energy corresponding to the energy band gap of each of the quantum dots 34 is emitted from each of the quantum dots 34. Light emitted in this way is collected by the light collection-transfer array 70, and is delivered to, for example, an optical signal processing apparatus or an optical signal analysis apparatus through the light transfer system 54.

(18) FIG. 3 is a cross-sectional view showing a quantum dot film 60 formed on the carrier transport layer 32 in the single photon devices of FIGS. 1 and 2. The quantum dot film 60 includes a plurality of quantum dots 34.

(19) Referring to FIG. 3, the quantum dot film 60 covers an entire upper surface of the carrier transport layer 32. The quantum dot film 60 may be formed by baking a material that includes the quantum dots 34 after coating the material on the carrier transport layer 32 using a spin coating method. Light collection-transfer units 50 are formed on the quantum dot film 60. The light collection-transfer array 70 of FIG. 2 may also be provided on the quantum dot film 60.

(20) Next, a method of manufacturing a single photon-emitting device (a single photon device) according to an exemplary embodiment will be briefly described with reference to FIG. 3.

(21) The carrier transport layer 32 is formed on the conductive substrate 30. The carrier transport layer 32 may be a hole transport layer. The quantum dot film 60 is formed on the carrier transport layer 32. The quantum dot film 60 may be formed by using a spin coating method. Instead of the quantum dot film 60, a single quantum dot 34 or a plurality of quantum dots 34 may be formed.

(22) Next, a method of operating the single photon device will be described with reference to FIG. 1.

(23) The STM tip 36 is placed on the quantum dot 34. A potential difference is formed between the STM tip 36 and the substrate 30. That is, a voltage is applied to the STM tip 36 and the substrate 30. At this point, a single charge may be injected into the quantum dot 34 from the STM tip 36 by controlling a current that is applied to the STM tip 36, and a single hole may be injected into the quantum dot 34 from the substrate 30 through the carrier transport layer 32. As a result, a single photon may be emitted from the quantum dot 34, as described above. The single photon emitted from the quantum dot 34 is delivered to the outside through the light collecting unit 40 and the light transfer system 42.

(24) It should be understood that the exemplary embodiments described herein should be considered to be descriptive only and not limiting. Descriptions of features or aspects within each embodiment should typically be considered as being available for other similar features or aspects in other embodiments.